KR860007414A - Textile treatment composition - Google Patents

Textile treatment composition Download PDF

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Publication number
KR860007414A
KR860007414A KR1019860002329A KR860002329A KR860007414A KR 860007414 A KR860007414 A KR 860007414A KR 1019860002329 A KR1019860002329 A KR 1019860002329A KR 860002329 A KR860002329 A KR 860002329A KR 860007414 A KR860007414 A KR 860007414A
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South Korea
Prior art keywords
dispersion
acid
alkyl
amine
siloxane
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KR1019860002329A
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Korean (ko)
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KR930008697B1 (en
Inventor
쾨니히 악셀
드 브자까리니 프란체스코
Original Assignee
더 프록터 앤드 갬블 캄파니
원본미기재
더프록터 앤드 갬블 캄파니
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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/61Polyamines polyimines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/52Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/528Carboxylic amides (R1-CO-NR2R3), where at least one of the chains R1, R2 or R3 is interrupted by a functional group, e.g. a -NH-, -NR-, -CO-, or -CON- group
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/40Monoamines or polyamines; Salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/001Softening compositions
    • C11D3/0015Softening compositions liquid

Abstract

내용 없음No content

Description

직물처리용 조성물Textile treatment composition

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (12)

(a) 일반식(I)의 디(고급알킬)환상 아민 ; 알킬렌 디아민, 알콕시알킬렌디아민, Nㅡ하이드록시알킬 ㅡ알킬렌트리아민 및 이들의 혼합물중에서 선택된 폴리아민과 고급 지방산과의 반응 생성물 ; 및 이들의 혼합물중에서 선택된 아민을 1 내지 40% 함유하며, (b) pKa값이 6이하인 브론스테트산중에서 선택된 분산보조제를 함유함을 특징으로 하는, pH5이하의 안정한 수성 분산액.(a) Di (higher alkyl) cyclic amine of general formula (I); Reaction products of polyamines and higher fatty acids selected from alkylene diamines, alkoxyalkylenediamines, N-hydroxyalkyl-alkylenetriamines and mixtures thereof; And 1 to 40% of an amine selected from the mixture thereof, and (b) a dispersing aid selected from bronsted acid having a pKa value of 6 or less. 상기 식에서,Where n은 2 또는 3, 바람직하게는 2이고;n is 2 or 3, preferably 2; R1및 R2은 각각 독립적으로, C8내지 C30의 알킬 또는 알케닐, 바람직하게는 C12내지 C20의 알킬, 보다 바람직하게는 C15내지 C18의 알킬이거나, 이들 알킬라디칼의 혼합물(예를들면, 코코넛 오일, “연성″(비경화) 탈로우 및 경화 탈로우로부터 수득된 알킬라디칼)이고;R 1 and R 2 are each independently C 8 to C 30 alkyl or alkenyl, preferably C 12 to C 20 alkyl, more preferably C 15 to C 18 alkyl, or a mixture of these alkyl radicals (Eg, coconut oil, alkyl radicals obtained from “soft” (uncured) tallow and hardening tallow); Q는 CH, CH2, NH 또는 N, 바람직하게는 N이고;Q is CH, CH 2 , NH or N, preferably N; X는〔여기에서, T는 O또는 NR5(여기에서, R5은 H 또는 C1내지 C4의 알킬, 바람직하게는 H이다)이고 ; R4은 C1내지 C3의 2가 알킬렌그룹 또는 (C2H4O)m(여기에서, m은 1 내지 8의 수이다)이다〕 또는 R4이다.X is [Wherein T is O or NR 5 , wherein R 5 is H or C 1 to C 4 alkyl, preferably H; R 4 is a C 1 to C 3 divalent alkylene group or (C 2 H 4 O) m (where m is a number from 1 to 8) or R 4 . 제1항에 있어서, 3 내지 35%의 아민을 함유하는 분산액.The dispersion of claim 1 which contains 3 to 35% amine. 제2항에 있어서, pH가 4 이하인 분산액.The dispersion of claim 2 wherein the pH is 4 or less. 제1항 내지 제3항중 어느 한 항에 있어서, 분산보조제가 무기 미네랄산, 일반식 R-COOH 또는 Rㅡ CH2ㅡ SO3H(여기에서, R은 수소 또는 C1내지 C4의 알킬이다)의 유기산, 및 이들의 혼합물중에서 선택된 산인 분산액.The dispersion aid according to any one of claims 1 to 3, wherein the dispersing aid is an inorganic mineral acid, general formula R-COOH or R-CH 2 -SO 3 H, wherein R is hydrogen or alkyl of C 1 to C 4 And an acid selected from organic acids, and mixtures thereof. 