KR840006661A - 피라노-피라졸 유도체의 제조방법 - Google Patents
피라노-피라졸 유도체의 제조방법 Download PDFInfo
- Publication number
- KR840006661A KR840006661A KR1019830005567A KR830005567A KR840006661A KR 840006661 A KR840006661 A KR 840006661A KR 1019830005567 A KR1019830005567 A KR 1019830005567A KR 830005567 A KR830005567 A KR 830005567A KR 840006661 A KR840006661 A KR 840006661A
- Authority
- KR
- South Korea
- Prior art keywords
- alkyl
- carbon atoms
- cyano
- same
- halogen
- Prior art date
Links
- DKAHKEKMRSHQLY-UHFFFAOYSA-N pyrano[3,2-c]pyrazole Chemical class C1=COC2=CN=NC2=C1 DKAHKEKMRSHQLY-UHFFFAOYSA-N 0.000 title claims 4
- 125000000217 alkyl group Chemical group 0.000 claims 16
- 125000004432 carbon atom Chemical group C* 0.000 claims 10
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 9
- 125000001424 substituent group Chemical group 0.000 claims 8
- 229910052739 hydrogen Inorganic materials 0.000 claims 6
- 239000001257 hydrogen Substances 0.000 claims 6
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 6
- 125000004093 cyano group Chemical group *C#N 0.000 claims 5
- -1 cyano, nitro, methyl Chemical group 0.000 claims 5
- 229910052736 halogen Inorganic materials 0.000 claims 5
- 150000002367 halogens Chemical group 0.000 claims 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 4
- 125000004453 alkoxycarbonyl group Chemical group 0.000 claims 4
- 229910052801 chlorine Inorganic materials 0.000 claims 4
- 239000000460 chlorine Substances 0.000 claims 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 3
- 125000003545 alkoxy group Chemical group 0.000 claims 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 3
- 125000004663 dialkyl amino group Chemical group 0.000 claims 3
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 claims 3
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims 3
- 229910052760 oxygen Inorganic materials 0.000 claims 3
- 239000001301 oxygen Substances 0.000 claims 3
- 229910052717 sulfur Inorganic materials 0.000 claims 3
- 239000011593 sulfur Substances 0.000 claims 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 2
- 125000004414 alkyl thio group Chemical group 0.000 claims 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 2
- 229910052794 bromium Inorganic materials 0.000 claims 2
- 125000001589 carboacyl group Chemical group 0.000 claims 2
- 125000003754 ethoxycarbonyl group Chemical group C(=O)(OCC)* 0.000 claims 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 2
- 229910052731 fluorine Inorganic materials 0.000 claims 2
- 239000011737 fluorine Substances 0.000 claims 2
- 125000001188 haloalkyl group Chemical group 0.000 claims 2
- 125000005843 halogen group Chemical group 0.000 claims 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims 2
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 2
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims 2
- XBYRMPXUBGMOJC-UHFFFAOYSA-N 1,2-dihydropyrazol-3-one Chemical class OC=1C=CNN=1 XBYRMPXUBGMOJC-UHFFFAOYSA-N 0.000 claims 1
- SCVJRXQHFJXZFZ-KVQBGUIXSA-N 2-amino-9-[(2r,4s,5r)-4-hydroxy-5-(hydroxymethyl)oxolan-2-yl]-3h-purine-6-thione Chemical compound C1=2NC(N)=NC(=S)C=2N=CN1[C@H]1C[C@H](O)[C@@H](CO)O1 SCVJRXQHFJXZFZ-KVQBGUIXSA-N 0.000 claims 1
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 claims 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 1
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 claims 1
- 150000003934 aromatic aldehydes Chemical class 0.000 claims 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims 1
- 239000003054 catalyst Substances 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 239000003085 diluting agent Substances 0.000 claims 1
- 125000001153 fluoro group Chemical group F* 0.000 claims 1
- 125000001160 methoxycarbonyl group Chemical group [H]C([H])([H])OC(*)=O 0.000 claims 1
- 125000003884 phenylalkyl group Chemical group 0.000 claims 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
- C07D493/12—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains three hetero rings
- C07D493/14—Ortho-condensed systems
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D491/00—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00
- C07D491/12—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00 in which the condensed system contains three hetero rings
- C07D491/14—Ortho-condensed systems
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
- C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
- C07C45/70—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction with functional groups containing oxygen only in singly bound form
- C07C45/71—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction with functional groups containing oxygen only in singly bound form being hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D495/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms
- C07D495/12—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms in which the condensed system contains three hetero rings
- C07D495/14—Ortho-condensed systems
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dentistry (AREA)
- Zoology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Plant Pathology (AREA)
- Environmental Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (3)
- 일반식(Ⅱ)의 치환된 방향족 알데하이드를 희석제의 존재하에, 적절하게는 촉매의 존재하에 일반식(Ⅰ)의 피라졸리논과 반응시킴을 특징으로 하여 일반식(Ⅰ)의 피라노-피라졸 유도체를 제조하는 방법.상기식에서, R1은 수소, 알킬, 알카노일, 알콕시카보닐, 임의로 치환된 페닐 또는 임의로 치환된 페닐알킬을 나타내며 ; R2및 R3는 동일하거나 다를수 있고, 수소, 알킬 또는 임의로 치환된 페닐을 나타내고 ; R4는 시아노, 알킬, 알콕시카보닐 또는 임의로 치환된 페닐을 나타내며 ; Y는 산소, 황 또는 메틸렌 그룹을 나타내고 ; X는 할로겐, 알킬, 알콕시, 알킬티오, 할로게노알킬, 디알킬아미노, 니트로 또는 시아노를 나타내며 ; n은 0내지 3을 나타낸다.
