KR830003513A - 이소올레핀 중합체 슬러리의 안정화법 - Google Patents
이소올레핀 중합체 슬러리의 안정화법 Download PDFInfo
- Publication number
- KR830003513A KR830003513A KR1019800003075A KR800003075A KR830003513A KR 830003513 A KR830003513 A KR 830003513A KR 1019800003075 A KR1019800003075 A KR 1019800003075A KR 800003075 A KR800003075 A KR 800003075A KR 830003513 A KR830003513 A KR 830003513A
- Authority
- KR
- South Korea
- Prior art keywords
- copolymer
- stabilizer
- chloride
- polymerization diluent
- lyophilic
- Prior art date
Links
- 229920000642 polymer Polymers 0.000 title claims 4
- 239000002002 slurry Substances 0.000 title claims 2
- 230000006641 stabilisation Effects 0.000 title 1
- 238000011105 stabilization Methods 0.000 title 1
- 229920001577 copolymer Polymers 0.000 claims 4
- 238000006116 polymerization reaction Methods 0.000 claims 4
- 239000003381 stabilizer Substances 0.000 claims 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims 3
- 239000003085 diluting agent Substances 0.000 claims 3
- 125000002091 cationic group Chemical group 0.000 claims 2
- 229920001519 homopolymer Polymers 0.000 claims 2
- 239000007788 liquid Substances 0.000 claims 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 1
- 229920005549 butyl rubber Polymers 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- NEHMKBQYUWJMIP-NJFSPNSNSA-N chloro(114C)methane Chemical compound [14CH3]Cl NEHMKBQYUWJMIP-NJFSPNSNSA-N 0.000 claims 1
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 claims 1
- 229960003750 ethyl chloride Drugs 0.000 claims 1
- 125000000524 functional group Chemical group 0.000 claims 1
- 229910052736 halogen Inorganic materials 0.000 claims 1
- 150000002367 halogens Chemical class 0.000 claims 1
- 238000011065 in-situ storage Methods 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 239000002243 precursor Substances 0.000 claims 1
- 239000011541 reaction mixture Substances 0.000 claims 1
- 230000000087 stabilizing effect Effects 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/08—Butenes
- C08F10/10—Isobutene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/08—Butenes
- C08F210/10—Isobutene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/08—Butenes
- C08F210/10—Isobutene
- C08F210/12—Isobutene with conjugated diolefins, e.g. butyl rubber
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Graft Or Block Polymers (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Polymerisation Methods In General (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (2)
- 본문에 상술한 바와 같이, 안정제는 친액 중합 희석제 가용부분 및 소액 중합 희석제 비용해 부분을 갖는 공중합체인바, 소액부분은 호모중합체 또는 공중합체에 의해 흡착되거나 용해되고, 반응혼합물 또는 생성 슬러리에 안정제의 혼합을 (ⅰ) 반응혼합물에 미리 형성된 안정제 공중합체를 가할때 주로 양이온 활성 불포화 유리 또는 관능기를 가하거나 (ⅱ) 안정제를 공중합체의 소액부분을 형성하는 생성 중합체와의 반응에 의해 원위치에서 형성하여 관능기로서 생성 중합체와 공중합할 수 있거나 화학결합할 수 있는 양이온 활성 할로겐 또는 양이온 활성 불포화를 함유하는 친액 중합체를 안정제 전구물질로서 가하여 실시함을 특징으로 하는, 반응혼합물 또는 중합 생성 슬러리 안정제에 혼합시키는 것으로 구성된, 염화메틸, 염화메틸렌, 염화비닐 또는 염화에틸로부터 선택된 중합 희석제 중에서 부틸 고무 공중합체의 C4-C7이소올레핀 호모 중합체의 중합 슬러리를 안정화시키는 방법.
- ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US63,253 | 1979-08-02 | ||
| US63253 | 1979-08-02 | ||
| US06/063,253 US4252710A (en) | 1979-08-02 | 1979-08-02 | Stabilized slurries of isoolefin polymers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR830003513A true KR830003513A (ko) | 1983-06-21 |
| KR850000174B1 KR850000174B1 (ko) | 1985-03-04 |
Family
ID=22047983
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019800003075A KR850000174B1 (ko) | 1979-08-02 | 1980-08-01 | 이소올레핀 중합체 슬러리의 안정화법 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US4252710A (ko) |
| JP (1) | JPS6021684B2 (ko) |
| KR (1) | KR850000174B1 (ko) |
| AU (1) | AU533627B2 (ko) |
| BE (1) | BE884575A (ko) |
| BR (1) | BR8004842A (ko) |
| DE (1) | DE3029252A1 (ko) |
| FR (1) | FR2463156A1 (ko) |
| GB (1) | GB2056469B (ko) |
| IN (1) | IN154509B (ko) |
| IT (1) | IT1132292B (ko) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4358560A (en) * | 1979-08-02 | 1982-11-09 | Exxon Research & Engineering Co. | Stabilized slurries of isoolefin polymers |
| US4780513A (en) * | 1982-09-30 | 1988-10-25 | Exxon Research & Engineering Co. | Modified Lewis acid catalyzed polymerization |
| CA1238145A (en) * | 1982-09-30 | 1988-06-14 | Kenneth W. Powers | Modified lewis acid catalyzed polymerization |
| US4474924A (en) * | 1983-01-27 | 1984-10-02 | Exxon Research & Engineering Co. | Stabilized slurries of isoolefin polymers |
| JPH0437396Y2 (ko) * | 1986-06-19 | 1992-09-02 | ||
| US5182333A (en) * | 1987-12-11 | 1993-01-26 | Exxon Chemical Patents Inc. | Production of rubbery isoolefin polymers |
| US5071913A (en) * | 1987-12-11 | 1991-12-10 | Exxon Chemical Patents Inc. | Rubbery isoolefin polymers exhibiting improved processability |
| DE4426756A1 (de) | 1994-07-28 | 1996-02-01 | Bayer Ag | Verfahren zur Herstellung von C¶4¶-C¶1¶¶6¶-Alkylkautschuken nach dem Slurry-Verfahren |
| CN104926973A (zh) * | 2015-07-13 | 2015-09-23 | 商巧玲 | 一种端氯基聚苯乙烯的制备方法及其应用 |
| CN111234077B (zh) * | 2020-04-03 | 2021-03-02 | 浙江信汇新材料股份有限公司 | 丁基橡胶的生产方法及装置 |
| CN112409522B (zh) * | 2020-11-16 | 2022-11-15 | 山东京博中聚新材料有限公司 | 一种丁基橡胶的制备方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE584369A (ko) * | 1958-11-05 | 1900-01-01 | ||
| AT229579B (de) * | 1958-11-05 | 1963-09-25 | Ici Ltd | Verfahren zur Herstellung stabiler Dispersionen synthetischer Polymere |
| NL259178A (ko) * | 1959-12-18 | |||
| GB1174391A (en) * | 1966-01-31 | 1969-12-17 | Ici Ltd | Dispersion Polymerisation. |
| US3904708A (en) * | 1966-07-26 | 1975-09-09 | Joseph P Kennedy | Process for graft polymerization |
| US4098980A (en) * | 1976-06-24 | 1978-07-04 | The Goodyear Tire & Rubber Company | Non-aqueous dispersion polymerization of conjugated diolefins |
-
1979
- 1979-08-02 US US06/063,253 patent/US4252710A/en not_active Expired - Lifetime
-
1980
- 1980-07-18 AU AU60639/80A patent/AU533627B2/en not_active Ceased
- 1980-07-21 IN IN534/DEL/80A patent/IN154509B/en unknown
- 1980-07-29 GB GB8024803A patent/GB2056469B/en not_active Expired
- 1980-07-31 BE BE0/201605A patent/BE884575A/fr not_active IP Right Cessation
- 1980-08-01 BR BR8004842A patent/BR8004842A/pt unknown
- 1980-08-01 FR FR8017102A patent/FR2463156A1/fr active Granted
- 1980-08-01 IT IT23883/80A patent/IT1132292B/it active
- 1980-08-01 DE DE19803029252 patent/DE3029252A1/de active Granted
- 1980-08-01 KR KR1019800003075A patent/KR850000174B1/ko active
- 1980-08-02 JP JP55106711A patent/JPS6021684B2/ja not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5624404A (en) | 1981-03-09 |
| FR2463156B1 (ko) | 1984-05-25 |
| GB2056469A (en) | 1981-03-18 |
| DE3029252C2 (ko) | 1987-09-24 |
| AU6063980A (en) | 1981-02-05 |
| IN154509B (ko) | 1984-11-03 |
| JPS6021684B2 (ja) | 1985-05-29 |
| KR850000174B1 (ko) | 1985-03-04 |
| GB2056469B (en) | 1984-04-26 |
| BE884575A (fr) | 1981-02-02 |
| FR2463156A1 (fr) | 1981-02-20 |
| BR8004842A (pt) | 1981-02-10 |
| IT8023883A0 (it) | 1980-08-01 |
| US4252710A (en) | 1981-02-24 |
| IT1132292B (it) | 1986-07-02 |
| DE3029252A1 (de) | 1981-02-19 |
| AU533627B2 (en) | 1983-12-01 |
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