KR860007328A - 자외선 경화형 수지 조성물 및 피복 광섬유 - Google Patents

자외선 경화형 수지 조성물 및 피복 광섬유 Download PDF

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KR860007328A
KR860007328A KR1019860002398A KR860002398A KR860007328A KR 860007328 A KR860007328 A KR 860007328A KR 1019860002398 A KR1019860002398 A KR 1019860002398A KR 860002398 A KR860002398 A KR 860002398A KR 860007328 A KR860007328 A KR 860007328A
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South Korea
Prior art keywords
hydroxyl group
diene polymer
composition according
composition
compound
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KR1019860002398A
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KR940006473B1 (ko
Inventor
다까오 기무라
신조 야마까와
료따로 오오노
Original Assignee
니혼 덴신 뎅와 가부시끼가이샤
신도 히사시
니흔 고오세이 고무 가부시끼가이샤
니혼 덴신 뎅와가부시끼가이샤
요시미쓰 히사시
니혼 고오세이 고무 가부시끼가이샤
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Application filed by 니혼 덴신 뎅와 가부시끼가이샤, 신도 히사시, 니흔 고오세이 고무 가부시끼가이샤, 니혼 덴신 뎅와가부시끼가이샤, 요시미쓰 히사시, 니혼 고오세이 고무 가부시끼가이샤 filed Critical 니혼 덴신 뎅와 가부시끼가이샤
Publication of KR860007328A publication Critical patent/KR860007328A/ko
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Publication of KR940006473B1 publication Critical patent/KR940006473B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • C08L75/08—Polyurethanes from polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/69—Polymers of conjugated dienes
    • C08G18/698—Mixtures with compounds of group C08G18/40
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/104—Coating to obtain optical fibres
    • C03C25/106—Single coatings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
    • C08G18/6204—Polymers of olefins
    • C08G18/6208—Hydrogenated polymers of conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/671—Unsaturated compounds having only one group containing active hydrogen
    • C08G18/672—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Geochemistry & Mineralogy (AREA)
  • General Chemical & Material Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Macromonomer-Based Addition Polymer (AREA)

Abstract

내용 없음

Description

자외선 경화형 수지 조성물 및 피복 광섬유
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (14)

  1. 폴리에테트폴리올 및 수산기를 갖는 디엔중합체로부터 유도되는 폴리우레탄으로 구성되고, 상기 수산기를 갖는 디엔 중합체가 함유하는 탄소-탄소 이중 결합과는 다른 중합성 이중 결합을 갖는 폴리우레탄을 주성분으로 하는 자외선 경화형 수지 조성물.
  2. 제 1 항에 있어서, 상기 폴리우레탄이 상기 폴리에테트폴리올, 수산기를 갖는 디엔중합체 및 중합성 이중 결합과 수산기를 갖는 화합물로 구성되고, 이들이 우레탄 결합에 의하여 결합된 것인 조성물.
  3. 제 1 항에 있어서, 상기 폴리우레탄이 상기 폴리에테트폴리올, 상기 수산기를 갖는 디엔중합체 및 중합성 이중 결합과 수산기를 갖는 화합물과 디이소시아네이트 화합물의 반응에 의하여 제조된 것인 조성물.
  4. 제 3 항에 있어서, 상기 폴리에테트폴리올이 수평균 분자량 300∼5,000인 조성물.
  5. 제 3 항에 있어서, 상기 수산기를 갖는 디엔중합체가 상호 용제의 존재하에서 디엔류와 과산화수소 수용액을 촉매로 하는 중합에 의하여 제조된 중합체인 조성물.
  6. 제 5 항에 있어서, 상기 수산기를 갖는 디엔 중합체가 분자중에 1,4-결합 단위를 60% 이상 갖는 것인 조성물.
  7. 제 3 항에 있어서, 상기 수산기를 갖는 디엔중합체가 1,2-결합 단위 및 3,4-결합 단위의 이중 결합에 대하여 선택적으로 수소첨가되고, 수소첨가율이 60% 이상인 조성물.
  8. 제 3 항에 있어서, 상기 수산기를 갖는 디엔중합체가, 비선택적으로 수소첨가되고, 수소첨가율이 10% 이상 50% 미만인 조성물.
  9. 제 3 항에 있어서, 상기 폴리에테트 폴리올의 사용량이 수산기를 갖는 상기 디엔 중합체 1몰당 0.1∼5몰인 조성물.
  10. 제 1 항에 있어서, 상기 중합성 이중 결합이 아크릴로일기 또는 메타크릴토일기로서 포함되어 있는 조성물.
  11. 제 3항에 있어서, 상기 중합성 이중 결합과 수산기를 갖는 화합물의 사용량이, 폴리에테트 폴리올 및 수산기를 갖는 디엔 중합체의 합계 1몰당 0.6∼1.6몰인 조성물.
  12. 제 3항에 있어서, 상기 디이소시아네이트 화합물의 사용량이 폴리에테트 폴리올 및 수산기를 갖는 디엔 중합체 1몰당 1.3∼1.8몰인 조성물.
  13. 제 3항에 있어서, 상기 폴리우레탄이 디이소시아네이트 화합물에 중합성 이중 결합과 수산기를 갖는 화합물을 반응시키고, 그 생성물을 폴리에테트폴리올 및 수산기를 갖는 디엔 중합체의 한쪽과 반응시키고, 이어서 얻어진 반응 생성물을 이들 2 화합물의 다른한쪽과 반응시켜서 제조한 것인 조성물.
  14. 제 1항의 수지조성물의 경화물로 되는 피복층을 갖는 피복 광섬유.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019860002398A 1985-03-29 1986-03-29 자외선 경화형 수지 조성물 및 피복 광섬유 KR940006473B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP6608085 1985-03-29
JP60-66080 1985-03-29

Publications (2)

Publication Number Publication Date
KR860007328A true KR860007328A (ko) 1986-10-10
KR940006473B1 KR940006473B1 (ko) 1994-07-20

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KR1019860002398A KR940006473B1 (ko) 1985-03-29 1986-03-29 자외선 경화형 수지 조성물 및 피복 광섬유

Country Status (6)

Country Link
US (1) US4720529A (ko)
EP (1) EP0200366B1 (ko)
KR (1) KR940006473B1 (ko)
AU (1) AU580856B2 (ko)
CA (1) CA1243444A (ko)
DE (1) DE3665470D1 (ko)

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Publication number Publication date
DE3665470D1 (en) 1989-10-12
US4720529A (en) 1988-01-19
EP0200366B1 (en) 1989-09-06
CA1243444A (en) 1988-10-18
AU5526486A (en) 1986-10-02
EP0200366A1 (en) 1986-11-05
AU580856B2 (en) 1989-02-02
KR940006473B1 (ko) 1994-07-20

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