KR880003880A - 4-메틸-1-펜텐의 제조방법 - Google Patents

4-메틸-1-펜텐의 제조방법 Download PDF

Info

Publication number
KR880003880A
KR880003880A KR1019870008330A KR870008330A KR880003880A KR 880003880 A KR880003880 A KR 880003880A KR 1019870008330 A KR1019870008330 A KR 1019870008330A KR 870008330 A KR870008330 A KR 870008330A KR 880003880 A KR880003880 A KR 880003880A
Authority
KR
South Korea
Prior art keywords
uranium
catalyst
methyl
cyclopentadienyl
alkyl
Prior art date
Application number
KR1019870008330A
Other languages
English (en)
Other versions
KR900006123B1 (ko
Inventor
씨. 스티븐스 제임스
에이.포디스 윌리암
에이. 포디스 윌리암
Original Assignee
더 다우 케미칼 캄파니
리챠드 지. 워터맨
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 더 다우 케미칼 캄파니, 리챠드 지. 워터맨 filed Critical 더 다우 케미칼 캄파니
Publication of KR880003880A publication Critical patent/KR880003880A/ko
Application granted granted Critical
Publication of KR900006123B1 publication Critical patent/KR900006123B1/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/107—Alkenes with six carbon atoms
    • C07C11/113—Methylpentenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • C07C2/34—Metal-hydrocarbon complexes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Abstract

내용 없음

Description

4-메틸-1-펜텐의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 우라늄 및 회토류금속 중에서 선택된 적어도 하나의 원소를 함유하는 촉매와 프로필렌을 4-메틸-1-펜텐이 생성되도록 하는 반응 조건하에서 접촉시킴을 특징으로 하여, 4-메틸-1-펜텐을 제조방법
  2. 제1항에 있어서, 촉매가 우라늄 디(다치환된 사이클로펜타디에닐)-하이드라이드 착화합물인 방법
  3. 제1항에 있어서 촉매를 ⒜우라늄(Ⅲ)-디-(다치환된 사이클로펜타디에닐)-하이드라이드 착화합물, ⒝우라늄(Ⅳ)-디(다치환된 사이클로펜타디에닐)-디하이드로겐 착화합물 및 ⒞우라늄(Ⅲ) 또는 우라늄(Ⅳ)-(다치환된 사이클로펜타디에닐)-알킬 착화합물 중에서 선택하고 알킬 착화합물을 수소가스와 반응시켜 하이드라이드 예비촉매를 형성시킴으로서 동일 반응계내에서 활성촉매를 제조하는 방법
  4. 제1항에 있어서, 촉매가 하기 일반식을 가지며 접촉 반응을 실질적으로 불활성인 환경하에 10℃ 내지 180℃의 온도에서 수행하는 방법
    [(Cp*)2-M+X-H(X2)]y
    상기 식에서, Cp*는 펜타합토펜타메틸 사이클로펜타디에닐이고, X는 3 도는 4이며, M은 U이고, y는 1 또는 2이다.
  5. 제3항에 있어서, 각각의 다치환된 사이클로펜타디에닐 잔기가 하기 일반식을 갖는 방법
    상기 식에서 각각의 R은 독립적으로 H, 탄소수 6이하의 알킬 또는 알킬-치환된 실릴이고, 단 적어도 두개의 R 잔기는 H가 아니다
  6. 제5항에 있어서, 각각의 R이 메틸 또는 H이고, 단 적어도 두개의 R잔기가 메틸인 방법
  7. 제4항에 있어서, X가 3 또는 4인 방법
  8. 제1항 내지 7항 중의 어느 한 항에 있어서, 기타 C6올레핀, 모든 C6화합물 또는 공정의 모든 생성물의 선택도가 적어도 94몰%인 방법
  9. 제1항 내지 7항중의 어느 한 항에 있어서, 기타 C6올레핀, 모든 C6화합물 또는 공정의 모든 생성물의 선택도가 적어도 96몰%인 방법
  10. 제1항 내지 7항중의 어느 한 항에 있어서, 기타 C6올레핀, 모든 C6화합물 또는 공정의 모든 생성물의 선택도가 적어도 99몰%인 방법
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019870008330A 1986-09-02 1987-07-30 4-메틸-1-펜텐의 제조방법 KR900006123B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US06/902,740 US4695669A (en) 1986-09-02 1986-09-02 Process for propylene dimerization
US902,740 1986-09-02
US902740 2004-07-29

Publications (2)

