KR20230078604A - Organic compounds and organic electro luminescence device comprising the same - Google Patents

Organic compounds and organic electro luminescence device comprising the same Download PDF

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KR20230078604A
KR20230078604A KR1020230064463A KR20230064463A KR20230078604A KR 20230078604 A KR20230078604 A KR 20230078604A KR 1020230064463 A KR1020230064463 A KR 1020230064463A KR 20230064463 A KR20230064463 A KR 20230064463A KR 20230078604 A KR20230078604 A KR 20230078604A
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김충한
손효석
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솔루스첨단소재 주식회사
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Abstract

본 발명은 신규 화합물 및 이를 포함하는 유기 전계 발광 소자에 관한 것으로서, 본 발명에 따른 화합물은 유기 전계 발광 소자의 유기물층, 바람직하게는 발광층에 사용됨에 따라 유기 전계 발광 소자의 발광 효율, 구동 전압, 수명 등을 향상시킬 수 있다.The present invention relates to a novel compound and an organic electroluminescent device including the same, and the compound according to the present invention is used in an organic material layer, preferably a light emitting layer, of the organic electroluminescent device, thereby improving luminous efficiency, driving voltage, and lifetime of the organic electroluminescent device. etc. can be improved.

Description

유기 화합물 및 이를 포함하는 유기 전계 발광 소자{ORGANIC COMPOUNDS AND ORGANIC ELECTRO LUMINESCENCE DEVICE COMPRISING THE SAME}Organic compounds and organic electroluminescent devices containing them {ORGANIC COMPOUNDS AND ORGANIC ELECTRO LUMINESCENCE DEVICE COMPRISING THE SAME}

본 발명은 유기 전계 발광 소자용 재료로서 사용될 수 있는 신규 유기 화합물 및 이를 포함하는 유기 전계 발광 소자에 관한 것이다.The present invention relates to a novel organic compound that can be used as a material for an organic electroluminescent device and an organic electroluminescent device including the same.

1950년대 베르나소스(Bernanose)의 유기 박막 발광 관측을 시점으로 하여, 1965년 안트라센 단결정을 이용한 청색 전기발광으로 이어진 유기 전계 발광(electroluminescent, EL) 소자에 대한 연구가 이어져 오다가, 1987년 탕(Tang)에 의하여 정공층과 발광층의 기능층으로 나눈 적층 구조의 유기 전계 발광 소자가 제시되었다. 이후, 고효율, 고수명의 유기 전계 발광 소자를 만들기 위하여, 소자 내 각각의 특징적인 유기물층을 도입하는 형태로 발전하여 왔으며, 이에 사용되는 특화된 물질의 개발로 이어졌다.With the observation of organic thin film emission by Bernanose in the 1950s as a starting point, research on organic electroluminescent (EL) devices led to blue electroluminescence using anthracene single crystal in 1965, followed by Tang in 1987. ), an organic electroluminescent device having a laminated structure divided into a hole layer and a functional layer of a light emitting layer was proposed. Since then, in order to make a high-efficiency, long-life organic electroluminescent device, it has been developed in the form of introducing each characteristic organic material layer in the device, leading to the development of specialized materials used therein.

유기 전계 발광 소자는 두 전극 사이에 전압을 걸어주면 양극에서는 정공이 유기물층으로 주입되고, 음극에서는 전자가 유기물층으로 주입된다. 주입된 정공과 전자가 만났을 때 엑시톤(exciton)이 형성되며, 이 엑시톤이 바닥상태로 떨어질 때 빛이 나게 된다. 이때, 유기물층으로 사용되는 물질은 그 기능에 따라, 발광 물질, 정공 주입 물질, 정공 수송 물질, 전자 수송 물질, 전자 주입 물질 등으로 분류될 수 있다.In the organic electroluminescent device, when a voltage is applied between the two electrodes, holes are injected into the organic material layer at the anode and electrons are injected into the organic material layer at the cathode. When the injected holes and electrons meet, excitons are formed, and when these excitons fall to the ground state, light is emitted. At this time, the material used as the organic material layer may be classified into a light emitting material, a hole injection material, a hole transport material, an electron transport material, an electron injection material, and the like according to its function.

발광 물질은 발광색에 따라 청색, 녹색, 적색 발광 물질과, 보다 나은 천연색을 구현하기 위한 노란색 및 주황색 발광 물질로 구분될 수 있다. 또한, 색순도의 증가와 에너지 전이를 통한 발광 효율을 증가시키기 위하여, 발광 물질로서 호스트/도펀트 계를 사용할 수 있다.Light-emitting materials may be classified into blue, green, and red light-emitting materials according to light-emitting colors, and yellow and orange light-emitting materials for implementing better natural colors. In addition, in order to increase color purity and increase light emitting efficiency through energy transfer, a host/dopant system may be used as a light emitting material.

도펀트 물질은 유기 물질을 사용하는 형광 도펀트와 Ir, Pt 등의 중원자(heavy atoms)가 포함된 금속 착체 화합물을 사용하는 인광 도펀트로 나눌 수 있다. 이때, 인광 재료의 개발은 이론적으로 형광에 비해 4배까지 발광 효율을 향상시킬 수 있기 때문에, 인광 도펀트 뿐만 아니라 인광 호스트 재료들에 대한 연구도 많이 진행되고 있다.The dopant material may be divided into a phosphorescent dopant using an organic material and a phosphorescent dopant using a metal complex compound containing heavy atoms such as Ir and Pt. At this time, since the development of phosphorescent materials can theoretically improve luminous efficiency up to 4 times compared to fluorescence, research on phosphorescent dopants as well as phosphorescent host materials is being conducted.

현재까지 정공 주입층, 정공 수송층, 정공 차단층, 전자 수송층 재료로는 NPB, BCP, Alq3 등이 널리 알려져 있으며, 발광층 재료로는 안트라센 유도체들이 보고되고 있다. 특히, 발광층 재료 중 효율 향상 측면에서 장점을 가지고 있는 Firpic, Ir(ppy)3, (acac)Ir(btp)2 등과 같은 Ir을 포함하는 금속 착체 화합물이 청색(blue), 녹색(green), 적색(red)의 인광 도판트 재료로 사용되고 있으며, 4,4-디카바졸리비페닐(4,4-dicarbazolybiphenyl, CBP)은 인광 호스트 재료로 사용되고 있다.Until now, NPB, BCP, Alq 3 and the like have been widely known as materials for the hole injection layer, hole transport layer, hole blocking layer, and electron transport layer, and anthracene derivatives have been reported as materials for the light emitting layer. In particular, metal complex compounds containing Ir, such as Firpic, Ir(ppy) 3 , (acac)Ir(btp) 2 , etc., which have advantages in terms of efficiency improvement among light emitting layer materials, produce blue, green, and red colors. (red) is used as a phosphorescent dopant material, and 4,4-dicarbazolibiphenyl (CBP) is used as a phosphorescent host material.

Figure pat00001
Figure pat00001

그러나 종래의 유기물층 재료들은 발광 특성 측면에서는 유리한 면이 있으나, 유리전이온도가 낮아 열적 안정성이 매우 좋지 않기 때문에, 유기 전계 발광 소자의 수명 측면에서 만족할 만한 수준이 되지 못하고 있다. 따라서, 성능이 뛰어난 유기물층 재료의 개발이 요구되고 있다.However, conventional organic layer materials are advantageous in terms of light emitting properties, but have poor thermal stability due to their low glass transition temperature, so they are not satisfactory in terms of lifespan of organic EL devices. Therefore, there is a demand for the development of organic layer materials with excellent performance.

본 발명은 유기 전계 발광 소자에 적용할 수 있으며, 정공, 전자 주입 및 수송능, 발광능 등이 모두 우수한 신규 유기 화합물을 제공하는 것을 목적으로 한다. An object of the present invention is to provide a novel organic compound that can be applied to an organic electroluminescent device and has excellent hole and electron injection and transport capabilities, luminescent performance, and the like.

또한, 본 발명은 상기 신규 유기 화합물을 포함하여 낮은 구동 전압과 높은 발광 효율을 나타내며 수명이 향상되는 유기 전계 발광 소자를 제공하는 것을 또 다른 목적으로 한다.In addition, another object of the present invention is to provide an organic electroluminescent device exhibiting a low driving voltage and high luminous efficiency and having an improved lifetime, including the novel organic compound.

상기한 목적을 달성하기 위해, 본 발명은 하기 화학식 1로 표시되는 화합물을 제공한다:In order to achieve the above object, the present invention provides a compound represented by Formula 1 below:

[화학식 1][Formula 1]

Figure pat00002
Figure pat00002

상기 화학식 1 에서,In Formula 1,

m은 0 내지 4의 정수이고;m is an integer from 0 to 4;

n은 0 내지 3의 정수이며;n is an integer from 0 to 3;

Y는 S, O 및 C(R5)(R6)로 이루어진 군에서 선택되고; Y is selected from the group consisting of S, O and C(R 5 )(R 6 );

L은 직접결합, C6~C18의 아릴렌기 및 핵원자수 5 내지 18개의 헤테로아릴렌기로 이루어진 군에서 선택되며;L is selected from the group consisting of a direct bond, a C 6 ~ C 18 arylene group, and a heteroarylene group having 5 to 18 nuclear atoms;

R1 내지 R6 및 Ar1은 각각 독립적으로 수소, 중수소, 할로겐, 시아노기, 니트로기, C1~C40의 알킬기, C2~C40의 알케닐기, C2~C40의 알키닐기, C3~C40의 시클로알킬기, 핵원자수 3 내지 40개의 헤테로시클로알킬기, C6~C60의 아릴기, 핵원자수 5 내지 60개의 헤테로아릴기, C1~C40의 알킬옥시기, C6~C60의 아릴옥시기, C3~C40의 알킬실릴기, C6~C60의 아릴실릴기, C1~C40의 알킬보론기, C6~C60의 아릴보론기, C6~C60의 아릴포스파닐기, C6~C60의 모노 또는 디아릴포스피닐기 및 C6~C60의 아릴아민기로 이루어진 군에서 선택되며; 상기 R1 내지 R4 각각이 복수 개인 경우 이들은 서로 동일하거나 상이하며;R 1 to R 6 and Ar1 are each independently hydrogen, deuterium, halogen, cyano group, nitro group, C 1 ~ C 40 alkyl group, C 2 ~ C 40 alkenyl group, C 2 ~ C 40 alkynyl group, C 3 ~ C 40 cycloalkyl group, 3 to 40 nuclear atoms heterocycloalkyl group, C 6 ~ C 60 aryl group, 5 to 60 nuclear atoms heteroaryl group, C 1 ~ C 40 alkyloxy group, C 6 ~ C 60 aryloxy group, C 3 ~ C 40 alkylsilyl group, C 6 ~ C 60 arylsilyl group, C 1 ~ C 40 alkylboron group, C 6 ~ C 60 arylboron group, C It is selected from the group consisting of a 6 ~C 60 arylphosphanyl group, a C 6 ~C 60 mono- or diarylphosphinyl group, and a C 6 ~C 60 arylamine group; When each of R 1 to R 4 is plural, they are identical to or different from each other;

상기 L의 아릴렌기 및 헤테로아릴렌기와, 상기 R1 내지 R6 및 Ar1의 알킬기, 알케닐기, 알키닐기, 아릴기, 헤테로아릴기, 아릴옥시기, 알킬옥시기, 시클로알킬기, 헤테로시클로알킬기, 아릴아민기, 알킬실릴기, 알킬보론기, 아릴보론기, 아릴포스파닐기, 모노 또는 디아릴포스피닐기 및 아릴실릴기는 각각 독립적으로 중수소, 할로겐, 시아노기, 니트로기, C1~C40의 알킬기, C2~C40의 알케닐기, C2~C40의 알키닐기, C6~C60의 아릴기, 핵원자수 5 내지 60개의 헤테로아릴기, C6~C60의 아릴옥시기, C1~C40의 알킬옥시기, C6~C60의 아릴아민기, C3~C40의 시클로알킬기, 핵원자수 3 내지 40개의 헤테로시클로알킬기, C1~C40의 알킬실릴기, C1~C40의 알킬보론기, C6~C60의 아릴보론기, C6~C60의 아릴포스파닐기, C6~C60의 모노 또는 디아릴포스피닐기 및 C6~C60의 아릴실릴기로 이루어진 군에서 선택된 1종 이상의 치환기로 치환되거나 비치환되고, 복수 개의 치환기로 치환되는 경우, 이들은 서로 동일하거나 상이하다.An arylene group and a heteroarylene group of L, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heteroaryl group, an aryloxy group, an alkyloxy group, a cycloalkyl group, a heterocycloalkyl group of R 1 to R 6 and Ar1, An arylamine group, an alkylsilyl group, an alkylboron group, an arylboron group, an arylphosphanyl group, a mono or diarylphosphinyl group, and an arylsilyl group are each independently deuterium, halogen, cyano group, nitro group, C 1 to C 40 Alkyl group, C 2 ~ C 40 alkenyl group, C 2 ~ C 40 alkynyl group, C 6 ~ C 60 aryl group, heteroaryl group having 5 to 60 nuclear atoms, C 6 ~ C 60 aryloxy group , C 1 ~ C 40 alkyloxy group, C 6 ~ C 60 arylamine group, C 3 ~ C 40 cycloalkyl group, 3 to 40 nuclear atoms heterocycloalkyl group, C 1 ~ C 40 alkylsilyl group , C 1 ~ C 40 alkyl boron group, C 6 ~ C 60 aryl boron group, C 6 ~ C 60 arylphosphanyl group, C 6 ~ C 60 mono or diaryl phosphinyl group and C 6 ~ C When substituted or unsubstituted with one or more substituents selected from the group consisting of 60 arylsilyl groups, and substituted with a plurality of substituents, they are the same as or different from each other.

본 발명은 양극, 음극 및 상기 양극과 음극 사이에 개재(介在)된 1층 이상의 유기물층을 포함하며, 상기 1층 이상의 유기물층 중에서 적어도 하나는 상기 화학식 1의 화합물을 포함하는 유기 전계 발광 소자를 제공한다.The present invention provides an organic electroluminescent device comprising an anode, a cathode, and one or more organic material layers interposed between the anode and the cathode, wherein at least one of the one or more organic material layers includes the compound of Formula 1 .

본 발명에서의 “알킬”은 탄소수 1 내지 40개의 직쇄 또는 측쇄의 포화 탄화수소에서 유래되는 1가의 치환기이며, 이의 예로는 메틸, 에틸, 프로필, 이소부틸, sec-부틸, 펜틸, iso-아밀, 헥실 등이 있는데, 이에 한정되지 않는다."Alkyl" in the present invention is a monovalent substituent derived from a straight or branched chain saturated hydrocarbon having 1 to 40 carbon atoms, examples thereof include methyl, ethyl, propyl, isobutyl, sec-butyl, pentyl, iso-amyl, hexyl etc., but is not limited thereto.

본 발명에서의 “알케닐(alkenyl)”은 탄소-탄소 이중 결합을 1개 이상 가진, 탄소수 2 내지 40개의 직쇄 또는 측쇄의 불포화 탄화수소에서 유래되는 1가의 치환기이며, 이의 예로는 비닐(vinyl), 알릴(allyl), 이소프로펜일(isopropenyl), 2-부텐일(2-butenyl) 등이 있는데, 이에 한정되지 않는다.In the present invention, “alkenyl” is a monovalent substituent derived from a straight-chain or branched chain unsaturated hydrocarbon having 2 to 40 carbon atoms and having at least one carbon-carbon double bond, examples thereof include vinyl, There are allyl, isopropenyl, 2-butenyl, etc., but is not limited thereto.

본 발명에서의 “알키닐(alkynyl)”은 탄소-탄소 삼중 결합을 1개 이상 가진, 탄소수 2 내지 40개의 직쇄 또는 측쇄의 불포화 탄화수소에서 유래되는 1가의 치환기이며, 이의 예로는 에티닐(ethynyl), 2-프로파닐(2-propynyl) 등이 있는데, 이에 한정되지 않는다.In the present invention, “alkynyl” is a monovalent substituent derived from a straight-chain or branched unsaturated hydrocarbon having 2 to 40 carbon atoms and having at least one carbon-carbon triple bond, an example of which is ethynyl , 2-propanil (2-propynyl) and the like, but are not limited thereto.

본 발명에서의 “아릴”은 단독 고리 또는 2 이상의 고리가 조합된, 탄소수 6 내지 60개의 방향족 탄화수소로부터 유래된 1가의 치환기를 의미한다. 또한, 2 이상의 고리가 서로 축합되어 있고, 고리 형성 원자로서 탄소만을 포함(예를 들어, 탄소수는 8 내지 60개일 수 있음)하고, 분자 전체가 비-방향족성(non-aromacity)를 갖는 1가 치환기도 포함될 수 있다. 이러한 아릴의 예로는 페닐, 나프틸, 페난트릴, 안트릴, 플루오레닐 등이 있는데, 이에 한정되지 않는다. 본 발명에서의 “헤테로아릴”은 핵원자수 5 내지 60개의 모노헤테로사이클릭 또는 폴리헤테로사이클릭 방향족 탄화수소로부터 유래된 1가의 치환기를 의미한다. 이때, 고리 중 하나 이상의 탄소, 바람직하게는 1 내지 3개의 탄소가 N, O, P, S 및 Se 중에서 선택된 헤테로원자로 치환된다. 또한, 2 이상의 고리가 서로 단순 부착(pendant)되거나 축합되어 있고, 고리 형성 원자로서 탄소 외에 N, O, P, S 및 Se 중에서 선택된 헤테로 원자를 포함하고, 분자 전체가 비-방향족성(non-aromacity)를 갖는 1가 그룹도 포함하는 것으로 해석된다. 이러한 헤테로아릴의 예로는 피리딜, 피라지닐, 피리미디닐, 피리다지닐, 트리아지닐과 같은 6-원 모노사이클릭 고리; 페녹사티에닐(phenoxathienyl), 인돌리지닐(indolizinyl), 인돌릴(indolyl), 퓨리닐(purinyl), 퀴놀릴(quinolyl), 벤조티아졸(벤조thiazole), 카바졸릴(carbazolyl)과 같은 폴리사이클릭 고리; 2-퓨라닐, N-이미다졸릴, 2-이속사졸릴, 2-피리디닐, 2-피리미디닐 등이 있는데, 이에 한정되지 않는다.In the present invention, “aryl” refers to a monovalent substituent derived from an aromatic hydrocarbon having 6 to 60 carbon atoms in a single ring or a combination of two or more rings. In addition, two or more rings are condensed with each other, contain only carbon as ring-forming atoms (for example, the number of carbon atoms may be 8 to 60), and the entire molecule has non-aromaticity. Substituents may also be included. Examples of such aryl include, but are not limited to, phenyl, naphthyl, phenanthryl, anthryl, fluorenyl, and the like. In the present invention, “heteroaryl” means a monovalent substituent derived from a monoheterocyclic or polyheterocyclic aromatic hydrocarbon having 5 to 60 nuclear atoms. At this time, at least one carbon, preferably 1 to 3 carbons in the ring is substituted with a heteroatom selected from N, O, P, S and Se. In addition, two or more rings are simply pendant or condensed with each other, contain heteroatoms selected from N, O, P, S, and Se in addition to carbon as ring-forming atoms, and the entire molecule is non-aromatic (non-aromatic). aromacity) is also construed to include monovalent groups. Examples of such heteroaryls include 6-membered monocyclic rings such as pyridyl, pyrazinyl, pyrimidinyl, pyridazinyl, and triazinyl; Polycyclics such as phenoxathienyl, indolizinyl, indolyl, purinyl, quinolyl, benzothiazole, and carbazolyl click ring; 2-furanyl, N-imidazolyl, 2-isoxazolyl, 2-pyridinyl, 2-pyrimidinyl, and the like, but are not limited thereto.

본 발명에서의 “아릴옥시”는 RO-로 표시되는 1가의 치환기로, 상기 R은 탄소수 5 내지 60개의 아릴을 의미한다. 이러한 아릴옥시의 예로는 페닐옥시, 나프틸옥시, 디페닐옥시 등이 있는데, 이에 한정되지 않는다.In the present invention, "aryloxy" is a monovalent substituent represented by RO-, wherein R means an aryl having 5 to 60 carbon atoms. Examples of such aryloxy include, but are not limited to, phenyloxy, naphthyloxy, diphenyloxy, and the like.

본 발명에서의 “알킬옥시”는 R’O-로 표시되는 1가의 치환기로, 상기 R’는 1 내지 40개의 알킬을 의미하며, 직쇄(linear), 측쇄(branched) 또는 사이클릭(cyclic) 구조를 포함하는 것으로 해석한다. 이러한 알킬옥시의 예로는 메톡시, 에톡시, n-프로폭시, 1-프로폭시, t-부톡시, n-부톡시, 펜톡시 등이 있는데, 이에 한정되지 않는다.“Alkyloxy” in the present invention is a monovalent substituent represented by R'O-, wherein R' means 1 to 40 alkyl, and has a linear, branched or cyclic structure. be interpreted as including Examples of such alkyloxy include, but are not limited to, methoxy, ethoxy, n-propoxy, 1-propoxy, t-butoxy, n-butoxy, pentoxy, and the like.

본 발명에서의 “아릴아민”은 탄소수 6 내지 60개의 아릴로 치환된 아민을 의미한다.In the present invention, “arylamine” means an amine substituted with an aryl having 6 to 60 carbon atoms.

본 발명에서의 “시클로알킬”은 탄소수 3 내지 40개의 모노사이클릭 또는 폴리사이클릭 비-방향족 탄화수소로부터 유래된 1가의 치환기를 의미한다. 이러한 사이클로알킬의 예로는 사이클로프로필, 사이클로펜틸, 사이클로헥실, 놀보닐(norbornyl), 아다만틴(adamantine) 등이 있는데, 이에 한정되지 않는다."Cycloalkyl" in the present invention means a monovalent substituent derived from a monocyclic or polycyclic non-aromatic hydrocarbon having 3 to 40 carbon atoms. Examples of such cycloalkyl include, but are not limited to, cyclopropyl, cyclopentyl, cyclohexyl, norbornyl, adamantine, and the like.

본 발명에서의 “헤테로시클로알킬”은 핵원자수 3 내지 40개의 비-방향족 탄화수소로부터 유래된 1가의 치환기를 의미하며, 고리 중 하나 이상의 탄소, 바람직하게는 1 내지 3개의 탄소가 N, O, S 또는 Se와 같은 헤테로 원자로 치환된다. 이러한 헤테로시클로알킬의 예로는 모르폴린, 피페라진 등이 있는데, 이에 한정되지 않는다.In the present invention, "heterocycloalkyl" means a monovalent substituent derived from a non-aromatic hydrocarbon having 3 to 40 nuclear atoms, and one or more carbons in the ring, preferably 1 to 3 carbons, are N, O, It is substituted with a heteroatom such as S or Se. Examples of such heterocycloalkyl include, but are not limited to, morpholine, piperazine, and the like.

본 발명에서의 “알킬실릴”은 탄소수 1 내지 40개의 알킬로 치환된 실릴이고, “아릴실릴”은 탄소수 5 내지 60개의 아릴로 치환된 실릴을 의미한다.In the present invention, “alkylsilyl” refers to silyl substituted with alkyl having 1 to 40 carbon atoms, and “arylsilyl” refers to silyl substituted with aryl having 5 to 60 carbon atoms.

본 발명에서의 “축합 고리”는 축합 지방족 고리, 축합 방향족 고리, 축합 헤테로지방족 고리, 축합 헤테로방향족 고리 또는 이들의 조합된 형태를 의미한다.In the present invention, "condensed ring" means a condensed aliphatic ring, a condensed aromatic ring, a condensed heteroaliphatic ring, a condensed heteroaromatic ring, or a combination thereof.

본 발명의 화합물은 열적 안정성, 캐리어 수송능, 발광능 등이 우수하기 때문에 유기 전계 발광 소자의 유기물층 재료로 유용하게 적용될 수 있다.Since the compound of the present invention is excellent in thermal stability, carrier transport ability, luminous ability, etc., it can be usefully applied as an organic material layer material of an organic electroluminescent device.

또한, 본 발명의 화합물을 유기물층에 포함하는 유기 전계 발광 소자는 발광성능, 구동전압, 수명, 효율 등의 측면이 크게 향상되어 풀 칼라 디스플레이 패널 등에 효과적으로 적용될 수 있다.In addition, the organic electroluminescent device including the compound of the present invention in an organic material layer can be effectively applied to a full color display panel, etc., as aspects such as light emitting performance, driving voltage, lifespan, and efficiency are greatly improved.

도 1은 본 발명의 일 실시예에 따른 유기 전계 발광 소자의 단면도를 나타낸 것이다.
도 2는 본 발명의 일 실시예에 따른 유기 전계 발광 소자의 단면도를 나타낸 것이다. 1 is a cross-sectional view of an organic electroluminescent device according to an embodiment of the present invention.
2 is a cross-sectional view of an organic electroluminescent device according to an embodiment of the present invention.

이하, 본 발명을 상세히 설명한다.Hereinafter, the present invention will be described in detail.

1.One. 신규 유기 화합물new organic compounds

본 발명의 신규 화합물은 하기 화학식 1로 표시될 수 있다:The novel compound of the present invention can be represented by Formula 1:

[화학식 1][Formula 1]

Figure pat00003
Figure pat00003

상기 화학식 1 에서,In Formula 1,

m은 0 내지 4의 정수이고;m is an integer from 0 to 4;

n은 0 내지 3의 정수이며;n is an integer from 0 to 3;

Y는 S, O 및 C(R5)(R6)로 이루어진 군에서 선택되고; Y is selected from the group consisting of S, O and C(R 5 )(R 6 );

L은 직접결합, C6~C18의 아릴렌기 및 핵원자수 5 내지 18개의 헤테로아릴렌기로 이루어진 군에서 선택되며;L is selected from the group consisting of a direct bond, a C 6 ~ C 18 arylene group, and a heteroarylene group having 5 to 18 nuclear atoms;

R1 내지 R6 및 Ar1은 각각 독립적으로 수소, 중수소, 할로겐, 시아노기, 니트로기, C1~C40의 알킬기, C2~C40의 알케닐기, C2~C40의 알키닐기, C3~C40의 시클로알킬기, 핵원자수 3 내지 40개의 헤테로시클로알킬기, C6~C60의 아릴기, 핵원자수 5 내지 60개의 헤테로아릴기, C1~C40의 알킬옥시기, C6~C60의 아릴옥시기, C3~C40의 알킬실릴기, C6~C60의 아릴실릴기, C1~C40의 알킬보론기, C6~C60의 아릴보론기, C6~C60의 아릴포스파닐기, C6~C60의 모노 또는 디아릴포스피닐기 및 C6~C60의 아릴아민기로 이루어진 군에서 선택되며; 상기 R1 내지 R4 각각이 복수 개인 경우 이들은 서로 동일하거나 상이하며;R 1 to R 6 and Ar1 are each independently hydrogen, deuterium, halogen, cyano group, nitro group, C 1 ~ C 40 alkyl group, C 2 ~ C 40 alkenyl group, C 2 ~ C 40 alkynyl group, C 3 ~ C 40 cycloalkyl group, 3 to 40 nuclear atoms heterocycloalkyl group, C 6 ~ C 60 aryl group, 5 to 60 nuclear atoms heteroaryl group, C 1 ~ C 40 alkyloxy group, C 6 ~ C 60 aryloxy group, C 3 ~ C 40 alkylsilyl group, C 6 ~ C 60 arylsilyl group, C 1 ~ C 40 alkylboron group, C 6 ~ C 60 arylboron group, C It is selected from the group consisting of a 6 ~C 60 arylphosphanyl group, a C 6 ~C 60 mono- or diarylphosphinyl group, and a C 6 ~C 60 arylamine group; When each of R 1 to R 4 is plural, they are identical to or different from each other;

상기 L의 아릴렌기 및 헤테로아릴렌기와, 상기 R1 내지 R6 및 Ar1의 알킬기, 알케닐기, 알키닐기, 아릴기, 헤테로아릴기, 아릴옥시기, 알킬옥시기, 시클로알킬기, 헤테로시클로알킬기, 아릴아민기, 알킬실릴기, 알킬보론기, 아릴보론기, 아릴포스파닐기, 모노 또는 디아릴포스피닐기 및 아릴실릴기는 각각 독립적으로 중수소, 할로겐, 시아노기, 니트로기, C1~C40의 알킬기, C2~C40의 알케닐기, C2~C40의 알키닐기, C6~C60의 아릴기, 핵원자수 5 내지 60개의 헤테로아릴기, C6~C60의 아릴옥시기, C1~C40의 알킬옥시기, C6~C60의 아릴아민기, C3~C40의 시클로알킬기, 핵원자수 3 내지 40개의 헤테로시클로알킬기, C1~C40의 알킬실릴기, C1~C40의 알킬보론기, C6~C60의 아릴보론기, C6~C60의 아릴포스파닐기, C6~C60의 모노 또는 디아릴포스피닐기 및 C6~C60의 아릴실릴기로 이루어진 군에서 선택된 1종 이상의 치환기로 치환되거나 비치환되고, 복수 개의 치환기로 치환되는 경우, 이들은 서로 동일하거나 상이하다.An arylene group and a heteroarylene group of L, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heteroaryl group, an aryloxy group, an alkyloxy group, a cycloalkyl group, a heterocycloalkyl group of R 1 to R 6 and Ar1, An arylamine group, an alkylsilyl group, an alkylboron group, an arylboron group, an arylphosphanyl group, a mono or diarylphosphinyl group, and an arylsilyl group are each independently deuterium, halogen, cyano group, nitro group, C 1 to C 40 Alkyl group, C 2 ~ C 40 alkenyl group, C 2 ~ C 40 alkynyl group, C 6 ~ C 60 aryl group, heteroaryl group having 5 to 60 nuclear atoms, C 6 ~ C 60 aryloxy group , C 1 ~ C 40 alkyloxy group, C 6 ~ C 60 arylamine group, C 3 ~ C 40 cycloalkyl group, 3 to 40 nuclear atoms heterocycloalkyl group, C 1 ~ C 40 alkylsilyl group , C 1 ~ C 40 alkyl boron group, C 6 ~ C 60 aryl boron group, C 6 ~ C 60 arylphosphanyl group, C 6 ~ C 60 mono or diaryl phosphinyl group and C 6 ~ C When substituted or unsubstituted with one or more substituents selected from the group consisting of 60 arylsilyl groups, and substituted with a plurality of substituents, they are the same as or different from each other.

본 발명의 화합물은 카바졸의 1번 위치에 다이벤조퓨란, 다이벤조사이오펜, 다이메틸플루오렌, 다이페닐플루오렌, 스파이로플루오렌, 잔틴등이 치환된 기본 골격에 질소-함유 헤테로환(예컨대, 피리딘기, 피리미딘기, 트리아진기등)과 같이 전자 흡수성이 큰 전자 끌개기(EWG)가 결합되어 분자 전체가 바이폴라(bipolar) 특성을 갖기 때문에, 정공과 전자의 결합력을 높일 수 있다.The compound of the present invention is a nitrogen-containing heterocycle in the basic skeleton in which dibenzofuran, dibenzothiophene, dimethylfluorene, diphenylfluorene, spirofluorene, xanthine, etc. are substituted at the 1-position of carbazole ( For example, since an electron withdrawing group (EWG) having high electron absorption such as a pyridine group, a pyrimidine group, a triazine group, etc.) is bonded to have a bipolar characteristic, the bonding force between holes and electrons can be increased.

본 발명의 화합물은 카바졸의 1번 위치의 치환 구조에 의해 입체장애(steric hindrance)를 가진다. 이로 인해 높은 삼중항 에너지를 갖고, 발광층에서 생성된 엑시톤이 발광층에 인접하는 전자수송층 또는 정공수송층으로 확산되는 것을 방지할 수 있다. 발광층 내에서 발광에 기여하는 엑시톤의 수가 증가되어 소자의 발광 효율이 개선될 수 있고, 소자의 내구성 및 안정성이 향상되어 소자의 수명이 효율적으로 증가될 수 있다.The compound of the present invention has a steric hindrance due to the substitution structure of the 1-position of carbazole. Due to this, it has high triplet energy and can prevent excitons generated in the light emitting layer from being diffused to an electron transport layer or a hole transport layer adjacent to the light emitting layer. The number of excitons contributing to light emission in the light emitting layer is increased so that the light emitting efficiency of the device can be improved, and the lifespan of the device can be effectively increased by improving durability and stability of the device.

따라서, 본 발명의 화학식 1로 표시되는 화합물은 유기 전계 발광 소자의 유기물층 재료, 바람직하게는 발광층 재료(녹색의 인광 호스트 재료), 전자 수송층/주입층 재료 발광보조층 재료, 전자수송보조층 재료, 더욱 바람직하게는 발광층 재료, 전자 수송층 재료, 전자수송보조층 재료로 사용될 수 있다. 또한, 상기 화학식 1의 화합물을 포함하는 유기 전계 발광 소자는 성능 및 수명 특성이 크게 향상될 수 있고, 이러한 유기 전계 발광 소자가 적용된 풀 칼라 유기 발광 패널도 성능이 극대화될 수 있다.Therefore, the compound represented by Formula 1 of the present invention is an organic material layer material of an organic electroluminescent device, preferably a light emitting layer material (green phosphorescent host material), an electron transport layer / injection layer material, a light emitting auxiliary layer material, an electron transport auxiliary layer material, More preferably, it can be used as a light emitting layer material, an electron transport layer material, and an electron transport auxiliary layer material. In addition, the performance and lifetime characteristics of the organic EL device including the compound of Formula 1 can be greatly improved, and the performance of a full-color organic light emitting panel to which the organic EL device is applied can also be maximized.

본 발명의 바람직한 한 구현 예에 따르면, 상기 화합물은 하기 화학식 2 내지 5 중 어느 하나로 표시될 수 있다:According to a preferred embodiment of the present invention, the compound may be represented by any one of Formulas 2 to 5:

[화학식 2][Formula 2]

Figure pat00004
Figure pat00004

[화학식 3][Formula 3]

Figure pat00005
Figure pat00005

[화학식 4][Formula 4]

Figure pat00006
Figure pat00006

[화학식 5][Formula 5]

Figure pat00007
Figure pat00007

상기 화학식 2 내지 5에서.In Formulas 2 to 5 above.

R1 내지 R4, m, n, Y, L 및 Ar1은 화학식 1에서 정의된 바와 같다.R 1 to R 4 , m, n, Y, L and Ar 1 are as defined in Formula 1.

본 발명의 바람직한 한 구현 예에 따르면, 상기 R1 내지 R4는 각각 독립적으로 C1~C40의 알킬기, C6~C60의 아릴기 및 핵원자수 5 내지 60개의 헤테로아릴기로 이루어진 군에서 선택되고,According to a preferred embodiment of the present invention, the R 1 to R 4 are each independently selected from the group consisting of a C 1 ~ C 40 alkyl group, a C 6 ~ C 60 aryl group, and a heteroaryl group having 5 to 60 nuclear atoms. being selected,

상기 R1 내지 R4의 알킬기, 아릴기 및 헤테로아릴기는 각각 독립적으로 C1~C40의 알킬기, C6~C60의 아릴기 및 핵원자수 5 내지 60개의 헤테로아릴기로 이루어진 군에서 선택된 1종 이상의 치환기로 치환되거나 비치환되고, 복수 개의 치환기로 치환되는 경우, 이들은 서로 동일하거나 상이할 수 있다.The alkyl group, aryl group and heteroaryl group of R 1 to R 4 are each independently selected from the group consisting of a C 1 ~ C 40 alkyl group, a C 6 ~ C 60 aryl group, and a heteroaryl group having 5 to 60 nuclear atoms. When substituted or unsubstituted with one or more substituents and substituted with a plurality of substituents, they may be the same as or different from each other.

본 발명의 바람직한 한 구현 예에 따르면, 상기 R1 내지 R4는 각각 독립적으로 메틸기, 에틸기, 프로필기, 부틸기, 펜틸기, 페닐기, 비페닐기, 터페닐기, 나프탈레닐기, 피리디닐기, 피리미디닐기, 트리아지닐기, 디벤조퓨라닐기, 디벤조티오페닐기, 카바졸릴기, 플루오레닐기, 스피로플루오레닐기 및 디벤조디옥시닐기로 이루어진 군에서 선택되며, According to a preferred embodiment of the present invention, R 1 to R 4 are each independently methyl, ethyl, propyl, butyl, pentyl, phenyl, biphenyl, terphenyl, naphthalenyl, pyridinyl, pyr It is selected from the group consisting of a midinyl group, a triazinyl group, a dibenzofuranyl group, a dibenzothiophenyl group, a carbazolyl group, a fluorenyl group, a spirofluorenyl group, and a dibenzodioxinyl group,

상기 R1 내지 R4는 메틸기, 에틸기, 프로필기, 부틸기, 펜틸기, 페닐기, 비페닐기, 터페닐기, 나프탈레닐기, 피리디닐기, 피리미디닐기, 트리아지닐기, 디벤조퓨라닐기, 디벤조티오페닐기, 카바졸릴기, 플루오레닐기, 스피로플루오레닐기 및 디벤조디옥시닐기는 각각 독립적으로 C1~C40의 알킬기, C6~C60의 아릴아민기, C6~C60의 아릴기 및 핵원자수 5 내지 60개의 헤테로아릴기로 이루어진 군에서 선택된 1종 이상의 치환기로 치환되거나 비치환되고, 복수 개의 치환기로 치환되는 경우, 이들은 서로 동일하거나 상이할 수 있다.R 1 to R 4 are methyl group, ethyl group, propyl group, butyl group, pentyl group, phenyl group, biphenyl group, terphenyl group, naphthalenyl group, pyridinyl group, pyrimidinyl group, triazinyl group, dibenzofuranyl group, di Benzothiophenyl group, carbazolyl group, fluorenyl group, spirofluorenyl group and dibenzodioxinyl group are each independently a C 1 ~ C 40 alkyl group, a C 6 ~ C 60 arylamine group, a C 6 ~ C 60 When unsubstituted or substituted with one or more substituents selected from the group consisting of an aryl group and a heteroaryl group having 5 to 60 nuclear atoms, and substituted with a plurality of substituents, these may be the same as or different from each other.

본 발명의 바람직한 한 구현 예에 따르면, 상기 L은 직접결합이거나, 하기 화학식 A-1 내지 A-4로 이루어진 군에서 선택된 링커일 수 있고, 보다 바람직하게는 직접결합이거나 A-1 또는 A-2로 표시되는 링커일 수 있다:According to a preferred embodiment of the present invention, L may be a direct bond or a linker selected from the group consisting of the following formulas A-1 to A-4, more preferably a direct bond or A-1 or A-2 It can be a linker denoted by:

Figure pat00008
Figure pat00008

상기 화학식 A-1 내지 A-4에서,In the above formulas A-1 to A-4,

*는 결합이 이루어지는 부분을 의미한다.* indicates the part where the coupling is made.

본 발명의 바람직한 한 구현 예에 따르면, 상기 Ar1은 C1~C40의 알킬기, C6~C60의 아릴기 및 핵원자수 5 내지 60개의 헤테로아릴기로 이루어진 군에서 선택되고, According to a preferred embodiment of the present invention, Ar 1 is selected from the group consisting of a C 1 ~ C 40 alkyl group, a C 6 ~ C 60 aryl group, and a heteroaryl group having 5 to 60 nuclear atoms,

상기 Ar1의 알킬기, 아릴기 및 헤테로아릴기는 각각 독립적으로 C1~C40의 알킬기, C6~C60의 아릴기 및 핵원자수 5 내지 60개의 헤테로아릴기로 이루어진 군에서 선택된 1종 이상의 치환기로 치환되거나 비치환되고, 복수 개의 치환기로 치환되는 경우, 이들은 서로 동일하거나 상이하다.The Ar 1 alkyl group, aryl group, and heteroaryl group are each independently one or more substituents selected from the group consisting of a C 1 to C 40 alkyl group, a C 6 to C 60 aryl group, and a heteroaryl group having 5 to 60 nuclear atoms. When substituted or unsubstituted with , and substituted with a plurality of substituents, they are the same as or different from each other.

본 발명의 바람직한 한 구현 예에 따르면, 상기 Ar1은 메틸기, 에틸기, 프로필기, 부틸기, 펜틸기, 페닐기, 비페닐기, 플루오레닐기, 카바졸릴기, 디벤조퓨란일기, 디벤조티오펜일기, 피리디닐기, 피리미디닐기, 트리아지닐기, 나프탈레닐기, 트리아졸로피리디닐기, 퀴놀리닐기, 이소퀴놀리닐기, 시놀리닐기, 퀴녹살리닐기 및 퀴나졸리닐기로 이루어진 군에서 선택되고, According to a preferred embodiment of the present invention, Ar 1 is a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, a phenyl group, a biphenyl group, a fluorenyl group, a carbazolyl group, a dibenzofuranyl group, or a dibenzothiophenyl group. , It is selected from the group consisting of a pyridinyl group, a pyrimidinyl group, a triazinyl group, a naphthalenyl group, a triazolopyridinyl group, a quinolinyl group, an isoquinolinyl group, a cinolinyl group, a quinoxalinyl group, and a quinazolinyl group,

상기 Ar1의 메틸기, 에틸기, 프로필기, 부틸기, 펜틸기, 페닐기, 비페닐기, 플루오레닐기, 카바졸릴기, 디벤조퓨란일기, 디벤조티오펜일기, 피리디닐기, 피리미디닐기, 트리아지닐기, 나프탈레닐기, 트리아졸로피리디닐기, 퀴놀리닐기, 이소퀴놀리닐기, 시놀리닐기, 퀴녹살리닐기 및 퀴나졸리닐기는 각각 독립적으로 C1~C40의 알킬기, C6~C60의 아릴기 및 핵원자수 5 내지 60개의 헤테로아릴기로 이루어진 군에서 선택된 1종 이상의 치환기로 치환되거나 비치환되고, 복수 개의 치환기로 치환되는 경우, 이들은 서로 동일하거나 상이하다.methyl group, ethyl group, propyl group, butyl group, pentyl group, phenyl group, biphenyl group, fluorenyl group, carbazolyl group, dibenzofuranyl group, dibenzothiophenyl group, pyridinyl group, pyrimidinyl group, tria of Ar 1 A jinyl group, a naphthalenyl group, a triazolopyridinyl group, a quinolinyl group, an isoquinolinyl group, a cinolinyl group, a quinoxalinyl group, and a quinazolinyl group are each independently a C 1 to C 40 alkyl group, C 6 to C 60 When unsubstituted or substituted with one or more substituents selected from the group consisting of an aryl group and a heteroaryl group having 5 to 60 nuclear atoms, and substituted with a plurality of substituents, they are the same as or different from each other.

본 발명의 바람직한 한 구현 예에 따르면, 상기 Ar1은 메틸기, 에틸기, 프로필기, 부틸기, 펜틸기, 페닐기, 비페닐기, 플루오레닐기, 카바졸릴기, 디벤조퓨란일기, 디벤조티오펜일기, 피리디닐기, 피리미디닐기, 트리아지닐기, 나프탈레닐기, 트리아졸로피리디닐기, 퀴놀리닐기, 이소퀴놀리닐기, 시놀리닐기, 퀴녹살리닐기 및 퀴나졸리닐기로 이루어진 군에서 선택되고, According to a preferred embodiment of the present invention, Ar 1 is a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, a phenyl group, a biphenyl group, a fluorenyl group, a carbazolyl group, a dibenzofuranyl group, or a dibenzothiophenyl group. , It is selected from the group consisting of a pyridinyl group, a pyrimidinyl group, a triazinyl group, a naphthalenyl group, a triazolopyridinyl group, a quinolinyl group, an isoquinolinyl group, a cinolinyl group, a quinoxalinyl group, and a quinazolinyl group,

상기 Ar1의 메틸기, 에틸기, 프로필기, 부틸기, 펜틸기, 페닐기, 비페닐기, 플루오레닐기, 카바졸릴기, 디벤조퓨란일기, 디벤조티오펜일기, 피리디닐기, 피리미디닐기, 트리아지닐기, 나프탈레닐기, 트리아졸로피리디닐기, 퀴놀리닐기, 이소퀴놀리닐기, 시놀리닐기, 퀴녹살리닐기 및 퀴나졸리닐기는 각각 독립적으로 메틸기, 에틸기, 프로필기, 부틸기, 펜틸기, 페닐기, 비페닐기, 플루오레닐기, 카바졸릴기, 디벤조퓨란일기, 디벤조티오펜일기, 피리디닐기, 피리미디닐기, 트리아지닐기, 나프탈레닐기, 트리아졸로피리디닐기, 퀴놀리닐기, 이소퀴놀리닐기, 시놀리닐기, 퀴녹살리닐기 및 퀴나졸리닐기로 이루어진 군에서 선택된 1종 이상의 치환기로 치환되거나 비치환되고, 복수 개의 치환기로 치환되는 경우, 이들은 서로 동일하거나 상이하다.methyl group, ethyl group, propyl group, butyl group, pentyl group, phenyl group, biphenyl group, fluorenyl group, carbazolyl group, dibenzofuranyl group, dibenzothiophenyl group, pyridinyl group, pyrimidinyl group, tria of Ar 1 Zinyl group, naphthalenyl group, triazolopyridinyl group, quinolinyl group, isoquinolinyl group, cinolinyl group, quinoxalinyl group and quinazolinyl group are each independently a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, A phenyl group, a biphenyl group, a fluorenyl group, a carbazolyl group, a dibenzofuranyl group, a dibenzothiophenyl group, a pyridinyl group, a pyrimidinyl group, a triazinyl group, a naphthalenyl group, a triazolopyridinyl group, a quinolinyl group, When unsubstituted or substituted with one or more substituents selected from the group consisting of an isoquinolinyl group, a cinolinyl group, a quinoxalinyl group, and a quinazolinyl group, and substituted with a plurality of substituents, they are the same as or different from each other.

본 발명의 바람직한 한 구현 예에 따르면, 상기 Ar1은 하기 화학식 6 내지 11 중 어느 하나로 표시되는 치환기일 수 있다:According to a preferred embodiment of the present invention, Ar 1 may be a substituent represented by any one of Formulas 6 to 11 below:

[화학식 6][Formula 6]

Figure pat00009
Figure pat00009

[화학식 7][Formula 7]

Figure pat00010
Figure pat00010

[화학식 8][Formula 8]

Figure pat00011
Figure pat00011

[화학식 9][Formula 9]

Figure pat00012
Figure pat00012

[화학식 10][Formula 10]

Figure pat00013
Figure pat00013

[화학식 11][Formula 11]

Figure pat00014
Figure pat00014

상기 화학식 6 내지 11에서,In Formulas 6 to 11,

*은 결합이 이루어지는 부분을 의미하고;* indicates the part where the bond is made;

Z1 내지 Z5는 각각 독립적으로 N 또는 C(R7)이며;Z 1 to Z 5 are each independently N or C (R 7 );

q는 0 내지 4의 정수이며;q is an integer from 0 to 4;

R7은 수소, 중수소, 할로겐, 시아노기, 니트로기, C1~C40의 알킬기, C2~C40의 알케닐기, C2~C40의 알키닐기, C3~C40의 시클로알킬기, 핵원자수 3 내지 40개의 헤테로시클로알킬기, C6~C60의 아릴기, 핵원자수 5 내지 60개의 헤테로아릴기, C1~C40의 알킬옥시기, C6~C60의 아릴옥시기, C3~C40의 알킬실릴기, C6~C60의 아릴실릴기, C1~C40의 알킬보론기, C6~C60의 아릴보론기, C6~C60의 아릴포스파닐기, C6~C60의 모노 또는 디아릴포스피닐기 및 C6~C60의 아릴아민기로 이루어진 군에서 선택되거나, 인접하는 기와 결합하여 축합 고리를 형성하고, 상기 R7이 복수 개인 경우 이들은 서로 동일하거나 상이하며;R 7 is hydrogen, heavy hydrogen, halogen, cyano group, nitro group, C 1 ~ C 40 alkyl group, C 2 ~ C 40 alkenyl group, C 2 ~ C 40 alkynyl group, C 3 ~ C 40 cycloalkyl group, Heterocycloalkyl group having 3 to 40 nuclear atoms, C 6 ~ C 60 aryl group, heteroaryl group having 5 to 60 nuclear atoms, C 1 ~ C 40 alkyloxy group, C 6 ~ C 60 aryloxy group , C 3 ~ C 40 alkylsilyl group, C 6 ~ C 60 arylsilyl group, C 1 ~ C 40 alkylboron group, C 6 ~ C 60 arylboron group, C 6 ~ C 60 aryl phospha It is selected from the group consisting of a yl group, a C 6 ~ C 60 mono or diarylphosphinyl group, and a C 6 ~ C 60 arylamine group, or is combined with an adjacent group to form a condensed ring, and when the R 7 is plural, they are identical to or different from each other;

R8 및 R9는 각각 독립적으로 수소, 중수소, 할로겐, 시아노기, 니트로기, C1~C40의 알킬기, C2~C40의 알케닐기, C2~C40의 알키닐기, C3~C40의 시클로알킬기, 핵원자수 3 내지 40개의 헤테로시클로알킬기, C6~C60의 아릴기, 핵원자수 5 내지 60개의 헤테로아릴기, C1~C40의 알킬옥시기, C6~C60의 아릴옥시기, C3~C40의 알킬실릴기, C6~C60의 아릴실릴기, C1~C40의 알킬보론기, C6~C60의 아릴보론기, C6~C60의 아릴포스파닐기, C6~C60의 모노 또는 디아릴포스피닐기 및 C6~C60의 아릴아민기로 이루어진 군에서 선택되거나, 인접하는 기와 결합하여 축합 고리를 형성하고, 상기 R8이 복수 개인 경우 이들은 서로 동일하거나 상이하며; R 8 and R 9 are each independently hydrogen, deuterium, halogen, cyano group, nitro group, C 1 ~ C 40 alkyl group, C 2 ~ C 40 alkenyl group, C 2 ~ C 40 alkynyl group, C 3 ~ C 40 cycloalkyl group, 3 to 40 nuclear atoms heterocycloalkyl group, C 6 ~ C 60 aryl group, 5 to 60 nuclear atoms heteroaryl group, C 1 ~ C 40 alkyloxy group, C 6 ~ C 60 aryloxy group, C 3 ~ C 40 alkylsilyl group, C 6 ~ C 60 arylsilyl group, C 1 ~ C 40 alkylboron group, C 6 ~ C 60 arylboron group, C 6 ~ It is selected from the group consisting of a C 60 arylphosphanyl group, a C 6 ~ C 60 mono- or diarylphosphinyl group, and a C 6 ~ C 60 arylamine group, or is combined with an adjacent group to form a condensed ring, wherein the R When 8 is plural, they are the same as or different from each other;

상기 R7 내지 R9의 알킬기, 알케닐기, 알키닐기, 아릴기, 헤테로아릴기, 아릴옥시기, 알킬옥시기, 시클로알킬기, 헤테로시클로알킬기, 아릴아민기, 알킬실릴기, 알킬보론기, 아릴보론기, 아릴포스파닐기, 모노 또는 디아릴포스피닐기 및 아릴실릴기는 각각 독립적으로 중수소, 할로겐, 시아노기, 니트로기, C1~C40의 알킬기, C2~C40의 알케닐기, C2~C40의 알키닐기, C6~C60의 아릴기, 핵원자수 5 내지 60개의 헤테로아릴기, C6~C60의 아릴옥시기, C1~C40의 알킬옥시기, C6~C60의 아릴아민기, C3~C40의 시클로알킬기, 핵원자수 3 내지 40개의 헤테로시클로알킬기, C1~C40의 알킬실릴기, C1~C40의 알킬보론기, C6~C60의 아릴보론기, C6~C60의 아릴포스파닐기, C6~C60의 모노 또는 디아릴포스피닐기 및 C6~C60의 아릴실릴기로 이루어진 군에서 선택된 1종 이상의 치환기로 치환되거나 비치환되고, 복수 개의 치환기로 치환되는 경우, 이들은 서로 동일하거나 상이하다.An alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heteroaryl group, an aryloxy group, an alkyloxy group, a cycloalkyl group, a heterocycloalkyl group, an arylamine group, an alkylsilyl group, an alkylboron group, and an aryl of R 7 to R 9 A boron group, an arylphosphanyl group, a mono- or diarylphosphinyl group, and an arylsilyl group are each independently deuterium, halogen, cyano group, nitro group, C 1 ~ C 40 alkyl group, C 2 ~ C 40 alkenyl group, C 2 ~ C 40 alkynyl group, C 6 ~ C 60 aryl group, heteroaryl group having 5 to 60 nuclear atoms, C 6 ~ C 60 aryloxy group, C 1 ~ C 40 alkyloxy group, C 6 ~C 60 arylamine group, C 3 ~C 40 cycloalkyl group, 3 to 40 nuclear atoms heterocycloalkyl group, C 1 ~C 40 alkylsilyl group, C 1 ~C 40 alkyl boron group, C 6 ~ C 60 arylboron group, C 6 ~ C 60 arylphosphanyl group, C 6 ~ C 60 mono or diarylphosphinyl group, and C 6 ~ C 60 arylsilyl group at least one selected from the group consisting of When substituted or unsubstituted with , and substituted with a plurality of substituents, they are the same as or different from each other.

본 발명의 바람직한 한 구현 예에 따르면, 상기 R7 내지 R9는 각각 독립적으로 C1~C40의 알킬기, C6~C60의 아릴기 및 핵원자수 5 내지 60개의 헤테로아릴기로 이루어진 군에서 선택되고,According to a preferred embodiment of the present invention, the R 7 to R 9 are each independently selected from the group consisting of a C 1 ~ C 40 alkyl group, a C 6 ~ C 60 aryl group, and a heteroaryl group having 5 to 60 nuclear atoms. being selected,

상기 R7 내지 R9의 알킬기, 아릴기 및 헤테로아릴기는 각각 독립적으로 C1~C40의 알킬기, C6~C60의 아릴기 및 핵원자수 5 내지 60개의 헤테로아릴기로 이루어진 군에서 선택된 1종 이상의 치환기로 치환되거나 비치환되고, 복수 개의 치환기로 치환되는 경우, 이들은 서로 동일하거나 상이하다.The alkyl group, aryl group and heteroaryl group of R 7 to R 9 are each independently selected from the group consisting of a C 1 ~ C 40 alkyl group, a C 6 ~ C 60 aryl group, and a heteroaryl group having 5 to 60 nuclear atoms. When substituted or unsubstituted with one or more substituents and substituted with a plurality of substituents, they are the same as or different from each other.

본 발명의 바람직한 한 구현 예에 따르면, 상기 R7 내지 R9는 각각 독립적으로 메틸기, 에틸기, 프로필기, 부틸기, 펜틸기, 페닐기, 비페닐기, 피리디닐기, 피리미디닐기 및 트리아지닐기로 이루어진 군에서 선택되고,According to a preferred embodiment of the present invention, the R 7 to R 9 are each independently composed of a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, a phenyl group, a biphenyl group, a pyridinyl group, a pyrimidinyl group, and a triazinyl group. selected from the group,

상기 R7 내지 R9의 메틸기, 에틸기, 프로필기, 부틸기, 펜틸기, 페닐기, 비페닐기, 피리디닐기, 피리미디닐기 및 트리아지닐기는 각각 독립적으로 C1~C40의 알킬기, C6~C60의 아릴기 및 핵원자수 5 내지 60개의 헤테로아릴기로 이루어진 군에서 선택된 1종 이상의 치환기로 치환되거나 비치환되고, 복수 개의 치환기로 치환되는 경우, 이들은 서로 동일하거나 상이하다.The methyl group, ethyl group, propyl group, butyl group, pentyl group, phenyl group, biphenyl group, pyridinyl group, pyrimidinyl group and triazinyl group of R 7 to R 9 are each independently a C 1 ~ C 40 alkyl group, C 6 ~ When unsubstituted or substituted with one or more substituents selected from the group consisting of a C 60 aryl group and a heteroaryl group having 5 to 60 nuclear atoms, and substituted with a plurality of substituents, they are the same as or different from each other.

*본 발명의 바람직한 한 구현 예에 따르면, 상기 R7 내지 R9는 각각 독립적으로 메틸기, 에틸기, 프로필기, 부틸기, 펜틸기, 페닐기, 비페닐기, 피리디닐기, 피리미디닐기 및 트리아지닐기로 이루어진 군에서 선택되고,* According to a preferred embodiment of the present invention, R 7 to R 9 are each independently a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, a phenyl group, a biphenyl group, a pyridinyl group, a pyrimidinyl group, and a triazinyl group. is selected from the group consisting of

상기 R7 내지 R9의 메틸기, 에틸기, 프로필기, 부틸기, 펜틸기, 페닐기, 비페닐기, 피리디닐기, 피리미디닐기 및 트리아지닐기는 각각 독립적으로 메틸기, 에틸기, 프로필기, 부틸기, 펜틸기, 페닐기, 비페닐기, 피리디닐기, 피리미디닐기 및 트리아지닐기로 이루어진 군에서 선택된 1종 이상의 치환기로 치환되거나 비치환되고, 복수 개의 치환기로 치환되는 경우, 이들은 서로 동일하거나 상이하다. A methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, a phenyl group, a biphenyl group, a pyridinyl group, a pyrimidinyl group, and a triazinyl group of R 7 to R 9 are each independently a methyl group, an ethyl group, a propyl group, a butyl group, a phen When unsubstituted or substituted with one or more substituents selected from the group consisting of a ethyl group, a phenyl group, a biphenyl group, a pyridinyl group, a pyrimidinyl group, and a triazinyl group, and substituted with a plurality of substituents, they are the same as or different from each other.

본 발명의 바람직한 한 구현 예에 따르면, 상기 화학식 6으로 표시되는 치환기는 하기 화학식 12로 표시되는 치환기일 수 있다:According to a preferred embodiment of the present invention, the substituent represented by Formula 6 may be a substituent represented by Formula 12 below:

[화학식 12][Formula 12]

Figure pat00015
Figure pat00015

상기 화학식 12에서,In Formula 12,

*은 결합이 이루어지는 부분을 의미하고;* indicates the part where the bond is made;

R10 및 R11은 각각 독립적으로 수소, 중수소, 할로겐, 시아노기, 니트로기, C1~C40의 알킬기, C2~C40의 알케닐기, C2~C40의 알키닐기, C3~C40의 시클로알킬기, 핵원자수 3 내지 40개의 헤테로시클로알킬기, C6~C60의 아릴기, 핵원자수 5 내지 60개의 헤테로아릴기, C1~C40의 알킬옥시기, C6~C60의 아릴옥시기, C3~C40의 알킬실릴기, C6~C60의 아릴실릴기, C1~C40의 알킬보론기, C6~C60의 아릴보론기, C6~C60의 아릴포스파닐기, C6~C60의 모노 또는 디아릴포스피닐기 및 C6~C60의 아릴아민기로 이루어진 군에서 선택되거며; R 10 and R 11 are each independently hydrogen, deuterium, halogen, cyano group, nitro group, C 1 ~ C 40 alkyl group, C 2 ~ C 40 alkenyl group, C 2 ~ C 40 alkynyl group, C 3 ~ C 40 cycloalkyl group, 3 to 40 nuclear atoms heterocycloalkyl group, C 6 ~ C 60 aryl group, 5 to 60 nuclear atoms heteroaryl group, C 1 ~ C 40 alkyloxy group, C 6 ~ C 60 aryloxy group, C 3 ~ C 40 alkylsilyl group, C 6 ~ C 60 arylsilyl group, C 1 ~ C 40 alkylboron group, C 6 ~ C 60 arylboron group, C 6 ~ It is selected from the group consisting of a C 60 arylphosphanyl group, a C 6 ~ C 60 mono- or diarylphosphinyl group, and a C 6 ~ C 60 arylamine group;

상기 R10 및 R11의 알킬기, 알케닐기, 알키닐기, 아릴기, 헤테로아릴기, 아릴옥시기, 알킬옥시기, 시클로알킬기, 헤테로시클로알킬기, 아릴아민기, 알킬실릴기, 알킬보론기, 아릴보론기, 아릴포스파닐기, 모노 또는 디아릴포스피닐기 및 아릴실릴기는 각각 독립적으로 중수소, 할로겐, 시아노기, 니트로기, C1~C40의 알킬기, C2~C40의 알케닐기, C2~C40의 알키닐기, C6~C60의 아릴기, 핵원자수 5 내지 60개의 헤테로아릴기, C6~C60의 아릴옥시기, C1~C40의 알킬옥시기, C6~C60의 아릴아민기, C3~C40의 시클로알킬기, 핵원자수 3 내지 40개의 헤테로시클로알킬기, C1~C40의 알킬실릴기, C1~C40의 알킬보론기, C6~C60의 아릴보론기, C6~C60의 아릴포스파닐기, C6~C60의 모노 또는 디아릴포스피닐기 및 C6~C60의 아릴실릴기로 이루어진 군에서 선택된 1종 이상의 치환기로 치환되거나 비치환되고, 복수 개의 치환기로 치환되는 경우, 이들은 서로 동일하거나 상이하며;An alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heteroaryl group, an aryloxy group, an alkyloxy group, a cycloalkyl group, a heterocycloalkyl group, an arylamine group, an alkylsilyl group, an alkylboron group, and an aryl of R 10 and R 11 A boron group, an arylphosphanyl group, a mono- or diarylphosphinyl group, and an arylsilyl group are each independently deuterium, halogen, cyano group, nitro group, C 1 ~ C 40 alkyl group, C 2 ~ C 40 alkenyl group, C 2 ~ C 40 alkynyl group, C 6 ~ C 60 aryl group, heteroaryl group having 5 to 60 nuclear atoms, C 6 ~ C 60 aryloxy group, C 1 ~ C 40 alkyloxy group, C 6 ~C 60 arylamine group, C 3 ~C 40 cycloalkyl group, 3 to 40 nuclear atoms heterocycloalkyl group, C 1 ~C 40 alkylsilyl group, C 1 ~C 40 alkyl boron group, C 6 ~ C 60 arylboron group, C 6 ~ C 60 arylphosphanyl group, C 6 ~ C 60 mono or diarylphosphinyl group, and C 6 ~ C 60 arylsilyl group at least one selected from the group consisting of When substituted or unsubstituted with , and substituted with a plurality of substituents, they are the same as or different from each other;

Z1, Z3 및 Z5은 화학식 6에서 정의된 바와 같다. Z 1 , Z 3 and Z 5 are as defined in formula (6).

본 발명의 바람직한 한 구현 예에 따르면, 상기 화학식 6으로 표시되는 치환기는 하기 화학식 B-1 내지 B-4 중 어느 하나로 표시되는 치환기일 수 있다:According to a preferred embodiment of the present invention, the substituent represented by Chemical Formula 6 may be a substituent represented by any one of the following Chemical Formulas B-1 to B-4:

Figure pat00016
Figure pat00016

상기 화학식 B-1 내지 B-4에서, In the above formulas B-1 to B-4,

*은 결합이 이루어지는 부분을 의미하고,* indicates the part where the coupling is made,

R10 및 R11은 각각 독립적으로 수소, 중수소, 할로겐, 시아노기, 니트로기, C1~C40의 알킬기, C2~C40의 알케닐기, C2~C40의 알키닐기, C3~C40의 시클로알킬기, 핵원자수 3 내지 40개의 헤테로시클로알킬기, C6~C60의 아릴기, 핵원자수 5 내지 60개의 헤테로아릴기, C1~C40의 알킬옥시기, C6~C60의 아릴옥시기, C3~C40의 알킬실릴기, C6~C60의 아릴실릴기, C1~C40의 알킬보론기, C6~C60의 아릴보론기, C6~C60의 아릴포스파닐기, C6~C60의 모노 또는 디아릴포스피닐기 및 C6~C60의 아릴아민기로 이루어진 군에서 선택되며;R 10 and R 11 are each independently hydrogen, deuterium, halogen, cyano group, nitro group, C 1 ~ C 40 alkyl group, C 2 ~ C 40 alkenyl group, C 2 ~ C 40 alkynyl group, C 3 ~ C 40 cycloalkyl group, 3 to 40 nuclear atoms heterocycloalkyl group, C 6 ~ C 60 aryl group, 5 to 60 nuclear atoms heteroaryl group, C 1 ~ C 40 alkyloxy group, C 6 ~ C 60 aryloxy group, C 3 ~ C 40 alkylsilyl group, C 6 ~ C 60 arylsilyl group, C 1 ~ C 40 alkylboron group, C 6 ~ C 60 arylboron group, C 6 ~ It is selected from the group consisting of a C 60 arylphosphanyl group, a C 6 ~ C 60 mono- or diarylphosphinyl group, and a C 6 ~ C 60 arylamine group;

상기 R10 및 R11의 알킬기, 알케닐기, 알키닐기, 아릴기, 헤테로아릴기, 아릴옥시기, 알킬옥시기, 시클로알킬기, 헤테로시클로알킬기, 아릴아민기, 알킬실릴기, 알킬보론기, 아릴보론기, 아릴포스파닐기, 모노 또는 디아릴포스피닐기 및 아릴실릴기는 각각 독립적으로 중수소, 할로겐, 시아노기, 니트로기, C1~C40의 알킬기, C2~C40의 알케닐기, C2~C40의 알키닐기, C6~C60의 아릴기, 핵원자수 5 내지 60개의 헤테로아릴기, C6~C60의 아릴옥시기, C1~C40의 알킬옥시기, C6~C60의 아릴아민기, C3~C40의 시클로알킬기, 핵원자수 3 내지 40개의 헤테로시클로알킬기, C1~C40의 알킬실릴기, C1~C40의 알킬보론기, C6~C60의 아릴보론기, C6~C60의 아릴포스파닐기, C6~C60의 모노 또는 디아릴포스피닐기 및 C6~C60의 아릴실릴기로 이루어진 군에서 선택된 1종 이상의 치환기로 치환되거나 비치환되고, 복수 개의 치환기로 치환되는 경우, 이들은 서로 동일하거나 상이하다.An alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heteroaryl group, an aryloxy group, an alkyloxy group, a cycloalkyl group, a heterocycloalkyl group, an arylamine group, an alkylsilyl group, an alkylboron group, and an aryl of R 10 and R 11 A boron group, an arylphosphanyl group, a mono- or diarylphosphinyl group, and an arylsilyl group are each independently deuterium, halogen, cyano group, nitro group, C 1 ~ C 40 alkyl group, C 2 ~ C 40 alkenyl group, C 2 ~ C 40 alkynyl group, C 6 ~ C 60 aryl group, heteroaryl group having 5 to 60 nuclear atoms, C 6 ~ C 60 aryloxy group, C 1 ~ C 40 alkyloxy group, C 6 ~C 60 arylamine group, C 3 ~C 40 cycloalkyl group, 3 to 40 nuclear atoms heterocycloalkyl group, C 1 ~C 40 alkylsilyl group, C 1 ~C 40 alkyl boron group, C 6 ~ C 60 arylboron group, C 6 ~ C 60 arylphosphanyl group, C 6 ~ C 60 mono or diarylphosphinyl group, and C 6 ~ C 60 arylsilyl group at least one selected from the group consisting of When substituted or unsubstituted with , and substituted with a plurality of substituents, they are the same as or different from each other.

