KR880000346B1 - The preparation method for mosquito coil - Google Patents

The preparation method for mosquito coil Download PDF

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KR880000346B1
KR880000346B1 KR1019850002467A KR850002467A KR880000346B1 KR 880000346 B1 KR880000346 B1 KR 880000346B1 KR 1019850002467 A KR1019850002467 A KR 1019850002467A KR 850002467 A KR850002467 A KR 850002467A KR 880000346 B1 KR880000346 B1 KR 880000346B1
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powder
seaweed
mosquito
mallow
seaweeds
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KR860007873A (en
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한인희
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태평양화학공업 주식회사
한정섭
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/20Combustible or heat-generating compositions
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/34Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/03Algae
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/06Coniferophyta [gymnosperms], e.g. cypress

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Plant Pathology (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Biotechnology (AREA)
  • Pest Control & Pesticides (AREA)
  • Natural Medicines & Medicinal Plants (AREA)
  • Toxicology (AREA)
  • Microbiology (AREA)
  • Mycology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The mosquito-repellent was prepd. Thus, 18g brown seaweed powder, 42g marsh mallow powder, 24g sclerophyll powder obtd. from an aromatic tree and 15.1g sawdust powder were mixed homogeneously. The mixt. was combined with 0.5g Allethrins, 0.2g dinitrophenol and 0.2g malachite Green, and shaped into a specified shape using a extruder.

Description

모기향의 제조방법Manufacturing method of mosquito scent

본 발명은 바다의 산물인 미역과(Laminariaceae)와 마미조과(Sargassaceae)의; 해조류, 아욱과(Malvaceae)에 속하는 식물 전초(全草)를 분말화하고, 공지의 침엽수 잎이나 잔가지(細枝)의 분말을 통상의 살충제인 알레드린이나 피레드린과 혼합, 성형 및 건조시켜서 모기향을 제조하는 방법에 관한 것이다.The present invention is a product of the seaweed (Laminariaceae) and Mamizoaceae (Sargassaceae); Mosquito scent by mixing powders of algae and plant vegetation belonging to Malvaceae, and mixing known powders of coniferous leaves and twigs with common insecticides, alledrin and pyredrin, It relates to a method of manufacturing.

종래의 모기향 제조방법은,Conventional mosquito flavor production method,

1. 각종 목분류, 침엽수 경엽분말에 결합제로서 합성호료인 카르복시 메틸셀루로즈나 옥수수전분, 조연제, 착색제등을 혼합 성형하는 방법.1. A method of mixing and molding various wood powders and coniferous leaf powders with a carboxymethylcellulose, corn starch, a softening agent, a coloring agent, etc., as a binder.

2. 인삼추출 잔유박 분말과 인삼잎 분말을 주로하고 결착제로서 카르복시메틸셀루로즈를 넣어 기제로 제조하는 방법(특허공고번호 : 79-1051)2. Method of preparing ginseng extract resid oil powder and ginseng leaf powder mainly and adding carboxymethyl cellulose as a binder (Patent No. 79-1051)

3. 침엽수 경엽분말과 운항과 식물의 과피나 열매 분말을 기제로 제조하는 방법(특허공고번호 : 80-1362)3. Method of manufacturing the coniferous foliage powder and the operation and plant peel or fruit powder as a base (Patent Publication No. 80-1362)

4. 침엽수 경엽분말과 살충협력 성분으로 니코틴 성분을 저농도로 한 엽연초 줄기 분말, 합성 결착제로 카복시 메틸세루로즈나 아라비아고무, 전분 등을 혼합한 기제로 제조하는 방법(특허공고번호 : 79-1622)4. A method of manufacturing a leaf tobacco powder with low concentration of nicotine as a coniferous foliage powder and pesticidal cooperative component, and a method of preparing a base of a mixture of carboxy methyl cellulose, gum arabic, and starch as a synthetic binder (Patent No. 79-1622)

5. 목탄, 저각탄 분말이나 마각탄, 톱밥탄 분말에 카복시 메틸세루로즈 등을 넣은 기제로 제조하는 방법등이 있다.5. Charcoal, low charcoal powder, or petroleum charcoal or sawdust charcoal powder is prepared by adding carboxy methyl cellulose.

