KR840005842A - 탄소질 고체원료의 액화 및/또는 기화방법 - Google Patents

탄소질 고체원료의 액화 및/또는 기화방법 Download PDF

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KR840005842A
KR840005842A KR1019830003288A KR830003288A KR840005842A KR 840005842 A KR840005842 A KR 840005842A KR 1019830003288 A KR1019830003288 A KR 1019830003288A KR 830003288 A KR830003288 A KR 830003288A KR 840005842 A KR840005842 A KR 840005842A
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alkali metal
aqueous solution
metal component
solution prepared
particles containing
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와이. 송 웬
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존 에이치. 윌슨. 주니어
엑손 리써치 앤드 엔지니어링 컴페니
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Publication of KR840005842A publication Critical patent/KR840005842A/ko

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G19/00—Refining hydrocarbon oils in the absence of hydrogen, by alkaline treatment
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/92—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/08—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal with moving catalysts
    • C10G1/086—Characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/54—Gasification of granular or pulverulent fuels by the Winkler technique, i.e. by fluidisation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/54—Gasification of granular or pulverulent fuels by the Winkler technique, i.e. by fluidisation
    • C10J3/56—Apparatus; Plants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/82—Gas withdrawal means
    • C10J3/84—Gas withdrawal means with means for removing dust or tar from the gas
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/093—Coal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0943—Coke
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0946—Waste, e.g. MSW, tires, glass, tar sand, peat, paper, lignite, oil shale
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0959—Oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0966—Hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0973—Water
    • C10J2300/0976—Water as steam
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0983—Additives
    • C10J2300/0986—Catalysts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1807—Recycle loops, e.g. gas, solids, heating medium, water
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

내용 없음

Description

탄소질 고체원료의 액화 및/또는 기화방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
첨부도면은 알카리금속 성분의 촉매가 본 발명에 따라 회수되는 촉매 석탄기화 공정의 유통도임.

Claims (11)

  1. 알카리금속 잔류물을 함유하는 입자가 생성되고, 알칼리금속 함유 촉매 존재하에 고체 탄소질 원료를 액체 및/또는 기체로 전환하는 방법에 있어서,
    (a) 상기 입자로부터 수용성 알카리금속 성분을 제거하므로써 알카리금속 성분이 풍부한 수용액을 만들기 위해 알카리금속 잔류물을 함유하는 입자를물 또는 알카리 수용액과 접촉시킨후;
    (b) 용액내에 함유된 규소 성분을 침전하기 위해서 알카리 금속 성분이 풍부한 상기 수용액을 이산화탄소와 접촉한 다음;
    (c) 상기 수용액이 농축될때 수용액중의 잔류 규소 성분이 침전되지 않도록 하기 위해 단계(d)에서 생성된 수용액의 충분히 높게 증가시키고;
    (d) 알카리금속 성분이 풍부한 수용액을 만들기 위해 단계(c)에서 제조된 수용액을 농축하고;
    (e) 상기 알카리금속 함유 촉매를 함유하는 알카리금속 성분중 적어도 일부로서 단계(b)에서 제조된 수용액의 알카리금속 성분을 상기 전환공정에 사용하는 것을 특징으로 하는 방법.
  2. 제1항에 있어서 전환 방법이 기화공정인 것을 특징으로 하는 방법.
  3. 제1항 또는 2항에 있어서, 상기 탄소질 고체원료가 석탄인 것을 특징으로 하는 방법.
  4. 제1항내지 3항중 어느 하나에 있어서, 상기 알카리금속 잔류물을 함유하는 입자가 다단계 역류 추출장치에서 물 또는 수용액과 접촉되는 것을 특징으로 하는 방법.
  5. 제1항내지 4항중 어느 하나에 있어서, 단계(b)에서 제조된 수용액의 pH가 약 12.5내지 15.0으로 증가되는 것을 특징으로 하는 방법.
  6. 제1항 내지 5항중 어느 하나에 있어서, 단계(a)에서 제조되고 알카리금속 성분이 풍부한 상기 수용액이 이산화탄소와 접촉되는 동안 상기 알카리금속 성분을 함유하는 입자와도 접촉되는 것을 특징으로 하는 방법.
  7. 제1항내지 6항중 어느 하나에 있어서, 단계(a)에서 제조되고 알카리금속 성분이 풍부한 상기 수용액이 이산화탄소와 접촉되기 전에 상기 알카리금속 잔류물을 함유하는 입자로부터 분리되는 것을 특징으로 하는 방법.
  8. 제1항내지 7항중 어느 하나에 있어서, 상기 입자가 탄소질 물질, 회분 및 알카리금속 잔류물을 함유하는 탄화물 입자로 구성된 것을 특징으로 하는 방법.
  9. 제1항내지 8항중 어느 하나에 있어서, 상기 알카리금속 함유 촉매가 칼륨 함유 촉매인 것을 특징으로 하는 방법.
  10. 제1항내지 9항중 어느 하나에 있어서, 단계(b)에서 제조된 수용액의 pH가 알카리금속 수산화물을 첨가하므로써 증가되는 것을 특징으로 하는 방법.
  11. 제10항에 있어서, 단계(b)에서 제조된 수용액의 pH가 수산화 칼륨을 첨가하므로써 증가되는 것을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019830003288A 1982-07-19 1983-07-18 탄소질 고체원료의 액화 및/또는 기화방법 KR840005842A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP82303764.3 1982-07-19
EP82303764A EP0099429B1 (en) 1982-07-19 1982-07-19 The recovery of alkali metal constituents from catalytic coal conversion residues

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KR840005842A true KR840005842A (ko) 1984-11-19

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KR1019830003288A KR840005842A (ko) 1982-07-19 1983-07-18 탄소질 고체원료의 액화 및/또는 기화방법

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EP (1) EP0099429B1 (ko)
JP (1) JPS5947295A (ko)
KR (1) KR840005842A (ko)
AU (1) AU1695583A (ko)
BR (1) BR8303837A (ko)
DE (1) DE3273344D1 (ko)
IT (1) IT1194324B (ko)
ZA (1) ZA835238B (ko)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3326634A1 (de) * 1983-07-23 1985-02-07 Metallgesellschaft Ag, 6000 Frankfurt Verfahren zum betreiben einer anlage zum vergasen fester brennstoffe
CN108479742B (zh) * 2018-03-19 2021-02-23 新奥科技发展有限公司 一种煤催化气化灰渣中催化剂的回收方法以及采用该回收方法回收获得的催化剂及其应用

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4057512A (en) * 1975-09-29 1977-11-08 Exxon Research & Engineering Co. Alkali metal catalyst recovery system
FR2378086A1 (fr) * 1977-01-24 1978-08-18 Exxon Research Engineering Co Procede de recuperation des metaux alcalins contenus dans les catalyseurs de transformation du charbon
US4193771A (en) * 1978-05-08 1980-03-18 Exxon Research & Engineering Co. Alkali metal recovery from carbonaceous material conversion process

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JPS5947295A (ja) 1984-03-16
ZA835238B (en) 1985-02-27
IT8322113A0 (it) 1983-07-18
DE3273344D1 (en) 1986-10-23
AU1695583A (en) 1984-01-26
IT1194324B (it) 1988-09-14
BR8303837A (pt) 1984-02-21
EP0099429B1 (en) 1986-09-17
IT8322113A1 (it) 1985-01-18
EP0099429A1 (en) 1984-02-01

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