KR880010106A - 인 함량이 낮은 윤활유 - Google Patents

인 함량이 낮은 윤활유 Download PDF

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KR880010106A
KR880010106A KR1019880002058A KR880002058A KR880010106A KR 880010106 A KR880010106 A KR 880010106A KR 1019880002058 A KR1019880002058 A KR 1019880002058A KR 880002058 A KR880002058 A KR 880002058A KR 880010106 A KR880010106 A KR 880010106A
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South Korea
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composition
copper
fat
phosphorus
ppm
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KR1019880002058A
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KR960014933B1 (ko
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테렌스 콜클로흐
존 프레드릭 마쉬
프레드릭 알리스테어 깁슨
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원본미기재
엑손 케미칼 페이턴츠 아이엔씨
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Abstract

내용 없음

Description

인 함량이 낮은 윤활유
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (24)

  1. 대부분의 윤활유와 지용성 형태로 부가된 구리 5-500 ppm(질량), 하나이상의 부가된 지용성 황 함유 화합물로 구성되어 총 황 함량이 0.5-2.0 wt% 이상이 되고 효과적인 양의 베어링 부식 억제제를 함유하며 0.01 wt% 미만의 인을 함유하는 자동차 엔진에 이용되는 크랭크실 윤활유 조성물.
  2. 제1항에 있어서, 부가된 구리의 양이 10-400 ppm인 조성물.
  3. 제2항에 있어서, 부가된 구리의 양이 10-200 ppm인 조성물.
  4. 제3항에 있어서, 부가된 구리의 양이 60-200 ppm인 조성물.
  5. 제1항 부터 제4항까지중 어느 한 항에 있어서, 구리가 C10-C18지방산, 불포화 카복실산, 분자량이 200-500인 나프텐산 또는 알킬 또는 알케닐 치환된 디카복실산 등의 구리염 형태로서 오일에 혼합되거나 또는 n이 1 또는 2이고 R 및 R'가 동일하거나 상이한 바 C1-18을 함유하는 하이드로카빌 라디칼인 일반식(RR'NCSS)nCu 인 지용성 코퍼디티오카바메이트, 코퍼 설포네이트, 코퍼 페네이트 또는 코퍼 아세틸아세토네이트 등으로 오일에 혼합되는 조성물.
  6. 전기한 항중 어느 한 항에 있어서, 지용성 황 화합물이 일반식 (RR'NCSS)nM (여기서 R, R' 및 n은 제3항에서와 동일하고 M은 적당한 금속)의 디티오카바메이트 또는 머캅타이드 황화된 불포화 유기 화합물, 설파이드, 티오에테르, 티오페놀, 티옥산테이트, 황화된 에스테르, 티오에스테르, 티오아이드. 티아졸 또는 티아디아졸인 조성물.
  7. 제6항에 있어서, 지용성 황 화합물이 C2-12를 함유하는 디알킬 디티오카바메이트인 조성물.
  8. 전기한 항중 어느 한 항에 있어서, 0.5-1.0 wt% 이상의 전체 S를 함유하고 부가된 지용성 황 함유 화합물로서 0.1-0.5 wt%의 S를 포함하는 조성물.
  9. 전기한 항중 어느 한 항에 있어서, 0.01-0.5 wt% Zn을 함유하는 조성물.
  10. 제6항에 있어서, 0.5-3 wt%의 징크 디티오카바메이트를 함유하는 조성물.
  11. 전기한 항중 어느 한 항에 있어서, 베어링 부식 억제제가 다음 일반식의 하나 이상의 보레이트 에스테르 ; B(OR)3, (RO)2B-O-B(OR)2(ROBO)3또는 (RO2)BOR1OB(OR)2식중, R은 치환되거나 비치환된 알킬, 아릴 또는 아랄킬 그룹 또는 두개의 그룹 R이 함께 치환된 또는 치환된 알킬렌 그룹을 형성하고, R1은 치환되거나 또는 비치환된 알킬렌 그룹 및/또는 C5-50을 함유하는 티아디아졸 폴리설파이드 및 이들 중합체의 유도체로 구성된 조성물.
  12. 제11항에 있어서, 0.01-10 wt%의 보레이트 에스테르를 함유한 조성물.
  13. 제11항 또는 제12항에 있어서, 보레이트 에스테르가 트리스(에톡시에틸) 오르토보레이트 에스테르 또는 부탄-1,3-디올의 바이보레이트인 조성물.
  14. 제11항에 있어서, 0.01-10 wt%의 2.5-비스(t-노닐디티오)-1,3,4-티아디아졸을 함유하는 조성물.
  15. 전기한 항중 어느 한 항에 있어서, 0.005 wt% 미만 인을 함유하는 조성물.
  16. 제15항에 있어서, 실제로 인이 전혀 없는 조성물.
  17. 전기한 항중 어느 한 항에 있어서, (A) 1-10 wt%의 무회 분산제 화합물 및/또는 (B) 점도지수 개선 중합체 분산제를 함유하는 0.3-10 wt%의 질소 또는 에스테르로 더욱 구성된 조성물.
  18. 전기한 항중 어느 한 항에 있어서, 2-8000 ppm의 칼슘 및/또는 마그네슘으로 구성된 조성물.
  19. 18항에 있어서, 염기성 칼슘 및/또는 마그네슘 설포네이트로서 500-5000 ppm의 칼슘 및/또는 마그네슘으로 구성된 조성물.
  20. 전기한 항중 어느 한 항에 있어서, 하나이상의 녹억제제, 유동점 강하제(pour point depressants), 부가 산화방지제 및 점도지수 개선제로 더욱 구성된 조성물.
  21. (1) 0.1 wt% 미만의 인 ; (2) 1-50 wt%의 지용성 황 함유 화합물 ; (3) 0.005-2 wt%의 구리 ; (4) 0.1-20 wt%의 베어링 부식억제제 ; 및 (5) 0-60 wt%의 무회의 분산제를 함유하는 오일용액으로 구성된 농축물.
  22. 제21항에 있어서, 0.01-8 wt%의 칼슘 및/또는 미그네슘으로 더욱 구성된 조성물.
  23. 지용성 황 함유 화합물, 베어링 부식억제제, 무회의 분산제 및/또는 점도지수 개선 중합체 분산제, 및 칼슘 및/또는 마그네슘을 함유하는 청정제로 구성된 인이 없는 윤활유 조성물내에서의 지용성 구리의 산화방지제로서의 용도.
  24. 0.01 wt% 미만의 인과 결합된 지용성 형태로 존재하는 부가된 구리 5-500 ppm, 총 S 0.5-2.0 wt% 이상, 산화, 마모, 부식등을 조절하기 위한 베어링 부식억제제등을 함유하며 최소한 API 엔진요구 규격의 표준 규격 SF 및/또는 CD의 품질 규격에 부합되는 자동차 엔진용 크랭크실 윤활유 조성물로서의 용도.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880002058A 1987-02-27 1988-02-27 인 함량이 낮은 윤활유 KR960014933B1 (ko)

