KR850000103B1 - Method of high tension cold steel sheet - Google Patents

Method of high tension cold steel sheet Download PDF

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KR850000103B1
KR850000103B1 KR1019800004513A KR800004513A KR850000103B1 KR 850000103 B1 KR850000103 B1 KR 850000103B1 KR 1019800004513 A KR1019800004513 A KR 1019800004513A KR 800004513 A KR800004513 A KR 800004513A KR 850000103 B1 KR850000103 B1 KR 850000103B1
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steel sheet
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rolled steel
amount
cooling rate
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KR830004424A (en
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오사무 아끼스에
데루아끼 야마다
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신닛본 세이데쓰 가부시기 가이샤
사이도오 에이시로오
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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/46Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals

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Abstract

This invention relates to high-tension cold-rolling steel sheet, which has a low yield point, low yield ratio, high ductility and 40- 80 kg/mm2 tensile strength. The steel sheet, which contains 0.01- 0.12% carbon, under 1.2% silicon, 1.0-1.8% Mn, 0.010.10% Sol. Al, and the remainder Fe and impurities, is first hot-rolled. The hot-rolled steel sheet is then cold-rolled. The hot-rolled steel sheet is then heated at 30-800≰C, for 20 sec.2min. Continuous annealing treatment is then performed on the sheet at 30-300≰C/sec. cooling velocity to a temperature under 250≰C.

Description

가공성이 뛰어난 복합조직 고장력 냉연강판의 제조방법Manufacturing method of composite structure high tensile cold rolled steel sheet with excellent workability

제1(a)도, 제1(b)도, 제1(c)도는 C양과 Mn양의 조합에 대하여 냉각속도 및 복합조직화의 경향을 나타낸 도면이다.1 (a), 1 (b), and 1 (c) are graphs showing the cooling rate and the tendency of complex organization for the combination of the amount of C and Mn.

본 발명은 저항복점, 저항복비 및 높은 연성을 가지며, 인장 강도가 40-80kg/mm2인 고장력 냉연강판을 제조하는 방법에 관한 것이다.The present invention relates to a method for producing a high tensile cold rolled steel sheet having a resistance yield point, a resistance ratio and high ductility, and a tensile strength of 40-80kg / mm 2 .

최근, 자동차업계에서는, 차체중량을 줄여 성 에너지를 도모함과 동시에 안전 대책의 일환으로서 종래의 연질강판에 대신하여 판두께를 얇게하여 사용할 수 있는 고장력 강판의 본격적인 사용을 추진해오고 있다. 이와 같은 자동차업계의 요구에 대하여 철강업계로서 이에 대응해 나가자면, 종래의 고강도 냉연강판이 상의 재질특성을 가짐과 동시에 가격이 싼 것을 제공해 나가야할 필요성이 있다.In recent years, the automobile industry has been promoting full-scale use of high-strength steel sheets that can be used by thinning the sheet thickness instead of the conventional soft steel sheet as a part of safety measures while reducing the body weight. In order to respond to the demands of the automotive industry as the steel industry, there is a need to provide a high-strength cold-rolled steel sheet having a material property of the phase and at the same time low price.

종래, 복합조직 고장력 냉연강판 및 그의 제조법이 예를들어 일본국 특개소 50-98419호 공보에 기술되어 있는데, 그 공보의 발명은 기본적으로는 C, Mn을 주체로 하고, 필요에 따라 Si를 0.1%-0.7%함유한 강을 상태도상에서 α,γ2상(相) 공존역(共存域)에 가열하고, 500℃까지의 평균 냉각속도가 0.5-30℃/sec가 되도록 비교적 급냉하므로서 얻어지는 페라트와 급냉 변태 생성물로서된 조직으로, 일부잔류 오스테나이트도 함유한 복합조직 강판을 얻고저 하는 것이다.Conventionally, a composite structure high tensile cold rolled steel sheet and a manufacturing method thereof are described, for example, in Japanese Patent Application Laid-Open No. 50-98419. The invention of the publication mainly consists of C and Mn, and Si as needed is 0.1. Ferat and the steel obtained by heating the steel containing% -0.7% in the α, γ2 phase coexistence zone in the state diagram, and relatively quenching so that the average cooling rate to 500 ° C is 0.5-30 ° C / sec. It is to obtain a composite steel sheet containing a structure of quench transformation, which also contains some residual austenite.

본 발명은, 특히 연속소둔에서의 균열(均熱)에 계속되는 냉각조건과, 출발소재의 성분조성과의 조합에 의하여 경제적으로 가공성이 우수한 복합조직 고장력 냉연 강판의 신규한 제조방업을 제공코저 하는 것이다.The present invention is to provide a novel manufacturing method for a composite high-strength cold rolled steel sheet which is economically workable by a combination of cooling conditions following a crack in continuous annealing and composition of a starting material. .

본 발명에 의해서 얻어진 강판은 저항복점을 나타내면서 40-80kg/mm2의 인장강도를 가지며, 높은 연성을 가지므로 아래와 같은 효과가 있다. 즉 항복점은 프레스 성형시의 재료의 스프링백에 관계하는 것으로서, 프레스 금형에 친화력을 가지며 성형품의 형상을 좋게하자면 저항복점(저항복비)의 쪽이 프레스 가 공기에의 부담을 증대시키지 않는다. 본 발명의 제조방법에 의해서 합금첨가량을 낮게하여 값싸게 복합조직 고강도 강판을 제조하면 자동차용 강판등의 고장력화에는 가일층 기여하게 된다. 또 본 발명에 의해서 얻어진 강판은 높은 연성을 가진다. 연성은 당연한 것이며 고도의 가공에 견딘다는 의미에서 높은편이 좋으므로 이러한 점에서도 본 발명에 의한 강판은 현저하게 유리하다.Steel sheet obtained by the present invention has a tensile strength of 40-80kg / mm 2 while showing a resistance point, and has a high ductility has the following effects. In other words, the yield point is related to the spring back of the material at the time of press molding. The yield point (resistance ratio) does not increase the pressure on the air in order to have affinity for the press die and improve the shape of the molded article. By manufacturing the high-strength composite steel sheet at low cost by lowering the alloying amount by the manufacturing method of the present invention, it contributes further to the high tension of the steel sheet for automobiles. Moreover, the steel plate obtained by this invention has high ductility. Since the ductility is natural and high in the sense of withstanding high processing, the steel sheet according to the present invention is remarkably advantageous in this respect.

한편, 자동차 용 외판에 쓰여지는 강판의 두께는 0.8mm 정도의 것이 일반적이 었으나, 최근 중량경감을 위하여 이를 더욱 삭감하려는 움직임이 활발하다. 그런경우 부재(部材)의 변형에 대한 저항을 나타내는 덴트저항성이 문제가 된다. 덴트(dent) 저항(국소적으로 오므라드는 것에 대한 저항)은 강판두께와 강도에 의존한다. 고강도 박(薄) 강판이 자동차용 외판으로 사용되는 이유는 바로 이 덴트 저항을 향상시키기 위함이다. 그런 의미에서 본 발명에 따라서, 저항복점과 높은 신도(伸度)로서 가공성을 확보할 수 있으며 또한 높은 인장강도로 덴트 저항을 향상시킨 강판이 얻어진다고 하는 것은, 고강도 박강판이 자동차의 외판용으로서 종래의 연질강판에 대신하여 자동차업계의 요망을 충분히 만족시켜 사용된다는 점에서 커다란 의미가 있다.On the other hand, the thickness of the steel sheet used on the outer plate for automobiles was generally about 0.8mm, but in recent years, the movement to reduce it further to reduce the weight is active. In such a case, the dent resistance indicating resistance to deformation of the member becomes a problem. Dent resistance (resistance to locally retracting) depends on sheet thickness and strength. The reason why the high strength thin steel sheet is used as an exterior plate for automobiles is to improve this dent resistance. In this sense, according to the present invention, a steel sheet capable of securing workability with a resistance point and high elongation and having improved dent resistance with high tensile strength is obtained. There is great significance in that it is used in place of the conventional soft steel sheet sufficiently satisfying the demands of the automotive industry.

이하, 본 발명의 내용을 상세히 설명한다.Hereinafter, the content of the present invention will be described in detail.

본 발명의 특징의 하나는 후술하는 바와 같으며, 연속 소둔에서의 냉각시 250℃ 이하의 온도까지를 30℃-300℃/sec의 매우 빠른 냉각속도를 채용하는데 있다. 이와 같은 급속냉각에 있어서 본 발명의 목적을 달성하자면, 먼저 소재의 성분조성은 아래와 같은 조건이 필요하다.One of the features of the present invention is as described below, and employs a very fast cooling rate of 30 ° C.-300 ° C./sec up to a temperature of 250 ° C. or less upon cooling in continuous annealing. In order to achieve the object of the present invention in such rapid cooling, first, the composition of the material requires the following conditions.

아래와 같은 조건이 필요하다.The following conditions are required.

C양은 0.01% 이상이지 않으면 급냉에 의해서 생기는 급냉조직의 존재량이 불충분하다. 한편 C양이 0.12%를 넘으면 급냉 변태 생성물이 지나치게 증대되어 본 발명이 의도하는 높은 연성을 갖는 복합조직으로 되는 것이 곤란하다. 이런 경우의 급냉변태 생성물은 마르텐사이트나, 미변태(未

Figure kpo00002
態) 오스테나이트상(相)으로 된다.If the amount of C is not more than 0.01%, the amount of quenching tissue generated by quenching is insufficient. On the other hand, if the amount of C exceeds 0.12%, the quench transformation product is excessively increased, making it difficult to obtain a composite structure having a high ductility intended by the present invention. In this case, the quench transformation product is martensite or untransformation.
Figure kpo00002
(Iii) It becomes an austenite phase.

다음에, Mn 양은 γ상(相)의 소입성(燒入性)을 높이며 냉각과정에서의 급냉 변태 생성물을 얻음과 동시에 페라이트 바탕을 강화하여 연성을 높이는 효과를 갖는다. 1.0%미만에서는 소입성이 불충분하며. 1.8%을 넘는 Mn양은 음접성을 열화(劣化)시킴과 동시에 경제성의 점에서 바람직하지 못하다.Next, the amount of Mn increases the quenchability of the γ phase, obtains the quench transformation product during the cooling process, and has the effect of enhancing the ductility by strengthening the ferrite substrate. Hardness is insufficient at less than 1.0%. An Mn amount of more than 1.8% is not preferable in terms of economical efficiency while deteriorating the negative contact.

Al은 탈산재(脫酸材)로서 필요한 것이며, 0.01%미만에서는 부족한 것이며, 또 0.01%-0.10%이면 충분히 탈산의 목적을 달성할 수 있다.Al is needed as a deoxidation material, it is insufficient in less than 0.01%, and if it is 0.01% -0.10%, the objective of deoxidation can fully be achieved.

Si는 기본적으로는 함유시킬 필요가 없고, Si≤0.1%로서 좋지만, 복합조직의 연성을 높이기 위해서는 1.2%이하의 범위로 첨가한다. 그 양보다 많아지면, 도장성, 내식성에 악 영향을 주게되므로 1.2%이하로 한정시켰다.Si does not basically need to be contained and is good as Si≤0.1%, but in order to increase the ductility of the composite structure, it is added in the range of 1.2% or less. If more than the amount, since it adversely affects the paintability and corrosion resistance, it was limited to 1.2% or less.

이밖에 더욱 강도를 늘리기 위하여, Cr, Cu, Ni를 각각 1%이하 및 휨(曲)가공성을 향상시키기 위하여 Ca, REM, Zr을 각각 0.1%이하의 범위로 함유시켜도 좋다.In addition, in order to further increase the strength, Ca, REM, and Zr may be contained in the range of 0.1% or less, respectively, in order to improve Cr, Cu, and Ni by 1% or less, and to improve the bending property.

이와 같이 성분조성이 조정된 소재는, 통상의 방법에 따라서 연속주조법 또는 강괴-분괴법에 의해 슬레브로 만들고 열연 및 냉연판으로 하고, 다음 본 발명의 특징적인 연속 소둔을 행한다. 연속 소둔의 균일은 730℃-800℃×20초-2분이 다음과 같은 이유에 의하여 필요하다. 이는 730℃미만, 20초 미만에서는 소망으로 하는 잔류 오스테나이트를 얻는데 필요한 γ양과 γ중의 C, Mn등의 농축이 불충분해지면, 설사 급냉을 행하였다하더라도 소망으로 하는 복합조직이 얻어지지 않으며 강도연성 밸런스가 좋은 강판을 얻을 수는 없다. 한편 800℃를 넘는 균열에서는 γ양이 지나치게 많아지며 또한, γ중의 C, Mn이 희박하게 된다. 그 결과, 급냉을 재용하더라도 소망으로 하는 잔류 오스테나 이트가 얻어지지 않으며 단단한 마르텐사이트가 많아지며, 강도-연성 밸런스가 좋은 강판은 얻어지지 않게된다. 균열시간의 상한선은 길어도 좋으나 노(爐)의 길이가 길어질수록 설비의 경제적인 면을 고려해서 2분으로 한정시켰다.Thus, the raw material whose composition is adjusted is made into a slab by the continuous casting method or the ingot-destructive method according to a conventional method, and made into a hot rolled and cold rolled plate, and performs the characteristic continuous annealing of this invention next. Uniformity of continuous annealing requires 730 ° C-800 ° C x 20 seconds-2 minutes for the following reasons. If the amount of γ necessary for obtaining the desired retained austenite and concentration of C and Mn in γ is insufficient when the residual amount of austenite is less than 730 ° C and less than 20 seconds, the desired composite structure cannot be obtained even if quenching is performed. Can't get a good grater. On the other hand, in the crack exceeding 800 ° C., the amount of γ is excessively large, and C and Mn in γ become lean. As a result, even if quenching is reused, the desired residual austenite is not obtained, hard martensite is increased, and steel sheets having a good strength-ductility balance are not obtained. The upper limit of crack time may be longer, but the longer the length of the furnace is, the more limited it is to 2 minutes in consideration of the economics of the installation.

상기한 균열후 행하는 냉각은 250℃까지를 30℃-300℃/sec, 바람직하게로는 100℃-2300℃/sec의 속도로 행한다. 이는, 먼저 급냉종점을 250℃로 한 것은 그 이상의 온도에서 급냉을 멈추면, 잔류 오스테나이드가 마르텐사이트로 변태하여 복합조급이 얻어지지 않기 때문이다.The cooling performed after the cracking is performed up to 250 ° C at a rate of 30 ° C-300 ° C / sec, preferably 100 ° C-2300 ° C / sec. This is because the quenching end point is 250 ° C. first because when quenching is stopped at a temperature higher than that, the residual austenide is transformed into martensite, and thus, the compound aid is not obtained.

다음에 냉각속도에 대해서는 그 속도가 30℃/sec미만에서는, 본 발명에서 규정란 저합금량을 가지고서는 복합조직을 얻기 어렵고, 한편 냉각 속도를 300℃/sec 이상으로 하면 연성의 저하가 일어난다. 즉 연성은 30˚-300℃/sec의 범위의 냉각속도에서는 거의 변하지 않는다. 이러한 제어된 냉각속도는, 기체냉각, 수중침지 냉각에서는 얻기가 어려운 것이며 기체-액체의 혼합기(混合氣)의 분사에 의한 기체 및 물에 의한 냉각법에 의해서 용이하게 얻어지는 것이다.Next, about the cooling rate, when the speed | rate is less than 30 degreeC / sec, it is difficult to obtain a composite structure with the low alloy amount prescribed | regulated by this invention, and when a cooling rate is 300 degreeC / sec or more, ductility will fall. In other words, the ductility hardly changes at a cooling rate in the range of 30 ° -300 ° C / sec. Such controlled cooling rate is difficult to obtain in gas cooling and submerged cooling, and is easily obtained by cooling by gas and water by injection of a gas-liquid mixer.

또한, 이 기체 및 물에 의한 냉각법에 의하면 강대(鋼帶)의 폭방향의 균일냉각이 가능하며, 균일한 재질이 얻어지는 특징도 가진다.Moreover, according to the cooling method by this gas and water, uniform cooling of the width direction of a steel strip is possible, and it also has the characteristic that a uniform material is obtained.

이리하여 연속소둔을 끝낸 재료는 통상 1.0% 전후의 압하율(壓下率)로서 형상이 교정된다.In this way, the shape of the material after continuous annealing is usually corrected as a reduction ratio of about 1.0%.

이하, 본 발명을 실시예에 의거하여 설명한다.EMBODIMENT OF THE INVENTION Hereinafter, this invention is demonstrated based on an Example.

제1표에 나타낸 바와 같은 각종의 성분을 가진 강을 용제(溶製)하여 열간압연에 의해서 2.5mm의 판두께의 열연강대를 제조하였다. 이를 다시 냉간압연에 의해서 0.7mm의 냉연강판으로 하고, 그것을 연속소둔하는데 있어서 770℃에서 40초의 균열후, 냉각속도를 10℃에서 수냉(W.Q 약 1000℃/sec)으로 바꾸어 상온까지 냉각하였다. 얻어진 강판의 재질을 제1표에 표시한다.Steel having various components as shown in Table 1 was melted to prepare a hot rolled steel strip having a thickness of 2.5 mm by hot rolling. This was cold rolled again to a cold rolled steel sheet of 0.7 mm, and after continuous cracking at 770 ° C. for 40 seconds, the cooling rate was changed from 10 ° C. to water cooling (W.Q about 1000 ° C./sec) and cooled to room temperature. The material of the obtained steel plate is shown in a 1st table | surface.

