KR830010133A - 고니트릴 공중합체 라텍스 코팅 조성물의 제조방법 - Google Patents

고니트릴 공중합체 라텍스 코팅 조성물의 제조방법 Download PDF

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Publication number
KR830010133A
KR830010133A KR1019820002290A KR820002290A KR830010133A KR 830010133 A KR830010133 A KR 830010133A KR 1019820002290 A KR1019820002290 A KR 1019820002290A KR 820002290 A KR820002290 A KR 820002290A KR 830010133 A KR830010133 A KR 830010133A
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South Korea
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composition
ester
vinyl ether
weight
group
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KR1019820002290A
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English (en)
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케일 아담스 리챠드
죤 웨이 살라 스테븐
Original Assignee
라리 윌리암 에반스
더 스탠다드 오일 캄파니
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Publication of KR830010133A publication Critical patent/KR830010133A/ko

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/04—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to rubbers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/18—Homopolymers or copolymers of nitriles
    • C09D133/20—Homopolymers or copolymers of acrylonitrile
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F226/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
    • C08F226/06—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a heterocyclic ring containing nitrogen
    • C08F226/10—N-Vinyl-pyrrolidone
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C08F279/04—Vinyl aromatic monomers and nitriles as the only monomers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D139/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Coating compositions based on derivatives of such polymers
    • C09D139/04—Homopolymers or copolymers of monomers containing heterocyclic rings having nitrogen as ring member
    • C09D139/06—Homopolymers or copolymers of N-vinyl-pyrrolidones
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/003—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Paints Or Removers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

내용 없음

Description

고니트릴 공중합체 라텍스 코팅 조성물의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (14)

  1. 0.75dl/gm보다 더 큰 고유점도를 갖는 폴리비닐 피롤리돈을 포함하는 수용해성 중간체와, 임의로 디엔고무의 존재하에 주성분의 단일 불포화 니트릴과 이들과 공중합할 수 있는 미량성분의 하나이상의 모노 비닐 단량체 성분의 중합에 의해 제조된 라텍스와로 구성된 코팅 조성물.
  2. 제1항에 있어서, 라텍스가 부타디엔과 이소프렌 또한 임으로 구조식을 갖는 니트릴, 스틸렌, 구조식을 갖는 에스테르 단량체로 구성되는 그룹으로부터 선택된 코모노마로 이루어지는 그룹에서 선택한 공액디엔 단량체의 고무상 중합체(여기에서 고무성 중합체는 50내지 100중량%의 중합된 공액디엔과 0 내지 50중량%의 코모노마를 함유) 0 내지 40중량의 존재하에 (A) 구조식을 갖는 하나이상의 니프릴의 60 내지 90중량%와; (B)구조식을 갖는 에스테르, 구조식을 갖는 알파올레핀, 비닐에테르(여기서 비닐에테르는 메틸비닐에테르, 에틸비닐에테르, 프로핀비닐에테르, 부틸비닐에테르로 구성되어 있는 그룹에서 선택한 것) 비닐아세테이트, 스틸렌 및 인덴등으로 구성되어 있는 그룹에서 선택한 하나 이상의 원(員)의 (B)와 (A)를 합친 10내지 40중량%와를 포함하는 상기 조성물. (상기 구조식에서 R은 수소, 탄소수1 내지 4의 저급알킬기 또한 할로겐이며, R1은 수소,탄소수 1내지 30의 알킬기 또는 할로겐이며, R2는 탄소수 1내지 6의 알킬기이며, R3및 R4는 탄소수 1 내지 7의 알킬기 이다)
  3. 제2항에 있어서 (A)가 아크릴로니트릴인 상기 조성물.
  4. 제2항에 있어서 (B)가 메틸아크릴레이트인 상기 조성물.
  5. 제2항에 있어서 70% 이상의 (A)와 30% 이하의 (B)을 포함하는 상기 조성물.
  6. 제1항에 있어서 라텍스가 5내지 15부의 (C)를 포함하는 상기 조성물.
  7. 제1항에 있어서 폴리비닐 피롤리돈 중합체가 최소한 5%의 폴리비닐피롤리돈을 포함하는 상기 조성물.
  8. 제7항에 있어서 중합체가 최소한 70%의 폴리비닐 피롤리돈을 포함하는 상기 조성물.
  9. 제1항에 있어서 폴리비닐 피롤리돈 중합체가 비닐피롤리돈과 하나 이상의 알킬 아크릴레이트의 공중 합체인 상기 조성물.
  10. 제1항에 있어서 코팅이 2중량% 이하의 에스테르를 포함하는 상기 조성물.
  11. 제1항에 있어서 코팅이 1중량% 이하의 에스테르를 포함하는 상기 조성물.
  12. 제1항에 있어서 에스테르가 1.0dl/gm보다 더큰 고유점도를 갖는 상기 조성물.
  13. 제1항에 있어서, 에스테르가 2.0dl/gm보다 더큰 고유점도를 갖는 상기 조성물.
  14. 임으로 디엔고무 존재하에 주성분의 단일 불포화 니트릴과 이들과 공중합할 수 있는 미량성분의 하나이상의 모노비닐 단량체 성분의 중합에 의해 생성된 라텍스와, 0.75dl/gm보다 더큰 고유 점도를 갖는 폴리비닐피롤리돈을 포함하는 수용해성 중합체와의 혼합물로 구성된 코팅의 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019820002290A 1981-05-26 1982-05-24 고니트릴 공중합체 라텍스 코팅 조성물의 제조방법 KR830010133A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US266.778 1981-05-26
US06/266,778 US4374948A (en) 1981-05-26 1981-05-26 High nitrile copolymer latex coating