- 제1항에 있어서, R1이 수소, 각각의 경우 알킬부분이 탄소수 4까지인 직쇄 또는 측쇄 알킬, 알카노일 또는 알콕시카보닐, 동일하거나 다른 치환기에 의해 임의로 일치환된 또는 다치환된 페닐 또는 페닐알킬(알킬부분이 탄소수 1 또는 2인)을 나타내는데, 이때 각각의 경우 페닐화상에서의 가능한 치환기는 할로겐, 시아노, 니트로, 탄소수 4까지의 알킬, 특정알킬 부분이 탄소수 1 또는 2인 알콕시, 알킬티오 및 디알킬아미노, 및 탄소수가 1 또는 2이고 5개 까지의 동일하거나 다른 할로겐원자를 갖는 할로게노알킬일수 있으며 ; R2및 R3가 동일하거나 다를수 있고, 수소, 탄소수 4까지의 직쇄 또는 측쇄 알킬, 또는 동거일하나 다른 치환기(예, 할로겐 및 탄소수 4까지의 알킬 그룹)에 의해 임의로 일치환된 또는 다치환된 페닐을 나타내고 ; R4가 각각의 경우 알킬부분이 탄소수 4까지인 직쇄 또는 측쇄 알킬 또는 알콕시카보닐, 시아노, 또는 동일하거나 다른 치환기(에, 할로겐 및 탄소수 4까지의 알킬 그룹)에 의해 임의로 일치환된 또는 다치환된 페닐을 나타내며 ; Y가 산소, 황 또는 메틸렌 그룹을 나타내고 ; X가 할로겐, 시아노, 니트로, 탄소수 4까지의 직쇄 또는 측쇄알킬, 특정 알킬 부분이 탄소수 1또는 2인 알콕시, 알킬티오 또는 디알킬아미노, 또는 탄소수가 1 또는 2이고 5개 까지의 동일하거나 다른 할로겐 원자를 갖는 할로게노알킬을 나타내며 ; n이 0내지 3을 나타내는 일반식(Ⅰ)의 피라노-피라졸 유도체를 제조하는 방법.
- R1이 수소, 메틸, 에틸 또는 n-또는 i-프로필, 아세틸, 메톡시카보닐 또는 에톡시카보닐, 또는 동일하거나 다른 치환기에 의해 임의로 일-, 이-또는 삼-치환된 페닐, 벤질 또는 펜에틸[특정페닐환상에서의 적절한 치환기는 불소, 염소, 브롬, 시아노, 니트로, 메틸, 메톡시, 메틸티오, 디메틸아미노) 및 트리플루오로메틸 일수 있다]을 나타내며; R2및 R3가 동일하거나 다를 수 있고, 수소, 메틸, 또는 동일하거나 다른 치환기(예, 염소 및 메틸 그룹)에 의해 임의로 일-, 이-또는 삼-치환된 페닐을 나타내며, R4가 메틸, 에틸, n-또는 i-프로필, t-부틸, 시아노, 메톡시카보닐, 에톡시카보닐, 또는 동일하거나 다른 치환기(예, 염소 및 메틸 그룹)에 의해 임의로 일-, 이-또는 삼-치환된 페닐을 나타내고 ; Y가 산소, 황 또는 메틸렌 그룹을 나타내며 ; X가 불소, 염소, 브롬, 시아노, 니트로, 메틸, 메톡시, 메틸티오, 디메틸아미노 또는 트리플루오로메틸을 나타내고 ; n이 0내지 2를 나타내는 일반식(Ⅰ)의 피라노-피라졸 유도체를 제조하는 방법.※참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19823243714 DE3243714A1 (de) | 1982-11-26 | 1982-11-26 | Pyrano-pyrazol-derivate |
| DEP3243714.5 | 1982-11-26 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR840006661A true KR840006661A (ko) | 1984-12-01 |
Family
ID=6179062
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019830005567A KR840006661A (ko) | 1982-11-26 | 1983-11-24 | 피라노-피라졸 유도체의 제조방법 |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US4515801A (ko) |
| EP (1) | EP0110243A1 (ko) |
| JP (1) | JPS59106490A (ko) |
| KR (1) | KR840006661A (ko) |
| AU (1) | AU2160083A (ko) |
| BR (1) | BR8306504A (ko) |
| CA (1) | CA1203240A (ko) |
| DD (1) | DD215460A5 (ko) |
| DE (1) | DE3243714A1 (ko) |
| DK (1) | DK541483A (ko) |
| ES (1) | ES527567A0 (ko) |
| GR (1) | GR79103B (ko) |
| IL (1) | IL70300A0 (ko) |
| MA (1) | MA19958A1 (ko) |
| NZ (1) | NZ206368A (ko) |
| PT (1) | PT77678B (ko) |
| TR (1) | TR21953A (ko) |
| ZA (1) | ZA838809B (ko) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4611001A (en) * | 1985-05-08 | 1986-09-09 | E. I. Du Pont De Nemours And Company | Antimycotic pyrazolotetrathiepins |