본 발명의 바람직한 한 구현 예에 따르면, 상기 R10 및 R11은 각각 독립적으로 C1~C40의 알킬기, C6~C60의 아릴기 및 핵원자수 5 내지 60개의 헤테로아릴기로 이루어진 군에서 선택되며;According to a preferred embodiment of the present invention, R 10 and R 11 are each independently selected from the group consisting of a C 1 ~ C 40 alkyl group, a C 6 ~ C 60 aryl group, and a heteroaryl group having 5 to 60 nuclear atoms. selected;

상기 R10 및 R11의 알킬기, 아릴기 및 헤테로아릴기는 각각 독립적으로 C1~C40의 알킬기, C6~C60의 아릴기 및 핵원자수 5 내지 60개의 헤테로아릴기로 이루어진 군에서 선택된 1종 이상의 치환기로 치환되거나 비치환되고, 복수 개의 치환기로 치환되는 경우, 이들은 서로 동일하거나 상이하다. The alkyl group, aryl group, and heteroaryl group of R 10 and R 11 are each independently selected from the group consisting of a C 1 ~ C 40 alkyl group, a C 6 ~ C 60 aryl group, and a heteroaryl group having 5 to 60 nuclear atoms. When substituted or unsubstituted with one or more substituents and substituted with a plurality of substituents, they are the same as or different from each other.

본 발명의 바람직한 한 구현 예에 따르면, 상기 R10 및 R11은 각각 독립적으로 페닐기, 비페닐기, 피리디닐기, 피리미디닐기, 디벤조퓨라닐기, 카바졸릴기, 플루오레닐기 및 디벤조티오페닐기로 이루어진 군에서 선택되고, According to a preferred embodiment of the present invention, R 10 and R 11 are each independently a phenyl group, a biphenyl group, a pyridinyl group, a pyrimidinyl group, a dibenzofuranyl group, a carbazolyl group, a fluorenyl group, and a dibenzothiophenyl group. is selected from the group consisting of

상기 R10 및 R11의 페닐기, 비페닐기, 피리디닐기, 피리미디닐기, 디벤조퓨라닐기, 카바졸릴기, 플루오레닐기 및 디벤조티오페닐기는 각각 독립적으로 C1~C40의 알킬기, C6~C60의 아릴기 및 핵원자수 5 내지 60개의 헤테로아릴기로 이루어진 군에서 선택된 1종 이상의 치환기로 치환되거나 비치환되고, 복수 개의 치환기로 치환되는 경우, 이들은 서로 동일하거나 상이하다. of the R 10 and R 11 A phenyl group, a biphenyl group, a pyridinyl group, a pyrimidinyl group, a dibenzofuranyl group, a carbazolyl group, a fluorenyl group, and a dibenzothiophenyl group are each independently a C 1 ~ C 40 alkyl group or a C 6 ~ C 60 aryl group. And when substituted or unsubstituted with one or more substituents selected from the group consisting of a heteroaryl group having 5 to 60 nuclear atoms, and substituted with a plurality of substituents, they are the same as or different from each other.

본 발명의 바람직한 한 구현 예에 따르면, 상기 R10 및 R11은 각각 독립적으로 페닐기, 비페닐기, 피리디닐기, 피리미디닐기, 디벤조퓨라닐기, 카바졸릴기, 플루오레닐기 및 디벤조티오페닐기로 이루어진 군에서 선택되고, According to a preferred embodiment of the present invention, R 10 and R 11 are each independently a phenyl group, a biphenyl group, a pyridinyl group, a pyrimidinyl group, a dibenzofuranyl group, a carbazolyl group, a fluorenyl group, and a dibenzothiophenyl group. is selected from the group consisting of

상기 R10 및 R11의 페닐기, 비페닐기, 피리디닐기, 피리미디닐기, 디벤조퓨라닐기, 카바졸릴기, 플루오레닐기 및 디벤조티오페닐기는 각각 독립적으로 메틸기, 에틸기, 프로파닐기, 뷰틸기, 페닐기, 비페닐기, 피리디닐기, 피리미디닐기, 디벤조퓨라닐기, 카바졸릴기, 플루오레닐기 및 디벤조티오페닐기로 이루어진 군에서 선택된 1종 이상의 치환기로 치환되거나 비치환되고, 복수 개의 치환기로 치환되는 경우, 이들은 서로 동일하거나 상이하다.of the R 10 and R 11 A phenyl group, a biphenyl group, a pyridinyl group, a pyrimidinyl group, a dibenzofuranyl group, a carbazolyl group, a fluorenyl group, and a dibenzothiophenyl group are each independently a methyl group, an ethyl group, a propanyl group, a butyl group, a phenyl group, a biphenyl group, When substituted or unsubstituted with one or more substituents selected from the group consisting of a pyridinyl group, a pyrimidinyl group, a dibenzofuranyl group, a carbazolyl group, a fluorenyl group, and a dibenzothiophenyl group, and substituted with a plurality of substituents, these are the same or different from each other

본 발명의 바람직한 한 구현 예에 따르면, 상기 화학식 7로 표시되는 치환기는 하기 화학식 C-1 또는 C-2로 표시되는 치환기일 수 있다:According to a preferred embodiment of the present invention, the substituent represented by Formula 7 may be a substituent represented by Formula C-1 or C-2 below:

Figure pat00017
Figure pat00017

상기 화학식 C-1 또는 C-2 에서, In the formula C-1 or C-2,

*은 결합이 이루어지는 부분을 의미하고,* indicates the part where the coupling is made,

q, R7 및 R8은 화학식 7에서 정의된 바와 같다.q, R 7 and R 8 are as defined in Formula 7.

본 발명의 바람직한 한 구현 예에 따르면, 상기 R7 및 R8은 각각 독립적으로 C1~C40의 알킬기, C6~C60의 아릴기 및 핵원자수 5 내지 60개의 헤테로아릴기로 이루어진 군에서 선택되며;According to a preferred embodiment of the present invention, the R 7 and R 8 are each independently selected from the group consisting of a C 1 ~ C 40 alkyl group, a C 6 ~ C 60 aryl group, and a heteroaryl group having 5 to 60 nuclear atoms. selected;

상기 R7 및 R8의 알킬기, 아릴기 및 헤테로아릴기는 각각 독립적으로 C1~C40의 알킬기, C6~C60의 아릴기 및 핵원자수 5 내지 60개의 헤테로아릴기로 이루어진 군에서 선택된 1종 이상의 치환기로 치환되거나 비치환되고, 복수 개의 치환기로 치환되는 경우, 이들은 서로 동일하거나 상이하다. The alkyl group, aryl group, and heteroaryl group of R 7 and R 8 are each independently selected from the group consisting of a C 1 ~ C 40 alkyl group, a C 6 ~ C 60 aryl group, and a heteroaryl group having 5 to 60 nuclear atoms. When substituted or unsubstituted with one or more substituents and substituted with a plurality of substituents, they are the same as or different from each other.

본 발명의 바람직한 한 구현 예에 따르면, 상기 R7 및 R8은 각각 독립적으로 페닐기, 비페닐기, 피리디닐기, 피리미디닐기, 디벤조퓨라닐기, 카바졸릴기, 플루오레닐기 및 디벤조티오페닐기로 이루어진 군에서 선택되고, According to a preferred embodiment of the present invention, R 7 and R 8 are each independently a phenyl group, a biphenyl group, a pyridinyl group, a pyrimidinyl group, a dibenzofuranyl group, a carbazolyl group, a fluorenyl group, and a dibenzothiophenyl group. is selected from the group consisting of

상기 R7 및 R8의 페닐기, 비페닐기, 피리디닐기, 피리미디닐기, 디벤조퓨라닐기, 카바졸릴기, 플루오레닐기 및 디벤조티오페닐기는 각각 독립적으로 C1~C40의 알킬기, C6~C60의 아릴기 및 핵원자수 5 내지 60개의 헤테로아릴기로 이루어진 군에서 선택된 1종 이상의 치환기로 치환되거나 비치환되고, 복수 개의 치환기로 치환되는 경우, 이들은 서로 동일하거나 상이하다. of the above R 7 and R 8 A phenyl group, a biphenyl group, a pyridinyl group, a pyrimidinyl group, a dibenzofuranyl group, a carbazolyl group, a fluorenyl group, and a dibenzothiophenyl group are each independently a C 1 ~ C 40 alkyl group or a C 6 ~ C 60 aryl group. And when substituted or unsubstituted with one or more substituents selected from the group consisting of a heteroaryl group having 5 to 60 nuclear atoms, and substituted with a plurality of substituents, they are the same as or different from each other.

본 발명의 바람직한 한 구현 예에 따르면, 상기 R7 및 R8은 각각 독립적으로 페닐기, 비페닐기, 피리디닐기, 피리미디닐기, 디벤조퓨라닐기, 카바졸릴기, 플루오레닐기 및 디벤조티오페닐기로 이루어진 군에서 선택되고, According to a preferred embodiment of the present invention, R 7 and R 8 are each independently a phenyl group, a biphenyl group, a pyridinyl group, a pyrimidinyl group, a dibenzofuranyl group, a carbazolyl group, a fluorenyl group, and a dibenzothiophenyl group. is selected from the group consisting of

상기 R7 및 R8의 페닐기, 비페닐기, 피리디닐기, 피리미디닐기, 디벤조퓨라닐기, 카바졸릴기, 플루오레닐기 및 디벤조티오페닐기는 각각 독립적으로 메틸기, 에틸기, 프로파닐기, 뷰틸기, 페닐기, 비페닐기, 피리디닐기, 피리미디닐기, 디벤조퓨라닐기, 카바졸릴기, 플루오레닐기 및 디벤조티오페닐기로 이루어진 군에서 선택된 1종 이상의 치환기로 치환되거나 비치환되고, 복수 개의 치환기로 치환되는 경우, 이들은 서로 동일하거나 상이하다.of the above R 7 and R 8 A phenyl group, a biphenyl group, a pyridinyl group, a pyrimidinyl group, a dibenzofuranyl group, a carbazolyl group, a fluorenyl group, and a dibenzothiophenyl group are each independently a methyl group, an ethyl group, a propanyl group, a butyl group, a phenyl group, a biphenyl group, When substituted or unsubstituted with one or more substituents selected from the group consisting of a pyridinyl group, a pyrimidinyl group, a dibenzofuranyl group, a carbazolyl group, a fluorenyl group, and a dibenzothiophenyl group, and substituted with a plurality of substituents, these are the same or different from each other

본 발명의 화학식 1로 표시되는 화합물은 하기 화합물로 나타낼 수 있으나 이에 한정되는 것은 아니다: The compound represented by Formula 1 of the present invention may be represented by the following compounds, but is not limited thereto:

Figure pat00018
Figure pat00018

Figure pat00019
Figure pat00019

Figure pat00020
Figure pat00020

Figure pat00021
Figure pat00021

Figure pat00022
Figure pat00022

Figure pat00023
Figure pat00023

Figure pat00024
Figure pat00024

Figure pat00025
Figure pat00025

Figure pat00026
Figure pat00026

Figure pat00027
Figure pat00027

Figure pat00028
Figure pat00028

Figure pat00029
Figure pat00029

Figure pat00030
Figure pat00030

Figure pat00031
Figure pat00031

Figure pat00032
Figure pat00032

Figure pat00033
Figure pat00033

Figure pat00034
Figure pat00034

Figure pat00035
Figure pat00035

Figure pat00036
Figure pat00036

Figure pat00037
Figure pat00037

Figure pat00038
Figure pat00038

Figure pat00039
Figure pat00039

Figure pat00040
Figure pat00040

Figure pat00041
Figure pat00041

Figure pat00042
Figure pat00042

Figure pat00043
Figure pat00043

Figure pat00044
Figure pat00044

Figure pat00045
Figure pat00045

Figure pat00046
Figure pat00046

Figure pat00047
Figure pat00047

Figure pat00048
Figure pat00048

Figure pat00049
Figure pat00049

Figure pat00050
Figure pat00050

Figure pat00051
Figure pat00051

Figure pat00052
Figure pat00052

Figure pat00053
Figure pat00053

Figure pat00054
Figure pat00054

본 발명의 화학식 1의 화합물은 일반적인 합성방법에 따라 합성될 수 있다(Chem. Rev., 60:313 (1960); J. Chem. SOC. 4482 (1955); Chem. Rev. 95: 2457 (1995) 등 참조). 본 발명의 화합물에 대한 상세한 합성 과정은 후술하는 합성예에서 구체적으로 기술하도록 한다. The compound of Formula 1 of the present invention can be synthesized according to general synthetic methods ( Chem. Rev. , 60 :313 (1960); J. Chem. SOC . 4482 (1955); Chem. Rev. 95: 2457 (1995). ), etc.). A detailed synthesis process for the compound of the present invention will be described in detail in Synthesis Examples to be described later.

2.2. 유기 전계 발광 소자organic electroluminescent device

한편, 본 발명의 다른 측면은 상기한 본 발명에 따른 화학식 1로 표시되는 화합물을 포함하는 유기 전계 발광 소자(유기 EL 소자)에 관한 것이다.Meanwhile, another aspect of the present invention relates to an organic electroluminescent device (organic EL device) including the compound represented by Formula 1 according to the present invention.

구체적으로, 본 발명은 양극(anode), 음극(cathode), 및 상기 양극과 음극 사이에 개재(介在)된 1층 이상의 유기물층을 포함하는 유기 전계 발광 소자로서, 상기 1층 이상의 유기물층 중 적어도 하나는 상기 화학식 1로 표시되는 화합물을 포함한다. 이때, 상기 화합물은 단독 또는 2 이상 혼합되어 사용될 수 있다.Specifically, the present invention is an organic electroluminescent device comprising an anode, a cathode, and one or more organic material layers interposed between the anode and the cathode, wherein at least one of the one or more organic material layers is It includes the compound represented by Formula 1 above. In this case, the above compounds may be used alone or in combination of two or more.

상기 1층 이상의 유기물층은 정공 주입층, 정공 수송층, 발광층, 발광 보조층, 수명 개선층, 전자 수송층, 전자 수송 보조층 및 전자 주입층 중 어느 하나 이상일 수 있고, 이 중에서 적어도 하나의 유기물층이 상기 화학식 1로 표시되는 화합물을 포함할 수 있다. The one or more organic material layers may be any one or more of a hole injection layer, a hole transport layer, a light emitting layer, a light emitting auxiliary layer, a lifespan improvement layer, an electron transport layer, an electron transport auxiliary layer, and an electron injection layer, and at least one organic material layer among them may be one or more of the above chemical formula. The compound represented by 1 may be included.

전술한 본 발명에 따른 유기 전계 발광 소자의 구조는 특별히 한정되지 않으나, 일 예시로 도 1을 참고하면, 예컨대 서로 마주하는 양극(10)과 음극(20), 그리고 상기 양극(10)과 음극(20) 사이에 위치하는 유기층(30)을 포함한다. 여기서, 상기 유기층(30)은 정공 수송층(31), 발광층(32) 및 전자 수송층(34)을 포함할 수 있다. 또한, 상기 정공 수송층(31)과 발광층(32) 사이에는 정공 수송 보조층(33)을 포함할 수 있으며, 상기 전자 수송층(34)과 발광층(32) 사이에는 전자 수송 보조층(35)을 포함할 수 있다. The structure of the organic electroluminescent device according to the present invention described above is not particularly limited, but referring to FIG. 1 as an example, for example, the anode 10 and the cathode 20 facing each other, and the anode 10 and the cathode ( 20) and an organic layer 30 positioned between them. Here, the organic layer 30 may include a hole transport layer 31 , an emission layer 32 , and an electron transport layer 34 . In addition, a hole transport auxiliary layer 33 may be included between the hole transport layer 31 and the light emitting layer 32, and an electron transport auxiliary layer 35 may be included between the electron transport layer 34 and the light emitting layer 32. can do.

본 발명의 다른 예시로 도 2를 참고하면, 상기 유기층(30)은 정공 수송층(31)과 양극(10)사이에 정공 주입층(37)을 더 포함할 수 있으며, 전자 수송층(34)과 음극(20)사이에는 전자 주입층(36)을 추가로 더 포함할 수 있다. Referring to FIG. 2 as another example of the present invention, the organic layer 30 may further include a hole injection layer 37 between the hole transport layer 31 and the anode 10, and the electron transport layer 34 and the cathode An electron injection layer 36 may be further included between (20).

본 발명에서 상기 정공 수송층(31)과 양극(10) 사이에 적층되는 정공 주입층(37)은 양극으로 사용되는 ITO와, 정공 수송층(31)으로 사용되는 유기물질 사이의 계면 특성을 개선할 뿐만 아니라 그 표면이 평탄하지 않은 ITO의 상부에 도포되어 ITO의 표면을 부드럽게 만들어주는 기능을 하는 층으로, 당 기술분야에서 통상적으로 사용되는 것이면 특별한 제한없이 사용할 수 있으며, 예컨대, 아민 화합물을 사용할 수 있으나 이에 한정되는 것은 아니다.In the present invention, the hole injection layer 37 stacked between the hole transport layer 31 and the anode 10 improves the interface characteristics between ITO used as the anode and the organic material used as the hole transport layer 31. Rather, it is a layer that is applied on top of ITO whose surface is not flat and functions to make the surface of ITO smooth. Anything commonly used in the art can be used without particular limitation, for example, an amine compound can be used. It is not limited to this.

또한, 상기 전자 주입층(36)은 전자 수송층(34)의 상부에 적층되어 음극으로부터의 전자 주입을 용이하게 해주어 궁극적으로 전력효율을 개선시키는 기능을 수행하는 층으로, 당 기술분야에서 통상적으로 사용되는 것이면 특별한 제한없이 사용할 수 있으며, 예컨대, LiF, Liq, NaCl, CsF, Li2O, BaO 등의 물질을 이용할 수 있다. In addition, the electron injection layer 36 is stacked on top of the electron transport layer 34 to facilitate injection of electrons from the cathode to ultimately improve power efficiency, and is commonly used in the art. Any material that can be used can be used without particular limitation, and for example, materials such as LiF, Liq, NaCl, CsF, Li 2 O, and BaO can be used.

또한, 본 발명에서 도면에는 도시하지 않았으나, 상기 정공 수송 보조층(33)과 발광층(32) 사이에 발광 보조층을 더 포함할 수 있다. 상기 발광 보조층은 발광층(32)에 정공을 수송하는 역할을 하면서 유기층(30)의 두께를 조정하는 역할을 할 수 있다. 상기 발광 보조층은 정공 수송 물질을 포함할 수 있고, 정공 수송층(31)과 동일한 물질로 만들어질 수 있다.In addition, although not shown in the drawing, in the present invention, a light emitting auxiliary layer may be further included between the hole transport auxiliary layer 33 and the light emitting layer 32 . The light emitting auxiliary layer may play a role of transporting holes to the light emitting layer 32 and adjusting the thickness of the organic layer 30 . The emission auxiliary layer may include a hole transport material and may be made of the same material as the hole transport layer 31 .

또한, 본 발명에서 도면에는 도시하지 않았으나, 상기 전자 수송 보조층 (35)과 발광층(32) 사이에 수명 개선층을 더 포함할 수 있다. 상기 발광층(32)으로 유기 발광 소자 내에서 이온화 포텐셜 레벨을 타고 이동하는 정공이 수명개선층의 높은 에너지 장벽에 막혀 전자 수송층으로 확산, 또는 이동하지 못해, 결과적으로 정공을 발광층에 제한시키는 기능을 한다. 이렇게 정공을 발광층에 제한시키는 기능은 환원에 의해 전자를 이동시키는 전자 수송층으로 정공이 확산되는 것을 막아, 산화에 의한 비가역적 분해반응을 통한 수명저하 현상을 억제하여, 유기 발광 소자의 수명 개선에 기여할 수 있다.In addition, although not shown in the drawing, a lifespan improvement layer may be further included between the electron transport auxiliary layer 35 and the light emitting layer 32 in the present invention. Holes moving along the ionization potential level in the organic light emitting layer 32 are blocked by the high energy barrier of the lifetime improvement layer and cannot diffuse or move to the electron transport layer, resulting in a function of confining holes to the light emitting layer. . This function of restricting holes in the light emitting layer prevents holes from diffusing into the electron transport layer that moves electrons by reduction, suppresses the phenomenon of lifespan degradation through irreversible decomposition caused by oxidation, and contributes to improving the lifespan of the organic light emitting device. can

본 발명의 화합물은 카바졸의 1번 위치에 다이벤조퓨란, 다이벤조사이오펜, 다이메틸플루오렌, 다이페닐플루오렌, 스파이로플루오렌, 잔틴등이 치환된 기본 골격에 질소-함유 헤테로환(예컨대, 피리딘기, 피리미딘기, 트리아진기등)과 같이 전자 흡수성이 큰 전자 끌개기(EWG)가 결합된 것이 구조적인 특징적이며, 저전압 구동과 고굴절률의 특성들을 가지며 이로 인한 고효율과 장수명의 물리적 특징들을 나타낸다.The compound of the present invention is a nitrogen-containing heterocycle in the basic skeleton in which dibenzofuran, dibenzothiophene, dimethylfluorene, diphenylfluorene, spirofluorene, xanthine, etc. are substituted at the 1-position of carbazole ( For example, pyridine group, pyrimidine group, triazine group, etc.) is structurally characterized by the combination of an electron withdrawing group (EWG) with high electron absorption, and has characteristics of low voltage drive and high refractive index, resulting in high efficiency and long lifespan. indicate features.

이로 인해, 본 발명의 대표 청구 구조인 화학식 1로 표시되는 화합물은 발광 특성이 우수하기 때문에, 유기 전계 발광 소자의 유기물층인 정공 주입층, 정공 수송층, 발광층, 전자 수송층 및 전자 주입층 중 어느 하나의 재료로 사용될 수 있다. 바람직하게는 정공 수송층 및 정공 보조 수송층 재료로 사용될 수 있다.For this reason, since the compound represented by Formula 1, which is a representative structure of the present invention, has excellent light emitting properties, it can be applied to any one of the hole injection layer, the hole transport layer, the light emitting layer, the electron transport layer, and the electron injection layer, which are the organic material layers of the organic electroluminescent device. material can be used. Preferably, it can be used as a hole transport layer and a hole auxiliary transport layer material.

또한, 본 발명에서 상기 유기 전계 발광 소자는 상기한 바와 같이 양극, 1층 이상의 유기물층 및 음극이 순차적으로 적층될 뿐만 아니라, 전극과 유기물층 계면에 절연층 또는 접착층을 추가로 포함할 수 있다. In addition, in the present invention, the organic electroluminescent device may include an anode, one or more organic material layers, and a cathode sequentially stacked as described above, and may further include an insulating layer or an adhesive layer at an interface between the electrode and the organic material layer.

본 발명의 유기 전계 발광 소자는 상기 유기물층 중 적어도 하나 이상(예컨대, 전자 수송 보조층)이 상기 화학식 1로 표시되는 화합물을 포함하도록 형성하는 것을 제외하고는, 당 기술 분야에 알려져 있는 재료 및 방법을 이용하여 다른 유기물층 및 전극을 형성하여 제조될 수 있다.The organic electroluminescent device of the present invention uses materials and methods known in the art, except that at least one or more of the organic material layers (eg, an electron transport auxiliary layer) is formed to include the compound represented by Formula 1. It can be prepared by forming another organic material layer and an electrode by using.

상기 유기물층은 진공 증착법이나 용액 도포법에 의하여 형성될 수 있다. 상기 용액 도포법의 예로는 스핀 코팅, 딥코팅, 닥터 블레이딩, 잉크젯 프린팅 또는 열 전사법 등이 있으나, 이에 한정되지 않는다.The organic layer may be formed by a vacuum deposition method or a solution coating method. Examples of the solution application method include, but are not limited to, spin coating, dip coating, doctor blading, inkjet printing, or thermal transfer.

본 발명에서 사용 가능한 기판으로는 특별히 한정되지 않으며, 실리콘 웨이퍼, 석영, 유리판, 금속판, 플라스틱 필름 및 시트 등이 사용될 수 있다.The substrate usable in the present invention is not particularly limited, and silicon wafers, quartz, glass plates, metal plates, plastic films and sheets, and the like may be used.

또, 양극 물질로는 예컨대 정공 주입이 원활하도록 일 함수가 높은 도전체로 만들어질 수 있으며, 바나듐, 크롬, 구리, 아연, 금과 같은 금속 또는 이들의 합금; 아연산화물, 인듐산화물, 인듐 주석 산화물(ITO), 인듐 아연 산화물(IZO)과 같은 금속 산화물; ZnO:Al 또는 SnO2:Sb와 같은 금속과 산화물의 조합; 폴리티오펜, 폴리(3-메틸티오펜), 폴리[3,4-(에틸렌-1,2-디옥시)티오펜](PEDT), 폴리피롤 또는 폴리아닐린과 같은 전도성 고분자; 및 카본블랙 등이 있으나, 이에 한정되지는 않는다.In addition, the anode material may be made of, for example, a conductor having a high work function so as to facilitate hole injection, and may include metals such as vanadium, chromium, copper, zinc, and gold, or alloys thereof; metal oxides such as zinc oxide, indium oxide, indium tin oxide (ITO), and indium zinc oxide (IZO); combinations of metals and oxides such as ZnO:Al or SnO 2 :Sb; conductive polymers such as polythiophene, poly(3-methylthiophene), poly[3,4-(ethylene-1,2-dioxy)thiophene] (PEDT), polypyrrole or polyaniline; and carbon black, but are not limited thereto.

또, 음극 물질로는 예컨대 전자 주입이 원활하도록 일 함수가 낮은 도전체로 만들어질 수 있으며, 마그네슘, 칼슘, 나트륨, 칼륨, 타이타늄, 인듐, 이트륨, 리튬, 가돌리늄, 알루미늄, 은, 주석, 또는 납과 같은 금속 또는 이들의 합금; 및 LiF/Al 또는 LiO2/Al과 같은 다층 구조 물질 등이 있으나, 이에 한정되지는 않는다.In addition, the anode material may be made of, for example, a conductor with a low work function so that electron injection is smooth, and magnesium, calcium, sodium, potassium, titanium, indium, yttrium, lithium, gadolinium, aluminum, silver, tin, or lead the same metals or alloys thereof; and multi-layered materials such as LiF/Al or LiO 2 /Al, but are not limited thereto.

이하 본 발명을 실시예를 통하여 상세히 설명하면 다음과 같다. 단, 하기 실시예는 본 발명을 예시하는 것일 뿐, 본 발명이 하기 실시예에 의해 한정되는 것은 아니다.Hereinafter, the present invention will be described in detail through examples. However, the following examples are only to illustrate the present invention, and the present invention is not limited by the following examples.

실시예Example

[준비예 1] [Preparation Example 1]

1-(디벤조[b,d]퓨란-4-일)-9H-카바졸 의 합성Synthesis of 1-(dibenzo[b,d]furan-4-yl)-9H-carbazole

Figure pat00055
Figure pat00055

질소 기류 하에서 1-브로모-9H-카바졸 (50g, 203mmol), 2-(디벤조[b,d]퓨란-4-일)-4,4,5,5-테트라메틸-1,3,2-디옥사보로란 (65.7g, 223mmol), K2CO3 (56.1g, 406mmol), Pd(PPh3)4 (11.7g, 10.15mmol)와 200ml/200ml/40ml의 Toluene/EtOH/H2O를 넣고 100℃에서 8시간 동안 교반하였다. 반응 종결 후 메틸렌클로라이드로 추출하고 감압조건에서 농축한 후 컬럼크로마토그래피를 이용하여 목적 화합물을 59.5g(88%)얻었다.1-bromo-9H-carbazole (50 g, 203 mmol), 2-(dibenzo[b,d]furan-4-yl)-4,4,5,5-tetramethyl-1,3, 2-dioxaborolane (65.7g, 223mmol), K 2 CO 3 (56.1g, 406mmol), Pd(PPh 3 ) 4 (11.7g, 10.15mmol) and 200ml/200ml/40ml of Toluene/EtOH/H 2 O was added and stirred at 100°C for 8 hours. After completion of the reaction, extraction with methylene chloride, concentration under reduced pressure, and 59.5 g (88%) of the target compound were obtained by column chromatography.

GC-Mass (이론치: 333.12g/mol, 측정치: 333.39 g/mol)GC-Mass (Theory: 333.12 g/mol, Measured: 333.39 g/mol)

1H-NMR: 11.7 (br, 1H), 8.29~8.19(d, 2H), 8.06~7.91(m, 4H), 7.63~7.20(m, 8H), 7.28(m, 4H)1H-NMR: 11.7 (br, 1H), 8.29 to 8.19 (d, 2H), 8.06 to 7.91 (m, 4H), 7.63 to 7.20 (m, 8H), 7.28 (m, 4H)

[준비예 2][Preparation Example 2]

1-(디벤조[b,d]퓨란-3-일)-9H-카바졸의 합성Synthesis of 1-(dibenzo[b,d]furan-3-yl)-9H-carbazole

Figure pat00056
Figure pat00056

반응물로 2-(디벤조[b,d]퓨란-3-일)-4,4,5,5-테트라메틸-1,3,2-디옥사보로란을 사용한 것을 제외하고는 [준비예 1]과 동일한 과정을 수행하여 목적 화합물 38g을 얻었다.;Except for using 2-(dibenzo[b,d]furan-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane as a reactant [Preparation Example 1] to obtain 38 g of the target compound;

GC-Mass (이론치: 333.12g/mol, 측정치: 333.39 g/mol) GC-Mass (Theory: 333.12 g/mol, Measured: 333.39 g/mol)

[준비예 3][Preparation Example 3]

1-(디벤조[b,d]퓨란-2-일)-9H-카바졸의 합성Synthesis of 1-(dibenzo[b,d]furan-2-yl)-9H-carbazole

Figure pat00057
Figure pat00057

반응물로 2-(디벤조[b,d]퓨란-2-일)-4,4,5,5-테트라메틸-1,3,2-디옥사보로란을 사용한 것을 제외하고는 [준비예 1]과 동일한 과정을 수행하여 목적 화합물 38g을 얻었다.;Except for using 2-(dibenzo[b,d]furan-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane as a reactant [Preparation Example 1] to obtain 38 g of the target compound;

GC-Mass (이론치: 333.12g/mol, 측정치: 333.39 g/mol) GC-Mass (Theory: 333.12 g/mol, Measured: 333.39 g/mol)

[준비예 4][Preparation Example 4]

1-(디벤조[b,d]퓨란-1-일)-9H-카바졸의 합성Synthesis of 1-(dibenzo[b,d]furan-1-yl)-9H-carbazole

Figure pat00058
Figure pat00058

반응물로 2-(디벤조[b,d]퓨란-1-일)-4,4,5,5-테트라메틸-1,3,2-디옥사보로란을 사용한 것을 제외하고는 [준비예 1]과 동일한 과정을 수행하여 목적 화합물 38g을 얻었다.;Except for using 2-(dibenzo[b,d]furan-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane as a reactant 1] to obtain 38 g of the target compound;

GC-Mass (이론치: 333.12g/mol, 측정치: 333.39 g/mol) GC-Mass (Theory: 333.12 g/mol, Measured: 333.39 g/mol)

[준비예 5][Preparation Example 5]

1-(디벤조[b,d]티오펜-4-일)-9H-카바졸 의 합성Synthesis of 1-(dibenzo[b,d]thiophen-4-yl)-9H-carbazole

Figure pat00059
Figure pat00059

반응물로 2-(디벤조[b,d]티오펜-4-일)-4,4,5,5-테트라메틸-1,3,2-디옥사보로란을 사용한 것을 제외하고는 [준비예 1]과 동일한 과정을 수행하여 목적 화합물 38g을 얻었다.;Except for using 2-(dibenzo[b,d]thiophen-4-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane as the reactant [preparation [Example 1] to obtain 38 g of the target compound;

GC-Mass (이론치: 349.09g/mol, 측정치: 349.45 g/mol) GC-Mass (Theory: 349.09 g/mol, Measured: 349.45 g/mol)

[준비예 6][Preparation Example 6]

1-(디벤조[b,d]티오펜-3-일)-9H-카바졸 의 합성Synthesis of 1-(dibenzo[b,d]thiophen-3-yl)-9H-carbazole

Figure pat00060
Figure pat00060

반응물로 2-(디벤조[b,d]티오펜-3-일)-4,4,5,5-테트라메틸-1,3,2-디옥사보로란을 사용한 것을 제외하고는 [준비예 1]과 동일한 과정을 수행하여 목적 화합물 38g을 얻었다.;Except for using 2-(dibenzo[b,d]thiophen-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane as the reactant [preparation [Example 1] to obtain 38 g of the target compound;

GC-Mass (이론치: 349.09g/mol, 측정치: 349.45 g/mol) GC-Mass (Theory: 349.09 g/mol, Measured: 349.45 g/mol)

[준비예 7][Preparation Example 7]

1-(디벤조[b,d]티오펜-2-일)-9H-카바졸 의 합성Synthesis of 1-(dibenzo[b,d]thiophen-2-yl)-9H-carbazole

Figure pat00061
Figure pat00061

반응물로 2-(디벤조[b,d]티오펜-2-일)-4,4,5,5-테트라메틸-1,3,2-디옥사보로란을 사용한 것을 제외하고는 [준비예 1]과 동일한 과정을 수행하여 목적 화합물 38g을 얻었다.;Except for using 2-(dibenzo[b,d]thiophen-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane as the reactant [preparation [Example 1] to obtain 38 g of the target compound;

GC-Mass (이론치: 349.09g/mol, 측정치: 349.45 g/mol) GC-Mass (Theory: 349.09 g/mol, Measured: 349.45 g/mol)

[준비예 8][Preparation Example 8]

1-(디벤조[b,d]티오펜-1-일)-9H-카바졸 의 합성Synthesis of 1-(dibenzo[b,d]thiophen-1-yl)-9H-carbazole

Figure pat00062
Figure pat00062

반응물로 2-(디벤조[b,d]티오펜-1-일)-4,4,5,5-테트라메틸-1,3,2-디옥사보로란을 사용한 것을 제외하고는 [준비예 1]과 동일한 과정을 수행하여 목적 화합물 38g을 얻었다.;Except for using 2-(dibenzo[b,d]thiophen-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane as the reactant [preparation [Example 1] to obtain 38 g of the target compound;

GC-Mass (이론치: 349.09g/mol, 측정치: 349.45 g/mol) GC-Mass (Theory: 349.09 g/mol, Measured: 349.45 g/mol)

[준비예 9][Preparation Example 9]

1-(9,9-디메틸-9H-플루오렌-1-일)-9H-카바졸 의 합성Synthesis of 1-(9,9-dimethyl-9H-fluoren-1-yl)-9H-carbazole

Figure pat00063
Figure pat00063

반응물로 2-(9,9-디메틸-9H-플루오렌-1-일)-4,4,5,5-테트라메틸-1,3,2-디옥사보로란을 사용한 것을 제외하고는 [준비예 1]과 동일한 과정을 수행하여 목적 화합물 38g을 얻었다.;[ 38g of the target compound was obtained by performing the same procedure as [Preparation Example 1];

GC-Mass (이론치: 349.17g/mol, 측정치: 359.47g/mol) GC-Mass (Theory: 349.17g/mol, Measured: 359.47g/mol)

[준비예 10][Preparation Example 10]

1-(9,9-디메틸-9H-플루오렌-2-일)-9H-카바졸의 합성Synthesis of 1-(9,9-dimethyl-9H-fluoren-2-yl)-9H-carbazole

Figure pat00064
Figure pat00064

반응물로 2-(9,9-디메틸-9H-플루오렌-2-일)-4,4,5,5-테트라메틸-1,3,2-디옥사보로란을 사용한 것을 제외하고는 [준비예 1]과 동일한 과정을 수행하여 목적 화합물 38g을 얻었다.;[ 38g of the target compound was obtained by performing the same procedure as [Preparation Example 1];

GC-Mass (이론치: 349.17g/mol, 측정치: 359.47g/mol) GC-Mass (Theory: 349.17g/mol, Measured: 359.47g/mol)

[준비예 11][Preparation Example 11]

1-(9,9-디메틸-9H-플루오렌-3-일)-9H-카바졸 의 합성Synthesis of 1-(9,9-dimethyl-9H-fluoren-3-yl)-9H-carbazole

Figure pat00065
Figure pat00065

반응물로 2-(9,9-디메틸-9H-플루오렌-3-일)-4,4,5,5-테트라메틸-1,3,2-디옥사보로란을 사용한 것을 제외하고는 [준비예 1]과 동일한 과정을 수행하여 목적 화합물 38g을 얻었다.;Except for using 2-(9,9-dimethyl-9H-fluoren-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane as the reactant [ 38g of the target compound was obtained by performing the same procedure as [Preparation Example 1];

GC-Mass (이론치: 349.17g/mol, 측정치: 359.47g/mol)GC-Mass (Theory: 349.17g/mol, Measured: 359.47g/mol)

[준비예 12][Preparation Example 12]

1-(9,9-디메틸-9H-플루오렌-4-일)-9H-카바졸의 합성Synthesis of 1-(9,9-dimethyl-9H-fluoren-4-yl)-9H-carbazole

Figure pat00066
Figure pat00066

반응물로 2-(9,9-디메틸-9H-플루오렌-4-일)-4,4,5,5-테트라메틸-1,3,2-디옥사보로란을 사용한 것을 제외하고는 [준비예 1]과 동일한 과정을 수행하여 목적 화합물 38g을 얻었다.;[ 38g of the target compound was obtained by performing the same procedure as [Preparation Example 1];

GC-Mass (이론치: 349.17g/mol, 측정치: 359.47g/mol) GC-Mass (Theory: 349.17g/mol, Measured: 359.47g/mol)

[준비예 13][Preparation Example 13]

1-(8-페닐디벤조[b,d]퓨란-4-일)-9H-카바졸의 합성Synthesis of 1-(8-phenyldibenzo[b,d]furan-4-yl)-9H-carbazole

Figure pat00067
Figure pat00067

반응물로 4,4,5,5-테트라메틸-2-(8-페닐디벤조[b,d]퓨란-4-일)-1,3,2-디옥사보로란을 사용한 것을 제외하고는 [준비예 1]과 동일한 과정을 수행하여 목적 화합물 42g을 얻었다.;Except for using 4,4,5,5-tetramethyl-2-(8-phenyldibenzo[b,d]furan-4-yl)-1,3,2-dioxaborolane as the reactant 42 g of the target compound was obtained by performing the same procedure as in [Preparation Example 1];

GC-Mass (이론치: 409.15g/mol, 측정치: 409.49g/mol) GC-Mass (Theory: 409.15g/mol, Measured: 409.49g/mol)

[준비예 14][Preparation Example 14]

1-(6-페닐디벤조[b,d]퓨란-4-일)-9H-카바졸의 합성Synthesis of 1-(6-phenyldibenzo[b,d]furan-4-yl)-9H-carbazole

Figure pat00068
Figure pat00068

반응물로 4,4,5,5-테트라메틸-2-(6-페닐디벤조[b,d]퓨란-4-일)-1,3,2-디옥사보로란을 사용한 것을 제외하고는 [준비예 1]과 동일한 과정을 수행하여 목적 화합물 33g을 얻었다.;Except for using 4,4,5,5-tetramethyl-2-(6-phenyldibenzo[b,d]furan-4-yl)-1,3,2-dioxaborolane as the reactant 33 g of the target compound was obtained by performing the same procedure as in [Preparation Example 1];

GC-Mass (이론치: 409.15g/mol, 측정치: 409.49g/mol) GC-Mass (Theory: 409.15g/mol, Measured: 409.49g/mol)

[준비예 15][Preparation Example 15]

1-(6-([1,1'-비페닐]-3-일)디벤조[b,d]퓨란-4-일)-9H-카바졸의 합성Synthesis of 1-(6-([1,1′-biphenyl]-3-yl)dibenzo[b,d]furan-4-yl)-9H-carbazole

Figure pat00069
Figure pat00069

반응물로 2-(6-([1,1'-비페닐]-3-일)디벤조[b,d]퓨란-4-일)-4,4,5,5-테트라메틸-1,3,2-디옥사보로란을 사용한 것을 제외하고는 [준비예 1]과 동일한 과정을 수행하여 목적 화합물 35g을 얻었다.;2-(6-([1,1'-biphenyl]-3-yl)dibenzo[b,d]furan-4-yl)-4,4,5,5-tetramethyl-1,3 as reactants Except for using ,2-dioxaborolane, the same procedure as in [Preparation Example 1] was performed to obtain 35 g of the target compound;

GC-Mass (이론치: 485.18g/mol, 측정치: 485.59g/mol) GC-Mass (Theory: 485.18g/mol, Measured: 485.59g/mol)

[준비예 16][Preparation Example 16]

1-(6-(9,9-디메틸-9H-플루오렌-3-일)디벤조[b,d]퓨란-4-일)-9H-카바졸의 합성Synthesis of 1-(6-(9,9-dimethyl-9H-fluoren-3-yl)dibenzo[b,d]furan-4-yl)-9H-carbazole

Figure pat00070
Figure pat00070

반응물로 2-(6-(9,9-디메틸-9H-플루오렌-3-일)디벤조[b,d]퓨란-4-일)-4,4,5,5-테트라메틸-1,3,2-디옥사보로란을 사용한 것을 제외하고는 [준비예 1]과 동일한 과정을 수행하여 목적 화합물 40g을 얻었다.;2-(6-(9,9-dimethyl-9H-fluoren-3-yl)dibenzo[b,d]furan-4-yl)-4,4,5,5-tetramethyl-1, 40 g of the target compound was obtained by performing the same procedure as in [Preparation Example 1] except for using 3,2-dioxaborolan;

GC-Mass (이론치: 525.21g/mol, 측정치: 525.65g/mol) GC-Mass (Theory: 525.21g/mol, Measured: 525.65g/mol)

[준비예 17][Preparation Example 17]

1-(2-페닐디벤조[b,d]퓨란-4-일)-9H-카바졸의 합성Synthesis of 1-(2-phenyldibenzo[b,d]furan-4-yl)-9H-carbazole

Figure pat00071
Figure pat00071

반응물로 4,4,5,5-테트라메틸-2-(2-페닐디벤조[b,d]퓨란-4-일)-1,3,2-디옥사보로란을 사용한 것을 제외하고는 [준비예 1]과 동일한 과정을 수행하여 목적 화합물 36g을 얻었다.;Except for using 4,4,5,5-tetramethyl-2-(2-phenyldibenzo[b,d]furan-4-yl)-1,3,2-dioxaborolane as the reactant 36 g of the target compound was obtained by performing the same procedure as in [Preparation Example 1];

GC-Mass (이론치: 409.15g/mol, 측정치: 409.49g/mol) GC-Mass (Theory: 409.15g/mol, Measured: 409.49g/mol)

[준비예 18][Preparation Example 18]

1-(1-([1,1'-비페닐]-2-일)디벤조[b,d]퓨란-4-일)-9H-카바졸의 합성Synthesis of 1-(1-([1,1′-biphenyl]-2-yl)dibenzo[b,d]furan-4-yl)-9H-carbazole

Figure pat00072
Figure pat00072

반응물로 2-(1-([1,1'-비페닐]-2-일)디벤조[b,d]퓨란-4-일)-4,4,5,5-테트라메틸-1,3,2-디옥사보로란을 사용한 것을 제외하고는 [준비예 1]과 동일한 과정을 수행하여 목적 화합물 41g을 얻었다.;2-(1-([1,1'-biphenyl]-2-yl)dibenzo[b,d]furan-4-yl)-4,4,5,5-tetramethyl-1,3 as reactants Except for using ,2-dioxaborolane, the same procedure as in [Preparation Example 1] was performed to obtain 41 g of the target compound;

GC-Mass (이론치: 349.17g/mol, 측정치: 359.47g/mol) GC-Mass (Theory: 349.17g/mol, Measured: 359.47g/mol)

[준비예 19][Preparation Example 19]

1-(디벤조[b,d]퓨란-4-일)-6-페닐-9H-카바졸의 합성Synthesis of 1-(dibenzo[b,d]furan-4-yl)-6-phenyl-9H-carbazole

Figure pat00073
Figure pat00073

반응물로 1-브로모-6-페닐-9H-카바졸을 사용한 것을 제외하고는 [준비예 1]과 동일한 과정을 수행하여 목적 화합물 42g을 얻었다.;Except for using 1-bromo-6-phenyl-9H-carbazole as a reactant, 42 g of the target compound was obtained by performing the same procedure as in [Preparation Example 1];

GC-Mass (이론치: 409.15g/mol, 측정치: 409.59g/mol) GC-Mass (Theory: 409.15g/mol, Measured: 409.59g/mol)

[준비예 20][Preparation Example 20]

6-페닐-1-(6-페닐디벤조[b,d]퓨란-4-일)-9H-카바졸의 합성Synthesis of 6-phenyl-1-(6-phenyldibenzo[b,d]furan-4-yl)-9H-carbazole

Figure pat00074
Figure pat00074

반응물로 2-(9,9-디메틸-9H-플루오렌-4-일)-4,4,5,5-테트라메틸-1,3,2-디옥사보로란을 사용한 것을 제외하고는 [준비예 19]과 동일한 과정을 수행하여 목적 화합물 39g을 얻었다.;[ 39 g of the target compound was obtained by performing the same procedure as in [Preparation Example 19];

GC-Mass (이론치: 485.18g/mol, 측정치: 485.59g/mol) GC-Mass (Theory: 485.18g/mol, Measured: 485.59g/mol)

[준비예 21][Preparation Example 21]

6-([1,1'-비페닐]-3-일)-1-(6-([1,1'-비페닐]-3-일)디벤조[b,d]퓨란-4-일)-9H-카바졸의 합성6-([1,1'-biphenyl]-3-yl)-1-(6-([1,1'-biphenyl]-3-yl)dibenzo[b,d]furan-4-yl ) Synthesis of -9H-carbazole

Figure pat00075
Figure pat00075

반응물로 6-([1,1'-비페닐]-3-일)-1-브로모-9H-카바졸을 사용한 것을 제외하고는 [준비예 15]과 동일한 과정을 수행하여 목적 화합물 40g을 얻었다.;40 g of the target compound was obtained by performing the same procedure as in [Preparation Example 15], except for using 6-([1,1'-biphenyl]-3-yl)-1-bromo-9H-carbazole as a reactant. got.;

GC-Mass (이론치: 349.17g/mol, 측정치: 359.47g/mol) GC-Mass (Theory: 349.17g/mol, Measured: 359.47g/mol)

[준비예 22][Preparation Example 22]

6-페닐-1-(2-페닐디벤조[b,d]퓨란-4-일)-9H-카바졸의 합성Synthesis of 6-phenyl-1-(2-phenyldibenzo[b,d]furan-4-yl)-9H-carbazole

Figure pat00076
Figure pat00076

반응물로 2-(9,9-디메틸-9H-플루오렌-4-일)-4,4,5,5-테트라메틸-1,3,2-디옥사보로란을 사용한 것을 제외하고는 [준비예 19]과 동일한 과정을 수행하여 목적 화합물 35g을 얻었다.;[ 35 g of the target compound was obtained by performing the same procedure as [Preparation Example 19];

GC-Mass (이론치: 349.17g/mol, 측정치: 359.47g/mol) GC-Mass (Theory: 349.17g/mol, Measured: 359.47g/mol)

[준비예 23][Preparation Example 23]

1-(디벤조[b,d]퓨란-4-일)-3-페닐-9H-카바졸의 합성Synthesis of 1-(dibenzo[b,d]furan-4-yl)-3-phenyl-9H-carbazole

Figure pat00077
Figure pat00077

반응물로 1-브로모-3-페닐-9H-카바졸을 사용한 것을 제외하고는 [준비예 1]과 동일한 과정을 수행하여 목적 화합물 45g을 얻었다.;Except for using 1-bromo-3-phenyl-9H-carbazole as a reactant, the same procedure as in [Preparation Example 1] was performed to obtain 45 g of the target compound;

GC-Mass (이론치: 409.15/mol, 측정치: 409.49g/mol) GC-Mass (Theory: 409.15/mol, Measured: 409.49 g/mol)

[준비예 24][Preparation Example 24]

3-페닐-1-(6-페닐디벤조[b,d]퓨란-4-일)-9H-카바졸의 합성Synthesis of 3-phenyl-1-(6-phenyldibenzo[b,d]furan-4-yl)-9H-carbazole

Figure pat00078
Figure pat00078

반응물로 4,4,5,5-테트라메틸-2-(6-페닐디벤조[b,d]퓨란-4-일)-1,3,2-디옥사보로란을 사용한 것을 제외하고는 [준비예 23]과 동일한 과정을 수행하여 목적 화합물 45g을 얻었다.;Except for using 4,4,5,5-tetramethyl-2-(6-phenyldibenzo[b,d]furan-4-yl)-1,3,2-dioxaborolane as the reactant 45 g of the target compound was obtained by performing the same procedure as in [Preparation Example 23];

GC-Mass (이론치: 481.18g/mol, 측정치: 481.59g/mol) GC-Mass (Theory: 481.18 g/mol, Measured: 481.59 g/mol)

[준비예 25][Preparation Example 25]

1-(1-([1,1'-비페닐]-3-일)디벤조[b,d]퓨란-4-일)-3-페닐-9H-카바졸의 합성Synthesis of 1-(1-([1,1′-biphenyl]-3-yl)dibenzo[b,d]furan-4-yl)-3-phenyl-9H-carbazole

Figure pat00079
Figure pat00079

반응물로 2-(1-([1,1'-비페닐]-3-일)디벤조[b,d]퓨란-4-일)-4,4,5,5-테트라메틸-1,3,2-디옥사보로란을 사용한 것을 제외하고는 [준비예 23]과 동일한 과정을 수행하여 목적 화합물 39g을 얻었다.;2-(1-([1,1'-biphenyl]-3-yl)dibenzo[b,d]furan-4-yl)-4,4,5,5-tetramethyl-1,3 as reactants Except for using ,2-dioxaborolane, the same procedure as in [Preparation Example 23] was performed to obtain 39 g of the target compound;

GC-Mass (이론치: 561.21g/mol, 측정치: 561.68g/mol) GC-Mass (Theory: 561.21 g/mol, Measured: 561.68 g/mol)

[준비예 26][Preparation Example 26]

1-(1-([1,1'-비페닐]-2-일)-6-페닐디벤조[b,d]퓨란-4-일)-3-페닐-9H-카바졸의 합성Synthesis of 1-(1-([1,1′-biphenyl]-2-yl)-6-phenyldibenzo[b,d]furan-4-yl)-3-phenyl-9H-carbazole

Figure pat00080
Figure pat00080

반응물로 2-(1-([1,1'-비페닐]-2-일)-6-페닐디벤조[b,d]퓨란-4-일)-4,4,5,5-테트라메틸-1,3,2-디옥사보로란을 사용한 것을 제외하고는 [준비예 23]과 동일한 과정을 수행하여 목적 화합물 40g을 얻었다.;2-(1-([1,1′-biphenyl]-2-yl)-6-phenyldibenzo[b,d]furan-4-yl)-4,4,5,5-tetramethyl as reactant 40 g of the target compound was obtained by performing the same procedure as in [Preparation Example 23] except that -1,3,2-dioxaborolane was used;

GC-Mass (이론치: 637.24g/mol, 측정치: 637.78g/mol) GC-Mass (Theory: 637.24g/mol, Measured: 637.78g/mol)

[준비예 27][Preparation Example 27]

1-(8-페닐디벤조[b,d]티오펜-4-일)-9H-카바졸의 합성Synthesis of 1-(8-phenyldibenzo[b,d]thiophen-4-yl)-9H-carbazole

Figure pat00081
Figure pat00081

반응물로 4,4,5,5-테트라메틸-2-(8-페닐디벤조[b,d]퓨란-4-일)-1,3,2-디옥사보로란을 사용한 것을 제외하고는 [준비예 13]과 동일한 과정을 수행하여 목적 화합물 42g을 얻었다.;Except for using 4,4,5,5-tetramethyl-2-(8-phenyldibenzo[b,d]furan-4-yl)-1,3,2-dioxaborolane as the reactant 42 g of the target compound was obtained by performing the same procedure as in [Preparation Example 13];

GC-Mass (이론치: 425.12g/mol, 측정치: 425.55g/mol) GC-Mass (Theory: 425.12g/mol, Measured: 425.55g/mol)

[준비예 28][Preparation Example 28]

1-(6-페닐디벤조[b,d]티오펜-4-일)-9H-카바졸의 합성Synthesis of 1-(6-phenyldibenzo[b,d]thiophen-4-yl)-9H-carbazole

Figure pat00082
Figure pat00082

반응물로 4,4,5,5-테트라메틸-2-(6-페닐디벤조[b,d]퓨란-4-일)-1,3,2-디옥사보로란을 사용한 것을 제외하고는 [준비예 14]과 동일한 과정을 수행하여 목적 화합물 33g을 얻었다.;Except for using 4,4,5,5-tetramethyl-2-(6-phenyldibenzo[b,d]furan-4-yl)-1,3,2-dioxaborolane as the reactant 33 g of the target compound was obtained by performing the same procedure as in [Preparation Example 14];

GC-Mass (이론치: 425.12g/mol, 측정치: 425.55g/mol) GC-Mass (Theory: 425.12g/mol, Measured: 425.55g/mol)

[준비예 29][Preparation Example 29]

1-(6-([1,1'-비페닐]-3-일)디벤조[b,d]티오펜-4-일)-9H-카바졸의 합성Synthesis of 1-(6-([1,1′-biphenyl]-3-yl)dibenzo[b,d]thiophen-4-yl)-9H-carbazole

Figure pat00083
Figure pat00083

반응물로 2-(6-([1,1'-비페닐]-3-일)디벤조[b,d]퓨란-4-일)-4,4,5,5-테트라메틸-1,3,2-디옥사보로란을 사용한 것을 제외하고는 [준비예 15]과 동일한 과정을 수행하여 목적 화합물 35g을 얻었다.;2-(6-([1,1'-biphenyl]-3-yl)dibenzo[b,d]furan-4-yl)-4,4,5,5-tetramethyl-1,3 as reactants 35 g of the target compound was obtained by performing the same procedure as in [Preparation Example 15] except that ,2-dioxaborolane was used;

GC-Mass (이론치: 501.16g/mol, 측정치: 501.65g/mol) GC-Mass (Theory: 501.16g/mol, Measured: 501.65g/mol)

[준비예 30][Preparation Example 30]

1-(6-(9,9-디메틸-9H-플루오렌-3-일)디벤조[b,d]티오펜-4-일)-9H-카바졸의 합성Synthesis of 1-(6-(9,9-dimethyl-9H-fluoren-3-yl)dibenzo[b,d]thiophen-4-yl)-9H-carbazole

Figure pat00084
Figure pat00084

반응물로 2-(6-(9,9-디메틸-9H-플루오렌-3-일)디벤조[b,d]퓨란-4-일)-4,4,5,5-테트라메틸-1,3,2-디옥사보로란을 사용한 것을 제외하고는 [준비예 16]과 동일한 과정을 수행하여 목적 화합물 40g을 얻었다.;2-(6-(9,9-dimethyl-9H-fluoren-3-yl)dibenzo[b,d]furan-4-yl)-4,4,5,5-tetramethyl-1, Except for using 3,2-dioxaborolane, the same procedure as in [Preparation Example 16] was performed to obtain 40 g of the target compound;

GC-Mass (이론치: 541.19g/mol, 측정치: 541.75g/mol) GC-Mass (Theory: 541.19g/mol, Measured: 541.75g/mol)

[준비예 31][Preparation Example 31]

1-(2-페닐디벤조[b,d]티오펜-4-일)-9H-카바졸의 합성Synthesis of 1-(2-phenyldibenzo[b,d]thiophen-4-yl)-9H-carbazole

Figure pat00085
Figure pat00085

반응물로 4,4,5,5-테트라메틸-2-(2-페닐디벤조[b,d]퓨란-4-일)-1,3,2-디옥사보로란을 사용한 것을 제외하고는 [준비예 17]과 동일한 과정을 수행하여 목적 화합물 36g을 얻었다.;Except for using 4,4,5,5-tetramethyl-2-(2-phenyldibenzo[b,d]furan-4-yl)-1,3,2-dioxaborolane as the reactant 36 g of the target compound was obtained by performing the same procedure as in [Preparation Example 17];

GC-Mass (이론치: 425.12g/mol, 측정치: 425.55g/mol) GC-Mass (Theory: 425.12g/mol, Measured: 425.55g/mol)

[준비예 32][Preparation Example 32]

1-(1-([1,1'-비페닐]-2-일)디벤조[b,d]티오펜-4-일)-9H-카바졸의 합성Synthesis of 1-(1-([1,1′-biphenyl]-2-yl)dibenzo[b,d]thiophen-4-yl)-9H-carbazole

Figure pat00086
Figure pat00086

반응물로 2-(1-([1,1'-비페닐]-2-일)디벤조[b,d]퓨란-4-일)-4,4,5,5-테트라메틸-1,3,2-디옥사보로란을 사용한 것을 제외하고는 [준비예 18]과 동일한 과정을 수행하여 목적 화합물 41g을 얻었다.;2-(1-([1,1'-biphenyl]-2-yl)dibenzo[b,d]furan-4-yl)-4,4,5,5-tetramethyl-1,3 as reactants Except for using ,2-dioxaborolane, the same procedure as in [Preparation Example 18] was performed to obtain 41 g of the target compound;

GC-Mass (이론치: 501.16g/mol, 측정치: 501.65g/mol) GC-Mass (Theory: 501.16g/mol, Measured: 501.65g/mol)

[준비예 33][Preparation Example 33]

1-(디벤조[b,d]티오펜-4-일)-6-페닐-9H-카바졸의 합성Synthesis of 1-(dibenzo[b,d]thiophen-4-yl)-6-phenyl-9H-carbazole

Figure pat00087
Figure pat00087

반응물로 2-(9,9-디메틸-9H-플루오렌-4-일)-4,4,5,5-테트라메틸-1,3,2-디옥사보로란을 사용한 것을 제외하고는 [준비예 19]과 동일한 과정을 수행하여 목적 화합물 42g을 얻었다.;[ 42 g of the target compound was obtained by performing the same procedure as in [Preparation Example 19];

GC-Mass (이론치: 425.12g/mol, 측정치: 425.55g/mol) GC-Mass (Theory: 425.12g/mol, Measured: 425.55g/mol)

**

[준비예 34][Preparation Example 34]

6-페닐-1-(6-페닐디벤조[b,d]티오펜-4-일)-9H-카바졸의 합성Synthesis of 6-phenyl-1-(6-phenyldibenzo[b,d]thiophen-4-yl)-9H-carbazole

Figure pat00088
Figure pat00088

반응물로 2-(9,9-디메틸-9H-플루오렌-4-일)-4,4,5,5-테트라메틸-1,3,2-디옥사보로란을 사용한 것을 제외하고는 [준비예 20]과 동일한 과정을 수행하여 목적 화합물 39g을 얻었다.;[ 39 g of the target compound was obtained by performing the same procedure as [Preparation Example 20];

GC-Mass (이론치: 501.16g/mol, 측정치: 501.65g/mol) GC-Mass (Theory: 501.16g/mol, Measured: 501.65g/mol)

[준비예 35][Preparation Example 35]

6-([1,1'-비페닐]-3-일)-1-(6-([1,1'-비페닐]-3-일)디벤조[b,d]티오펜-4-일)-9H-카바졸의 합성6-([1,1'-biphenyl]-3-yl)-1-(6-([1,1'-biphenyl]-3-yl)dibenzo[b,d]thiophene-4- 1) Synthesis of -9H-carbazole

Figure pat00089
Figure pat00089

반응물로 6-([1,1'-비페닐]-3-일)-1-브로모-9H-카바졸을 사용한 것을 제외하고는 [준비예 21]과 동일한 과정을 수행하여 목적 화합물 40g을 얻었다.;40 g of the target compound was obtained by performing the same procedure as in [Preparation Example 21], except that 6-([1,1'-biphenyl]-3-yl)-1-bromo-9H-carbazole was used as a reactant. got.;

GC-Mass (이론치: 653.22g/mol, 측정치: 653.85g/mol) GC-Mass (Theory: 653.22g/mol, Measured: 653.85g/mol)

[준비예 36][Preparation Example 36]

6-페닐-1-(2-페닐디벤조[b,d]티오펜-4-일)-9H-카바졸의 합성Synthesis of 6-phenyl-1-(2-phenyldibenzo[b,d]thiophen-4-yl)-9H-carbazole

Figure pat00090
Figure pat00090

반응물로 2-(9,9-디메틸-9H-플루오렌-4-일)-4,4,5,5-테트라메틸-1,3,2-디옥사보로란을 사용한 것을 제외하고는 [준비예 22]과 동일한 과정을 수행하여 목적 화합물 35g을 얻었다.;[ 35 g of the target compound was obtained by performing the same procedure as in [Preparation Example 22];

GC-Mass (이론치: 501.16g/mol, 측정치: 501.65g/mol) GC-Mass (Theory: 501.16g/mol, Measured: 501.65g/mol)

[준비예 37][Preparation Example 37]

1-(디벤조[b,d]티오펜-4-일)-3-페닐-9H-카바졸의 합성Synthesis of 1-(dibenzo[b,d]thiophen-4-yl)-3-phenyl-9H-carbazole

Figure pat00091
Figure pat00091

반응물로 1-브로모-3-페닐-9H-카바졸을 사용한 것을 제외하고는 [준비예 23]과 동일한 과정을 수행하여 목적 화합물 45g을 얻었다.;Except for using 1-bromo-3-phenyl-9H-carbazole as a reactant, the same procedure as in [Preparation Example 23] was performed to obtain 45 g of the target compound;

GC-Mass (이론치: 425.12/mol, 측정치: 425.55g/mol) GC-Mass (Theory: 425.12/mol, Measured: 425.55 g/mol)

[준비예 38][Preparation Example 38]

3-페닐-1-(6-페닐디벤조[b,d]티오펜-4-일)-9H-카바졸의 합성Synthesis of 3-phenyl-1-(6-phenyldibenzo[b,d]thiophen-4-yl)-9H-carbazole

Figure pat00092
Figure pat00092

반응물로 4,4,5,5-테트라메틸-2-(6-페닐디벤조[b,d]퓨란-4-일)-1,3,2-디옥사보로란을 사용한 것을 제외하고는 [준비예 24]과 동일한 과정을 수행하여 목적 화합물 45g을 얻었다.;Except for using 4,4,5,5-tetramethyl-2-(6-phenyldibenzo[b,d]furan-4-yl)-1,3,2-dioxaborolane as the reactant 45 g of the target compound was obtained by performing the same procedure as in [Preparation Example 24];

GC-Mass (이론치: 501.16g/mol, 측정치: 501.65g/mol) GC-Mass (Theory: 501.16g/mol, Measured: 501.65g/mol)

[준비예 39][Preparation Example 39]

1-(1-([1,1'-비페닐]-3-일)디벤조[b,d]티오펜-4-일)-3-페닐-9H-카바졸의 합성Synthesis of 1-(1-([1,1′-biphenyl]-3-yl)dibenzo[b,d]thiophen-4-yl)-3-phenyl-9H-carbazole

Figure pat00093
Figure pat00093

반응물로 2-(1-([1,1'-비페닐]-3-일)디벤조[b,d]퓨란-4-일)-4,4,5,5-테트라메틸-1,3,2-디옥사보로란을 사용한 것을 제외하고는 [준비예 25]과 동일한 과정을 수행하여 목적 화합물 39g을 얻었다.;2-(1-([1,1'-biphenyl]-3-yl)dibenzo[b,d]furan-4-yl)-4,4,5,5-tetramethyl-1,3 as reactants Except for using ,2-dioxaborolane, the same procedure as in [Preparation Example 25] was performed to obtain 39 g of the target compound;

GC-Mass (이론치: 577.19g/mol, 측정치: 577.75g/mol) GC-Mass (Theory: 577.19g/mol, Measured: 577.75g/mol)

[준비예 40][Preparation Example 40]

1-(1-([1,1'-비페닐]-2-일)-6-페닐디벤조[b,d]티오펜-4-일)-3-페닐-9H-카바졸의 합성Synthesis of 1-(1-([1,1′-biphenyl]-2-yl)-6-phenyldibenzo[b,d]thiophen-4-yl)-3-phenyl-9H-carbazole