Publications (1)

Publication Number Publication Date
KR830010133A true KR830010133A (ko) 1983-12-26

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KR1019820002290A KR830010133A (ko) 1981-05-26 1982-05-24 고니트릴 공중합체 라텍스 코팅 조성물의 제조방법

Country Status (6)

Country Link
US (1) US4374948A (ko)
EP (1) EP0068620B1 (ko)
JP (1) JPS57195770A (ko)
KR (1) KR830010133A (ko)
CA (1) CA1189994A (ko)
DE (1) DE3263647D1 (ko)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5002975A (en) * 1985-01-07 1991-03-26 The Standard Oil Company Photocurable coating compositions
US4828756A (en) * 1986-11-21 1989-05-09 The Standard Oil Company Electrically conductive composites of polyacetylene and high-nitrile resins and method thereof
US4859521A (en) * 1987-07-16 1989-08-22 Century Adhesives Corp. Cold-seal adhesives and comestible packages formed therewith
US4810745A (en) * 1987-07-16 1989-03-07 Century Adhesives Corp. Cold-seal adhesives and comestible packages formed therewith
US5489201A (en) * 1993-04-15 1996-02-06 Cullom Machine Tool & Die, Inc. Plastic tile corrugator and mold blocks
EP1905787B1 (en) * 2006-09-27 2011-05-18 FUJIFILM Corporation Lithographic printing plate precursor using a polymer latex of high acrylonitrile content
US8106120B2 (en) * 2007-12-21 2012-01-31 The Euclid Chemical Company Easily removable concrete curing compound
KR102251967B1 (ko) * 2019-10-25 2021-05-17 금호석유화학 주식회사 딥 성형용 라텍스 조성물, 그 제조방법 및 그로부터 제조된 딥 성형품

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3426102A (en) * 1965-08-18 1969-02-04 Standard Oil Co Polymerizates of olefinic nitriles and diene-nitrile rubbers
US3503918A (en) * 1965-12-07 1970-03-31 Rohm & Haas Aqueous dispersion of thermosettable acrylonitrile copolymers and articles coated therewith
US3586737A (en) * 1969-02-13 1971-06-22 Standard Oil Co Impact-resistant rubber-modified olefinic nitrile-acrylic ester polymers
US3763278A (en) * 1970-08-10 1973-10-02 Standard Oil Co Olefinic nitrile styrene copolymerization process
DE2128004C3 (de) * 1971-06-05 1978-11-23 Bayer Ag, 5090 Leverkusen Filme, Fäden und Fasern aus Acrylnitril-Copolymerisaten mit verbesserter Glanzstabilität
DE2141060C3 (de) * 1971-08-17 1980-06-19 Bayer Ag, 5090 Leverkusen Verfahren zur Herstellung von Losungen, die Copolymerisate aus 10 bis 99 Gew.-% N-Vinylpyrrolidon und 1 bis 90 Gew.-% Acrylsäuremethylester und/oder Acrylnitril enthalten
DE2210483B2 (de) * 1972-03-04 1980-01-03 Basf Ag, 6700 Ludwigshafen Überzugs-, Imprägnierung«- und Verklebungsmittel
US4329401A (en) * 1978-02-17 1982-05-11 The Standard Oil Company Metal coatings from nitrile copolymer latexes
US4238535A (en) * 1978-02-17 1980-12-09 Standard Oil Company Can coatings from nitrile copolymer latexes

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Publication number Publication date
EP0068620B1 (en) 1985-05-08
EP0068620A1 (en) 1983-01-05
US4374948A (en) 1983-02-22
DE3263647D1 (en) 1985-06-13
JPS57195770A (en) 1982-12-01
CA1189994A (en) 1985-07-02

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