KR880007423A - 카르보닐 화합물의 합성방법 - Google Patents
카르보닐 화합물의 합성방법Info
- Publication number
- KR880007423A KR880007423A KR860014829A KR860014829A KR880007423A KR 880007423 A KR880007423 A KR 880007423A KR 860014829 A KR860014829 A KR 860014829A KR 860014829 A KR860014829 A KR 860014829A KR 880007423 A KR880007423 A KR 880007423A
- Authority
- KR
- South Korea
- Prior art keywords
- alcohol
- carbonyl compound
- catalyst
- reaction temperature
- range
- Prior art date
Links
- 150000001728 carbonyl compounds Chemical class 0.000 title claims 4
- 238000001308 synthesis method Methods 0.000 title 1
- 238000000034 method Methods 0.000 claims 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 6
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims 3
- 239000003054 catalyst Substances 0.000 claims 3
- 238000006243 chemical reaction Methods 0.000 claims 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims 2
- 229910052760 oxygen Inorganic materials 0.000 claims 2
- 239000001301 oxygen Substances 0.000 claims 2
- 229910052709 silver Inorganic materials 0.000 claims 2
- 239000004332 silver Substances 0.000 claims 2
- 230000015572 biosynthetic process Effects 0.000 claims 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 claims 1
- 239000002360 explosive Substances 0.000 claims 1
- 239000008246 gaseous mixture Substances 0.000 claims 1
- 150000003378 silver Chemical class 0.000 claims 1
- 238000003786 synthesis reaction Methods 0.000 claims 1
- 239000012808 vapor phase Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
- C07C45/39—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups being a secondary hydroxyl group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
- C07C45/38—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups being a primary hydroxyl group
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
내용 없음.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (12)
- 알코올 대 산소의 농도가 폭발한계 이하인, 알코올과 산소를 함유하는 기체혼합물을 은으로 된 촉매상에 통과시키는 것으로 되어 있는 것을 특징으로 하는 알코올로부터 카르보닐 화합물을 증기상 합성하는 방법.
- 제1항에 있어서, 반응온도가 200 내지 450℃의 범위인 것을 특징으로 하는 방법.
- 제1항에 있어서, 반응온도가 250 내지 400℃의 범위인 것을 특징으로 하는 방법.
- 제1항 내지 3항중의 어느 하나에 있어서, 반응온도가 대기압이상으로(위의) 0.01 내지 0.35㎏㎠의 범위인 것을 특징으로 하는 방법.
- 제1항 내지 4항중 어느 하나에 있어서, 촉매가 은 금속으로 되어 있는 것을 특징으로 하는 방법.
- 제5항에 있어서, 은 금속이 은망(gauze)의 형으로 존재하는 것을 특징으로 하는 방법.
- 제1항 내지 4항중의 어느 하나에 있어서, 촉매가 불황성 담체위에 분산되어 있는 것을 특징으로 하는 방법.
- 제1항 내지 7항중의 어느 하나에 있어서, 알코올이 10개 이하의 탄소원자를 갖고 있는 것을 특징으로 하는 방법.
- 제1항 내지 8항중의 어느 하나에 있어서, 알코올이 6 내지 10개의 탄소원자를 갖고 있는 것을 특징으로 하는 방법.
- 제1항 내지 9항중의 어느 하나에 있어서, 알코올이 시클로헥사놀이고 카르보닐화합물이 시클로헥사논인것을 특징으로 하는 방법.
- 제1항 내지 10항중의 어느 하나에 있어서, 명세서의 실시예에 기재한 바와 같은 것을 특징으로 하는 방법.
- 제1항 내지 제11항중의 어느 한 방법에 의해 제조되는 것을 특징으로 하는 카르보닐 화합물.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8630727 | 1985-12-23 | ||
| GB868630727A GB8630727D0 (en) | 1986-12-23 | 1986-12-23 | Synthesis of carbonyl compounds |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR880007423A true KR880007423A (ko) | 1988-08-27 |
Family
ID=10609494
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR860014829A KR880007423A (ko) | 1985-12-23 | 1986-12-23 | 카르보닐 화합물의 합성방법 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US4820875A (ko) |
| EP (1) | EP0272846B1 (ko) |
| JP (1) | JPS63170331A (ko) |
| KR (1) | KR880007423A (ko) |
| DE (1) | DE3785735D1 (ko) |
| GB (1) | GB8630727D0 (ko) |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2015751A (en) * | 1934-07-13 | 1935-10-01 | Du Pont | Catalytic process for producing alicyclic ketones |
| US2918497A (en) * | 1957-12-23 | 1959-12-22 | Allied Chem | Production of phenoxyacetaldehyde |
| US3518284A (en) * | 1967-02-20 | 1970-06-30 | Shell Oil Co | Partial oxidation of organic compounds |
| US3794221A (en) * | 1971-12-06 | 1974-02-26 | Inter Polymer Res Corp | Cartridge for storing, mixing and dispensing a plurality of ingredients |
| US4097535A (en) * | 1977-01-31 | 1978-06-27 | Continental Oil Company | Preparation of aldehydes from alcohols |
| FR2460907A1 (fr) * | 1978-05-24 | 1981-01-30 | Inst Francais Du Petrole | Preparation de derives carbonyles par oxydation d'alcools par l'oxygene moleculaire |
| DE2831595A1 (de) * | 1978-07-19 | 1980-01-31 | Basf Ag | Verfahren zur herstellung von carbonylverbindungen |
-
1986
- 1986-12-23 KR KR860014829A patent/KR880007423A/ko unknown
- 1986-12-23 GB GB868630727A patent/GB8630727D0/en active Pending
-
1987
- 1987-12-10 EP EP87310852A patent/EP0272846B1/en not_active Expired - Lifetime
- 1987-12-10 DE DE8787310852T patent/DE3785735D1/de not_active Expired - Lifetime
- 1987-12-22 JP JP62323065A patent/JPS63170331A/ja active Pending
- 1987-12-23 US US07/137,001 patent/US4820875A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US4820875A (en) | 1989-04-11 |
| JPS63170331A (ja) | 1988-07-14 |
| EP0272846A3 (en) | 1989-07-26 |
| EP0272846A2 (en) | 1988-06-29 |
| GB8630727D0 (en) | 1987-02-04 |
| EP0272846B1 (en) | 1993-05-05 |
| DE3785735D1 (de) | 1993-06-09 |
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