Figure pat00094
Figure pat00094

반응물로 2-(1-([1,1'-비페닐]-2-일)-6-페닐디벤조[b,d]퓨란-4-일)-4,4,5,5-테트라메틸-1,3,2-디옥사보로란을 사용한 것을 제외하고는 [준비예 26]과 동일한 과정을 수행하여 목적 화합물 40g을 얻었다.;2-(1-([1,1′-biphenyl]-2-yl)-6-phenyldibenzo[b,d]furan-4-yl)-4,4,5,5-tetramethyl as reactant 40 g of the target compound was obtained by performing the same procedure as in [Preparation Example 26] except that -1,3,2-dioxaborolane was used;

GC-Mass (이론치: 653.22g/mol, 측정치: 653.83g/mol) GC-Mass (Theory: 653.22g/mol, Measured: 653.83g/mol)

[합성예 1] Mat 1의 합성 [Synthesis Example 1] Synthesis of Mat 1

Figure pat00095
Figure pat00095

질소 기류 하에서 [준비예1](10g, 29.9mmol)을 DMF 100ml에 녹인 후 상온에서 NaH(1.07g, 44.9mmol)을 천천히 적가한다. 1시간 충분히 교반한 후, 2-클로로-4,6-디페닐-1,3,5-트리아진 9.6g(35.88mmol) 을 천천히 넣는다. 상온에서 4시간 동안 교반하였다. 반응 종결 후 메틸렌클로라이드로 추출하고 감압조건에서 농축한 후 컬럼크로마토그래피를 이용하여 목적 화합물을 12.8g(76%)얻었다. 1H-NMR: 8.55(d, 1H), 8.36(dd 4H), 8.08~7.94(m, 5H), 7.50~7.31(m, 12H), 7.16(t, 1H); HRMS [M]+: 565.20After dissolving [Preparation Example 1] (10g, 29.9mmol) in 100ml of DMF under a nitrogen stream, NaH (1.07g, 44.9mmol) was slowly added dropwise at room temperature. After sufficiently stirring for 1 hour, 9.6 g (35.88 mmol) of 2-chloro-4,6-diphenyl-1,3,5-triazine was slowly added. It was stirred for 4 hours at room temperature. After completion of the reaction, extraction with methylene chloride, concentration under reduced pressure, and 12.8 g (76%) of the target compound were obtained by column chromatography. 1H-NMR: 8.55 (d, 1H), 8.36 (dd 4H), 8.08-7.94 (m, 5H), 7.50-7.31 (m, 12H), 7.16 (t, 1H); HRMS [M] + : 565.20

[합성예 2] Mat 2의 합성[Synthesis Example 2] Synthesis of Mat 2

Figure pat00096
Figure pat00096

반응물로 2,4-디([1,1'-비페닐]-4-일)-6-클로로-1,3,5-트리아진을 사용한 것을 제외하고는 [합성예 1]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 717.26The same procedure as in [Synthesis Example 1] was performed except that 2,4-di([1,1'-biphenyl]-4-yl)-6-chloro-1,3,5-triazine was used as the reactant. This was carried out to obtain 13.2 g of the target compound; HRMS [M]+: 717.26

[합성예 3] Mat 3의 합성[Synthesis Example 3] Synthesis of Mat 3

Figure pat00097
Figure pat00097

반응물로 2,4-디([1,1'-비페닐]-3-일)-6-클로로-1,3,5-트리아진을 사용한 것을 제외하고는 [합성예 1]과 동일한 과정을 수행하여 목적 화합물 10.9g을 얻었다.; HRMS [M]+: 717.26The same procedure as in [Synthesis Example 1] was performed except that 2,4-di([1,1'-biphenyl]-3-yl)-6-chloro-1,3,5-triazine was used as the reactant. This was carried out to obtain 10.9 g of the target compound; HRMS [M]+: 717.26

[합성예 4] Mat 4의 합성[Synthesis Example 4] Synthesis of Mat 4

Figure pat00098
Figure pat00098

반응물로 2-클로로-4,6-디(나프탈렌-2-일)-1,3,5-트리아진을 사용한 것을 제외하고는 [합성예 1]과 동일한 과정을 수행하여 목적 화합물 9.8g을 얻었다.; HRMS [M]+: 665.23Except for using 2-chloro-4,6-di(naphthalen-2-yl)-1,3,5-triazine as a reactant, the same procedure as in [Synthesis Example 1] was performed to obtain 9.8 g of the target compound. .; HRMS [M]+: 665.23

[합성예 5] Mat 5의 합성[Synthesis Example 5] Synthesis of Mat 5

Figure pat00099
Figure pat00099

반응물로 2-([1,1'-비페닐]-4-일)-4-클로로-6-페닐-1,3,5-트리아진을 사용한 것을 제외하고는 [합성예 1]과 동일한 과정을 수행하여 목적 화합물 11g을 얻었다.; HRMS [M]+: 641.23Same procedure as [Synthesis Example 1] except that 2-([1,1'-biphenyl]-4-yl)-4-chloro-6-phenyl-1,3,5-triazine was used as the reactant. was carried out to obtain 11 g of the target compound; HRMS [M]+: 641.23

[합성예 6] Mat 6의 합성[Synthesis Example 6] Synthesis of Mat 6

Figure pat00100
Figure pat00100

반응물로 2-클로로-4-(디벤조[b,d]퓨란-3-일)-6-페닐-1,3,5-트리아진을 사용한 것을 제외하고는 [합성예 1]과 동일한 과정을 수행하여 목적 화합물 10.8g을 얻었다.; HRMS [M]+: 655.21The same procedure as in [Synthesis Example 1] was performed except that 2-chloro-4-(dibenzo[b,d]furan-3-yl)-6-phenyl-1,3,5-triazine was used as the reactant. This was carried out to obtain 10.8 g of the target compound; HRMS [M]+: 655.21

[합성예 7] Mat 7의 합성[Synthesis Example 7] Synthesis of Mat 7

Figure pat00101
Figure pat00101

반응물로 2-클로로-4-(디벤조[b,d]티오펜-3-일)-6-페닐-1,3,5-트리아진을 사용한 것을 제외하고는 [합성예 1]과 동일한 과정을 수행하여 목적 화합물 9.9g을 얻었다.; HRMS [M]+: 671.19Same procedure as [Synthesis Example 1] except that 2-chloro-4-(dibenzo[b,d]thiophen-3-yl)-6-phenyl-1,3,5-triazine was used as the reactant. was carried out to obtain 9.9 g of the target compound; HRMS [M]+: 671.19

[합성예 8] Mat 8의 합성[Synthesis Example 8] Synthesis of Mat 8

Figure pat00102
Figure pat00102

반응물로 2-클로로-4-(9,9-디메틸-9H-플루오렌-2-일)-6-페닐-1,3,5-트리아진을 사용한 것을 제외하고는 [합성예 1]과 동일한 과정을 수행하여 목적 화합물 8.5g을 얻었다.; HRMS [M]+: 680.81Same as [Synthesis Example 1] except for using 2-chloro-4-(9,9-dimethyl-9H-fluoren-2-yl)-6-phenyl-1,3,5-triazine as a reactant. The process was carried out to obtain 8.5 g of the target compound; HRMS [M]+: 680.81

[합성예 9] Mat 9의 합성[Synthesis Example 9] Synthesis of Mat 9

Figure pat00103
Figure pat00103

반응물로 2-([1,1'-비페닐]-3-일)-4-클로로-6-페닐-1,3,5-트리아진을 사용한 것을 제외하고는 [합성예 1]과 동일한 과정을 수행하여 목적 화합물 10.5g을 얻었다.; HRMS [M]+: 640.75Same procedure as [Synthesis Example 1] except that 2-([1,1'-biphenyl]-3-yl)-4-chloro-6-phenyl-1,3,5-triazine was used as the reactant. was carried out to obtain 10.5 g of the target compound; HRMS [M]+: 640.75

[합성예 10] Mat 10의 합성[Synthesis Example 10] Synthesis of Mat 10

Figure pat00104
Figure pat00104

반응물로 2-클로로-4-(디벤조[b,d]퓨란-4-일)-6-페닐-1,3,5-트리아진을 사용한 것을 제외하고는 [합성예 1]과 동일한 과정을 수행하여 목적 화합물 8.9g을 얻었다.; HRMS [M]+: 655.21The same procedure as in [Synthesis Example 1] was performed except that 2-chloro-4-(dibenzo[b,d]furan-4-yl)-6-phenyl-1,3,5-triazine was used as the reactant. This was carried out to obtain 8.9 g of the target compound; HRMS [M]+: 655.21

[합성예 11] Mat 11의 합성[Synthesis Example 11] Synthesis of Mat 11

Figure pat00105
Figure pat00105

반응물로 2-클로로-4-(디벤조[b,d]퓨란-2-일)-6-페닐-1,3,5-트리아진을 사용한 것을 제외하고는 [합성예 1]과 동일한 과정을 수행하여 목적 화합물 9.1g을 얻었다.; HRMS [M]+: 655.21The same procedure as in [Synthesis Example 1] was performed except that 2-chloro-4-(dibenzo[b,d]furan-2-yl)-6-phenyl-1,3,5-triazine was used as the reactant. This was carried out to obtain 9.1 g of the target compound; HRMS [M]+: 655.21

[합성예 12] Mat 12의 합성[Synthesis Example 12] Synthesis of Mat 12

Figure pat00106
Figure pat00106

반응물로 2-클로로-4-(디벤조[b,d]퓨란-1-일)-6-페닐-1,3,5-트리아진을 사용한 것을 제외하고는 [합성예 1]과 동일한 과정을 수행하여 목적 화합물 9.4g을 얻었다.; HRMS [M]+: 655.21The same procedure as in [Synthesis Example 1] was performed except that 2-chloro-4-(dibenzo[b,d]furan-1-yl)-6-phenyl-1,3,5-triazine was used as the reactant. This was carried out to obtain 9.4 g of the target compound; HRMS [M]+: 655.21

[합성예 13] Mat 13의 합성[Synthesis Example 13] Synthesis of Mat 13

Figure pat00107
Figure pat00107

반응물로 2-클로로-4-페닐-6-(4-(피리딘-3-일)페닐)-1,3,5-트리아진을 사용한 것을 제외하고는 [합성예 1]과 동일한 과정을 수행하여 목적 화합물 11.2 g을 얻었다.; HRMS [M]+: 642.22The same process as [Synthesis Example 1] was performed except for using 2-chloro-4-phenyl-6-(4-(pyridin-3-yl)phenyl)-1,3,5-triazine as a reactant. 11.2 g of the target compound was obtained; HRMS [M]+: 642.22

[합성예 14] Mat 14의 합성[Synthesis Example 14] Synthesis of Mat 14

Figure pat00108
Figure pat00108

반응물로 2-클로로-4-페닐-6-(4-(피리딘-4-일)페닐)-1,3,5-트리아진을 사용한 것을 제외하고는 [합성예 1]과 동일한 과정을 수행하여 목적 화합물 10.8g을 얻었다.; HRMS [M]+: 642.22The same process as [Synthesis Example 1] was performed except for using 2-chloro-4-phenyl-6-(4-(pyridin-4-yl)phenyl)-1,3,5-triazine as a reactant. 10.8 g of the target compound was obtained; HRMS [M]+: 642.22

[합성예 15] Mat 15의 합성[Synthesis Example 15] Synthesis of Mat 15

Figure pat00109
Figure pat00109

반응물로 2-클로로-4-페닐-6-(3-(피리딘-3-일)페닐)-1,3,5-트리아진을 사용한 것을 제외하고는 [합성예 1]과 동일한 과정을 수행하여 목적 화합물 12g을 얻었다.; HRMS [M]+: 642.22The same process as [Synthesis Example 1] was performed except for using 2-chloro-4-phenyl-6-(3-(pyridin-3-yl)phenyl)-1,3,5-triazine as a reactant. 12 g of the target compound was obtained; HRMS [M]+: 642.22

[합성예 16] Mat 16의 합성[Synthesis Example 16] Synthesis of Mat 16

Figure pat00110
Figure pat00110

반응물로 2-([1,1'-비페닐]-4-일)-4-클로로-6-(피리딘-3-일)-1,3,5-트리아진을 사용한 것을 제외하고는 [합성예 1]과 동일한 과정을 수행하여 목적 화합물 12.3g을 얻었다.; HRMS [M]+: 642.22Except for using 2-([1,1'-biphenyl]-4-yl)-4-chloro-6-(pyridin-3-yl)-1,3,5-triazine as the reactant [synthesis 12.3 g of the target compound was obtained by performing the same procedure as in [Example 1]; HRMS [M]+: 642.22

[합성예 17] Mat 17의 합성[Synthesis Example 17] Synthesis of Mat 17

Figure pat00111
Figure pat00111

반응물로 2-클로로-4-(피리딘-3-일)-6-(4-(피리딘-3-일)페닐)-1,3,5-트리아진을 사용한 것을 제외하고는 [합성예 1]과 동일한 과정을 수행하여 목적 화합물 8.2g을 얻었다.; HRMS [M]+: 643.22[Synthesis Example 1] except that 2-chloro-4-(pyridin-3-yl)-6-(4-(pyridin-3-yl)phenyl)-1,3,5-triazine was used as the reactant. 8.2 g of the target compound was obtained by performing the same procedure as; HRMS [M]+: 643.22

[합성예 18] Mat 18의 합성[Synthesis Example 18] Synthesis of Mat 18

Figure pat00112
Figure pat00112

반응물로 2-클로로-4-(나프탈렌-2-일)-6-(피리딘-3-일)-1,3,5-트리아진을 사용한 것을 제외하고는 [합성예 1]과 동일한 과정을 수행하여 목적 화합물 8.5g을 얻었다.; HRMS [M]+: 616.21The same procedure as in [Synthesis Example 1] was performed except that 2-chloro-4-(naphthalen-2-yl)-6-(pyridin-3-yl)-1,3,5-triazine was used as the reactant. 8.5 g of the target compound was obtained; HRMS [M]+: 616.21

[합성예 19] Mat 19의 합성[Synthesis Example 19] Synthesis of Mat 19

Figure pat00113
Figure pat00113

반응물로 6-(4-클로로-6-(피리딘-3-일)-1,3,5-트리아진-2-일)퀴놀린을 사용한 것을 제외하고는 [합성예 1]과 동일한 과정을 수행하여 목적 화합물 9.8g을 얻었다.; HRMS [M]+: 617.20The same procedure as in [Synthesis Example 1] was performed except for using 6-(4-chloro-6-(pyridin-3-yl)-1,3,5-triazin-2-yl)quinoline as a reactant. 9.8 g of the target compound was obtained; HRMS [M]+: 617.20

[합성예 20] Mat 20의 합성[Synthesis Example 20] Synthesis of Mat 20

Figure pat00114
Figure pat00114

반응물로 9-(3-(4-클로로-6-페닐-1,3,5-트리아진-2-일)페닐)-9H-카바졸을 사용한 것을 제외하고는 [합성예 1]과 동일한 과정을 수행하여 목적 화합물 13.4g을 얻었다.; HRMS [M]+: 730.26Same procedure as [Synthesis Example 1] except that 9-(3-(4-chloro-6-phenyl-1,3,5-triazin-2-yl)phenyl)-9H-carbazole was used as the reactant was carried out to obtain 13.4 g of the target compound; HRMS [M]+: 730.26

[합성예 21] Mat 21의 합성[Synthesis Example 21] Synthesis of Mat 21

Figure pat00115
Figure pat00115

반응물로 9-(4-클로로-6-페닐-1,3,5-트리아진-2-일)-9H-카바졸을 사용한 것을 제외하고는 [합성예 1]과 동일한 과정을 수행하여 목적 화합물 12.4g을 얻었다.; HRMS [M]+: 654.22Except for using 9-(4-chloro-6-phenyl-1,3,5-triazin-2-yl)-9H-carbazole as a reactant, the same procedure as in [Synthesis Example 1] was performed to obtain the desired compound. 12.4 g was obtained; HRMS [M]+: 654.22

[합성예 22] Mat 22의 합성[Synthesis Example 22] Synthesis of Mat 22

Figure pat00116
Figure pat00116

반응물로 2,4-디클로로-6-페닐-1,3,5-트리아진을 사용한 것을 제외하고는 [합성예 1]과 동일한 과정을 수행하여 목적 화합물 10.6g을 얻었다.; HRMS [M]+: 820.27Except for using 2,4-dichloro-6-phenyl-1,3,5-triazine as a reactant, the same procedure as in [Synthesis Example 1] was performed to obtain 10.6 g of the target compound; HRMS [M]+: 820.27

[합성예 23] Mat 23의 합성[Synthesis Example 23] Synthesis of Mat 23

Figure pat00117
Figure pat00117

반응물로 2-([1,1'-비페닐]-3-일)-4-([1,1'-비페닐]-4-일)-6-클로로-1,3,5-트리아진을 사용한 것을 제외하고는 [합성예 1]과 동일한 과정을 수행하여 목적 화합물 12.2g을 얻었다.; HRMS [M]+: 717.262-([1,1'-biphenyl]-3-yl)-4-([1,1'-biphenyl]-4-yl)-6-chloro-1,3,5-triazine as reactant 12.2 g of the target compound was obtained by performing the same procedure as [Synthesis Example 1] except for using; HRMS [M]+: 717.26

[합성예 24] Mat 24의 합성[Synthesis Example 24] Synthesis of Mat 24

Figure pat00118
Figure pat00118

반응물로 2-([1,1'-비페닐]-3-일)-4-클로로-6-(나프탈렌-2-일)-1,3,5-트리아진을 사용한 것을 제외하고는 [합성예 1]과 동일한 과정을 수행하여 목적 화합물 8.5g을 얻었다.; HRMS [M]+: 691.25Except for using 2-([1,1'-biphenyl]-3-yl)-4-chloro-6-(naphthalen-2-yl)-1,3,5-triazine as the reactant [synthesis 8.5 g of the target compound was obtained by performing the same procedure as in [Example 1]; HRMS [M]+: 691.25

[합성예 25] Mat 25의 합성[Synthesis Example 25] Synthesis of Mat 25

Figure pat00119
Figure pat00119

반응물로 2-([1,1'-비페닐]-3-일)-4-클로로-6-(4-(피리딘-3-일)페닐)-1,3,5-트리아진을 사용한 것을 제외하고는 [합성예 1]과 동일한 과정을 수행하여 목적 화합물 11.8g을 얻었다.; HRMS [M]+: 718.262-([1,1'-biphenyl]-3-yl)-4-chloro-6-(4-(pyridin-3-yl)phenyl)-1,3,5-triazine was used as the reactant 11.8 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 1] except for; HRMS [M]+: 718.26

[합성예 26] Mat 26의 합성[Synthesis Example 26] Synthesis of Mat 26

Figure pat00120
Figure pat00120

반응물로 9-(4-클로로-6-(4-(피리딘-3-일)페닐)-1,3,5-트리아진-2-일)-9H-카바졸을 사용한 것을 제외하고는 [합성예 1]과 동일한 과정을 수행하여 목적 화합물 12.6g을 얻었다.; HRMS [M]+: 731.25Except for using 9-(4-chloro-6-(4-(pyridin-3-yl)phenyl)-1,3,5-triazin-2-yl)-9H-carbazole as the reactant [synthesis 12.6 g of the target compound was obtained by performing the same procedure as in [Example 1]; HRMS [M]+: 731.25

[합성예 27] Mat 27의 합성[Synthesis Example 27] Synthesis of Mat 27

Figure pat00121
Figure pat00121

반응물로 9-(4-클로로-6-(나프탈렌-2-일)-1,3,5-트리아진-2-일)-9H-카바졸을 사용한 것을 제외하고는 [합성예 1]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 704.24Same as [Synthesis Example 1] except that 9-(4-chloro-6-(naphthalen-2-yl)-1,3,5-triazin-2-yl)-9H-carbazole was used as the reactant. The process was carried out to obtain 13.2 g of the target compound; HRMS [M]+: 704.24

[합성예 28] Mat 28의 합성[Synthesis Example 28] Synthesis of Mat 28

Figure pat00122
Figure pat00122

반응물로 2-([1,1'-비페닐]-4-일)-4,6-디클로로-1,3,5-트리아진을 사용한 것을 제외하고는 [합성예 1]과 동일한 과정을 수행하여 목적 화합물 12.5g을 얻었다.; HRMS [M]+: 896.30The same procedure as in [Synthesis Example 1] was performed except for using 2-([1,1'-biphenyl]-4-yl)-4,6-dichloro-1,3,5-triazine as a reactant. 12.5 g of the target compound was obtained; HRMS [M]+: 896.30

[합성예 29] Mat 29의 합성[Synthesis Example 29] Synthesis of Mat 29

Figure pat00123
Figure pat00123

반응물로 2-([1,1'-비페닐]-3-일)-4,6-디클로로-1,3,5-트리아진을 사용한 것을 제외하고는 [합성예 1]과 동일한 과정을 수행하여 목적 화합물 12.4g을 얻었다.; HRMS [M]+: 896.30The same procedure as in [Synthesis Example 1] was performed except that 2-([1,1'-biphenyl]-3-yl)-4,6-dichloro-1,3,5-triazine was used as the reactant. 12.4 g of the target compound was obtained; HRMS [M]+: 896.30

[합성예 30] Mat 30의 합성[Synthesis Example 30] Synthesis of Mat 30

Figure pat00124
Figure pat00124

반응물로 9,9'-(6-클로로-1,3,5-트리아진-2,4-디일)비스(9H-카바졸을 사용한 것을 제외하고는 [합성예 1]과 동일한 과정을 수행하여 목적 화합물 12.5g을 얻었다.; HRMS [M]+: 743.25The same process as [Synthesis Example 1] was performed except that 9,9'-(6-chloro-1,3,5-triazine-2,4-diyl)bis(9H-carbazole was used as the reactant 12.5 g of the target compound was obtained; HRMS [M]+: 743.25

[합성예 31] Mat 31의 합성[Synthesis Example 31] Synthesis of Mat 31

Figure pat00125
Figure pat00125

반응물로 9-(4,6-디클로로-1,3,5-트리아진-2-일)-9H-카바졸을 사용한 것을 제외하고는 [합성예 1]과 동일한 과정을 수행하여 목적 화합물 13.1g을 얻었다.; HRMS [M]+: 909.29Except for using 9-(4,6-dichloro-1,3,5-triazin-2-yl)-9H-carbazole as a reactant, the same process as [Synthesis Example 1] was performed to obtain 13.1 g of the target compound. got .; HRMS [M]+: 909.29

[합성예 32] Mat 32의 합성[Synthesis Example 32] Synthesis of Mat 32

Figure pat00126
Figure pat00126

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 1]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 565.20Except for using [Preparation Example 2] as a reactant, 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 1]; HRMS [M]+: 565.20

[합성예 33] Mat 33의 합성[Synthesis Example 33] Synthesis of Mat 33

Figure pat00127
Figure pat00127

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 2]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 717.26Except for using [Preparation Example 2] as a reactant, 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 2]; HRMS [M]+: 717.26

[합성예 34] Mat 34의 합성[Synthesis Example 34] Synthesis of Mat 34

Figure pat00128
Figure pat00128

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 3]과 동일한 과정을 수행하여 목적 화합물 10.9g을 얻었다.; HRMS [M]+: 717.26Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 3] was performed to obtain 10.9 g of the target compound; HRMS [M]+: 717.26

[합성예 35] Mat 35의 합성[Synthesis Example 35] Synthesis of Mat 35

Figure pat00129
Figure pat00129

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 4]과 동일한 과정을 수행하여 목적 화합물 9.8g을 얻었다.; HRMS [M]+: 665.23Except for using [Preparation Example 2] as a reactant, 9.8 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 4]; HRMS [M]+: 665.23

[합성예 36] Mat 36의 합성[Synthesis Example 36] Synthesis of Mat 36

Figure pat00130
Figure pat00130

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 5]과 동일한 과정을 수행하여 목적 화합물 11g을 얻었다.; HRMS [M]+: 641.23Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 5] was performed to obtain 11 g of the target compound; HRMS [M]+: 641.23

[합성예 37] Mat 37의 합성[Synthesis Example 37] Synthesis of Mat 37

Figure pat00131
Figure pat00131

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 6]과 동일한 과정을 수행하여 목적 화합물 10.8g을 얻었다.; HRMS [M]+: 655.21Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 6] was performed to obtain 10.8 g of the target compound; HRMS [M]+: 655.21

[합성예 38] Mat 38의 합성[Synthesis Example 38] Synthesis of Mat 38

Figure pat00132
Figure pat00132

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 7]과 동일한 과정을 수행하여 목적 화합물 9.9g을 얻었다.; HRMS [M]+: 671.19Except for using [Preparation Example 2] as a reactant, 9.9 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 7]; HRMS [M]+: 671.19

[합성예 39] Mat 39의 합성[Synthesis Example 39] Synthesis of Mat 39

Figure pat00133
Figure pat00133

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 8]과 동일한 과정을 수행하여 목적 화합물 8.5g을 얻었다.; HRMS [M]+: 680.81Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 8] was performed to obtain 8.5 g of the target compound; HRMS [M]+: 680.81

[합성예 40] Mat 40의 합성[Synthesis Example 40] Synthesis of Mat 40

Figure pat00134
Figure pat00134

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 9]과 동일한 과정을 수행하여 목적 화합물 10.5g을 얻었다.; HRMS [M]+: 640.75Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 9] was performed to obtain 10.5 g of the target compound; HRMS [M]+: 640.75

[합성예 41] Mat 41의 합성[Synthesis Example 41] Synthesis of Mat 41

Figure pat00135
Figure pat00135

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 10]과 동일한 과정을 수행하여 목적 화합물 8.9g을 얻었다.; HRMS [M]+: 655.21Except for using [Preparation Example 2] as a reactant, 8.9 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 10]; HRMS [M]+: 655.21

[합성예 42] Mat 42의 합성[Synthesis Example 42] Synthesis of Mat 42

Figure pat00136
Figure pat00136

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 11]과 동일한 과정을 수행하여 목적 화합물 9.1g을 얻었다.; HRMS [M]+: 655.21Except for using [Preparation Example 2] as a reactant, 9.1 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 11]; HRMS [M]+: 655.21

[합성예 43] Mat 43의 합성[Synthesis Example 43] Synthesis of Mat 43

Figure pat00137
Figure pat00137

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 12]과 동일한 과정을 수행하여 목적 화합물 9.4g을 얻었다.; HRMS [M]+: 655.21Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 12] was performed to obtain 9.4 g of the target compound; HRMS [M]+: 655.21

[합성예 44] Mat 44의 합성[Synthesis Example 44] Synthesis of Mat 44

Figure pat00138
Figure pat00138

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 13]과 동일한 과정을 수행하여 목적 화합물 11.2 g을 얻었다.; HRMS [M]+: 642.22Except for using [Preparation Example 2] as a reactant, 11.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 13]; HRMS [M]+: 642.22

[합성예 45] Mat 45의 합성[Synthesis Example 45] Synthesis of Mat 45

Figure pat00139
Figure pat00139

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 14]과 동일한 과정을 수행하여 목적 화합물 10.8g을 얻었다.; HRMS [M]+: 642.22Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 14] was performed to obtain 10.8 g of the target compound; HRMS [M]+: 642.22

[합성예 46] Mat 46의 합성[Synthesis Example 46] Synthesis of Mat 46

Figure pat00140
Figure pat00140

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 15]과 동일한 과정을 수행하여 목적 화합물 12g을 얻었다.; HRMS [M]+: 642.22Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 15] was performed to obtain 12 g of the target compound; HRMS [M]+: 642.22

[합성예 47] Mat 47의 합성[Synthesis Example 47] Synthesis of Mat 47

Figure pat00141
Figure pat00141

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 16]과 동일한 과정을 수행하여 목적 화합물 12.3g을 얻었다.; HRMS [M]+: 642.22Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 16] was performed to obtain 12.3 g of the target compound; HRMS [M]+: 642.22

[합성예 48] Mat 48의 합성[Synthesis Example 48] Synthesis of Mat 48

Figure pat00142
Figure pat00142

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 17]과 동일한 과정을 수행하여 목적 화합물 8.2g을 얻었다.; HRMS [M]+: 643.22Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 17] was performed to obtain 8.2 g of the target compound; HRMS [M]+: 643.22

[합성예 49] Mat 49의 합성[Synthesis Example 49] Synthesis of Mat 49

Figure pat00143
Figure pat00143

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 18]과 동일한 과정을 수행하여 목적 화합물 8.5g을 얻었다.; HRMS [M]+: 616.21Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 18] was performed to obtain 8.5 g of the target compound; HRMS [M]+: 616.21

[합성예 50] Mat 50의 합성[Synthesis Example 50] Synthesis of Mat 50

Figure pat00144
Figure pat00144

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 19]과 동일한 과정을 수행하여 목적 화합물 9.8g을 얻었다.; HRMS [M]+: 617.20Except for using [Preparation Example 2] as a reactant, 9.8 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 19]; HRMS [M]+: 617.20

[합성예 51] Mat 51의 합성[Synthesis Example 51] Synthesis of Mat 51

Figure pat00145
Figure pat00145

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 20]과 동일한 과정을 수행하여 목적 화합물 13.4g을 얻었다.; HRMS [M]+: 730.26Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 20] was performed to obtain 13.4 g of the target compound; HRMS [M]+: 730.26

[합성예 52] Mat 52의 합성[Synthesis Example 52] Synthesis of Mat 52

Figure pat00146
Figure pat00146

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 21]과 동일한 과정을 수행하여 목적 화합물 12.4g을 얻었다.; HRMS [M]+: 654.22Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 21] was performed to obtain 12.4 g of the target compound; HRMS [M]+: 654.22

[합성예 53] Mat 53의 합성[Synthesis Example 53] Synthesis of Mat 53

Figure pat00147
Figure pat00147

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 22]과 동일한 과정을 수행하여 목적 화합물 10.6g을 얻었다.; HRMS [M]+: 820.27Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 22] was performed to obtain 10.6 g of the target compound; HRMS [M]+: 820.27

**

[합성예 54] Mat 54의 합성[Synthesis Example 54] Synthesis of Mat 54

Figure pat00148
Figure pat00148

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 23]과 동일한 과정을 수행하여 목적 화합물 12.2g을 얻었다.; HRMS [M]+: 717.26Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 23] was performed to obtain 12.2 g of the target compound; HRMS [M]+: 717.26

[합성예 55] Mat 55의 합성[Synthesis Example 55] Synthesis of Mat 55

Figure pat00149
Figure pat00149

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 24]과 동일한 과정을 수행하여 목적 화합물 8.5g을 얻었다.; HRMS [M]+: 691.25Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 24] was performed to obtain 8.5 g of the target compound; HRMS [M]+: 691.25

[합성예 56] Mat 56의 합성[Synthesis Example 56] Synthesis of Mat 56

Figure pat00150
Figure pat00150

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 25]과 동일한 과정을 수행하여 목적 화합물 11.8g을 얻었다.; HRMS [M]+: 718.26Except for using [Preparation Example 2] as a reactant, 11.8 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 25]; HRMS [M]+: 718.26

[합성예 57] Mat 57의 합성[Synthesis Example 57] Synthesis of Mat 57

Figure pat00151
Figure pat00151

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 26]과 동일한 과정을 수행하여 목적 화합물 12.6g을 얻었다.; HRMS [M]+: 731.25Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 26] was performed to obtain 12.6 g of the target compound; HRMS [M]+: 731.25

[합성예 58] Mat 58의 합성[Synthesis Example 58] Synthesis of Mat 58

Figure pat00152
Figure pat00152

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 27]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 704.24Except for using [Preparation Example 2] as a reactant, 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 27]; HRMS [M]+: 704.24

[합성예 59] Mat 59의 합성[Synthesis Example 59] Synthesis of Mat 59

Figure pat00153
Figure pat00153

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 28]과 동일한 과정을 수행하여 목적 화합물 12.5g을 얻었다.; HRMS [M]+: 896.30Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 28] was performed to obtain 12.5 g of the target compound; HRMS [M]+: 896.30

[합성예 60] Mat 60의 합성[Synthesis Example 60] Synthesis of Mat 60

Figure pat00154
Figure pat00154

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 29]과 동일한 과정을 수행하여 목적 화합물 12.4g을 얻었다.; HRMS [M]+: 896.30Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 29] was performed to obtain 12.4 g of the target compound; HRMS [M]+: 896.30

[합성예 61] Mat 61의 합성[Synthesis Example 61] Synthesis of Mat 61

Figure pat00155
Figure pat00155

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 30]과 동일한 과정을 수행하여 목적 화합물 12.5g을 얻었다.; HRMS [M]+: 743.25Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 30] was performed to obtain 12.5 g of the target compound; HRMS [M]+: 743.25

[합성예 62] Mat 62의 합성[Synthesis Example 62] Synthesis of Mat 62

Figure pat00156
Figure pat00156

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 31]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 909.20Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 31] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 909.20

[합성예 63] Mat 63의 합성[Synthesis Example 63] Synthesis of Mat 63

Figure pat00157
Figure pat00157

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 1]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 565.20Except for using [Preparation Example 3] as a reactant, 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 1]; HRMS [M]+: 565.20

**

[합성예 64] Mat 64의 합성[Synthesis Example 64] Synthesis of Mat 64

Figure pat00158
Figure pat00158

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 2]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 717.26Except for using [Preparation Example 3] as a reactant, 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 2]; HRMS [M]+: 717.26

[합성예 65] Mat 65의 합성[Synthesis Example 65] Synthesis of Mat 65

Figure pat00159
Figure pat00159

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 3]과 동일한 과정을 수행하여 목적 화합물 10.9g을 얻었다.; HRMS [M]+: 717.26Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 3] was performed to obtain 10.9 g of the target compound; HRMS [M]+: 717.26

[합성예 66] Mat 66의 합성[Synthesis Example 66] Synthesis of Mat 66

Figure pat00160
Figure pat00160

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 4]과 동일한 과정을 수행하여 목적 화합물 9.8g을 얻었다.; HRMS [M]+: 665.23Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 4] was performed to obtain 9.8 g of the target compound; HRMS [M]+: 665.23

[합성예 67] Mat 67의 합성[Synthesis Example 67] Synthesis of Mat 67

Figure pat00161
Figure pat00161

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 5]과 동일한 과정을 수행하여 목적 화합물 11g을 얻었다.; HRMS [M]+: 641.23Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 5] was performed to obtain 11 g of the target compound; HRMS [M]+: 641.23

[합성예 68] Mat 68의 합성[Synthesis Example 68] Synthesis of Mat 68

Figure pat00162
Figure pat00162

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 6]과 동일한 과정을 수행하여 목적 화합물 10.8g을 얻었다.; HRMS [M]+: 655.21Except for using [Preparation Example 3] as a reactant, 10.8 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 6]; HRMS [M]+: 655.21

[합성예 69] Mat 69의 합성[Synthesis Example 69] Synthesis of Mat 69

Figure pat00163
Figure pat00163

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 7]과 동일한 과정을 수행하여 목적 화합물 9.9g을 얻었다.; HRMS [M]+: 671.19Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 7] was performed to obtain 9.9 g of the target compound; HRMS [M]+: 671.19

[합성예 70] Mat 70의 합성[Synthesis Example 70] Synthesis of Mat 70

Figure pat00164
Figure pat00164

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 8]과 동일한 과정을 수행하여 목적 화합물 8.5g을 얻었다.; HRMS [M]+: 680.81Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 8] was performed to obtain 8.5 g of the target compound; HRMS [M]+: 680.81

[합성예 71] Mat 71의 합성[Synthesis Example 71] Synthesis of Mat 71

Figure pat00165
Figure pat00165

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 9]과 동일한 과정을 수행하여 목적 화합물 10.5g을 얻었다.; HRMS [M]+: 640.75Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 9] was performed to obtain 10.5 g of the target compound; HRMS [M]+: 640.75

[합성예 72] Mat 72의 합성[Synthesis Example 72] Synthesis of Mat 72

Figure pat00166
Figure pat00166

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 10]과 동일한 과정을 수행하여 목적 화합물 8.9g을 얻었다.; HRMS [M]+: 655.21Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 10] was performed to obtain 8.9 g of the target compound; HRMS [M]+: 655.21

[합성예 73] Mat 73의 합성[Synthesis Example 73] Synthesis of Mat 73

Figure pat00167
Figure pat00167

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 11]과 동일한 과정을 수행하여 목적 화합물 9.1g을 얻었다.; HRMS [M]+: 655.21Except for using [Preparation Example 3] as a reactant, 9.1 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 11]; HRMS [M]+: 655.21

[합성예 74] Mat 74의 합성[Synthesis Example 74] Synthesis of Mat 74

Figure pat00168
Figure pat00168

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 12]과 동일한 과정을 수행하여 목적 화합물 9.4g을 얻었다.; HRMS [M]+: 655.21Except for using [Preparation Example 3] as a reactant, 9.4 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 12]; HRMS [M]+: 655.21

[합성예 75] Mat 75의 합성[Synthesis Example 75] Synthesis of Mat 75

Figure pat00169
Figure pat00169

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 13]과 동일한 과정을 수행하여 목적 화합물 11.2 g을 얻었다.; HRMS [M]+: 642.22Except for using [Preparation Example 3] as a reactant, 11.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 13]; HRMS [M]+: 642.22

[합성예 76] Mat 76의 합성[Synthesis Example 76] Synthesis of Mat 76

Figure pat00170
Figure pat00170

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 14]과 동일한 과정을 수행하여 목적 화합물 10.8g을 얻었다.; HRMS [M]+: 642.22Except for using [Preparation Example 3] as a reactant, 10.8 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 14]; HRMS [M]+: 642.22

[합성예 77] Mat 77의 합성[Synthesis Example 77] Synthesis of Mat 77

Figure pat00171
Figure pat00171

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 15]과 동일한 과정을 수행하여 목적 화합물 12g을 얻었다.; HRMS [M]+: 642.22Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 15] was performed to obtain 12 g of the target compound; HRMS [M]+: 642.22

[합성예 78] Mat 78의 합성[Synthesis Example 78] Synthesis of Mat 78

Figure pat00172
Figure pat00172

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 16]과 동일한 과정을 수행하여 목적 화합물 12.3g을 얻었다.; HRMS [M]+: 642.22Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 16] was performed to obtain 12.3 g of the target compound; HRMS [M]+: 642.22

[합성예 79] Mat 79의 합성[Synthesis Example 79] Synthesis of Mat 79

Figure pat00173
Figure pat00173

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 17]과 동일한 과정을 수행하여 목적 화합물 8.2g을 얻었다.; HRMS [M]+: 643.22Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 17] was performed to obtain 8.2 g of the target compound; HRMS [M]+: 643.22

[합성예 80] Mat 80의 합성[Synthesis Example 80] Synthesis of Mat 80

Figure pat00174
Figure pat00174

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 18]과 동일한 과정을 수행하여 목적 화합물 8.5g을 얻었다.; HRMS [M]+: 616.21Except for using [Preparation Example 3] as a reactant, 8.5 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 18]; HRMS [M]+: 616.21

[합성예 81] Mat 81의 합성[Synthesis Example 81] Synthesis of Mat 81

Figure pat00175
Figure pat00175

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 19]과 동일한 과정을 수행하여 목적 화합물 9.8g을 얻었다.; HRMS [M]+: 617.20Except for using [Preparation Example 3] as a reactant, 9.8 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 19]; HRMS [M]+: 617.20

[합성예 82] Mat 82의 합성[Synthesis Example 82] Synthesis of Mat 82

Figure pat00176
Figure pat00176

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 20]과 동일한 과정을 수행하여 목적 화합물 13.4g을 얻었다.; HRMS [M]+: 730.26Except for using [Preparation Example 3] as a reactant, 13.4 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 20]; HRMS [M]+: 730.26

[합성예 83] Mat 83의 합성[Synthesis Example 83] Synthesis of Mat 83

Figure pat00177
Figure pat00177

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 21]과 동일한 과정을 수행하여 목적 화합물 12.4g을 얻었다.; HRMS [M]+: 654.22Except for using [Preparation Example 3] as a reactant, 12.4 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 21]; HRMS [M]+: 654.22

[합성예 84] Mat 84의 합성[Synthesis Example 84] Synthesis of Mat 84

Figure pat00178
Figure pat00178

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 22]과 동일한 과정을 수행하여 목적 화합물 10.6g을 얻었다.; HRMS [M]+: 820.27Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 22] was performed to obtain 10.6 g of the target compound; HRMS [M]+: 820.27

[합성예 85] Mat 85의 합성[Synthesis Example 85] Synthesis of Mat 85

Figure pat00179
Figure pat00179

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 23]과 동일한 과정을 수행하여 목적 화합물 12.2g을 얻었다.; HRMS [M]+: 717.26Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 23] was performed to obtain 12.2 g of the target compound; HRMS [M]+: 717.26

[합성예 86] Mat 86의 합성[Synthesis Example 86] Synthesis of Mat 86

Figure pat00180
Figure pat00180

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 24]과 동일한 과정을 수행하여 목적 화합물 8.5g을 얻었다.; HRMS [M]+: 691.25Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 24] was performed to obtain 8.5 g of the target compound; HRMS [M]+: 691.25

[합성예 87] Mat 87의 합성[Synthesis Example 87] Synthesis of Mat 87

Figure pat00181
Figure pat00181

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 25]과 동일한 과정을 수행하여 목적 화합물 11.8g을 얻었다.; HRMS [M]+: 718.26Except for using [Preparation Example 3] as a reactant, 11.8 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 25]; HRMS [M]+: 718.26

**

[합성예 88] Mat 88의 합성[Synthesis Example 88] Synthesis of Mat 88

Figure pat00182
Figure pat00182

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 26]과 동일한 과정을 수행하여 목적 화합물 12.6g을 얻었다.; HRMS [M]+: 731.25Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 26] was performed to obtain 12.6 g of the target compound; HRMS [M]+: 731.25

[합성예 89] Mat 89의 합성[Synthesis Example 89] Synthesis of Mat 89

Figure pat00183
Figure pat00183

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 27]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 704.24Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 27] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 704.24

[합성예 90] Mat 90의 합성[Synthesis Example 90] Synthesis of Mat 90

Figure pat00184
Figure pat00184

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 28]과 동일한 과정을 수행하여 목적 화합물 12.5g을 얻었다.; HRMS [M]+: 896.3012.5 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 28] except that [Preparation Example 3] was used as a reactant; HRMS [M]+: 896.30

[합성예 91] Mat 91의 합성[Synthesis Example 91] Synthesis of Mat 91

Figure pat00185
Figure pat00185

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 29]과 동일한 과정을 수행하여 목적 화합물 12.4g을 얻었다.; HRMS [M]+: 896.30Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 29] was performed to obtain 12.4 g of the target compound; HRMS [M]+: 896.30

[합성예 92] Mat 92의 합성[Synthesis Example 92] Synthesis of Mat 92

Figure pat00186
Figure pat00186

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 30]과 동일한 과정을 수행하여 목적 화합물 12.5g을 얻었다.; HRMS [M]+: 743.25Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 30] was performed to obtain 12.5 g of the target compound; HRMS [M]+: 743.25

[합성예 93] Mat 93의 합성[Synthesis Example 93] Synthesis of Mat 93

Figure pat00187
Figure pat00187

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 31]과 동일한 과정을 수행하여 목적 화합물 13.1g을 얻었다.; HRMS [M]+: 909.29Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 31] was performed to obtain 13.1 g of the target compound; HRMS [M]+: 909.29

[합성예 94] Mat 94의 합성[Synthesis Example 94] Synthesis of Mat 94

Figure pat00188
Figure pat00188

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 1]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 565.20Except for using [Preparation Example 4] as a reactant, 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 1]; HRMS [M]+: 565.20

[합성예 95] Mat 95의 합성[Synthesis Example 95] Synthesis of Mat 95

Figure pat00189
Figure pat00189

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 2]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 717.26Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 2] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 717.26

[합성예 96] Mat 96의 합성[Synthesis Example 96] Synthesis of Mat 96

Figure pat00190
Figure pat00190

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 3]과 동일한 과정을 수행하여 목적 화합물 10.9g을 얻었다.; HRMS [M]+: 717.26Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 3] was performed to obtain 10.9 g of the target compound; HRMS [M]+: 717.26

[합성예 97] Mat 97의 합성[Synthesis Example 97] Synthesis of Mat 97

Figure pat00191
Figure pat00191

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 4]과 동일한 과정을 수행하여 목적 화합물 9.8g을 얻었다.; HRMS [M]+: 665.23Except for using [Preparation Example 4] as a reactant, 9.8 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 4]; HRMS [M]+: 665.23

[합성예 98] Mat 98의 합성[Synthesis Example 98] Synthesis of Mat 98

Figure pat00192
Figure pat00192

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 5]과 동일한 과정을 수행하여 목적 화합물 11g을 얻었다.; HRMS [M]+: 641.23Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 5] was performed to obtain 11 g of the target compound; HRMS [M]+: 641.23

[합성예 99] Mat 99의 합성[Synthesis Example 99] Synthesis of Mat 99

Figure pat00193
Figure pat00193

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 6]과 동일한 과정을 수행하여 목적 화합물 10.8g을 얻었다.; HRMS [M]+: 655.21Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 6] was performed to obtain 10.8 g of the target compound; HRMS [M]+: 655.21

[합성예 100] Mat 100의 합성[Synthesis Example 100] Synthesis of Mat 100

Figure pat00194
Figure pat00194

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 7]과 동일한 과정을 수행하여 목적 화합물 9.9g을 얻었다.; HRMS [M]+: 671.19Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 7] was performed to obtain 9.9 g of the target compound; HRMS [M]+: 671.19

[합성예 101] Mat 101의 합성[Synthesis Example 101] Synthesis of Mat 101

Figure pat00195
Figure pat00195

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 8]과 동일한 과정을 수행하여 목적 화합물 8.5g을 얻었다.; HRMS [M]+: 680.81Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 8] was performed to obtain 8.5 g of the target compound; HRMS [M]+: 680.81

[합성예 102] Mat 102의 합성[Synthesis Example 102] Synthesis of Mat 102

Figure pat00196
Figure pat00196

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 9]과 동일한 과정을 수행하여 목적 화합물 10.5g을 얻었다.; HRMS [M]+: 640.75Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 9] was performed to obtain 10.5 g of the target compound; HRMS [M]+: 640.75

[합성예 103] Mat 103의 합성[Synthesis Example 103] Synthesis of Mat 103

Figure pat00197
Figure pat00197

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 10]과 동일한 과정을 수행하여 목적 화합물 8.9g을 얻었다.; HRMS [M]+: 655.21Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 10] was performed to obtain 8.9 g of the target compound; HRMS [M]+: 655.21

[합성예 104] Mat 104의 합성[Synthesis Example 104] Synthesis of Mat 104

Figure pat00198
Figure pat00198

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 11]과 동일한 과정을 수행하여 목적 화합물 9.1g을 얻었다.; HRMS [M]+: 655.21Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 11] was performed to obtain 9.1 g of the target compound; HRMS [M]+: 655.21

[합성예 105] Mat 105의 합성[Synthesis Example 105] Synthesis of Mat 105

Figure pat00199
Figure pat00199

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 12]과 동일한 과정을 수행하여 목적 화합물 9.4g을 얻었다.; HRMS [M]+: 655.21Except for using [Preparation Example 4] as a reactant, 9.4 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 12]; HRMS [M]+: 655.21

[합성예 106] Mat 106의 합성[Synthesis Example 106] Synthesis of Mat 106

Figure pat00200
Figure pat00200

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 13]과 동일한 과정을 수행하여 목적 화합물 11.2 g을 얻었다.; HRMS [M]+: 642.2211.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 13] except that [Preparation Example 4] was used as a reactant; HRMS [M]+: 642.22

[합성예 107] Mat 107의 합성[Synthesis Example 107] Synthesis of Mat 107

Figure pat00201
Figure pat00201

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 14]과 동일한 과정을 수행하여 목적 화합물 10.8g을 얻었다.; HRMS [M]+: 642.22Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 14] was performed to obtain 10.8 g of the target compound; HRMS [M]+: 642.22

[합성예 108] Mat 108의 합성[Synthesis Example 108] Synthesis of Mat 108

Figure pat00202
Figure pat00202

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 15]과 동일한 과정을 수행하여 목적 화합물 12g을 얻었다.; HRMS [M]+: 642.22Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 15] was performed to obtain 12 g of the target compound; HRMS [M]+: 642.22

[합성예 109] Mat 109의 합성[Synthesis Example 109] Synthesis of Mat 109

Figure pat00203
Figure pat00203

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 16]과 동일한 과정을 수행하여 목적 화합물 12.3g을 얻었다.; HRMS [M]+: 642.22Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 16] was performed to obtain 12.3 g of the target compound; HRMS [M]+: 642.22

[합성예 110] Mat 110의 합성[Synthesis Example 110] Synthesis of Mat 110

Figure pat00204
Figure pat00204

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 17]과 동일한 과정을 수행하여 목적 화합물 8.2g을 얻었다.; HRMS [M]+: 643.22Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 17] was performed to obtain 8.2 g of the target compound; HRMS [M]+: 643.22

[합성예 111] Mat 111의 합성[Synthesis Example 111] Synthesis of Mat 111

Figure pat00205
Figure pat00205

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 18]과 동일한 과정을 수행하여 목적 화합물 8.5g을 얻었다.; HRMS [M]+: 616.21Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 18] was performed to obtain 8.5 g of the target compound; HRMS [M]+: 616.21

[합성예 112] Mat 112의 합성[Synthesis Example 112] Synthesis of Mat 112

Figure pat00206
Figure pat00206

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 19]과 동일한 과정을 수행하여 목적 화합물 9.8g을 얻었다.; HRMS [M]+: 617.20Except for using [Preparation Example 4] as a reactant, 9.8 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 19]; HRMS [M]+: 617.20

[합성예 113] Mat 113의 합성[Synthesis Example 113] Synthesis of Mat 113

Figure pat00207
Figure pat00207

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 20]과 동일한 과정을 수행하여 목적 화합물 13.4g을 얻었다.; HRMS [M]+: 730.26Except for using [Preparation Example 4] as a reactant, 13.4 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 20]; HRMS [M]+: 730.26

[합성예 114] Mat 114의 합성[Synthesis Example 114] Synthesis of Mat 114

Figure pat00208
Figure pat00208

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 21]과 동일한 과정을 수행하여 목적 화합물 12.4g을 얻었다.; HRMS [M]+: 654.22Except for using [Preparation Example 4] as a reactant, 12.4 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 21]; HRMS [M]+: 654.22

[합성예 115] Mat 115의 합성[Synthesis Example 115] Synthesis of Mat 115

Figure pat00209
Figure pat00209

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 22]과 동일한 과정을 수행하여 목적 화합물 10.6g을 얻었다.; HRMS [M]+: 820.27Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 22] was performed to obtain 10.6 g of the target compound; HRMS [M]+: 820.27

[합성예 116] Mat 116의 합성[Synthesis Example 116] Synthesis of Mat 116

Figure pat00210
Figure pat00210

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 23]과 동일한 과정을 수행하여 목적 화합물 12.2g을 얻었다.; HRMS [M]+: 717.26Except for using [Preparation Example 4] as a reactant, 12.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 23]; HRMS [M]+: 717.26

[합성예 117] Mat 117의 합성[Synthesis Example 117] Synthesis of Mat 117

Figure pat00211
Figure pat00211

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 24]과 동일한 과정을 수행하여 목적 화합물 8.5g을 얻었다.; HRMS [M]+: 691.25Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 24] was performed to obtain 8.5 g of the target compound; HRMS [M]+: 691.25

[합성예 118] Mat 118의 합성[Synthesis Example 118] Synthesis of Mat 118

Figure pat00212
Figure pat00212

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 25]과 동일한 과정을 수행하여 목적 화합물 11.8g을 얻었다.; HRMS [M]+: 718.26Except for using [Preparation Example 4] as a reactant, 11.8 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 25]; HRMS [M]+: 718.26

[합성예 119] Mat 119의 합성[Synthesis Example 119] Synthesis of Mat 119

Figure pat00213
Figure pat00213

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 26]과 동일한 과정을 수행하여 목적 화합물 12.6g을 얻었다.; HRMS [M]+: 731.25Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 26] was performed to obtain 12.6 g of the target compound; HRMS [M]+: 731.25

[합성예 120] Mat 120의 합성[Synthesis Example 120] Synthesis of Mat 120

Figure pat00214
Figure pat00214

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 27]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 704.24Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 27] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 704.24

[합성예 121] Mat 121의 합성[Synthesis Example 121] Synthesis of Mat 121

Figure pat00215
Figure pat00215

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 28]과 동일한 과정을 수행하여 목적 화합물 12.5g을 얻었다.; HRMS [M]+: 896.30Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 28] was performed to obtain 12.5 g of the target compound; HRMS [M]+: 896.30

[합성예 122] Mat 122의 합성[Synthesis Example 122] Synthesis of Mat 122

Figure pat00216
Figure pat00216

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 29]과 동일한 과정을 수행하여 목적 화합물 12.4g을 얻었다.; HRMS [M]+: 896.30Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 29] was performed to obtain 12.4 g of the target compound; HRMS [M]+: 896.30

[합성예 123] Mat 123의 합성[Synthesis Example 123] Synthesis of Mat 123

Figure pat00217
Figure pat00217

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 30]과 동일한 과정을 수행하여 목적 화합물 12.5g을 얻었다.; HRMS [M]+: 743.25Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 30] was performed to obtain 12.5 g of the target compound; HRMS [M]+: 743.25

[합성예 124] Mat 124의 합성[Synthesis Example 124] Synthesis of Mat 124

Figure pat00218
Figure pat00218

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 31]과 동일한 과정을 수행하여 목적 화합물 13.1g을 얻었다.; HRMS [M]+: 909.29Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 31] was performed to obtain 13.1 g of the target compound; HRMS [M]+: 909.29

[합성예 125] Mat 125의 합성[Synthesis Example 125] Synthesis of Mat 125

Figure pat00219
Figure pat00219

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 1]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 581.18Except for using [Preparation Example 5] as a reactant, 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 1]; HRMS [M]+: 581.18

[합성예 126] Mat 126의 합성[Synthesis Example 126] Synthesis of Mat 126

Figure pat00220
Figure pat00220

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 2]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 733.24Except for using [Preparation Example 5] as a reactant, 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 2]; HRMS [M]+: 733.24

[합성예 127] Mat 127의 합성[Synthesis Example 127] Synthesis of Mat 127

Figure pat00221
Figure pat00221

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 3]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 733.24Except for using [Preparation Example 5] as a reactant, 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 3]; HRMS [M]+: 733.24

[합성예 128] Mat 128의 합성[Synthesis Example 128] Synthesis of Mat 128

Figure pat00222
Figure pat00222

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 4]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 681.21Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 4] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 681.21

[합성예 129] Mat 129의 합성[Synthesis Example 129] Synthesis of Mat 129

Figure pat00223
Figure pat00223

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 5]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 657.21Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 5] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 657.21

[합성예 130] Mat 130의 합성[Synthesis Example 130] Synthesis of Mat 130

Figure pat00224
Figure pat00224

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 6]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 671.19Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 6] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 671.19

[합성예 131] Mat 131의 합성[Synthesis Example 131] Synthesis of Mat 131

Figure pat00225
Figure pat00225

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 7]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 687.16Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 7] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 687.16

[합성예 132] Mat 132의 합성[Synthesis Example 132] Synthesis of Mat 132

Figure pat00226
Figure pat00226

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 8]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 697.24Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 8] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 697.24

[합성예 133] Mat 133의 합성[Synthesis Example 133] Synthesis of Mat 133

Figure pat00227
Figure pat00227

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 9]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 657.21Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 9] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 657.21

[합성예 134] Mat 134의 합성[Synthesis Example 134] Synthesis of Mat 134

Figure pat00228
Figure pat00228

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 10]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 671.19Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 10] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 671.19

[합성예 135] Mat 135의 합성[Synthesis Example 135] Synthesis of Mat 135

Figure pat00229
Figure pat00229

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 11]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 671.19Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 11] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 671.19

[합성예 136] Mat 136의 합성[Synthesis Example 136] Synthesis of Mat 136

Figure pat00230
Figure pat00230

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 12]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 671.19Except for using [Preparation Example 5] as a reactant, 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 12]; HRMS [M]+: 671.19

[합성예 137] Mat 137의 합성[Synthesis Example 137] Synthesis of Mat 137

Figure pat00231
Figure pat00231

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 13]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 658.20Except for using [Preparation Example 5] as a reactant, 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 13]; HRMS [M]+: 658.20

[합성예 138] Mat 138의 합성[Synthesis Example 138] Synthesis of Mat 138

Figure pat00232
Figure pat00232

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 14]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 658.20Except for using [Preparation Example 5] as a reactant, 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 14]; HRMS [M]+: 658.20

[합성예 139] Mat 139의 합성[Synthesis Example 139] Synthesis of Mat 139

Figure pat00233
Figure pat00233

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 15]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 658.20Except for using [Preparation Example 5] as a reactant, 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 15]; HRMS [M]+: 658.20

[합성예 140] Mat 140의 합성[Synthesis Example 140] Synthesis of Mat 140

Figure pat00234
Figure pat00234

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 16]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 658.20Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 16] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 658.20

[합성예 141] Mat 141의 합성[Synthesis Example 141] Synthesis of Mat 141

Figure pat00235
Figure pat00235

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 17]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 659.20Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 17] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 659.20

[합성예 142] Mat 142의 합성[Synthesis Example 142] Synthesis of Mat 142

Figure pat00236
Figure pat00236

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 18]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 632.19Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 18] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 632.19

[합성예 143] Mat 143의 합성[Synthesis Example 143] Synthesis of Mat 143

Figure pat00237
Figure pat00237

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 19]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 633.18Except for using [Preparation Example 5] as a reactant, 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 19]; HRMS [M]+: 633.18

[합성예 144] Mat 144의 합성[Synthesis Example 144] Synthesis of Mat 144

Figure pat00238
Figure pat00238

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 20]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 746.23Except for using [Preparation Example 5] as a reactant, 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 20]; HRMS [M]+: 746.23

[합성예 145] Mat 145의 합성[Synthesis Example 145] Synthesis of Mat 145

Figure pat00239
Figure pat00239

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 21]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 670.20Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 21] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 670.20

[합성예 146] Mat 146의 합성[Synthesis Example 146] Synthesis of Mat 146

Figure pat00240
Figure pat00240

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 22]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 852.22Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 22] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 852.22

[합성예 147] Mat 147의 합성[Synthesis Example 147] Synthesis of Mat 147

Figure pat00241
Figure pat00241

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 23]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 733.24Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 23] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 733.24

[합성예 148] Mat 148의 합성[Synthesis Example 148] Synthesis of Mat 148

Figure pat00242
Figure pat00242

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 24]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 707.22Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 24] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 707.22

[합성예 149] Mat 149의 합성[Synthesis Example 149] Synthesis of Mat 149

Figure pat00243
Figure pat00243

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 25]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 734.23Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 25] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 734.23

[합성예 150] Mat 150의 합성[Synthesis Example 150] Synthesis of Mat 150

Figure pat00244
Figure pat00244

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 26]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+:747.23Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 26] was performed to obtain 13.2 g of the target compound; HRMS [M]+:747.23

[합성예 151] Mat 151의 합성[Synthesis Example 151] Synthesis of Mat 151

Figure pat00245
Figure pat00245

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 27]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 720.22Except for using [Preparation Example 5] as a reactant, 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 27]; HRMS [M]+: 720.22

[합성예 152] Mat 152의 합성[Synthesis Example 152] Synthesis of Mat 152

Figure pat00246
Figure pat00246

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 28]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 928.25Except for using [Preparation Example 5] as a reactant, 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 28]; HRMS [M]+: 928.25

[합성예 153] Mat 153의 합성[Synthesis Example 153] Synthesis of Mat 153

Figure pat00247
Figure pat00247

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 29]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 928.25Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 29] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 928.25

[합성예 154] Mat 154의 합성[Synthesis Example 154] Synthesis of Mat 154

Figure pat00248
Figure pat00248

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 30]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 759.23Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 30] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 759.23

[합성예 155] Mat 155의 합성[Synthesis Example 155] Synthesis of Mat 155

Figure pat00249
Figure pat00249

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 31]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 941.25Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 31] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 941.25

[합성예 156] Mat 156의 합성[Synthesis Example 156] Synthesis of Mat 156

Figure pat00250
Figure pat00250

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 1]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 581.18Except for using [Preparation Example 6] as a reactant, 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 1]; HRMS [M]+: 581.18

[합성예 157] Mat 157의 합성[Synthesis Example 157] Synthesis of Mat 157

Figure pat00251
Figure pat00251

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 2]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 733.24Except for using [Preparation Example 6] as a reactant, 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 2]; HRMS [M]+: 733.24

**

[합성예 158] Mat 158의 합성[Synthesis Example 158] Synthesis of Mat 158

Figure pat00252
Figure pat00252

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 3]과 동일한 과정을 수행하여 목적 화합물 10.9g을 얻었다.; HRMS [M]+: 733.24Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 3] was performed to obtain 10.9 g of the target compound; HRMS [M]+: 733.24

[합성예 159] Mat 159의 합성[Synthesis Example 159] Synthesis of Mat 159

Figure pat00253
Figure pat00253

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 4]과 동일한 과정을 수행하여 목적 화합물 9.8g을 얻었다.; HRMS [M]+: 681.21Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 4] was performed to obtain 9.8 g of the target compound; HRMS [M]+: 681.21

[합성예 160] Mat 160의 합성[Synthesis Example 160] Synthesis of Mat 160

Figure pat00254
Figure pat00254

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 5]과 동일한 과정을 수행하여 목적 화합물 11g을 얻었다.; HRMS [M]+: 657.21Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 5] was performed to obtain 11 g of the target compound; HRMS [M]+: 657.21

[합성예 161] Mat 161의 합성[Synthesis Example 161] Synthesis of Mat 161

Figure pat00255
Figure pat00255

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 6]과 동일한 과정을 수행하여 목적 화합물 10.8g을 얻었다.; HRMS [M]+: 671.19Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 6] was performed to obtain 10.8 g of the target compound; HRMS [M]+: 671.19

[합성예 162] Mat 162의 합성[Synthesis Example 162] Synthesis of Mat 162

Figure pat00256
Figure pat00256

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 7]과 동일한 과정을 수행하여 목적 화합물 9.9g을 얻었다.; HRMS [M]+: 687.16Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 7] was performed to obtain 9.9 g of the target compound; HRMS [M]+: 687.16

[합성예 163] Mat 163의 합성[Synthesis Example 163] Synthesis of Mat 163

Figure pat00257
Figure pat00257

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 8]과 동일한 과정을 수행하여 목적 화합물 8.5g을 얻었다.; HRMS [M]+: 697.24Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 8] was performed to obtain 8.5 g of the target compound; HRMS [M]+: 697.24

[합성예 164] Mat 164의 합성[Synthesis Example 164] Synthesis of Mat 164

Figure pat00258
Figure pat00258

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 9]과 동일한 과정을 수행하여 목적 화합물 10.5g을 얻었다.; HRMS [M]+: 657.21Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 9] was performed to obtain 10.5 g of the target compound; HRMS [M]+: 657.21

[합성예 165] Mat 165의 합성[Synthesis Example 165] Synthesis of Mat 165

Figure pat00259
Figure pat00259

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 10]과 동일한 과정을 수행하여 목적 화합물 8.9g을 얻었다.; HRMS [M]+: 671.19Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 10] was performed to obtain 8.9 g of the target compound; HRMS [M]+: 671.19

[합성예 166] Mat 166의 합성[Synthesis Example 166] Synthesis of Mat 166

Figure pat00260
Figure pat00260

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 11]과 동일한 과정을 수행하여 목적 화합물 9.1g을 얻었다.; HRMS [M]+: 671.19Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 11] was performed to obtain 9.1 g of the target compound; HRMS [M]+: 671.19

[합성예 167] Mat 167의 합성[Synthesis Example 167] Synthesis of Mat 167

*

Figure pat00261
*
Figure pat00261

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 12]과 동일한 과정을 수행하여 목적 화합물 9.4g을 얻었다.; HRMS [M]+: 671.19Except for using [Preparation Example 6] as a reactant, 9.4 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 12]; HRMS [M]+: 671.19

[합성예 168] Mat 168의 합성[Synthesis Example 168] Synthesis of Mat 168

Figure pat00262
Figure pat00262

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 13]과 동일한 과정을 수행하여 목적 화합물 11.2 g을 얻었다.; HRMS [M]+: 658.20Except for using [Preparation Example 6] as a reactant, 11.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 13]; HRMS [M]+: 658.20

[합성예 169] Mat 169의 합성[Synthesis Example 169] Synthesis of Mat 169

Figure pat00263
Figure pat00263

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 14]과 동일한 과정을 수행하여 목적 화합물 10.8g을 얻었다.; HRMS [M]+: 658.20Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 14] was performed to obtain 10.8 g of the target compound; HRMS [M]+: 658.20

[합성예 170] Mat 170의 합성[Synthesis Example 170] Synthesis of Mat 170

Figure pat00264
Figure pat00264

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 15]과 동일한 과정을 수행하여 목적 화합물 12g을 얻었다.; HRMS [M]+: 658.20Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 15] was performed to obtain 12 g of the target compound; HRMS [M]+: 658.20

[합성예 171] Mat 171의 합성[Synthesis Example 171] Synthesis of Mat 171

Figure pat00265
Figure pat00265

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 16]과 동일한 과정을 수행하여 목적 화합물 12.3g을 얻었다.; HRMS [M]+: 658.20Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 16] was performed to obtain 12.3 g of the target compound; HRMS [M]+: 658.20

[합성예 172] Mat 172의 합성[Synthesis Example 172] Synthesis of Mat 172

Figure pat00266
Figure pat00266

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 17]과 동일한 과정을 수행하여 목적 화합물 8.2g을 얻었다.; HRMS [M]+: 659.70Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 17] was performed to obtain 8.2 g of the target compound; HRMS [M]+: 659.70