상기 기제들은 3항을 제외하고는 모두 합성호료, 결착제를 사용하였다. 또한, 결착제인 합성호료를 사용함으로써 야기되는 단점은 기특허(공고번호 : 80-1362)에 열거되었다. 모기향원료분말 기제로서 합성호료, 결착제를 사용할 경우나 운향과 식물로써 만으로는 압출 성형이 원만하지가 못하다. 즉, 공업적으로 다량 모기향을 제조할 때 와권상으로 성형시, 혼합기에 모기향 원료분말, 살충성분, 방부제, 착색제, 결착제 등을 균질 혼합하고 여기에 물을 일정량 넣고 연합한 후 압출기로 이송되어 강력하게 압출되는 과정에서 판상(板狀)압출 조건에 맞지 않음으로 해서 실질적인 산업화가 어렵다든가, 압출속도가 늦음으로 해서 제품의 제조원가에 큰 악영향을 주고 있는 실정이다. 그렇기 때문에 대부분 외국에서 모기향 원료분말 전량을 수입하여 사용하든가, 수입원료에 일정량 비율로 국내 원료 분말을 혼합하여 사용하는 방법을 택하고 있는 실정이다.Except for the above 3, all of the bases used synthetic paints and binders. In addition, disadvantages caused by the use of the synthetic synthetic binder as a binder have been listed in the prior patent (Publication No. 80-1362). When mosquito flavor raw materials are used as synthetic bases and binders, or by fragrance and plants alone, extrusion is not easy. That is, when industrially manufacturing a large amount of mosquito scent, when molding into a vortex, homogeneously mixed mosquito scent powder, pesticide, preservative, colorant, binder, etc. into a mixer, put a certain amount of water in it, and then transfer it to the extruder. In the process of extruded strongly, it does not meet the conditions of plate extrusion, which is difficult to industrialize practically, or the slow rate of extrusion has a great adverse effect on the manufacturing cost of the product. For this reason, most of the countries are importing or using all of the mosquito-flavored raw material powder from foreign countries or mixing domestic raw material powder in a certain amount ratio with imported raw materials.

본 발명자는 종래 모기향 제조시 원료 분말의 압출 과정에서 상기와 같은 결점들을 없애고 국내 자원으로 대체하여 기술 축적의 면과 외화절약의 효과를 얻기 위하여 다년간 조사 및 연구 개발하여 본 발명을 완성하였다. 이와같은 본 발명의 배경을 더욱 상세히 설명하면, 천연식물로서 모기향 원료의 기본 조건은 연소가 용이하고, 결착력 즉, 점액질이나 펙틴질, 알긴산, 폴리우로나이드, 전분립, 당류 등이 있어야 한다. 이런 조건을 만족시켜 주고 국내에 널리 분포된 것으로는 미역과 마미조과 및 아욱과 식물이 있으며 이들 중 미역과, 마미조과 식물은 해조류로서 세포막은 셀루로즈 이외에 펙틴질로 되어 있고, 어떤 것은 세포안에 점액을 가지고 있어서 점활성이 있으며 성분으로는 만니톨, 무기질, 함질소 감미성분, 알긴산, 갈락탄, 요오등을 함유하고 있어 식용, 약품의 자원, 퇴비 등으로 쓰이며, 산지로는 북부동해안, 동남해안 등지이다.The present inventors have completed the present invention by research and development for many years in order to eliminate the above-mentioned defects in the extrusion process of the raw material powder in the production of conventional mosquito scent and replace it with domestic resources to obtain the effect of technology accumulation and foreign currency saving. When explaining the background of the present invention in more detail, the basic conditions of the mosquito repellent raw materials as a natural plant should be easy to burn, ie, slime, pectin, alginic acid, polyuronide, starch granules, sugars and the like. The seaweeds, Mamizoaceae and Malvaceae plants that satisfy these conditions and are widely distributed in Korea are among the seaweeds, Mamizoaceae, among them, the seaweeds, and the membranes are made of pectin in addition to cellulose, and some mucilage in the cells. It has a viscous activity and contains mannitol, minerals, nitrogen-containing sweetening ingredients, alginic acid, galactan, and iodine. It is used for food, medicine, and compost. .

또한 아욱과 식물은 점액 세포가 있고 섬유가 발달된 것도 있으며 성분으로는 아라반, 갈락탄, 팀노산 등의 점액질과 폴리우로나이드가 있으며, 점활제, 풀, 섬유원료, 식용소채, 한방약제로 쓰이고 국내 각 지방에서 관상으로 널리 재배 또는 자생한다.In addition, mallow plants have mucous cells and fibers are developed, and the components include arabic, galactan, and thinoic acid, and polyuroneides. They are used as viscous agents, grasses, fiber ingredients, edible vegetables, and herbal medicines. It is widely cultivated or grown natively in each country in Korea.

