KR970042691A - Silicon-containing water soluble high molecular compound and its manufacturing method and use - Google Patents

Silicon-containing water soluble high molecular compound and its manufacturing method and use Download PDF

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Publication number
KR970042691A
KR970042691A KR1019960067184A KR19960067184A KR970042691A KR 970042691 A KR970042691 A KR 970042691A KR 1019960067184 A KR1019960067184 A KR 1019960067184A KR 19960067184 A KR19960067184 A KR 19960067184A KR 970042691 A KR970042691 A KR 970042691A
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South Korea
Prior art keywords
silicon
high molecular
compound
soluble high
group
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KR1019960067184A
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Korean (ko)
Inventor
사토시 야마모토
요시후미 요시다
시게토 마키노
도시시게 하마구치
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고사이 아키오
스미토모가가쿠고교가부시키가이샤
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Application filed by 고사이 아키오, 스미토모가가쿠고교가부시키가이샤 filed Critical 고사이 아키오
Publication of KR970042691A publication Critical patent/KR970042691A/en

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/38—Polysiloxanes modified by chemical after-treatment
    • C08G77/382—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon
    • C08G77/388—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/42—Introducing metal atoms or metal-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/59—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/06—Paper forming aids
    • D21H21/10—Retention agents or drainage improvers

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Paper (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
  • Epoxy Resins (AREA)
  • Silicon Polymers (AREA)

Abstract

본 발명은 양이온성 그룹을 가진 통상적인 공지의 수용성 고분자 화학물 대신에 제지 등을 위한 첨가제로서 사용될 수 있고, 종이를 보강하고 충전재를 함유하는 제지에서 충전재의 잔류비를 증가시킴에 있어서 우수한 효과를 나타내며, 아미노 그룹 또는 암모늄 그룹을 가진 규소 함유 수용성 고분자 화합물(여기서, 에폭시 그룹을 가진 규소 함유 화합물(S)이 당해 고분자 화합물에 결합된다)이고, 에폭시 그룹을 가진 규소 함유 화합물(S)을 1급, 2급 또는 3급 아미노 그룹을 가진 수용성 고분자 화합물과 반응시킴으로써 생성되는 신규한 수용성 고분자 화합물에 관한 것이다.The present invention can be used as an additive for papermaking or the like instead of the conventionally known water-soluble polymer chemicals having cationic groups, and has an excellent effect in increasing the residual ratio of filler in paper reinforcement and paper containing filler. A silicon-containing water-soluble high molecular compound having an amino group or an ammonium group (wherein a silicon-containing compound (S) having an epoxy group is bonded to the polymer compound), and a silicon-containing compound (S) having an epoxy group The present invention relates to a novel water soluble high molecular compound produced by reacting with a water soluble high molecular compound having a secondary or tertiary amino group.

Description

규소 함유 수용성 고분자 화합물 및 이의 제조방법 및 용도Silicon-containing water soluble high molecular compound and its manufacturing method and use

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (10)