[합성예 173] Mat 173의 합성[Synthesis Example 173] Synthesis of Mat 173

*

Figure pat00267
*
Figure pat00267

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 18]과 동일한 과정을 수행하여 목적 화합물 8.5g을 얻었다.; HRMS [M]+: 632.19Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 18] was performed to obtain 8.5 g of the target compound; HRMS [M]+: 632.19

[합성예 174] Mat 174의 합성[Synthesis Example 174] Synthesis of Mat 174

Figure pat00268
Figure pat00268

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 19]과 동일한 과정을 수행하여 목적 화합물 9.8g을 얻었다.; HRMS [M]+: 633.18Except for using [Preparation Example 6] as a reactant, 9.8 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 19]; HRMS [M]+: 633.18

[합성예 175] Mat 175의 합성[Synthesis Example 175] Synthesis of Mat 175

Figure pat00269
Figure pat00269

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 20]과 동일한 과정을 수행하여 목적 화합물 13.4g을 얻었다.; HRMS [M]+: 746.23Except for using [Preparation Example 6] as a reactant, 13.4 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 20]; HRMS [M]+: 746.23

[합성예 176] Mat 176의 합성[Synthesis Example 176] Synthesis of Mat 176

Figure pat00270
Figure pat00270

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 21]과 동일한 과정을 수행하여 목적 화합물 12.4g을 얻었다.; HRMS [M]+: 670.20Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 21] was performed to obtain 12.4 g of the target compound; HRMS [M]+: 670.20

[합성예 177] Mat 177의 합성[Synthesis Example 177] Synthesis of Mat 177

Figure pat00271
Figure pat00271

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 22]과 동일한 과정을 수행하여 목적 화합물 10.6g을 얻었다.; HRMS [M]+: 852.22Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 22] was performed to obtain 10.6 g of the target compound; HRMS [M]+: 852.22

[합성예 178] Mat 178의 합성[Synthesis Example 178] Synthesis of Mat 178

Figure pat00272
Figure pat00272

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 23]과 동일한 과정을 수행하여 목적 화합물 12.2g을 얻었다.; HRMS [M]+: 733.24Except for using [Preparation Example 6] as a reactant, 12.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 23]; HRMS [M]+: 733.24

[합성예 179] Mat 179의 합성[Synthesis Example 179] Synthesis of Mat 179

Figure pat00273
Figure pat00273

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 24]과 동일한 과정을 수행하여 목적 화합물 8.5g을 얻었다.; HRMS [M]+: 702.22Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 24] was performed to obtain 8.5 g of the target compound; HRMS [M]+: 702.22

[합성예 180] Mat 180의 합성[Synthesis Example 180] Synthesis of Mat 180

Figure pat00274
Figure pat00274

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 25]과 동일한 과정을 수행하여 목적 화합물 11.8g을 얻었다.; HRMS [M]+: 734.23Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 25] was performed to obtain 11.8 g of the target compound; HRMS [M]+: 734.23

[합성예 181] Mat 181의 합성[Synthesis Example 181] Synthesis of Mat 181

Figure pat00275
Figure pat00275

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 26]과 동일한 과정을 수행하여 목적 화합물 12.6g을 얻었다.; HRMS [M]+: 747.23Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 26] was performed to obtain 12.6 g of the target compound; HRMS [M]+: 747.23

[합성예 182] Mat 182의 합성[Synthesis Example 182] Synthesis of Mat 182

Figure pat00276
Figure pat00276

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 27]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 720.22Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 27] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 720.22

[합성예 183] Mat 183의 합성[Synthesis Example 183] Synthesis of Mat 183

Figure pat00277
Figure pat00277

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 28]과 동일한 과정을 수행하여 목적 화합물 12.5g을 얻었다.; HRMS [M]+: 928.25Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 28] was performed to obtain 12.5 g of the target compound; HRMS [M]+: 928.25

[합성예 184] Mat 184의 합성[Synthesis Example 184] Synthesis of Mat 184

Figure pat00278
Figure pat00278

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 29]과 동일한 과정을 수행하여 목적 화합물 12.4g을 얻었다.; HRMS [M]+: 928.25Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 29] was performed to obtain 12.4 g of the target compound; HRMS [M]+: 928.25

[합성예 185] Mat 185의 합성[Synthesis Example 185] Synthesis of Mat 185

Figure pat00279
Figure pat00279

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 30]과 동일한 과정을 수행하여 목적 화합물 12.5g을 얻었다.; HRMS [M]+: 759.23Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 30] was performed to obtain 12.5 g of the target compound; HRMS [M]+: 759.23

[합성예 186] Mat 186의 합성[Synthesis Example 186] Synthesis of Mat 186

Figure pat00280
Figure pat00280

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 31]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 941.2513.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 31] except that [Preparation Example 6] was used as a reactant; HRMS [M]+: 941.25

[합성예 187] Mat 187 합성[Synthesis Example 187] Synthesis of Mat 187

Figure pat00281
Figure pat00281

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 1]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 581.18Except for using [Preparation Example 7] as a reactant, 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 1]; HRMS [M]+: 581.18

[합성예 188] Mat 188의 합성[Synthesis Example 188] Synthesis of Mat 188

Figure pat00282
Figure pat00282

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 2]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 733.24Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 2] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 733.24

[합성예 189] Mat 189의 합성[Synthesis Example 189] Synthesis of Mat 189

Figure pat00283
Figure pat00283

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 3]과 동일한 과정을 수행하여 목적 화합물 10.9g을 얻었다.; HRMS [M]+: 733.24Except for using [Preparation Example 7] as a reactant, 10.9 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 3]; HRMS [M]+: 733.24

[합성예 190] Mat 190의 합성[Synthesis Example 190] Synthesis of Mat 190

Figure pat00284
Figure pat00284

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 4]과 동일한 과정을 수행하여 목적 화합물 9.8g을 얻었다.; HRMS [M]+: 681.21Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 4] was performed to obtain 9.8 g of the target compound; HRMS [M]+: 681.21

[합성예 191] Mat 191의 합성[Synthesis Example 191] Synthesis of Mat 191

Figure pat00285
Figure pat00285

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 5]과 동일한 과정을 수행하여 목적 화합물 11g을 얻었다.; HRMS [M]+: 657.21Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 5] was performed to obtain 11 g of the target compound; HRMS [M]+: 657.21

[합성예 192] Mat 192의 합성[Synthesis Example 192] Synthesis of Mat 192

Figure pat00286
Figure pat00286

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 6]과 동일한 과정을 수행하여 목적 화합물 10.8g을 얻었다.; HRMS [M]+: 671.19Except for using [Preparation Example 7] as a reactant, 10.8 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 6]; HRMS [M]+: 671.19

[합성예 193] Mat 193의 합성[Synthesis Example 193] Synthesis of Mat 193

Figure pat00287
Figure pat00287

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 7]과 동일한 과정을 수행하여 목적 화합물 9.9g을 얻었다.; HRMS [M]+: 687.16Except for using [Preparation Example 7] as a reactant, 9.9 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 7]; HRMS [M]+: 687.16

[합성예 194] Mat 194의 합성[Synthesis Example 194] Synthesis of Mat 194

Figure pat00288
Figure pat00288

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 8]과 동일한 과정을 수행하여 목적 화합물 8.5g을 얻었다.; HRMS [M]+: 697.24Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 8] was performed to obtain 8.5 g of the target compound; HRMS [M]+: 697.24

[합성예 195] Mat 195의 합성[Synthesis Example 195] Synthesis of Mat 195

Figure pat00289
Figure pat00289

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 9]과 동일한 과정을 수행하여 목적 화합물 10.5g을 얻었다.; HRMS [M]+: 657.21Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 9] was performed to obtain 10.5 g of the target compound; HRMS [M]+: 657.21

[합성예 196] Mat 196의 합성[Synthesis Example 196] Synthesis of Mat 196

Figure pat00290
Figure pat00290

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 10]과 동일한 과정을 수행하여 목적 화합물 8.9g을 얻었다.; HRMS [M]+: 671.19Except for using [Preparation Example 7] as a reactant, 8.9 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 10]; HRMS [M]+: 671.19

[합성예 197] Mat 197의 합성[Synthesis Example 197] Synthesis of Mat 197

Figure pat00291
Figure pat00291

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 11]과 동일한 과정을 수행하여 목적 화합물 9.1g을 얻었다.; HRMS [M]+: 671.19Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 11] was performed to obtain 9.1 g of the target compound; HRMS [M]+: 671.19

[합성예 198] Mat 198의 합성[Synthesis Example 198] Synthesis of Mat 198

Figure pat00292
Figure pat00292

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 12]과 동일한 과정을 수행하여 목적 화합물 9.4g을 얻었다.; HRMS [M]+: 671.19Except for using [Preparation Example 7] as a reactant, 9.4 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 12]; HRMS [M]+: 671.19

[합성예 199] Mat 199의 합성[Synthesis Example 199] Synthesis of Mat 199

Figure pat00293
Figure pat00293

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 13]과 동일한 과정을 수행하여 목적 화합물 11.2 g을 얻었다.; HRMS [M]+: 658.20Except for using [Preparation Example 7] as a reactant, 11.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 13]; HRMS [M]+: 658.20

[합성예 200] Mat 200의 합성[Synthesis Example 200] Synthesis of Mat 200

Figure pat00294
Figure pat00294

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 14]과 동일한 과정을 수행하여 목적 화합물 10.8g을 얻었다.; HRMS [M]+: 658.20Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 14] was performed to obtain 10.8 g of the target compound; HRMS [M]+: 658.20

[합성예 201] Mat 201의 합성[Synthesis Example 201] Synthesis of Mat 201

Figure pat00295
Figure pat00295

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 15]과 동일한 과정을 수행하여 목적 화합물 12g을 얻었다.; HRMS [M]+: 658.20Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 15] was performed to obtain 12 g of the target compound; HRMS [M]+: 658.20

[합성예 202] Mat 202의 합성[Synthesis Example 202] Synthesis of Mat 202

Figure pat00296
Figure pat00296

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 16]과 동일한 과정을 수행하여 목적 화합물 12.3g을 얻었다.; HRMS [M]+: 658.20Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 16] was performed to obtain 12.3 g of the target compound; HRMS [M]+: 658.20

[합성예 203] Mat 203의 합성[Synthesis Example 203] Synthesis of Mat 203

Figure pat00297
Figure pat00297

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 17]과 동일한 과정을 수행하여 목적 화합물 8.2g을 얻었다.; HRMS [M]+: 659.20Except for using [Preparation Example 7] as a reactant, 8.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 17]; HRMS [M]+: 659.20

[합성예 204] Mat 204의 합성[Synthesis Example 204] Synthesis of Mat 204

Figure pat00298
Figure pat00298

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 18]과 동일한 과정을 수행하여 목적 화합물 8.5g을 얻었다.; HRMS [M]+: 632.19Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 18] was performed to obtain 8.5 g of the target compound; HRMS [M]+: 632.19

[합성예 205] Mat 205의 합성[Synthesis Example 205] Synthesis of Mat 205

Figure pat00299
Figure pat00299

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 19]과 동일한 과정을 수행하여 목적 화합물 9.8g을 얻었다.; HRMS [M]+: 633.18Except for using [Preparation Example 7] as a reactant, 9.8 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 19]; HRMS [M]+: 633.18

[합성예 206] Mat 206의 합성[Synthesis Example 206] Synthesis of Mat 206

Figure pat00300
Figure pat00300

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 20]과 동일한 과정을 수행하여 목적 화합물 13.4g을 얻었다.; HRMS [M]+: 746.23Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 20] was performed to obtain 13.4 g of the target compound; HRMS [M]+: 746.23

[합성예 207] Mat 207의 합성[Synthesis Example 207] Synthesis of Mat 207

Figure pat00301
Figure pat00301

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 21]과 동일한 과정을 수행하여 목적 화합물 12.4g을 얻었다.; HRMS [M]+: 670.20Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 21] was performed to obtain 12.4 g of the target compound; HRMS [M]+: 670.20

[합성예 208] Mat 208의 합성[Synthesis Example 208] Synthesis of Mat 208

Figure pat00302
Figure pat00302

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 22]과 동일한 과정을 수행하여 목적 화합물 10.6g을 얻었다.; HRMS [M]+: 852.22Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 22] was performed to obtain 10.6 g of the target compound; HRMS [M]+: 852.22

[합성예 209] Mat 209의 합성[Synthesis Example 209] Synthesis of Mat 209

Figure pat00303
Figure pat00303

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 23]과 동일한 과정을 수행하여 목적 화합물 12.2g을 얻었다.; HRMS [M]+: 733.24Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 23] was performed to obtain 12.2 g of the target compound; HRMS [M]+: 733.24

[합성예 210] Mat 210의 합성[Synthesis Example 210] Synthesis of Mat 210

Figure pat00304
Figure pat00304

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 24]과 동일한 과정을 수행하여 목적 화합물 8.5g을 얻었다.; HRMS [M]+: 702.22Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 24] was performed to obtain 8.5 g of the target compound; HRMS [M]+: 702.22

[합성예 211] Mat 211의 합성[Synthesis Example 211] Synthesis of Mat 211

Figure pat00305
Figure pat00305

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 25]과 동일한 과정을 수행하여 목적 화합물 11.8g을 얻었다.; HRMS [M]+: 734.23Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 25] was performed to obtain 11.8 g of the target compound; HRMS [M]+: 734.23

[합성예 212] Mat 212의 합성[Synthesis Example 212] Synthesis of Mat 212

Figure pat00306
Figure pat00306

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 26]과 동일한 과정을 수행하여 목적 화합물 12.6g을 얻었다.; HRMS [M]+: 747.23Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 26] was performed to obtain 12.6 g of the target compound; HRMS [M]+: 747.23

[합성예 213] Mat 213의 합성[Synthesis Example 213] Synthesis of Mat 213

Figure pat00307
Figure pat00307

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 27]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 720.22Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 27] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 720.22

[합성예 214] Mat 214의 합성[Synthesis Example 214] Synthesis of Mat 214

Figure pat00308
Figure pat00308

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 28]과 동일한 과정을 수행하여 목적 화합물 12.5g을 얻었다.; HRMS [M]+: 928.25Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 28] was performed to obtain 12.5 g of the target compound; HRMS [M]+: 928.25

[합성예 215] Mat 215의 합성[Synthesis Example 215] Synthesis of Mat 215

Figure pat00309
Figure pat00309

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 29]과 동일한 과정을 수행하여 목적 화합물 12.4g을 얻었다.; HRMS [M]+: 928.25Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 29] was performed to obtain 12.4 g of the target compound; HRMS [M]+: 928.25

[합성예 216] Mat 216의 합성[Synthesis Example 216] Synthesis of Mat 216

Figure pat00310
Figure pat00310

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 30]과 동일한 과정을 수행하여 목적 화합물 12.5g을 얻었다.; HRMS [M]+: 759.23Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 30] was performed to obtain 12.5 g of the target compound; HRMS [M]+: 759.23

[합성예 217] Mat 217의 합성[Synthesis Example 217] Synthesis of Mat 217

Figure pat00311
Figure pat00311

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 31]과 동일한 과정을 수행하여 목적 화합물 13.1g을 얻었다.; HRMS [M]+: 941.25Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 31] was performed to obtain 13.1 g of the target compound; HRMS [M]+: 941.25

[합성예 218] Mat 218의 합성[Synthesis Example 218] Synthesis of Mat 218

Figure pat00312
Figure pat00312

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 1]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 581.18Except for using [Preparation Example 8] as a reactant, 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 1]; HRMS [M]+: 581.18

[합성예 219] Mat 219의 합성[Synthesis Example 219] Synthesis of Mat 219

Figure pat00313
Figure pat00313

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 2]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 733.24Except for using [Preparation Example 8] as a reactant, 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 2]; HRMS [M]+: 733.24

[합성예 220] Mat 220의 합성[Synthesis Example 220] Synthesis of Mat 220

Figure pat00314
Figure pat00314

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 3]과 동일한 과정을 수행하여 목적 화합물 10.9g을 얻었다.; HRMS [M]+: 733.24Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 3] was performed to obtain 10.9 g of the target compound; HRMS [M]+: 733.24

[합성예 221] Mat 221의 합성[Synthesis Example 221] Synthesis of Mat 221

Figure pat00315
Figure pat00315

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 4]과 동일한 과정을 수행하여 목적 화합물 9.8g을 얻었다.; HRMS [M]+: 681.21Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 4] was performed to obtain 9.8 g of the target compound; HRMS [M]+: 681.21

[합성예 222] Mat 222의 합성[Synthesis Example 222] Synthesis of Mat 222

Figure pat00316
Figure pat00316

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 5]과 동일한 과정을 수행하여 목적 화합물 11g을 얻었다.; HRMS [M]+: 657.21Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 5] was performed to obtain 11 g of the target compound; HRMS [M]+: 657.21

[합성예 223] Mat 223의 합성[Synthesis Example 223] Synthesis of Mat 223

Figure pat00317
Figure pat00317

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 6]과 동일한 과정을 수행하여 목적 화합물 10.8g을 얻었다.; HRMS [M]+: 671.19Except for using [Preparation Example 8] as a reactant, 10.8 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 6]; HRMS [M]+: 671.19

**

[합성예 224] Mat 224의 합성[Synthesis Example 224] Synthesis of Mat 224

Figure pat00318
Figure pat00318

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 7]과 동일한 과정을 수행하여 목적 화합물 9.9g을 얻었다.; HRMS [M]+: 687.26Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 7] was performed to obtain 9.9 g of the target compound; HRMS [M]+: 687.26

[합성예 225] Mat 225의 합성[Synthesis Example 225] Synthesis of Mat 225

Figure pat00319
Figure pat00319

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 8]과 동일한 과정을 수행하여 목적 화합물 8.5g을 얻었다.; HRMS [M]+: 697.24Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 8] was performed to obtain 8.5 g of the target compound; HRMS [M]+: 697.24

[합성예 226] Mat 226의 합성[Synthesis Example 226] Synthesis of Mat 226

Figure pat00320
Figure pat00320

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 9]과 동일한 과정을 수행하여 목적 화합물 10.5g을 얻었다.; HRMS [M]+: 657.21Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 9] was performed to obtain 10.5 g of the target compound; HRMS [M]+: 657.21

[합성예 227] Mat 227의 합성[Synthesis Example 227] Synthesis of Mat 227

Figure pat00321
Figure pat00321

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 10]과 동일한 과정을 수행하여 목적 화합물 8.9g을 얻었다.; HRMS [M]+: 671.19Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 10] was performed to obtain 8.9 g of the target compound; HRMS [M]+: 671.19

[합성예 228] Mat 228의 합성[Synthesis Example 228] Synthesis of Mat 228

Figure pat00322
Figure pat00322

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 11]과 동일한 과정을 수행하여 목적 화합물 9.1g을 얻었다.; HRMS [M]+: 671.19Except for using [Preparation Example 8] as a reactant, 9.1 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 11]; HRMS [M]+: 671.19

[합성예 229] Mat 229의 합성[Synthesis Example 229] Synthesis of Mat 229

Figure pat00323
Figure pat00323

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 12]과 동일한 과정을 수행하여 목적 화합물 9.4g을 얻었다.; HRMS [M]+: 671.19Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 12] was performed to obtain 9.4 g of the target compound; HRMS [M]+: 671.19

[합성예 230] Mat 230의 합성[Synthesis Example 230] Synthesis of Mat 230

Figure pat00324
Figure pat00324

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 13]과 동일한 과정을 수행하여 목적 화합물 11.2 g을 얻었다.; HRMS [M]+: 658.2011.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 13] except that [Preparation Example 8] was used as a reactant; HRMS [M]+: 658.20

[합성예 231] Mat 231의 합성[Synthesis Example 231] Synthesis of Mat 231

Figure pat00325
Figure pat00325

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 14]과 동일한 과정을 수행하여 목적 화합물 10.8g을 얻었다.; HRMS [M]+: 658.20Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 14] was performed to obtain 10.8 g of the target compound; HRMS [M]+: 658.20

[합성예 232] Mat 232의 합성[Synthesis Example 232] Synthesis of Mat 232

Figure pat00326
Figure pat00326

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 15]과 동일한 과정을 수행하여 목적 화합물 12g을 얻었다.; HRMS [M]+: 658.20Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 15] was performed to obtain 12 g of the target compound; HRMS [M]+: 658.20

[합성예 233] Mat 233의 합성[Synthesis Example 233] Synthesis of Mat 233

Figure pat00327
Figure pat00327

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 16]과 동일한 과정을 수행하여 목적 화합물 12.3g을 얻었다.; HRMS [M]+: 658.20Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 16] was performed to obtain 12.3 g of the target compound; HRMS [M]+: 658.20

[합성예 234] Mat 234의 합성[Synthesis Example 234] Synthesis of Mat 234

Figure pat00328
Figure pat00328

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 17]과 동일한 과정을 수행하여 목적 화합물 8.2g을 얻었다.; HRMS [M]+: 659.70Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 17] was performed to obtain 8.2 g of the target compound; HRMS [M]+: 659.70

[합성예 235] Mat 235의 합성[Synthesis Example 235] Synthesis of Mat 235

Figure pat00329
Figure pat00329

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 18]과 동일한 과정을 수행하여 목적 화합물 8.5g을 얻었다.; HRMS [M]+: 632.19Except for using [Preparation Example 8] as a reactant, 8.5 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 18]; HRMS [M]+: 632.19

[합성예 236] Mat 236의 합성[Synthesis Example 236] Synthesis of Mat 236

Figure pat00330
Figure pat00330

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 19]과 동일한 과정을 수행하여 목적 화합물 9.8g을 얻었다.; HRMS [M]+: 633.18Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 19] was performed to obtain 9.8 g of the target compound; HRMS [M]+: 633.18

[합성예 237] Mat 237의 합성[Synthesis Example 237] Synthesis of Mat 237

Figure pat00331
Figure pat00331

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 20]과 동일한 과정을 수행하여 목적 화합물 13.4g을 얻었다.; HRMS [M]+: 746.23Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 20] was performed to obtain 13.4 g of the target compound; HRMS [M]+: 746.23

[합성예 238] Mat 238의 합성[Synthesis Example 238] Synthesis of Mat 238

Figure pat00332
Figure pat00332

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 21]과 동일한 과정을 수행하여 목적 화합물 12.4g을 얻었다.; HRMS [M]+: 670.20Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 21] was performed to obtain 12.4 g of the target compound; HRMS [M]+: 670.20

[합성예 239] Mat 239의 합성[Synthesis Example 239] Synthesis of Mat 239

Figure pat00333
Figure pat00333

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 22]과 동일한 과정을 수행하여 목적 화합물 10.6g을 얻었다.; HRMS [M]+: 852.22Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 22] was performed to obtain 10.6 g of the target compound; HRMS [M]+: 852.22

[합성예 240] Mat 240의 합성[Synthesis Example 240] Synthesis of Mat 240

Figure pat00334
Figure pat00334

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 23]과 동일한 과정을 수행하여 목적 화합물 12.2g을 얻었다.; HRMS [M]+: 733.24Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 23] was performed to obtain 12.2 g of the target compound; HRMS [M]+: 733.24

[합성예 241] Mat 241의 합성[Synthesis Example 241] Synthesis of Mat 241

Figure pat00335
Figure pat00335

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 24]과 동일한 과정을 수행하여 목적 화합물 8.5g을 얻었다.; HRMS [M]+: 702.22Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 24] was performed to obtain 8.5 g of the target compound; HRMS [M]+: 702.22

[합성예 242] Mat 242의 합성[Synthesis Example 242] Synthesis of Mat 242

Figure pat00336
Figure pat00336

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 25]과 동일한 과정을 수행하여 목적 화합물 11.8g을 얻었다.; HRMS [M]+: 734.23Except for using [Preparation Example 8] as a reactant, 11.8 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 25]; HRMS [M]+: 734.23

[합성예 243] Mat 243의 합성[Synthesis Example 243] Synthesis of Mat 243

Figure pat00337
Figure pat00337

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 26]과 동일한 과정을 수행하여 목적 화합물 12.6g을 얻었다.; HRMS [M]+: 747.23Except for using [Preparation Example 8] as a reactant, 12.6 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 26]; HRMS [M]+: 747.23

[합성예 244] Mat 244의 합성[Synthesis Example 244] Synthesis of Mat 244

Figure pat00338
Figure pat00338

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 27]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 720.22Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 27] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 720.22

[합성예 245] Mat 245의 합성[Synthesis Example 245] Synthesis of Mat 245

Figure pat00339
Figure pat00339

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 28]과 동일한 과정을 수행하여 목적 화합물 12.5g을 얻었다.; HRMS [M]+: 928.25Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 28] was performed to obtain 12.5 g of the target compound; HRMS [M]+: 928.25

[합성예 246] Mat 246의 합성[Synthesis Example 246] Synthesis of Mat 246

Figure pat00340
Figure pat00340

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 29]과 동일한 과정을 수행하여 목적 화합물 12.4g을 얻었다.; HRMS [M]+: 928.20Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 29] was performed to obtain 12.4 g of the target compound; HRMS [M]+: 928.20

[합성예 247] Mat 247의 합성[Synthesis Example 247] Synthesis of Mat 247

Figure pat00341
Figure pat00341

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 30]과 동일한 과정을 수행하여 목적 화합물 12.5g을 얻었다.; HRMS [M]+: 759.23Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 30] was performed to obtain 12.5 g of the target compound; HRMS [M]+: 759.23

[합성예 248] Mat 248의 합성[Synthesis Example 248] Synthesis of Mat 248

Figure pat00342
Figure pat00342

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 31]과 동일한 과정을 수행하여 목적 화합물 13.1g을 얻었다.; HRMS [M]+: 941.25Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 31] was performed to obtain 13.1 g of the target compound; HRMS [M]+: 941.25

[합성예 249] Mat 249의 합성[Synthesis Example 249] Synthesis of Mat 249

Figure pat00343
Figure pat00343

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 1]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 591.25Except for using [Preparation Example 9] as a reactant, 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 1]; HRMS [M]+: 591.25

[합성예 250] Mat 250의 합성[Synthesis Example 250] Synthesis of Mat 250

Figure pat00344
Figure pat00344

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 2]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 743.31Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 2] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 743.31

[합성예 251] Mat 251의 합성[Synthesis Example 251] Synthesis of Mat 251

Figure pat00345
Figure pat00345

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 3]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 743.31Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 3] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 743.31

[합성예 252] Mat 252의 합성[Synthesis Example 252] Synthesis of Mat 252

Figure pat00346
Figure pat00346

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 4]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 691.28Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 4] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 691.28

[합성예 253] Mat 253의 합성[Synthesis Example 253] Synthesis of Mat 253

Figure pat00347
Figure pat00347

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 5]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 667.28Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 5] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 667.28

[합성예 254] Mat 254의 합성[Synthesis Example 254] Synthesis of Mat 254

Figure pat00348
Figure pat00348

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 6]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 681.26Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 6] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 681.26

[합성예 255] Mat 255의 합성[Synthesis Example 255] Synthesis of Mat 255

Figure pat00349
Figure pat00349

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 7]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 697.24Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 7] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 697.24

[합성예 256] Mat 256의 합성[Synthesis Example 256] Synthesis of Mat 256

Figure pat00350
Figure pat00350

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 8]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 707.31Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 8] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 707.31

[합성예 257] Mat 257의 합성[Synthesis Example 257] Synthesis of Mat 257

Figure pat00351
Figure pat00351

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 9]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 667.28Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 9] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 667.28

[합성예 258] Mat 258의 합성[Synthesis Example 258] Synthesis of Mat 258

Figure pat00352
Figure pat00352

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 10]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 681.26Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 10] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 681.26

[합성예 259] Mat 259의 합성[Synthesis Example 259] Synthesis of Mat 259

Figure pat00353
Figure pat00353

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 11]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 681.26Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 11] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 681.26

[합성예 260] Mat 260의 합성[Synthesis Example 260] Synthesis of Mat 260

Figure pat00354
Figure pat00354

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 12]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 681.26Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 12] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 681.26

[합성예 261] Mat 261의 합성[Synthesis Example 261] Synthesis of Mat 261

Figure pat00355
Figure pat00355

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 13]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 668.28Except for using [Preparation Example 9] as a reactant, 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 13]; HRMS [M]+: 668.28

[합성예 262] Mat 262의 합성[Synthesis Example 262] Synthesis of Mat 262

Figure pat00356
Figure pat00356

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 14]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 668.28Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 14] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 668.28

[합성예 263] Mat 263의 합성[Synthesis Example 263] Synthesis of Mat 263

Figure pat00357
Figure pat00357

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 15]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 668.28Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 15] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 668.28

[합성예 264] Mat 264의 합성[Synthesis Example 264] Synthesis of Mat 264

Figure pat00358
Figure pat00358

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 16]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 668.28Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 16] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 668.28

[합성예 265] Mat 265의 합성[Synthesis Example 265] Synthesis of Mat 265

Figure pat00359
Figure pat00359

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 17]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 669.27Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 17] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 669.27

[합성예 266] Mat 266의 합성[Synthesis Example 266] Synthesis of Mat 266

Figure pat00360
Figure pat00360

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 18]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 642.26Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 18] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 642.26

[합성예 267] Mat 267의 합성[Synthesis Example 267] Synthesis of Mat 267

Figure pat00361
Figure pat00361

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 19]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 643.26Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 19] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 643.26

[합성예 268] Mat 268의 합성[Synthesis Example 268] Synthesis of Mat 268

Figure pat00362
Figure pat00362

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 20]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 756.31Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 20] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 756.31

[합성예 269] Mat 269의 합성[Synthesis Example 269] Synthesis of Mat 269

Figure pat00363
Figure pat00363

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 21]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 680.28Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 21] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 680.28

[합성예 270] Mat 270의 합성[Synthesis Example 270] Synthesis of Mat 270

Figure pat00364
Figure pat00364

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 22]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 862.30 Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 22] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 862.30

[합성예 271] Mat 271의 합성[Synthesis Example 271] Synthesis of Mat 271

Figure pat00365
Figure pat00365

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 23]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 743.31Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 23] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 743.31

[합성예 272] Mat 272의 합성[Synthesis Example 272] Synthesis of Mat 272

Figure pat00366
Figure pat00366

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 24]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 717.30Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 24] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 717.30

[합성예 273] Mat 273의 합성[Synthesis Example 273] Synthesis of Mat 273

Figure pat00367
Figure pat00367

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 25]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 744.31Except for using [Preparation Example 9] as a reactant, 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 25]; HRMS [M]+: 744.31

[합성예 274] Mat 274의 합성[Synthesis Example 274] Synthesis of Mat 274

Figure pat00368
Figure pat00368

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 26]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+:757.30Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 26] was performed to obtain 13.2 g of the target compound; HRMS [M]+:757.30

[합성예 275] Mat 275의 합성[Synthesis Example 275] Synthesis of Mat 275

Figure pat00369
Figure pat00369

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 27]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 730.29Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 27] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 730.29

[합성예 276] Mat 276의 합성[Synthesis Example 276] Synthesis of Mat 276

Figure pat00370
Figure pat00370

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 28]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 948.40Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 28] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 948.40

[합성예 277] Mat 277의 합성[Synthesis Example 277] Synthesis of Mat 277

Figure pat00371
Figure pat00371

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 29]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 948.40Except for using [Preparation Example 9] as a reactant, 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 29]; HRMS [M]+: 948.40

[합성예 278] Mat 278의 합성[Synthesis Example 278] Synthesis of Mat 278

Figure pat00372
Figure pat00372

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 30]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 769.30Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 30] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 769.30

[합성예 279] Mat 279의 합성[Synthesis Example 279] Synthesis of Mat 279

Figure pat00373
Figure pat00373

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 31]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 961.40Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 31] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 961.40

[합성예 280] Mat 280의 합성[Synthesis Example 280] Synthesis of Mat 280

Figure pat00374
Figure pat00374

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 1]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 591.25Except for using [Preparation Example 10] as a reactant, 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 1]; HRMS [M]+: 591.25

[합성예 281] Mat 281의 합성[Synthesis Example 281] Synthesis of Mat 281

Figure pat00375
Figure pat00375

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 2]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 743.31Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 2] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 743.31

[합성예 282] Mat 2782의 합성[Synthesis Example 282] Synthesis of Mat 2782

Figure pat00376
Figure pat00376

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 3]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 743.31Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 3] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 743.31

[합성예 283] Mat 283의 합성[Synthesis Example 283] Synthesis of Mat 283

Figure pat00377
Figure pat00377

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 4]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 691.28Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 4] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 691.28

[합성예 284] Mat 284의 합성[Synthesis Example 284] Synthesis of Mat 284

Figure pat00378
Figure pat00378

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 5]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 667.28Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 5] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 667.28

[합성예 285] Mat 285의 합성[Synthesis Example 285] Synthesis of Mat 285

Figure pat00379
Figure pat00379

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 6]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 681.26Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 6] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 681.26

[합성예 286] Mat 286의 합성[Synthesis Example 286] Synthesis of Mat 286

Figure pat00380
Figure pat00380

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 7]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 697.24Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 7] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 697.24

[합성예 287] Mat 287의 합성[Synthesis Example 287] Synthesis of Mat 287

Figure pat00381
Figure pat00381

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 8]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 707.31Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 8] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 707.31

[합성예 288] Mat 288의 합성[Synthesis Example 288] Synthesis of Mat 288

Figure pat00382
Figure pat00382

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 9]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 667.28Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 9] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 667.28

[합성예 289] Mat 289의 합성[Synthesis Example 289] Synthesis of Mat 289

Figure pat00383
Figure pat00383

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 10]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 681.26Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 10] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 681.26

[합성예 290] Mat 290의 합성[Synthesis Example 290] Synthesis of Mat 290

Figure pat00384
Figure pat00384

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 11]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 681.26Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 11] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 681.26

[합성예 291] Mat 291의 합성[Synthesis Example 291] Synthesis of Mat 291

Figure pat00385
Figure pat00385

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 12]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 681.26Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 12] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 681.26

[합성예 292] Mat 292의 합성[Synthesis Example 292] Synthesis of Mat 292

Figure pat00386
Figure pat00386

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 13]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 668.28Except for using [Preparation Example 10] as a reactant, 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 13]; HRMS [M]+: 668.28

[합성예 293] Mat 293의 합성[Synthesis Example 293] Synthesis of Mat 293

Figure pat00387
Figure pat00387

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 14]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 668.28Except for using [Preparation Example 10] as a reactant, 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 14]; HRMS [M]+: 668.28

[합성예 294] Mat 294의 합성[Synthesis Example 294] Synthesis of Mat 294

Figure pat00388
Figure pat00388

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 15]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 668.28Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 15] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 668.28

[합성예 295] Mat 295의 합성[Synthesis Example 295] Synthesis of Mat 295

Figure pat00389
Figure pat00389

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 16]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 668.28Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 16] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 668.28

[합성예 296] Mat 296의 합성[Synthesis Example 296] Synthesis of Mat 296

Figure pat00390
Figure pat00390

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 17]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 669.27Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 17] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 669.27

[합성예 297] Mat 297의 합성[Synthesis Example 297] Synthesis of Mat 297

Figure pat00391
Figure pat00391

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 18]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 642.26Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 18] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 642.26

[합성예 298] Mat 298의 합성[Synthesis Example 298] Synthesis of Mat 298

Figure pat00392
Figure pat00392

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 19]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 643.26Except for using [Preparation Example 10] as a reactant, 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 19]; HRMS [M]+: 643.26

[합성예 299] Mat 299의 합성[Synthesis Example 299] Synthesis of Mat 299

Figure pat00393
Figure pat00393

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 20]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 756.31Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 20] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 756.31

[합성예 300] Mat 300의 합성[Synthesis Example 300] Synthesis of Mat 300

Figure pat00394
Figure pat00394

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 21]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 680.28Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 21] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 680.28

[합성예 301] Mat 301의 합성[Synthesis Example 301] Synthesis of Mat 301

Figure pat00395
Figure pat00395

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 22]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 862.30 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 22] except that [Preparation Example 10] was used as a reactant; HRMS [M]+: 862.30

[합성예 302] Mat 302의 합성[Synthesis Example 302] Synthesis of Mat 302

Figure pat00396
Figure pat00396

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 23]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 743.31Except for using [Preparation Example 10] as a reactant, 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 23]; HRMS [M]+: 743.31

[합성예 303] Mat 303의 합성[Synthesis Example 303] Synthesis of Mat 303

Figure pat00397
Figure pat00397

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 24]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 717.30Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 24] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 717.30

[합성예 304] Mat 304의 합성[Synthesis Example 304] Synthesis of Mat 304

Figure pat00398
Figure pat00398

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 25]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 744.31Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 25] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 744.31

[합성예 305] Mat 305의 합성[Synthesis Example 305] Synthesis of Mat 305

Figure pat00399
Figure pat00399

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 26]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+:757.30Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 26] was performed to obtain 13.2 g of the target compound; HRMS [M]+:757.30

[합성예 306] Mat 306의 합성[Synthesis Example 306] Synthesis of Mat 306

Figure pat00400
Figure pat00400

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 27]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 730.29Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 27] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 730.29

[합성예 307] Mat 307의 합성[Synthesis Example 307] Synthesis of Mat 307

Figure pat00401
Figure pat00401

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 28]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 948.40Except for using [Preparation Example 10] as a reactant, 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 28]; HRMS [M]+: 948.40

[합성예 308] Mat 308의 합성[Synthesis Example 308] Synthesis of Mat 308

Figure pat00402
Figure pat00402

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 29]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 948.40Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 29] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 948.40

[합성예 309] Mat 309의 합성[Synthesis Example 309] Synthesis of Mat 309

Figure pat00403
Figure pat00403

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 30]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 769.3013.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 30] except that [Preparation Example 10] was used as a reactant; HRMS [M]+: 769.30

[합성예 310] Mat 310의 합성[Synthesis Example 310] Synthesis of Mat 310

Figure pat00404
Figure pat00404

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 31]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 961.40Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 31] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 961.40

[합성예 311] Mat 311의 합성[Synthesis Example 311] Synthesis of Mat 311

Figure pat00405
Figure pat00405

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 1]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 591.25Except for using [Preparation Example 11] as a reactant, 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 1]; HRMS [M]+: 591.25

[합성예 312] Mat 312의 합성[Synthesis Example 312] Synthesis of Mat 312

Figure pat00406
Figure pat00406

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 2]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 743.31Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 2] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 743.31

[합성예 313] Mat 313의 합성[Synthesis Example 313] Synthesis of Mat 313

Figure pat00407
Figure pat00407

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 3]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 743.31Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 3] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 743.31

[합성예 314] Mat 314의 합성[Synthesis Example 314] Synthesis of Mat 314

Figure pat00408
Figure pat00408

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 4]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 691.28Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 4] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 691.28

[합성예 315] Mat 315의 합성[Synthesis Example 315] Synthesis of Mat 315

Figure pat00409
Figure pat00409

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 5]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 667.28Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 5] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 667.28

[합성예 316] Mat 316의 합성[Synthesis Example 316] Synthesis of Mat 316

Figure pat00410
Figure pat00410

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 6]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 681.26Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 6] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 681.26

[합성예 317] Mat 317의 합성[Synthesis Example 317] Synthesis of Mat 317

Figure pat00411
Figure pat00411

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 7]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 697.24Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 7] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 697.24

[합성예 318] Mat 318의 합성[Synthesis Example 318] Synthesis of Mat 318

Figure pat00412
Figure pat00412

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 8]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 707.31Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 8] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 707.31

[합성예 319] Mat 319의 합성[Synthesis Example 319] Synthesis of Mat 319

Figure pat00413
Figure pat00413

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 9]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 667.28Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 9] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 667.28

[합성예 320] Mat 320의 합성[Synthesis Example 320] Synthesis of Mat 320

Figure pat00414
Figure pat00414

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 10]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 681.26Except for using [Preparation Example 11] as a reactant, 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 10]; HRMS [M]+: 681.26

[합성예 321] Mat 321의 합성[Synthesis Example 321] Synthesis of Mat 321

Figure pat00415
Figure pat00415

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 11]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 681.26Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 11] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 681.26

[합성예 322] Mat 322의 합성[Synthesis Example 322] Synthesis of Mat 322

Figure pat00416
Figure pat00416

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 12]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 681.26Except for using [Preparation Example 11] as a reactant, 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 12]; HRMS [M]+: 681.26

[합성예 323] Mat 323의 합성[Synthesis Example 323] Synthesis of Mat 323

Figure pat00417
Figure pat00417

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 13]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 668.28Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 13] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 668.28

[합성예 324] Mat 324의 합성[Synthesis Example 324] Synthesis of Mat 324

Figure pat00418
Figure pat00418

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 14]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 668.28Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 14] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 668.28

[합성예 325] Mat 325의 합성[Synthesis Example 325] Synthesis of Mat 325

Figure pat00419
Figure pat00419

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 15]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 668.28Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 15] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 668.28

[합성예 326] Mat 326의 합성[Synthesis Example 326] Synthesis of Mat 326

Figure pat00420
Figure pat00420

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 16]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 668.28Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 16] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 668.28

[합성예 327] Mat 327의 합성[Synthesis Example 327] Synthesis of Mat 327

Figure pat00421
Figure pat00421

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 17]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 669.27Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 17] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 669.27

[합성예 328] Mat 328의 합성[Synthesis Example 328] Synthesis of Mat 328

Figure pat00422
Figure pat00422

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 18]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 642.26Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 18] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 642.26

[합성예 329] Mat 329의 합성[Synthesis Example 329] Synthesis of Mat 329

Figure pat00423
Figure pat00423

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 19]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 643.26Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 19] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 643.26

[합성예 330] Mat 330의 합성[Synthesis Example 330] Synthesis of Mat 330

Figure pat00424
Figure pat00424

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 20]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 756.31Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 20] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 756.31

[합성예 331] Mat 331의 합성[Synthesis Example 331] Synthesis of Mat 331

Figure pat00425
Figure pat00425

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 21]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 680.28Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 21] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 680.28

[합성예 332] Mat 332의 합성[Synthesis Example 332] Synthesis of Mat 332

Figure pat00426
Figure pat00426

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 22]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 862.30 Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 22] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 862.30

[합성예 333] Mat 333의 합성[Synthesis Example 333] Synthesis of Mat 333

Figure pat00427
Figure pat00427

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 23]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 743.31Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 23] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 743.31

[합성예 334] Mat 334의 합성[Synthesis Example 334] Synthesis of Mat 334

Figure pat00428
Figure pat00428

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 24]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 717.30Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 24] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 717.30

[합성예 335] Mat 335의 합성[Synthesis Example 335] Synthesis of Mat 335

Figure pat00429
Figure pat00429

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 25]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 744.31Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 25] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 744.31

[합성예 336] Mat 336의 합성[Synthesis Example 336] Synthesis of Mat 336

Figure pat00430
Figure pat00430

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 26]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+:757.30Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 26] was performed to obtain 13.2 g of the target compound; HRMS [M]+:757.30

[합성예 337] Mat 337의 합성[Synthesis Example 337] Synthesis of Mat 337

Figure pat00431
Figure pat00431

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 27]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 730.29Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 27] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 730.29

[합성예 338] Mat 338의 합성[Synthesis Example 338] Synthesis of Mat 338

Figure pat00432
Figure pat00432

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 28]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 948.40Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 28] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 948.40

[합성예 339] Mat 339의 합성[Synthesis Example 339] Synthesis of Mat 339

Figure pat00433
Figure pat00433

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 29]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 948.40Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 29] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 948.40

[합성예 340] Mat 340의 합성[Synthesis Example 340] Synthesis of Mat 340

Figure pat00434
Figure pat00434

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 30]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 769.30Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 30] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 769.30

[합성예 341] Mat 341의 합성[Synthesis Example 341] Synthesis of Mat 341

Figure pat00435
Figure pat00435

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 31]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 961.40Except for using [Preparation Example 11] as a reactant, 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 31]; HRMS [M]+: 961.40

[합성예 342] Mat 342의 합성[Synthesis Example 342] Synthesis of Mat 342

Figure pat00436
Figure pat00436

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 1]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 591.25Except for using [Preparation Example 12] as a reactant, 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 1]; HRMS [M]+: 591.25

[합성예 343] Mat 343의 합성[Synthesis Example 343] Synthesis of Mat 343

Figure pat00437
Figure pat00437

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 2]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 743.31Except for using [Preparation Example 12] as a reactant, 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 2]; HRMS [M]+: 743.31

[합성예 344] Mat 344의 합성[Synthesis Example 344] Synthesis of Mat 344

Figure pat00438
Figure pat00438

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 3]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 743.31Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 3] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 743.31

[합성예 345] Mat 345의 합성[Synthesis Example 345] Synthesis of Mat 345

Figure pat00439
Figure pat00439

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 4]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 691.28Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 4] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 691.28

[합성예 346] Mat 346의 합성[Synthesis Example 346] Synthesis of Mat 346

Figure pat00440
Figure pat00440

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 5]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 667.28Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 5] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 667.28

[합성예 347] Mat 347의 합성[Synthesis Example 347] Synthesis of Mat 347

Figure pat00441
Figure pat00441

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 6]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 681.26Except for using [Preparation Example 12] as a reactant, 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 6]; HRMS [M]+: 681.26

[합성예 348] Mat 348의 합성[Synthesis Example 348] Synthesis of Mat 348

Figure pat00442
Figure pat00442

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 7]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 697.24Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 7] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 697.24

[합성예 349] Mat 349의 합성[Synthesis Example 349] Synthesis of Mat 349

Figure pat00443
Figure pat00443

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 8]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 707.31Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 8] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 707.31

[합성예 350] Mat 350의 합성[Synthesis Example 350] Synthesis of Mat 350

Figure pat00444
Figure pat00444

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 9]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 667.28Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 9] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 667.28

[합성예 351] Mat 351의 합성[Synthesis Example 351] Synthesis of Mat 351

Figure pat00445
Figure pat00445

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 10]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 681.26Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 10] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 681.26

[합성예 352] Mat 352의 합성[Synthesis Example 352] Synthesis of Mat 352

Figure pat00446
Figure pat00446

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 11]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 681.26Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 11] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 681.26

[합성예 353] Mat 353의 합성[Synthesis Example 353] Synthesis of Mat 353

Figure pat00447
Figure pat00447

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 12]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 681.26Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 12] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 681.26

[합성예 354] Mat 354의 합성[Synthesis Example 354] Synthesis of Mat 354

Figure pat00448
Figure pat00448

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 13]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 668.28Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 13] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 668.28

[합성예 355] Mat 355의 합성[Synthesis Example 355] Synthesis of Mat 355

Figure pat00449
Figure pat00449

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 14]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 668.28Except for using [Preparation Example 12] as a reactant, 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 14]; HRMS [M]+: 668.28

[합성예 356] Mat 356의 합성[Synthesis Example 356] Synthesis of Mat 356

Figure pat00450
Figure pat00450

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 15]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 668.28Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 15] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 668.28

[합성예 357] Mat 357의 합성[Synthesis Example 357] Synthesis of Mat 357

Figure pat00451
Figure pat00451

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 16]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 668.28Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 16] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 668.28

[합성예 358] Mat 358의 합성[Synthesis Example 358] Synthesis of Mat 358

Figure pat00452
Figure pat00452

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 17]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 669.27Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 17] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 669.27

[합성예 359] Mat 359의 합성[Synthesis Example 359] Synthesis of Mat 359

Figure pat00453
Figure pat00453

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 18]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 642.26Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 18] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 642.26

[합성예 360] Mat 360의 합성[Synthesis Example 360] Synthesis of Mat 360

Figure pat00454
Figure pat00454

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 19]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 643.26Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 19] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 643.26

[합성예 361] Mat 361의 합성[Synthesis Example 361] Synthesis of Mat 361

Figure pat00455
Figure pat00455

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 20]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 756.31Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 20] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 756.31

[합성예 362] Mat 362의 합성[Synthesis Example 362] Synthesis of Mat 362

Figure pat00456
Figure pat00456

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 21]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 680.2813.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 21] except that [Preparation Example 12] was used as a reactant; HRMS [M]+: 680.28

[합성예 363] Mat 363의 합성[Synthesis Example 363] Synthesis of Mat 363

Figure pat00457
Figure pat00457

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 22]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 862.30 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 22] except that [Preparation Example 12] was used as a reactant; HRMS [M]+: 862.30

[합성예 364] Mat 364의 합성[Synthesis Example 364] Synthesis of Mat 364

Figure pat00458
Figure pat00458

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 23]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 743.31Except for using [Preparation Example 12] as a reactant, 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 23]; HRMS [M]+: 743.31

[합성예 365] Mat 365의 합성[Synthesis Example 365] Synthesis of Mat 365

Figure pat00459
Figure pat00459

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 24]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 717.30Except for using [Preparation Example 12] as a reactant, 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 24]; HRMS [M]+: 717.30

[합성예 366] Mat 366의 합성[Synthesis Example 366] Synthesis of Mat 366

Figure pat00460
Figure pat00460

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 25]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 744.31Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 25] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 744.31

[합성예 367] Mat 367의 합성[Synthesis Example 367] Synthesis of Mat 367

Figure pat00461
Figure pat00461

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 26]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+:757.30Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 26] was performed to obtain 13.2 g of the target compound; HRMS [M]+:757.30

[합성예 368] Mat 368의 합성[Synthesis Example 368] Synthesis of Mat 368

Figure pat00462
Figure pat00462

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 27]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 730.29Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 27] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 730.29

[합성예 369] Mat 369의 합성[Synthesis Example 369] Synthesis of Mat 369

Figure pat00463
Figure pat00463

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 28]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 948.40Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 28] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 948.40

[합성예 370] Mat 370의 합성[Synthesis Example 370] Synthesis of Mat 370

Figure pat00464
Figure pat00464

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 29]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 948.40Except for using [Preparation Example 12] as a reactant, 13.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 29]; HRMS [M]+: 948.40

[합성예 371] Mat 371의 합성[Synthesis Example 371] Synthesis of Mat 371

Figure pat00465
Figure pat00465

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 30]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 769.30Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 30] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 769.30

[합성예 372] Mat 372의 합성[Synthesis Example 372] Synthesis of Mat 372

Figure pat00466
Figure pat00466

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 31]과 동일한 과정을 수행하여 목적 화합물 13.2g을 얻었다.; HRMS [M]+: 961.40Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 31] was performed to obtain 13.2 g of the target compound; HRMS [M]+: 961.40

[합성예 373] Mat 373의 합성[Synthesis Example 373] Synthesis of Mat 373

Figure pat00467
Figure pat00467

[준비예1] 5g(14.99mmol)과 4-브로모-2,6-디페닐피리미딘 5.6g(17.99mmol)에 자일렌 250 mL를 가하였다. Pd2(dba)3 0.68g(0.75mmol), P(t-Bu)3 0.3g(1.499mmol), NaOtBu 3.59g(37.47mol)을 첨가 후 120에서 24시간 가열환류하였다. 상온으로 온도를 냉각하고 반응액에 염화암모늄 수용액 500 mL로 반응을 종결시켰다. 혼합액을 M.C 500 mL로 추출한 후, 증류수로 세척하였다. 얻어진 유기층을 무수 MgSO4로 건조하고, 감압증류하고 실리카겔 컬럼크로마토그래피로 정제하여 목적 화합물 7.1g(수율 85%)을 얻었다. 1H-NMR: 8.55(d, 1H), 8.29(d 1H), 8.19(dd, 2H), 8.06~7.92(m, 7H), 7.55~7.48(m, 9H), 7.39~7.31(m, 3H), 7.24(s, 1H), 7.16(t, 1H); HRMS [M]+: 564.20[Preparation Example 1] 250 mL of xylene was added to 5 g (14.99 mmol) and 5.6 g (17.99 mmol) of 4-bromo-2,6-diphenylpyrimidine. After adding 0.68g (0.75mmol) of Pd 2 (dba) 3 , 0.3g (1.499mmol) of P(t-Bu) 3 , and 3.59g (37.47mol) of NaOtBu, the mixture was heated under reflux at 120°C for 24 hours. The temperature was cooled to room temperature, and the reaction was terminated with 500 mL of an aqueous ammonium chloride solution. The mixed solution was extracted with 500 mL of MC and washed with distilled water. The resulting organic layer was dried over anhydrous MgSO 4 , distilled under reduced pressure, and purified by silica gel column chromatography to obtain 7.1 g of the target compound (yield: 85%). 1H-NMR: 8.55 (d, 1H), 8.29 (d 1H), 8.19 (dd, 2H), 8.06 to 7.92 (m, 7H), 7.55 to 7.48 (m, 9H), 7.39 to 7.31 (m, 3H) , 7.24(s, 1H), 7.16(t, 1H); HRMS [M] + : 564.20

[합성예 374] Mat 374의 합성[Synthesis Example 374] Synthesis of Mat 374

Figure pat00468
Figure pat00468

반응물로 2,4-디([1,1'-비페닐]-4-일)-6-클로로피리미딘 을 사용한 것을 제외하고는 [합성예 373]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 716.2716.4 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 373], except that 2,4-di([1,1'-biphenyl]-4-yl)-6-chloropyrimidine was used as a reactant. got.; HRMS [M]+: 716.27

[합성예 375] Mat 375의 합성[Synthesis Example 375] Synthesis of Mat 375

Figure pat00469
Figure pat00469

반응물로 2-([1,1'-비페닐]-3-일)-4-([1,1'-비페닐]-4-일)-6-클로로피리미딘 을 사용한 것을 제외하고는 [합성예 373]과 동일한 과정을 수행하여 목적 화합물 15.8g을 얻었다.; HRMS [M]+: 716.27Except for using 2-([1,1'-biphenyl]-3-yl)-4-([1,1'-biphenyl]-4-yl)-6-chloropyrimidine as the reactant [ Synthesis Example 373] was performed to obtain 15.8 g of the target compound; HRMS [M]+: 716.27

[합성예 376] Mat 376의 합성[Synthesis Example 376] Synthesis of Mat 376

Figure pat00470
Figure pat00470

반응물로 4-([1,1'-비페닐]-4-일)-6-클로로-2-페닐피리미딘을 사용한 것을 제외하고는 [합성예 373]과 동일한 과정을 수행하여 목적 화합물 14.1g을 얻었다.; HRMS [M]+: 640.2314.1 g of the target compound was obtained in the same manner as in Synthesis Example 373, except that 4-([1,1'-biphenyl]-4-yl)-6-chloro-2-phenylpyrimidine was used as a reactant. got .; HRMS [M]+: 640.23

[합성예 377] Mat 377의 합성[Synthesis Example 377] Synthesis of Mat 377

Figure pat00471
Figure pat00471

반응물로 4-클로로-6-(디벤조[b,d]퓨란-3-일)-2-페닐피리미딘을 사용한 것을 제외하고는 [합성예 373]과 동일한 과정을 수행하여 목적 화합물 14.3g을 얻었다.; HRMS [M]+: 654.2114.3 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 373], except that 4-chloro-6-(dibenzo[b,d]furan-3-yl)-2-phenylpyrimidine was used as a reactant. got.; HRMS [M]+: 654.21

[합성예 378] Mat 378의 합성[Synthesis Example 378] Synthesis of Mat 378

Figure pat00472
Figure pat00472

반응물로 2-클로로-4,6-디페닐피리미딘을 사용한 것을 제외하고는 [합성예 373]과 동일한 과정을 수행하여 목적 화합물 12.1g을 얻었다.; HRMS [M]+: 564.20Except for using 2-chloro-4,6-diphenylpyrimidine as a reactant, the same procedure as in [Synthesis Example 373] was performed to obtain 12.1 g of the target compound; HRMS [M]+: 564.20

[합성예 379] Mat 379의 합성[Synthesis Example 379] Synthesis of Mat 379

Figure pat00473
Figure pat00473

반응물로 4,6-디([1,1'-비페닐]-4-일)-2-클로로피리미딘을 사용한 것을 제외하고는 [합성예 373]과 동일한 과정을 수행하여 목적 화합물 13.9g을 얻었다.; HRMS [M]+: 716.2713.9 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 373], except that 4,6-di([1,1'-biphenyl]-4-yl)-2-chloropyrimidine was used as a reactant. got.; HRMS [M]+: 716.27

[합성예 380] Mat 380의 합성[Synthesis Example 380] Synthesis of Mat 380

Figure pat00474
Figure pat00474

반응물로 4-([1,1'-비페닐]-4-일)-2-클로로-6-페닐피리미딘을 사용한 것을 제외하고는 [합성예 373]과 동일한 과정을 수행하여 목적 화합물 14.8g을 얻었다.; HRMS [M]+: 740.2314.8 g of the desired compound was obtained by performing the same procedure as in [Synthesis Example 373], except that 4-([1,1'-biphenyl] -4-yl) -2-chloro-6-phenylpyrimidine was used as a reactant. got .; HRMS [M]+: 740.23

[합성예 381] Mat 381의 합성[Synthesis Example 381] Synthesis of Mat 381

Figure pat00475
Figure pat00475

반응물로 2-클로로-4-(디벤조[b,d]퓨란-3-일)-6-페닐피리미딘을 사용한 것을 제외하고는 [합성예 373]과 동일한 과정을 수행하여 목적 화합물 13.5g을 얻었다.; HRMS [M]+: 654.2113.5 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 373], except that 2-chloro-4-(dibenzo[b,d]furan-3-yl)-6-phenylpyrimidine was used as a reactant. got.; HRMS [M]+: 654.21

[합성예 382] Mat 382의 합성[Synthesis Example 382] Synthesis of Mat 382

Figure pat00476
Figure pat00476

반응물로 4-([1,1'-비페닐]-3-일)-6-([1,1'-비페닐]-4-일)-2-클로로피리미딘을 사용한 것을 제외하고는 [합성예 373]과 동일한 과정을 수행하여 목적 화합물 12.7g을 얻었다.; HRMS [M]+: 716.27[1,1'-biphenyl]-3-yl)-6-([1,1'-biphenyl]-4-yl)-2-chloropyrimidine as the reactant [ Synthesis Example 373] was performed to obtain 12.7 g of the target compound; HRMS [M]+: 716.27

[합성예 383] Mat 383의 합성[Synthesis Example 383] Synthesis of Mat 383

Figure pat00477
Figure pat00477

반응물로 4-(3-브로모페닐)-2,6-디페닐피리미딘을 사용한 것을 제외하고는 [합성예 373]과 동일한 과정을 수행하여 목적 화합물 15.6g을 얻었다.; HRMS [M]+: 640.23Except for using 4-(3-bromophenyl)-2,6-diphenylpyrimidine as a reactant, the same procedure as in [Synthesis Example 373] was performed to obtain 15.6 g of the target compound; HRMS [M]+: 640.23

[합성예 384] Mat 384의 합성[Synthesis Example 384] Synthesis of Mat 384

Figure pat00478
Figure pat00478

반응물로 2,4-디([1,1'-비페닐]-4-일)-6-(3-브로모페닐)피리미딘을 사용한 것을 제외하고는 [합성예 373]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 792.20The same procedure as in [Synthesis Example 373] was performed except that 2,4-di([1,1'-biphenyl]-4-yl)-6-(3-bromophenyl)pyrimidine was used as the reactant. 16.4 g of the target compound was obtained; HRMS [M]+: 792.20

[합성예 385] Mat 385의 합성[Synthesis Example 385] Synthesis of Mat 385

Figure pat00479
Figure pat00479

반응물로 4-([1,1'-비페닐]-4-일)-6-(3-브로모페닐)-2-페닐피리미딘을 사용한 것을 제외하고는 [합성예 373]과 동일한 과정을 수행하여 목적 화합물 15.9g을 얻었다.; HRMS [M]+: 716.27The same procedure as in [Synthesis Example 373] was performed except that 4-([1,1'-biphenyl]-4-yl)-6-(3-bromophenyl)-2-phenylpyrimidine was used as the reactant. This was carried out to obtain 15.9 g of the target compound; HRMS [M]+: 716.27

[합성예 386] Mat 386의 합성[Synthesis Example 386] Synthesis of Mat 386

Figure pat00480
Figure pat00480

반응물로 4-(3-브로모페닐)-6-(디벤조[b,d]퓨란-3-일)-2-페닐피리미딘을 사용한 것을 제외하고는 [합성예 373]과 동일한 과정을 수행하여 목적 화합물 16.6g을 얻었다.; HRMS [M]+: 730.24The same procedure as in [Synthesis Example 373] was performed except that 4-(3-bromophenyl)-6-(dibenzo[b,d]furan-3-yl)-2-phenylpyrimidine was used as the reactant. 16.6 g of the target compound was obtained; HRMS [M]+: 730.24

[합성예 387] Mat 387의 합성[Synthesis Example 387] Synthesis of Mat 387

Figure pat00481
Figure pat00481

반응물로 2-(3-브로모페닐)-4,6-디페닐-1,3,5-트리아진을 사용한 것을 제외하고는 [합성예 373]과 동일한 과정을 수행하여 목적 화합물 14.2g을 얻었다.; HRMS [M]+: 641.2314.2 g of the target compound was obtained by performing the same procedure as in Synthesis Example 373, except that 2-(3-bromophenyl)-4,6-diphenyl-1,3,5-triazine was used as a reactant. .; HRMS [M]+: 641.23

* [합성예 388] Mat 388의 합성 * [Synthesis Example 388] Synthesis of Mat 388

Figure pat00482
Figure pat00482

반응물로 2,4-디([1,1'-비페닐]-4-일)-6-(3-브로모페닐)-1,3,5-트리아진을 사용한 것을 제외하고는 [합성예 373]과 동일한 과정을 수행하여 목적 화합물 16.3g을 얻었다.; HRMS [M]+: 793.29Except for using 2,4-di([1,1'-biphenyl]-4-yl)-6-(3-bromophenyl)-1,3,5-triazine as the reactant [Synthesis Example 373] to obtain 16.3 g of the target compound; HRMS [M]+: 793.29

[합성예 389] Mat 389의 합성[Synthesis Example 389] Synthesis of Mat 389

Figure pat00483
Figure pat00483

반응물로 2-([1,1'-비페닐]-4-일)-4-(3-브로모페닐)-6-페닐-1,3,5-트리아진을 사용한 것을 제외하고는 [합성예 373]과 동일한 과정을 수행하여 목적 화합물 15.3g을 얻었다.; HRMS [M]+: 717.26Except for using 2-([1,1'-biphenyl]-4-yl)-4-(3-bromophenyl)-6-phenyl-1,3,5-triazine as the reactant [synthesis Example 373] to obtain 15.3 g of the target compound; HRMS [M]+: 717.26

[합성예 390] Mat 390의 합성[Synthesis Example 390] Synthesis of Mat 390

Figure pat00484
Figure pat00484

반응물로 2-(3-브로모페닐)-4-(디벤조[b,d]퓨란-3-일)-6-페닐-1,3,5-트리아진을 사용한 것을 제외하고는 [합성예 373]과 동일한 과정을 수행하여 목적 화합물 14.7g을 얻었다.; HRMS [M]+: 731.24Except for using 2-(3-bromophenyl)-4-(dibenzo[b,d]furan-3-yl)-6-phenyl-1,3,5-triazine as the reactant [Synthesis Example 373] to obtain 14.7 g of the target compound; HRMS [M]+: 731.24

[합성예 391] Mat 391의 합성[Synthesis Example 391] Synthesis of Mat 391

Figure pat00485
Figure pat00485

반응물로 2-(4-브로모페닐)-4,6-디페닐-1,3,5-트리아진을 사용한 것을 제외하고는 [합성예 373]과 동일한 과정을 수행하여 목적 화합물 12.1g을 얻었다.; HRMS [M]+: 741.2312.1 g of the target compound was obtained by performing the same procedure as in Synthesis Example 373, except that 2-(4-bromophenyl)-4,6-diphenyl-1,3,5-triazine was used as a reactant. .; HRMS [M]+: 741.23

[합성예 392] Mat 392의 합성[Synthesis Example 392] Synthesis of Mat 392

Figure pat00486
Figure pat00486

반응물로 2,4-디([1,1'-비페닐]-4-일)-6-(4-브로모페닐)-1,3,5-트리아진을 사용한 것을 제외하고는 [합성예 373]과 동일한 과정을 수행하여 목적 화합물 13.9g을 얻었다.; HRMS [M]+: 793.29Except for using 2,4-di([1,1'-biphenyl]-4-yl)-6-(4-bromophenyl)-1,3,5-triazine as the reactant [Synthesis Example 373] to obtain 13.9 g of the target compound; HRMS [M]+: 793.29

[합성예 393] Mat 393의 합성[Synthesis Example 393] Synthesis of Mat 393

Figure pat00487
Figure pat00487

반응물로 2-([1,1'-비페닐]-3-일)-4-([1,1'-비페닐]-4-일)-6-(4-브로모페닐)-1,3,5-트리아진을 사용한 것을 제외하고는 [합성예 373]과 동일한 과정을 수행하여 목적 화합물 14.8g을 얻었다.; HRMS [M]+: 793.292-([1,1'-biphenyl]-3-yl)-4-([1,1'-biphenyl]-4-yl)-6-(4-bromophenyl)-1, Except for using 3,5-triazine, 14.8 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 373]; HRMS [M]+: 793.29

[합성예 394] Mat 394의 합성[Synthesis Example 394] Synthesis of Mat 394

Figure pat00488
Figure pat00488

반응물로 2-([1,1'-비페닐]-4-일)-4-(4-브로모페닐)-6-페닐-1,3,5-트리아진을 사용한 것을 제외하고는 [합성예 373]과 동일한 과정을 수행하여 목적 화합물 13.8g을 얻었다.; HRMS [M]+: 717.26Except for using 2-([1,1'-biphenyl]-4-yl)-4-(4-bromophenyl)-6-phenyl-1,3,5-triazine as the reactant [synthesis Example 373] to obtain 13.8 g of the target compound; HRMS [M]+: 717.26