제4항에 있어서, 분산보조제가 포름산, 인산 또는 메틸설폰산인 분산액.The dispersion according to claim 4, wherein the dispersion aid is formic acid, phosphoric acid or methylsulfonic acid. 제4항에 있어서, 아민성분이 n이 2이고 ; R1및 R2이 각각 독립적으로 C12내지 C20의 알킬이고 ; Q가 N이고 ; X가 ㅡ C2H4ㅡNHㅡ COㅡ인 일반식(I)의 화합물인 분산액.The amine component according to claim 4, wherein n is 2; R 1 and R 2 are each independently C 12 to C 20 alkyl; Q is N; A dispersion wherein X is -C 2 H 4 -NH-CO-, a compound of general formula (I). 제4항에 있어서, 통상적인 4급 암모늄 유연제 화합물, 바람직하게는 하기 일반식의 화합물을 더욱 (바람직하게는 0.5 내지 10%의 함량으로) 함유하는 분산액.The dispersion according to claim 4, which further contains (preferably in an amount of 0.5 to 10%) of conventional quaternary ammonium softener compounds, preferably compounds of the general formula: 상기 식에서,Where R2는 C15내지 C22의 비환상 지방족 탄화수소그룹이고 ;R 2 is a C 15 to C 22 acyclic aliphatic hydrocarbon group; R3은 C1내지 C4의 포화 알킬 또는 하이드록시알킬그룹이고 ;R 3 is C 1 to C 4 saturated alkyl or hydroxyalkyl group; R4및 R5은 R2및 R3중에서 선택되고 ;R 4 and R 5 are selected from R 2 and R 3 ; A 는 음이온이다.A Is an anion. 제4항에 있어서, 거의 선성인 디(C1내지 C5) 알킬 또는 C1내지 C5알킬아릴 실록산(여기에서, 알킬그룹은 부분적으로 또는 전체적으로 불소화될 수 있으며, 또한, 양이온성 질소그룹으로 치환될 수 있고 ; 실록산의 점도는 25℃에서 100cs 이상, 8000cs이하이다)의 유제를 더욱 함유하며, 이때, 아민 성분에 대한 유제중의 실록산성분의 중량비율이 5 : 1 내지 1 : 100, 바람직하게는 2 : 1 내지 1 : 10인 분산액.The method of claim 4, wherein the substantially linear di (C 1 to C 5 ) alkyl or C 1 to C 5 alkylaryl siloxane, wherein the alkyl group may be partially or wholly fluorinated, and further And the viscosity of the siloxane may be at least 100 cs and not more than 8000 cs at 25 ° C.), wherein the weight ratio of the siloxane component in the emulsion to the amine component is 5: 1 to 1: 100, preferably Preferably a dispersion of 2: 1 to 1:10. 제8항에 있어서, 실록산이 폴리디메틸 실록산인 분산액.The dispersion of claim 8 wherein the siloxane is polydimethyl siloxane. 제4항에 있어서 0.5 내지 10%의 비이온성 물질, 바람직하게는 글리세롤 에스테르, 지방 알콜 또는 알콕 실화된 알콜을 더욱 함유하는 분산액.Dispersion according to claim 4, which further contains 0.5 to 10% of nonionic material, preferably glycerol ester, fatty alcohol or alkoxylated alcohol. 제4항에 있어서, 분산보조제의 함량이 아민의 중량을 기준으로 하여 3 내지 50%, 바람직하게는 5 내지 30%인 분산액.The dispersion according to claim 4, wherein the content of the dispersion aid is 3 to 50%, preferably 5 to 30%, based on the weight of the amine. (a)4 내지 35%의 1ㅡ탈로우아미도에틸ㅡ2ㅡ탈로우이미다졸린을 함유하고 ; (b) 염산, 브롬화수소산, 황산, 아황산, 인산, 포름산, 아세트산, 메틸설폰산 및 에틸설폰산중에서 선택된 산을 이미다졸린 유도체(a)의 중량을 기준으로 하여 5 내지 30%의 양으로 분산보조제로서 함유하며 ; (c) 통상적인 4급 암모늄 유연제를 분산액의 중량을 기준으로 하여 0 내지 10%의 양으로 함유하고 ; (d) 저분자량의 수ㅡ혼화성 지방족 알콜을 분산액의 중량을 기준으로 하여 0 내지 10%의 양으로 함유하며 ; (e) 25℃에서 점도가 100 내지 100,000cs인 폴리디메틸 실록산의 유제를 아민(a)에 대한 실록산성분(e)의 중량비율이 2 : 1 내지 1 : 10인 범위에서 임의로 함유함을 특징으로 하는, 린스첨가 직물유연제로서 사용되는 안정한 수성 분산액.(a) 4 to 35% of 1-tallowamidoethyl-2 tallowimidazoline; (b) dispersing an acid selected from hydrochloric acid, hydrobromic acid, sulfuric acid, sulfurous acid, phosphoric acid, formic acid, acetic acid, methylsulfonic acid and ethylsulfonic acid in an amount of 5 to 30% based on the weight of the imidazoline derivative (a) As an adjuvant; (c) containing a conventional quaternary ammonium softener in an amount of 0 to 10% by weight of the dispersion; (d) contains low molecular weight water-miscible aliphatic alcohols in an amount of from 0 to 10% by weight of the dispersion; (e) optionally containing an emulsion of polydimethyl siloxane having a viscosity of 100 to 100,000cs at 25 ° C in a range of 2: 1 to 1:10 by weight ratio of siloxane component (e) to amine (a). A stable aqueous dispersion used as a rinse additive fabric softener. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019860002329A 1985-03-28 1986-03-28 Textile treatment composition KR930008697B1 (en)