Publication Number Publication Date
KR880003880A true KR880003880A (ko) 1988-06-01
KR900006123B1 KR900006123B1 (ko) 1990-08-24

Family

ID=25416340

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019870008330A KR900006123B1 (ko) 1986-09-02 1987-07-30 4-메틸-1-펜텐의 제조방법

Country Status (10)

Country Link
US (1) US4695669A (ko)
EP (1) EP0258973B1 (ko)
JP (1) JPS6363628A (ko)
KR (1) KR900006123B1 (ko)
AR (1) AR243148A1 (ko)
AU (1) AU595896B2 (ko)
CA (1) CA1268487A (ko)
DE (1) DE3782587T2 (ko)
ES (1) ES2035063T3 (ko)
NO (1) NO165754C (ko)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5081231A (en) * 1987-08-27 1992-01-14 The Dow Chemical Company Uranium (III) catalyst for the selective dimerization of propylene to 4-methyl-1-pentene
US4855523A (en) * 1987-08-27 1989-08-08 The Dow Chemical Company Catalyst and process for the selective dimerization of propylene to 4-methyl-1-pentene
US4820671A (en) * 1988-01-11 1989-04-11 The Dow Chemical Company Regeneration of an organouranium catalyst
US5276220A (en) * 1992-06-18 1994-01-04 Ethyl Corporation Actinide catalyzed chain growth process
JP2003246791A (ja) * 2002-02-26 2003-09-02 Nitto Denko Corp 三価有機ランタノイド錯体、（メタ）アクリル系重合体製造用触媒および（メタ）アクリル系重合体

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA907325A (en) * 1972-08-15 G. Dewitt Earl Antiknock fuel
US3152157A (en) * 1954-03-22 1964-10-06 Ethyl Corp Preparation of cyclopentadienyl compounds of groups iiia, iiib, vb and vib metals
US2986588A (en) * 1957-09-27 1961-05-30 California Research Corp Propylene dimerization
US2968681A (en) * 1959-02-17 1961-01-17 Union Carbide Corp Method of preparing hydrogenated binaphthyls
US3095461A (en) * 1961-01-05 1963-06-25 California Research Corp Preparation of 1-alkenes
US3175020A (en) * 1961-09-15 1965-03-23 California Research Corp Production of 4-methyl-1-pentene
US3251895A (en) * 1962-07-20 1966-05-17 Chevron Res Allyl alkylation catalyst and alkylation process
US3414633A (en) * 1966-01-10 1968-12-03 Phillips Petroleum Co Dimerization of internal monoolefins
DE1592420C3 (de) * 1966-03-04 1974-02-21 Gesellschaft Fuer Kernforschung Mbh, 7500 Karlsruhe Verfahren zum Trennen von Actiniden und Überführen in die Actinid-Oxide
US3684739A (en) * 1966-04-04 1972-08-15 Edward H Mottus Polymerization of olefinic compounds and catalysts therefor
US3536632A (en) * 1967-10-10 1970-10-27 Exxon Research Engineering Co Heterogeneous catalysts
US3641188A (en) * 1968-05-08 1972-02-08 Atlantic Richfield Co Process for polymerizing olefins
US3655811A (en) * 1968-07-15 1972-04-11 Atlantic Richfield Co Olefin polymerization process
US3808150A (en) * 1968-07-15 1974-04-30 Atlantic Richfield Co Olefin polymerization process and catalyst
GB1225559A (ko) * 1968-12-19 1971-03-17
GB1233020A (ko) * 1968-12-30 1971-05-26
US3596927A (en) * 1969-10-10 1971-08-03 Exxon Research Engineering Co Production of 4-methylpentene-1
LU63721A1 (ko) * 1970-08-20 1971-12-21
US3994945A (en) * 1971-11-26 1976-11-30 Snam Progetti S.P.A. Uranium allyl compounds
BE791708A (fr) * 1971-11-26 1973-03-16 Snam Progetti Composes allyles d'uranium et leur procede de
DE2835944A1 (de) * 1978-08-17 1980-03-13 Heyl & Co Metallhaltige loesliche polymere katalysatoren fuer polymerisationen, verfahren zur herstellung derselben und ihre verwendung in polymerisationsverfahren
EP0015603B1 (en) * 1979-03-02 1983-02-02 Shell Internationale Researchmaatschappij B.V. Process for the dimerization of 1-alkenes
IT1140452B (it) * 1981-09-25 1986-09-24 Anic Spa Procedimento per la polimerizzazione di diolefine coniugate e mezzi adatti allo scopo
US4668773A (en) * 1985-03-25 1987-05-26 Northwestern University Organolanthanide catalysts
EP0268214B1 (en) * 1986-11-13 1991-08-21 Idemitsu Kosan Company Limited Process for producing propylene oligomers