[합성예 395] Mat 395의 합성[Synthesis Example 395] Synthesis of Mat 395

Figure pat00489
Figure pat00489

반응물로 2-(4-브로모페닐)-4-(디벤조[b,d]퓨란-3-일)-6-페닐-1,3,5-트리아진을 사용한 것을 제외하고는 [합성예 373]과 동일한 과정을 수행하여 목적 화합물 14.3g을 얻었다.; HRMS [M]+: 731.24Except for using 2-(4-bromophenyl)-4-(dibenzo[b,d]furan-3-yl)-6-phenyl-1,3,5-triazine as the reactant [Synthesis Example 373] to obtain 14.3 g of the target compound; HRMS [M]+: 731.24

[합성예 396] Mat 396의 합성[Synthesis Example 396] Synthesis of Mat 396

Figure pat00490
Figure pat00490

반응물로 2-(3'-클로로-[1,1'-비페닐]-3-일)-4,6-디페닐-1,3,5-트리아진을 사용한 것을 제외하고는 [합성예 373]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 717.26Except for using 2- (3'-chloro- [1,1'-biphenyl] -3-yl) -4,6-diphenyl-1,3,5-triazine as a reactant [Synthesis Example 373 ] to obtain 16.4 g of the target compound; HRMS [M]+: 717.26

[합성예 397] Mat 397의 합성[Synthesis Example 397] Synthesis of Mat 397

Figure pat00491
Figure pat00491

반응물로 2,4-디([1,1'-비페닐]-4-일)-6-(3'-클로로-[1,1'-비페닐]-3-일)-1,3,5-트리아진을 사용한 것을 제외하고는 [합성예 373]과 동일한 과정을 수행하여 목적 화합물 12.7g을 얻었다.; HRMS [M]+: 869.322,4-di([1,1'-biphenyl]-4-yl)-6-(3'-chloro-[1,1'-biphenyl]-3-yl)-1,3, 12.7 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 373] except that 5-triazine was used; HRMS [M]+: 869.32

[합성예 398] Mat 398의 합성[Synthesis Example 398] Synthesis of Mat 398

Figure pat00492
Figure pat00492

반응물로 2-([1,1'-비페닐]-3-일)-4-([1,1'-비페닐]-4-일)-6-(3'-클로로-[1,1'-비페닐]-3-일)-1,3,5-트리아진을 사용한 것을 제외하고는 [합성예 373]과 동일한 과정을 수행하여 목적 화합물 13.3g을 얻었다.; HRMS [M]+: 869.322-([1,1'-biphenyl]-3-yl)-4-([1,1'-biphenyl]-4-yl)-6-(3'-chloro-[1,1 13.3 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 373] except for using '-biphenyl] -3-yl) -1,3,5-triazine; HRMS [M]+: 869.32

[합성예 399] Mat 399의 합성[Synthesis Example 399] Synthesis of Mat 399

Figure pat00493
Figure pat00493

반응물로 2-([1,1'-비페닐]-4-일)-4-(3'-클로로-[1,1'-비페닐]-3-일)-6-페닐-1,3,5-트리아진을 사용한 것을 제외하고는 [합성예 373]과 동일한 과정을 수행하여 목적 화합물 15.6g을 얻었다.; HRMS [M]+: 793.292-([1,1'-biphenyl]-4-yl)-4-(3'-chloro-[1,1'-biphenyl]-3-yl)-6-phenyl-1,3 Except for using ,5-triazine, the same procedure as in [Synthesis Example 373] was performed to obtain 15.6 g of the target compound; HRMS [M]+: 793.29

[합성예 400] Mat 400의 합성[Synthesis Example 400] Synthesis of Mat 400

Figure pat00494
Figure pat00494

반응물로 2-(3'-클로로-[1,1'-비페닐]-3-일)-4-(디벤조[b,d]퓨란-3-일)-6-페닐-1,3,5-트리아진을 사용한 것을 제외하고는 [합성예 373]과 동일한 과정을 수행하여 목적 화합물 14.8g을 얻었다.; HRMS [M]+: 807.272-(3'-chloro-[1,1'-biphenyl]-3-yl)-4-(dibenzo[b,d]furan-3-yl)-6-phenyl-1,3, 14.8 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 373] except that 5-triazine was used; HRMS [M]+: 807.27

[합성예 401] Mat 401의 합성[Synthesis Example 401] Synthesis of Mat 401

Figure pat00495
Figure pat00495

반응물로 2-클로로-4-페닐퀴나졸린을 사용한 것을 제외하고는 [합성예 373]과 동일한 과정을 수행하여 목적 화합물 13.7g을 얻었다.; HRMS [M]+: 538.19Except for using 2-chloro-4-phenylquinazoline as a reactant, the same procedure as in [Synthesis Example 373] was performed to obtain 13.7 g of the target compound; HRMS [M]+: 538.19

[합성예 402] Mat 402의 합성[Synthesis Example 402] Synthesis of Mat 402

Figure pat00496
Figure pat00496

반응물로 4-([1,1'-비페닐]-4-일)-2-클로로퀴나졸린을 사용한 것을 제외하고는 [합성예 373]과 동일한 과정을 수행하여 목적 화합물 14.6g을 얻었다.; HRMS [M]+: 614.2214.6 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 373], except that 4-([1,1'-biphenyl]-4-yl)-2-chloroquinazoline was used as a reactant; HRMS [M]+: 614.22

[합성예 403] Mat 403의 합성[Synthesis Example 403] Synthesis of Mat 403

Figure pat00497
Figure pat00497

반응물로 2-클로로-4-(4-(나프탈렌-1-일)페닐)퀴나졸린을 사용한 것을 제외하고는 [합성예 373]과 동일한 과정을 수행하여 목적 화합물 15.1g을 얻었다.; HRMS [M]+: 368.0915.1 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 373], except that 2-chloro-4-(4-(naphthalen-1-yl)phenyl)quinazoline was used as a reactant; HRMS [M]+: 368.09

* [합성예 404] Mat 404의 합성 * [Synthesis Example 404] Synthesis of Mat 404

Figure pat00498
Figure pat00498

반응물로 2-클로로-4-페닐벤조[h]퀴나졸린을 사용한 것을 제외하고는 [합성예 373]과 동일한 과정을 수행하여 목적 화합물 14.5g을 얻었다.; HRMS [M]+: 588.2014.5 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 373], except that 2-chloro-4-phenylbenzo[h]quinazoline was used as a reactant; HRMS [M]+: 588.20

* [합성예 405] Mat 405의 합성 * [Synthesis Example 405] Synthesis of Mat 405

Figure pat00499
Figure pat00499

반응물로 2-클로로-3-페닐퀴녹살린을 사용한 것을 제외하고는 [합성예 373]과 동일한 과정을 수행하여 목적 화합물 13.5g을 얻었다.; HRMS [M]+: 538.19Except for using 2-chloro-3-phenylquinoxaline as a reactant, the same procedure as in [Synthesis Example 373] was performed to obtain 13.5 g of the target compound; HRMS [M]+: 538.19

[합성예 406] Mat 406의 합성[Synthesis Example 406] Synthesis of Mat 406

Figure pat00500
Figure pat00500

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 373]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 564.20Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 373] was performed to obtain 16.4 g of the target compound; HRMS [M]+: 564.20

[합성예 407] Mat 407의 합성[Synthesis Example 407] Synthesis of Mat 407

Figure pat00501
Figure pat00501

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 374]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 716.27Except for using [Preparation Example 2] as a reactant, 16.4 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 374]; HRMS [M]+: 716.27

[합성예 408] Mat 408의 합성[Synthesis Example 408] Synthesis of Mat 408

Figure pat00502
Figure pat00502

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 375]과 동일한 과정을 수행하여 목적 화합물 15.8g을 얻었다.; HRMS [M]+: 716.27Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 375] was performed to obtain 15.8 g of the target compound; HRMS [M]+: 716.27

[합성예 409] Mat 409의 합성[Synthesis Example 409] Synthesis of Mat 409

Figure pat00503
Figure pat00503

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 376]과 동일한 과정을 수행하여 목적 화합물 14.1g을 얻었다.; HRMS [M]+: 640.23Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 376] was performed to obtain 14.1 g of the target compound; HRMS [M]+: 640.23

[합성예 410] Mat 410의 합성[Synthesis Example 410] Synthesis of Mat 410

Figure pat00504
Figure pat00504

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 377]과 동일한 과정을 수행하여 목적 화합물 14.3g을 얻었다.; HRMS [M]+: 654.21Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 377] was performed to obtain 14.3 g of the target compound; HRMS [M]+: 654.21

[합성예 411] Mat 411의 합성[Synthesis Example 411] Synthesis of Mat 411

Figure pat00505
Figure pat00505

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 378]과 동일한 과정을 수행하여 목적 화합물 12.1g을 얻었다.; HRMS [M]+: 564.20Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 378] was performed to obtain 12.1 g of the target compound; HRMS [M]+: 564.20

[합성예 412] Mat 412의 합성[Synthesis Example 412] Synthesis of Mat 412

Figure pat00506
Figure pat00506

반응물로 [준비예2]e을 사용한 것을 제외하고는 [합성예 379]과 동일한 과정을 수행하여 목적 화합물 13.9g을 얻었다.; HRMS [M]+: 716.27Except for using [Preparation Example 2] e as a reactant, the same procedure as in [Synthesis Example 379] was performed to obtain 13.9 g of the target compound; HRMS [M]+: 716.27

[합성예 413] Mat 413의 합성[Synthesis Example 413] Synthesis of Mat 413

Figure pat00507
Figure pat00507

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 380]과 동일한 과정을 수행하여 목적 화합물 14.8g을 얻었다.; HRMS [M]+: 740.23Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 380] was performed to obtain 14.8 g of the target compound; HRMS [M]+: 740.23

[합성예 414] Mat 414의 합성[Synthesis Example 414] Synthesis of Mat 414

Figure pat00508
Figure pat00508

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 381]과 동일한 과정을 수행하여 목적 화합물 13.5g을 얻었다.; HRMS [M]+: 654.2113.5 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 381] except that [Preparation Example 2] was used as a reactant; HRMS [M]+: 654.21

[합성예 415] Mat 415의 합성[Synthesis Example 415] Synthesis of Mat 415

Figure pat00509
Figure pat00509

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 382]과 동일한 과정을 수행하여 목적 화합물 12.7g을 얻었다.; HRMS [M]+: 716.2712.7 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 382] except that [Preparation Example 2] was used as a reactant; HRMS [M]+: 716.27

[합성예 416] Mat 416의 합성[Synthesis Example 416] Synthesis of Mat 416

Figure pat00510
Figure pat00510

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 383]과 동일한 과정을 수행하여 목적 화합물 15.6g을 얻었다.; HRMS [M]+: 640.23Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 383] was performed to obtain 15.6 g of the target compound; HRMS [M]+: 640.23

[합성예 417] Mat 417의 합성[Synthesis Example 417] Synthesis of Mat 417

Figure pat00511
Figure pat00511

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 384]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 792.20Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 384] was performed to obtain 16.4 g of the target compound; HRMS [M]+: 792.20

[합성예 418] Mat 418의 합성[Synthesis Example 418] Synthesis of Mat 418

Figure pat00512
Figure pat00512

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 385]과 동일한 과정을 수행하여 목적 화합물 15.9g을 얻었다.; HRMS [M]+: 716.27Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 385] was performed to obtain 15.9 g of the target compound; HRMS [M]+: 716.27

[합성예 419] Mat 419의 합성[Synthesis Example 419] Synthesis of Mat 419

Figure pat00513
Figure pat00513

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 386]과 동일한 과정을 수행하여 목적 화합물 16.6g을 얻었다.; HRMS [M]+: 730.24Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 386] was performed to obtain 16.6 g of the target compound; HRMS [M]+: 730.24

[합성예 420] Mat 420의 합성[Synthesis Example 420] Synthesis of Mat 420

Figure pat00514
Figure pat00514

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 387]과 동일한 과정을 수행하여 목적 화합물 14.2g을 얻었다.; HRMS [M]+: 641.23Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 387] was performed to obtain 14.2 g of the target compound; HRMS [M]+: 641.23

[합성예 421] Mat 421의 합성[Synthesis Example 421] Synthesis of Mat 421

Figure pat00515
Figure pat00515

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 388]과 동일한 과정을 수행하여 목적 화합물 16.3g을 얻었다.; HRMS [M]+: 793.29Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 388] was performed to obtain 16.3 g of the target compound; HRMS [M]+: 793.29

[합성예 422] Mat 422의 합성[Synthesis Example 422] Synthesis of Mat 422

Figure pat00516
Figure pat00516

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 389]과 동일한 과정을 수행하여 목적 화합물 15.3g을 얻었다.; HRMS [M]+: 717.26Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 389] was performed to obtain 15.3 g of the target compound; HRMS [M]+: 717.26

[합성예 423] Mat 423의 합성[Synthesis Example 423] Synthesis of Mat 423

Figure pat00517
Figure pat00517

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 390]과 동일한 과정을 수행하여 목적 화합물 14.7g을 얻었다.; HRMS [M]+: 731.24Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 390] was performed to obtain 14.7 g of the target compound; HRMS [M]+: 731.24

[합성예 424] Mat 424의 합성[Synthesis Example 424] Synthesis of Mat 424

Figure pat00518
Figure pat00518

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 391]과 동일한 과정을 수행하여 목적 화합물 12.1g을 얻었다.; HRMS [M]+: 741.23Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 391] was performed to obtain 12.1 g of the target compound; HRMS [M]+: 741.23

[합성예 425] Mat 425의 합성[Synthesis Example 425] Synthesis of Mat 425

Figure pat00519
Figure pat00519

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 392]과 동일한 과정을 수행하여 목적 화합물 13.9g을 얻었다.; HRMS [M]+: 793.29Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 392] was performed to obtain 13.9 g of the target compound; HRMS [M]+: 793.29

[합성예 426] Mat 426의 합성[Synthesis Example 426] Synthesis of Mat 426

Figure pat00520
Figure pat00520

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 393]과 동일한 과정을 수행하여 목적 화합물 14.8g을 얻었다.; HRMS [M]+: 793.29Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 393] was performed to obtain 14.8 g of the target compound; HRMS [M]+: 793.29

[합성예 427] Mat 427의 합성[Synthesis Example 427] Synthesis of Mat 427

Figure pat00521
Figure pat00521

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 394]과 동일한 과정을 수행하여 목적 화합물 13.8g을 얻었다.; HRMS [M]+: 717.26Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 394] was performed to obtain 13.8 g of the target compound; HRMS [M]+: 717.26

[합성예 428] Mat 428의 합성[Synthesis Example 428] Synthesis of Mat 428

Figure pat00522
Figure pat00522

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 395]과 동일한 과정을 수행하여 목적 화합물 14.3g을 얻었다.; HRMS [M]+: 731.24Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 395] was performed to obtain 14.3 g of the target compound; HRMS [M]+: 731.24

[합성예 429] Mat 429의 합성[Synthesis Example 429] Synthesis of Mat 429

Figure pat00523
Figure pat00523

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 396]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 717.26Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 396] was performed to obtain 16.4 g of the target compound; HRMS [M]+: 717.26

[합성예 430] Mat 430의 합성[Synthesis Example 430] Synthesis of Mat 430

Figure pat00524
Figure pat00524

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 397]과 동일한 과정을 수행하여 목적 화합물 12.7g을 얻었다.; HRMS [M]+: 869.32Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 397] was performed to obtain 12.7 g of the target compound; HRMS [M]+: 869.32

[합성예 431] Mat 431의 합성[Synthesis Example 431] Synthesis of Mat 431

Figure pat00525
Figure pat00525

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 398]과 동일한 과정을 수행하여 목적 화합물 13.3g을 얻었다.; HRMS [M]+: 869.32Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 398] was performed to obtain 13.3 g of the target compound; HRMS [M]+: 869.32

[합성예 432] Mat 432의 합성[Synthesis Example 432] Synthesis of Mat 432

Figure pat00526
Figure pat00526

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 399]과 동일한 과정을 수행하여 목적 화합물 15.6g을 얻었다.; HRMS [M]+: 793.29Except for using [Preparation Example 2] as a reactant, 15.6 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 399]; HRMS [M]+: 793.29

[합성예 433] Mat 433의 합성[Synthesis Example 433] Synthesis of Mat 433

Figure pat00527
Figure pat00527

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 400]과 동일한 과정을 수행하여 목적 화합물 14.8g을 얻었다.; HRMS [M]+: 807.27Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 400] was performed to obtain 14.8 g of the target compound; HRMS [M]+: 807.27

[합성예 434] Mat 434의 합성[Synthesis Example 434] Synthesis of Mat 434

Figure pat00528
Figure pat00528

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 401]과 동일한 과정을 수행하여 목적 화합물 13.7g을 얻었다.; HRMS [M]+: 538.19Except for using [Preparation Example 2] as a reactant, 13.7 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 401]; HRMS [M]+: 538.19

[합성예 435] Mat 435의 합성[Synthesis Example 435] Synthesis of Mat 435

Figure pat00529
Figure pat00529

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 402]과 동일한 과정을 수행하여 목적 화합물 14.6g을 얻었다.; HRMS [M]+: 614.22Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 402] was performed to obtain 14.6 g of the target compound; HRMS [M]+: 614.22

[합성예 436] Mat 436의 합성[Synthesis Example 436] Synthesis of Mat 436

Figure pat00530
Figure pat00530

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 403]과 동일한 과정을 수행하여 목적 화합물 15.1g을 얻었다.; HRMS [M]+: 368.09Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 403] was performed to obtain 15.1 g of the target compound; HRMS [M]+: 368.09

[합성예 437] Mat 437의 합성[Synthesis Example 437] Synthesis of Mat 437

Figure pat00531
Figure pat00531

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 404]과 동일한 과정을 수행하여 목적 화합물 14.5g을 얻었다.; HRMS [M]+: 588.20Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 404] was performed to obtain 14.5 g of the target compound; HRMS [M]+: 588.20

[합성예 438] Mat 438의 합성[Synthesis Example 438] Synthesis of Mat 438

Figure pat00532
Figure pat00532

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 405]과 동일한 과정을 수행하여 목적 화합물 13.5g을 얻었다.; HRMS [M]+: 538.19Except for using [Preparation Example 2] as a reactant, 13.5 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 405].; HRMS [M]+: 538.19

[합성예 439] Mat 439의 합성[Synthesis Example 439] Synthesis of Mat 439

Figure pat00533
Figure pat00533

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 373]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 564.20Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 373] was performed to obtain 16.4 g of the target compound; HRMS [M]+: 564.20

[합성예 440] Mat 440의 합성[Synthesis Example 440] Synthesis of Mat 440

Figure pat00534
Figure pat00534

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 374]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 716.27Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 374] was performed to obtain 16.4 g of the target compound; HRMS [M]+: 716.27

[합성예 441] Mat 441의 합성[Synthesis Example 441] Synthesis of Mat 441

Figure pat00535
Figure pat00535

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 375]과 동일한 과정을 수행하여 목적 화합물 15.8g을 얻었다.; HRMS [M]+: 716.27Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 375] was performed to obtain 15.8 g of the target compound; HRMS [M]+: 716.27

[합성예 442] Mat 442의 합성[Synthesis Example 442] Synthesis of Mat 442

Figure pat00536
Figure pat00536

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 376]과 동일한 과정을 수행하여 목적 화합물 14.1g을 얻었다.; HRMS [M]+: 640.23Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 376] was performed to obtain 14.1 g of the target compound; HRMS [M]+: 640.23

[합성예 443] Mat 443의 합성[Synthesis Example 443] Synthesis of Mat 443

Figure pat00537
Figure pat00537

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 377]과 동일한 과정을 수행하여 목적 화합물 14.3g을 얻었다.; HRMS [M]+: 654.21Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 377] was performed to obtain 14.3 g of the target compound; HRMS [M]+: 654.21

[합성예 444] Mat 444의 합성[Synthesis Example 444] Synthesis of Mat 444

Figure pat00538
Figure pat00538

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 378]과 동일한 과정을 수행하여 목적 화합물 12.1g을 얻었다.; HRMS [M]+: 564.20Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 378] was performed to obtain 12.1 g of the target compound; HRMS [M]+: 564.20

[합성예 445] Mat 445의 합성[Synthesis Example 445] Synthesis of Mat 445

Figure pat00539
Figure pat00539

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 379]과 동일한 과정을 수행하여 목적 화합물 13.9g을 얻었다.; HRMS [M]+: 716.27Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 379] was performed to obtain 13.9 g of the target compound; HRMS [M]+: 716.27

[합성예 446] Mat 446의 합성[Synthesis Example 446] Synthesis of Mat 446

Figure pat00540
Figure pat00540

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 380]과 동일한 과정을 수행하여 목적 화합물 14.8g을 얻었다.; HRMS [M]+: 740.23Except for using [Preparation Example 3] as a reactant, 14.8 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 380]; HRMS [M]+: 740.23

[합성예 447] Mat 447의 합성[Synthesis Example 447] Synthesis of Mat 447

Figure pat00541
Figure pat00541

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 381]과 동일한 과정을 수행하여 목적 화합물 13.5g을 얻었다.; HRMS [M]+: 654.21Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 381] was performed to obtain 13.5 g of the target compound; HRMS [M]+: 654.21

[합성예 448] Mat 448의 합성[Synthesis Example 448] Synthesis of Mat 448

Figure pat00542
Figure pat00542

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 382]과 동일한 과정을 수행하여 목적 화합물 12.7g을 얻었다.; HRMS [M]+: 716.27Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 382] was performed to obtain 12.7 g of the target compound; HRMS [M]+: 716.27

[합성예 449] Mat 449의 합성[Synthesis Example 449] Synthesis of Mat 449

Figure pat00543
Figure pat00543

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 383]과 동일한 과정을 수행하여 목적 화합물 15.6g을 얻었다.; HRMS [M]+: 640.23Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 383] was performed to obtain 15.6 g of the target compound; HRMS [M]+: 640.23

[합성예 450] Mat 450의 합성[Synthesis Example 450] Synthesis of Mat 450

Figure pat00544
Figure pat00544

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 384]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 792.20Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 384] was performed to obtain 16.4 g of the target compound; HRMS [M]+: 792.20

[합성예 451] Mat 451의 합성[Synthesis Example 451] Synthesis of Mat 451

Figure pat00545
Figure pat00545

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 385]과 동일한 과정을 수행하여 목적 화합물 15.9g을 얻었다.; HRMS [M]+: 716.27Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 385] was performed to obtain 15.9 g of the target compound; HRMS [M]+: 716.27

[합성예 452] Mat 452의 합성[Synthesis Example 452] Synthesis of Mat 452

Figure pat00546
Figure pat00546

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 386]과 동일한 과정을 수행하여 목적 화합물 16.6g을 얻었다.; HRMS [M]+: 730.24Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 386] was performed to obtain 16.6 g of the target compound; HRMS [M]+: 730.24

[합성예 453] Mat 453의 합성[Synthesis Example 453] Synthesis of Mat 453

Figure pat00547
Figure pat00547

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 387]과 동일한 과정을 수행하여 목적 화합물 14.2g을 얻었다.; HRMS [M]+: 641.2314.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 387] except that [Preparation Example 3] was used as a reactant; HRMS [M]+: 641.23

[합성예 454] Mat 454의 합성[Synthesis Example 454] Synthesis of Mat 454

Figure pat00548
Figure pat00548

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 388]과 동일한 과정을 수행하여 목적 화합물 16.3g을 얻었다.; HRMS [M]+: 793.29Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 388] was performed to obtain 16.3 g of the target compound; HRMS [M]+: 793.29

[합성예 455] Mat 455의 합성[Synthesis Example 455] Synthesis of Mat 455

Figure pat00549
Figure pat00549

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 389]과 동일한 과정을 수행하여 목적 화합물 15.3g을 얻었다.; HRMS [M]+: 717.26Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 389] was performed to obtain 15.3 g of the target compound; HRMS [M]+: 717.26

[합성예 456] Mat 456의 합성[Synthesis Example 456] Synthesis of Mat 456

Figure pat00550
Figure pat00550

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 390]과 동일한 과정을 수행하여 목적 화합물 14.7g을 얻었다.; HRMS [M]+: 731.2414.7 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 390] except that [Preparation Example 3] was used as a reactant; HRMS [M]+: 731.24

[합성예 457] Mat 457의 합성[Synthesis Example 457] Synthesis of Mat 457

Figure pat00551
Figure pat00551

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 391]과 동일한 과정을 수행하여 목적 화합물 12.1g을 얻었다.; HRMS [M]+: 741.23Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 391] was performed to obtain 12.1 g of the target compound; HRMS [M]+: 741.23

[합성예 458] Mat 458의 합성[Synthesis Example 458] Synthesis of Mat 458

Figure pat00552
Figure pat00552

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 392]과 동일한 과정을 수행하여 목적 화합물 13.9g을 얻었다.; HRMS [M]+: 793.29Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 392] was performed to obtain 13.9 g of the target compound; HRMS [M]+: 793.29

[합성예 459] Mat 459의 합성[Synthesis Example 459] Synthesis of Mat 459

Figure pat00553
Figure pat00553

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 393]과 동일한 과정을 수행하여 목적 화합물 14.8g을 얻었다.; HRMS [M]+: 793.29Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 393] was performed to obtain 14.8 g of the target compound; HRMS [M]+: 793.29

[합성예 460] Mat 460의 합성[Synthesis Example 460] Synthesis of Mat 460

Figure pat00554
Figure pat00554

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 394]과 동일한 과정을 수행하여 목적 화합물 13.8g을 얻었다.; HRMS [M]+: 717.26Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 394] was performed to obtain 13.8 g of the target compound; HRMS [M]+: 717.26

[합성예 461] Mat 461의 합성[Synthesis Example 461] Synthesis of Mat 461

Figure pat00555
Figure pat00555

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 395]과 동일한 과정을 수행하여 목적 화합물 14.3g을 얻었다.; HRMS [M]+: 731.24Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 395] was performed to obtain 14.3 g of the target compound; HRMS [M]+: 731.24

[합성예 462] Mat 462의 합성[Synthesis Example 462] Synthesis of Mat 462

Figure pat00556
Figure pat00556

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 396]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 717.26Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 396] was performed to obtain 16.4 g of the target compound; HRMS [M]+: 717.26

[합성예 463] Mat 463의 합성[Synthesis Example 463] Synthesis of Mat 463

Figure pat00557
Figure pat00557

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 397]과 동일한 과정을 수행하여 목적 화합물 12.7g을 얻었다.; HRMS [M]+: 869.32Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 397] was performed to obtain 12.7 g of the target compound; HRMS [M]+: 869.32

[합성예 464] Mat 464의 합성[Synthesis Example 464] Synthesis of Mat 464

Figure pat00558
Figure pat00558

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 398]과 동일한 과정을 수행하여 목적 화합물 13.3g을 얻었다.; HRMS [M]+: 869.32Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 398] was performed to obtain 13.3 g of the target compound; HRMS [M]+: 869.32

[합성예 465] Mat 465의 합성[Synthesis Example 465] Synthesis of Mat 465

Figure pat00559
Figure pat00559

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 399]과 동일한 과정을 수행하여 목적 화합물 15.6g을 얻었다.; HRMS [M]+: 793.29Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 399] was performed to obtain 15.6 g of the target compound; HRMS [M]+: 793.29

[합성예 466] Mat 466의 합성[Synthesis Example 466] Synthesis of Mat 466

Figure pat00560
Figure pat00560

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 400]과 동일한 과정을 수행하여 목적 화합물 14.8g을 얻었다.; HRMS [M]+: 807.2714.8 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 400] except that [Preparation Example 3] was used as a reactant; HRMS [M]+: 807.27

[합성예 467] Mat 467의 합성[Synthesis Example 467] Synthesis of Mat 467

Figure pat00561
Figure pat00561

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 401]과 동일한 과정을 수행하여 목적 화합물 13.7g을 얻었다.; HRMS [M]+: 538.19Except for using [Preparation Example 3] as a reactant, 13.7 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 401]; HRMS [M]+: 538.19

[합성예 468] Mat 468의 합성[Synthesis Example 468] Synthesis of Mat 468

Figure pat00562
Figure pat00562

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 402]과 동일한 과정을 수행하여 목적 화합물 14.6g을 얻었다.; HRMS [M]+: 614.22Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 402] was performed to obtain 14.6 g of the target compound; HRMS [M]+: 614.22

[합성예 469] Mat 469의 합성[Synthesis Example 469] Synthesis of Mat 469

Figure pat00563
Figure pat00563

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 403]과 동일한 과정을 수행하여 목적 화합물 15.1g을 얻었다.; HRMS [M]+: 368.0915.1 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 403] except that [Preparation Example 3] was used as a reactant; HRMS [M]+: 368.09

[합성예 470] Mat 470의 합성[Synthesis Example 470] Synthesis of Mat 470

Figure pat00564
Figure pat00564

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 404]과 동일한 과정을 수행하여 목적 화합물 14.5g을 얻었다.; HRMS [M]+: 588.20Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 404] was performed to obtain 14.5 g of the target compound; HRMS [M]+: 588.20

[합성예 471] Mat 471의 합성[Synthesis Example 471] Synthesis of Mat 471

Figure pat00565
Figure pat00565

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 405]과 동일한 과정을 수행하여 목적 화합물 13.5g을 얻었다.; HRMS [M]+: 538.19Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 405] was performed to obtain 13.5 g of the target compound; HRMS [M]+: 538.19

[합성예 472] Mat 472의 합성[Synthesis Example 472] Synthesis of Mat 472

Figure pat00566
Figure pat00566

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 373]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 564.20Except for using [Preparation Example 4] as a reactant, 16.4 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 373]; HRMS [M]+: 564.20

[합성예 473] Mat 473의 합성[Synthesis Example 473] Synthesis of Mat 473

Figure pat00567
Figure pat00567

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 374]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 716.27Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 374] was performed to obtain 16.4 g of the target compound; HRMS [M]+: 716.27

[합성예 474] Mat 474의 합성[Synthesis Example 474] Synthesis of Mat 474

Figure pat00568
Figure pat00568

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 375]과 동일한 과정을 수행하여 목적 화합물 15.8g을 얻었다.; HRMS [M]+: 716.27Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 375] was performed to obtain 15.8 g of the target compound; HRMS [M]+: 716.27

[합성예 475] Mat 475의 합성[Synthesis Example 475] Synthesis of Mat 475

Figure pat00569
Figure pat00569

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 376]과 동일한 과정을 수행하여 목적 화합물 14.1g을 얻었다.; HRMS [M]+: 640.23Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 376] was performed to obtain 14.1 g of the target compound; HRMS [M]+: 640.23

[합성예 476] Mat 476의 합성[Synthesis Example 476] Synthesis of Mat 476

Figure pat00570
Figure pat00570

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 377]과 동일한 과정을 수행하여 목적 화합물 14.3g을 얻었다.; HRMS [M]+: 654.21Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 377] was performed to obtain 14.3 g of the target compound; HRMS [M]+: 654.21

[합성예 477] Mat 477의 합성[Synthesis Example 477] Synthesis of Mat 477

Figure pat00571
Figure pat00571

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 378]과 동일한 과정을 수행하여 목적 화합물 12.1g을 얻었다.; HRMS [M]+: 564.20Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 378] was performed to obtain 12.1 g of the target compound; HRMS [M]+: 564.20

[합성예 478] Mat 478의 합성[Synthesis Example 478] Synthesis of Mat 478

Figure pat00572
Figure pat00572

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 379]과 동일한 과정을 수행하여 목적 화합물 13.9g을 얻었다.; HRMS [M]+: 716.27Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 379] was performed to obtain 13.9 g of the target compound; HRMS [M]+: 716.27

[합성예 479] Mat 479의 합성[Synthesis Example 479] Synthesis of Mat 479

Figure pat00573
Figure pat00573

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 380]과 동일한 과정을 수행하여 목적 화합물 14.8g을 얻었다.; HRMS [M]+: 740.23Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 380] was performed to obtain 14.8 g of the target compound; HRMS [M]+: 740.23

[합성예 480] Mat 480의 합성[Synthesis Example 480] Synthesis of Mat 480

Figure pat00574
Figure pat00574

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 381]과 동일한 과정을 수행하여 목적 화합물 13.5g을 얻었다.; HRMS [M]+: 654.21Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 381] was performed to obtain 13.5 g of the target compound; HRMS [M]+: 654.21

[합성예 481] Mat 481의 합성[Synthesis Example 481] Synthesis of Mat 481

Figure pat00575
Figure pat00575

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 382]과 동일한 과정을 수행하여 목적 화합물 12.7g을 얻었다.; HRMS [M]+: 716.27Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 382] was performed to obtain 12.7 g of the target compound; HRMS [M]+: 716.27

[합성예 482] Mat 482의 합성[Synthesis Example 482] Synthesis of Mat 482

Figure pat00576
Figure pat00576

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 383]과 동일한 과정을 수행하여 목적 화합물 15.6g을 얻었다.; HRMS [M]+: 640.23Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 383] was performed to obtain 15.6 g of the target compound; HRMS [M]+: 640.23

[합성예 483] Mat 483의 합성[Synthesis Example 483] Synthesis of Mat 483

Figure pat00577
Figure pat00577

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 384]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 792.20Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 384] was performed to obtain 16.4 g of the target compound; HRMS [M]+: 792.20

[합성예 484] Mat 484의 합성[Synthesis Example 484] Synthesis of Mat 484

Figure pat00578
Figure pat00578

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 385]과 동일한 과정을 수행하여 목적 화합물 15.9g을 얻었다.; HRMS [M]+: 716.27Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 385] was performed to obtain 15.9 g of the target compound; HRMS [M]+: 716.27

[합성예 485] Mat 485의 합성[Synthesis Example 485] Synthesis of Mat 485

Figure pat00579
Figure pat00579

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 386]과 동일한 과정을 수행하여 목적 화합물 16.6g을 얻었다.; HRMS [M]+: 730.24Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 386] was performed to obtain 16.6 g of the target compound; HRMS [M]+: 730.24

[합성예 486] Mat 486의 합성[Synthesis Example 486] Synthesis of Mat 486

Figure pat00580
Figure pat00580

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 387]과 동일한 과정을 수행하여 목적 화합물 14.2g을 얻었다.; HRMS [M]+: 641.2314.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 387] except that [Preparation Example 4] was used as a reactant; HRMS [M]+: 641.23

[합성예 487] Mat 487의 합성[Synthesis Example 487] Synthesis of Mat 487

Figure pat00581
Figure pat00581

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 388]과 동일한 과정을 수행하여 목적 화합물 16.3g을 얻었다.; HRMS [M]+: 793.29Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 388] was performed to obtain 16.3 g of the target compound; HRMS [M]+: 793.29

[합성예 488] Mat 488의 합성[Synthesis Example 488] Synthesis of Mat 488

Figure pat00582
Figure pat00582

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 389]과 동일한 과정을 수행하여 목적 화합물 15.3g을 얻었다.; HRMS [M]+: 717.26Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 389] was performed to obtain 15.3 g of the target compound; HRMS [M]+: 717.26

[합성예 489] Mat 489의 합성[Synthesis Example 489] Synthesis of Mat 489

Figure pat00583
Figure pat00583

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 390]과 동일한 과정을 수행하여 목적 화합물 14.7g을 얻었다.; HRMS [M]+: 731.24Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 390] was performed to obtain 14.7 g of the target compound; HRMS [M]+: 731.24

[합성예 490] Mat 490의 합성[Synthesis Example 490] Synthesis of Mat 490

Figure pat00584
Figure pat00584

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 391]과 동일한 과정을 수행하여 목적 화합물 12.1g을 얻었다.; HRMS [M]+: 741.23Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 391] was performed to obtain 12.1 g of the target compound; HRMS [M]+: 741.23

[합성예 491] Mat 491의 합성[Synthesis Example 491] Synthesis of Mat 491

Figure pat00585
Figure pat00585

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 392]과 동일한 과정을 수행하여 목적 화합물 13.9g을 얻었다.; HRMS [M]+: 793.29Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 392] was performed to obtain 13.9 g of the target compound; HRMS [M]+: 793.29

[합성예 492] Mat 492의 합성[Synthesis Example 492] Synthesis of Mat 492

Figure pat00586
Figure pat00586

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 393]과 동일한 과정을 수행하여 목적 화합물 14.8g을 얻었다.; HRMS [M]+: 793.29Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 393] was performed to obtain 14.8 g of the target compound; HRMS [M]+: 793.29

[합성예 493] Mat 493의 합성[Synthesis Example 493] Synthesis of Mat 493

Figure pat00587
Figure pat00587

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 394]과 동일한 과정을 수행하여 목적 화합물 13.8g을 얻었다.; HRMS [M]+: 717.26Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 394] was performed to obtain 13.8 g of the target compound; HRMS [M]+: 717.26

[합성예 494] Mat 494의 합성[Synthesis Example 494] Synthesis of Mat 494

Figure pat00588
Figure pat00588

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 395]과 동일한 과정을 수행하여 목적 화합물 14.3g을 얻었다.; HRMS [M]+: 731.24Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 395] was performed to obtain 14.3 g of the target compound; HRMS [M]+: 731.24

[합성예 495] Mat 495의 합성[Synthesis Example 495] Synthesis of Mat 495

Figure pat00589
Figure pat00589

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 396]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 717.26Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 396] was performed to obtain 16.4 g of the target compound; HRMS [M]+: 717.26

[합성예 496] Mat 496의 합성[Synthesis Example 496] Synthesis of Mat 496

Figure pat00590
Figure pat00590

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 397]과 동일한 과정을 수행하여 목적 화합물 12.7g을 얻었다.; HRMS [M]+: 869.32Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 397] was performed to obtain 12.7 g of the target compound; HRMS [M]+: 869.32

[합성예 497] Mat 497의 합성[Synthesis Example 497] Synthesis of Mat 497

Figure pat00591
Figure pat00591

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 398]과 동일한 과정을 수행하여 목적 화합물 13.3g을 얻었다.; HRMS [M]+: 869.32Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 398] was performed to obtain 13.3 g of the target compound; HRMS [M]+: 869.32

[합성예 498] Mat 498의 합성[Synthesis Example 498] Synthesis of Mat 498

Figure pat00592
Figure pat00592

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 399]과 동일한 과정을 수행하여 목적 화합물 15.6g을 얻었다.; HRMS [M]+: 793.29Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 399] was performed to obtain 15.6 g of the target compound; HRMS [M]+: 793.29

[합성예 499] Mat 499의 합성[Synthesis Example 499] Synthesis of Mat 499

Figure pat00593
Figure pat00593

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 400]과 동일한 과정을 수행하여 목적 화합물 14.8g을 얻었다.; HRMS [M]+: 807.27Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 400] was performed to obtain 14.8 g of the target compound; HRMS [M]+: 807.27

[합성예 500] Mat 500의 합성[Synthesis Example 500] Synthesis of Mat 500

Figure pat00594
Figure pat00594

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 401]과 동일한 과정을 수행하여 목적 화합물 13.7g을 얻었다.; HRMS [M]+: 538.19Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 401] was performed to obtain 13.7 g of the target compound; HRMS [M]+: 538.19

[합성예 501] Mat 501의 합성[Synthesis Example 501] Synthesis of Mat 501

Figure pat00595
Figure pat00595

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 402]과 동일한 과정을 수행하여 목적 화합물 14.6g을 얻었다.; HRMS [M]+: 614.22Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 402] was performed to obtain 14.6 g of the target compound; HRMS [M]+: 614.22

[합성예 502] Mat 502의 합성[Synthesis Example 502] Synthesis of Mat 502

Figure pat00596
Figure pat00596

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 403]과 동일한 과정을 수행하여 목적 화합물 15.1g을 얻었다.; HRMS [M]+: 368.09Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 403] was performed to obtain 15.1 g of the target compound; HRMS [M]+: 368.09

[합성예 503] Mat 503의 합성[Synthesis Example 503] Synthesis of Mat 503

Figure pat00597
Figure pat00597

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 404]과 동일한 과정을 수행하여 목적 화합물 14.5g을 얻었다.; HRMS [M]+: 588.20Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 404] was performed to obtain 14.5 g of the target compound; HRMS [M]+: 588.20

[합성예 504] Mat 504의 합성[Synthesis Example 504] Synthesis of Mat 504

Figure pat00598
Figure pat00598

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 405]과 동일한 과정을 수행하여 목적 화합물 13.5g을 얻었다.; HRMS [M]+: 538.19Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 405] was performed to obtain 13.5 g of the target compound; HRMS [M]+: 538.19

[합성예 505] Mat 505의 합성[Synthesis Example 505] Synthesis of Mat 505

Figure pat00599
Figure pat00599

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 373]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 580.18Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 373] was performed to obtain 16.4 g of the target compound; HRMS [M]+: 580.18

[합성예 506] Mat 506의 합성[Synthesis Example 506] Synthesis of Mat 506

Figure pat00600
Figure pat00600

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 374]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 732.24Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 374] was performed to obtain 16.4 g of the target compound; HRMS [M]+: 732.24

[합성예 507] Mat 507의 합성[Synthesis Example 507] Synthesis of Mat 507

Figure pat00601
Figure pat00601

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 375]과 동일한 과정을 수행하여 목적 화합물 15.8g을 얻었다.; HRMS [M]+: 732.24Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 375] was performed to obtain 15.8 g of the target compound; HRMS [M]+: 732.24

[합성예 508] Mat 508의 합성[Synthesis Example 508] Synthesis of Mat 508

Figure pat00602
Figure pat00602

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 376]과 동일한 과정을 수행하여 목적 화합물 14.1g을 얻었다.; HRMS [M]+: 656.21Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 376] was performed to obtain 14.1 g of the target compound; HRMS [M]+: 656.21

[합성예 509] Mat 509의 합성[Synthesis Example 509] Synthesis of Mat 509

Figure pat00603
Figure pat00603

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 377]과 동일한 과정을 수행하여 목적 화합물 14.3g을 얻었다.; HRMS [M]+: 670.19Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 377] was performed to obtain 14.3 g of the target compound; HRMS [M]+: 670.19

[합성예 510] Mat 510의 합성[Synthesis Example 510] Synthesis of Mat 510

Figure pat00604
Figure pat00604

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 378]과 동일한 과정을 수행하여 목적 화합물 12.1g을 얻었다.; HRMS [M]+: 580.18Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 378] was performed to obtain 12.1 g of the target compound; HRMS [M]+: 580.18

[합성예 511] Mat 511의 합성[Synthesis Example 511] Synthesis of Mat 511

Figure pat00605
Figure pat00605

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 379]과 동일한 과정을 수행하여 목적 화합물 13.9g을 얻었다.; HRMS [M]+: 732.24Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 379] was performed to obtain 13.9 g of the target compound; HRMS [M]+: 732.24

[합성예 512] Mat 512의 합성[Synthesis Example 512] Synthesis of Mat 512

Figure pat00606
Figure pat00606

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 380]과 동일한 과정을 수행하여 목적 화합물 14.8g을 얻었다.; HRMS [M]+: 656.21Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 380] was performed to obtain 14.8 g of the target compound; HRMS [M]+: 656.21

[합성예 513] Mat 513의 합성[Synthesis Example 513] Synthesis of Mat 513

Figure pat00607
Figure pat00607

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 381]과 동일한 과정을 수행하여 목적 화합물 13.5g을 얻었다.; HRMS [M]+: 670.1913.5 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 381] except that [Preparation Example 5] was used as a reactant; HRMS [M]+: 670.19

[합성예 514] Mat 514의 합성[Synthesis Example 514] Synthesis of Mat 514

Figure pat00608
Figure pat00608

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 382]과 동일한 과정을 수행하여 목적 화합물 12.7g을 얻었다.; HRMS [M]+: 732.24Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 382] was performed to obtain 12.7 g of the target compound; HRMS [M]+: 732.24

[합성예 515] Mat 515의 합성[Synthesis Example 515] Synthesis of Mat 515

Figure pat00609
Figure pat00609

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 383]과 동일한 과정을 수행하여 목적 화합물 15.6g을 얻었다.; HRMS [M]+: 656.21Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 383] was performed to obtain 15.6 g of the target compound; HRMS [M]+: 656.21

[합성예 516] Mat 516의 합성[Synthesis Example 516] Synthesis of Mat 516

Figure pat00610
Figure pat00610

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 384]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 808.27Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 384] was performed to obtain 16.4 g of the target compound; HRMS [M]+: 808.27

[합성예 517] Mat 517의 합성[Synthesis Example 517] Synthesis of Mat 517

Figure pat00611
Figure pat00611

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 385]과 동일한 과정을 수행하여 목적 화합물 15.9g을 얻었다.; HRMS [M]+: 732.24Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 385] was performed to obtain 15.9 g of the target compound; HRMS [M]+: 732.24

[합성예 518] Mat 518의 합성[Synthesis Example 518] Synthesis of Mat 518

Figure pat00612
Figure pat00612

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 386]과 동일한 과정을 수행하여 목적 화합물 16.6g을 얻었다.; HRMS [M]+: 746.22Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 386] was performed to obtain 16.6 g of the target compound; HRMS [M]+: 746.22

[합성예 519] Mat 519의 합성[Synthesis Example 519] Synthesis of Mat 519

Figure pat00613
Figure pat00613

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 387]과 동일한 과정을 수행하여 목적 화합물 14.2g을 얻었다.; HRMS [M]+: 657.21Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 387] was performed to obtain 14.2 g of the target compound; HRMS [M]+: 657.21

[합성예 520] Mat 520의 합성[Synthesis Example 520] Synthesis of Mat 520

Figure pat00614
Figure pat00614

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 388]과 동일한 과정을 수행하여 목적 화합물 16.3g을 얻었다.; HRMS [M]+: 809.27Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 388] was performed to obtain 16.3 g of the target compound; HRMS [M]+: 809.27

[합성예 521] Mat 521의 합성[Synthesis Example 521] Synthesis of Mat 521

Figure pat00615
Figure pat00615

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 389]과 동일한 과정을 수행하여 목적 화합물 15.3g을 얻었다.; HRMS [M]+: 733.24Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 389] was performed to obtain 15.3 g of the target compound; HRMS [M]+: 733.24

[합성예 522] Mat 522의 합성[Synthesis Example 522] Synthesis of Mat 522

Figure pat00616
Figure pat00616

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 390]과 동일한 과정을 수행하여 목적 화합물 14.7g을 얻었다.; HRMS [M]+: 747.22Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 390] was performed to obtain 14.7 g of the target compound; HRMS [M]+: 747.22

[합성예 523] Mat 523의 합성[Synthesis Example 523] Synthesis of Mat 523

Figure pat00617
Figure pat00617

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 391]과 동일한 과정을 수행하여 목적 화합물 12.1g을 얻었다.; HRMS [M]+: 657.21Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 391] was performed to obtain 12.1 g of the target compound; HRMS [M]+: 657.21

[합성예 524] Mat 524의 합성[Synthesis Example 524] Synthesis of Mat 524

Figure pat00618
Figure pat00618

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 392]과 동일한 과정을 수행하여 목적 화합물 13.9g을 얻었다.; HRMS [M]+: 809.27Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 392] was performed to obtain 13.9 g of the target compound; HRMS [M]+: 809.27

[합성예 525] Mat 525의 합성[Synthesis Example 525] Synthesis of Mat 525

Figure pat00619
Figure pat00619

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 393]과 동일한 과정을 수행하여 목적 화합물 14.8g을 얻었다.; HRMS [M]+: 809.27Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 393] was performed to obtain 14.8 g of the target compound; HRMS [M]+: 809.27

[합성예 526] Mat 526의 합성[Synthesis Example 526] Synthesis of Mat 526

Figure pat00620
Figure pat00620

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 394]과 동일한 과정을 수행하여 목적 화합물 13.8g을 얻었다.; HRMS [M]+: 733.24Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 394] was performed to obtain 13.8 g of the target compound; HRMS [M]+: 733.24

[합성예 527] Mat 527의 합성[Synthesis Example 527] Synthesis of Mat 527

Figure pat00621
Figure pat00621

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 395]과 동일한 과정을 수행하여 목적 화합물 14.3g을 얻었다.; HRMS [M]+: 747.22Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 395] was performed to obtain 14.3 g of the target compound; HRMS [M]+: 747.22

[합성예 528] Mat 528의 합성[Synthesis Example 528] Synthesis of Mat 528

Figure pat00622
Figure pat00622

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 396]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 733.24Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 396] was performed to obtain 16.4 g of the target compound; HRMS [M]+: 733.24

[합성예 529] Mat 529의 합성[Synthesis Example 529] Synthesis of Mat 529

Figure pat00623
Figure pat00623

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 397]과 동일한 과정을 수행하여 목적 화합물 12.7g을 얻었다.; HRMS [M]+: 885.30Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 397] was performed to obtain 12.7 g of the target compound; HRMS [M]+: 885.30

[합성예 530] Mat 530의 합성[Synthesis Example 530] Synthesis of Mat 530

Figure pat00624
Figure pat00624

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 398]과 동일한 과정을 수행하여 목적 화합물 13.3g을 얻었다.; HRMS [M]+: 885.30Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 398] was performed to obtain 13.3 g of the target compound; HRMS [M]+: 885.30

[합성예 531] Mat 531의 합성[Synthesis Example 531] Synthesis of Mat 531

Figure pat00625
Figure pat00625

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 399]과 동일한 과정을 수행하여 목적 화합물 15.6g을 얻었다.; HRMS [M]+: 809.27Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 399] was performed to obtain 15.6 g of the target compound; HRMS [M]+: 809.27

[합성예 532] Mat 532의 합성[Synthesis Example 532] Synthesis of Mat 532

Figure pat00626
Figure pat00626

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 400]과 동일한 과정을 수행하여 목적 화합물 14.8g을 얻었다.; HRMS [M]+: 823.25Except for using [Preparation Example 5] as a reactant, 14.8 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 400]; HRMS [M]+: 823.25

[합성예 533] Mat 533의 합성[Synthesis Example 533] Synthesis of Mat 533

Figure pat00627
Figure pat00627

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 401]과 동일한 과정을 수행하여 목적 화합물 13.7g을 얻었다.; HRMS [M]+: 554.16Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 401] was performed to obtain 13.7 g of the target compound; HRMS [M]+: 554.16

[합성예 534] Mat 534의 합성[Synthesis Example 534] Synthesis of Mat 534

Figure pat00628
Figure pat00628

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 402]과 동일한 과정을 수행하여 목적 화합물 14.6g을 얻었다.; HRMS [M]+: 630.20Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 402] was performed to obtain 14.6 g of the target compound; HRMS [M]+: 630.20

[합성예 535] Mat 535의 합성[Synthesis Example 535] Synthesis of Mat 535

Figure pat00629
Figure pat00629

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 403]과 동일한 과정을 수행하여 목적 화합물 15.1g을 얻었다.; HRMS [M]+: 680.21Except for using [Preparation Example 5] as a reactant, 15.1 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 403]; HRMS [M]+: 680.21

[합성예 536] Mat 536의 합성[Synthesis Example 536] Synthesis of Mat 536

Figure pat00630
Figure pat00630

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 404]과 동일한 과정을 수행하여 목적 화합물 14.5g을 얻었다.; HRMS [M]+: 604.18Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 404] was performed to obtain 14.5 g of the target compound; HRMS [M]+: 604.18

[합성예 537] Mat 537의 합성[Synthesis Example 537] Synthesis of Mat 537

Figure pat00631
Figure pat00631

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 405]과 동일한 과정을 수행하여 목적 화합물 13.5g을 얻었다.; HRMS [M]+: 554.16Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 405] was performed to obtain 13.5 g of the target compound; HRMS [M]+: 554.16

[합성예 538] Mat 538의 합성[Synthesis Example 538] Synthesis of Mat 538

Figure pat00632
Figure pat00632

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 406]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 580.18Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 406] was performed to obtain 16.4 g of the target compound; HRMS [M]+: 580.18

[합성예 539] Mat 539의 합성[Synthesis Example 539] Synthesis of Mat 539

Figure pat00633
Figure pat00633

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 407]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 732.24Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 407] was performed to obtain 16.4 g of the target compound; HRMS [M]+: 732.24

[합성예 540] Mat 540의 합성[Synthesis Example 540] Synthesis of Mat 540

Figure pat00634
Figure pat00634

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 408]과 동일한 과정을 수행하여 목적 화합물 15.8g을 얻었다.; HRMS [M]+: 732.24Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 408] was performed to obtain 15.8 g of the target compound; HRMS [M]+: 732.24

[합성예 541] Mat 541의 합성[Synthesis Example 541] Synthesis of Mat 541

Figure pat00635
Figure pat00635

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 409]과 동일한 과정을 수행하여 목적 화합물 14.1g을 얻었다.; HRMS [M]+: 656.21Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 409] was performed to obtain 14.1 g of the target compound; HRMS [M]+: 656.21

[합성예 542] Mat 542의 합성[Synthesis Example 542] Synthesis of Mat 542

Figure pat00636
Figure pat00636

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 410]과 동일한 과정을 수행하여 목적 화합물 14.3g을 얻었다.; HRMS [M]+: 670.19Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 410] was performed to obtain 14.3 g of the target compound; HRMS [M]+: 670.19

[합성예 543] Mat 543의 합성[Synthesis Example 543] Synthesis of Mat 543

Figure pat00637
Figure pat00637

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 411]과 동일한 과정을 수행하여 목적 화합물 12.1g을 얻었다.; HRMS [M]+: 580.18Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 411] was performed to obtain 12.1 g of the target compound; HRMS [M]+: 580.18

[합성예 544] Mat 544의 합성[Synthesis Example 544] Synthesis of Mat 544

Figure pat00638
Figure pat00638

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 412]과 동일한 과정을 수행하여 목적 화합물 13.9g을 얻었다.; HRMS [M]+: 732.24Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 412] was performed to obtain 13.9 g of the target compound; HRMS [M]+: 732.24

[합성예 545] Mat 545의 합성[Synthesis Example 545] Synthesis of Mat 545

Figure pat00639
Figure pat00639

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 413]과 동일한 과정을 수행하여 목적 화합물 14.8g을 얻었다.; HRMS [M]+: 656.21Except for using [Preparation Example 6] as a reactant, 14.8 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 413]; HRMS [M]+: 656.21

[합성예 546] Mat 546의 합성[Synthesis Example 546] Synthesis of Mat 546

Figure pat00640
Figure pat00640

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 414]과 동일한 과정을 수행하여 목적 화합물 13.5g을 얻었다.; HRMS [M]+: 670.19Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 414] was performed to obtain 13.5 g of the target compound; HRMS [M]+: 670.19

[합성예 547] Mat 547의 합성[Synthesis Example 547] Synthesis of Mat 547

Figure pat00641
Figure pat00641

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 415]과 동일한 과정을 수행하여 목적 화합물 12.7g을 얻었다.; HRMS [M]+: 732.24Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 415] was performed to obtain 12.7 g of the target compound; HRMS [M]+: 732.24

[합성예 548] Mat 548의 합성[Synthesis Example 548] Synthesis of Mat 548

Figure pat00642
Figure pat00642

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 416]과 동일한 과정을 수행하여 목적 화합물 15.6g을 얻었다.; HRMS [M]+: 656.2115.6 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 416], except that [Preparation Example 6] was used as a reactant; HRMS [M]+: 656.21

[합성예 549] Mat 549의 합성[Synthesis Example 549] Synthesis of Mat 549

Figure pat00643
Figure pat00643

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 417]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 808.27Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 417] was performed to obtain 16.4 g of the target compound; HRMS [M]+: 808.27

[합성예 550] Mat 550의 합성[Synthesis Example 550] Synthesis of Mat 550

Figure pat00644
Figure pat00644

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 418]과 동일한 과정을 수행하여 목적 화합물 15.9g을 얻었다.; HRMS [M]+: 732.24Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 418] was performed to obtain 15.9 g of the target compound; HRMS [M]+: 732.24

[합성예 551] Mat 551의 합성[Synthesis Example 551] Synthesis of Mat 551

Figure pat00645
Figure pat00645

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 419]과 동일한 과정을 수행하여 목적 화합물 16.6g을 얻었다.; HRMS [M]+: 746.22Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 419] was performed to obtain 16.6 g of the target compound; HRMS [M]+: 746.22

[합성예 552] Mat 552의 합성[Synthesis Example 552] Synthesis of Mat 552

Figure pat00646
Figure pat00646

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 420]과 동일한 과정을 수행하여 목적 화합물 14.2g을 얻었다.; HRMS [M]+: 657.21Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 420] was performed to obtain 14.2 g of the target compound; HRMS [M]+: 657.21

[합성예 553] Mat 553의 합성[Synthesis Example 553] Synthesis of Mat 553

Figure pat00647
Figure pat00647

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 421]과 동일한 과정을 수행하여 목적 화합물 16.3g을 얻었다.; HRMS [M]+: 809.27Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 421] was performed to obtain 16.3 g of the target compound; HRMS [M]+: 809.27

[합성예 554] Mat 554의 합성[Synthesis Example 554] Synthesis of Mat 554

Figure pat00648
Figure pat00648

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 422]과 동일한 과정을 수행하여 목적 화합물 15.3g을 얻었다.; HRMS [M]+: 733.24Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 422] was performed to obtain 15.3 g of the target compound; HRMS [M]+: 733.24

[합성예 555] Mat 555의 합성[Synthesis Example 555] Synthesis of Mat 555

Figure pat00649
Figure pat00649

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 423]과 동일한 과정을 수행하여 목적 화합물 14.7g을 얻었다.; HRMS [M]+: 747.22Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 423] was performed to obtain 14.7 g of the target compound; HRMS [M]+: 747.22

[합성예 556] Mat 556의 합성[Synthesis Example 556] Synthesis of Mat 556

Figure pat00650
Figure pat00650

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 424]과 동일한 과정을 수행하여 목적 화합물 12.1g을 얻었다.; HRMS [M]+: 657.21Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 424] was performed to obtain 12.1 g of the target compound; HRMS [M]+: 657.21

[합성예 557] Mat 557의 합성[Synthesis Example 557] Synthesis of Mat 557

Figure pat00651
Figure pat00651

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 425]과 동일한 과정을 수행하여 목적 화합물 13.9g을 얻었다.; HRMS [M]+: 809.27Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 425] was performed to obtain 13.9 g of the target compound; HRMS [M]+: 809.27

[합성예 558] Mat 558의 합성[Synthesis Example 558] Synthesis of Mat 558

Figure pat00652
Figure pat00652

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 426]과 동일한 과정을 수행하여 목적 화합물 14.8g을 얻었다.; HRMS [M]+: 809.27Except for using [Preparation Example 6] as a reactant, 14.8 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 426]; HRMS [M]+: 809.27

[합성예 559] Mat 559의 합성[Synthesis Example 559] Synthesis of Mat 559

Figure pat00653
Figure pat00653

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 427]과 동일한 과정을 수행하여 목적 화합물 13.8g을 얻었다.; HRMS [M]+: 733.24Except for using [Preparation Example 6] as a reactant, 13.8 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 427]; HRMS [M]+: 733.24

[합성예 560] Mat 560의 합성[Synthesis Example 560] Synthesis of Mat 560

Figure pat00654
Figure pat00654

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 428]과 동일한 과정을 수행하여 목적 화합물 14.3g을 얻었다.; HRMS [M]+: 747.22Except for using [Preparation Example 6] as a reactant, 14.3 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 428]; HRMS [M]+: 747.22

[합성예 561] Mat 561의 합성[Synthesis Example 561] Synthesis of Mat 561

Figure pat00655
Figure pat00655

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 429]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 733.24Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 429] was performed to obtain 16.4 g of the target compound; HRMS [M]+: 733.24

[합성예 562] Mat 562의 합성[Synthesis Example 562] Synthesis of Mat 562

Figure pat00656
Figure pat00656

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 430]과 동일한 과정을 수행하여 목적 화합물 12.7g을 얻었다.; HRMS [M]+: 885.30Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 430] was performed to obtain 12.7 g of the target compound; HRMS [M]+: 885.30

[합성예 563] Mat 563의 합성[Synthesis Example 563] Synthesis of Mat 563

Figure pat00657
Figure pat00657

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 431]과 동일한 과정을 수행하여 목적 화합물 13.3g을 얻었다.; HRMS [M]+: 885.30Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 431] was performed to obtain 13.3 g of the target compound; HRMS [M]+: 885.30

[합성예 564] Mat 564의 합성[Synthesis Example 564] Synthesis of Mat 564

Figure pat00658
Figure pat00658

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 432]과 동일한 과정을 수행하여 목적 화합물 15.6g을 얻었다.; HRMS [M]+: 809.27Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 432] was performed to obtain 15.6 g of the target compound; HRMS [M]+: 809.27

[합성예 565] Mat 565의 합성[Synthesis Example 565] Synthesis of Mat 565

Figure pat00659
Figure pat00659

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 433]과 동일한 과정을 수행하여 목적 화합물 14.8g을 얻었다.; HRMS [M]+: 823.25Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 433] was performed to obtain 14.8 g of the target compound; HRMS [M]+: 823.25

[합성예 566] Mat 566의 합성[Synthesis Example 566] Synthesis of Mat 566

Figure pat00660
Figure pat00660

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 434]과 동일한 과정을 수행하여 목적 화합물 13.7g을 얻었다.; HRMS [M]+: 554.16Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 434] was performed to obtain 13.7 g of the target compound; HRMS [M]+: 554.16

[합성예 567] Mat 567의 합성[Synthesis Example 567] Synthesis of Mat 567

Figure pat00661
Figure pat00661

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 435]과 동일한 과정을 수행하여 목적 화합물 14.6g을 얻었다.; HRMS [M]+: 630.20Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 435] was performed to obtain 14.6 g of the target compound; HRMS [M]+: 630.20

[합성예 568] Mat 568의 합성[Synthesis Example 568] Synthesis of Mat 568

Figure pat00662
Figure pat00662

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 436]과 동일한 과정을 수행하여 목적 화합물 15.1g을 얻었다.; HRMS [M]+: 680.21Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 436] was performed to obtain 15.1 g of the target compound; HRMS [M]+: 680.21

[합성예 569] Mat 569의 합성[Synthesis Example 569] Synthesis of Mat 569

Figure pat00663
Figure pat00663

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 437]과 동일한 과정을 수행하여 목적 화합물 14.5g을 얻었다.; HRMS [M]+: 604.18Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 437] was performed to obtain 14.5 g of the target compound; HRMS [M]+: 604.18

[합성예 570] Mat 570의 합성[Synthesis Example 570] Synthesis of Mat 570

Figure pat00664
Figure pat00664

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 438]과 동일한 과정을 수행하여 목적 화합물 13.5g을 얻었다.; HRMS [M]+: 554.16Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 438] was performed to obtain 13.5 g of the target compound; HRMS [M]+: 554.16

[합성예 571] Mat 571의 합성[Synthesis Example 571] Synthesis of Mat 571

Figure pat00665
Figure pat00665

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 439]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 580.18Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 439] was performed to obtain 16.4 g of the target compound; HRMS [M]+: 580.18

[합성예 572] Mat 572의 합성[Synthesis Example 572] Synthesis of Mat 572

Figure pat00666
Figure pat00666

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 440]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 732.24Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 440] was performed to obtain 16.4 g of the target compound; HRMS [M]+: 732.24

[합성예 573] Mat 573의 합성[Synthesis Example 573] Synthesis of Mat 573

Figure pat00667
Figure pat00667

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 441]과 동일한 과정을 수행하여 목적 화합물 15.8g을 얻었다.; HRMS [M]+: 732.24Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 441] was performed to obtain 15.8 g of the target compound; HRMS [M]+: 732.24

[합성예 574] Mat 574의 합성[Synthesis Example 574] Synthesis of Mat 574

Figure pat00668
Figure pat00668

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 442]과 동일한 과정을 수행하여 목적 화합물 14.1g을 얻었다.; HRMS [M]+: 656.21Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 442] was performed to obtain 14.1 g of the target compound; HRMS [M]+: 656.21

[합성예 575] Mat 575의 합성[Synthesis Example 575] Synthesis of Mat 575

Figure pat00669
Figure pat00669

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 443]과 동일한 과정을 수행하여 목적 화합물 14.3g을 얻었다.; HRMS [M]+: 670.19Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 443] was performed to obtain 14.3 g of the target compound; HRMS [M]+: 670.19

[합성예 576] Mat 576의 합성[Synthesis Example 576] Synthesis of Mat 576

Figure pat00670
Figure pat00670

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 444]과 동일한 과정을 수행하여 목적 화합물 12.1g을 얻었다.; HRMS [M]+: 580.18Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 444] was performed to obtain 12.1 g of the target compound; HRMS [M]+: 580.18

[합성예 577] Mat 577의 합성[Synthesis Example 577] Synthesis of Mat 577

Figure pat00671
Figure pat00671

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 445]과 동일한 과정을 수행하여 목적 화합물 13.9g을 얻었다.; HRMS [M]+: 732.24Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 445] was performed to obtain 13.9 g of the target compound; HRMS [M]+: 732.24

[합성예 578] Mat 578의 합성[Synthesis Example 578] Synthesis of Mat 578

Figure pat00672
Figure pat00672

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 446]과 동일한 과정을 수행하여 목적 화합물 14.8g을 얻었다.; HRMS [M]+: 656.21Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 446] was performed to obtain 14.8 g of the target compound; HRMS [M]+: 656.21

[합성예 579] Mat 579의 합성[Synthesis Example 579] Synthesis of Mat 579

Figure pat00673
Figure pat00673

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 447]과 동일한 과정을 수행하여 목적 화합물 13.5g을 얻었다.; HRMS [M]+: 670.19Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 447] was performed to obtain 13.5 g of the target compound; HRMS [M]+: 670.19

[합성예 580] Mat 580의 합성[Synthesis Example 580] Synthesis of Mat 580

Figure pat00674
Figure pat00674

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 448]과 동일한 과정을 수행하여 목적 화합물 12.7g을 얻었다.; HRMS [M]+: 732.24Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 448] was performed to obtain 12.7 g of the target compound; HRMS [M]+: 732.24

[합성예 581] Mat 581의 합성[Synthesis Example 581] Synthesis of Mat 581

Figure pat00675
Figure pat00675

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 449]과 동일한 과정을 수행하여 목적 화합물 15.6g을 얻었다.; HRMS [M]+: 656.21Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 449] was performed to obtain 15.6 g of the target compound; HRMS [M]+: 656.21

