KR20230175305A - 프로필렌계 공중합체, 이의 제조 공정 및 용도, 및 이를 함유하는 폴리프로필렌 조성물 - Google Patents

프로필렌계 공중합체, 이의 제조 공정 및 용도, 및 이를 함유하는 폴리프로필렌 조성물 Download PDF

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Publication number
KR20230175305A
KR20230175305A KR1020237040682A KR20237040682A KR20230175305A KR 20230175305 A KR20230175305 A KR 20230175305A KR 1020237040682 A KR1020237040682 A KR 1020237040682A KR 20237040682 A KR20237040682 A KR 20237040682A KR 20230175305 A KR20230175305 A KR 20230175305A
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South Korea
Prior art keywords
propylene
based copolymer
polypropylene
polymerization
cocatalyst
Prior art date
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Pending
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KR1020237040682A
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English (en)
Korean (ko)
Inventor
웬보 송
위안위안 팡
수량 한
자오 진
루성 왕
징란 뤼
Original Assignee
차이나 페트로리움 앤드 케미컬 코포레이션
베이징 리서치 인스티튜트 오브 케미컬 인더스트리, 차이나 페트로리움 앤드 케미컬 코포레이션
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from CN202110449881.5A external-priority patent/CN115232236B/zh
Priority claimed from CN202110449898.0A external-priority patent/CN115246967B/zh
Priority claimed from CN202110448666.3A external-priority patent/CN115232235B/zh
Application filed by 차이나 페트로리움 앤드 케미컬 코포레이션, 베이징 리서치 인스티튜트 오브 케미컬 인더스트리, 차이나 페트로리움 앤드 케미컬 코포레이션 filed Critical 차이나 페트로리움 앤드 케미컬 코포레이션
Publication of KR20230175305A publication Critical patent/KR20230175305A/ko
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/14—Copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/27—Amount of comonomer in wt% or mol%
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2308/00—Chemical blending or stepwise polymerisation process with the same catalyst
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00—Polymer mixtures characterised by way of preparation
    • C08L2314/06—Metallocene or single site catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerisation Methods In General (AREA)
KR1020237040682A 2021-04-25 2022-04-21 프로필렌계 공중합체, 이의 제조 공정 및 용도, 및 이를 함유하는 폴리프로필렌 조성물 Pending KR20230175305A (ko)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
CN202110449881.5A CN115232236B (zh) 2021-04-25 2021-04-25 一种丙烯基共聚物及其制备方法和应用和聚丙烯组合物
CN202110449881.5 2021-04-25
CN202110449898.0A CN115246967B (zh) 2021-04-25 2021-04-25 一种丙烯基组合物及应用和聚丙烯材料
CN202110448666.3 2021-04-25
CN202110448666.3A CN115232235B (zh) 2021-04-25 2021-04-25 一种烯烃聚合物的制造方法及烯烃聚合物
CN202110449898.0 2021-04-25
PCT/CN2022/088102 WO2022228260A1 (zh) 2021-04-25 2022-04-21 丙烯基共聚物、其制备方法和用途和包含其的聚丙烯组合物

Publications (1)

Publication Number Publication Date
KR20230175305A true KR20230175305A (ko) 2023-12-29

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ID=83847809

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020237040682A Pending KR20230175305A (ko) 2021-04-25 2022-04-21 프로필렌계 공중합체, 이의 제조 공정 및 용도, 및 이를 함유하는 폴리프로필렌 조성물

Country Status (9)

Country Link
US (1) US20240218098A1 (https=)
EP (1) EP4332132A4 (https=)
JP (1) JP2024514968A (https=)
KR (1) KR20230175305A (https=)
CN (1) CN117321095A (https=)
BR (1) BR112023022186A2 (https=)
CA (1) CA3216518A1 (https=)
TW (1) TW202309112A (https=)
WO (1) WO2022228260A1 (https=)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116239716A (zh) * 2023-03-21 2023-06-09 广东新华粤石化集团股份公司 一种丙烯共聚物及其制备方法
CN119684499A (zh) * 2023-09-22 2025-03-25 国家能源投资集团有限责任公司 用于烯烃聚合过程的催化剂、丙烯聚合物及其生产方法

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EP0582194B1 (de) 1992-08-03 1998-05-06 TARGOR GmbH Verfahren zur Herstellung eines Olefinpolymers unter Verwendung von Metallocenen mit speziell substituierten Indenylliganden
US5714554A (en) * 1992-09-08 1998-02-03 Rexene Corporation High tensile strength amorphous 1-butene/propylene and ethylene/propylene copolymers
US5317036A (en) * 1992-10-16 1994-05-31 Union Carbide Chemicals & Plastics Technology Corporation Gas phase polymerization reactions utilizing soluble unsupported catalysts
US6313240B1 (en) 1993-02-22 2001-11-06 Tosoh Corporation Process for producing ethylene/α-olefin copolymer
US5767208A (en) 1995-10-20 1998-06-16 Exxon Chemical Patents Inc. High temperature olefin polymerization process
DE19544828A1 (de) 1995-12-01 1997-06-05 Hoechst Ag Hochmolekulare Copolymere
US6525157B2 (en) 1997-08-12 2003-02-25 Exxonmobile Chemical Patents Inc. Propylene ethylene polymers
US7232871B2 (en) 1997-08-12 2007-06-19 Exxonmobil Chemical Patents Inc. Propylene ethylene polymers and production process
ES2182494T3 (es) 1998-03-11 2003-03-01 Dow Chemical Co Procedimiento integrado para la preparacion de complejos de dienos.
JP2001064322A (ja) * 1999-06-24 2001-03-13 Idemitsu Petrochem Co Ltd プロピレン系重合体及びその成形体並びにプロピレン系重合体の製造方法
KR100374154B1 (ko) 2000-06-24 2003-02-26 장학선 전원신호 및 데이터신호를 송수신하기 위한 시스템
JP2004527617A (ja) 2001-04-12 2004-09-09 エクソンモービル・ケミカル・パテンツ・インク プロピレン−エチレンコポリマー
US7700707B2 (en) * 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US8618219B2 (en) * 2002-10-15 2013-12-31 Exxonmobil Chemical Patents Inc. Propylene copolymers for adhesive applications
KR20070039930A (ko) * 2004-07-08 2007-04-13 엑손모빌 케미칼 패턴츠 인코포레이티드 초임계 조건에서 중합체의 제조방법
DE602007009851D1 (de) * 2007-11-30 2010-11-25 Borealis Tech Oy Random-Propylencopolymer mit hohem Comonomergehalt
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KR20220139378A (ko) * 2020-02-11 2022-10-14 엑손모빌 케미칼 패턴츠 인코포레이티드 전이 금속 비스(페놀레이트) 촉매 복합체를 사용하여 얻은 프로필렌 공중합체 및 그의 균질한 제조 방법

Also Published As

Publication number Publication date
BR112023022186A2 (pt) 2023-12-19
TW202309112A (zh) 2023-03-01
EP4332132A1 (en) 2024-03-06
US20240218098A1 (en) 2024-07-04
CN117321095A (zh) 2023-12-29
EP4332132A4 (en) 2025-08-20
JP2024514968A (ja) 2024-04-03
WO2022228260A1 (zh) 2022-11-03
CA3216518A1 (en) 2022-11-03

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