| WO2010140339A1 (ja) * | 2009-06-01 | 2010-12-09 | 武田薬品工業株式会社 | 複素環化合物 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2745305A1 (de) * | 1977-10-07 | 1979-04-19 | Bayer Ag | Insektizide und akarizide mittel |
| FR2521568A1 (fr) * | 1982-02-18 | 1983-08-19 | Roussel Uclaf | Nouveaux produits derives du squelette indeno /5,4-e/indazole, leur procede de preparation, leur application comme medicaments et produits intermediaires utilises pour leur preparation |
-
1982
- 1982-11-26 DE DE19823243714 patent/DE3243714A1/de not_active Withdrawn
-
1983
- 1983-11-08 US US06/550,076 patent/US4515801A/en not_active Expired - Fee Related
- 1983-11-16 PT PT77678A patent/PT77678B/pt unknown
- 1983-11-17 EP EP83111477A patent/EP0110243A1/de not_active Withdrawn
- 1983-11-22 JP JP58218840A patent/JPS59106490A/ja active Pending
- 1983-11-22 TR TR21953A patent/TR21953A/xx unknown
- 1983-11-23 AU AU21600/83A patent/AU2160083A/en not_active Abandoned
- 1983-11-23 NZ NZ206368A patent/NZ206368A/en unknown
- 1983-11-23 IL IL70300A patent/IL70300A0/xx unknown
- 1983-11-24 DD DD83257085A patent/DD215460A5/de unknown
- 1983-11-24 GR GR73063A patent/GR79103B/el unknown
- 1983-11-24 KR KR1019830005567A patent/KR840006661A/ko not_active Application Discontinuation
- 1983-11-24 CA CA000441912A patent/CA1203240A/en not_active Expired
- 1983-11-25 ZA ZA838809A patent/ZA838809B/xx unknown
- 1983-11-25 DK DK541483A patent/DK541483A/da not_active Application Discontinuation
- 1983-11-25 BR BR8306504A patent/BR8306504A/pt unknown
- 1983-11-25 ES ES527567A patent/ES527567A0/es active Granted
- 1983-11-25 MA MA20179A patent/MA19958A1/fr unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ES8406489A1 (es) | 1984-08-01 |
| BR8306504A (pt) | 1984-06-26 |
| PT77678B (en) | 1986-03-27 |
| US4515801A (en) | 1985-05-07 |
| DE3243714A1 (de) | 1984-05-30 |
| IL70300A0 (en) | 1984-02-29 |
| MA19958A1 (fr) | 1984-07-01 |
| ZA838809B (en) | 1984-07-25 |
| AU2160083A (en) | 1984-05-31 |
| DK541483D0 (da) | 1983-11-25 |
| TR21953A (tr) | 1985-12-05 |
| EP0110243A1 (de) | 1984-06-13 |
| NZ206368A (en) | 1985-08-30 |
| GR79103B (ko) | 1984-10-02 |
| JPS59106490A (ja) | 1984-06-20 |
| ES527567A0 (es) | 1984-08-01 |
| PT77678A (en) | 1983-12-01 |
| DD215460A5 (de) | 1984-11-14 |
| DK541483A (da) | 1984-05-27 |
| CA1203240A (en) | 1986-04-15 |
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