[합성예 582] Mat 582의 합성[Synthesis Example 582] Synthesis of Mat 582

Figure pat00676
Figure pat00676

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 450]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 808.27Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 450] was performed to obtain 16.4 g of the target compound; HRMS [M]+: 808.27

[합성예 583] Mat 583의 합성[Synthesis Example 583] Synthesis of Mat 583

Figure pat00677
Figure pat00677

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 451]과 동일한 과정을 수행하여 목적 화합물 15.9g을 얻었다.; HRMS [M]+: 732.24Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 451] was performed to obtain 15.9 g of the target compound; HRMS [M]+: 732.24

[합성예 584] Mat 584의 합성[Synthesis Example 584] Synthesis of Mat 584

Figure pat00678
Figure pat00678

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 452]과 동일한 과정을 수행하여 목적 화합물 16.6g을 얻었다.; HRMS [M]+: 746.22Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 452] was performed to obtain 16.6 g of the target compound; HRMS [M]+: 746.22

[합성예 585] Mat 585의 합성[Synthesis Example 585] Synthesis of Mat 585

Figure pat00679
Figure pat00679

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 453]과 동일한 과정을 수행하여 목적 화합물 14.2g을 얻었다.; HRMS [M]+: 657.21Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 453] was performed to obtain 14.2 g of the target compound; HRMS [M]+: 657.21

[합성예 586] Mat 586의 합성[Synthesis Example 586] Synthesis of Mat 586

Figure pat00680
Figure pat00680

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 454]과 동일한 과정을 수행하여 목적 화합물 16.3g을 얻었다.; HRMS [M]+: 809.27Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 454] was performed to obtain 16.3 g of the target compound; HRMS [M]+: 809.27

[합성예 587] Mat 587의 합성[Synthesis Example 587] Synthesis of Mat 587

Figure pat00681
Figure pat00681

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 455]과 동일한 과정을 수행하여 목적 화합물 15.3g을 얻었다.; HRMS [M]+: 733.24Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 455] was performed to obtain 15.3 g of the target compound; HRMS [M]+: 733.24

[합성예 588] Mat 588의 합성[Synthesis Example 588] Synthesis of Mat 588

Figure pat00682
Figure pat00682

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 456]과 동일한 과정을 수행하여 목적 화합물 14.7g을 얻었다.; HRMS [M]+: 747.22Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 456] was performed to obtain 14.7 g of the target compound; HRMS [M]+: 747.22

[합성예 589] Mat 589의 합성[Synthesis Example 589] Synthesis of Mat 589

Figure pat00683
Figure pat00683

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 457]과 동일한 과정을 수행하여 목적 화합물 12.1g을 얻었다.; HRMS [M]+: 657.21Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 457] was performed to obtain 12.1 g of the target compound; HRMS [M]+: 657.21

[합성예 590] Mat 590의 합성[Synthesis Example 590] Synthesis of Mat 590

Figure pat00684
Figure pat00684

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 458]과 동일한 과정을 수행하여 목적 화합물 13.9g을 얻었다.; HRMS [M]+: 809.27Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 458] was performed to obtain 13.9 g of the target compound; HRMS [M]+: 809.27

[합성예 591] Mat 591의 합성[Synthesis Example 591] Synthesis of Mat 591

Figure pat00685
Figure pat00685

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 459]과 동일한 과정을 수행하여 목적 화합물 14.8g을 얻었다.; HRMS [M]+: 809.27Except for using [Preparation Example 7] as a reactant, 14.8 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 459]; HRMS [M]+: 809.27

[합성예 592] Mat 592의 합성[Synthesis Example 592] Synthesis of Mat 592

Figure pat00686
Figure pat00686

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 460]과 동일한 과정을 수행하여 목적 화합물 13.8g을 얻었다.; HRMS [M]+: 733.24Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 460] was performed to obtain 13.8 g of the target compound; HRMS [M]+: 733.24

[합성예 593] Mat 593의 합성[Synthesis Example 593] Synthesis of Mat 593

Figure pat00687
Figure pat00687

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 461]과 동일한 과정을 수행하여 목적 화합물 14.3g을 얻었다.; HRMS [M]+: 747.22Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 461] was performed to obtain 14.3 g of the target compound; HRMS [M]+: 747.22

[합성예 594] Mat 594의 합성[Synthesis Example 594] Synthesis of Mat 594

Figure pat00688
Figure pat00688

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 462]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 733.24Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 462] was performed to obtain 16.4 g of the target compound; HRMS [M]+: 733.24

[합성예 595] Mat 595의 합성[Synthesis Example 595] Synthesis of Mat 595

Figure pat00689
Figure pat00689

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 463]과 동일한 과정을 수행하여 목적 화합물 12.7g을 얻었다.; HRMS [M]+: 885.30Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 463] was performed to obtain 12.7 g of the target compound; HRMS [M]+: 885.30

[합성예 596] Mat 596의 합성[Synthesis Example 596] Synthesis of Mat 596

Figure pat00690
Figure pat00690

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 464]과 동일한 과정을 수행하여 목적 화합물 13.3g을 얻었다.; HRMS [M]+: 885.30Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 464] was performed to obtain 13.3 g of the target compound; HRMS [M]+: 885.30

[합성예 597] Mat 597의 합성[Synthesis Example 597] Synthesis of Mat 597

Figure pat00691
Figure pat00691

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 465]과 동일한 과정을 수행하여 목적 화합물 15.6g을 얻었다.; HRMS [M]+: 809.27Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 465] was performed to obtain 15.6 g of the target compound; HRMS [M]+: 809.27

[합성예 598] Mat 598의 합성[Synthesis Example 598] Synthesis of Mat 598

Figure pat00692
Figure pat00692

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 466]과 동일한 과정을 수행하여 목적 화합물 14.8g을 얻었다.; HRMS [M]+: 823.25Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 466] was performed to obtain 14.8 g of the target compound; HRMS [M]+: 823.25

[합성예 599] Mat 599의 합성[Synthesis Example 599] Synthesis of Mat 599

Figure pat00693
Figure pat00693

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 467]과 동일한 과정을 수행하여 목적 화합물 13.7g을 얻었다.; HRMS [M]+: 554.16Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 467] was performed to obtain 13.7 g of the target compound; HRMS [M]+: 554.16

[합성예 600] Mat 600의 합성[Synthesis Example 600] Synthesis of Mat 600

Figure pat00694
Figure pat00694

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 468]과 동일한 과정을 수행하여 목적 화합물 14.6g을 얻었다.; HRMS [M]+: 630.20Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 468] was performed to obtain 14.6 g of the target compound; HRMS [M]+: 630.20

[합성예 601] Mat 601의 합성[Synthesis Example 601] Synthesis of Mat 601

Figure pat00695
Figure pat00695

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 469]과 동일한 과정을 수행하여 목적 화합물 15.1g을 얻었다.; HRMS [M]+: 680.21Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 469] was performed to obtain 15.1 g of the target compound; HRMS [M]+: 680.21

[합성예 602] Mat 602의 합성[Synthesis Example 602] Synthesis of Mat 602

Figure pat00696
Figure pat00696

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 470]과 동일한 과정을 수행하여 목적 화합물 14.5g을 얻었다.; HRMS [M]+: 604.18Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 470] was performed to obtain 14.5 g of the target compound; HRMS [M]+: 604.18

[합성예 603] Mat 603의 합성[Synthesis Example 603] Synthesis of Mat 603

Figure pat00697
Figure pat00697

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 471]과 동일한 과정을 수행하여 목적 화합물 13.5g을 얻었다.; HRMS [M]+: 554.16Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 471] was performed to obtain 13.5 g of the target compound; HRMS [M]+: 554.16

[합성예 604] Mat 604의 합성[Synthesis Example 604] Synthesis of Mat 604

Figure pat00698
Figure pat00698

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 472]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 580.18Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 472] was performed to obtain 16.4 g of the target compound; HRMS [M]+: 580.18

[합성예 605] Mat 605의 합성[Synthesis Example 605] Synthesis of Mat 605

Figure pat00699
Figure pat00699

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 473]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 732.24Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 473] was performed to obtain 16.4 g of the target compound; HRMS [M]+: 732.24

[합성예 606] Mat 606의 합성[Synthesis Example 606] Synthesis of Mat 606

Figure pat00700
Figure pat00700

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 474]과 동일한 과정을 수행하여 목적 화합물 15.8g을 얻었다.; HRMS [M]+: 732.24Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 474] was performed to obtain 15.8 g of the target compound; HRMS [M]+: 732.24

[합성예 607] Mat607의 합성[Synthesis Example 607] Synthesis of Mat607

Figure pat00701
Figure pat00701

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 475]과 동일한 과정을 수행하여 목적 화합물 14.1g을 얻었다.; HRMS [M]+: 656.21Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 475] was performed to obtain 14.1 g of the target compound; HRMS [M]+: 656.21

[합성예 608] Mat 608의 합성[Synthesis Example 608] Synthesis of Mat 608

Figure pat00702
Figure pat00702

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 476]과 동일한 과정을 수행하여 목적 화합물 14.3g을 얻었다.; HRMS [M]+: 670.19Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 476] was performed to obtain 14.3 g of the target compound; HRMS [M]+: 670.19

[합성예 609] Mat 609의 합성[Synthesis Example 609] Synthesis of Mat 609

Figure pat00703
Figure pat00703

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 477]과 동일한 과정을 수행하여 목적 화합물 12.1g을 얻었다.; HRMS [M]+: 580.18Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 477] was performed to obtain 12.1 g of the target compound; HRMS [M]+: 580.18

[합성예 610] Mat 610의 합성[Synthesis Example 610] Synthesis of Mat 610

Figure pat00704
Figure pat00704

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 478]과 동일한 과정을 수행하여 목적 화합물 13.9g을 얻었다.; HRMS [M]+: 732.24Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 478] was performed to obtain 13.9 g of the target compound; HRMS [M]+: 732.24

[합성예 611] Mat 611의 합성[Synthesis Example 611] Synthesis of Mat 611

Figure pat00705
Figure pat00705

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 479]과 동일한 과정을 수행하여 목적 화합물 14.8g을 얻었다.; HRMS [M]+: 656.21Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 479] was performed to obtain 14.8 g of the target compound; HRMS [M]+: 656.21

[합성예 612] Mat 612의 합성[Synthesis Example 612] Synthesis of Mat 612

Figure pat00706
Figure pat00706

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 480]과 동일한 과정을 수행하여 목적 화합물 13.5g을 얻었다.; HRMS [M]+: 670.19Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 480] was performed to obtain 13.5 g of the target compound; HRMS [M]+: 670.19

[합성예 613] Mat 613의 합성[Synthesis Example 613] Synthesis of Mat 613

Figure pat00707
Figure pat00707

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 481]과 동일한 과정을 수행하여 목적 화합물 12.7g을 얻었다.; HRMS [M]+: 732.24Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 481] was performed to obtain 12.7 g of the target compound; HRMS [M]+: 732.24

[합성예 614] Mat 614의 합성[Synthesis Example 614] Synthesis of Mat 614

Figure pat00708
Figure pat00708

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 482]과 동일한 과정을 수행하여 목적 화합물 15.6g을 얻었다.; HRMS [M]+: 656.21Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 482] was performed to obtain 15.6 g of the target compound; HRMS [M]+: 656.21

[합성예 615] Mat 615의 합성[Synthesis Example 615] Synthesis of Mat 615

Figure pat00709
Figure pat00709

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 483]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 808.27Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 483] was performed to obtain 16.4 g of the target compound; HRMS [M]+: 808.27

[합성예 616] Mat 616의 합성[Synthesis Example 616] Synthesis of Mat 616

Figure pat00710
Figure pat00710

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 484]과 동일한 과정을 수행하여 목적 화합물 15.9g을 얻었다.; HRMS [M]+: 732.24Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 484] was performed to obtain 15.9 g of the target compound; HRMS [M]+: 732.24

[합성예 617] Mat 617의 합성[Synthesis Example 617] Synthesis of Mat 617

Figure pat00711
Figure pat00711

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 485]과 동일한 과정을 수행하여 목적 화합물 16.6g을 얻었다.; HRMS [M]+: 746.22Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 485] was performed to obtain 16.6 g of the target compound; HRMS [M]+: 746.22

[합성예 618] Mat 618의 합성[Synthesis Example 618] Synthesis of Mat 618

Figure pat00712
Figure pat00712

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 486]과 동일한 과정을 수행하여 목적 화합물 14.2g을 얻었다.; HRMS [M]+: 657.21Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 486] was performed to obtain 14.2 g of the target compound; HRMS [M]+: 657.21

[합성예 619] Mat 619의 합성[Synthesis Example 619] Synthesis of Mat 619

Figure pat00713
Figure pat00713

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 487]과 동일한 과정을 수행하여 목적 화합물 16.3g을 얻었다.; HRMS [M]+: 809.27Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 487] was performed to obtain 16.3 g of the target compound; HRMS [M]+: 809.27

[합성예 620] Mat 620의 합성[Synthesis Example 620] Synthesis of Mat 620

Figure pat00714
Figure pat00714

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 488]과 동일한 과정을 수행하여 목적 화합물 15.3g을 얻었다.; HRMS [M]+: 733.24Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 488] was performed to obtain 15.3 g of the target compound; HRMS [M]+: 733.24

[합성예 621] Mat 621의 합성[Synthesis Example 621] Synthesis of Mat 621

Figure pat00715
Figure pat00715

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 489]과 동일한 과정을 수행하여 목적 화합물 14.7g을 얻었다.; HRMS [M]+: 747.22Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 489] was performed to obtain 14.7 g of the target compound; HRMS [M]+: 747.22

[합성예 622] Mat 622의 합성[Synthesis Example 622] Synthesis of Mat 622

Figure pat00716
Figure pat00716

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 490]과 동일한 과정을 수행하여 목적 화합물 12.1g을 얻었다.; HRMS [M]+: 657.21Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 490] was performed to obtain 12.1 g of the target compound; HRMS [M]+: 657.21

[합성예 623] Mat 623의 합성[Synthesis Example 623] Synthesis of Mat 623

Figure pat00717
Figure pat00717

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 491]과 동일한 과정을 수행하여 목적 화합물 13.9g을 얻었다.; HRMS [M]+: 809.27Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 491] was performed to obtain 13.9 g of the target compound; HRMS [M]+: 809.27

[합성예 624] Mat 624의 합성[Synthesis Example 624] Synthesis of Mat 624

Figure pat00718
Figure pat00718

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 492]과 동일한 과정을 수행하여 목적 화합물 14.8g을 얻었다.; HRMS [M]+: 809.27Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 492] was performed to obtain 14.8 g of the target compound; HRMS [M]+: 809.27

[합성예 625] Mat 625의 합성[Synthesis Example 625] Synthesis of Mat 625

Figure pat00719
Figure pat00719

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 493]과 동일한 과정을 수행하여 목적 화합물 13.8g을 얻었다.; HRMS [M]+: 733.24Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 493] was performed to obtain 13.8 g of the target compound; HRMS [M]+: 733.24

[합성예 626] Mat 626의 합성[Synthesis Example 626] Synthesis of Mat 626

Figure pat00720
Figure pat00720

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 494]과 동일한 과정을 수행하여 목적 화합물 14.3g을 얻었다.; HRMS [M]+: 747.22Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 494] was performed to obtain 14.3 g of the target compound; HRMS [M]+: 747.22

[합성예 627] Mat 627의 합성[Synthesis Example 627] Synthesis of Mat 627

Figure pat00721
Figure pat00721

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 495]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 733.24Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 495] was performed to obtain 16.4 g of the target compound; HRMS [M]+: 733.24

[합성예 628] Mat 628의 합성[Synthesis Example 628] Synthesis of Mat 628

Figure pat00722
Figure pat00722

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 496]과 동일한 과정을 수행하여 목적 화합물 12.7g을 얻었다.; HRMS [M]+: 885.30Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 496] was performed to obtain 12.7 g of the target compound; HRMS [M]+: 885.30

[합성예 629] Mat 629의 합성[Synthesis Example 629] Synthesis of Mat 629

Figure pat00723
Figure pat00723

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 497]과 동일한 과정을 수행하여 목적 화합물 13.3g을 얻었다.; HRMS [M]+: 885.30Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 497] was performed to obtain 13.3 g of the target compound; HRMS [M]+: 885.30

[합성예 630] Mat 630의 합성[Synthesis Example 630] Synthesis of Mat 630

Figure pat00724
Figure pat00724

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 498]과 동일한 과정을 수행하여 목적 화합물 15.6g을 얻었다.; HRMS [M]+: 809.27Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 498] was performed to obtain 15.6 g of the target compound; HRMS [M]+: 809.27

[합성예 631] Mat 631의 합성[Synthesis Example 631] Synthesis of Mat 631

Figure pat00725
Figure pat00725

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 499]과 동일한 과정을 수행하여 목적 화합물 14.8g을 얻었다.; HRMS [M]+: 823.25Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 499] was performed to obtain 14.8 g of the target compound; HRMS [M]+: 823.25

[합성예 632] Mat 632의 합성[Synthesis Example 632] Synthesis of Mat 632

Figure pat00726
Figure pat00726

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 500]과 동일한 과정을 수행하여 목적 화합물 13.7g을 얻었다.; HRMS [M]+: 554.16Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 500] was performed to obtain 13.7 g of the target compound; HRMS [M]+: 554.16

[합성예 633] Mat 633의 합성[Synthesis Example 633] Synthesis of Mat 633

Figure pat00727
Figure pat00727

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 501]과 동일한 과정을 수행하여 목적 화합물 14.6g을 얻었다.; HRMS [M]+: 630.20Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 501] was performed to obtain 14.6 g of the target compound; HRMS [M]+: 630.20

[합성예 634] Mat 634의 합성[Synthesis Example 634] Synthesis of Mat 634

Figure pat00728
Figure pat00728

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 502]과 동일한 과정을 수행하여 목적 화합물 15.1g을 얻었다.; HRMS [M]+: 680.21Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 502] was performed to obtain 15.1 g of the target compound; HRMS [M]+: 680.21

[합성예 635] Mat 635의 합성[Synthesis Example 635] Synthesis of Mat 635

Figure pat00729
Figure pat00729

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 503]과 동일한 과정을 수행하여 목적 화합물 14.5g을 얻었다.; HRMS [M]+: 604.18Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 503] was performed to obtain 14.5 g of the target compound; HRMS [M]+: 604.18

[합성예 636] Mat 636의 합성[Synthesis Example 636] Synthesis of Mat 636

Figure pat00730
Figure pat00730

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 504]과 동일한 과정을 수행하여 목적 화합물 13.5g을 얻었다.; HRMS [M]+: 554.16Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 504] was performed to obtain 13.5 g of the target compound; HRMS [M]+: 554.16

[합성예 637] Mat 637의 합성[Synthesis Example 637] Synthesis of Mat 637

Figure pat00731
Figure pat00731

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 373]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 590.26Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 373] was performed to obtain 16.4 g of the target compound; HRMS [M]+: 590.26

[합성예 638] Mat 638의 합성[Synthesis Example 638] Synthesis of Mat 638

Figure pat00732
Figure pat00732

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 374]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 742.32Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 374] was performed to obtain 16.4 g of the target compound; HRMS [M]+: 742.32

[합성예 639] Mat 639의 합성[Synthesis Example 639] Synthesis of Mat 639

Figure pat00733
Figure pat00733

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 375]과 동일한 과정을 수행하여 목적 화합물 15.8g을 얻었다.; HRMS [M]+: 742.32Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 375] was performed to obtain 15.8 g of the target compound; HRMS [M]+: 742.32

[합성예 640] Mat 640의 합성[Synthesis Example 640] Synthesis of Mat 640

Figure pat00734
Figure pat00734

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 376]과 동일한 과정을 수행하여 목적 화합물 14.1g을 얻었다.; HRMS [M]+: 666.29Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 376] was performed to obtain 14.1 g of the target compound; HRMS [M]+: 666.29

[합성예 641] Mat 641의 합성[Synthesis Example 641] Synthesis of Mat 641

Figure pat00735
Figure pat00735

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 377]과 동일한 과정을 수행하여 목적 화합물 14.3g을 얻었다.; HRMS [M]+: 680.27Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 377] was performed to obtain 14.3 g of the target compound; HRMS [M]+: 680.27

[합성예 642] Mat 642의 합성[Synthesis Example 642] Synthesis of Mat 642

Figure pat00736
Figure pat00736

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 378]과 동일한 과정을 수행하여 목적 화합물 12.1g을 얻었다.; HRMS [M]+: 590.26Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 378] was performed to obtain 12.1 g of the target compound; HRMS [M]+: 590.26

[합성예 543] Mat 643의 합성[Synthesis Example 543] Synthesis of Mat 643

Figure pat00737
Figure pat00737

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 379]과 동일한 과정을 수행하여 목적 화합물 13.9g을 얻었다.; HRMS [M]+: 742.32Except for using [Preparation Example 9] as a reactant, 13.9 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 379]; HRMS [M]+: 742.32

[합성예 644] Mat 644의 합성[Synthesis Example 644] Synthesis of Mat 644

Figure pat00738
Figure pat00738

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 380]과 동일한 과정을 수행하여 목적 화합물 14.8g을 얻었다.; HRMS [M]+: 666.29Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 380] was performed to obtain 14.8 g of the target compound; HRMS [M]+: 666.29

[합성예 645] Mat 645의 합성[Synthesis Example 645] Synthesis of Mat 645

Figure pat00739
Figure pat00739

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 381]과 동일한 과정을 수행하여 목적 화합물 13.5g을 얻었다.; HRMS [M]+: 680.27Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 381] was performed to obtain 13.5 g of the target compound; HRMS [M]+: 680.27

[합성예 646] Mat 646의 합성[Synthesis Example 646] Synthesis of Mat 646

Figure pat00740
Figure pat00740

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 382]과 동일한 과정을 수행하여 목적 화합물 12.7g을 얻었다.; HRMS [M]+: 742.32Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 382] was performed to obtain 12.7 g of the target compound; HRMS [M]+: 742.32

[합성예 647] Mat 647의 합성[Synthesis Example 647] Synthesis of Mat 647

Figure pat00741
Figure pat00741

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 383]과 동일한 과정을 수행하여 목적 화합물 15.6g을 얻었다.; HRMS [M]+: 666.29Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 383] was performed to obtain 15.6 g of the target compound; HRMS [M]+: 666.29

[합성예 648] Mat 648의 합성[Synthesis Example 648] Synthesis of Mat 648

Figure pat00742
Figure pat00742

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 384]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 819.35Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 384] was performed to obtain 16.4 g of the target compound; HRMS [M]+: 819.35

[합성예 649] Mat 649의 합성[Synthesis Example 649] Synthesis of Mat 649

Figure pat00743
Figure pat00743

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 385]과 동일한 과정을 수행하여 목적 화합물 15.9g을 얻었다.; HRMS [M]+: 742.32Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 385] was performed to obtain 15.9 g of the target compound; HRMS [M]+: 742.32

[합성예 650] Mat 650의 합성[Synthesis Example 650] Synthesis of Mat 650

Figure pat00744
Figure pat00744

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 386]과 동일한 과정을 수행하여 목적 화합물 16.6g을 얻었다.; HRMS [M]+: 756.30Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 386] was performed to obtain 16.6 g of the target compound; HRMS [M]+: 756.30

[합성예 651] Mat 651의 합성[Synthesis Example 651] Synthesis of Mat 651

Figure pat00745
Figure pat00745

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 387]과 동일한 과정을 수행하여 목적 화합물 14.2g을 얻었다.; HRMS [M]+: 667.28Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 387] was performed to obtain 14.2 g of the target compound; HRMS [M]+: 667.28

[합성예 652] Mat 652의 합성[Synthesis Example 652] Synthesis of Mat 652

Figure pat00746
Figure pat00746

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 388]과 동일한 과정을 수행하여 목적 화합물 16.3g을 얻었다.; HRMS [M]+: 819.34Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 388] was performed to obtain 16.3 g of the target compound; HRMS [M]+: 819.34

[합성예 653] Mat 653의 합성[Synthesis Example 653] Synthesis of Mat 653

Figure pat00747
Figure pat00747

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 389]과 동일한 과정을 수행하여 목적 화합물 15.3g을 얻었다.; HRMS [M]+: 743.3115.3 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 389] except that [Preparation Example 9] was used as a reactant; HRMS [M]+: 743.31

[합성예 654] Mat 645의 합성[Synthesis Example 654] Synthesis of Mat 645

Figure pat00748
Figure pat00748

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 390]과 동일한 과정을 수행하여 목적 화합물 14.7g을 얻었다.; HRMS [M]+: 757.29Except for using [Preparation Example 9] as a reactant, 14.7 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 390]; HRMS [M]+: 757.29

[합성예 655] Mat 655의 합성[Synthesis Example 655] Synthesis of Mat 655

Figure pat00749
Figure pat00749

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 391]과 동일한 과정을 수행하여 목적 화합물 12.1g을 얻었다.; HRMS [M]+: 667.28Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 391] was performed to obtain 12.1 g of the target compound; HRMS [M]+: 667.28

[합성예 656] Mat 656의 합성[Synthesis Example 656] Synthesis of Mat 656

Figure pat00750
Figure pat00750

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 392]과 동일한 과정을 수행하여 목적 화합물 13.9g을 얻었다.; HRMS [M]+: 819.3413.9 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 392] except that [Preparation Example 9] was used as a reactant; HRMS [M]+: 819.34

[합성예 657] Mat 657의 합성[Synthesis Example 657] Synthesis of Mat 657

Figure pat00751
Figure pat00751

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 393]과 동일한 과정을 수행하여 목적 화합물 14.8g을 얻었다.; HRMS [M]+: 819.34Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 393] was performed to obtain 14.8 g of the target compound; HRMS [M]+: 819.34

[합성예 658] Mat 658의 합성[Synthesis Example 658] Synthesis of Mat 658

Figure pat00752
Figure pat00752

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 394]과 동일한 과정을 수행하여 목적 화합물 13.8g을 얻었다.; HRMS [M]+: 743.31Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 394] was performed to obtain 13.8 g of the target compound; HRMS [M]+: 743.31

[합성예 659] Mat 659의 합성[Synthesis Example 659] Synthesis of Mat 659

Figure pat00753
Figure pat00753

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 395]과 동일한 과정을 수행하여 목적 화합물 14.3g을 얻었다.; HRMS [M]+: 757.29Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 395] was performed to obtain 14.3 g of the target compound; HRMS [M]+: 757.29

[합성예 660] Mat 660의 합성[Synthesis Example 660] Synthesis of Mat 660

Figure pat00754
Figure pat00754

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 396]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 743.31Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 396] was performed to obtain 16.4 g of the target compound; HRMS [M]+: 743.31

[합성예 661] Mat 661의 합성[Synthesis Example 661] Synthesis of Mat 661

Figure pat00755
Figure pat00755

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 397]과 동일한 과정을 수행하여 목적 화합물 12.7g을 얻었다.; HRMS [M]+: 895.38Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 397] was performed to obtain 12.7 g of the target compound; HRMS [M]+: 895.38

[합성예 662] Mat 662의 합성[Synthesis Example 662] Synthesis of Mat 662

Figure pat00756
Figure pat00756

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 398]과 동일한 과정을 수행하여 목적 화합물 13.3g을 얻었다.; HRMS [M]+: 895.38Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 398] was performed to obtain 13.3 g of the target compound; HRMS [M]+: 895.38

[합성예 663] Mat 663의 합성[Synthesis Example 663] Synthesis of Mat 663

Figure pat00757
Figure pat00757

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 399]과 동일한 과정을 수행하여 목적 화합물 15.6g을 얻었다.; HRMS [M]+: 819.3415.6 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 399] except that [Preparation Example 9] was used as a reactant; HRMS [M]+: 819.34

[합성예 664] Mat 664의 합성[Synthesis Example 664] Synthesis of Mat 664

Figure pat00758
Figure pat00758

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 400]과 동일한 과정을 수행하여 목적 화합물 14.8g을 얻었다.; HRMS [M]+: 833.32Except for using [Preparation Example 9] as a reactant, 14.8 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 400].; HRMS [M]+: 833.32

[합성예 665] Mat 665의 합성[Synthesis Example 665] Synthesis of Mat 665

Figure pat00759
Figure pat00759

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 401]과 동일한 과정을 수행하여 목적 화합물 13.7g을 얻었다.; HRMS [M]+: 564.24Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 401] was performed to obtain 13.7 g of the target compound; HRMS [M]+: 564.24

[합성예 666] Mat 666의 합성[Synthesis Example 666] Synthesis of Mat 666

Figure pat00760
Figure pat00760

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 402]과 동일한 과정을 수행하여 목적 화합물 14.6g을 얻었다.; HRMS [M]+: 640.27Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 402] was performed to obtain 14.6 g of the target compound; HRMS [M]+: 640.27

[합성예 667] Mat 667의 합성[Synthesis Example 667] Synthesis of Mat 667

Figure pat00761
Figure pat00761

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 403]과 동일한 과정을 수행하여 목적 화합물 15.1g을 얻었다.; HRMS [M]+: 690.29Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 403] was performed to obtain 15.1 g of the target compound; HRMS [M]+: 690.29

[합성예 668] Mat 668의 합성[Synthesis Example 668] Synthesis of Mat 668

Figure pat00762
Figure pat00762

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 404]과 동일한 과정을 수행하여 목적 화합물 14.5g을 얻었다.; HRMS [M]+: 614.26Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 404] was performed to obtain 14.5 g of the target compound; HRMS [M]+: 614.26

[합성예 669] Mat 669의 합성[Synthesis Example 669] Synthesis of Mat 669

Figure pat00763
Figure pat00763

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 405]과 동일한 과정을 수행하여 목적 화합물 13.5g을 얻었다.; HRMS [M]+: 564.24Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 405] was performed to obtain 13.5 g of the target compound; HRMS [M]+: 564.24

[합성예 670] Mat 670의 합성[Synthesis Example 670] Synthesis of Mat 670

Figure pat00764
Figure pat00764

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 406]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 590.26Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 406] was performed to obtain 16.4 g of the target compound; HRMS [M]+: 590.26

[합성예 671] Mat 671의 합성[Synthesis Example 671] Synthesis of Mat 671

Figure pat00765
Figure pat00765

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 407]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 742.32Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 407] was performed to obtain 16.4 g of the target compound; HRMS [M]+: 742.32

[합성예 672] Mat 672의 합성[Synthesis Example 672] Synthesis of Mat 672

Figure pat00766
Figure pat00766

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 408]과 동일한 과정을 수행하여 목적 화합물 15.8g을 얻었다.; HRMS [M]+: 742.32Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 408] was performed to obtain 15.8 g of the target compound; HRMS [M]+: 742.32

[합성예 673] Mat 673의 합성[Synthesis Example 673] Synthesis of Mat 673

Figure pat00767
Figure pat00767

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 409]과 동일한 과정을 수행하여 목적 화합물 14.1g을 얻었다.; HRMS [M]+: 666.29Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 409] was performed to obtain 14.1 g of the target compound; HRMS [M]+: 666.29

[합성예 674] Mat 674의 합성[Synthesis Example 674] Synthesis of Mat 674

Figure pat00768
Figure pat00768

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 410]과 동일한 과정을 수행하여 목적 화합물 14.3g을 얻었다.; HRMS [M]+: 680.27Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 410] was performed to obtain 14.3 g of the target compound; HRMS [M]+: 680.27

[합성예 675] Mat 675의 합성[Synthesis Example 675] Synthesis of Mat 675

Figure pat00769
Figure pat00769

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 411]과 동일한 과정을 수행하여 목적 화합물 12.1g을 얻었다.; HRMS [M]+: 590.26Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 411] was performed to obtain 12.1 g of the target compound; HRMS [M]+: 590.26

[합성예 676] Mat 676의 합성[Synthesis Example 676] Synthesis of Mat 676

Figure pat00770
Figure pat00770

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 412]과 동일한 과정을 수행하여 목적 화합물 13.9g을 얻었다.; HRMS [M]+: 742.32Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 412] was performed to obtain 13.9 g of the target compound; HRMS [M]+: 742.32

[합성예 677] Mat 677의 합성[Synthesis Example 677] Synthesis of Mat 677

Figure pat00771
Figure pat00771

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 413]과 동일한 과정을 수행하여 목적 화합물 14.8g을 얻었다.; HRMS [M]+: 666.29Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 413] was performed to obtain 14.8 g of the target compound; HRMS [M]+: 666.29

[합성예 678] Mat 678의 합성[Synthesis Example 678] Synthesis of Mat 678

Figure pat00772
Figure pat00772

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 414]과 동일한 과정을 수행하여 목적 화합물 13.5g을 얻었다.; HRMS [M]+: 680.27Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 414] was performed to obtain 13.5 g of the target compound; HRMS [M]+: 680.27

[합성예 679] Mat 679의 합성[Synthesis Example 679] Synthesis of Mat 679

Figure pat00773
Figure pat00773

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 415]과 동일한 과정을 수행하여 목적 화합물 12.7g을 얻었다.; HRMS [M]+: 742.32Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 415] was performed to obtain 12.7 g of the target compound; HRMS [M]+: 742.32

[합성예 680] Mat 680의 합성[Synthesis Example 680] Synthesis of Mat 680

Figure pat00774
Figure pat00774

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 416]과 동일한 과정을 수행하여 목적 화합물 15.6g을 얻었다.; HRMS [M]+: 666.29Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 416] was performed to obtain 15.6 g of the target compound; HRMS [M]+: 666.29

[합성예 681] Mat 681의 합성[Synthesis Example 681] Synthesis of Mat 681

Figure pat00775
Figure pat00775

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 417]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 818.35Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 417] was performed to obtain 16.4 g of the target compound; HRMS [M]+: 818.35

[합성예 682] Mat 682의 합성[Synthesis Example 682] Synthesis of Mat 682

Figure pat00776
Figure pat00776

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 418]과 동일한 과정을 수행하여 목적 화합물 15.9g을 얻었다.; HRMS [M]+: 742.32Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 418] was performed to obtain 15.9 g of the target compound; HRMS [M]+: 742.32

[합성예 683] Mat 683의 합성[Synthesis Example 683] Synthesis of Mat 683

Figure pat00777
Figure pat00777

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 419]과 동일한 과정을 수행하여 목적 화합물 16.6g을 얻었다.; HRMS [M]+: 756.30Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 419] was performed to obtain 16.6 g of the target compound; HRMS [M]+: 756.30

[합성예 684] Mat 684의 합성[Synthesis Example 684] Synthesis of Mat 684

Figure pat00778
Figure pat00778

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 420]과 동일한 과정을 수행하여 목적 화합물 14.2g을 얻었다.; HRMS [M]+: 667.28Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 420] was performed to obtain 14.2 g of the target compound; HRMS [M]+: 667.28

[합성예 685] Mat 685의 합성[Synthesis Example 685] Synthesis of Mat 685

Figure pat00779
Figure pat00779

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 421]과 동일한 과정을 수행하여 목적 화합물 16.3g을 얻었다.; HRMS [M]+: 819.34Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 421] was performed to obtain 16.3 g of the target compound; HRMS [M]+: 819.34

[합성예 686] Mat 686의 합성[Synthesis Example 686] Synthesis of Mat 686

Figure pat00780
Figure pat00780

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 422]과 동일한 과정을 수행하여 목적 화합물 15.3g을 얻었다.; HRMS [M]+: 743.31Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 422] was performed to obtain 15.3 g of the target compound; HRMS [M]+: 743.31

[합성예 687] Mat 687의 합성[Synthesis Example 687] Synthesis of Mat 687

Figure pat00781
Figure pat00781

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 423]과 동일한 과정을 수행하여 목적 화합물 14.7g을 얻었다.; HRMS [M]+: 757.29Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 423] was performed to obtain 14.7 g of the target compound; HRMS [M]+: 757.29

[합성예 688] Mat 688의 합성[Synthesis Example 688] Synthesis of Mat 688

Figure pat00782
Figure pat00782

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 424]과 동일한 과정을 수행하여 목적 화합물 12.1g을 얻었다.; HRMS [M]+: 667.28Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 424] was performed to obtain 12.1 g of the target compound; HRMS [M]+: 667.28

[합성예 689] Mat 689의 합성[Synthesis Example 689] Synthesis of Mat 689

Figure pat00783
Figure pat00783

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 425]과 동일한 과정을 수행하여 목적 화합물 13.9g을 얻었다.; HRMS [M]+: 819.34Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 425] was performed to obtain 13.9 g of the target compound; HRMS [M]+: 819.34

[합성예 690] Mat 690의 합성[Synthesis Example 690] Synthesis of Mat 690

Figure pat00784
Figure pat00784

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 426]과 동일한 과정을 수행하여 목적 화합물 14.8g을 얻었다.; HRMS [M]+: 819.34Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 426] was performed to obtain 14.8 g of the target compound; HRMS [M]+: 819.34

[합성예 691] Mat 691의 합성[Synthesis Example 691] Synthesis of Mat 691

Figure pat00785
Figure pat00785

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 427]과 동일한 과정을 수행하여 목적 화합물 13.8g을 얻었다.; HRMS [M]+: 743.31Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 427] was performed to obtain 13.8 g of the target compound; HRMS [M]+: 743.31

[합성예 692] Mat 692의 합성[Synthesis Example 692] Synthesis of Mat 692

Figure pat00786
Figure pat00786

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 428]과 동일한 과정을 수행하여 목적 화합물 14.3g을 얻었다.; HRMS [M]+: 757.29Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 428] was performed to obtain 14.3 g of the target compound; HRMS [M]+: 757.29

[합성예 693] Mat 693의 합성[Synthesis Example 693] Synthesis of Mat 693

Figure pat00787
Figure pat00787

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 429]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 743.31Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 429] was performed to obtain 16.4 g of the target compound; HRMS [M]+: 743.31

[합성예 694] Mat 694의 합성[Synthesis Example 694] Synthesis of Mat 694

Figure pat00788
Figure pat00788

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 430]과 동일한 과정을 수행하여 목적 화합물 12.7g을 얻었다.; HRMS [M]+: 895.38Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 430] was performed to obtain 12.7 g of the target compound; HRMS [M]+: 895.38

[합성예 695] Mat 695의 합성[Synthesis Example 695] Synthesis of Mat 695

Figure pat00789
Figure pat00789

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 431]과 동일한 과정을 수행하여 목적 화합물 13.3g을 얻었다.; HRMS [M]+: 895.38Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 431] was performed to obtain 13.3 g of the target compound; HRMS [M]+: 895.38

[합성예 696] Mat 696의 합성[Synthesis Example 696] Synthesis of Mat 696

Figure pat00790
Figure pat00790

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 432]과 동일한 과정을 수행하여 목적 화합물 15.6g을 얻었다.; HRMS [M]+: 819.34Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 432] was performed to obtain 15.6 g of the target compound; HRMS [M]+: 819.34

[합성예 697] Mat 697의 합성[Synthesis Example 697] Synthesis of Mat 697

Figure pat00791
Figure pat00791

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 433]과 동일한 과정을 수행하여 목적 화합물 14.8g을 얻었다.; HRMS [M]+: 833.32Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 433] was performed to obtain 14.8 g of the target compound; HRMS [M]+: 833.32

[합성예 698] Mat 698의 합성[Synthesis Example 698] Synthesis of Mat 698

Figure pat00792
Figure pat00792

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 434]과 동일한 과정을 수행하여 목적 화합물 13.7g을 얻었다.; HRMS [M]+: 564.24Except for using [Preparation Example 10] as a reactant, 13.7 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 434]; HRMS [M]+: 564.24

[합성예 699] Mat 699의 합성[Synthesis Example 699] Synthesis of Mat 699

Figure pat00793
Figure pat00793

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 435]과 동일한 과정을 수행하여 목적 화합물 14.6g을 얻었다.; HRMS [M]+: 640.27Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 435] was performed to obtain 14.6 g of the target compound; HRMS [M]+: 640.27

[합성예 700] Mat 700의 합성[Synthesis Example 700] Synthesis of Mat 700

Figure pat00794
Figure pat00794

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 436]과 동일한 과정을 수행하여 목적 화합물 15.1g을 얻었다.; HRMS [M]+: 690.29Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 436] was performed to obtain 15.1 g of the target compound; HRMS [M]+: 690.29

[합성예 701] Mat 701의 합성[Synthesis Example 701] Synthesis of Mat 701

Figure pat00795
Figure pat00795

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 437]과 동일한 과정을 수행하여 목적 화합물 14.5g을 얻었다.; HRMS [M]+: 614.26Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 437] was performed to obtain 14.5 g of the target compound; HRMS [M]+: 614.26

[합성예 702] Mat 702의 합성[Synthesis Example 702] Synthesis of Mat 702

Figure pat00796
Figure pat00796

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 438]과 동일한 과정을 수행하여 목적 화합물 13.5g을 얻었다.; HRMS [M]+: 564.24Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 438] was performed to obtain 13.5 g of the target compound; HRMS [M]+: 564.24

[합성예 703] Mat 703의 합성[Synthesis Example 703] Synthesis of Mat 703

Figure pat00797
Figure pat00797

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 439]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 590.26Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 439] was performed to obtain 16.4 g of the target compound; HRMS [M]+: 590.26

[합성예 704] Mat 704의 합성[Synthesis Example 704] Synthesis of Mat 704

Figure pat00798
Figure pat00798

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 440]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 742.32Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 440] was performed to obtain 16.4 g of the target compound; HRMS [M]+: 742.32

[합성예 705] Mat 705의 합성[Synthesis Example 705] Synthesis of Mat 705

Figure pat00799
Figure pat00799

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 441]과 동일한 과정을 수행하여 목적 화합물 15.8g을 얻었다.; HRMS [M]+: 742.32Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 441] was performed to obtain 15.8 g of the target compound; HRMS [M]+: 742.32

[합성예 706] Mat 706의 합성[Synthesis Example 706] Synthesis of Mat 706

Figure pat00800
Figure pat00800

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 442]과 동일한 과정을 수행하여 목적 화합물 14.1g을 얻었다.; HRMS [M]+: 666.29Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 442] was performed to obtain 14.1 g of the target compound; HRMS [M]+: 666.29

[합성예 707] Mat 707의 합성[Synthesis Example 707] Synthesis of Mat 707

Figure pat00801
Figure pat00801

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 443]과 동일한 과정을 수행하여 목적 화합물 14.3g을 얻었다.; HRMS [M]+: 680.27Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 443] was performed to obtain 14.3 g of the target compound; HRMS [M]+: 680.27

[합성예 708] Mat 708의 합성[Synthesis Example 708] Synthesis of Mat 708

Figure pat00802
Figure pat00802

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 444]과 동일한 과정을 수행하여 목적 화합물 12.1g을 얻었다.; HRMS [M]+: 590.26Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 444] was performed to obtain 12.1 g of the target compound; HRMS [M]+: 590.26

[합성예 709] Mat 709의 합성[Synthesis Example 709] Synthesis of Mat 709

Figure pat00803
Figure pat00803

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 445]과 동일한 과정을 수행하여 목적 화합물 13.9g을 얻었다.; HRMS [M]+: 742.32Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 445] was performed to obtain 13.9 g of the target compound; HRMS [M]+: 742.32

[합성예 710] Mat 710의 합성[Synthesis Example 710] Synthesis of Mat 710

Figure pat00804
Figure pat00804

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 446]과 동일한 과정을 수행하여 목적 화합물 14.8g을 얻었다.; HRMS [M]+: 666.29Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 446] was performed to obtain 14.8 g of the target compound; HRMS [M]+: 666.29

[합성예 711] Mat 711의 합성[Synthesis Example 711] Synthesis of Mat 711

Figure pat00805
Figure pat00805

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 447]과 동일한 과정을 수행하여 목적 화합물 13.5g을 얻었다.; HRMS [M]+: 680.27Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 447] was performed to obtain 13.5 g of the target compound; HRMS [M]+: 680.27

[합성예 712] Mat 712의 합성[Synthesis Example 712] Synthesis of Mat 712

Figure pat00806
Figure pat00806

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 448]과 동일한 과정을 수행하여 목적 화합물 12.7g을 얻었다.; HRMS [M]+: 742.32Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 448] was performed to obtain 12.7 g of the target compound; HRMS [M]+: 742.32

[합성예 713] Mat 713의 합성[Synthesis Example 713] Synthesis of Mat 713

Figure pat00807
Figure pat00807

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 449]과 동일한 과정을 수행하여 목적 화합물 15.6g을 얻었다.; HRMS [M]+: 666.29Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 449] was performed to obtain 15.6 g of the target compound; HRMS [M]+: 666.29

[합성예 714] Mat 714의 합성[Synthesis Example 714] Synthesis of Mat 714

Figure pat00808
Figure pat00808

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 450]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 818.35Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 450] was performed to obtain 16.4 g of the target compound; HRMS [M]+: 818.35

[합성예 715] Mat 715의 합성[Synthesis Example 715] Synthesis of Mat 715

Figure pat00809
Figure pat00809

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 451]과 동일한 과정을 수행하여 목적 화합물 15.9g을 얻었다.; HRMS [M]+: 742.32Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 451] was performed to obtain 15.9 g of the target compound; HRMS [M]+: 742.32

[합성예 716] Mat 716의 합성[Synthesis Example 716] Synthesis of Mat 716

Figure pat00810
Figure pat00810

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 452]과 동일한 과정을 수행하여 목적 화합물 16.6g을 얻었다.; HRMS [M]+: 756.30Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 452] was performed to obtain 16.6 g of the target compound; HRMS [M]+: 756.30

[합성예 717] Mat 717의 합성[Synthesis Example 717] Synthesis of Mat 717

Figure pat00811
Figure pat00811

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 453]과 동일한 과정을 수행하여 목적 화합물 14.2g을 얻었다.; HRMS [M]+: 667.28Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 453] was performed to obtain 14.2 g of the target compound; HRMS [M]+: 667.28

[합성예 718] Mat 718의 합성[Synthesis Example 718] Synthesis of Mat 718

Figure pat00812
Figure pat00812

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 454]과 동일한 과정을 수행하여 목적 화합물 16.3g을 얻었다.; HRMS [M]+: 819.34Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 454] was performed to obtain 16.3 g of the target compound; HRMS [M]+: 819.34

[합성예 719] Mat 719의 합성[Synthesis Example 719] Synthesis of Mat 719

Figure pat00813
Figure pat00813

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 455]과 동일한 과정을 수행하여 목적 화합물 15.3g을 얻었다.; HRMS [M]+: 743.31Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 455] was performed to obtain 15.3 g of the target compound; HRMS [M]+: 743.31

[합성예 720] Mat 720의 합성[Synthesis Example 720] Synthesis of Mat 720

Figure pat00814
Figure pat00814

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 456]과 동일한 과정을 수행하여 목적 화합물 14.7g을 얻었다.; HRMS [M]+: 757.29Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 456] was performed to obtain 14.7 g of the target compound; HRMS [M]+: 757.29

[합성예 721] Mat 721의 합성[Synthesis Example 721] Synthesis of Mat 721

Figure pat00815
Figure pat00815

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 457]과 동일한 과정을 수행하여 목적 화합물 12.1g을 얻었다.; HRMS [M]+: 667.28Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 457] was performed to obtain 12.1 g of the target compound; HRMS [M]+: 667.28

[합성예 722] Mat 722의 합성[Synthesis Example 722] Synthesis of Mat 722

Figure pat00816
Figure pat00816

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 458]과 동일한 과정을 수행하여 목적 화합물 13.9g을 얻었다.; HRMS [M]+: 819.34Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 458] was performed to obtain 13.9 g of the target compound; HRMS [M]+: 819.34

[합성예 723] Mat 723의 합성[Synthesis Example 723] Synthesis of Mat 723

Figure pat00817
Figure pat00817

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 459]과 동일한 과정을 수행하여 목적 화합물 14.8g을 얻었다.; HRMS [M]+: 819.34Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 459] was performed to obtain 14.8 g of the target compound; HRMS [M]+: 819.34

[합성예 724] Mat 724의 합성[Synthesis Example 724] Synthesis of Mat 724

Figure pat00818
Figure pat00818

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 460]과 동일한 과정을 수행하여 목적 화합물 13.8g을 얻었다.; HRMS [M]+: 743.31Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 460] was performed to obtain 13.8 g of the target compound; HRMS [M]+: 743.31

[합성예 725] Mat 725의 합성[Synthesis Example 725] Synthesis of Mat 725

Figure pat00819
Figure pat00819

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 461]과 동일한 과정을 수행하여 목적 화합물 14.3g을 얻었다.; HRMS [M]+: 757.29Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 461] was performed to obtain 14.3 g of the target compound; HRMS [M]+: 757.29

[합성예 726] Mat 726의 합성[Synthesis Example 726] Synthesis of Mat 726

Figure pat00820
Figure pat00820

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 462]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 743.31Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 462] was performed to obtain 16.4 g of the target compound; HRMS [M]+: 743.31

[합성예 727] Mat 727의 합성[Synthesis Example 727] Synthesis of Mat 727

Figure pat00821
Figure pat00821

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 463]과 동일한 과정을 수행하여 목적 화합물 12.7g을 얻었다.; HRMS [M]+: 895.38Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 463] was performed to obtain 12.7 g of the target compound; HRMS [M]+: 895.38

[합성예 728] Mat 728의 합성[Synthesis Example 728] Synthesis of Mat 728

Figure pat00822
Figure pat00822

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 464]과 동일한 과정을 수행하여 목적 화합물 13.3g을 얻었다.; HRMS [M]+: 895.38Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 464] was performed to obtain 13.3 g of the target compound; HRMS [M]+: 895.38

[합성예 729] Mat 729의 합성[Synthesis Example 729] Synthesis of Mat 729

Figure pat00823
Figure pat00823

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 465]과 동일한 과정을 수행하여 목적 화합물 15.6g을 얻었다.; HRMS [M]+: 819.34Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 465] was performed to obtain 15.6 g of the target compound; HRMS [M]+: 819.34

[합성예 730] Mat 730의 합성[Synthesis Example 730] Synthesis of Mat 730

Figure pat00824
Figure pat00824

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 466]과 동일한 과정을 수행하여 목적 화합물 14.8g을 얻었다.; HRMS [M]+: 833.32Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 466] was performed to obtain 14.8 g of the target compound; HRMS [M]+: 833.32

[합성예 731] Mat 731의 합성[Synthesis Example 731] Synthesis of Mat 731

Figure pat00825
Figure pat00825

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 467]과 동일한 과정을 수행하여 목적 화합물 13.7g을 얻었다.; HRMS [M]+: 564.24Except for using [Preparation Example 11] as a reactant, 13.7 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 467]; HRMS [M]+: 564.24

[합성예 732] Mat 732의 합성[Synthesis Example 732] Synthesis of Mat 732

Figure pat00826
Figure pat00826

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 468]과 동일한 과정을 수행하여 목적 화합물 14.6g을 얻었다.; HRMS [M]+: 640.27Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 468] was performed to obtain 14.6 g of the target compound; HRMS [M]+: 640.27

[합성예 733] Mat 733의 합성[Synthesis Example 733] Synthesis of Mat 733

Figure pat00827
Figure pat00827

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 469]과 동일한 과정을 수행하여 목적 화합물 15.1g을 얻었다.; HRMS [M]+: 690.29Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 469] was performed to obtain 15.1 g of the target compound; HRMS [M]+: 690.29

[합성예 734] Mat 734의 합성[Synthesis Example 734] Synthesis of Mat 734

Figure pat00828
Figure pat00828

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 470]과 동일한 과정을 수행하여 목적 화합물 14.5g을 얻었다.; HRMS [M]+: 614.26Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 470] was performed to obtain 14.5 g of the target compound; HRMS [M]+: 614.26

[합성예735] Mat 735의 합성[Synthesis Example 735] Synthesis of Mat 735

Figure pat00829
Figure pat00829

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 471]과 동일한 과정을 수행하여 목적 화합물 13.5g을 얻었다.; HRMS [M]+: 564.24Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 471] was performed to obtain 13.5 g of the target compound; HRMS [M]+: 564.24

[합성예 736] Mat 736의 합성[Synthesis Example 736] Synthesis of Mat 736

Figure pat00830
Figure pat00830

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 472]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 580.18Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 472] was performed to obtain 16.4 g of the target compound; HRMS [M]+: 580.18

[합성예 737] Mat 737의 합성[Synthesis Example 737] Synthesis of Mat 737

Figure pat00831
Figure pat00831

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 473]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 732.24Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 473] was performed to obtain 16.4 g of the target compound; HRMS [M]+: 732.24

[합성예 738] Mat 738의 합성[Synthesis Example 738] Synthesis of Mat 738

Figure pat00832
Figure pat00832

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 474]과 동일한 과정을 수행하여 목적 화합물 15.8g을 얻었다.; HRMS [M]+: 732.24Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 474] was performed to obtain 15.8 g of the target compound; HRMS [M]+: 732.24

[합성예 739] Mat739의 합성[Synthesis Example 739] Synthesis of Mat739

Figure pat00833
Figure pat00833

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 475]과 동일한 과정을 수행하여 목적 화합물 14.1g을 얻었다.; HRMS [M]+: 656.21Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 475] was performed to obtain 14.1 g of the target compound; HRMS [M]+: 656.21

[합성예 740] Mat 740의 합성[Synthesis Example 740] Synthesis of Mat 740

Figure pat00834
Figure pat00834

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 476]과 동일한 과정을 수행하여 목적 화합물 14.3g을 얻었다.; HRMS [M]+: 670.19Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 476] was performed to obtain 14.3 g of the target compound; HRMS [M]+: 670.19

[합성예 741] Mat 741의 합성[Synthesis Example 741] Synthesis of Mat 741

Figure pat00835
Figure pat00835

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 477]과 동일한 과정을 수행하여 목적 화합물 12.1g을 얻었다.; HRMS [M]+: 580.18Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 477] was performed to obtain 12.1 g of the target compound; HRMS [M]+: 580.18

[합성예 742] Mat 742의 합성[Synthesis Example 742] Synthesis of Mat 742

Figure pat00836
Figure pat00836

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 478]과 동일한 과정을 수행하여 목적 화합물 13.9g을 얻었다.; HRMS [M]+: 732.24Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 478] was performed to obtain 13.9 g of the target compound; HRMS [M]+: 732.24

[합성예 743] Mat 743의 합성[Synthesis Example 743] Synthesis of Mat 743

Figure pat00837
Figure pat00837

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 479]과 동일한 과정을 수행하여 목적 화합물 14.8g을 얻었다.; HRMS [M]+: 656.21Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 479] was performed to obtain 14.8 g of the target compound; HRMS [M]+: 656.21

[합성예 744] Mat 744의 합성[Synthesis Example 744] Synthesis of Mat 744

Figure pat00838
Figure pat00838

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 480]과 동일한 과정을 수행하여 목적 화합물 13.5g을 얻었다.; HRMS [M]+: 670.19Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 480] was performed to obtain 13.5 g of the target compound; HRMS [M]+: 670.19

[합성예 745] Mat 745의 합성[Synthesis Example 745] Synthesis of Mat 745

Figure pat00839
Figure pat00839

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 481]과 동일한 과정을 수행하여 목적 화합물 12.7g을 얻었다.; HRMS [M]+: 732.24Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 481] was performed to obtain 12.7 g of the target compound; HRMS [M]+: 732.24

[합성예 746] Mat 746의 합성[Synthesis Example 746] Synthesis of Mat 746

Figure pat00840
Figure pat00840

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 482]과 동일한 과정을 수행하여 목적 화합물 15.6g을 얻었다.; HRMS [M]+: 656.21Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 482] was performed to obtain 15.6 g of the target compound; HRMS [M]+: 656.21

[합성예 747] Mat 747의 합성[Synthesis Example 747] Synthesis of Mat 747

Figure pat00841
Figure pat00841

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 483]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 808.27Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 483] was performed to obtain 16.4 g of the target compound; HRMS [M]+: 808.27

[합성예 748] Mat 748의 합성[Synthesis Example 748] Synthesis of Mat 748

Figure pat00842
Figure pat00842

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 484]과 동일한 과정을 수행하여 목적 화합물 15.9g을 얻었다.; HRMS [M]+: 732.24Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 484] was performed to obtain 15.9 g of the target compound; HRMS [M]+: 732.24

[합성예 749] Mat 749의 합성[Synthesis Example 749] Synthesis of Mat 749

Figure pat00843
Figure pat00843

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 485]과 동일한 과정을 수행하여 목적 화합물 16.6g을 얻었다.; HRMS [M]+: 746.22Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 485] was performed to obtain 16.6 g of the target compound; HRMS [M]+: 746.22

[합성예 750] Mat 750의 합성[Synthesis Example 750] Synthesis of Mat 750

Figure pat00844
Figure pat00844

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 486]과 동일한 과정을 수행하여 목적 화합물 14.2g을 얻었다.; HRMS [M]+: 657.21Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 486] was performed to obtain 14.2 g of the target compound; HRMS [M]+: 657.21

[합성예 751] Mat 751의 합성[Synthesis Example 751] Synthesis of Mat 751

Figure pat00845
Figure pat00845

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 487]과 동일한 과정을 수행하여 목적 화합물 16.3g을 얻었다.; HRMS [M]+: 809.27Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 487] was performed to obtain 16.3 g of the target compound; HRMS [M]+: 809.27

[합성예 752] Mat 752의 합성[Synthesis Example 752] Synthesis of Mat 752

Figure pat00846
Figure pat00846

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 488]과 동일한 과정을 수행하여 목적 화합물 15.3g을 얻었다.; HRMS [M]+: 733.24Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 488] was performed to obtain 15.3 g of the target compound; HRMS [M]+: 733.24

[합성예 753] Mat 753의 합성[Synthesis Example 753] Synthesis of Mat 753

Figure pat00847
Figure pat00847

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 489]과 동일한 과정을 수행하여 목적 화합물 14.7g을 얻었다.; HRMS [M]+: 747.22Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 489] was performed to obtain 14.7 g of the target compound; HRMS [M]+: 747.22

[합성예 754] Mat 754의 합성[Synthesis Example 754] Synthesis of Mat 754

Figure pat00848
Figure pat00848

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 490]과 동일한 과정을 수행하여 목적 화합물 12.1g을 얻었다.; HRMS [M]+: 657.21Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 490] was performed to obtain 12.1 g of the target compound; HRMS [M]+: 657.21

[합성예 755] Mat 755의 합성[Synthesis Example 755] Synthesis of Mat 755

Figure pat00849
Figure pat00849

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 491]과 동일한 과정을 수행하여 목적 화합물 13.9g을 얻었다.; HRMS [M]+: 809.27Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 491] was performed to obtain 13.9 g of the target compound; HRMS [M]+: 809.27

[합성예 756] Mat 756의 합성[Synthesis Example 756] Synthesis of Mat 756

Figure pat00850
Figure pat00850

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 492]과 동일한 과정을 수행하여 목적 화합물 14.8g을 얻었다.; HRMS [M]+: 809.27Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 492] was performed to obtain 14.8 g of the target compound; HRMS [M]+: 809.27

[합성예 757] Mat 757의 합성[Synthesis Example 757] Synthesis of Mat 757

Figure pat00851
Figure pat00851

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 493]과 동일한 과정을 수행하여 목적 화합물 13.8g을 얻었다.; HRMS [M]+: 733.24Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 493] was performed to obtain 13.8 g of the target compound; HRMS [M]+: 733.24

[합성예 758] Mat 758의 합성[Synthesis Example 758] Synthesis of Mat 758

Figure pat00852
Figure pat00852

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 494]과 동일한 과정을 수행하여 목적 화합물 14.3g을 얻었다.; HRMS [M]+: 747.22Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 494] was performed to obtain 14.3 g of the target compound; HRMS [M]+: 747.22

[합성예 759] Mat 759의 합성[Synthesis Example 759] Synthesis of Mat 759

Figure pat00853
Figure pat00853

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 495]과 동일한 과정을 수행하여 목적 화합물 16.4g을 얻었다.; HRMS [M]+: 733.24Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 495] was performed to obtain 16.4 g of the target compound; HRMS [M]+: 733.24

[합성예 760] Mat 760의 합성[Synthesis Example 760] Synthesis of Mat 760

Figure pat00854
Figure pat00854

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 496]과 동일한 과정을 수행하여 목적 화합물 12.7g을 얻었다.; HRMS [M]+: 885.30Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 496] was performed to obtain 12.7 g of the target compound; HRMS [M]+: 885.30

[합성예 761] Mat 761의 합성[Synthesis Example 761] Synthesis of Mat 761

Figure pat00855
Figure pat00855

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 497]과 동일한 과정을 수행하여 목적 화합물 13.3g을 얻었다.; HRMS [M]+: 885.30Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 497] was performed to obtain 13.3 g of the target compound; HRMS [M]+: 885.30

[합성예 762] Mat 762의 합성[Synthesis Example 762] Synthesis of Mat 762

Figure pat00856
Figure pat00856

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 498]과 동일한 과정을 수행하여 목적 화합물 15.6g을 얻었다.; HRMS [M]+: 809.27Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 498] was performed to obtain 15.6 g of the target compound; HRMS [M]+: 809.27

[합성예 763] Mat 763의 합성[Synthesis Example 763] Synthesis of Mat 763

Figure pat00857
Figure pat00857

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 499]과 동일한 과정을 수행하여 목적 화합물 14.8g을 얻었다.; HRMS [M]+: 823.25Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 499] was performed to obtain 14.8 g of the target compound; HRMS [M]+: 823.25

[합성예 764] Mat 764의 합성[Synthesis Example 764] Synthesis of Mat 764

Figure pat00858
Figure pat00858

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 500]과 동일한 과정을 수행하여 목적 화합물 13.7g을 얻었다.; HRMS [M]+: 554.16Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 500] was performed to obtain 13.7 g of the target compound; HRMS [M]+: 554.16

[합성예 765] Mat 765의 합성[Synthesis Example 765] Synthesis of Mat 765

Figure pat00859
Figure pat00859

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 501]과 동일한 과정을 수행하여 목적 화합물 14.6g을 얻었다.; HRMS [M]+: 630.20Except for using [Preparation Example 12] as a reactant, 14.6 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 501]; HRMS [M]+: 630.20

[합성예 766] Mat 766의 합성[Synthesis Example 766] Synthesis of Mat 766

Figure pat00860
Figure pat00860

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 502]과 동일한 과정을 수행하여 목적 화합물 15.1g을 얻었다.; HRMS [M]+: 680.21Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 502] was performed to obtain 15.1 g of the target compound; HRMS [M]+: 680.21

[합성예 767] Mat 767의 합성[Synthesis Example 767] Synthesis of Mat 767

Figure pat00861
Figure pat00861

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 503]과 동일한 과정을 수행하여 목적 화합물 14.5g을 얻었다.; HRMS [M]+: 604.18Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 503] was performed to obtain 14.5 g of the target compound; HRMS [M]+: 604.18

[합성예 768] Mat 768의 합성[Synthesis Example 768] Synthesis of Mat 768

Figure pat00862
Figure pat00862

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 504]과 동일한 과정을 수행하여 목적 화합물 13.5g을 얻었다.; HRMS [M]+: 554.16Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 504] was performed to obtain 13.5 g of the target compound; HRMS [M]+: 554.16

[합성예 769] Mat 769의 합성[Synthesis Example 769] Synthesis of Mat 769

Figure pat00863
Figure pat00863

[준비예1] 5g(14.99mmol)과 5'-브로모-1,1':3',1''-테르페닐 5.1g(16.5mmol)에 자일렌 250 mL를 가하였다. Pd2(dba)3 0.68g (0.74mmol), Xphos 0.71g(1.5mmol), NaOtBu 3.6g(37.47mol)을 첨가 후 120에서 24시간 가열환류하였다. 상온으로 온도를 냉각하고 반응액에 염화암모늄 수용액 500 mL로 반응을 종결시켰다. 혼합액을 M.C 500 mL로 추출한 후, 증류수로 세척하였다. 얻어진 유기층을 무수 MgSO4로 건조하고, 감압증류하고 실리카겔 컬럼크로마토그래피로 정제하여 목적 화합물 6.99g(수율 83%)을 얻었다.[Preparation Example 1] 250 mL of xylene was added to 5 g (14.99 mmol) and 5.1 g (16.5 mmol) of 5'-bromo-1,1':3',1''-terphenyl. After adding 0.68g (0.74mmol) of Pd2(dba)3, 0.71g (1.5mmol) of Xphos, and 3.6g (37.47mol) of NaOtBu, the mixture was heated under reflux at 120°C for 24 hours. The temperature was cooled to room temperature, and the reaction was terminated with 500 mL of an aqueous ammonium chloride solution. The mixed solution was extracted with 500 mL of MC and washed with distilled water. The resulting organic layer was dried over anhydrous MgSO 4 , distilled under reduced pressure, and purified by silica gel column chromatography to obtain 6.99 g of the target compound (yield: 83%).

