KR850003549A - 세포상 가교 폴리디시클로펜타디엔의 제조방법 - Google Patents

세포상 가교 폴리디시클로펜타디엔의 제조방법 Download PDF

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KR850003549A
KR850003549A KR1019840007219A KR840007219A KR850003549A KR 850003549 A KR850003549 A KR 850003549A KR 1019840007219 A KR1019840007219 A KR 1019840007219A KR 840007219 A KR840007219 A KR 840007219A KR 850003549 A KR850003549 A KR 850003549A
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catalyst
mixture
dicyclopentadiene
reactant
reactant solution
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KR1019840007219A
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KR920002149B1 (ko
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로버트 리치 더글라스
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미챌 비. 키한
헤르쿨레스 인코오포레이티드
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Priority claimed from US06/552,872 external-priority patent/US4458037A/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
    • C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
    • C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2345/00—Characterised by the use of homopolymers or copolymers of compounds having no unsaturated aliphatic radicals in side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic or in a heterocyclic ring system; Derivatives of such polymers

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  • Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)

Abstract

내용 없음

Description

세포상 가교 폴리디시클로펜타디엔의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (12)

  1. 치환-촉매계의 알킬알루미늄 할라이드 활성제를 함유하는 반응제 용액을 치환-촉매계의 촉매를 함유하는 반응제용액, 디시클로펜타디엔을 함유하는 적어도 하나의 반응제용액과 혼합하고, 이 혼합물을 충분시간 가열하여 디시클로펜타디엔을 중합한 후, 가교중합체를 호수하여 디시클로펜타디엔 단위를 함유하는 가교 열경화성중합체를 제조하는 방법에 있어서, 적어도 하나의 반응제 용액이 발포제를 함유하고, 알킬알루미늄 할라이드 활성제는 디알킬알루미늄 요오드화물, 알킬알루미늄 디요오드화물, 또는 트리알킬 알루미늄 화합물과 원소요오드와의 혼합물이고, 사기 혼합물을 약 30-80℃의 온도로 가열시켜 세포상중합체를 제조함을 특징으로 하는 세포상 가교 폴리 디시클로펜타디엔의 제조방법.
  2. 제1항에 있어서, 알킬알루미늄 할라이드 활성제가 디에틸알루미늄 요오드화물임을 특징으로 하는 세포상 가교폴리디시클로펜타디엔의 제조방법.
  3. 제1항 또는 제2항에 있어서, 적어도 하나의 반응제류가 약 5-12개의 탄소원자를 함유하는 1이상의 다른 시클로올레핀 단량체의 약 20%(디시클로 펜타디엔의 중량기준)까지 함유함을 특징으로 하는 세포상가교 폴리 디시클로펜타디엔의 제조방법.
  4. 제3항에 있어서, 다른 시클로올레핀 단량체가 노르보르넨, 노르보르나디엔, 시클로펜텐, 디메탄헥사 히드로나프탈렌 및 디메탄 옥타히드로 나프탈렌의 그룹으로부터 선별된 것임을 특징으로 하는 세포상 가교 폴리 디시클로펜타디엔의 제조방법.
  5. 제1항 내지 제4항중 어느 한행에 있어서, 상기 치환- 촉매계의 촉매가 텅스텐을 함유하는 촉매임을 특징으로 하는 세포상 가교 폴리 디시클로펜타디엔의 제조방법.
  6. 제1항 내지 제5항중 어느 한항에 있어서, 적어도 하나의 반응제류가 디시클로펜타디엔의 중량을 기준으로 한 3-15중량%의 탄성체를 함유함은 특징으로 하는 세포상 가교폴리디시클로펜타디엔의 제조방법.
  7. 치환-촉매계의 알킬알루미늄 할라이드 활성제를 함유하는 반응제용액 혼합물(a), 치환-촉매계의 촉매를 함유하는 반응제 용액혼합물, 디시클로펜타디엔을 함유하는 적어도 하나의 반응제용액 혼합물(b)로 수성되는 반응제 용액 혼합물에 있어서, 상기 혼합물은 발포제를 함유하고 활성제는 디알킬알루미늄 요오드화물, 알킬알루미늄 디요오드화물, 또는 트리알킬 알루미늄 화합물과 원소 요오드와의 혼합물임을 특징으로 하는 반응제 용액 혼합물.
  8. 제7항에 있어서, 알킬알루미늄 할라이드 활성제가 디에틸 알루미늄 요오드화물임을 특징으로 하는 반응제 용액 혼합물.
  9. 제7항에 있어서, 적어도 하나의 반응제류가 약 5-12개의 탄소원자를 함유하는 1이상의 다른 시클로올레핀 단량체의 약 20%(디시클로펜타디엔의 중량기준)까지 함유함을 특징으로 하는 반응제 용액 혼합물.
  10. 제9항에 있어서, 다른 시클로올레핀 단량체가 노르보르넨, 노르보르나디엔, 시클로펜텐, 디메탄헥사히드로나프탈렌 및 디메탄 옥타히드로나프탈렌의 그룹으로부터 선별된 것임을 특징으로 하는 반응제용액 혼합물.
  11. 제1항에 있어서, 상기 치환-촉매계의 촉매가 텅스텐을 함유하는 촉매임을 특징으로 하는 반응제 용액 혼합물.
  12. 제1항에 있어서, 적어도 하나의 반응제류가 디시클로 펜타디엔의 중량을 기준으로 한 약 3-5중량%의 탄성체를 함유함을 특징으로 하는 반응제 용액 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019840007219A 1983-11-17 1984-11-17 기포상 가교 폴리디시클로펜타디엔의 제조방법 KR920002149B1 (ko)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US552872 1983-11-17
US06/552,872 US4458037A (en) 1983-11-17 1983-11-17 Method of making cellular crosslinked poly(dicyclopentadiene)
US552,872 1983-11-17
US623307 1984-06-21
US623,307 1984-06-21
US06/623,307 US4496669A (en) 1983-11-17 1984-06-21 Method of making cellular crosslinked poly(dicyclopentadiene)

