KR840005073A - 나프탈렌아민 유도체의 제조방법 - Google Patents

나프탈렌아민 유도체의 제조방법 Download PDF

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Publication number
KR840005073A
KR840005073A KR1019830001867A KR830001867A KR840005073A KR 840005073 A KR840005073 A KR 840005073A KR 1019830001867 A KR1019830001867 A KR 1019830001867A KR 830001867 A KR830001867 A KR 830001867A KR 840005073 A KR840005073 A KR 840005073A
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South Korea
Prior art keywords
phenyl
naphthalenamine
halogen
dinitro
trifluoromethyl
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KR1019830001867A
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English (en)
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KR860001567B1 (ko
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제임스 클링톤 알버트 (외 1)
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아더 알·웨일
일라이 릴리 앤드 캄파니
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Priority claimed from US06/374,802 external-priority patent/US4423065A/en
Application filed by 아더 알·웨일, 일라이 릴리 앤드 캄파니 filed Critical 아더 알·웨일
Publication of KR840005073A publication Critical patent/KR840005073A/ko
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Publication of KR860001567B1 publication Critical patent/KR860001567B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/04—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups
    • C07C209/14—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups
    • C07C209/16—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups with formation of amino groups bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds containing nitrogen-to-oxygen bonds
    • A01N33/18—Nitro compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00—Compounds containing amino groups bound to a carbon skeleton
    • C07C211/01—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms
    • C07C211/26—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of an unsaturated carbon skeleton containing at least one six-membered aromatic ring
    • C07C211/30—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of an unsaturated carbon skeleton containing at least one six-membered aromatic ring the six-membered aromatic ring being part of a condensed ring system formed by two rings

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Agronomy & Crop Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)

Abstract

내용 없음

Description

나프탈렌아민 유도체의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (7)

  1. 다음 일반식(Ⅵ)의 나프틸 유도체를 염기의 존재하에서 다음 일반식(Ⅶ)의 페닐유도체와 반응시키고, 임의로 생성된 n이 0인 일반식(I)의 생성물을 할로겐화하여 n이 1인 일반식(I)의 나프탈렌아민을 형성시킴을 특징으로 하여, 다음 일반식(I)의 나프탈렌아민 유도체를 제조하는 방법.
    상기식에서 R1은 C1내지 C4알킬이며:R2는 할로겐, 페닐, 니트로, 시아노, C1내지 C4플루오로알킬, C1내지 C4플루오로알콕시 또는 C1내지 C4-플루오로알킬티오이고;R3는 할로겐이며;R4는 수소 또는 할로겐이고;m은 0,1 또는 2이며; n은 0, 1 또는 1이고; X 및 Y중의 하나는 NH2이며, 다른하나는 이탈그룹이고; 단, R2와 디니트아닐린 부위는 둘다 동일한 페닐환상의 치환체이다.
  2. 제1항에 있어서, R2가 페닐, 니트로 또는 시아노인 일반식(I)의 나프탈렌아민 유도체를 제조하는 방법.
  3. 제1항에 있어서, 다음 일반식(Ⅲ)의 나프탈렌아민을 제조하는 방법.
    상기식에서 R1은 C1내지 C4알킬이며;R2는 할로겐, C1내지 C4플루오로알킬, C1내지 C4플루오로알콜시 또는 C1내지 C4플루오로알킬티오이고;R3는 할로겐이며;R4는 수소 또는 할로겐이고; m은 0, 1 또는 2이다.
  4. 제1항에 있어서, R2가 할로겐, C1내지 C4플루오로알킬, C1내지 C4플루오로알콕시 또는 C1내지 C4플루오로알킬티오이며; 단, R2와 디니트로아닐린 부위가 동일한 페닐환상에 있고 나프탈렌계의 1-및 4-위치에 동시에 결합되지 않는 일반식(I)의 나프탈렌아민을 제조하는 방법.
  5. 제1항에 있어서, 다음 일반식(Ⅴ)의 나프탈렌아민을 제조하는 방법.
    상기식에서 R1은 C1내지 C4알킬이며;R2는 할로겐, C1내지 C4플루오로알킬, C1내지 C4플루오로알콕시 또는 C1내지 C4플루오로알킬티오이고;R3는 할로겐이며;R4는 수소 또는 할로겐이고; m은 0, 1 또는 2이며, n은 0 또는 1이고; 단, R3치환체가 존재하는 경우에 이것은 2-위치가 아닌 위치에 존재한다.
  6. 제1항 내지 제5항중의 어느 하나에 있어서, 생성된 나프탈렌아민이 m이 0이며 R4가 수소인 화합물인 방법.
  7. 제1항에 있어서
    1-니트로-N-(2,4-디니트로-6-(트리플루오로메틸)-페닐)-1-나프탈렌아민;
    4-클로로-N-(2,4-디니트로-6-(트리플루오로메틸)-페닐)-1-나프탈렌아민;
    2-브로모-4-클로로-N-(2,4-디니트로-6-(트리플루오로메틸)-페닐)-1-나프탈렌아민;
    4-브로모-N-(2,4-디니트로-6-(트리플루오로메틸)-페닐)-1-나프탈렌아민;
    4-페닐-N-(2,4-디니트로-6-(트리플루오로메틸)-페닐)-1-나프탈렌아민;
    4-니트로-N-(2,4-디니트로-6-(트리플루오로메틸)-페닐)-1-나프탈렌아민;
    4-시아노-N-(2,4-디니트로-6-(트리플루오로메틸)-페닐)-1-나프탈렌아민; 및
    2,4-디브로모-N-(2,4-디니트로-6-(트리플루오로메틸)-페닐)-1-나프탈렌아민중에서 선택된 일반식(I)의 나프탈렌아민을 제조하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019830001867A 1982-05-04 1983-05-02 나프탈렌아민 유도체의 제조방법 KR860001567B1 (ko)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US37480182A 1982-05-04 1982-05-04
US374,801 1982-05-04
US374802 1982-05-04
US374,802 1982-05-04
US06/374,802 US4423065A (en) 1982-05-04 1982-05-04 Naphthalenamine insecticides
US374801 1982-05-04