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GB858508129A GB8508129D0 (en) 1985-03-28 1985-03-28 Textile treatment composition
GB8508129 1985-03-28

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KR860007414A true KR860007414A (en) 1986-10-13
KR930008697B1 KR930008697B1 (en) 1993-09-13

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US (1) US4724089A (en)
EP (1) EP0199383B1 (en)
JP (1) JPH0730510B2 (en)
KR (1) KR930008697B1 (en)
CN (1) CN1005784B (en)
AT (1) ATE67236T1 (en)
AU (1) AU588864B2 (en)
CA (1) CA1286059C (en)
DE (1) DE3681322D1 (en)
DK (1) DK139686A (en)
EG (1) EG17934A (en)
FI (1) FI92330C (en)
GB (2) GB8508129D0 (en)
GR (1) GR860815B (en)
HK (1) HK104192A (en)
IE (1) IE58594B1 (en)
MA (1) MA20654A1 (en)
MX (1) MX164051B (en)
MY (1) MY101024A (en)
TR (1) TR23398A (en)

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ATE67236T1 (en) 1991-09-15
MX164051B (en) 1992-07-13
FI861337A0 (en) 1986-03-27
GB8508129D0 (en) 1985-05-01
US4724089A (en) 1988-02-09
MY101024A (en) 1991-06-29
GB2173827B (en) 1988-12-29
FI92330C (en) 1994-10-25
IE58594B1 (en) 1993-10-20
IE860830L (en) 1986-09-28
CA1286059C (en) 1991-07-16
EG17934A (en) 1991-03-30
JPH0730510B2 (en) 1995-04-05
GR860815B (en) 1986-07-21
HK104192A (en) 1992-12-31
FI92330B (en) 1994-07-15
EP0199383A2 (en) 1986-10-29
JPS61275474A (en) 1986-12-05
EP0199383B1 (en) 1991-09-11
DK139686A (en) 1986-09-29
KR930008697B1 (en) 1993-09-13
CN86102986A (en) 1986-10-01
EP0199383A3 (en) 1987-12-02
DE3681322D1 (en) 1991-10-17
GB2173827A (en) 1986-10-22
FI861337A (en) 1986-09-29
AU5535586A (en) 1986-10-02
AU588864B2 (en) 1989-09-28
DK139686D0 (en) 1986-03-25
MA20654A1 (en) 1986-10-01
GB8607690D0 (en) 1986-04-30
CN1005784B (en) 1989-11-15
TR23398A (en) 1989-12-29

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