에폭시 그룹을 가진 규소 함유 화합물(S)이 결합되어 있는, 아미노 그룹 또는 암모늄 그룹을 가진 규소 함유 수용성 고분자 화합물.A silicon-containing water-soluble high molecular compound having an amino group or an ammonium group, to which a silicon-containing compound (S) having an epoxy group is bonded. 제1항에 있어서, 분자내에 하기 화학식 1로 표현되는 그룹 및 하기 화학식 2로 표현되는 그룹을 함유하는 규소 수용성 고분자 화합물.The silicon water-soluble polymer compound according to claim 1, which contains a group represented by the following formula (1) and a group represented by the following formula (2) in a molecule. 화학식 1Formula 1 화학식 2Formula 2 상기 식에서,Where R1은 알킬 또는 알케닐 그룹이고,R 1 is an alkyl or alkenyl group, R2및 R3은 독립적을 알킬, 알케닐, 알콕시 또는 알케닐옥시 그룹이며, R4는 수소 또는 알킬 그룹이다.R 2 and R 3 are independently alkyl, alkenyl, alkoxy or alkenyloxy groups, and R 4 is hydrogen or an alkyl group. 제1항에 있어서, 하기 화학식 3으로 표현되는 규소 함유 수용성 고분자 화합물.The silicon-containing water-soluble high molecular compound of Claim 1 represented by following formula (3). 화학식 3Formula 3 상기식에서, R1, R2, R3및 R4는 제2항에서 정의한 바와 같고,Wherein R 1 , R 2 , R 3 and R 4 are as defined in claim 2, R5는 수소 또는 알킬 그룹이며,R 5 is hydrogen or an alkyl group, X는 지방족 연결 그룹이고,X is an aliphatic linking group, X및 R5중의 탄소 원자는 결합하여 포화된 탄소 환을 형성할 수 있다.The carbon atoms in X and R 5 may combine to form a saturated carbon ring. 제1항에 있어서, 에폭시 그룹을 가진 규소 함유 화합물(S)을 1급, 2급 또는 3급 아미노 그룹을 가진 수용성 고분자 화합물(A)과 반응시킴으로써 수득되는 규소함유 수용성 고분자 화합물.The silicon-containing water-soluble high molecular compound according to claim 1, which is obtained by reacting a silicon-containing compound (S) having an epoxy group with a water-soluble high molecular compound (A) having a primary, secondary or tertiary amino group. 제4항에 있어서, 수용성 고분자 화합물(A)이 1급 또는 2급 아미노 그룹을 가진 규소 함유 수용성 고분자 화합물.The silicon-containing water-soluble high molecular compound according to claim 4, wherein the water-soluble high molecular compound (A) has a primary or secondary amino group. 제4항에 있어서, 수용성 고분자 화합물(A)이 1급, 2급 또는 3급 아미노 그룹을 가진 양이온성 또는 양쪽성(메트)아크릴아미드형 중합체인 규소 함유 수용성 고분자 화합물.The silicon-containing water-soluble high molecular compound according to claim 4, wherein the water-soluble high molecular compound (A) is a cationic or amphoteric (meth) acrylamide type polymer having a primary, secondary or tertiary amino group. 제6항에 있어서, (메트)아크릴아미드형 중합체가 1급 또는 2급 아미노 그룹을 가진 규소 함유 수용성 고분자 화합물.The silicon-containing water-soluble high molecular compound according to claim 6, wherein the (meth) acrylamide type polymer has a primary or secondary amino group. 제1항에 있어서, 에폭시 그룹을 가진 규소 함유 화합물(S)을 1급, 2급 또는 3급 아미노 그룹을 가진 아미노 화합물과 반응시킨 다음, 중합 또는 중축합 반응을 수행함으로써 수득되는 규소 함유 수용성 고분자 화합물.The silicon-containing water-soluble polymer according to claim 1, wherein the silicon-containing compound (S) having an epoxy group is reacted with an amino compound having a primary, secondary or tertiary amino group, and then subjected to a polymerization or polycondensation reaction. compound. 제1항에 있어서, 규소 함유 화합물(S)이 규소 원자로 환산하여 0.1 내지 10 중량%의 양으로 상기 고분자 화합물에 결합되는 규소 함유 수용성 고분자 화합물.The silicon-containing water-soluble polymer compound according to claim 1, wherein the silicon-containing compound (S) is bonded to the polymer compound in an amount of 0.1 to 10% by weight in terms of silicon atoms. 1급, 2급 또는 3급 아미노 그룹을 가진 수용성 고분자 화합물(A)을 물 또는 알콜 중에서 에폭시 그룹을 가진 규소 함유 화합물(S)과 반응시킴으로써, 규소 함유 수용성 화합물을 제조하는 방법.A method for producing a silicon-containing water-soluble compound by reacting a water-soluble high molecular compound (A) having a primary, secondary or tertiary amino group with a silicon-containing compound (S) having an epoxy group in water or alcohol.
KR1019960067184A 1995-12-19 1996-12-18 Silicon-containing water soluble high molecular compound and its manufacturing method and use KR970042691A (en)

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JP7330330A JPH09169817A (en) 1995-12-19 1995-12-19 Water-soluble silicon-containing polymer, its preparation and use of the same
JP1995-330330 1995-12-19

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CA (1) CA2193155A1 (en)
FI (1) FI965064A (en)
NZ (1) NZ299968A (en)
SE (1) SE9604654L (en)

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JP4759805B2 (en) * 2000-12-05 2011-08-31 凸版印刷株式会社 Magnetic fiber body and method for producing the same
AU2006236212A1 (en) * 2005-04-20 2006-10-26 Dow Corning Corporation Removal of organic deposits from recycled fibers used for producing paper
CN101360764B (en) * 2005-11-14 2011-12-14 西巴控股公司 Preparation of functionalized cationic polymers and their preparation and application in personal care
US7999065B2 (en) 2006-10-13 2011-08-16 Cytec Technology Corp. Hydrophobically modified polyamine scale inhibitors
CA2666389C (en) 2006-10-13 2014-10-28 Cytec Technology Corp. Hydrophobically modified polyamine scale inhibitors
JP4998702B2 (en) * 2007-01-17 2012-08-15 信越化学工業株式会社 Articles coated or surface-treated with a coating agent composition
EP2139812B1 (en) * 2007-04-20 2019-01-02 Cytec Technology Corp. Use of silicon-containing polymers to improve red mud flocculation in the bayer process
JP5549433B2 (en) * 2010-07-05 2014-07-16 日東紡績株式会社 Water-soluble polymer compound, method for producing the same, and surface treatment agent containing the same
JP2012097270A (en) * 2011-12-22 2012-05-24 Shin-Etsu Chemical Co Ltd Coating agent composition, and method for producing the same

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NZ299968A (en) 1998-04-27
SE9604654D0 (en) 1996-12-18
CA2193155A1 (en) 1997-06-20
SE9604654L (en) 1997-06-20
FI965064A (en) 1997-06-20
FI965064A0 (en) 1996-12-17
JPH09169817A (en) 1997-06-30

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