KR870010110A - 반응성 방화 제제 및 그것의 제조방법 - Google Patents

반응성 방화 제제 및 그것의 제조방법 Download PDF

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KR870010110A
KR870010110A KR870003279A KR870003279A KR870010110A KR 870010110 A KR870010110 A KR 870010110A KR 870003279 A KR870003279 A KR 870003279A KR 870003279 A KR870003279 A KR 870003279A KR 870010110 A KR870010110 A KR 870010110A
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bromomethyl
neopentane
mixture
bis
reaction product
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KR870003279A
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KR930008186B1 (ko
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발테르 뷔트젠스
우토 케세르
에른스트 네우키르켄
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봄, 케세르
케미세 파브릭 칼크 게엠베하
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3802—Low-molecular-weight compounds having heteroatoms other than oxygen having halogens
    • C08G18/3804—Polyhydroxy compounds
    • C08G18/3806—Polyhydroxy compounds having chlorine and/or bromine atoms
    • C08G18/381—Polyhydroxy compounds having chlorine and/or bromine atoms having bromine atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805—Compounds having only one group containing active hydrogen
    • C08G18/288—Compounds containing at least one heteroatom other than oxygen or nitrogen
    • C08G18/2885—Compounds containing at least one heteroatom other than oxygen or nitrogen containing halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3878—Low-molecular-weight compounds having heteroatoms other than oxygen having phosphorus
    • C08G18/3889—Low-molecular-weight compounds having heteroatoms other than oxygen having phosphorus having nitrogen in addition to phosphorus
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4829—Polyethers containing at least three hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/50—Polyethers having heteroatoms other than oxygen
    • C08G18/5021—Polyethers having heteroatoms other than oxygen having nitrogen
    • C08G18/5033—Polyethers having heteroatoms other than oxygen having nitrogen containing carbocyclic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/64—Macromolecular compounds not provided for by groups C08G18/42 - C08G18/63
    • C08G18/6461—Macromolecular compounds not provided for by groups C08G18/42 - C08G18/63 having phosphorus
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0025—Foam properties rigid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/005—< 50kg/m3
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S521/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S521/904—Polyurethane cellular product having high resiliency or cold cure property
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S521/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S521/906—Polyurethane cellular product containing unreacted flame-retardant material

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Polyethers (AREA)
  • Fireproofing Substances (AREA)

Abstract

내용 없음

Description

반응성 방화 제제 및 그것의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (7)

  1. 방향족 아민, 또는 솔비톨 또는 테트롤, 또는 그것의 혼합물에 기초한 폴리에테르-폴리올 ; 브롬 및 하이드록시 그룹을 포함하는 네오펜탄 화합물 ; 및 디에탄올 아민 및 디메틸 메탄 포스포네이트의 반응 생성물의 균일 액체 혼합물로 구성되는, 경질 폴리우레탄 거품 재료가 되게 하는 반응성 방화 제제.
  2. 방향족 아민, 또는 솔비톨 또는 테트롤, 또는 그것의 혼합물에 기초한 약 30∼40중량%의 폴리에테르-폴리올 : 브롬 및 하이드톡시 그룹을 포함하는 약 55∼65중량%의 네오펜탄 화합물 ; 및 동일몰량 디에탄올 아미노 및 디메틸 메탄포스포네이트의 약 8∼12중량% 반응 생성물의 균일 혼합물로 구성되는, 경질 폴리우레탄 거품 재료가 되게 하는 반응성 방화 제제.
  3. 제 2항에 있어서, 네오펜탄 화합물이 디브로모네오펜틸글리콜 또는 2-브로모메틸-2-하이드록시메틸-프로I판디올-1,3 : 2,2-비스-(브로모메틸)-프로판디올-1,3 ; 및 3-브로모-2,2-비스(브로모메틸)-프로판올-1의 혼합물인 제제.
  4. 제 3항에 있어서, 혼합물이 약 1∼20중량% 2-브로모메틸-2-하이드록시메 틸-프로판디올-1,3 :약 60∼85중량% 2,2-비스-(브로모메틸)-프로판디올-1,3 : 및 약 10∼20중량% 3-브로모-2,2-비스(브로모메틸)-프로판올-1로 구성되는 제제.
  5. 제 2항에 있어서, 반응 생성물이 동일몰량의 디에탄올아민 및 디메틸 메탄 포스포네이트로부터 형성되는 것인 제제.
  6. 방향족 아민, 또는 솔비톨 또는 테트롤, 또는 그것이 혼합물에 기초한 폴리에테르-폴리올을 응용 반응매체가 형성되도록 약 120∼140℃까지 가열하고 : 결과 제제의 온도를 약 120∼140℃ 유지하며 교반하면서 반응매체에 네오펜탄 화합물 및 반응 생성물을 부가하고 ; 얼마의 시간 동안 교반을 계속하는 단계로 구성되는, 제 1항에서 제 5항까지의 제제를 제조하는 방법.
  7. 제 6항에 있어서 얼마의 시간이 최소한 약 30분인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019870003279A 1986-04-07 1987-04-07 반응성 방화 제제 및 그것의 제조방법 KR930008186B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3611566 1986-04-07
DE3611566.5 1986-04-07