GC-Mass (이론치: 561.21 g/mol, 측정치: 561.68 g/mol)GC-Mass (Theory: 561.21 g/mol, Measured: 561.68 g/mol)

1H-NMR: 8.55 (d, 1H), 7.31(s, 2H), 8.29(d, 1H), 8.06~7.75 (m, 6H), 7.75 (m, 4H), 7.54~7.31 (m, 12H), 7.16 (t, 1H)1H-NMR: 8.55 (d, 1H), 7.31 (s, 2H), 8.29 (d, 1H), 8.06 to 7.75 (m, 6H), 7.75 (m, 4H), 7.54 to 7.31 (m, 12H), 7.16 (t, 1H)

[합성예 770] Mat 770의 합성[Synthesis Example 770] Synthesis of Mat 770

Figure pat00864
Figure pat00864

반응물로 5''-브로모-1,1':4',1'':3'',1''':4''',1''''-퀸쿼페닐을 사용한 것을 제외하고는 [합성예 769]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 714.28[ Synthesis Example 769] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 714.28

[합성예 771] Mat 771의 합성[Synthesis Example 771] Synthesis of Mat 771

Figure pat00865
Figure pat00865

반응물로 5''-브로모-1,1':3',1'':3'',1''':3''',1''''-퀸쿼페닐을 사용한 것을 제외하고는 [합성예 769]과 동일한 과정을 수행하여 목적 화합물 5.3g을 얻었다.; HRMS [M]+: 714.28[ Synthesis Example 769] was performed to obtain 5.3 g of the target compound; HRMS [M]+: 714.28

[합성예 772] Mat 772의 합성[Synthesis Example 772] Synthesis of Mat 772

Figure pat00866
Figure pat00866

반응물로 2,2'-(5-브로모-1,3-페닐렌)디나프탈렌을 사용한 것을 제외하고는 [합성예 769]과 동일한 과정을 수행하여 목적 화합물 4.4g을 얻었다.; HRMS [M]+: 662.24Except for using 2,2'-(5-bromo-1,3-phenylene)dinaphthalene as a reactant, the same procedure as in [Synthesis Example 769] was performed to obtain 4.4 g of the target compound; HRMS [M]+: 662.24

[합성예 773] Mat 773의 합성[Synthesis Example 773] Synthesis of Mat 773

Figure pat00867
Figure pat00867

반응물로 5'-브로모-1,1':3',1'':4'',1'''-쿼터페닐을 사용한 것을 제외하고는 [합성예 769]과 동일한 과정을 수행하여 목적 화합물 4.8g을 얻었다.; HRMS [M]+: 638.24The target compound was obtained by performing the same procedure as in [Synthesis Example 769], except that 5'-bromo-1,1': 3', 1'': 4'', 1'''-quaterphenyl was used as a reactant. 4.8 g was obtained; HRMS [M]+: 638.24

[합성예 774] Mat 774의 합성[Synthesis Example 774] Synthesis of Mat 774

Figure pat00868
Figure pat00868

반응물로 3-(5-브로모-[1,1'-비페닐]-3-일)디벤조[b,d]퓨란을 사용한 것을 제외하고는 [합성예 769]과 동일한 과정을 수행하여 목적 화합물 6.6g을 얻었다.; HRMS [M]+: 652.22The same procedure as in [Synthesis Example 769] was performed except that 3-(5-bromo-[1,1'-biphenyl]-3-yl)dibenzo[b,d]furan was used as the reactant. 6.6 g of compound was obtained; HRMS [M]+: 652.22

[합성예 775] Mat 775의 합성[Synthesis Example 775] Synthesis of Mat 775

Figure pat00869
Figure pat00869

반응물로 3-(5-브로모-[1,1'-비페닐]-3-일)디벤조[b,d]티오펜을 사용한 것을 제외하고는 [합성예 769]과 동일한 과정을 수행하여 목적 화합물 6.3g을 얻었다.; HRMS [M]+: 688.20The same procedure as in [Synthesis Example 769] was performed except that 3-(5-bromo-[1,1'-biphenyl]-3-yl)dibenzo[b,d]thiophene was used as a reactant. 6.3 g of the target compound was obtained; HRMS [M]+: 688.20

[합성예 776] Mat 776의 합성[Synthesis Example 776] Synthesis of Mat 776

Figure pat00870
Figure pat00870

반응물로 2-(5-브로모-[1,1'-비페닐]-3-일)-9,9-디메틸-9H-플루오렌을 사용한 것을 제외하고는 [합성예 769]과 동일한 과정을 수행하여 목적 화합물 5.9g을 얻었다.; HRMS [M]+: 678.28The same procedure as in [Synthesis Example 769] was performed except that 2-(5-bromo-[1,1'-biphenyl]-3-yl)-9,9-dimethyl-9H-fluorene was used as the reactant. This was carried out to obtain 5.9 g of the target compound; HRMS [M]+: 678.28

[합성예 777] Mat 777의 합성[Synthesis Example 777] Synthesis of Mat 777

Figure pat00871
Figure pat00871

반응물로 5'-브로모-1,1':3',1'':3'',1'''-쿼터페닐을 사용한 것을 제외하고는 [합성예 769]과 동일한 과정을 수행하여 목적 화합물 4.7g을 얻었다.; HRMS [M]+: 638.24The target compound was obtained in the same manner as in [Synthesis Example 769], except that 5'-bromo-1,1':3',1'':3'',1'''-quaterphenyl was used as a reactant. 4.7 g was obtained; HRMS [M]+: 638.24

[합성예 778] Mat 778의 합성[Synthesis Example 778] Synthesis of Mat 778

Figure pat00872
Figure pat00872

반응물로 4-(5-브로모-[1,1'-비페닐]-3-일)디벤조[b,d]퓨란을 사용한 것을 제외하고는 [합성예 769]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 652.22The same procedure as in [Synthesis Example 769] was performed except that 4-(5-bromo-[1,1'-biphenyl]-3-yl)dibenzo[b,d]furan was used as the reactant. 5.1 g of compound was obtained; HRMS [M]+: 652.22

[합성예 779] Mat 779의 합성[Synthesis Example 779] Synthesis of Mat 779

Figure pat00873
Figure pat00873

반응물로 2-(5-브로모-[1,1'-비페닐]-3-일)디벤조[b,d]퓨란을 사용한 것을 제외하고는 [합성예 769]과 동일한 과정을 수행하여 목적 화합물 5.7g을 얻었다.; HRMS [M]+: 652.22The same procedure as in [Synthesis Example 769] was performed except that 2-(5-bromo-[1,1'-biphenyl]-3-yl)dibenzo[b,d]furan was used as the reactant. 5.7 g of the compound was obtained; HRMS [M]+: 652.22

[합성예 780] Mat 780의 합성[Synthesis Example 780] Synthesis of Mat 780

Figure pat00874
Figure pat00874

반응물로 1-(5-브로모-[1,1'-비페닐]-3-일)디벤조[b,d]퓨란을 사용한 것을 제외하고는 [합성예 769]과 동일한 과정을 수행하여 목적 화합물 6.0g을 얻었다.; HRMS [M]+: 652.22The same procedure as in [Synthesis Example 769] was performed except that 1-(5-bromo-[1,1'-biphenyl]-3-yl)dibenzo[b,d]furan was used as the reactant. 6.0 g of compound was obtained; HRMS [M]+: 652.22

[합성예 781] Mat 781의 합성[Synthesis Example 781] Synthesis of Mat 781

Figure pat00875
Figure pat00875

반응물로 2-브로모트리페닐렌을 사용한 것을 제외하고는 [합성예 769]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 560.20Except for using 2-bromotriphenylene as a reactant, the same procedure as in [Synthesis Example 769] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 560.20

[합성예 782] Mat 782의 합성[Synthesis Example 782] Synthesis of Mat 782

Figure pat00876
Figure pat00876

반응물로 2-브로모페난트렌을 사용한 것을 제외하고는 [합성예 769]과 동일한 과정을 수행하여 목적 화합물 5.5g을 얻었다.; HRMS [M]+: 510.18Except for using 2-bromophenanthrene as a reactant, the same procedure as in [Synthesis Example 769] was performed to obtain 5.5 g of the target compound; HRMS [M]+: 510.18

[합성예 783] Mat 783의 합성[Synthesis Example 783] Synthesis of Mat 783

Figure pat00877
Figure pat00877

반응물로 2-(5-브로모-[1,1'-비페닐]-3-일)나프탈렌을 사용한 것을 제외하고는 [합성예 769]과 동일한 과정을 수행하여 목적 화합물 4.8g을 얻었다.; HRMS [M]+: 612.23Except for using 2-(5-bromo-[1,1'-biphenyl]-3-yl)naphthalene as a reactant, the same procedure as in [Synthesis Example 769] was performed to obtain 4.8 g of the target compound; HRMS [M]+: 612.23

[합성예 784] Mat 784의 합성[Synthesis Example 784] Synthesis of Mat 784

Figure pat00878
Figure pat00878

반응물로 9-(5'-브로모-[1,1':3',1''-테르페닐]-3-일)-9H-카바졸을 사용한 것을 제외하고는 [합성예 769]과 동일한 과정을 수행하여 목적 화합물 5.5g을 얻었다.; HRMS [M]+: 727.27Same as [Synthesis Example 769] except that 9-(5'-bromo-[1,1':3',1''-terphenyl]-3-yl)-9H-carbazole was used as the reactant. The process was carried out to obtain 5.5 g of the target compound; HRMS [M]+: 727.27

[합성예 785] Mat 785의 합성[Synthesis Example 785] Synthesis of Mat 785

Figure pat00879
Figure pat00879

반응물로 9-(5-브로모-[1,1'-비페닐]-3-일)-9H-카바졸을 사용한 것을 제외하고는 [합성예 769]과 동일한 과정을 수행하여 목적 화합물 5.2g을 얻었다.; HRMS [M]+: 651.245.2 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 769], except that 9-(5-bromo-[1,1'-biphenyl]-3-yl)-9H-carbazole was used as a reactant. got .; HRMS [M]+: 651.24

[합성예 786] Mat 786의 합성[Synthesis Example 786] Synthesis of Mat 786

Figure pat00880
Figure pat00880

반응물로 3,5-디브로모-1,1'-비페닐을 사용한 것을 제외하고는 [합성예 769]과 동일한 과정을 수행하여 목적 화합물 7.6g을 얻었다.; HRMS [M]+: 817.287.6 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 769], except that 3,5-dibromo-1,1'-biphenyl was used as a reactant; HRMS [M]+: 817.28

* [합성예 787] Mat 787의 합성 * [Synthesis Example 787] Synthesis of Mat 787

Figure pat00881
Figure pat00881

반응물로 5''-브로모-1,1':3',1'':3'',1''':4''',1''''-퀸쿼페닐을 사용한 것을 제외하고는 [합성예 769]과 동일한 과정을 수행하여 목적 화합물 5.8g을 얻었다.; HRMS [M]+: 714.28[ Synthesis Example 769] was performed to obtain 5.8 g of the target compound; HRMS [M]+: 714.28

[합성예 788] Mat 788의 합성[Synthesis Example 788] Synthesis of Mat 788

Figure pat00882
Figure pat00882

반응물로 2-(5-브로모-[1,1':3',1''-테르페닐]-3-일)나프탈렌을 사용한 것을 제외하고는 [합성예 769]과 동일한 과정을 수행하여 목적 화합물 6.1g을 얻었다.; HRMS [M]+: 688.26The same procedure as in [Synthesis Example 769] was carried out except that 2-(5-bromo-[1,1':3',1''-terphenyl]-3-yl)naphthalene was used as the reactant. 6.1 g of compound was obtained; HRMS [M]+: 688.26

[합성예 789] Mat 789의 합성[Synthesis Example 789] Synthesis of Mat 789

Figure pat00883
Figure pat00883

반응물로 9-(5-브로모-[1,1':4',1''-테르페닐]-3-일)-9H-카바졸을 사용한 것을 제외하고는 [합성예 769]과 동일한 과정을 수행하여 목적 화합물 5.7g을 얻었다.; HRMS [M]+: 727.27Same procedure as in [Synthesis Example 769] except that 9-(5-bromo-[1,1':4',1''-terphenyl]-3-yl)-9H-carbazole was used as the reactant. was carried out to obtain 5.7 g of the target compound; HRMS [M]+: 727.27

[합성예 790] Mat 790의 합성[Synthesis Example 790] Synthesis of Mat 790

Figure pat00884
Figure pat00884

반응물로 9-(3-브로모-5-(나프탈렌-2-일)페닐)-9H-카바졸을 사용한 것을 제외하고는 [합성예 769]과 동일한 과정을 수행하여 목적 화합물 7.1g을 얻었다.; HRMS [M]+: 701.257.1 g of the target compound was obtained in the same manner as in Synthesis Example 769, except that 9-(3-bromo-5-(naphthalen-2-yl)phenyl)-9H-carbazole was used as a reactant. ; HRMS [M]+: 701.25

[합성예 791] Mat 791의 합성[Synthesis Example 791] Synthesis of Mat 791

Figure pat00885
Figure pat00885

반응물로 2-(3-클로로페닐)트리페닐렌을 사용한 것을 제외하고는 [합성예 769]과 동일한 과정을 수행하여 목적 화합물 6.5g을 얻었다.; HRMS [M]+: 636.236.5 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 769], except that 2-(3-chlorophenyl)triphenylene was used as a reactant; HRMS [M]+: 636.23

[합성예 792] Mat 792의 합성[Synthesis Example 792] Synthesis of Mat 792

Figure pat00886
Figure pat00886

반응물로 3-브로모-5'-페닐-1,1':3',1''-테르페닐을 사용한 것을 제외하고는 [합성예 769]과 동일한 과정을 수행하여 목적 화합물 5.8g을 얻었다.; HRMS [M]+: 638.245.8 g of the target compound was obtained by performing the same procedure as in Synthesis Example 769, except that 3-bromo-5'-phenyl-1,1':3',1''-terphenyl was used as a reactant. ; HRMS [M]+: 638.24

[합성예 793] Mat 793의 합성[Synthesis Example 793] Synthesis of Mat 793

Figure pat00887
Figure pat00887

반응물로 3-브로모-9-페닐-9H-카바졸을 사용한 것을 제외하고는 [합성예 769]과 동일한 과정을 수행하여 목적 화합물 4.7g을 얻었다.; HRMS [M]+: 575.21Except for using 3-bromo-9-phenyl-9H-carbazole as a reactant, the same procedure as in [Synthesis Example 769] was performed to obtain 4.7 g of the target compound; HRMS [M]+: 575.21

[합성예 794] Mat 794의 합성[Synthesis Example 794] Synthesis of Mat 794

Figure pat00888
Figure pat00888

반응물로 3-(3-클로로페닐)-9-페닐-9H-카바졸을 사용한 것을 제외하고는 [합성예 769]과 동일한 과정을 수행하여 목적 화합물 6.8g을 얻었다.; HRMS [M]+: 651.24Except for using 3-(3-chlorophenyl)-9-phenyl-9H-carbazole as a reactant, the same procedure as in [Synthesis Example 769] was performed to obtain 6.8 g of the target compound; HRMS [M]+: 651.24

[합성예 795] Mat 795의 합성[Synthesis Example 795] Synthesis of Mat 795

Figure pat00889
Figure pat00889

반응물로 3,5-디브로모-1,1':4',1''-테르페닐을 사용한 것을 제외하고는 [합성예 769]과 동일한 과정을 수행하여 목적 화합물 12.9g을 얻었다.; HRMS [M]+: 893.3112.9 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 769], except that 3,5-dibromo-1,1':4',1''-terphenyl was used as a reactant; HRMS [M]+: 893.31

[합성예 796] Mat 796의 합성[Synthesis Example 796] Synthesis of Mat 796

Figure pat00890
Figure pat00890

반응물로 3,5-디브로모-1,1':3',1''-테르페닐을 사용한 것을 제외하고는 [합성예 769]과 동일한 과정을 수행하여 목적 화합물 11.4g을 얻었다.; HRMS [M]+: 893.3111.4 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 769], except that 3,5-dibromo-1,1':3',1''-terphenyl was used as a reactant; HRMS [M]+: 893.31

[합성예 797] Mat 797의 합성[Synthesis Example 797] Synthesis of Mat 797

Figure pat00891
Figure pat00891

반응물로 9,9'-(5-브로모-1,3-페닐렌)비스(9H-카바졸)을 사용한 것을 제외하고는 [합성예 769]과 동일한 과정을 수행하여 목적 화합물 10.2g을 얻었다.; HRMS [M]+: 740.2710.2 g of the target compound was obtained by performing the same procedure as in Synthesis Example 769, except that 9,9′-(5-bromo-1,3-phenylene)bis(9H-carbazole) was used as a reactant. .; HRMS [M]+: 740.27

[합성예 798] Mat 798의 합성[Synthesis Example 798] Synthesis of Mat 798

Figure pat00892
Figure pat00892

반응물로 9-(3,5-디브로모페닐)-9H-카바졸을 사용한 것을 제외하고는 [합성예 769]과 동일한 과정을 수행하여 목적 화합물 13.5g을 얻었다.; HRMS [M]+: 906.3113.5 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 769] except that 9-(3,5-dibromophenyl)-9H-carbazole was used as a reactant; HRMS [M]+: 906.31

[합성예 799] Mat 799의 합성[Synthesis Example 799] Synthesis of Mat 799

Figure pat00893
Figure pat00893

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 769]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 562.21Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 769] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 562.21

[합성예 800] Mat 800의 합성[Synthesis Example 800] Synthesis of Mat 800

Figure pat00894
Figure pat00894

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 770]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 714.28Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 770] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 714.28

[합성예 801] Mat 801의 합성[Synthesis Example 801] Synthesis of Mat 801

Figure pat00895
Figure pat00895

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 771]과 동일한 과정을 수행하여 목적 화합물 5.3g을 얻었다.; HRMS [M]+: 714.28Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 771] was performed to obtain 5.3 g of the target compound; HRMS [M]+: 714.28

[합성예 802] Mat 802의 합성[Synthesis Example 802] Synthesis of Mat 802

Figure pat00896
Figure pat00896

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 772]과 동일한 과정을 수행하여 목적 화합물 4.4g을 얻었다.; HRMS [M]+: 662.24Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 772] was performed to obtain 4.4 g of the target compound; HRMS [M]+: 662.24

[합성예 803] Mat 803의 합성[Synthesis Example 803] Synthesis of Mat 803

Figure pat00897
Figure pat00897

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 773]과 동일한 과정을 수행하여 목적 화합물 4.8g을 얻었다.; HRMS [M]+: 638.24Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 773] was performed to obtain 4.8 g of the target compound; HRMS [M]+: 638.24

[합성예 804] Mat 804의 합성[Synthesis Example 804] Synthesis of Mat 804

Figure pat00898
Figure pat00898

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 774]과 동일한 과정을 수행하여 목적 화합물 6.6g을 얻었다.; HRMS [M]+: 652.22Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 774] was performed to obtain 6.6 g of the target compound; HRMS [M]+: 652.22

[합성예 805] Mat 805의 합성[Synthesis Example 805] Synthesis of Mat 805

Figure pat00899
Figure pat00899

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 775]과 동일한 과정을 수행하여 목적 화합물 6.3g을 얻었다.; HRMS [M]+: 688.20Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 775] was performed to obtain 6.3 g of the target compound; HRMS [M]+: 688.20

[합성예 806] Mat 806의 합성[Synthesis Example 806] Synthesis of Mat 806

Figure pat00900
Figure pat00900

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 776]과 동일한 과정을 수행하여 목적 화합물 5.9g을 얻었다.; HRMS [M]+: 678.28Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 776] was performed to obtain 5.9 g of the target compound; HRMS [M]+: 678.28

[합성예 807] Mat 807의 합성[Synthesis Example 807] Synthesis of Mat 807

Figure pat00901
Figure pat00901

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 777]과 동일한 과정을 수행하여 목적 화합물 4.7g을 얻었다.; HRMS [M]+: 638.24Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 777] was performed to obtain 4.7 g of the target compound; HRMS [M]+: 638.24

[합성예 808] Mat 808의 합성[Synthesis Example 808] Synthesis of Mat 808

Figure pat00902
Figure pat00902

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 778]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 652.22Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 778] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 652.22

[합성예 809] Mat 809의 합성[Synthesis Example 809] Synthesis of Mat 809

Figure pat00903
Figure pat00903

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 779]과 동일한 과정을 수행하여 목적 화합물 5.7g을 얻었다.; HRMS [M]+: 652.22Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 779] was performed to obtain 5.7 g of the target compound; HRMS [M]+: 652.22

[합성예 810] Mat 810의 합성[Synthesis Example 810] Synthesis of Mat 810

Figure pat00904
Figure pat00904

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 780]과 동일한 과정을 수행하여 목적 화합물 6.0g을 얻었다.; HRMS [M]+: 652.22Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 780] was performed to obtain 6.0 g of the target compound; HRMS [M]+: 652.22

[합성예 811] Mat 811의 합성[Synthesis Example 811] Synthesis of Mat 811

Figure pat00905
Figure pat00905

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 781]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 560.20Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 781] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 560.20

[합성예 812] Mat 812의 합성[Synthesis Example 812] Synthesis of Mat 812

Figure pat00906
Figure pat00906

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 782]과 동일한 과정을 수행하여 목적 화합물 5.5g을 얻었다.; HRMS [M]+: 510.18Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 782] was performed to obtain 5.5 g of the target compound; HRMS [M]+: 510.18

[합성예 813] Mat 813의 합성[Synthesis Example 813] Synthesis of Mat 813

Figure pat00907
Figure pat00907

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 783]과 동일한 과정을 수행하여 목적 화합물 4.8g을 얻었다.; HRMS [M]+: 612.23Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 783] was performed to obtain 4.8 g of the target compound; HRMS [M]+: 612.23

[합성예 814] Mat 814의 합성[Synthesis Example 814] Synthesis of Mat 814

Figure pat00908
Figure pat00908

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 784]과 동일한 과정을 수행하여 목적 화합물 5.5g을 얻었다.; HRMS [M]+: 727.27Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 784] was performed to obtain 5.5 g of the target compound; HRMS [M]+: 727.27

[합성예 815] Mat 815의 합성[Synthesis Example 815] Synthesis of Mat 815

Figure pat00909
Figure pat00909

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 785]과 동일한 과정을 수행하여 목적 화합물 5.2g을 얻었다.; HRMS [M]+: 651.24Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 785] was performed to obtain 5.2 g of the target compound; HRMS [M]+: 651.24

[합성예 816] Mat 816의 합성[Synthesis Example 816] Synthesis of Mat 816

Figure pat00910
Figure pat00910

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 786]과 동일한 과정을 수행하여 목적 화합물 7.6g을 얻었다.; HRMS [M]+: 817.28Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 786] was performed to obtain 7.6 g of the target compound; HRMS [M]+: 817.28

[합성예 817] Mat 817의 합성[Synthesis Example 817] Synthesis of Mat 817

Figure pat00911
Figure pat00911

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 787]과 동일한 과정을 수행하여 목적 화합물 5.8g을 얻었다.; HRMS [M]+: 714.28Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 787] was performed to obtain 5.8 g of the target compound; HRMS [M]+: 714.28

[합성예 818] Mat 818의 합성[Synthesis Example 818] Synthesis of Mat 818

Figure pat00912
Figure pat00912

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 788]과 동일한 과정을 수행하여 목적 화합물 6.1g을 얻었다.; HRMS [M]+: 688.26Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 788] was performed to obtain 6.1 g of the target compound; HRMS [M]+: 688.26

[합성예 819] Mat 819의 합성[Synthesis Example 819] Synthesis of Mat 819

Figure pat00913
Figure pat00913

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 789]과 동일한 과정을 수행하여 목적 화합물 5.7g을 얻었다.; HRMS [M]+: 727.27Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 789] was performed to obtain 5.7 g of the target compound; HRMS [M]+: 727.27

[합성예 820] Mat 820의 합성[Synthesis Example 820] Synthesis of Mat 820

Figure pat00914
Figure pat00914

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 790]과 동일한 과정을 수행하여 목적 화합물 7.1g을 얻었다.; HRMS [M]+: 701.25Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 790] was performed to obtain 7.1 g of the target compound; HRMS [M]+: 701.25

[합성예 821] Mat 821의 합성[Synthesis Example 821] Synthesis of Mat 821

Figure pat00915
Figure pat00915

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 791]과 동일한 과정을 수행하여 목적 화합물 6.5g을 얻었다.; HRMS [M]+: 636.23Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 791] was performed to obtain 6.5 g of the target compound; HRMS [M]+: 636.23

[합성예 822] Mat 822의 합성[Synthesis Example 822] Synthesis of Mat 822

Figure pat00916
Figure pat00916

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 792]과 동일한 과정을 수행하여 목적 화합물 5.8g을 얻었다.; HRMS [M]+: 638.24Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 792] was performed to obtain 5.8 g of the target compound; HRMS [M]+: 638.24

[합성예 823] Mat 823의 합성[Synthesis Example 823] Synthesis of Mat 823

Figure pat00917
Figure pat00917

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 793]과 동일한 과정을 수행하여 목적 화합물 4.7g을 얻었다.; HRMS [M]+: 575.21Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 793] was performed to obtain 4.7 g of the target compound; HRMS [M]+: 575.21

[합성예 824] Mat 824의 합성[Synthesis Example 824] Synthesis of Mat 824

Figure pat00918
Figure pat00918

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 794]과 동일한 과정을 수행하여 목적 화합물 6.8g을 얻었다.; HRMS [M]+: 651.24Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 794] was performed to obtain 6.8 g of the target compound; HRMS [M]+: 651.24

[합성예 825] Mat 825의 합성[Synthesis Example 825] Synthesis of Mat 825

Figure pat00919
Figure pat00919

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 795]과 동일한 과정을 수행하여 목적 화합물 12.9g을 얻었다.; HRMS [M]+: 893.31Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 795] was performed to obtain 12.9 g of the target compound; HRMS [M]+: 893.31

[합성예 826] Mat 826의 합성[Synthesis Example 826] Synthesis of Mat 826

Figure pat00920
Figure pat00920

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 796]과 동일한 과정을 수행하여 목적 화합물 11.4g을 얻었다.; HRMS [M]+: 893.31Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 796] was performed to obtain 11.4 g of the target compound; HRMS [M]+: 893.31

[합성예 827] Mat 827의 합성[Synthesis Example 827] Synthesis of Mat 827

Figure pat00921
Figure pat00921

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 797]과 동일한 과정을 수행하여 목적 화합물 10.2g을 얻었다.; HRMS [M]+: 740.27Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 797] was performed to obtain 10.2 g of the target compound; HRMS [M]+: 740.27

[합성예 828] Mat 828의 합성[Synthesis Example 828] Synthesis of Mat 828

Figure pat00922
Figure pat00922

반응물로 [준비예2]을 사용한 것을 제외하고는 [합성예 798]과 동일한 과정을 수행하여 목적 화합물 13.5g을 얻었다.; HRMS [M]+: 906.31Except for using [Preparation Example 2] as a reactant, the same procedure as in [Synthesis Example 798] was performed to obtain 13.5 g of the target compound; HRMS [M]+: 906.31

[합성예 829] Mat 829의 합성[Synthesis Example 829] Synthesis of Mat 829

Figure pat00923
Figure pat00923

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 769]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 562.21Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 769] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 562.21

[합성예 830] Mat 830의 합성[Synthesis Example 830] Synthesis of Mat 830

Figure pat00924
Figure pat00924

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 770]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 714.28Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 770] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 714.28

[합성예 831] Mat 831의 합성[Synthesis Example 831] Synthesis of Mat 831

Figure pat00925
Figure pat00925

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 771]과 동일한 과정을 수행하여 목적 화합물 5.3g을 얻었다.; HRMS [M]+: 714.28Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 771] was performed to obtain 5.3 g of the target compound; HRMS [M]+: 714.28

[합성예 832] Mat 832의 합성[Synthesis Example 832] Synthesis of Mat 832

Figure pat00926
Figure pat00926

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 772]과 동일한 과정을 수행하여 목적 화합물 4.4g을 얻었다.; HRMS [M]+: 662.24Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 772] was performed to obtain 4.4 g of the target compound; HRMS [M]+: 662.24

[합성예 833] Mat 833의 합성[Synthesis Example 833] Synthesis of Mat 833

Figure pat00927
Figure pat00927

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 773]과 동일한 과정을 수행하여 목적 화합물 4.8g을 얻었다.; HRMS [M]+: 638.24Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 773] was performed to obtain 4.8 g of the target compound; HRMS [M]+: 638.24

[합성예 834] Mat 834의 합성[Synthesis Example 834] Synthesis of Mat 834

Figure pat00928
Figure pat00928

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 774]과 동일한 과정을 수행하여 목적 화합물 6.6g을 얻었다.; HRMS [M]+: 652.22Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 774] was performed to obtain 6.6 g of the target compound; HRMS [M]+: 652.22

[합성예 835] Mat 835의 합성[Synthesis Example 835] Synthesis of Mat 835

Figure pat00929
Figure pat00929

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 775]과 동일한 과정을 수행하여 목적 화합물 6.3g을 얻었다.; HRMS [M]+: 688.20Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 775] was performed to obtain 6.3 g of the target compound; HRMS [M]+: 688.20

[합성예 836] Mat 836의 합성[Synthesis Example 836] Synthesis of Mat 836

Figure pat00930
Figure pat00930

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 776]과 동일한 과정을 수행하여 목적 화합물 5.9g을 얻었다.; HRMS [M]+: 678.28Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 776] was performed to obtain 5.9 g of the target compound; HRMS [M]+: 678.28

[합성예 837] Mat 837의 합성[Synthesis Example 837] Synthesis of Mat 837

Figure pat00931
Figure pat00931

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 777]과 동일한 과정을 수행하여 목적 화합물 4.7g을 얻었다.; HRMS [M]+: 638.24Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 777] was performed to obtain 4.7 g of the target compound; HRMS [M]+: 638.24

[합성예 838] Mat 838의 합성[Synthesis Example 838] Synthesis of Mat 838

Figure pat00932
Figure pat00932

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 778]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 652.22Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 778] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 652.22

[합성예 839] Mat 839의 합성[Synthesis Example 839] Synthesis of Mat 839

Figure pat00933
Figure pat00933

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 779]과 동일한 과정을 수행하여 목적 화합물 5.7g을 얻었다.; HRMS [M]+: 652.22Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 779] was performed to obtain 5.7 g of the target compound; HRMS [M]+: 652.22

[합성예 840] Mat 840의 합성[Synthesis Example 840] Synthesis of Mat 840

Figure pat00934
Figure pat00934

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 780]과 동일한 과정을 수행하여 목적 화합물 6.0g을 얻었다.; HRMS [M]+: 652.22Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 780] was performed to obtain 6.0 g of the target compound; HRMS [M]+: 652.22

[합성예 841] Mat 841의 합성[Synthesis Example 841] Synthesis of Mat 841

Figure pat00935
Figure pat00935

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 781]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 560.20Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 781] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 560.20

[합성예 842] Mat 842의 합성[Synthesis Example 842] Synthesis of Mat 842

Figure pat00936
Figure pat00936

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 782]과 동일한 과정을 수행하여 목적 화합물 5.5g을 얻었다.; HRMS [M]+: 510.18Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 782] was performed to obtain 5.5 g of the target compound; HRMS [M]+: 510.18

[합성예 843] Mat 843의 합성[Synthesis Example 843] Synthesis of Mat 843

Figure pat00937
Figure pat00937

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 783]과 동일한 과정을 수행하여 목적 화합물 4.8g을 얻었다.; HRMS [M]+: 612.23Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 783] was performed to obtain 4.8 g of the target compound; HRMS [M]+: 612.23

[합성예 844] Mat 844의 합성[Synthesis Example 844] Synthesis of Mat 844

Figure pat00938
Figure pat00938

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 784]과 동일한 과정을 수행하여 목적 화합물 5.5g을 얻었다.; HRMS [M]+: 727.27Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 784] was performed to obtain 5.5 g of the target compound; HRMS [M]+: 727.27

[합성예 845] Mat 845의 합성[Synthesis Example 845] Synthesis of Mat 845

Figure pat00939
Figure pat00939

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 785]과 동일한 과정을 수행하여 목적 화합물 5.2g을 얻었다.; HRMS [M]+: 651.24Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 785] was performed to obtain 5.2 g of the target compound; HRMS [M]+: 651.24

[합성예 846] Mat 846의 합성[Synthesis Example 846] Synthesis of Mat 846

Figure pat00940
Figure pat00940

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 786]과 동일한 과정을 수행하여 목적 화합물 7.6g을 얻었다.; HRMS [M]+: 817.28Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 786] was performed to obtain 7.6 g of the target compound; HRMS [M]+: 817.28

[합성예 847] Mat 847의 합성[Synthesis Example 847] Synthesis of Mat 847

Figure pat00941
Figure pat00941

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 787]과 동일한 과정을 수행하여 목적 화합물 5.8g을 얻었다.; HRMS [M]+: 714.28Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 787] was performed to obtain 5.8 g of the target compound; HRMS [M]+: 714.28

[합성예 848] Mat 848의 합성[Synthesis Example 848] Synthesis of Mat 848

Figure pat00942
Figure pat00942

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 788]과 동일한 과정을 수행하여 목적 화합물 6.1g을 얻었다.; HRMS [M]+: 688.26Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 788] was performed to obtain 6.1 g of the target compound; HRMS [M]+: 688.26

[합성예 849] Mat 849의 합성[Synthesis Example 849] Synthesis of Mat 849

Figure pat00943
Figure pat00943

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 789]과 동일한 과정을 수행하여 목적 화합물 5.7g을 얻었다.; HRMS [M]+: 727.27Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 789] was performed to obtain 5.7 g of the target compound; HRMS [M]+: 727.27

[합성예 850] Mat 850의 합성[Synthesis Example 850] Synthesis of Mat 850

Figure pat00944
Figure pat00944

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 790]과 동일한 과정을 수행하여 목적 화합물 7.1g을 얻었다.; HRMS [M]+: 701.25Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 790] was performed to obtain 7.1 g of the target compound; HRMS [M]+: 701.25

[합성예 851] Mat 851의 합성[Synthesis Example 851] Synthesis of Mat 851

Figure pat00945
Figure pat00945

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 791]과 동일한 과정을 수행하여 목적 화합물 6.5g을 얻었다.; HRMS [M]+: 636.23Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 791] was performed to obtain 6.5 g of the target compound; HRMS [M]+: 636.23

[합성예 852] Mat 852의 합성[Synthesis Example 852] Synthesis of Mat 852

Figure pat00946
Figure pat00946

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 792]과 동일한 과정을 수행하여 목적 화합물 5.8g을 얻었다.; HRMS [M]+: 638.24Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 792] was performed to obtain 5.8 g of the target compound; HRMS [M]+: 638.24

[합성예 853] Mat 853의 합성[Synthesis Example 853] Synthesis of Mat 853

Figure pat00947
Figure pat00947

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 793]과 동일한 과정을 수행하여 목적 화합물 4.7g을 얻었다.; HRMS [M]+: 575.21Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 793] was performed to obtain 4.7 g of the target compound; HRMS [M]+: 575.21

[합성예 854] Mat 854의 합성[Synthesis Example 854] Synthesis of Mat 854

Figure pat00948
Figure pat00948

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 794]과 동일한 과정을 수행하여 목적 화합물 6.8g을 얻었다.; HRMS [M]+: 651.24Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 794] was performed to obtain 6.8 g of the target compound; HRMS [M]+: 651.24

[합성예 855] Mat 855의 합성[Synthesis Example 855] Synthesis of Mat 855

Figure pat00949
Figure pat00949

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 795]과 동일한 과정을 수행하여 목적 화합물 12.9g을 얻었다.; HRMS [M]+: 893.31Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 795] was performed to obtain 12.9 g of the target compound; HRMS [M]+: 893.31

[합성예 856] Mat 856의 합성[Synthesis Example 856] Synthesis of Mat 856

Figure pat00950
Figure pat00950

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 796]과 동일한 과정을 수행하여 목적 화합물 11.4g을 얻었다.; HRMS [M]+: 893.31Except for using [Preparation Example 3] as a reactant, 11.4 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 796]; HRMS [M]+: 893.31

[합성예 857] Mat 857의 합성[Synthesis Example 857] Synthesis of Mat 857

Figure pat00951
Figure pat00951

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 797]과 동일한 과정을 수행하여 목적 화합물 10.2g을 얻었다.; HRMS [M]+: 740.27Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 797] was performed to obtain 10.2 g of the target compound; HRMS [M]+: 740.27

[합성예 858] Mat 858의 합성[Synthesis Example 858] Synthesis of Mat 858

Figure pat00952
Figure pat00952

반응물로 [준비예3]을 사용한 것을 제외하고는 [합성예 798]과 동일한 과정을 수행하여 목적 화합물 13.5g을 얻었다.; HRMS [M]+: 906.31Except for using [Preparation Example 3] as a reactant, the same procedure as in [Synthesis Example 798] was performed to obtain 13.5 g of the target compound; HRMS [M]+: 906.31

[합성예 859] Mat 859의 합성[Synthesis Example 859] Synthesis of Mat 859

Figure pat00953
Figure pat00953

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 769]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 562.21Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 769] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 562.21

[합성예 860] Mat 860의 합성[Synthesis Example 860] Synthesis of Mat 860

Figure pat00954
Figure pat00954

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 770]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 714.28Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 770] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 714.28

[합성예 861] Mat 861의 합성[Synthesis Example 861] Synthesis of Mat 861

Figure pat00955
Figure pat00955

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 771]과 동일한 과정을 수행하여 목적 화합물 5.3g을 얻었다.; HRMS [M]+: 714.28Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 771] was performed to obtain 5.3 g of the target compound; HRMS [M]+: 714.28

[합성예 862] Mat 862의 합성[Synthesis Example 862] Synthesis of Mat 862

Figure pat00956
Figure pat00956

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 772]과 동일한 과정을 수행하여 목적 화합물 4.4g을 얻었다.; HRMS [M]+: 662.24Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 772] was performed to obtain 4.4 g of the target compound; HRMS [M]+: 662.24

[합성예 863] Mat 863의 합성[Synthesis Example 863] Synthesis of Mat 863

Figure pat00957
Figure pat00957

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 773]과 동일한 과정을 수행하여 목적 화합물 4.8g을 얻었다.; HRMS [M]+: 638.24Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 773] was performed to obtain 4.8 g of the target compound; HRMS [M]+: 638.24

[합성예 864] Mat 864의 합성[Synthesis Example 864] Synthesis of Mat 864

Figure pat00958
Figure pat00958

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 774]과 동일한 과정을 수행하여 목적 화합물 6.6g을 얻었다.; HRMS [M]+: 652.22Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 774] was performed to obtain 6.6 g of the target compound; HRMS [M]+: 652.22

[합성예 865] Mat 865의 합성[Synthesis Example 865] Synthesis of Mat 865

Figure pat00959
Figure pat00959

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 775]과 동일한 과정을 수행하여 목적 화합물 6.3g을 얻었다.; HRMS [M]+: 688.20Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 775] was performed to obtain 6.3 g of the target compound; HRMS [M]+: 688.20

[합성예 866] Mat 866의 합성[Synthesis Example 866] Synthesis of Mat 866

Figure pat00960
Figure pat00960

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 776]과 동일한 과정을 수행하여 목적 화합물 5.9g을 얻었다.; HRMS [M]+: 678.28Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 776] was performed to obtain 5.9 g of the target compound; HRMS [M]+: 678.28

[합성예 867] Mat 867의 합성[Synthesis Example 867] Synthesis of Mat 867

Figure pat00961
Figure pat00961

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 777]과 동일한 과정을 수행하여 목적 화합물 4.7g을 얻었다.; HRMS [M]+: 638.24Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 777] was performed to obtain 4.7 g of the target compound; HRMS [M]+: 638.24

[합성예 868] Mat 868의 합성[Synthesis Example 868] Synthesis of Mat 868

Figure pat00962
Figure pat00962

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 778]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 652.22Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 778] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 652.22

[합성예 869] Mat 869의 합성[Synthesis Example 869] Synthesis of Mat 869

Figure pat00963
Figure pat00963

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 779]과 동일한 과정을 수행하여 목적 화합물 5.7g을 얻었다.; HRMS [M]+: 652.22Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 779] was performed to obtain 5.7 g of the target compound; HRMS [M]+: 652.22

[합성예 870] Mat 870의 합성[Synthesis Example 870] Synthesis of Mat 870

Figure pat00964
Figure pat00964

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 780]과 동일한 과정을 수행하여 목적 화합물 6.0g을 얻었다.; HRMS [M]+: 652.22Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 780] was performed to obtain 6.0 g of the target compound; HRMS [M]+: 652.22

[합성예 871] Mat 871의 합성[Synthesis Example 871] Synthesis of Mat 871

Figure pat00965
Figure pat00965

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 781]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 560.20Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 781] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 560.20

[합성예 872] Mat 872의 합성[Synthesis Example 872] Synthesis of Mat 872

Figure pat00966
Figure pat00966

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 782]과 동일한 과정을 수행하여 목적 화합물 5.5g을 얻었다.; HRMS [M]+: 510.18Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 782] was performed to obtain 5.5 g of the target compound; HRMS [M]+: 510.18

[합성예 873] Mat 873의 합성[Synthesis Example 873] Synthesis of Mat 873

Figure pat00967
Figure pat00967

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 783]과 동일한 과정을 수행하여 목적 화합물 4.8g을 얻었다.; HRMS [M]+: 612.23Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 783] was performed to obtain 4.8 g of the target compound; HRMS [M]+: 612.23

[합성예 874] Mat 874의 합성[Synthesis Example 874] Synthesis of Mat 874

Figure pat00968
Figure pat00968

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 784]과 동일한 과정을 수행하여 목적 화합물 5.5g을 얻었다.; HRMS [M]+: 727.27Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 784] was performed to obtain 5.5 g of the target compound; HRMS [M]+: 727.27

[합성예 875] Mat 875의 합성[Synthesis Example 875] Synthesis of Mat 875

Figure pat00969
Figure pat00969

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 785]과 동일한 과정을 수행하여 목적 화합물 5.2g을 얻었다.; HRMS [M]+: 651.24Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 785] was performed to obtain 5.2 g of the target compound; HRMS [M]+: 651.24

[합성예 876] Mat 876의 합성[Synthesis Example 876] Synthesis of Mat 876

Figure pat00970
Figure pat00970

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 786]과 동일한 과정을 수행하여 목적 화합물 7.6g을 얻었다.; HRMS [M]+: 817.28Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 786] was performed to obtain 7.6 g of the target compound; HRMS [M]+: 817.28

[합성예 877] Mat 877의 합성[Synthesis Example 877] Synthesis of Mat 877

Figure pat00971
Figure pat00971

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 787]과 동일한 과정을 수행하여 목적 화합물 5.8g을 얻었다.; HRMS [M]+: 714.28Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 787] was performed to obtain 5.8 g of the target compound; HRMS [M]+: 714.28

[합성예 878] Mat 878의 합성[Synthesis Example 878] Synthesis of Mat 878

Figure pat00972
Figure pat00972

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 788]과 동일한 과정을 수행하여 목적 화합물 6.1g을 얻었다.; HRMS [M]+: 688.26Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 788] was performed to obtain 6.1 g of the target compound; HRMS [M]+: 688.26

[합성예 879] Mat 879의 합성[Synthesis Example 879] Synthesis of Mat 879

Figure pat00973
Figure pat00973

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 789]과 동일한 과정을 수행하여 목적 화합물 5.7g을 얻었다.; HRMS [M]+: 727.27Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 789] was performed to obtain 5.7 g of the target compound; HRMS [M]+: 727.27

[합성예 880] Mat 880의 합성[Synthesis Example 880] Synthesis of Mat 880

Figure pat00974
Figure pat00974

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 790]과 동일한 과정을 수행하여 목적 화합물 7.1g을 얻었다.; HRMS [M]+: 701.25Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 790] was performed to obtain 7.1 g of the target compound; HRMS [M]+: 701.25

[합성예 881] Mat 881의 합성[Synthesis Example 881] Synthesis of Mat 881

Figure pat00975
Figure pat00975

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 791]과 동일한 과정을 수행하여 목적 화합물 6.5g을 얻었다.; HRMS [M]+: 636.23Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 791] was performed to obtain 6.5 g of the target compound; HRMS [M]+: 636.23

[합성예 882] Mat 882의 합성[Synthesis Example 882] Synthesis of Mat 882

Figure pat00976
Figure pat00976

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 792]과 동일한 과정을 수행하여 목적 화합물 5.8g을 얻었다.; HRMS [M]+: 638.24Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 792] was performed to obtain 5.8 g of the target compound; HRMS [M]+: 638.24

[합성예 883] Mat 883의 합성[Synthesis Example 883] Synthesis of Mat 883

Figure pat00977
Figure pat00977

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 793]과 동일한 과정을 수행하여 목적 화합물 4.7g을 얻었다.; HRMS [M]+: 575.21Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 793] was performed to obtain 4.7 g of the target compound; HRMS [M]+: 575.21

[합성예 884] Mat 884의 합성[Synthesis Example 884] Synthesis of Mat 884

Figure pat00978
Figure pat00978

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 794]과 동일한 과정을 수행하여 목적 화합물 6.8g을 얻었다.; HRMS [M]+: 651.24Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 794] was performed to obtain 6.8 g of the target compound; HRMS [M]+: 651.24

[합성예 885] Mat 885의 합성[Synthesis Example 885] Synthesis of Mat 885

Figure pat00979
Figure pat00979

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 795]과 동일한 과정을 수행하여 목적 화합물 12.9g을 얻었다.; HRMS [M]+: 893.31Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 795] was performed to obtain 12.9 g of the target compound; HRMS [M]+: 893.31

[합성예 886] Mat 886의 합성[Synthesis Example 886] Synthesis of Mat 886

Figure pat00980
Figure pat00980

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 796]과 동일한 과정을 수행하여 목적 화합물 11.4g을 얻었다.; HRMS [M]+: 893.31Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 796] was performed to obtain 11.4 g of the target compound; HRMS [M]+: 893.31

[합성예 887] Mat 887의 합성[Synthesis Example 887] Synthesis of Mat 887

Figure pat00981
Figure pat00981

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 797]과 동일한 과정을 수행하여 목적 화합물 10.2g을 얻었다.; HRMS [M]+: 740.27Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 797] was performed to obtain 10.2 g of the target compound; HRMS [M]+: 740.27

[합성예 888] Mat 888의 합성[Synthesis Example 888] Synthesis of Mat 888

Figure pat00982
Figure pat00982

반응물로 [준비예4]을 사용한 것을 제외하고는 [합성예 798]과 동일한 과정을 수행하여 목적 화합물 13.5g을 얻었다.; HRMS [M]+: 906.31Except for using [Preparation Example 4] as a reactant, the same procedure as in [Synthesis Example 798] was performed to obtain 13.5 g of the target compound; HRMS [M]+: 906.31

[합성예 889] Mat 889의 합성[Synthesis Example 889] Synthesis of Mat 889

Figure pat00983
Figure pat00983

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 769]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 578.19Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 769] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 578.19

[합성예 890] Mat 890의 합성[Synthesis Example 890] Synthesis of Mat 890

Figure pat00984
Figure pat00984

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 770]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 730.25Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 770] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 730.25

[합성예 891] Mat 891의 합성[Synthesis Example 891] Synthesis of Mat 891

Figure pat00985
Figure pat00985

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 771]과 동일한 과정을 수행하여 목적 화합물 5.3g을 얻었다.; HRMS [M]+: 730.25Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 771] was performed to obtain 5.3 g of the target compound; HRMS [M]+: 730.25

[합성예 892] Mat 892의 합성[Synthesis Example 892] Synthesis of Mat 892

Figure pat00986
Figure pat00986

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 772]과 동일한 과정을 수행하여 목적 화합물 4.4g을 얻었다.; HRMS [M]+: 678.22Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 772] was performed to obtain 4.4 g of the target compound; HRMS [M]+: 678.22

[합성예 893] Mat 893의 합성[Synthesis Example 893] Synthesis of Mat 893

Figure pat00987
Figure pat00987

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 773]과 동일한 과정을 수행하여 목적 화합물 4.8g을 얻었다.; HRMS [M]+: 654.22Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 773] was performed to obtain 4.8 g of the target compound; HRMS [M]+: 654.22

[합성예 894] Mat 894의 합성[Synthesis Example 894] Synthesis of Mat 894

Figure pat00988
Figure pat00988

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 774]과 동일한 과정을 수행하여 목적 화합물 6.6g을 얻었다.; HRMS [M]+: 668.20Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 774] was performed to obtain 6.6 g of the target compound; HRMS [M]+: 668.20

[합성예 895] Mat 895의 합성[Synthesis Example 895] Synthesis of Mat 895

Figure pat00989
Figure pat00989

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 775]과 동일한 과정을 수행하여 목적 화합물 6.3g을 얻었다.; HRMS [M]+: 684.18Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 775] was performed to obtain 6.3 g of the target compound; HRMS [M]+: 684.18

[합성예 896] Mat 896의 합성[Synthesis Example 896] Synthesis of Mat 896

Figure pat00990
Figure pat00990

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 776]과 동일한 과정을 수행하여 목적 화합물 5.9g을 얻었다.; HRMS [M]+: 694.25Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 776] was performed to obtain 5.9 g of the target compound; HRMS [M]+: 694.25

[합성예 897] Mat 897의 합성[Synthesis Example 897] Synthesis of Mat 897

Figure pat00991
Figure pat00991

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 777]과 동일한 과정을 수행하여 목적 화합물 4.7g을 얻었다.; HRMS [M]+: 654.22Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 777] was performed to obtain 4.7 g of the target compound; HRMS [M]+: 654.22

[합성예 898] Mat 898의 합성[Synthesis Example 898] Synthesis of Mat 898

Figure pat00992
Figure pat00992

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 778]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 668.20Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 778] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 668.20

[합성예 899] Mat 899의 합성[Synthesis Example 899] Synthesis of Mat 899

Figure pat00993
Figure pat00993

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 779]과 동일한 과정을 수행하여 목적 화합물 5.7g을 얻었다.; HRMS [M]+: 668.20Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 779] was performed to obtain 5.7 g of the target compound; HRMS [M]+: 668.20

[합성예 900] Mat 900의 합성[Synthesis Example 900] Synthesis of Mat 900

Figure pat00994
Figure pat00994

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 780]과 동일한 과정을 수행하여 목적 화합물 6.0g을 얻었다.; HRMS [M]+: 668.20Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 780] was performed to obtain 6.0 g of the target compound; HRMS [M]+: 668.20

[합성예 901] Mat 901의 합성[Synthesis Example 901] Synthesis of Mat 901

Figure pat00995
Figure pat00995

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 781]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 576.17Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 781] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 576.17

[합성예 902] Mat 902의 합성[Synthesis Example 902] Synthesis of Mat 902

Figure pat00996
Figure pat00996

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 782]과 동일한 과정을 수행하여 목적 화합물 5.5g을 얻었다.; HRMS [M]+: 526.16Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 782] was performed to obtain 5.5 g of the target compound; HRMS [M]+: 526.16

[합성예 903] Mat 903의 합성[Synthesis Example 903] Synthesis of Mat 903

Figure pat00997
Figure pat00997

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 783]과 동일한 과정을 수행하여 목적 화합물 4.8g을 얻었다.; HRMS [M]+: 627.20Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 783] was performed to obtain 4.8 g of the target compound; HRMS [M]+: 627.20

[합성예 904] Mat 904의 합성[Synthesis Example 904] Synthesis of Mat 904

Figure pat00998
Figure pat00998

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 784]과 동일한 과정을 수행하여 목적 화합물 5.5g을 얻었다.; HRMS [M]+: 742.94Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 784] was performed to obtain 5.5 g of the target compound; HRMS [M]+: 742.94

[합성예 905] Mat 905의 합성[Synthesis Example 905] Synthesis of Mat 905

Figure pat00999
Figure pat00999

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 785]과 동일한 과정을 수행하여 목적 화합물 5.2g을 얻었다.; HRMS [M]+: 667.22Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 785] was performed to obtain 5.2 g of the target compound; HRMS [M]+: 667.22

[합성예 906] Mat 906의 합성[Synthesis Example 906] Synthesis of Mat 906

Figure pat01000
Figure pat01000

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 786]과 동일한 과정을 수행하여 목적 화합물 7.6g을 얻었다.; HRMS [M]+: 849.24Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 786] was performed to obtain 7.6 g of the target compound; HRMS [M]+: 849.24

[합성예 907] Mat 907의 합성[Synthesis Example 907] Synthesis of Mat 907

Figure pat01001
Figure pat01001

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 787]과 동일한 과정을 수행하여 목적 화합물 5.8g을 얻었다.; HRMS [M]+: 704.24Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 787] was performed to obtain 5.8 g of the target compound; HRMS [M]+: 704.24

[합성예 908] Mat 908의 합성[Synthesis Example 908] Synthesis of Mat 908

Figure pat01002
Figure pat01002

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 788]과 동일한 과정을 수행하여 목적 화합물 6.1g을 얻었다.; HRMS [M]+: 704.24Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 788] was performed to obtain 6.1 g of the target compound; HRMS [M]+: 704.24

[합성예 909] Mat 909의 합성[Synthesis Example 909] Synthesis of Mat 909

Figure pat01003
Figure pat01003

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 789]과 동일한 과정을 수행하여 목적 화합물 5.7g을 얻었다.; HRMS [M]+: 743.25Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 789] was performed to obtain 5.7 g of the target compound; HRMS [M]+: 743.25

[합성예 910] Mat 910의 합성[Synthesis Example 910] Synthesis of Mat 910

Figure pat01004
Figure pat01004

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 790]과 동일한 과정을 수행하여 목적 화합물 7.1g을 얻었다.; HRMS [M]+: 717.23Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 790] was performed to obtain 7.1 g of the target compound; HRMS [M]+: 717.23

[합성예 911] Mat 911의 합성[Synthesis Example 911] Synthesis of Mat 911

Figure pat01005
Figure pat01005

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 791]과 동일한 과정을 수행하여 목적 화합물 6.5g을 얻었다.; HRMS [M]+: 652.21Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 791] was performed to obtain 6.5 g of the target compound; HRMS [M]+: 652.21

[합성예 912] Mat 912의 합성[Synthesis Example 912] Synthesis of Mat 912

Figure pat01006
Figure pat01006

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 792]과 동일한 과정을 수행하여 목적 화합물 5.8g을 얻었다.; HRMS [M]+: 654.22Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 792] was performed to obtain 5.8 g of the target compound; HRMS [M]+: 654.22

[합성예 913] Mat 913의 합성[Synthesis Example 913] Synthesis of Mat 913

Figure pat01007
Figure pat01007

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 793]과 동일한 과정을 수행하여 목적 화합물 4.7g을 얻었다.; HRMS [M]+: 591.19Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 793] was performed to obtain 4.7 g of the target compound; HRMS [M]+: 591.19

[합성예 914] Mat 914의 합성[Synthesis Example 914] Synthesis of Mat 914

Figure pat01008
Figure pat01008

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 794]과 동일한 과정을 수행하여 목적 화합물 6.8g을 얻었다.; HRMS [M]+: 667.22Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 794] was performed to obtain 6.8 g of the target compound; HRMS [M]+: 667.22

[합성예 915] Mat 915의 합성[Synthesis Example 915] Synthesis of Mat 915

Figure pat01009
Figure pat01009

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 795]과 동일한 과정을 수행하여 목적 화합물 12.9g을 얻었다.; HRMS [M]+: 925.27Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 795] was performed to obtain 12.9 g of the target compound; HRMS [M]+: 925.27

[합성예 916] Mat 916의 합성[Synthesis Example 916] Synthesis of Mat 916

Figure pat01010
Figure pat01010

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 796]과 동일한 과정을 수행하여 목적 화합물 11.4g을 얻었다.; HRMS [M]+: 925.27Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 796] was performed to obtain 11.4 g of the target compound; HRMS [M]+: 925.27

[합성예 917] Mat 917의 합성[Synthesis Example 917] Synthesis of Mat 917

Figure pat01011
Figure pat01011

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 797]과 동일한 과정을 수행하여 목적 화합물 10.2g을 얻었다.; HRMS [M]+: 756.24Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 797] was performed to obtain 10.2 g of the target compound; HRMS [M]+: 756.24

[합성예 918] Mat 918의 합성[Synthesis Example 918] Synthesis of Mat 918

Figure pat01012
Figure pat01012

반응물로 [준비예5]을 사용한 것을 제외하고는 [합성예 798]과 동일한 과정을 수행하여 목적 화합물 13.5g을 얻었다.; HRMS [M]+: 938.26Except for using [Preparation Example 5] as a reactant, the same procedure as in [Synthesis Example 798] was performed to obtain 13.5 g of the target compound; HRMS [M]+: 938.26

[합성예 919] Mat 919의 합성[Synthesis Example 919] Synthesis of Mat 919

Figure pat01013
Figure pat01013

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 769]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 578.19Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 769] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 578.19

[합성예 920] Mat 920의 합성[Synthesis Example 920] Synthesis of Mat 920

Figure pat01014
Figure pat01014

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 770]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 730.25Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 770] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 730.25

[합성예 921] Mat 921의 합성[Synthesis Example 921] Synthesis of Mat 921

Figure pat01015
Figure pat01015

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 771]과 동일한 과정을 수행하여 목적 화합물 5.3g을 얻었다.; HRMS [M]+: 730.25Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 771] was performed to obtain 5.3 g of the target compound; HRMS [M]+: 730.25

[합성예 922] Mat 922의 합성[Synthesis Example 922] Synthesis of Mat 922

Figure pat01016
Figure pat01016

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 772]과 동일한 과정을 수행하여 목적 화합물 4.4g을 얻었다.; HRMS [M]+: 678.22Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 772] was performed to obtain 4.4 g of the target compound; HRMS [M]+: 678.22

[합성예 923] Mat 923의 합성[Synthesis Example 923] Synthesis of Mat 923

Figure pat01017
Figure pat01017

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 773]과 동일한 과정을 수행하여 목적 화합물 4.8g을 얻었다.; HRMS [M]+: 654.22Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 773] was performed to obtain 4.8 g of the target compound; HRMS [M]+: 654.22

[합성예 924] Mat 924의 합성[Synthesis Example 924] Synthesis of Mat 924

Figure pat01018
Figure pat01018

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 774]과 동일한 과정을 수행하여 목적 화합물 6.6g을 얻었다.; HRMS [M]+: 668.20Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 774] was performed to obtain 6.6 g of the target compound; HRMS [M]+: 668.20

[합성예 925] Mat 925의 합성[Synthesis Example 925] Synthesis of Mat 925

Figure pat01019
Figure pat01019

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 775]과 동일한 과정을 수행하여 목적 화합물 6.3g을 얻었다.; HRMS [M]+: 684.18Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 775] was performed to obtain 6.3 g of the target compound; HRMS [M]+: 684.18

[합성예 926] Mat 926의 합성[Synthesis Example 926] Synthesis of Mat 926

Figure pat01020
Figure pat01020

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 776]과 동일한 과정을 수행하여 목적 화합물 5.9g을 얻었다.; HRMS [M]+: 694.25Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 776] was performed to obtain 5.9 g of the target compound; HRMS [M]+: 694.25

[합성예 927] Mat 927의 합성[Synthesis Example 927] Synthesis of Mat 927

Figure pat01021
Figure pat01021

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 777]과 동일한 과정을 수행하여 목적 화합물 4.7g을 얻었다.; HRMS [M]+: 654.22Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 777] was performed to obtain 4.7 g of the target compound; HRMS [M]+: 654.22

[합성예 928] Mat 928의 합성[Synthesis Example 928] Synthesis of Mat 928

Figure pat01022
Figure pat01022

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 778]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 668.20Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 778] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 668.20

[합성예 929] Mat 929의 합성[Synthesis Example 929] Synthesis of Mat 929

Figure pat01023
Figure pat01023

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 779]과 동일한 과정을 수행하여 목적 화합물 5.7g을 얻었다.; HRMS [M]+: 668.20Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 779] was performed to obtain 5.7 g of the target compound; HRMS [M]+: 668.20

[합성예 930] Mat 930의 합성[Synthesis Example 930] Synthesis of Mat 930

Figure pat01024
Figure pat01024

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 780]과 동일한 과정을 수행하여 목적 화합물 6.0g을 얻었다.; HRMS [M]+: 668.20Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 780] was performed to obtain 6.0 g of the target compound; HRMS [M]+: 668.20

[합성예 931] Mat 931의 합성[Synthesis Example 931] Synthesis of Mat 931

Figure pat01025
Figure pat01025

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 781]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 576.17Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 781] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 576.17

[합성예 932] Mat 932의 합성[Synthesis Example 932] Synthesis of Mat 932

Figure pat01026
Figure pat01026

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 782]과 동일한 과정을 수행하여 목적 화합물 5.5g을 얻었다.; HRMS [M]+: 526.16Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 782] was performed to obtain 5.5 g of the target compound; HRMS [M]+: 526.16

[합성예 933] Mat 933의 합성[Synthesis Example 933] Synthesis of Mat 933

Figure pat01027
Figure pat01027

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 783]과 동일한 과정을 수행하여 목적 화합물 4.8g을 얻었다.; HRMS [M]+: 627.20Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 783] was performed to obtain 4.8 g of the target compound; HRMS [M]+: 627.20

[합성예 934] Mat 934의 합성[Synthesis Example 934] Synthesis of Mat 934

Figure pat01028
Figure pat01028

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 784]과 동일한 과정을 수행하여 목적 화합물 5.5g을 얻었다.; HRMS [M]+: 742.94Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 784] was performed to obtain 5.5 g of the target compound; HRMS [M]+: 742.94

[합성예 935] Mat 935의 합성[Synthesis Example 935] Synthesis of Mat 935

Figure pat01029
Figure pat01029

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 785]과 동일한 과정을 수행하여 목적 화합물 5.2g을 얻었다.; HRMS [M]+: 667.22Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 785] was performed to obtain 5.2 g of the target compound; HRMS [M]+: 667.22

[합성예 936] Mat 936의 합성[Synthesis Example 936] Synthesis of Mat 936

Figure pat01030
Figure pat01030

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 786]과 동일한 과정을 수행하여 목적 화합물 7.6g을 얻었다.; HRMS [M]+: 849.24Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 786] was performed to obtain 7.6 g of the target compound; HRMS [M]+: 849.24

[합성예 937] Mat 937의 합성[Synthesis Example 937] Synthesis of Mat 937

Figure pat01031
Figure pat01031

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 787]과 동일한 과정을 수행하여 목적 화합물 5.8g을 얻었다.; HRMS [M]+: 704.24Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 787] was performed to obtain 5.8 g of the target compound; HRMS [M]+: 704.24

[합성예 938] Mat 938의 합성[Synthesis Example 938] Synthesis of Mat 938

Figure pat01032
Figure pat01032

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 788]과 동일한 과정을 수행하여 목적 화합물 6.1g을 얻었다.; HRMS [M]+: 704.24Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 788] was performed to obtain 6.1 g of the target compound; HRMS [M]+: 704.24

[합성예 939] Mat 939의 합성[Synthesis Example 939] Synthesis of Mat 939

Figure pat01033
Figure pat01033

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 789]과 동일한 과정을 수행하여 목적 화합물 5.7g을 얻었다.; HRMS [M]+: 743.25Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 789] was performed to obtain 5.7 g of the target compound; HRMS [M]+: 743.25

[합성예 940] Mat 940의 합성[Synthesis Example 940] Synthesis of Mat 940

Figure pat01034
Figure pat01034

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 790]과 동일한 과정을 수행하여 목적 화합물 7.1g을 얻었다.; HRMS [M]+: 717.23Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 790] was performed to obtain 7.1 g of the target compound; HRMS [M]+: 717.23

[합성예 941] Mat 941의 합성[Synthesis Example 941] Synthesis of Mat 941

Figure pat01035
Figure pat01035

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 791]과 동일한 과정을 수행하여 목적 화합물 6.5g을 얻었다.; HRMS [M]+: 652.21Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 791] was performed to obtain 6.5 g of the target compound; HRMS [M]+: 652.21

[합성예 942] Mat 942의 합성[Synthesis Example 942] Synthesis of Mat 942

Figure pat01036
Figure pat01036

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 792]과 동일한 과정을 수행하여 목적 화합물 5.8g을 얻었다.; HRMS [M]+: 654.22Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 792] was performed to obtain 5.8 g of the target compound; HRMS [M]+: 654.22

[합성예 943] Mat 943의 합성[Synthesis Example 943] Synthesis of Mat 943

Figure pat01037
Figure pat01037

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 793]과 동일한 과정을 수행하여 목적 화합물 4.7g을 얻었다.; HRMS [M]+: 591.19Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 793] was performed to obtain 4.7 g of the target compound; HRMS [M]+: 591.19

[합성예 944] Mat 944의 합성[Synthesis Example 944] Synthesis of Mat 944

Figure pat01038
Figure pat01038

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 794]과 동일한 과정을 수행하여 목적 화합물 6.8g을 얻었다.; HRMS [M]+: 667.22Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 794] was performed to obtain 6.8 g of the target compound; HRMS [M]+: 667.22

[합성예 945] Mat 945의 합성[Synthesis Example 945] Synthesis of Mat 945

Figure pat01039
Figure pat01039

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 795]과 동일한 과정을 수행하여 목적 화합물 12.9g을 얻었다.; HRMS [M]+: 925.27Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 795] was performed to obtain 12.9 g of the target compound; HRMS [M]+: 925.27

[합성예 946] Mat 946의 합성[Synthesis Example 946] Synthesis of Mat 946

Figure pat01040
Figure pat01040

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 796]과 동일한 과정을 수행하여 목적 화합물 11.4g을 얻었다.; HRMS [M]+: 925.27Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 796] was performed to obtain 11.4 g of the target compound; HRMS [M]+: 925.27

[합성예 947] Mat 947의 합성[Synthesis Example 947] Synthesis of Mat 947

Figure pat01041
Figure pat01041

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 797]과 동일한 과정을 수행하여 목적 화합물 10.2g을 얻었다.; HRMS [M]+: 756.24Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 797] was performed to obtain 10.2 g of the target compound; HRMS [M]+: 756.24

[합성예 948] Mat 948의 합성[Synthesis Example 948] Synthesis of Mat 948

Figure pat01042
Figure pat01042

반응물로 [준비예6]을 사용한 것을 제외하고는 [합성예 798]과 동일한 과정을 수행하여 목적 화합물 13.5g을 얻었다.; HRMS [M]+: 938.26Except for using [Preparation Example 6] as a reactant, the same procedure as in [Synthesis Example 798] was performed to obtain 13.5 g of the target compound; HRMS [M]+: 938.26

[합성예 949] Mat 949의 합성[Synthesis Example 949] Synthesis of Mat 949

Figure pat01043
Figure pat01043

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 769]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 578.19Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 769] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 578.19

[합성예 950] Mat 950의 합성[Synthesis Example 950] Synthesis of Mat 950

Figure pat01044
Figure pat01044

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 770]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 730.25Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 770] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 730.25

[합성예 951] Mat 951의 합성[Synthesis Example 951] Synthesis of Mat 951

Figure pat01045
Figure pat01045

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 771]과 동일한 과정을 수행하여 목적 화합물 5.3g을 얻었다.; HRMS [M]+: 730.25Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 771] was performed to obtain 5.3 g of the target compound; HRMS [M]+: 730.25