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US8704682 1987-02-27
GB878704682A GB8704682D0 (en) 1987-02-27 1987-02-27 Low phosphorus lubricants
GB8704682 1987-02-27

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KR880010106A true KR880010106A (ko) 1988-10-07
KR960014933B1 KR960014933B1 (ko) 1996-10-21

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JP2004083746A (ja) 2002-08-27 2004-03-18 Nippon Oil Corp 内燃機関用潤滑油組成物
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US20080020952A1 (en) * 2004-10-19 2008-01-24 Kazuhiro Yagishita Lubricant Composition
CN101583702B (zh) * 2006-12-21 2013-11-13 卢布里佐尔公司 用于氢燃料发动机的润滑剂
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JP6480323B2 (ja) * 2015-12-28 2019-03-06 Jxtgエネルギー株式会社 潤滑油組成物
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ES2045102T3 (es) 1994-01-16
GB8704682D0 (en) 1987-04-01
AR244317A1 (es) 1993-10-29
JP2505019B2 (ja) 1996-06-05
BR8800835A (pt) 1988-10-04
NO880846L (no) 1988-08-29
DE3875630D1 (de) 1992-12-10
NO172853C (no) 1993-09-15
NO172853B (no) 1993-06-07
EP0280580A3 (en) 1989-07-12
CA1306741C (en) 1992-08-25
DK103788A (da) 1988-08-28
ATE82020T1 (de) 1992-11-15
DE3875630T2 (de) 1993-03-18
SG50093G (en) 1993-06-25
AU603186B2 (en) 1990-11-08
NO880846D0 (no) 1988-02-26
DK103788D0 (da) 1988-02-26
MX170110B (es) 1993-09-09
EP0280580A2 (en) 1988-08-31
AU1235188A (en) 1988-09-01
MY103223A (en) 1993-05-29
EP0280580B1 (en) 1992-11-04
ZA881262B (en) 1988-08-22
JPS63304096A (ja) 1988-12-12
KR960014933B1 (ko) 1996-10-21

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