KR870000719A - 유리를 제조하는 방법 - Google Patents
유리를 제조하는 방법 Download PDFInfo
- Publication number
- KR870000719A KR870000719A KR1019860004512A KR860004512A KR870000719A KR 870000719 A KR870000719 A KR 870000719A KR 1019860004512 A KR1019860004512 A KR 1019860004512A KR 860004512 A KR860004512 A KR 860004512A KR 870000719 A KR870000719 A KR 870000719A
- Authority
- KR
- South Korea
- Prior art keywords
- slurry
- interpolymer
- water
- solution
- methanol
- Prior art date
Links
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims 15
- 238000000034 method Methods 0.000 claims 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 7
- 239000002002 slurry Substances 0.000 claims 6
- 239000000243 solution Substances 0.000 claims 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 4
- 229910052710 silicon Inorganic materials 0.000 claims 4
- 239000010703 silicon Substances 0.000 claims 4
- 229910052810 boron oxide Inorganic materials 0.000 claims 3
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims 3
- 239000011521 glass Substances 0.000 claims 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims 2
- 150000004703 alkoxides Chemical class 0.000 claims 2
- 229910052796 boron Inorganic materials 0.000 claims 2
- 238000010438 heat treatment Methods 0.000 claims 2
- 239000000203 mixture Chemical group 0.000 claims 2
- 239000002699 waste material Substances 0.000 claims 2
- VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 claims 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 239000007864 aqueous solution Substances 0.000 claims 1
- 238000009835 boiling Methods 0.000 claims 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims 1
- 239000004327 boric acid Substances 0.000 claims 1
- 238000001704 evaporation Methods 0.000 claims 1
- 150000002366 halogen compounds Chemical group 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- NBTOZLQBSIZIKS-UHFFFAOYSA-N methoxide Chemical compound [O-]C NBTOZLQBSIZIKS-UHFFFAOYSA-N 0.000 claims 1
- 229920000642 polymer Polymers 0.000 claims 1
- 239000002244 precipitate Substances 0.000 claims 1
- 239000005049 silicon tetrachloride Substances 0.000 claims 1
- 239000010936 titanium Chemical group 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
Classifications
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/28—Treating solids
- G21F9/30—Processing
- G21F9/301—Processing by fixation in stable solid media
- G21F9/302—Processing by fixation in stable solid media in an inorganic matrix
- G21F9/305—Glass or glass like matrix
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F1/00—Shielding characterised by the composition of the materials
- G21F1/02—Selection of uniform shielding materials
- G21F1/06—Ceramics; Glasses; Refractories
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/006—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels to produce glass through wet route
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/025—Silicon compounds without C-silicon linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
- C08G79/14—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing two or more elements other than carbon, oxygen, nitrogen, sulfur and silicon
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- General Engineering & Computer Science (AREA)
- High Energy & Nuclear Physics (AREA)
- Polymers & Plastics (AREA)
- Geochemistry & Mineralogy (AREA)
- Medicinal Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
- Processing Of Solid Wastes (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Glass Melting And Manufacturing (AREA)
- Glass Compositions (AREA)
Abstract
내용 없음.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (10)
- (A) (1) 일반식 M(OR)4의 알콕사이드, R은 C1으로부터 C4까지 알킬기이고 M은 실리콘, 티타늄 또는 그것의 혼합물. (2) 붕소 및 M을 포함하는 혼성 중합체의 수성용액을 생성하기 위해서, 산화붕소, 붕산, 또는 그것의 혼합물, 즉(1)을 (2)와 반응하는 것; (B) 상기 혼성중합체를 침전하고 교차 결합하기 위해서 상기 용액에 물을 첨가하는 것; (C) 상기 용액으로부터 알코올과 물을 분리시키는 것; (D) 상기 유리를 생성하기 위해서 상기 혼성중합체를 융해하는 것을 특징으로 하는 유리를 제조하는 방법.
- 제1항에 있어서, 침전된 혼성중합체는 물과 알코올을 증발하기 위해서 열에 의해서 용액으로부터 분리되는 것을 특징으로 하는 유리를 제조하는 방법.
- 제2항에 있어서, 핵폐물은 물을 증발시키기 전에 용액과 혼합되는 것을 특징으로 하는 유리를 제조하는 방법.
- 제3항에 있어서, 알코올은 메탄올이 되는 것을 특징으로 하는 유리를 제조하는 방법.
- 제4항에 있어서, 알콕사이드는 MX4를 알코올과 반응하는 것에 의해서 생성되고, X는 할로겐 화합물이 되는 것을 특징으로 하는 유리를 제조하는 방법.
- 제5항에 있어서, MX4는 테트라클로라이드화 실리콘이 되는 것을 특징으로 하는 유리를 제조하는 방법.
- 제1항에서 6항중 어느 한 항에 있어서 (A),(B),(C) 단계는 동일 콘테이너 내에서 수행되는 것을 특징으로 하는 유리를 제조하는 방법.