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KR870010110A true KR870010110A (ko) 1987-11-30
KR930008186B1 KR930008186B1 (ko) 1993-08-26

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Country Link
US (1) US4717509A (ko)
EP (1) EP0240806B1 (ko)
JP (1) JPH0668070B2 (ko)
KR (1) KR930008186B1 (ko)
DE (1) DE3780058T2 (ko)
IL (1) IL82116A (ko)

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US4892892A (en) * 1987-10-09 1990-01-09 Great Lakes Chemical Corporation Flame retardant polyurethane foam compositions containing polynuclearbrominated alkylbenzene
DE3803030C2 (de) * 1988-02-02 1995-04-06 Boehme Chem Fab Kg Verwendung von Phosphonaten als Flammschutzmittel in Kunststoffen
DE19528537A1 (de) * 1995-08-03 1997-02-06 Basf Ag Flammgeschützte Hartschaumstoffe auf Isocyanatbasis
CA2321904C (en) * 1998-02-27 2005-07-26 Solutia Inc. Fire retardant concentrates and methods for preparation thereof and the like
US6802994B1 (en) 2000-11-28 2004-10-12 Astaris Llc Fire retardant compositions containing ammonium polyphosphate and iron additives for corrosion inhibition
WO2002044305A2 (en) * 2000-11-28 2002-06-06 Astaris Llc Fire retardant compositions with reduced aluminum corrosivity
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US6846437B2 (en) * 2000-11-28 2005-01-25 Astaris, Llc Ammonium polyphosphate solutions containing multi-functional phosphonate corrosion inhibitors
DE10156247A1 (de) * 2001-11-15 2003-06-12 Bayer Ag Prepolymere für flammwidrig ausgerüstete Polyurethane
US8545974B2 (en) * 2005-02-09 2013-10-01 Laird Technologies, Inc. Flame retardant EMI shields
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JP5451380B2 (ja) 2006-05-15 2014-03-26 ブロマイン コンパウンズ リミテッド 難燃剤組成物
US20080157915A1 (en) * 2007-01-03 2008-07-03 Ethan Lin Flame retardant, electrically-conductive pressure sensitive adhesive materials and methods of making the same
WO2013143129A1 (en) * 2012-03-30 2013-10-03 Air Products And Chemicals, Inc. Polyurethane foam production process, pre-mix, formulation, and product
US20140073712A1 (en) * 2012-09-13 2014-03-13 Basf Se Polyurethanes comprising halogen compounds
CN106432740B (zh) * 2016-09-08 2020-06-09 四川大学 一种含羟基聚膦酸酯阻燃剂及其制备方法和应用
CN106496507A (zh) * 2016-10-27 2017-03-15 湖北科技学院 一种磷氮协同阻燃硬质聚氨酯泡沫塑料

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GB1063605A (en) * 1965-02-03 1967-03-30 Dow Chemical Co Fire-retardant polyurethanes
US3525708A (en) * 1965-08-09 1970-08-25 Textron Inc Fire retardant polyurethane coating compositions
US3548038A (en) * 1967-10-20 1970-12-15 Stauffer Chemical Co 2-bis(diesters of phosphonomethyl)amino 1,3-dihydroxy propanes
US3906061A (en) * 1970-07-16 1975-09-16 Borg Warner Halogen containing phosphorus monools
US3997449A (en) * 1975-09-29 1976-12-14 Michigan Chemical Corporation Low viscosity flame retardant
US4202779A (en) * 1975-11-21 1980-05-13 The Upjohn Company Mixture of bis(2-hydroxyalkyl) N,N-di(lower alkyl)aminomethanephosphonates with polyols
US4273881A (en) * 1979-12-03 1981-06-16 Basf Wyandotte Corporation Organo-phosphorus flame-retardant for polyurethane foams prepared from graft polyoxyalkylene polyether polyols
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US4454255A (en) * 1982-04-01 1984-06-12 Basf Wyandotte Corporation Process for the preparation of white graft polymer dispersions and flame-retardant polyurethane foams
ATE23722T1 (de) * 1982-10-12 1986-12-15 Ciba Geigy Ag Feuerhemmende zusammensetzungen.

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Publication number Publication date
US4717509A (en) 1988-01-05
JPS62241921A (ja) 1987-10-22
JPH0668070B2 (ja) 1994-08-31
IL82116A0 (en) 1987-10-30
EP0240806A3 (en) 1989-01-18
EP0240806A2 (en) 1987-10-14
EP0240806B1 (en) 1992-07-01
DE3780058D1 (de) 1992-08-06
IL82116A (en) 1991-01-31
KR930008186B1 (ko) 1993-08-26
DE3780058T2 (de) 1993-02-25

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