본 발명에서 미역과, 마미조과의 해조류는 연소시 약한 해조류 냄새가 나지만 다른 목분류, 향나무 경엽분말, 아욱과 식물 분말을 혼가하여 해조류취를 거의 인지할 수 없을 정도로 마스킹 할 수 있다.Seaweed of seaweed and seaweed in the present invention smells a little algae when burning, but can be masked to the extent that the algae smell is hardly noticeable by mixing other wood classification, juniper foliage powder, mallow plant powder.

특히 해조류는 모기향 제조에 있어서, 압출 성형시 압출되는 과정 중 기계의 면과의 관계에서 점활성으로 인해 압출 속도의 증가 효과를 줄 뿐만 아니라, 자체의 세포막은 셀루로즈 이외에 펙틴질로 되어 있어 다른 모기향 원료 분말과의 결합 능력을 갖게 되어 별도의 합성호료 등 결합제를 첨가할 필요가 없다. 또한, 아욱과 식물도 점활성이 있어 해조류와 유사한 작용을 나타내지만 특히 섬유가 발달되어 결합 능력뿐만 아니라, 해조류의 연소를 도와 준다.In particular, in the production of mosquito scents, not only does it increase the extrusion rate due to viscous activity in relation to the surface of the machine during the extrusion process, but its cell membrane is made of pectin in addition to cellulose, and thus other mosquito scent raw materials. It has the ability to bind with the powder, so there is no need to add a binder such as a synthetic paint. In addition, mallow has a viscous activity similar to that of algae, but in particular, fiber is developed, as well as binding capacity, as well as help the burning of algae.

즉, 압출, 성형시 압출되는 과정에서 판상(板狀)압출을 용이하게 하고 압출 속도의 증가 효과와 제품의 경도를 높여 준다는 것을 발견하여 연구 개발한 후 본 발명을 완성하게 된 것이다.That is, the present invention was completed after research and development by discovering that the plate-like extrusion is facilitated in the process of extrusion and molding, and the effect of increasing the extrusion speed and the hardness of the product is increased.

본 발명의 지금까지 모기향 기체로서 전혀 사용한 적이 없는 참미역, 미역등의 미역과의 말(海

Figure kpo00001
, 속칭 : 몰, 모자원, 솔몰)등의 마미조관에 속하는 해조류를 민물로 세척하여 염분을 제거한 후 건조하여 악 100-200 메쉬로 분말화 한 것과 촉규화(접시꽃, 접대꽃), 동규자(아욱)등의 아욱과 식물 전초를 건조후 약100-200 메쉬로 분말화 한 것을 공지의 침엽수인 소나무, 향나무, 전나무 잎이나 잔가지를 건조한 후 약 100-200 메쉬로 분말화 한 것과 또한 공지의 살충제인 알레드린 또는 피레드린, 방부제로 지니트로페놀 필요하면 조연제, 착색제를 첨가하여 온수를 적당량 넣고 공지의 연합기로 반죽한 후 압출기로 이송, 판상으로 압출한 후 와권상(Coil)으로 성형한 후 건조시켜 본 발명의 모기향을 제조한다. 이때 해조류는 민물로 세척하여 염분을 제거치 않으면 분말화가 어렵고 제품이 습기를 흡수하여 견고성이 결여되고 연소 저해 요인이 된다.Seaweed with seaweed such as seaweed and seaweed which have never been used as a mosquito-scented gas of the present invention
Figure kpo00001
, So-called: mole, mawon, sol-mol), seaweeds belonging to Mamijokan, etc., washed with fresh water, dried to remove salt and dried into wicked 100-200 mesh, and quenched (dish flower, hospitality flower), Donggyuja (mallow) Drying of mallow and plant outposts into powder of about 100-200 mesh and drying of known conifers, pine, juniper, fir leaves or twigs, drying to powder of about 100-200 mesh and also known insecticide If nitriphenol is used as a preservative or pyrethrin, preservatives, add a moderate amount of hot water, add a supporting agent and a colorant, knead it with a known coalescing machine, transfer it to an extruder, extrude into a plate shape, and then form a coil and dry it. The mosquito scent of the present invention is prepared. At this time, algae is difficult to be powdered if it is not washed with fresh water to remove salts, and the product absorbs moisture and thus lacks firmness and becomes a combustion inhibiting factor.

본 발명의 제조방법과 종래의 방법을 비교하여 실험한 결과를 다음표(1)과 같다.The results of experiments comparing the manufacturing method of the present invention and the conventional method are shown in the following Table (1).

