KR840006479A - Process for preparing azole compound - Google Patents

Process for preparing azole compound Download PDF

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Publication number
KR840006479A
KR840006479A KR1019830005093A KR830005093A KR840006479A KR 840006479 A KR840006479 A KR 840006479A KR 1019830005093 A KR1019830005093 A KR 1019830005093A KR 830005093 A KR830005093 A KR 830005093A KR 840006479 A KR840006479 A KR 840006479A
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KR
South Korea
Prior art keywords
compound
formula
unsubstituted
acid addition
metal
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KR1019830005093A
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Korean (ko)
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스쵸오브 프리츠
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원본미기재
산도즈 리미티드
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Publication of KR840006479A publication Critical patent/KR840006479A/en

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/12—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/69—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by addition to carbon-to-carbon double or triple bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/76—Ketones containing a keto group bound to a six-membered aromatic ring
    • C07C49/80—Ketones containing a keto group bound to a six-membered aromatic ring containing halogen
    • C07C49/813—Ketones containing a keto group bound to a six-membered aromatic ring containing halogen polycyclic
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
    • C07D233/56—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
    • C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
    • C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dentistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Epoxy Compounds (AREA)

Abstract

내용 없음No content

Description

아졸 화합물의 제조방법Process for preparing azole compound

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음As this is a public information case, the full text was not included.

Claims (2)

하기 일반식(Ⅱ)의 화합물을 2-아릴-2-R1-옥시탄 또는 이의 반응성 작용 유도체와 반응시키고, 필요에 따라 수득된 에탄올 화합물을 에테르화 또는 에스테르화시키고, 수득된 화합물을 유리형태, 산부가염형태, 알코올 레이트형태 또는 금속착화합물 형태 또는 에테르및 에스테르형태로 회수함을 특징으로 하여 유리형태 또는 산부가염, 알코올레이트, 금속착화합물, 에테르 및 에스테르 형태의 하기 일반식(Ⅰ)의 화합물을 제조하는 방법.The compound of formula II is reacted with 2-aryl-2-R 1 -oxytan or a reactive functional derivative thereof, etherification or esterification of the obtained ethanol compound is carried out, and the obtained compound is in free form. , The acid addition salt form, alcoholate form or metal complex compound or ether and ester form, characterized in that the free form or acid addition salt, alcoholate, metal complex, ether and ester form of the compound of formula (I) How to manufacture. 상기 일반식에서In the above general formula R1은-탄소원자에 직접적으로 또는 알킬렌을 통하여 결합된 할로겐화 시클로프로필이고 Y는 CH또는 N이고 Aryl은 비치환되거나 치환된 방향족 탄화수소(바람직하게는 페닐), 또는 비치환되거나 치환된 헤테로 방향적고리를 나타내고 M은 H, 금속 또는 트리알킬실릴그룹이다.R 1 is Halogenated cyclopropyl bonded directly or through an alkylene to a carbon atom, Y is CH or N and Aryl is an unsubstituted or substituted aromatic hydrocarbon (preferably phenyl), or an unsubstituted or substituted heteroaromatic ring And M is H, a metal or a trialkylsilyl group. 제1항에 있어서, 하기 일반식(Ⅱ)의 화합물을 하기 일반식(Ⅲ)의 화합물이나 이화합물의 반응성 작용 유도체와 반응시킨 후, 제조된 화합물을 유리형태 또는 산부가염, 알코올레이트 또는 금속 착화합물 형태로 회수함을 특징으로하여 유리형태 또는 산부가염, 알코올레이트 및 금속착화합물형태의 하기 일반식(Ⅰ')의 화합물을 제조하는 방법.A compound according to claim 1, wherein the compound of formula (II) is reacted with a compound of formula (III) or a reactive derivative of the compound, and then the prepared compound is in free form or in acid addition salts, alcoholates or metal complexes. A process for preparing a compound of formula (I ') in free form or in acid addition salts, alcoholates and metal complex compounds, characterized in that it is recovered in the form. 상기 일반식에서In the above general formula R1은-탄소원자에 직접적으로 또는 알킬렌 그룹을 통하여 결합된 할로겐화 시클로프로필이고 R2와 R3는 각각 H ; 할로겐, 비치환되거나 할로겐화된 C1-5알킬, C2-5알케닐, C2-5알키닐, C1-5알콕시 또는 C1-5알킬리오 ; 비치환되거나 치환된 페닐이나 페녹시 ; 또는 NO2이며 M은 H, 금속 또는 트리알실그룹이고 Y는 CH 또는 N이다.R 1 is Halogenated cyclopropyl bonded directly to a carbon atom or through an alkylene group and R 2 and R 3 are each H; Halogen, unsubstituted or halogenated C 1-5 alkyl, C 2-5 alkenyl, C 2-5 alkynyl, C 1-5 alkoxy or C 1-5 alkylrio; Unsubstituted or substituted phenyl or phenoxy; Or NO 2 , M is H, a metal or triacyl group and Y is CH or N. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019830005093A 1982-10-28 1983-10-27 Process for preparing azole compound KR840006479A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH630082 1982-10-28
CH6300 1982-10-28