Publications (2)

Publication Number Publication Date
KR840005073A true KR840005073A (ko) 1984-11-03
KR860001567B1 KR860001567B1 (ko) 1986-10-08

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EP (1) EP0102680B1 (ko)
KR (1) KR860001567B1 (ko)
AU (1) AU557503B2 (ko)
BR (1) BR8302284A (ko)
CA (1) CA1198123A (ko)
CS (1) CS311083A2 (ko)
DD (1) DD210255A5 (ko)
DE (1) DE3362389D1 (ko)
DK (1) DK196783A (ko)
ES (1) ES522004A0 (ko)
FI (1) FI831500L (ko)
GB (1) GB2119380B (ko)
GR (1) GR77460B (ko)
HU (1) HU190627B (ko)
IE (1) IE55547B1 (ko)
IL (1) IL68500A (ko)
NZ (1) NZ204087A (ko)
PH (1) PH20554A (ko)
PL (1) PL241756A1 (ko)
PT (1) PT76623B (ko)
SU (1) SU1346041A3 (ko)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
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EP2712862A1 (en) 2012-09-28 2014-04-02 Splicos New anti-invasive compounds

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* Cited by examiner, † Cited by third party
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DE2708440A1 (de) * 1977-02-26 1978-08-31 Bayer Ag 1-arylamino-2,4-dinitronaphthaline, verfahren zu ihrer herstellung sowie ihre verwendung als schaedlingsbekaempfungsmittel

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Publication number Publication date
KR860001567B1 (ko) 1986-10-08
IE55547B1 (en) 1990-10-24
GR77460B (ko) 1984-09-24
DE3362389D1 (en) 1986-04-10
DK196783A (da) 1983-11-05
CA1198123A (en) 1985-12-17
EP0102680A1 (en) 1984-03-14
ES8406061A1 (es) 1984-07-01
ES522004A0 (es) 1984-07-01
EP0102680B1 (en) 1986-03-05
IE831017L (en) 1983-11-04
AU557503B2 (en) 1986-12-24
SU1346041A3 (ru) 1987-10-15
BR8302284A (pt) 1984-01-03
FI831500L (fi) 1983-11-05
PT76623B (en) 1986-02-26
IL68500A0 (en) 1983-07-31
DD210255A5 (de) 1984-06-06
HU190627B (en) 1986-09-29
PT76623A (en) 1983-06-01
CS311083A2 (en) 1985-07-16
FI831500A0 (fi) 1983-05-02
PL241756A1 (en) 1984-08-27
IL68500A (en) 1986-07-31
DK196783D0 (da) 1983-05-03
PH20554A (en) 1987-02-09
GB2119380B (en) 1986-07-02
GB8312033D0 (en) 1983-06-08
GB2119380A (en) 1983-11-16
NZ204087A (en) 1985-05-31
AU1414383A (en) 1983-11-10

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