- 테트라 메톡사이드화 실리콘을 생성하기 위해서 테트라 콜로라이드화 실리콘을 화학량론을 초과하여 10에서 100몰%가 되는 메탄올과 반응하는 것; 메톡사이드화 실리콘-붕소 혼성 중합체의 메탄올 용액을 생성하기 위해서 상기 테트라 메톡사이드화 실리콘을 화학량론의 약 ±20몰%가 되는 산화 붕소와 동일 반응용기 내에서 반응하는 것; 40에서 60중량%를 가지는 슬러리를 생성하는 상기 혼성 중합체를 교차 결합하고 침전하도록 상기 맑은 용액에 물을 첨천가하는 것; 상기 메탄올을 증발하기 위해서 상기 슬러리를 가열하는 것; 상기 슬러리 내에서 10에서 50중량%로 구성되는 핵 폐물을 상기 슬러리에 첨가하는 것; 상기 유리를 생성하는 상기 혼성 중합체를 융해하고 상기 물을 증발하기 위해서 상기 슬러리를 가열하는 것을 특징으로 하는 유리의 핵 폐물을 부동시키는 방법.
- 제8항에 있어서, 산화붕소량은 약 ±5몰%의 화학량론이 되는 것을 특징으로 하는 유리의 핵폐물을 부동시키는 방법.
- 제8항 또는 9항에 있어서, 슬러리는 메탄올을 증발하기 위해서 물의 비등점까지 가열되는 것을 특징으로 하는 유리의 핵 폐물을 부동시키는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US74283785A | 1985-06-10 | 1985-06-10 | |
| US742,837 | 1985-06-10 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR870000719A true KR870000719A (ko) | 1987-02-20 |
Family
ID=24986454
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019860004512A KR870000719A (ko) | 1985-06-10 | 1986-06-07 | 유리를 제조하는 방법 |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP0205313A1 (ko) |
| JP (1) | JPS61286231A (ko) |
| KR (1) | KR870000719A (ko) |
| ES (1) | ES8802552A1 (ko) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5166384A (en) * | 1992-04-07 | 1992-11-24 | Union Carbide Chemicals & Plastics Technology Corporation | Method for the removal of siloxane dissolved in the solvent employed in the preparation of trimethoxysilane via methanol-silicon metal reaction |
| GB2497755A (en) * | 2011-12-19 | 2013-06-26 | Charles Donald Ingham | A process for the rapid shut-down of nuclear fission reactions |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1019373A (en) * | 1962-08-10 | 1966-02-02 | Atomic Energy Authority Uk | A new glass containing radioactive waste oxides |
| JPS55100231A (en) * | 1979-01-19 | 1980-07-31 | Hitachi Ltd | Production of optical fiber base material |
| US4422965A (en) * | 1980-08-11 | 1983-12-27 | Westinghouse Electric Corp. | Nuclear waste encapsulation in borosilicate glass by chemical polymerization |
-
1986
- 1986-06-04 EP EP86304279A patent/EP0205313A1/en not_active Withdrawn
- 1986-06-06 JP JP61132593A patent/JPS61286231A/ja active Pending
- 1986-06-07 KR KR1019860004512A patent/KR870000719A/ko not_active Application Discontinuation
- 1986-06-09 ES ES555869A patent/ES8802552A1/es not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| EP0205313A1 (en) | 1986-12-17 |
| JPS61286231A (ja) | 1986-12-16 |
| ES8802552A1 (es) | 1988-07-01 |
| ES555869A0 (es) | 1988-07-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR850000461B1 (ko) | 핵 폐기물 고화방법 | |
| Zelinski et al. | Crystallization behavior of sol-gel derived glasses | |
| KR890013043A (ko) | 메틸 메틸포스폰산의 금속 또는 메탈로이드염의 제조방법 | |
| JPS5534238A (en) | Preparation of alpha-olefin polymer | |
| EP0421546A3 (en) | Solid, polymeric electrolyte on polyepoxy basis | |
| Kishioka | Glass formation in the Li2O-TiO2-P2O5, MgO-TiO2-P2O5, and CaO-TiO2-P2O5 systems. | |
| KR870000719A (ko) | 유리를 제조하는 방법 | |
| EP0165174A3 (en) | Stabilized unsaturated polyesters | |
| FR2594121B1 (fr) | Procede de preparation d'imides halogenes, compositions les contenant et leur application comme agents d'ignifugation | |
| KR830004320A (ko) | 퀴나졸린 유도체의 제조방법 | |
| EP0338215A3 (en) | Process for the preparation of halogen-substituted phthalic anhydride | |
| US2675411A (en) | Bis(4-beta-hydroxyalkoxyphenyl) ketones and process of preparation | |
| ES8404306A1 (es) | "un metodo de preparacion de una solucion transparente de alcoxido de aluminio parcialmente hidrolizado". | |
| JPS5556151A (en) | Aromatic polyester polycarbonate resin composition | |
| GB1112021A (en) | Polycarbonates with increased crystallizability | |
| US3024222A (en) | Preparation of glassy polymers | |
| ATE77394T1 (de) | Borharze mit hoher selektiver absorptionswirkung. | |
| US5117041A (en) | Sulfonation process | |
| JPS57185288A (en) | Preparation of bis(alkylbenzylidene)sorbitol | |
| JPS5531870A (en) | Preparation of modified polyester | |
| JPS5736148A (ja) | Horiesuteruseikeihinnoseizoho | |
| SU808517A1 (ru) | Теплоаккумулирующий состав | |
| JPS56112954A (en) | Stabilizer for halogen-containing resin | |
| ES8304167A1 (es) | Procedimiento para preparar polimeros termicamente curables. | |
| JPS5558248A (en) | Aromatic copolyester composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| WITN | Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid |