KR840009319A - Hardening or Crosslinking of Curable Halogen Rubber Mixtures - Google Patents

Hardening or Crosslinking of Curable Halogen Rubber Mixtures Download PDF

Info

Publication number
KR840009319A
KR840009319A KR1019840002937A KR840002937A KR840009319A KR 840009319 A KR840009319 A KR 840009319A KR 1019840002937 A KR1019840002937 A KR 1019840002937A KR 840002937 A KR840002937 A KR 840002937A KR 840009319 A KR840009319 A KR 840009319A
Authority
KR
South Korea
Prior art keywords
group
phenyl
same
halogen rubber
alkyl group
Prior art date
Application number
KR1019840002937A
Other languages
Korean (ko)
Other versions
KR910008802B1 (en
Inventor
볼프(외 2) 지그프리드
Original Assignee
게르하르트 노박, 로렌쯔크로이쯔비클러
데구사 아크티엔 게젤샤프트
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 게르하르트 노박, 로렌쯔크로이쯔비클러, 데구사 아크티엔 게젤샤프트 filed Critical 게르하르트 노박, 로렌쯔크로이쯔비클러
Publication of KR840009319A publication Critical patent/KR840009319A/en
Application granted granted Critical
Publication of KR910008802B1 publication Critical patent/KR910008802B1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L15/00—Compositions of rubber derivatives
    • C08L15/02—Rubber derivatives containing halogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C08K5/548—Silicon-containing compounds containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C08K5/5406—Silicon-containing compounds containing elements other than oxygen or nitrogen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

The invention is directed to vulcanizable halogen containing rubber mixtures which contain a silicate filler and a silicon containing isothiuronium compound and a process for vulcanizing or cross-linking these mixtures.

Description

경화성 할로겐 고무혼합물의 경화 또는 교차 결합방법Hardening or Crosslinking of Curable Halogen Rubber Mixtures

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (2)

할로겐 고무 100중량부를 기준으로 하여 0.1내지 5중량부의 양으로 일반식(I)의 이소티유로니움 화합물 적어도 하나를 함유함을 특징으로 하는, 적어도 하나의 할로겐 고무, 실리케이트 충진제 및 임의로 할로실란을 함유하는 경화성 고무 혼합물.At least one halogen rubber, silicate filler and optionally halosilane, characterized in that it contains at least one isothyuronium compound of formula (I) in an amount of 0.1 to 5 parts by weight based on 100 parts by weight of halogen rubber. Curable rubber mixture. 상기식에서,는 클로라이드, 브로마이드 또는 아이오다이드이고, m은 1 내지 6이며, R1은 C1-C5-알킬그룹, C5또는 C6-시클로알킬그룹 또는 페닐그룹이고, R은 C1-C5-알킬그룹, C5또는 C6-시클로알킬그룹, β-메톡시에틸그룹, 페닐 또는 벤질그룹이며, n은 0,1 또는 2이고, R3,R4,R5,R6은 서로 같거나 다르며 수소 또는 C1-C5-알킬그룹을 나타내거나, R3및 R5는 수소를 나타내고 R4및 R6는 서로 같거나 다르며 수소, C5-C6-시킬로알킬그룹, 페닐 또는 벤질 그룹을 나타내거나, R4와 R6는 함께 C2-C4-알킬렌체인을 나타낸다.In the above formula, Is chloride, bromide or iodide, m is 1 to 6, R 1 is C1-C5-alkyl group, C 5 or C 6 -cycloalkyl group or phenyl group, R is C 1 -C 5 -alkyl Group, C 5 or C 6 -cycloalkyl group, β-methoxyethyl group, phenyl or benzyl group, n is 0, 1 or 2, R 3 , R 4 , R 5 , R 6 are the same or different Hydrogen or C 1 -C 5 -alkyl group, or R 3 and R 5 represent hydrogen and R 4 and R 6 are the same or different and are hydrogen, C 5 -C 6 -haloalkyl group, phenyl or benzyl group Or R 4 and R 6 together represent C 2 -C 4 -alkylene chain. 혼합물이 성형된 후, 가열온도에 따라서 1 내지 200분에 걸쳐 100 내지 200°C온도에서 혼합물을 가열함으로써 제1항의 할로겐 고무 혼합물을 경화 또는 교차 결합시키는 방법에 있어서, 할로겐 고무 100중량부를 기준으로 하여 0.1 내지 5중량부의 양으로 일반식(I)의 이소티유로니움 화합물 적어도 하나를 할로겐 고무 혼합물에 혼합하고 동시에 분포시킴을 특징으로 하는 방법.In the method of curing or crosslinking the halogen rubber mixture of claim 1 by heating the mixture at a temperature of 100 to 200 ° C over 1 to 200 minutes depending on the heating temperature after the mixture is molded, based on 100 parts by weight of the halogen rubber Mixing at least one isothyuronium compound of formula (I) in a halogen rubber mixture and simultaneously distributing the same in an amount of 0.1 to 5 parts by weight. 상기식에서,는 클로라이드, 브로마이드 또는 아이오다이드이고, m은 1 내지 5이며, R1은 C1-C5-알킬그룹, C5-C8시클로알킬그룹 또는 페닐그룹이고, R은 C1-C5알킬그룹, C5-C8시클로알킬그룹, β-메톡시에틸그룹, 페닐그룹, 또는 벤질그룹이며, n은 0,1 또는 2이고, R3,R4,R5,R6는 서로 같거나 다르며 수소 또는 C1-C5알킬그룹을 나타내거나, R3및 R5는 수소를 나타내고 R4및 R6는 서로 같거나 다르며 수소, C5-C8-시클로알킬그룹, 페닐 또는 벤질그룹을 나타내거나, R4및 R6는 함께 C2-C|4알킬렌 체인을 나타낸다.In the above formula, Is chloride, bromide or iodide, m is 1 to 5, R 1 is C 1 -C 5 -alkyl group, C 5 -C 8 cycloalkyl group or phenyl group, R is C 1 -C 5 alkyl Group, C 5 -C 8 cycloalkyl group, β-methoxyethyl group, phenyl group, or benzyl group, n is 0, 1 or 2, and R 3 , R 4 , R 5 , R 6 are the same as each other Different and represent hydrogen or a C 1 -C 5 alkyl group, or R 3 and R 5 represent hydrogen and R 4 and R 6 are the same or different and represent hydrogen, a C 5 -C 8 -cycloalkyl group, phenyl or benzyl group R 4 and R 6 together represent C 2 -C | 4 alkylene chain. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019840002937A 1983-05-27 1984-05-26 Vulcanisable halogen rubber mixtures and a process for vulcanising or cross-linking KR910008802B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DEP3319251.0 1983-05-27
DE3319251A DE3319251C1 (en) 1983-05-27 1983-05-27 Vulcanizable halogen rubber compounds and methods for vulcanizing or crosslinking
DKP3319251.0 1983-05-27

Publications (2)

Publication Number Publication Date
KR840009319A true KR840009319A (en) 1984-12-26
KR910008802B1 KR910008802B1 (en) 1991-10-21

Family

ID=6200022

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019840002937A KR910008802B1 (en) 1983-05-27 1984-05-26 Vulcanisable halogen rubber mixtures and a process for vulcanising or cross-linking

Country Status (12)

Country Link
US (1) US4517335A (en)
EP (1) EP0126870B1 (en)
JP (1) JPS59232133A (en)
KR (1) KR910008802B1 (en)
AT (1) ATE27707T1 (en)
AU (1) AU571230B2 (en)
BR (1) BR8402467A (en)
CA (1) CA1252937A (en)
DE (2) DE3319251C1 (en)
ES (1) ES8502714A1 (en)
IN (1) IN162947B (en)
ZA (1) ZA841948B (en)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3821463A1 (en) * 1988-06-25 1989-12-28 Degussa VULCANIZABLE ORGANIC LYSYLYL FUNCTIONAL THINOCARES CONTAINING HALOGENIC RUBBER MIXTURES
US5162409B1 (en) * 1991-08-02 1997-08-26 Pirelli Armstrong Tire Corp Tire tread rubber composition
US6008272A (en) * 1995-05-22 1999-12-28 Cabot Corporation Elastomeric compounds incorporating silicon-treated carbon blacks
TW440594B (en) * 1995-05-22 2001-06-16 Cabot Corp Elastomeric compounds incorporating partially coated carbon blacks
US6323273B1 (en) 1995-05-22 2001-11-27 Cabot Corporation Elastomeric compounds incorporating silicon-treated carbon blacks
US6028137A (en) * 1995-05-22 2000-02-22 Cabot Corporation Elastomeric compounds incorporating silicon-treated carbon blacks
US5877238A (en) * 1995-05-22 1999-03-02 Cabot Corporation Elastomeric compounds incorporating silicon-treated carbon blacks and coupling agents
US5830930A (en) * 1995-05-22 1998-11-03 Cabot Corporation Elastomeric compounds incorporating silicon-treated carbon blacks
US5622557A (en) * 1995-05-22 1997-04-22 Cabot Corporation Mineral binders colored with silicon-containing carbon black
US5948835A (en) * 1995-09-15 1999-09-07 Cabot Corporation Silicon-treated carbon black/elastomer formulations and applications
US5747562A (en) * 1996-06-14 1998-05-05 Cabot Corporation Ink and coating compositions containing silicon-treated carbon black
CA2258189A1 (en) * 1996-06-14 1997-12-18 Cabot Corporation Modified carbon adsorbents and processes for adsorption using the same
US20020056686A1 (en) * 1996-06-14 2002-05-16 Agathagelos Kyrlidis Chromatography and other adsorptions using modified carbon adsorbents
US5919855A (en) * 1997-02-11 1999-07-06 Cabot Corporation Use of modified carbon black in gas-phase polymerizations
US6448322B1 (en) 1997-03-06 2002-09-10 Exxon Mobil Chemical Patents Inc. Stabilization of halogenated rubber
US6230773B1 (en) * 1998-03-17 2001-05-15 The Goodyear Tire & Rubber Company Tire with sidewall carcass reinforcement
DE19858706A1 (en) * 1998-12-18 2000-06-21 Pulver Kautschuk Union Gmbh Rubber powder (compounds) and process for their preparation
JP5503298B2 (en) * 2008-02-22 2014-05-28 株式会社ブリヂストン Organosilicon compound, and rubber composition, tire, primer composition, coating composition and adhesive using the same
JP5513010B2 (en) * 2009-05-20 2014-06-04 株式会社ブリヂストン Organosilicon compound, and rubber composition, tire, primer composition, coating composition and adhesive using the same

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3215718A (en) * 1961-11-24 1965-11-02 Dow Corning Sulfur-containing organosilicon compounds and method of preparation
US3637779A (en) * 1970-04-23 1972-01-25 Dow Corning Preparation of beta-silathiuronium salts
DE2536674C3 (en) * 1975-08-18 1979-09-27 Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler, 6000 Frankfurt Crosslinkable mixtures based on rubber, organosilanes and silicate fillers
DE2819638C3 (en) * 1978-05-05 1986-11-13 Degussa Ag, 6000 Frankfurt Vulcanizable halogen rubber compounds
SU740762A1 (en) * 1978-07-12 1980-06-15 Сумский Филиал Харьковского Ордена Ленина Политехнического Института Им. В.И.Ленина Method of preparing s-alkylisothiuronium chloride
DE3220712A1 (en) * 1982-06-02 1983-12-15 Degussa Ag, 6000 Frankfurt Water-containing solutions of silicon-containing isothiuronium compounds, process for the preparation and their use

Also Published As

Publication number Publication date
BR8402467A (en) 1985-04-02
AU2856884A (en) 1984-11-29
AU571230B2 (en) 1988-04-14
ZA841948B (en) 1984-11-28
IN162947B (en) 1988-07-23
DE3464141D1 (en) 1987-07-16
JPH0214370B2 (en) 1990-04-06
KR910008802B1 (en) 1991-10-21
EP0126870A1 (en) 1984-12-05
US4517335A (en) 1985-05-14
CA1252937A (en) 1989-04-18
DE3319251C1 (en) 1984-04-19
ATE27707T1 (en) 1987-06-15
EP0126870B1 (en) 1987-06-10
JPS59232133A (en) 1984-12-26
ES532361A0 (en) 1985-01-16
ES8502714A1 (en) 1985-01-16

Similar Documents

Publication Publication Date Title
KR840009319A (en) Hardening or Crosslinking of Curable Halogen Rubber Mixtures
GB1024234A (en) Improvements in or relating to siloxane elastomers
SE8005783L (en) SILAN / FILLING PREPARATION, PROCEDURE FOR PREPARING IT AND USING IT
ES538885A0 (en) A PROCEDURE FOR PREPARING VULCANIZABLE HOT ORGANOPOLYSILOXANIC ELASTOMER COMPOSITIONS
FR2572415B1 (en) ORGANOPOLYSILOXANE VULCANIZABLE COMPOSITION WITH AMBIENT TEMPERATURE IN SELF-ADHERENT ELASTOMER
KR930012949A (en) Vulcanizable Ethylene-Propylene-Conjugated Diene Copolymer (EPDM) -containing Rubber Composition
ATE143044T1 (en) PLATINUM CATALYST AND CURED ORGANOPOLYSILOXANE MATERIAL CONTAINING THIS PLATINUM CATALYST
ATE22572T1 (en) POLYSILOXANE MOLDING COMPOUNDS.
ES409786A1 (en) Rubber stabilized with phenylene-diamine-s-triazines
NO871194L (en) N, N [-SUBSTITUTED BIS (2,4-DIAMINO-S-TRIAZIN-6-YL) -TETRASULPHIDES AND THEIR DISPORPORATION PRODUCTS, PROCEDURES FOR THEIR PREPARATION AND THEIR USE IN VULCANIZABLE BASES.
JPS55149435A (en) Manufacturing of rubber elastic vibration damping material
FR2434701A1 (en) METHOD FOR FIXING SILICONE RUBBER ON THE SURFACE OF A SUPPORT
GB793594A (en) Vulcanisable compositions
GB911887A (en) Improvements in or relating to organopolysiloxane-based elastomers
GB1085015A (en) Improvements in or relating to silicone rubbers
KR860002530A (en) Uncured Rubber Composition
BR8207463A (en) VULCANIZABLE ELASTOMERIC COMPOSITION PROCESS FOR VULCANIZING AN ELASTOMERIC COMPOSITION; VULCANIZED ARTICLES
BR8505061A (en) COMPOSITES NOTES WITH THE PURPOSE OF IMPROVING THE PROPERTIES OF THE VULCANIZED
ATE802T1 (en) ROOM TEMPERATURE CURING SILICONE RUBBER COMPOUND.
JPH0569863B2 (en)

Legal Events

Date Code Title Description
A201 Request for examination
G160 Decision to publish patent application
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
LAPS Lapse due to unpaid annual fee