[제1표][Table 1]

Figure kpo00003
Figure kpo00003

[제1표](계속)[Table 1] (continued)

Figure kpo00004
Figure kpo00004

Figure kpo00005
Figure kpo00005

종래의 연속 소둔방법에 있어서는 균열후의 냉각속도는 약 10℃/sec이다. 이와 같이 느린 냉각속도의 경우에는 상기표의 D처럼 합금성분(Mn)양이 많지않으면 항복점이 낮아서 항복비가 낮은 복합조직강판은 얻어지지 않는다. 또한, Mn양의 증가에 수반하여, 용접성의 열화를 수반하게 되고 가격이 상승된다고 하는 난점이 있다.In the conventional continuous annealing method, the cooling rate after cracking is about 10 ° C / sec. In the case of such a slow cooling rate, if the amount of the alloying component (Mn) is not large, as shown in Table D, the yield point is low, so that a composite steel sheet having a low yield ratio is not obtained. In addition, with the increase of the Mn amount, there is a difficulty in that the weldability is deteriorated and the price is increased.

이에 대하여 본 발명과 같이 냉각속도를 30˚-300℃/sec으로하면 A-C, E-I와 같이 합금첨가량을 적게 하더라도 복합조직이 얻어지며 더구나 그의 연성은 냉각속도가 본 발명의 범위에 있어서는 거의 변하지 않는다. 이에 대하여 냉각속도를 더 높게하여 350℃/sec(물분무), 1000℃(수중침지)로 하면 연성이 현저하게 열화하여 본 발명의 목적에 합치되지 않는다.On the contrary, when the cooling rate is 30 ° -300 ° C./sec as in the present invention, a composite structure is obtained even if the amount of alloy addition is reduced, such as A-C and E-I. Moreover, the ductility thereof is hardly changed in the scope of the present invention. On the other hand, when the cooling rate is increased to 350 ° C./sec (water spray) and 1000 ° C. (water immersion), the ductility deteriorates remarkably and does not meet the object of the present invention.

또, 제1(a)도, 제1(b)도, 제1(c)도에는 여러가지의 탄소량과 Mn량의 조합에 대하여 냉각속도와 복합조직화 경향의 관계를 나타낸 것이다.1 (a), 1 (b), and 1 (c) show the relationship between the cooling rate and the composite texture tendency for various combinations of carbon amount and Mn amount.

도면중의 숫자는 항복비(%)를 나타내며 항복비 50%에서 복합 조직화의 경계로 하고 있다.The numbers in the figure represent the yield ratio (%), and the 50% yield ratio is the boundary of complex organization.

도면에서 명백한바와 같이 냉각속도가 빨라짐에 따라서 합금원소량은 적더라도 복합조직화 한다는 것을 알 수 있다. 더구나, 제1표에 나타낸 바와 같이 본 발명의 냉각속도 30˚-300℃/sec의 범위에 있어서는 연성이 열화하는 나쁜상태는 발생하지 않는다.As can be seen from the figure, as the cooling rate increases, it can be seen that even if the amount of alloying elements is small, it is composited. Moreover, as shown in the first table, in the range of the cooling rate 30 ° -300 ° C / sec of the present invention, no bad state in which ductility deteriorates occurs.

Claims (1)

C 0.01-0.12%, Si 1.2%이하, Mn 1.0-1.8%, Sol.Al 0.01-0.10%, 잔부(殘部) Fe 및 불순물로서 된 강을 열연하고, 그 열연 강판을 냉연하고, 이어서 이 냉연강판을 730˚-800℃에서 20초-2분으로 균열(均熱)한 다음, 30˚-300℃/초의 냉각속도로 250℃이하의 온도까지 냉각하는 연속소둔 처리를 행하는 것을 특징으로 하는 가공성이 뛰어난 복합조직 고장력 냉연강판의 제조방법.C 0.01-0.12%, Si 1.2% or less, Mn 1.0-1.8%, Sol.Al 0.01-0.10%, hot rolled steel with remainder Fe and impurities, cold rolled hot rolled steel sheet, and then this cold rolled steel sheet The processability is characterized by performing a continuous annealing treatment in which the film is cracked at 730 DEG -800 DEG C for 20 seconds-2 minutes and then cooled to a temperature of 250 DEG C or lower at a cooling rate of 30 DEG -300 DEG C / sec. Excellent composite structure high tensile cold rolled steel sheet manufacturing method.
KR1019800004513A 1980-11-26 1980-11-26 Method of high tension cold steel sheet KR850000103B1 (en)

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