Also Published As

Publication number Publication date
AR243148A1 (es) 1993-07-30
JPS6363628A (ja) 1988-03-22
NO873201D0 (no) 1987-07-30
NO165754C (no) 1991-04-10
EP0258973A3 (en) 1988-08-31
DE3782587D1 (de) 1992-12-17
ES2035063T3 (es) 1993-04-16
US4695669A (en) 1987-09-22
AU595896B2 (en) 1990-04-12
DE3782587T2 (de) 1993-03-25
NO165754B (no) 1990-12-27
EP0258973A2 (en) 1988-03-09
AU7503387A (en) 1988-03-10
CA1268487A (en) 1990-05-01
EP0258973B1 (en) 1992-11-11
NO873201L (no) 1988-03-03
KR900006123B1 (ko) 1990-08-24

Similar Documents

Publication Publication Date Title
Guo et al. Cationic Zirconium and Hafnium Isobutyl Complexes as Models for Intermediates in Metallocene-Catalyzed Propylene Polymerizations. Detection of an. alpha.-Agostic Interaction in (C5Me5) 2Hf (CH2CHMe2)(PMe3)+
Schwartz et al. Hydrozirconation: A new transition metal reagent for organic synthesis
Edelmann Cyclopentadienyl‐Free Organolanthanide Chemistry
US3591649A (en) Conversion catalyst
Plass et al. A novel transmetalation reaction: a route to transition metallatranes
Cowley et al. Organometallic chemical vapor deposition of III/V compound semiconductors with novel organometallic precursors
MY114317A (en) Supported catalyst containing rhenium and aluminium, process for the preparation thereof and use for the metathesis of olefins
Shiner et al. The mechanism of the Meerwein-Ponndorf-Verley reaction
KR880003880A (ko) 4-메틸-1-펜텐의 제조방법
Ramprasad et al. Synthesis and characterization of trans-chlorohydridobis (trimethylphosphine) platinum and an investigation of its role in olefin hydration catalysis
Koenig et al. Synthesis of novel polyfunctional nickel (II)-nickel (II) dimer Ni2Cl2 [C (SiMe3)(PMe3)] 2 by photolysis of the first [(trimethylsilyl) diazomethyl] nickel (II) complex Ni [C (N2) SiMe3] Cl (PMe3) 2
Smith et al. Oxidation of the molybdenum hydride CpMo (CO) 2 (PPh3) H. Synthesis of cis-and trans-CpMo (CO) 2 (PPh3)(NCMe)+ and the kinetics of their interconversion
US4699775A (en) Catalyst and method for producing hydrogen gas from carbon monoxide and water
FR2394557A1 (fr) Procede de preparation de polyolefines en continu
GB1502883A (en) Preparing solid titanium trichloride
Saadeh et al. Syntheses, properties, and X-ray crystal structures of the molybdenum dimers [# Cp2Mo2Br2 (CO) 2] and [# Cp2Mo2Br4](# Cp=. eta. 5-1-(2, 5-dimethoxyphenyl)-2, 3, 4, 5-tetraphenylcyclopentadienyl)
Becker et al. Lithium dibenzoylphosphide· 1, 2-Dimethoxyethane: a new 2-phospha-1, 3-dionate
US4374755A (en) Magnesium disiloxide compounds
Davis Jr et al. Reactions of coordinated molecules. 41. Addition of a platinum-hydrogen bond across a M. tplbond. C bond: a direct route to a heterodinuclear. mu.-alklylidene complex
US4820671A (en) Regeneration of an organouranium catalyst
EP0021496B1 (en) Synthesis of long-chain alkanes having terminal functionality
Chen et al. Structure of trans-[Rh (CO) Cl {P (C6H5) 3} 2]: a centrosymmetric triclinic phase
US5905162A (en) Enhanced production of bridged hafnocenes
Shapley et al. Synthesis of [Ru (N) R4][NBu4], the first alkyl complexes of ruthenium (VI)
US4366101A (en) Synthesis of long-chain alkanes having terminal functionality

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
G160 Decision to publish patent application
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 19940609

Year of fee payment: 5

LAPS Lapse due to unpaid annual fee