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KR850003549A true KR850003549A (ko) 1985-06-20
KR920002149B1 KR920002149B1 (ko) 1992-03-12

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US (1) US4496669A (ko)
JP (1) JPH0674341B2 (ko)
KR (1) KR920002149B1 (ko)
CA (1) CA1242850A (ko)

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US4657981A (en) * 1962-05-14 1987-04-14 Hercules Incorporated Dicyclopentadiene polymer containing elastomer
US4604408A (en) * 1983-08-26 1986-08-05 Hercules Incorporated Composition for making cellular thermoset polymerized dicyclopentadiene polymer
US4598102A (en) * 1983-11-17 1986-07-01 Hercules Incorporated Method, composition and product produced by delayed gelation in the polymerization of cycloolefins
USRE35717E (en) * 1986-04-11 1998-01-20 Metton America, Inc. Cycloolefin copolymerization method, feed composition and product
CA1284247C (en) * 1986-06-24 1991-05-14 Shigeyoshi Hara Metathesis polymerization of cycloolefins
JPH0717740B2 (ja) * 1986-10-01 1995-03-01 帝人株式会社 架橋重合体成型物の製造方法
EP0287762A3 (en) * 1987-02-16 1991-01-23 Hercules Incorporated Methathesis polymerized copolymer
CA1296836C (en) * 1987-03-13 1992-03-03 Zen-Ichiro Endo Metathesis polymerized copolymer
US4891387A (en) * 1988-06-28 1990-01-02 The B. F. Goodrich Company Bulk polymerized cycloolefin monomers containing microencapsulated blowing agents
US4959395A (en) * 1988-06-28 1990-09-25 The B. F. Goodrich Company Bulk polymerized molded products containing cycloolefin monoments with microencapsulated blowing agents
CA2010319C (en) * 1989-02-20 2001-03-13 Yohzoh Yamamoto Foamable polymer composition and foamed article
USH1388H (en) * 1992-12-23 1994-12-06 Hercules Incorporated Polyolefin polymer and method of making same
CA2112146A1 (en) * 1992-12-23 1994-06-24 Nitya P. Khasat Polydicyclopentadiene having improved stability and toughened with polymeric particles
US5840820A (en) * 1995-04-13 1998-11-24 The University Of North Carolina At Chapel Hill Olefin metathesis reactions in carbon dioxide medium
DE19619813A1 (de) * 1995-10-30 1997-11-20 Hoechst Ag Polymere Schäume
JP2003040983A (ja) * 2001-07-30 2003-02-13 Teijin Meton Kk 発泡重合成形体及びその製造方法
US20070105755A1 (en) * 2005-10-26 2007-05-10 Neose Technologies, Inc. One pot desialylation and glycopegylation of therapeutic peptides
US9630311B2 (en) 2014-12-23 2017-04-25 Charlie Creelman Pistol grip attachment for use with a paintbrush

Family Cites Families (3)

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US4400340A (en) * 1982-01-25 1983-08-23 Hercules Incorporated Method for making a dicyclopentadiene thermoset polymer
US4002815A (en) * 1973-11-05 1977-01-11 The B. F. Goodrich Company Cyclopentene-dicyclopentadiene copolymers and method of making same
JPS5290603A (en) * 1976-01-22 1977-07-30 Takiron Co Synthetic leather

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JPH0674341B2 (ja) 1994-09-21
CA1242850A (en) 1988-10-04
KR920002149B1 (ko) 1992-03-12
JPH05255530A (ja) 1993-10-05
US4496669A (en) 1985-01-29

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