Publications (1)

Publication Number Publication Date
KR840006479A true KR840006479A (en) 1984-11-30

Family

ID=4307381

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019830005093A KR840006479A (en) 1982-10-28 1983-10-27 Process for preparing azole compound

Country Status (22)

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JP (1) JPS5998061A (en)
KR (1) KR840006479A (en)
AU (1) AU2060283A (en)
BE (1) BE898070A (en)
BR (1) BR8305935A (en)
CS (1) CS243477B2 (en)
DE (1) DE3337937A1 (en)
DK (1) DK493583A (en)
ES (1) ES8504733A1 (en)
FI (1) FI833859A (en)
FR (1) FR2535321B1 (en)
GB (1) GB2129000B (en)
GR (1) GR79636B (en)
IL (1) IL70058A0 (en)
IT (1) IT1172351B (en)
LU (1) LU85066A1 (en)
NL (1) NL8303651A (en)
PL (1) PL244326A1 (en)
PT (1) PT77558B (en)
SE (1) SE8305878L (en)
SU (1) SU1222193A3 (en)
ZA (1) ZA838076B (en)

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NL8402548A (en) * 1983-09-01 1985-04-01 Sandoz Ag NEW AZOLE CONNECTIONS.
GB8414519D0 (en) * 1984-06-07 1984-07-11 Pfizer Ltd Triazole antifungal agents
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DE3530799A1 (en) * 1985-08-29 1987-03-05 Hoechst Ag AZOLYL-CYCLOPROPYL-ETHANOL DERIVATIVES, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE
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DE3608792A1 (en) * 1986-03-15 1987-09-24 Hoechst Ag 1,1-DISUBSTITUTED CYCLOPROPANE DERIVATIVES, METHOD FOR THEIR PRODUCTION AND THEIR USE
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DE3813129A1 (en) * 1987-07-01 1989-01-12 Bayer Ag HYDROXYETHYL AZOLYL DERIVATIVES
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DE3732385A1 (en) * 1987-09-25 1989-04-06 Bayer Ag HYDROXYALKYLCYCLOPROPYL1-1,2,4-TRIAZOLYL OR IMIDAZOLYL DERIVATIVES AND THEIR USE AS ANTIMYCOTIC AGENTS
DE3824434A1 (en) * 1988-07-19 1990-01-25 Bayer Ag, 51373 Leverkusen SUBSTITUTED 1-ARYL-3-CYCLOALKYL-4- (1,2,4-TRIAZOL-1-YL) -BUT-1-IN-3-OLE, METHOD AND SUBSTITUTED 2-ARYLETHINYL-2-CYCLOALKYL-OXIRANE AND CYCLOALK ARYLETHINYLKETONE AS INTERMEDIATE PRODUCTS FOR THEIR PRODUCTION, AND THEIR USE IN FUNGICIDES
DE3824435A1 (en) * 1988-07-19 1990-01-25 Bayer Ag, 51373 Leverkusen SUBSTITUTED 2,2-DIHALOGENCYCLOPROPYL-HYDROXYETHYL-1,2,4-TRIAZOLES, METHODS AND 2,2-DIHALOGENCYCLOPROPYL-OXIRANES, CYCLOPROPYLKETONE AND HALOGENMETHYL-CYCLETELLUNGPRODUCTED OXYGENOZYLENOXIDE
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CN102803230A (en) 2009-06-12 2012-11-28 巴斯夫欧洲公司 Antifungal 1,2,4-triazolyl derivatives having a 5-sulfur substituent
US20120238762A1 (en) 2009-12-08 2012-09-20 Kureha Corporation Azole derivatives and methods for producing the same, intermediate compounds for the derivatives and methods for producing the same, and agro-horticultural agents and industrial material protecting agents containing the derivatives