[표1 ]Table 1

공지의 제조방법과 발명의 제조방법 비교설명Comparison of Known Manufacturing Methods and Invention Methods

Figure kpo00002
Figure kpo00002

표1에서 보는 바와 같이 공지의 원료 분말 중 종래 국내 순수원료로써 만으로 압출 성형이 불가능하며, 완전 수입 원료와는 압출 속도에서 약간 늦는 반면 연소 시간은 길다. 자극취도 본 발명의 제품이 완전 수입 원료 보다 약하다.As shown in Table 1, it is impossible to extrudate only with conventional domestic pure raw materials among known raw powders, and the combustion time is long while slightly lower at the extrusion speed than with the fully imported raw materials. The irritant odor is also weaker than the products of the present invention.

[실시예 1]Example 1

미역분말(100-200 메쉬)18g, 아욱과 식물인 아욱 전초 분말(100-200 메쉬)40g, 공지의 향나무경엽분말 24g, 목분 14.1g을 균질 혼합하고 알레드린 0.5g, 디니트로페놀 0.2g, 말라카이트그린0.2g을 넣어 혼합한후 물을 적당량 넣어 연합하고 압출 성형하여 건조시켜 모기향을 얻는다.18g seaweed powder (100-200 mesh), 40g of mallow starch powder (100-200 mesh), 24g of known cedar leaf powder, 14.1g of wood powder, homogeneous mixture of alledrin 0.5g, dinitrophenol 0.2g, 0.2 g of malachite green is added, mixed with water, an appropriate amount is combined, extruded, and dried to obtain a mosquito flavor.

[실시예 2]Example 2

해조(말)분말(100-200메쉬)20g, 아욱과 식물인 촉규환 전초분말(100-200 메쉬)40g, 공지의 향나무경엽분말 25g, 목분 14.1g을 균질 혼합하고 알레드린 0.5g, 디니트로페놀 0.2g, 말라카이트그린 0.2g을 넣어 혼합한 후 물을 적당량 넣어 연합하고 압출 성형하여 건조시켜 모기향을 얻는다.Homogeneous seaweed powder (100-200 mesh) 20g, mungwak jeonhwahwan starch powder (100-200 mesh) 40g, known cedar leaf powder 25g, wood powder 14.1g homogeneously mixed, 0.5g allenrin, dinitro Add 0.2 g of phenol and 0.2 g of malachite green, mix, add water in an appropriate amount, combine, extruding and dry to obtain mosquito flavor.

상술한 바와 같이 본 발명은 종래 국내 원료로써 갖지 못하는 결합력, 점활성, 압출 불가능이란 문제를 완전히 해결했으며, 뚜렷하고 우수할 뿐만 아니라, 결합제로서 합성 호료등을 전혀 사용하지 않고 수입 원료와 비슷한 제품을 얻을 수 있고 자극면에서는 오히려 약하여 인체에 나쁜 영향을 덜 주는 제품을 얻을 수 있어서 수입에만 주로 의존하던 모기향 기제를 국내의 부존 자원으로 대체 할 수 있다.As described above, the present invention completely solves the problems of bonding strength, viscous activity, and extrudability, which are not conventionally obtained as domestic raw materials, and are not only clear and excellent, but also obtain a product similar to imported raw materials without using any synthetic paste as a binder. It is possible to obtain a product that is weak in terms of irritation and has less adverse effects on the human body, so that the mosquito repellent mechanism, which was mainly dependent on imports, can be replaced by domestic resources.

Claims (4)

침엽수 경엽분말과 살충제로 구성된 모기향을 제조함에 있어서, 100-200 메쉬로 분말화한 미역과와 마미조과의 해조류, 아욱과 식물의 전초를 분말화한 것을 기계로 사용함을 특징으로 하는 모기향의 제조방법.In the production of mosquito scent composed of coniferous foliage powder and insecticide, a method of producing mosquito scents using powdered seaweeds and seaweeds of Mamijo and powdered malt plants of 100-200 mesh. . 제1항에 있어, 미역과는 참미역, 미역(昆布)등이며, 마미조과는 해조(마미조, 말)등을 사용하는 방법.The method according to claim 1, wherein seaweed is seaweed, seaweed, etc., and seaweed is used for seaweed. 제1항에 있어서, 아욱과는 아욱, 분홍아욱(錦葵花), 촉규화(접시꽃, 접대꽃)등의 전초를 사용하는 방법.The method according to claim 1, wherein the mallow family uses outposts such as mallow, pink mallow, and cucurbita. 제1항에 있어서, 미역과와 마미조과의 해조류를 건조 분말화함에 있어서, 미리 민물로 세척하여 염분(소금)을 제거하는 방법.The method according to claim 1, wherein, in dry powdering of seaweeds of wakame and mamizo, the salt (salt) is removed by washing with fresh water in advance.
KR1019850002467A 1985-04-12 1985-04-12 The preparation method for mosquito coil KR880000346B1 (en)

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