EA201201288A1 (en) 2010-03-16 2013-04-30 Басф Се METHOD OF APPLICATION OF REAGENTS OF GRINIAR
EP2621922A1 (en) 2010-09-30 2013-08-07 Basf Se A process for the synthesis of thio-triazolo-group containing compounds
WO2012130823A1 (en) 2011-03-30 2012-10-04 Basf Se Suspension concentrates
WO2012146598A1 (en) 2011-04-28 2012-11-01 Basf Se Process for the preparation of 2-substituted 4-amino-2,4-dihydro-[1,2,4]triazole-3-thiones
WO2012146535A1 (en) 2011-04-28 2012-11-01 Basf Se Process for the preparation of 2-substituted 2,4-dihydro-[1,2,4]triazole-3-thiones
WO2012165499A1 (en) 2011-05-31 2012-12-06 株式会社クレハ Triazole compound and use thereof
WO2012165498A1 (en) * 2011-06-03 2012-12-06 株式会社クレハ Triazole compound and use thereof
BR112013030438A2 (en) 2011-06-07 2016-08-16 Kureha Corp agricultural or horticultural chemical agent, composition for controlling plant diseases, method for controlling plant diseases, and product for controlling plant diseases
WO2014095381A1 (en) 2012-12-19 2014-06-26 Basf Se Fungicidal imidazolyl and triazolyl compounds
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AU2015261166A1 (en) * 2014-05-13 2016-12-01 Basf Se Substituted [1,2,4]triazole and imidazole compounds as fungicides
CN109111402B (en) * 2018-10-30 2021-10-15 徐州工业职业技术学院 Preparation method of imidazole ethanol
CN112471168A (en) * 2020-12-17 2021-03-12 浙江禾本科技股份有限公司 Bactericide composition containing triphenyltin acetate and cyproconazole and application thereof

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CH647513A5 (en) * 1979-11-13 1985-01-31 Sandoz Ag TRIAZOLE DERIVATIVES, THEIR PRODUCTION AND USE.

Also Published As

Publication number Publication date
FR2535321B1 (en) 1985-10-18
ES526780A0 (en) 1985-05-01
DE3337937A1 (en) 1984-05-03
SU1222193A3 (en) 1986-03-30
GR79636B (en) 1984-10-31
LU85066A1 (en) 1984-05-10
SE8305878L (en) 1984-04-29
GB2129000B (en) 1986-03-19
DK493583A (en) 1984-04-29
GB2129000A (en) 1984-05-10
FI833859A0 (en) 1983-10-21
ZA838076B (en) 1985-06-26
SE8305878D0 (en) 1983-10-26
GB8328492D0 (en) 1983-11-23
IT1172351B (en) 1987-06-18
BE898070A (en) 1984-04-25
CS786283A2 (en) 1985-08-15
FR2535321A1 (en) 1984-05-04
IT8349185A0 (en) 1983-10-20
JPS5998061A (en) 1984-06-06
FI833859A (en) 1984-04-29
CS243477B2 (en) 1986-06-12
PT77558B (en) 1986-04-16
ES8504733A1 (en) 1985-05-01
PL244326A1 (en) 1984-09-24
DK493583D0 (en) 1983-10-27
NL8303651A (en) 1984-05-16
AU2060283A (en) 1984-05-03
IL70058A0 (en) 1984-01-31
BR8305935A (en) 1984-06-05
PT77558A (en) 1983-11-01

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