[합성예 952] Mat 952의 합성[Synthesis Example 952] Synthesis of Mat 952

Figure pat01046
Figure pat01046

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 772]과 동일한 과정을 수행하여 목적 화합물 4.4g을 얻었다.; HRMS [M]+: 678.22Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 772] was performed to obtain 4.4 g of the target compound; HRMS [M]+: 678.22

[합성예 953] Mat 953의 합성[Synthesis Example 953] Synthesis of Mat 953

Figure pat01047
Figure pat01047

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 773]과 동일한 과정을 수행하여 목적 화합물 4.8g을 얻었다.; HRMS [M]+: 654.22Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 773] was performed to obtain 4.8 g of the target compound; HRMS [M]+: 654.22

[합성예 954] Mat 954의 합성[Synthesis Example 954] Synthesis of Mat 954

Figure pat01048
Figure pat01048

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 774]과 동일한 과정을 수행하여 목적 화합물 6.6g을 얻었다.; HRMS [M]+: 668.20Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 774] was performed to obtain 6.6 g of the target compound; HRMS [M]+: 668.20

[합성예 955] Mat 955의 합성[Synthesis Example 955] Synthesis of Mat 955

Figure pat01049
Figure pat01049

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 775]과 동일한 과정을 수행하여 목적 화합물 6.3g을 얻었다.; HRMS [M]+: 684.18Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 775] was performed to obtain 6.3 g of the target compound; HRMS [M]+: 684.18

[합성예 956] Mat 956의 합성[Synthesis Example 956] Synthesis of Mat 956

Figure pat01050
Figure pat01050

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 776]과 동일한 과정을 수행하여 목적 화합물 5.9g을 얻었다.; HRMS [M]+: 694.25Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 776] was performed to obtain 5.9 g of the target compound; HRMS [M]+: 694.25

[합성예 957] Mat 957의 합성[Synthesis Example 957] Synthesis of Mat 957

Figure pat01051
Figure pat01051

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 777]과 동일한 과정을 수행하여 목적 화합물 4.7g을 얻었다.; HRMS [M]+: 654.22Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 777] was performed to obtain 4.7 g of the target compound; HRMS [M]+: 654.22

[합성예 958] Mat 958의 합성[Synthesis Example 958] Synthesis of Mat 958

Figure pat01052
Figure pat01052

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 778]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 668.20Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 778] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 668.20

[합성예 959] Mat 959의 합성[Synthesis Example 959] Synthesis of Mat 959

Figure pat01053
Figure pat01053

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 779]과 동일한 과정을 수행하여 목적 화합물 5.7g을 얻었다.; HRMS [M]+: 668.20Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 779] was performed to obtain 5.7 g of the target compound; HRMS [M]+: 668.20

[합성예 960] Mat 960의 합성[Synthesis Example 960] Synthesis of Mat 960

Figure pat01054
Figure pat01054

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 780]과 동일한 과정을 수행하여 목적 화합물 6.0g을 얻었다.; HRMS [M]+: 668.20Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 780] was performed to obtain 6.0 g of the target compound; HRMS [M]+: 668.20

[합성예 961] Mat 961의 합성[Synthesis Example 961] Synthesis of Mat 961

Figure pat01055
Figure pat01055

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 781]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 576.17Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 781] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 576.17

[합성예 962] Mat 962의 합성[Synthesis Example 962] Synthesis of Mat 962

Figure pat01056
Figure pat01056

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 782]과 동일한 과정을 수행하여 목적 화합물 5.5g을 얻었다.; HRMS [M]+: 526.16Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 782] was performed to obtain 5.5 g of the target compound; HRMS [M]+: 526.16

[합성예 963] Mat 963의 합성[Synthesis Example 963] Synthesis of Mat 963

Figure pat01057
Figure pat01057

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 783]과 동일한 과정을 수행하여 목적 화합물 4.8g을 얻었다.; HRMS [M]+: 627.20Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 783] was performed to obtain 4.8 g of the target compound; HRMS [M]+: 627.20

[합성예 964] Mat 964의 합성[Synthesis Example 964] Synthesis of Mat 964

Figure pat01058
Figure pat01058

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 784]과 동일한 과정을 수행하여 목적 화합물 5.5g을 얻었다.; HRMS [M]+: 742.94Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 784] was performed to obtain 5.5 g of the target compound; HRMS [M]+: 742.94

[합성예 965] Mat 965의 합성[Synthesis Example 965] Synthesis of Mat 965

Figure pat01059
Figure pat01059

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 785]과 동일한 과정을 수행하여 목적 화합물 5.2g을 얻었다.; HRMS [M]+: 667.22Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 785] was performed to obtain 5.2 g of the target compound; HRMS [M]+: 667.22

[합성예 966] Mat 966의 합성[Synthesis Example 966] Synthesis of Mat 966

Figure pat01060
Figure pat01060

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 786]과 동일한 과정을 수행하여 목적 화합물 7.6g을 얻었다.; HRMS [M]+: 849.24Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 786] was performed to obtain 7.6 g of the target compound; HRMS [M]+: 849.24

[합성예 967] Mat 967의 합성[Synthesis Example 967] Synthesis of Mat 967

Figure pat01061
Figure pat01061

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 787]과 동일한 과정을 수행하여 목적 화합물 5.8g을 얻었다.; HRMS [M]+: 704.24Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 787] was performed to obtain 5.8 g of the target compound; HRMS [M]+: 704.24

[합성예 968] Mat 968의 합성[Synthesis Example 968] Synthesis of Mat 968

Figure pat01062
Figure pat01062

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 788]과 동일한 과정을 수행하여 목적 화합물 6.1g을 얻었다.; HRMS [M]+: 704.24Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 788] was performed to obtain 6.1 g of the target compound; HRMS [M]+: 704.24

[합성예 969] Mat 969의 합성[Synthesis Example 969] Synthesis of Mat 969

Figure pat01063
Figure pat01063

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 789]과 동일한 과정을 수행하여 목적 화합물 5.7g을 얻었다.; HRMS [M]+: 743.25Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 789] was performed to obtain 5.7 g of the target compound; HRMS [M]+: 743.25

[합성예 970] Mat 970의 합성[Synthesis Example 970] Synthesis of Mat 970

Figure pat01064
Figure pat01064

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 790]과 동일한 과정을 수행하여 목적 화합물 7.1g을 얻었다.; HRMS [M]+: 717.23Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 790] was performed to obtain 7.1 g of the target compound; HRMS [M]+: 717.23

[합성예 971] Mat 971의 합성[Synthesis Example 971] Synthesis of Mat 971

Figure pat01065
Figure pat01065

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 791]과 동일한 과정을 수행하여 목적 화합물 6.5g을 얻었다.; HRMS [M]+: 652.21Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 791] was performed to obtain 6.5 g of the target compound; HRMS [M]+: 652.21

[합성예 972] Mat 972의 합성[Synthesis Example 972] Synthesis of Mat 972

Figure pat01066
Figure pat01066

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 792]과 동일한 과정을 수행하여 목적 화합물 5.8g을 얻었다.; HRMS [M]+: 654.22Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 792] was performed to obtain 5.8 g of the target compound; HRMS [M]+: 654.22

[합성예 973] Mat 973의 합성[Synthesis Example 973] Synthesis of Mat 973

Figure pat01067
Figure pat01067

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 793]과 동일한 과정을 수행하여 목적 화합물 4.7g을 얻었다.; HRMS [M]+: 591.19Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 793] was performed to obtain 4.7 g of the target compound; HRMS [M]+: 591.19

[합성예 974] Mat 974의 합성[Synthesis Example 974] Synthesis of Mat 974

Figure pat01068
Figure pat01068

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 794]과 동일한 과정을 수행하여 목적 화합물 6.8g을 얻었다.; HRMS [M]+: 667.22Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 794] was performed to obtain 6.8 g of the target compound; HRMS [M]+: 667.22

[합성예 975] Mat 975의 합성[Synthesis Example 975] Synthesis of Mat 975

Figure pat01069
Figure pat01069

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 795]과 동일한 과정을 수행하여 목적 화합물 12.9g을 얻었다.; HRMS [M]+: 925.27Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 795] was performed to obtain 12.9 g of the target compound; HRMS [M]+: 925.27

[합성예 976] Mat 976의 합성[Synthesis Example 976] Synthesis of Mat 976

Figure pat01070
Figure pat01070

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 796]과 동일한 과정을 수행하여 목적 화합물 11.4g을 얻었다.; HRMS [M]+: 925.27Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 796] was performed to obtain 11.4 g of the target compound; HRMS [M]+: 925.27

[합성예 977] Mat 977의 합성[Synthesis Example 977] Synthesis of Mat 977

Figure pat01071
Figure pat01071

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 797]과 동일한 과정을 수행하여 목적 화합물 10.2g을 얻었다.; HRMS [M]+: 756.24Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 797] was performed to obtain 10.2 g of the target compound; HRMS [M]+: 756.24

[합성예 978] Mat 978의 합성[Synthesis Example 978] Synthesis of Mat 978

Figure pat01072
Figure pat01072

반응물로 [준비예7]을 사용한 것을 제외하고는 [합성예 798]과 동일한 과정을 수행하여 목적 화합물 13.5g을 얻었다.; HRMS [M]+: 938.26Except for using [Preparation Example 7] as a reactant, the same procedure as in [Synthesis Example 798] was performed to obtain 13.5 g of the target compound; HRMS [M]+: 938.26

[합성예 979] Mat 979의 합성[Synthesis Example 979] Synthesis of Mat 979

Figure pat01073
Figure pat01073

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 769]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 578.19Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 769] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 578.19

[합성예 980] Mat 980의 합성[Synthesis Example 980] Synthesis of Mat 980

Figure pat01074
Figure pat01074

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 770]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 730.25Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 770] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 730.25

[합성예 981] Mat 981의 합성[Synthesis Example 981] Synthesis of Mat 981

Figure pat01075
Figure pat01075

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 771]과 동일한 과정을 수행하여 목적 화합물 5.3g을 얻었다.; HRMS [M]+: 730.25Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 771] was performed to obtain 5.3 g of the target compound; HRMS [M]+: 730.25

[합성예 982] Mat 982의 합성[Synthesis Example 982] Synthesis of Mat 982

Figure pat01076
Figure pat01076

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 772]과 동일한 과정을 수행하여 목적 화합물 4.4g을 얻었다.; HRMS [M]+: 678.22Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 772] was performed to obtain 4.4 g of the target compound; HRMS [M]+: 678.22

[합성예 983] Mat 983의 합성[Synthesis Example 983] Synthesis of Mat 983

Figure pat01077
Figure pat01077

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 773]과 동일한 과정을 수행하여 목적 화합물 4.8g을 얻었다.; HRMS [M]+: 654.22Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 773] was performed to obtain 4.8 g of the target compound; HRMS [M]+: 654.22

[합성예 984] Mat 984의 합성[Synthesis Example 984] Synthesis of Mat 984

Figure pat01078
Figure pat01078

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 774]과 동일한 과정을 수행하여 목적 화합물 6.6g을 얻었다.; HRMS [M]+: 668.20Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 774] was performed to obtain 6.6 g of the target compound; HRMS [M]+: 668.20

[합성예 985] Mat 985의 합성[Synthesis Example 985] Synthesis of Mat 985

Figure pat01079
Figure pat01079

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 775]과 동일한 과정을 수행하여 목적 화합물 6.3g을 얻었다.; HRMS [M]+: 684.18Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 775] was performed to obtain 6.3 g of the target compound; HRMS [M]+: 684.18

[합성예 986] Mat 986의 합성[Synthesis Example 986] Synthesis of Mat 986

Figure pat01080
Figure pat01080

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 776]과 동일한 과정을 수행하여 목적 화합물 5.9g을 얻었다.; HRMS [M]+: 694.25Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 776] was performed to obtain 5.9 g of the target compound; HRMS [M]+: 694.25

[합성예 987] Mat 987의 합성[Synthesis Example 987] Synthesis of Mat 987

Figure pat01081
Figure pat01081

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 777]과 동일한 과정을 수행하여 목적 화합물 4.7g을 얻었다.; HRMS [M]+: 654.22Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 777] was performed to obtain 4.7 g of the target compound; HRMS [M]+: 654.22

[합성예 988] Mat 988의 합성[Synthesis Example 988] Synthesis of Mat 988

Figure pat01082
Figure pat01082

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 778]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 668.20Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 778] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 668.20

[합성예 989] Mat 989의 합성[Synthesis Example 989] Synthesis of Mat 989

Figure pat01083
Figure pat01083

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 779]과 동일한 과정을 수행하여 목적 화합물 5.7g을 얻었다.; HRMS [M]+: 668.20Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 779] was performed to obtain 5.7 g of the target compound; HRMS [M]+: 668.20

[합성예 990] Mat 990의 합성[Synthesis Example 990] Synthesis of Mat 990

Figure pat01084
Figure pat01084

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 780]과 동일한 과정을 수행하여 목적 화합물 6.0g을 얻었다.; HRMS [M]+: 668.20Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 780] was performed to obtain 6.0 g of the target compound; HRMS [M]+: 668.20

[합성예 991] Mat 991의 합성[Synthesis Example 991] Synthesis of Mat 991

Figure pat01085
Figure pat01085

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 781]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 576.17Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 781] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 576.17

[합성예 992] Mat 992의 합성[Synthesis Example 992] Synthesis of Mat 992

Figure pat01086
Figure pat01086

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 782]과 동일한 과정을 수행하여 목적 화합물 5.5g을 얻었다.; HRMS [M]+: 526.16Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 782] was performed to obtain 5.5 g of the target compound; HRMS [M]+: 526.16

[합성예 993] Mat 993의 합성[Synthesis Example 993] Synthesis of Mat 993

Figure pat01087
Figure pat01087

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 783]과 동일한 과정을 수행하여 목적 화합물 4.8g을 얻었다.; HRMS [M]+: 627.20Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 783] was performed to obtain 4.8 g of the target compound; HRMS [M]+: 627.20

[합성예 994] Mat 994의 합성[Synthesis Example 994] Synthesis of Mat 994

Figure pat01088
Figure pat01088

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 784]과 동일한 과정을 수행하여 목적 화합물 5.5g을 얻었다.; HRMS [M]+: 742.94Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 784] was performed to obtain 5.5 g of the target compound; HRMS [M]+: 742.94

[합성예 995] Mat 995의 합성[Synthesis Example 995] Synthesis of Mat 995

Figure pat01089
Figure pat01089

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 785]과 동일한 과정을 수행하여 목적 화합물 5.2g을 얻었다.; HRMS [M]+: 667.22Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 785] was performed to obtain 5.2 g of the target compound; HRMS [M]+: 667.22

[합성예 996] Mat 996의 합성[Synthesis Example 996] Synthesis of Mat 996

Figure pat01090
Figure pat01090

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 786]과 동일한 과정을 수행하여 목적 화합물 7.6g을 얻었다.; HRMS [M]+: 849.24Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 786] was performed to obtain 7.6 g of the target compound; HRMS [M]+: 849.24

[합성예 997] Mat 997의 합성[Synthesis Example 997] Synthesis of Mat 997

Figure pat01091
Figure pat01091

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 787]과 동일한 과정을 수행하여 목적 화합물 5.8g을 얻었다.; HRMS [M]+: 704.24Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 787] was performed to obtain 5.8 g of the target compound; HRMS [M]+: 704.24

[합성예 998] Mat 998의 합성[Synthesis Example 998] Synthesis of Mat 998

Figure pat01092
Figure pat01092

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 788]과 동일한 과정을 수행하여 목적 화합물 6.1g을 얻었다.; HRMS [M]+: 704.24Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 788] was performed to obtain 6.1 g of the target compound; HRMS [M]+: 704.24

[합성예 999] Mat 999의 합성[Synthesis Example 999] Synthesis of Mat 999

Figure pat01093
Figure pat01093

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 789]과 동일한 과정을 수행하여 목적 화합물 5.7g을 얻었다.; HRMS [M]+: 743.25Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 789] was performed to obtain 5.7 g of the target compound; HRMS [M]+: 743.25

[합성예 1000] Mat 1000의 합성[Synthesis Example 1000] Synthesis of Mat 1000

Figure pat01094
Figure pat01094

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 790]과 동일한 과정을 수행하여 목적 화합물 7.1g을 얻었다.; HRMS [M]+: 717.23Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 790] was performed to obtain 7.1 g of the target compound; HRMS [M]+: 717.23

[합성예 1001] Mat 1001의 합성[Synthesis Example 1001] Synthesis of Mat 1001

Figure pat01095
Figure pat01095

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 791]과 동일한 과정을 수행하여 목적 화합물 6.5g을 얻었다.; HRMS [M]+: 652.21Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 791] was performed to obtain 6.5 g of the target compound; HRMS [M]+: 652.21

[합성예 1002] Mat 1002의 합성[Synthesis Example 1002] Synthesis of Mat 1002

Figure pat01096
Figure pat01096

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 792]과 동일한 과정을 수행하여 목적 화합물 5.8g을 얻었다.; HRMS [M]+: 654.22Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 792] was performed to obtain 5.8 g of the target compound; HRMS [M]+: 654.22

[합성예 1003] Mat 1003의 합성[Synthesis Example 1003] Synthesis of Mat 1003

Figure pat01097
Figure pat01097

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 793]과 동일한 과정을 수행하여 목적 화합물 4.7g을 얻었다.; HRMS [M]+: 591.19Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 793] was performed to obtain 4.7 g of the target compound; HRMS [M]+: 591.19

[합성예 1004] Mat 1004의 합성[Synthesis Example 1004] Synthesis of Mat 1004

Figure pat01098
Figure pat01098

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 794]과 동일한 과정을 수행하여 목적 화합물 6.8g을 얻었다.; HRMS [M]+: 667.22Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 794] was performed to obtain 6.8 g of the target compound; HRMS [M]+: 667.22

[합성예 1005] Mat 1005의 합성[Synthesis Example 1005] Synthesis of Mat 1005

Figure pat01099
Figure pat01099

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 795]과 동일한 과정을 수행하여 목적 화합물 12.9g을 얻었다.; HRMS [M]+: 925.27Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 795] was performed to obtain 12.9 g of the target compound; HRMS [M]+: 925.27

[합성예 1006] Mat 1006의 합성[Synthesis Example 1006] Synthesis of Mat 1006

Figure pat01100
Figure pat01100

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 796]과 동일한 과정을 수행하여 목적 화합물 11.4g을 얻었다.; HRMS [M]+: 925.27Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 796] was performed to obtain 11.4 g of the target compound; HRMS [M]+: 925.27

[합성예 1007] Mat 1007의 합성[Synthesis Example 1007] Synthesis of Mat 1007

Figure pat01101
Figure pat01101

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 797]과 동일한 과정을 수행하여 목적 화합물 10.2g을 얻었다.; HRMS [M]+: 756.24Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 797] was performed to obtain 10.2 g of the target compound; HRMS [M]+: 756.24

[합성예 1008] Mat 1008의 합성[Synthesis Example 1008] Synthesis of Mat 1008

Figure pat01102
Figure pat01102

반응물로 [준비예8]을 사용한 것을 제외하고는 [합성예 798]과 동일한 과정을 수행하여 목적 화합물 13.5g을 얻었다.; HRMS [M]+: 938.26Except for using [Preparation Example 8] as a reactant, the same procedure as in [Synthesis Example 798] was performed to obtain 13.5 g of the target compound; HRMS [M]+: 938.26

[합성예 1009] Mat 1009의 합성[Synthesis Example 1009] Synthesis of Mat 1009

Figure pat01103
Figure pat01103

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 769]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 588.26Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 769] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 588.26

[합성예 1010] Mat 1010의 합성[Synthesis Example 1010] Synthesis of Mat 1010

Figure pat01104
Figure pat01104

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 770]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 740.33Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 770] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 740.33

[합성예 1011] Mat 1011의 합성[Synthesis Example 1011] Synthesis of Mat 1011

Figure pat01105
Figure pat01105

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 771]과 동일한 과정을 수행하여 목적 화합물 5.3g을 얻었다.; HRMS [M]+: 740.33Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 771] was performed to obtain 5.3 g of the target compound; HRMS [M]+: 740.33

[합성예 1012] Mat 1012의 합성[Synthesis Example 1012] Synthesis of Mat 1012

Figure pat01106
Figure pat01106

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 772]과 동일한 과정을 수행하여 목적 화합물 4.4g을 얻었다.; HRMS [M]+: 688.30Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 772] was performed to obtain 4.4 g of the target compound; HRMS [M]+: 688.30

[합성예 1013] Mat 1013의 합성[Synthesis Example 1013] Synthesis of Mat 1013

Figure pat01107
Figure pat01107

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 773]과 동일한 과정을 수행하여 목적 화합물 4.8g을 얻었다.; HRMS [M]+: 664.30Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 773] was performed to obtain 4.8 g of the target compound; HRMS [M]+: 664.30

[합성예 1014] Mat 1014의 합성[Synthesis Example 1014] Synthesis of Mat 1014

Figure pat01108
Figure pat01108

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 774]과 동일한 과정을 수행하여 목적 화합물 6.6g을 얻었다.; HRMS [M]+: 678.28Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 774] was performed to obtain 6.6 g of the target compound; HRMS [M]+: 678.28

[합성예 1015] Mat 1015의 합성[Synthesis Example 1015] Synthesis of Mat 1015

Figure pat01109
Figure pat01109

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 775]과 동일한 과정을 수행하여 목적 화합물 6.3g을 얻었다.; HRMS [M]+: 694.25Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 775] was performed to obtain 6.3 g of the target compound; HRMS [M]+: 694.25

[합성예 1016] Mat 1016의 합성[Synthesis Example 1016] Synthesis of Mat 1016

Figure pat01110
Figure pat01110

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 776]과 동일한 과정을 수행하여 목적 화합물 5.9g을 얻었다.; HRMS [M]+: 704.33Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 776] was performed to obtain 5.9 g of the target compound; HRMS [M]+: 704.33

[합성예 1017] Mat 1017의 합성[Synthesis Example 1017] Synthesis of Mat 1017

Figure pat01111
Figure pat01111

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 777]과 동일한 과정을 수행하여 목적 화합물 4.7g을 얻었다.; HRMS [M]+: 664.30Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 777] was performed to obtain 4.7 g of the target compound; HRMS [M]+: 664.30

[합성예 1018] Mat 1018의 합성[Synthesis Example 1018] Synthesis of Mat 1018

Figure pat01112
Figure pat01112

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 778]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 668.20Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 778] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 668.20

[합성예 1019] Mat 1019의 합성[Synthesis Example 1019] Synthesis of Mat 1019

Figure pat01113
Figure pat01113

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 779]과 동일한 과정을 수행하여 목적 화합물 5.7g을 얻었다.; HRMS [M]+: 678.28Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 779] was performed to obtain 5.7 g of the target compound; HRMS [M]+: 678.28

[합성예 1020] Mat 1020의 합성[Synthesis Example 1020] Synthesis of Mat 1020

Figure pat01114
Figure pat01114

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 780]과 동일한 과정을 수행하여 목적 화합물 6.0g을 얻었다.; HRMS [M]+: 678.28Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 780] was performed to obtain 6.0 g of the target compound; HRMS [M]+: 678.28

[합성예 1021] Mat 1021의 합성[Synthesis Example 1021] Synthesis of Mat 1021

Figure pat01115
Figure pat01115

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 781]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 586.25Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 781] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 586.25

[합성예 1022] Mat 1022의 합성[Synthesis Example 1022] Synthesis of Mat 1022

Figure pat01116
Figure pat01116

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 782]과 동일한 과정을 수행하여 목적 화합물 5.5g을 얻었다.; HRMS [M]+: 536.23Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 782] was performed to obtain 5.5 g of the target compound; HRMS [M]+: 536.23

[합성예 1023] Mat 1023의 합성[Synthesis Example 1023] Synthesis of Mat 1023

Figure pat01117
Figure pat01117

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 783]과 동일한 과정을 수행하여 목적 화합물 4.8g을 얻었다.; HRMS [M]+: 638.28Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 783] was performed to obtain 4.8 g of the target compound; HRMS [M]+: 638.28

[합성예 1024] Mat 1024의 합성[Synthesis Example 1024] Synthesis of Mat 1024

Figure pat01118
Figure pat01118

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 784]과 동일한 과정을 수행하여 목적 화합물 5.5g을 얻었다.; HRMS [M]+: 753.32Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 784] was performed to obtain 5.5 g of the target compound; HRMS [M]+: 753.32

[합성예 1025] Mat 1025의 합성[Synthesis Example 1025] Synthesis of Mat 1025

Figure pat01119
Figure pat01119

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 785]과 동일한 과정을 수행하여 목적 화합물 5.2g을 얻었다.; HRMS [M]+: 677.29Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 785] was performed to obtain 5.2 g of the target compound; HRMS [M]+: 677.29

[합성예 1026] Mat 1026의 합성[Synthesis Example 1026] Synthesis of Mat 1026

Figure pat01120
Figure pat01120

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 786]과 동일한 과정을 수행하여 목적 화합물 7.6g을 얻었다.; HRMS [M]+: 869.39Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 786] was performed to obtain 7.6 g of the target compound; HRMS [M]+: 869.39

[합성예 1027] Mat 1027의 합성[Synthesis Example 1027] Synthesis of Mat 1027

Figure pat01121
Figure pat01121

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 787]과 동일한 과정을 수행하여 목적 화합물 5.8g을 얻었다.; HRMS [M]+: 740.33Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 787] was performed to obtain 5.8 g of the target compound; HRMS [M]+: 740.33

[합성예 1028] Mat 1028의 합성[Synthesis Example 1028] Synthesis of Mat 1028

Figure pat01122
Figure pat01122

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 788]과 동일한 과정을 수행하여 목적 화합물 6.1g을 얻었다.; HRMS [M]+: 714.31Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 788] was performed to obtain 6.1 g of the target compound; HRMS [M]+: 714.31

[합성예 1029] Mat 1029의 합성[Synthesis Example 1029] Synthesis of Mat 1029

Figure pat01123
Figure pat01123

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 789]과 동일한 과정을 수행하여 목적 화합물 5.7g을 얻었다.; HRMS [M]+: 753.32Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 789] was performed to obtain 5.7 g of the target compound; HRMS [M]+: 753.32

[합성예 1030] Mat 1030의 합성[Synthesis Example 1030] Synthesis of Mat 1030

Figure pat01124
Figure pat01124

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 790]과 동일한 과정을 수행하여 목적 화합물 7.1g을 얻었다.; HRMS [M]+: 727.31Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 790] was performed to obtain 7.1 g of the target compound; HRMS [M]+: 727.31

[합성예 1031] Mat 1031의 합성[Synthesis Example 1031] Synthesis of Mat 1031

Figure pat01125
Figure pat01125

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 791]과 동일한 과정을 수행하여 목적 화합물 6.5g을 얻었다.; HRMS [M]+: 662.28Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 791] was performed to obtain 6.5 g of the target compound; HRMS [M]+: 662.28

[합성예 1032] Mat 1032의 합성[Synthesis Example 1032] Synthesis of Mat 1032

Figure pat01126
Figure pat01126

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 792]과 동일한 과정을 수행하여 목적 화합물 5.8g을 얻었다.; HRMS [M]+: 664.30Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 792] was performed to obtain 5.8 g of the target compound; HRMS [M]+: 664.30

[합성예 1033] Mat 1033의 합성[Synthesis Example 1033] Synthesis of Mat 1033

Figure pat01127
Figure pat01127

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 793]과 동일한 과정을 수행하여 목적 화합물 4.7g을 얻었다.; HRMS [M]+: 601.26Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 793] was performed to obtain 4.7 g of the target compound; HRMS [M]+: 601.26

[합성예 1034] Mat 1034의 합성[Synthesis Example 1034] Synthesis of Mat 1034

Figure pat01128
Figure pat01128

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 794]과 동일한 과정을 수행하여 목적 화합물 6.8g을 얻었다.; HRMS [M]+: 677.29Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 794] was performed to obtain 6.8 g of the target compound; HRMS [M]+: 677.29

[합성예 1035] Mat 1035의 합성[Synthesis Example 1035] Synthesis of Mat 1035

Figure pat01129
Figure pat01129

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 795]과 동일한 과정을 수행하여 목적 화합물 12.9g을 얻었다.; HRMS [M]+: 945.42Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 795] was performed to obtain 12.9 g of the target compound; HRMS [M]+: 945.42

[합성예 1036] Mat 1036의 합성[Synthesis Example 1036] Synthesis of Mat 1036

Figure pat01130
Figure pat01130

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 796]과 동일한 과정을 수행하여 목적 화합물 11.4g을 얻었다.; HRMS [M]+: 945.42Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 796] was performed to obtain 11.4 g of the target compound; HRMS [M]+: 945.42

[합성예 1037] Mat 1037의 합성[Synthesis Example 1037] Synthesis of Mat 1037

Figure pat01131
Figure pat01131

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 797]과 동일한 과정을 수행하여 목적 화합물 10.2g을 얻었다.; HRMS [M]+: 766.32Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 797] was performed to obtain 10.2 g of the target compound; HRMS [M]+: 766.32

[합성예 1038] Mat 1038의 합성[Synthesis Example 1038] Synthesis of Mat 1038

Figure pat01132
Figure pat01132

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 798]과 동일한 과정을 수행하여 목적 화합물 13.5g을 얻었다.; HRMS [M]+: 958.41Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 798] was performed to obtain 13.5 g of the target compound; HRMS [M]+: 958.41

[합성예 1039] Mat 1039의 합성[Synthesis Example 1039] Synthesis of Mat 1039

Figure pat01133
Figure pat01133

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 769]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 588.26Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 769] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 588.26

[합성예 1040] Mat 1040의 합성[Synthesis Example 1040] Synthesis of Mat 1040

Figure pat01134
Figure pat01134

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 770]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 740.33Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 770] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 740.33

[합성예 1041] Mat 1041의 합성[Synthesis Example 1041] Synthesis of Mat 1041

Figure pat01135
Figure pat01135

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 771]과 동일한 과정을 수행하여 목적 화합물 5.3g을 얻었다.; HRMS [M]+: 740.33Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 771] was performed to obtain 5.3 g of the target compound; HRMS [M]+: 740.33

[합성예 1042] Mat 1042의 합성[Synthesis Example 1042] Synthesis of Mat 1042

Figure pat01136
Figure pat01136

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 772]과 동일한 과정을 수행하여 목적 화합물 4.4g을 얻었다.; HRMS [M]+: 688.30Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 772] was performed to obtain 4.4 g of the target compound; HRMS [M]+: 688.30

[합성예 1043] Mat 1043의 합성[Synthesis Example 1043] Synthesis of Mat 1043

Figure pat01137
Figure pat01137

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 773]과 동일한 과정을 수행하여 목적 화합물 4.8g을 얻었다.; HRMS [M]+: 664.30Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 773] was performed to obtain 4.8 g of the target compound; HRMS [M]+: 664.30

[합성예 1044] Mat 1044의 합성[Synthesis Example 1044] Synthesis of Mat 1044

Figure pat01138
Figure pat01138

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 774]과 동일한 과정을 수행하여 목적 화합물 6.6g을 얻었다.; HRMS [M]+: 678.28Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 774] was performed to obtain 6.6 g of the target compound; HRMS [M]+: 678.28

[합성예 1045] Mat 1045의 합성[Synthesis Example 1045] Synthesis of Mat 1045

Figure pat01139
Figure pat01139

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 775]과 동일한 과정을 수행하여 목적 화합물 6.3g을 얻었다.; HRMS [M]+: 694.25Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 775] was performed to obtain 6.3 g of the target compound; HRMS [M]+: 694.25

[합성예 1046] Mat 1046의 합성[Synthesis Example 1046] Synthesis of Mat 1046

Figure pat01140
Figure pat01140

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 776]과 동일한 과정을 수행하여 목적 화합물 5.9g을 얻었다.; HRMS [M]+: 704.33Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 776] was performed to obtain 5.9 g of the target compound; HRMS [M]+: 704.33

[합성예 1047] Mat 1047의 합성[Synthesis Example 1047] Synthesis of Mat 1047

Figure pat01141
Figure pat01141

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 777]과 동일한 과정을 수행하여 목적 화합물 4.7g을 얻었다.; HRMS [M]+: 664.30Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 777] was performed to obtain 4.7 g of the target compound; HRMS [M]+: 664.30

[합성예 1048] Mat 1048의 합성[Synthesis Example 1048] Synthesis of Mat 1048

Figure pat01142
Figure pat01142

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 778]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 668.20Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 778] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 668.20

[합성예 1049] Mat 1049의 합성[Synthesis Example 1049] Synthesis of Mat 1049

Figure pat01143
Figure pat01143

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 779]과 동일한 과정을 수행하여 목적 화합물 5.7g을 얻었다.; HRMS [M]+: 678.28Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 779] was performed to obtain 5.7 g of the target compound; HRMS [M]+: 678.28

[합성예 1050] Mat 1050의 합성[Synthesis Example 1050] Synthesis of Mat 1050

Figure pat01144
Figure pat01144

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 780]과 동일한 과정을 수행하여 목적 화합물 6.0g을 얻었다.; HRMS [M]+: 678.28Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 780] was performed to obtain 6.0 g of the target compound; HRMS [M]+: 678.28

[합성예 1051] Mat 1051의 합성[Synthesis Example 1051] Synthesis of Mat 1051

Figure pat01145
Figure pat01145

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 781]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 586.25Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 781] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 586.25

[합성예 1052] Mat 1052의 합성[Synthesis Example 1052] Synthesis of Mat 1052

Figure pat01146
Figure pat01146

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 782]과 동일한 과정을 수행하여 목적 화합물 5.5g을 얻었다.; HRMS [M]+: 536.23Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 782] was performed to obtain 5.5 g of the target compound; HRMS [M]+: 536.23

[합성예 1053] Mat 1053의 합성[Synthesis Example 1053] Synthesis of Mat 1053

Figure pat01147
Figure pat01147

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 783]과 동일한 과정을 수행하여 목적 화합물 4.8g을 얻었다.; HRMS [M]+: 638.28Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 783] was performed to obtain 4.8 g of the target compound; HRMS [M]+: 638.28

[합성예 1054] Mat 1054의 합성[Synthesis Example 1054] Synthesis of Mat 1054

Figure pat01148
Figure pat01148

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 784]과 동일한 과정을 수행하여 목적 화합물 5.5g을 얻었다.; HRMS [M]+: 753.32Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 784] was performed to obtain 5.5 g of the target compound; HRMS [M]+: 753.32

[합성예 1055] Mat 1055의 합성[Synthesis Example 1055] Synthesis of Mat 1055

Figure pat01149
Figure pat01149

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 785]과 동일한 과정을 수행하여 목적 화합물 5.2g을 얻었다.; HRMS [M]+: 677.29Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 785] was performed to obtain 5.2 g of the target compound; HRMS [M]+: 677.29

[합성예 1056] Mat 1056의 합성[Synthesis Example 1056] Synthesis of Mat 1056

Figure pat01150
Figure pat01150

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 786]과 동일한 과정을 수행하여 목적 화합물 7.6g을 얻었다.; HRMS [M]+: 869.39Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 786] was performed to obtain 7.6 g of the target compound; HRMS [M]+: 869.39

[합성예 1057] Mat 1057의 합성[Synthesis Example 1057] Synthesis of Mat 1057

Figure pat01151
Figure pat01151

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 787]과 동일한 과정을 수행하여 목적 화합물 5.8g을 얻었다.; HRMS [M]+: 740.33Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 787] was performed to obtain 5.8 g of the target compound; HRMS [M]+: 740.33

[합성예 1058] Mat 1058의 합성[Synthesis Example 1058] Synthesis of Mat 1058

Figure pat01152
Figure pat01152

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 788]과 동일한 과정을 수행하여 목적 화합물 6.1g을 얻었다.; HRMS [M]+: 714.31Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 788] was performed to obtain 6.1 g of the target compound; HRMS [M]+: 714.31

[합성예 1059] Mat 1059의 합성[Synthesis Example 1059] Synthesis of Mat 1059

Figure pat01153
Figure pat01153

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 789]과 동일한 과정을 수행하여 목적 화합물 5.7g을 얻었다.; HRMS [M]+: 753.32Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 789] was performed to obtain 5.7 g of the target compound; HRMS [M]+: 753.32

[합성예 1060] Mat 1060의 합성[Synthesis Example 1060] Synthesis of Mat 1060

Figure pat01154
Figure pat01154

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 790]과 동일한 과정을 수행하여 목적 화합물 7.1g을 얻었다.; HRMS [M]+: 727.31Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 790] was performed to obtain 7.1 g of the target compound; HRMS [M]+: 727.31

[합성예 1061] Mat 1061의 합성[Synthesis Example 1061] Synthesis of Mat 1061

Figure pat01155
Figure pat01155

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 791]과 동일한 과정을 수행하여 목적 화합물 6.5g을 얻었다.; HRMS [M]+: 662.28Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 791] was performed to obtain 6.5 g of the target compound; HRMS [M]+: 662.28

[합성예 1062] Mat 1062의 합성[Synthesis Example 1062] Synthesis of Mat 1062

Figure pat01156
Figure pat01156

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 792]과 동일한 과정을 수행하여 목적 화합물 5.8g을 얻었다.; HRMS [M]+: 664.30Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 792] was performed to obtain 5.8 g of the target compound; HRMS [M]+: 664.30

[합성예 1063] Mat 1063의 합성[Synthesis Example 1063] Synthesis of Mat 1063

Figure pat01157
Figure pat01157

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 793]과 동일한 과정을 수행하여 목적 화합물 4.7g을 얻었다.; HRMS [M]+: 601.26Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 793] was performed to obtain 4.7 g of the target compound; HRMS [M]+: 601.26

[합성예 1064] Mat 1064의 합성[Synthesis Example 1064] Synthesis of Mat 1064

Figure pat01158
Figure pat01158

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 794]과 동일한 과정을 수행하여 목적 화합물 6.8g을 얻었다.; HRMS [M]+: 677.29Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 794] was performed to obtain 6.8 g of the target compound; HRMS [M]+: 677.29

[합성예 1065] Mat 1065의 합성[Synthesis Example 1065] Synthesis of Mat 1065

Figure pat01159
Figure pat01159

반응물로 [준비예9]을 사용한 것을 제외하고는 [합성예 795]과 동일한 과정을 수행하여 목적 화합물 12.9g을 얻었다.; HRMS [M]+: 945.42Except for using [Preparation Example 9] as a reactant, the same procedure as in [Synthesis Example 795] was performed to obtain 12.9 g of the target compound; HRMS [M]+: 945.42

[합성예 1066] Mat 1066의 합성[Synthesis Example 1066] Synthesis of Mat 1066

Figure pat01160
Figure pat01160

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 796]과 동일한 과정을 수행하여 목적 화합물 11.4g을 얻었다.; HRMS [M]+: 945.42Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 796] was performed to obtain 11.4 g of the target compound; HRMS [M]+: 945.42

[합성예 1067] Mat 1067의 합성[Synthesis Example 1067] Synthesis of Mat 1067

Figure pat01161
Figure pat01161

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 797]과 동일한 과정을 수행하여 목적 화합물 10.2g을 얻었다.; HRMS [M]+: 766.32Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 797] was performed to obtain 10.2 g of the target compound; HRMS [M]+: 766.32

[합성예 1068] Mat 1068의 합성[Synthesis Example 1068] Synthesis of Mat 1068

Figure pat01162
Figure pat01162

반응물로 [준비예10]을 사용한 것을 제외하고는 [합성예 798]과 동일한 과정을 수행하여 목적 화합물 13.5g을 얻었다.; HRMS [M]+: 958.41Except for using [Preparation Example 10] as a reactant, the same procedure as in [Synthesis Example 798] was performed to obtain 13.5 g of the target compound; HRMS [M]+: 958.41

[합성예 1069] Mat 1069의 합성[Synthesis Example 1069] Synthesis of Mat 1069

Figure pat01163
Figure pat01163

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 769]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 588.26Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 769] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 588.26

[합성예 1070] Mat 1070의 합성[Synthesis Example 1070] Synthesis of Mat 1070

Figure pat01164
Figure pat01164

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 770]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 740.33Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 770] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 740.33

[합성예 1071] Mat 1071의 합성[Synthesis Example 1071] Synthesis of Mat 1071

Figure pat01165
Figure pat01165

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 771]과 동일한 과정을 수행하여 목적 화합물 5.3g을 얻었다.; HRMS [M]+: 740.33Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 771] was performed to obtain 5.3 g of the target compound; HRMS [M]+: 740.33

[합성예 1072] Mat 1072의 합성[Synthesis Example 1072] Synthesis of Mat 1072

Figure pat01166
Figure pat01166

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 772]과 동일한 과정을 수행하여 목적 화합물 4.4g을 얻었다.; HRMS [M]+: 688.30Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 772] was performed to obtain 4.4 g of the target compound; HRMS [M]+: 688.30

[합성예 1073] Mat 1073의 합성[Synthesis Example 1073] Synthesis of Mat 1073

Figure pat01167
Figure pat01167

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 773]과 동일한 과정을 수행하여 목적 화합물 4.8g을 얻었다.; HRMS [M]+: 664.30Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 773] was performed to obtain 4.8 g of the target compound; HRMS [M]+: 664.30

[합성예 1074] Mat 1074의 합성[Synthesis Example 1074] Synthesis of Mat 1074

Figure pat01168
Figure pat01168

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 774]과 동일한 과정을 수행하여 목적 화합물 6.6g을 얻었다.; HRMS [M]+: 678.28Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 774] was performed to obtain 6.6 g of the target compound; HRMS [M]+: 678.28

[합성예 1075] Mat 1075의 합성[Synthesis Example 1075] Synthesis of Mat 1075

Figure pat01169
Figure pat01169

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 775]과 동일한 과정을 수행하여 목적 화합물 6.3g을 얻었다.; HRMS [M]+: 694.25Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 775] was performed to obtain 6.3 g of the target compound; HRMS [M]+: 694.25

[합성예 1076] Mat 1076의 합성[Synthesis Example 1076] Synthesis of Mat 1076

Figure pat01170
Figure pat01170

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 776]과 동일한 과정을 수행하여 목적 화합물 5.9g을 얻었다.; HRMS [M]+: 704.33Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 776] was performed to obtain 5.9 g of the target compound; HRMS [M]+: 704.33

[합성예 1077] Mat 1077의 합성[Synthesis Example 1077] Synthesis of Mat 1077

Figure pat01171
Figure pat01171

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 777]과 동일한 과정을 수행하여 목적 화합물 4.7g을 얻었다.; HRMS [M]+: 664.30Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 777] was performed to obtain 4.7 g of the target compound; HRMS [M]+: 664.30

[합성예 1078] Mat 1078의 합성[Synthesis Example 1078] Synthesis of Mat 1078

Figure pat01172
Figure pat01172

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 778]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 668.20Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 778] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 668.20

[합성예 1079] Mat 1079의 합성[Synthesis Example 1079] Synthesis of Mat 1079

Figure pat01173
Figure pat01173

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 779]과 동일한 과정을 수행하여 목적 화합물 5.7g을 얻었다.; HRMS [M]+: 678.28Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 779] was performed to obtain 5.7 g of the target compound; HRMS [M]+: 678.28

[합성예 1080] Mat 1080의 합성[Synthesis Example 1080] Synthesis of Mat 1080

Figure pat01174
Figure pat01174

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 780]과 동일한 과정을 수행하여 목적 화합물 6.0g을 얻었다.; HRMS [M]+: 678.28Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 780] was performed to obtain 6.0 g of the target compound; HRMS [M]+: 678.28

[합성예 1081] Mat 1081의 합성[Synthesis Example 1081] Synthesis of Mat 1081

Figure pat01175
Figure pat01175

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 781]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 586.25Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 781] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 586.25

[합성예 1082] Mat 1082의 합성[Synthesis Example 1082] Synthesis of Mat 1082

Figure pat01176
Figure pat01176

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 782]과 동일한 과정을 수행하여 목적 화합물 5.5g을 얻었다.; HRMS [M]+: 536.23Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 782] was performed to obtain 5.5 g of the target compound; HRMS [M]+: 536.23

[합성예 1083] Mat 1083의 합성[Synthesis Example 1083] Synthesis of Mat 1083

Figure pat01177
Figure pat01177

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 783]과 동일한 과정을 수행하여 목적 화합물 4.8g을 얻었다.; HRMS [M]+: 638.28Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 783] was performed to obtain 4.8 g of the target compound; HRMS [M]+: 638.28

[합성예 1084] Mat 1084의 합성[Synthesis Example 1084] Synthesis of Mat 1084

Figure pat01178
Figure pat01178

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 784]과 동일한 과정을 수행하여 목적 화합물 5.5g을 얻었다.; HRMS [M]+: 753.32Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 784] was performed to obtain 5.5 g of the target compound; HRMS [M]+: 753.32

[합성예 1085] Mat 1085의 합성[Synthesis Example 1085] Synthesis of Mat 1085

Figure pat01179
Figure pat01179

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 785]과 동일한 과정을 수행하여 목적 화합물 5.2g을 얻었다.; HRMS [M]+: 677.29Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 785] was performed to obtain 5.2 g of the target compound; HRMS [M]+: 677.29

[합성예 1086] Mat 1086의 합성[Synthesis Example 1086] Synthesis of Mat 1086

Figure pat01180
Figure pat01180

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 786]과 동일한 과정을 수행하여 목적 화합물 7.6g을 얻었다.; HRMS [M]+: 869.39Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 786] was performed to obtain 7.6 g of the target compound; HRMS [M]+: 869.39

[합성예 1087] Mat 1087의 합성[Synthesis Example 1087] Synthesis of Mat 1087

Figure pat01181
Figure pat01181

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 787]과 동일한 과정을 수행하여 목적 화합물 5.8g을 얻었다.; HRMS [M]+: 740.33Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 787] was performed to obtain 5.8 g of the target compound; HRMS [M]+: 740.33

[합성예 1088] Mat 1088의 합성[Synthesis Example 1088] Synthesis of Mat 1088

Figure pat01182
Figure pat01182

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 788]과 동일한 과정을 수행하여 목적 화합물 6.1g을 얻었다.; HRMS [M]+: 714.31Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 788] was performed to obtain 6.1 g of the target compound; HRMS [M]+: 714.31

[합성예 1089] Mat 10589의 합성[Synthesis Example 1089] Synthesis of Mat 10589

Figure pat01183
Figure pat01183

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 789]과 동일한 과정을 수행하여 목적 화합물 5.7g을 얻었다.; HRMS [M]+: 753.32Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 789] was performed to obtain 5.7 g of the target compound; HRMS [M]+: 753.32

[합성예 1090] Mat 1090의 합성[Synthesis Example 1090] Synthesis of Mat 1090

Figure pat01184
Figure pat01184

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 790]과 동일한 과정을 수행하여 목적 화합물 7.1g을 얻었다.; HRMS [M]+: 727.31Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 790] was performed to obtain 7.1 g of the target compound; HRMS [M]+: 727.31

[합성예 1091] Mat 1091의 합성[Synthesis Example 1091] Synthesis of Mat 1091

Figure pat01185
Figure pat01185

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 791]과 동일한 과정을 수행하여 목적 화합물 6.5g을 얻었다.; HRMS [M]+: 662.28Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 791] was performed to obtain 6.5 g of the target compound; HRMS [M]+: 662.28

[합성예 1092] Mat 1092의 합성[Synthesis Example 1092] Synthesis of Mat 1092

Figure pat01186
Figure pat01186

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 792]과 동일한 과정을 수행하여 목적 화합물 5.8g을 얻었다.; HRMS [M]+: 664.30Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 792] was performed to obtain 5.8 g of the target compound; HRMS [M]+: 664.30

[합성예 1093] Mat 1093의 합성[Synthesis Example 1093] Synthesis of Mat 1093

Figure pat01187
Figure pat01187

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 793]과 동일한 과정을 수행하여 목적 화합물 4.7g을 얻었다.; HRMS [M]+: 601.26Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 793] was performed to obtain 4.7 g of the target compound; HRMS [M]+: 601.26

[합성예 1094] Mat 1094의 합성[Synthesis Example 1094] Synthesis of Mat 1094

Figure pat01188
Figure pat01188

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 794]과 동일한 과정을 수행하여 목적 화합물 6.8g을 얻었다.; HRMS [M]+: 677.29Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 794] was performed to obtain 6.8 g of the target compound; HRMS [M]+: 677.29

[합성예 1095] Mat 1095의 합성[Synthesis Example 1095] Synthesis of Mat 1095

Figure pat01189
Figure pat01189

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 795]과 동일한 과정을 수행하여 목적 화합물 12.9g을 얻었다.; HRMS [M]+: 945.42Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 795] was performed to obtain 12.9 g of the target compound; HRMS [M]+: 945.42

[합성예 1096] Mat 1096의 합성[Synthesis Example 1096] Synthesis of Mat 1096

Figure pat01190
Figure pat01190

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 796]과 동일한 과정을 수행하여 목적 화합물 11.4g을 얻었다.; HRMS [M]+: 945.42Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 796] was performed to obtain 11.4 g of the target compound; HRMS [M]+: 945.42

[합성예 1097] Mat 1097의 합성[Synthesis Example 1097] Synthesis of Mat 1097

Figure pat01191
Figure pat01191

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 797]과 동일한 과정을 수행하여 목적 화합물 10.2g을 얻었다.; HRMS [M]+: 766.32Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 797] was performed to obtain 10.2 g of the target compound; HRMS [M]+: 766.32

[합성예 1098] Mat 1098의 합성[Synthesis Example 1098] Synthesis of Mat 1098

Figure pat01192
Figure pat01192

반응물로 [준비예11]을 사용한 것을 제외하고는 [합성예 798]과 동일한 과정을 수행하여 목적 화합물 13.5g을 얻었다.; HRMS [M]+: 958.41Except for using [Preparation Example 11] as a reactant, the same procedure as in [Synthesis Example 798] was performed to obtain 13.5 g of the target compound; HRMS [M]+: 958.41

[합성예 1099] Mat 1099의 합성[Synthesis Example 1099] Synthesis of Mat 1099

Figure pat01193
Figure pat01193

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 769]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 588.26Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 769] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 588.26

[합성예 1100] Mat 1100의 합성[Synthesis Example 1100] Synthesis of Mat 1100

Figure pat01194
Figure pat01194

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 770]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 740.33Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 770] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 740.33

[합성예 1101] Mat 1101의 합성[Synthesis Example 1101] Synthesis of Mat 1101

Figure pat01195
Figure pat01195

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 771]과 동일한 과정을 수행하여 목적 화합물 5.3g을 얻었다.; HRMS [M]+: 740.33Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 771] was performed to obtain 5.3 g of the target compound; HRMS [M]+: 740.33

[합성예 1102] Mat 1102의 합성[Synthesis Example 1102] Synthesis of Mat 1102

Figure pat01196
Figure pat01196

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 772]과 동일한 과정을 수행하여 목적 화합물 4.4g을 얻었다.; HRMS [M]+: 688.30Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 772] was performed to obtain 4.4 g of the target compound; HRMS [M]+: 688.30

[합성예 1103] Mat 1103의 합성[Synthesis Example 1103] Synthesis of Mat 1103

Figure pat01197
Figure pat01197

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 773]과 동일한 과정을 수행하여 목적 화합물 4.8g을 얻었다.; HRMS [M]+: 664.30Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 773] was performed to obtain 4.8 g of the target compound; HRMS [M]+: 664.30

[합성예 1104] Mat 1104의 합성[Synthesis Example 1104] Synthesis of Mat 1104

Figure pat01198
Figure pat01198

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 774]과 동일한 과정을 수행하여 목적 화합물 6.6g을 얻었다.; HRMS [M]+: 678.28Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 774] was performed to obtain 6.6 g of the target compound; HRMS [M]+: 678.28

[합성예 1105] Mat 1105의 합성[Synthesis Example 1105] Synthesis of Mat 1105

Figure pat01199
Figure pat01199

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 775]과 동일한 과정을 수행하여 목적 화합물 6.3g을 얻었다.; HRMS [M]+: 694.25Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 775] was performed to obtain 6.3 g of the target compound; HRMS [M]+: 694.25

[합성예 1106] Mat 1106의 합성[Synthesis Example 1106] Synthesis of Mat 1106

Figure pat01200
Figure pat01200

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 776]과 동일한 과정을 수행하여 목적 화합물 5.9g을 얻었다.; HRMS [M]+: 704.33Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 776] was performed to obtain 5.9 g of the target compound; HRMS [M]+: 704.33

[합성예 1107] Mat 1107의 합성[Synthesis Example 1107] Synthesis of Mat 1107

Figure pat01201
Figure pat01201

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 777]과 동일한 과정을 수행하여 목적 화합물 4.7g을 얻었다.; HRMS [M]+: 664.30Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 777] was performed to obtain 4.7 g of the target compound; HRMS [M]+: 664.30

[합성예 1008] Mat 1008의 합성[Synthesis Example 1008] Synthesis of Mat 1008

Figure pat01202
Figure pat01202

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 778]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 668.20Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 778] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 668.20

[합성예 1009] Mat 1009의 합성[Synthesis Example 1009] Synthesis of Mat 1009

Figure pat01203
Figure pat01203

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 779]과 동일한 과정을 수행하여 목적 화합물 5.7g을 얻었다.; HRMS [M]+: 678.28Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 779] was performed to obtain 5.7 g of the target compound; HRMS [M]+: 678.28

[합성예 1110] Mat 1110의 합성[Synthesis Example 1110] Synthesis of Mat 1110

Figure pat01204
Figure pat01204

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 780]과 동일한 과정을 수행하여 목적 화합물 6.0g을 얻었다.; HRMS [M]+: 678.28Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 780] was performed to obtain 6.0 g of the target compound; HRMS [M]+: 678.28

[합성예 1111] Mat 1111의 합성[Synthesis Example 1111] Synthesis of Mat 1111

Figure pat01205
Figure pat01205

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 781]과 동일한 과정을 수행하여 목적 화합물 5.1g을 얻었다.; HRMS [M]+: 586.25Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 781] was performed to obtain 5.1 g of the target compound; HRMS [M]+: 586.25

[합성예 1112] Mat 1112의 합성[Synthesis Example 1112] Synthesis of Mat 1112

Figure pat01206
Figure pat01206

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 782]과 동일한 과정을 수행하여 목적 화합물 5.5g을 얻었다.; HRMS [M]+: 536.23Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 782] was performed to obtain 5.5 g of the target compound; HRMS [M]+: 536.23

[합성예 1113] Mat 1113의 합성[Synthesis Example 1113] Synthesis of Mat 1113

Figure pat01207
Figure pat01207

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 783]과 동일한 과정을 수행하여 목적 화합물 4.8g을 얻었다.; HRMS [M]+: 638.28Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 783] was performed to obtain 4.8 g of the target compound; HRMS [M]+: 638.28

[합성예 1114] Mat 1114의 합성[Synthesis Example 1114] Synthesis of Mat 1114

Figure pat01208
Figure pat01208

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 784]과 동일한 과정을 수행하여 목적 화합물 5.5g을 얻었다.; HRMS [M]+: 753.32Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 784] was performed to obtain 5.5 g of the target compound; HRMS [M]+: 753.32

[합성예 1115] Mat 1115의 합성[Synthesis Example 1115] Synthesis of Mat 1115

Figure pat01209
Figure pat01209

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 785]과 동일한 과정을 수행하여 목적 화합물 5.2g을 얻었다.; HRMS [M]+: 677.29Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 785] was performed to obtain 5.2 g of the target compound; HRMS [M]+: 677.29

[합성예 1116] Mat 1116의 합성[Synthesis Example 1116] Synthesis of Mat 1116

Figure pat01210
Figure pat01210

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 786]과 동일한 과정을 수행하여 목적 화합물 7.6g을 얻었다.; HRMS [M]+: 869.39Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 786] was performed to obtain 7.6 g of the target compound; HRMS [M]+: 869.39

[합성예 1117] Mat 1117의 합성[Synthesis Example 1117] Synthesis of Mat 1117

Figure pat01211
Figure pat01211

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 787]과 동일한 과정을 수행하여 목적 화합물 5.8g을 얻었다.; HRMS [M]+: 740.33Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 787] was performed to obtain 5.8 g of the target compound; HRMS [M]+: 740.33

[합성예 1118] Mat 1118의 합성[Synthesis Example 1118] Synthesis of Mat 1118

Figure pat01212
Figure pat01212

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 788]과 동일한 과정을 수행하여 목적 화합물 6.1g을 얻었다.; HRMS [M]+: 714.31Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 788] was performed to obtain 6.1 g of the target compound; HRMS [M]+: 714.31

[합성예 1119] Mat 1119의 합성[Synthesis Example 1119] Synthesis of Mat 1119

Figure pat01213
Figure pat01213

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 789]과 동일한 과정을 수행하여 목적 화합물 5.7g을 얻었다.; HRMS [M]+: 753.32Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 789] was performed to obtain 5.7 g of the target compound; HRMS [M]+: 753.32

[합성예 1120] Mat 1120의 합성[Synthesis Example 1120] Synthesis of Mat 1120

Figure pat01214
Figure pat01214

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 790]과 동일한 과정을 수행하여 목적 화합물 7.1g을 얻었다.; HRMS [M]+: 727.31Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 790] was performed to obtain 7.1 g of the target compound; HRMS [M]+: 727.31

[합성예 1121] Mat 1121의 합성[Synthesis Example 1121] Synthesis of Mat 1121

Figure pat01215
Figure pat01215

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 791]과 동일한 과정을 수행하여 목적 화합물 6.5g을 얻었다.; HRMS [M]+: 662.28Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 791] was performed to obtain 6.5 g of the target compound; HRMS [M]+: 662.28

[합성예 1122] Mat 1122의 합성[Synthesis Example 1122] Synthesis of Mat 1122

Figure pat01216
Figure pat01216

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 792]과 동일한 과정을 수행하여 목적 화합물 5.8g을 얻었다.; HRMS [M]+: 664.30Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 792] was performed to obtain 5.8 g of the target compound; HRMS [M]+: 664.30

[합성예 1123] Mat 1123의 합성[Synthesis Example 1123] Synthesis of Mat 1123

Figure pat01217
Figure pat01217

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 793]과 동일한 과정을 수행하여 목적 화합물 4.7g을 얻었다.; HRMS [M]+: 601.26Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 793] was performed to obtain 4.7 g of the target compound; HRMS [M]+: 601.26

[합성예 1124] Mat 1124의 합성[Synthesis Example 1124] Synthesis of Mat 1124

Figure pat01218
Figure pat01218

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 794]과 동일한 과정을 수행하여 목적 화합물 6.8g을 얻었다.; HRMS [M]+: 677.29Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 794] was performed to obtain 6.8 g of the target compound; HRMS [M]+: 677.29

[합성예 1125] Mat 1125의 합성[Synthesis Example 1125] Synthesis of Mat 1125

Figure pat01219
Figure pat01219

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 795]과 동일한 과정을 수행하여 목적 화합물 12.9g을 얻었다.; HRMS [M]+: 945.42Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 795] was performed to obtain 12.9 g of the target compound; HRMS [M]+: 945.42

[합성예 1126] Mat 1126의 합성[Synthesis Example 1126] Synthesis of Mat 1126

Figure pat01220
Figure pat01220

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 796]과 동일한 과정을 수행하여 목적 화합물 11.4g을 얻었다.; HRMS [M]+: 945.42Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 796] was performed to obtain 11.4 g of the target compound; HRMS [M]+: 945.42

[합성예 1127] Mat 1127의 합성[Synthesis Example 1127] Synthesis of Mat 1127

Figure pat01221
Figure pat01221

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 797]과 동일한 과정을 수행하여 목적 화합물 10.2g을 얻었다.; HRMS [M]+: 766.32Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 797] was performed to obtain 10.2 g of the target compound; HRMS [M]+: 766.32

[합성예 1128] Mat 1128의 합성[Synthesis Example 1128] Synthesis of Mat 1128

Figure pat01222
Figure pat01222

반응물로 [준비예12]을 사용한 것을 제외하고는 [합성예 798]과 동일한 과정을 수행하여 목적 화합물 13.5g을 얻었다.; HRMS [M]+: 958.41Except for using [Preparation Example 12] as a reactant, the same procedure as in [Synthesis Example 798] was performed to obtain 13.5 g of the target compound; HRMS [M]+: 958.41

[합성예 1129] Mat 1129의 합성[Synthesis Example 1129] Synthesis of Mat 1129

Figure pat01223
Figure pat01223

반응물로 [준비예13]을 사용한 것을 제외하고는 [합성예 5]과 동일한 과정을 수행하여 목적 화합물 13.5g을 얻었다.; HRMS [M]+: 717.26Except for using [Preparation Example 13] as a reactant, the same procedure as in [Synthesis Example 5] was performed to obtain 13.5 g of the target compound; HRMS [M]+: 717.26

[합성예 1130] Mat 1130의 합성[Synthesis Example 1130] Synthesis of Mat 1130

Figure pat01224
Figure pat01224

반응물로 [준비예14]을 사용한 것을 제외하고는 [합성예 5]과 동일한 과정을 수행하여 목적 화합물 13.8g을 얻었다.; HRMS [M]+: 717.26Except for using [Preparation Example 14] as a reactant, the same procedure as in [Synthesis Example 5] was performed to obtain 13.8 g of the target compound; HRMS [M]+: 717.26

[합성예 1131] Mat 1131의 합성[Synthesis Example 1131] Synthesis of Mat 1131

Figure pat01225
Figure pat01225

반응물로 [준비예15]을 사용한 것을 제외하고는 [합성예 5]과 동일한 과정을 수행하여 목적 화합물 15.5g을 얻었다.; HRMS [M]+: 793.29Except for using [Preparation Example 15] as a reactant, the same procedure as in [Synthesis Example 5] was performed to obtain 15.5 g of the target compound; HRMS [M]+: 793.29

[합성예 1132] Mat 1132의 합성[Synthesis Example 1132] Synthesis of Mat 1132

Figure pat01226
Figure pat01226

반응물로 [준비예16]을 사용한 것을 제외하고는 [합성예 5]과 동일한 과정을 수행하여 목적 화합물 16.3g을 얻었다.; HRMS [M]+: 833.32Except for using [Preparation Example 16] as a reactant, the same procedure as in [Synthesis Example 5] was performed to obtain 16.3 g of the target compound; HRMS [M]+: 833.32

[합성예 1133] Mat 1133의 합성[Synthesis Example 1133] Synthesis of Mat 1133

Figure pat01227
Figure pat01227

반응물로 [준비예17]을 사용한 것을 제외하고는 [합성예 5]과 동일한 과정을 수행하여 목적 화합물 12.4g을 얻었다.; HRMS [M]+: 717.26Except for using [Preparation Example 17] as a reactant, the same procedure as in [Synthesis Example 5] was performed to obtain 12.4 g of the target compound; HRMS [M]+: 717.26

[합성예 1134] Mat 1134의 합성[Synthesis Example 1134] Synthesis of Mat 1134

Figure pat01228
Figure pat01228

반응물로 [준비예18]을 사용한 것을 제외하고는 [합성예 5]과 동일한 과정을 수행하여 목적 화합물 13.5g을 얻었다.; HRMS [M]+: 793.29Except for using [Preparation Example 18] as a reactant, the same procedure as in [Synthesis Example 5] was performed to obtain 13.5 g of the target compound; HRMS [M]+: 793.29

[합성예 1135] Mat 1135의 합성[Synthesis Example 1135] Synthesis of Mat 1135

Figure pat01229
Figure pat01229

반응물로 [준비예19]을 사용한 것을 제외하고는 [합성예 5]과 동일한 과정을 수행하여 목적 화합물 14.3g을 얻었다.; HRMS [M]+: 717.26Except for using [Preparation Example 19] as a reactant, the same procedure as in [Synthesis Example 5] was performed to obtain 14.3 g of the target compound; HRMS [M]+: 717.26

[합성예 1136] Mat 1136의 합성[Synthesis Example 1136] Synthesis of Mat 1136

Figure pat01230
Figure pat01230

반응물로 [준비예20]을 사용한 것을 제외하고는 [합성예 389]과 동일한 과정을 수행하여 목적 화합물 16.6g을 얻었다.; HRMS [M]+: 869.32Except for using [Preparation Example 20] as a reactant, the same procedure as in [Synthesis Example 389] was performed to obtain 16.6 g of the target compound; HRMS [M]+: 869.32

[합성예 1137] Mat 1137의 합성[Synthesis Example 1137] Synthesis of Mat 1137

Figure pat01231
Figure pat01231

반응물로 [준비예21]을 사용한 것을 제외하고는 [합성예 5]과 동일한 과정을 수행하여 목적 화합물 17.6g을 얻었다.; HRMS [M]+: 945.35Except for using [Preparation Example 21] as a reactant, the same procedure as in [Synthesis Example 5] was performed to obtain 17.6 g of the target compound; HRMS [M]+: 945.35

[합성예 1138] Mat 1138의 합성[Synthesis Example 1138] Synthesis of Mat 1138

Figure pat01232
Figure pat01232

반응물로 [준비예22]을 사용한 것을 제외하고는 [합성예 5]과 동일한 과정을 수행하여 목적 화합물 15.5g을 얻었다.; HRMS [M]+: 717.26Except for using [Preparation Example 22] as a reactant, 15.5 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 5]; HRMS [M]+: 717.26

[합성예 1139] Mat 1139의 합성[Synthesis Example 1139] Synthesis of Mat 1139

Figure pat01233
Figure pat01233

반응물로 [준비예23]을 사용한 것을 제외하고는 [합성예 5]과 동일한 과정을 수행하여 목적 화합물 13.1g을 얻었다.; HRMS [M]+: 717.26Except for using [Preparation Example 23] as a reactant, 13.1 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 5]; HRMS [M]+: 717.26

[합성예 1140] Mat 1140의 합성[Synthesis Example 1140] Synthesis of Mat 1140

Figure pat01234
Figure pat01234

반응물로 [준비예24]을 사용한 것을 제외하고는 [합성예 5]과 동일한 과정을 수행하여 목적 화합물 12.7g을 얻었다.; HRMS [M]+: 793.29Except for using [Preparation Example 24] as a reactant, 12.7 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 5]; HRMS [M]+: 793.29

[합성예 1141] Mat 1141의 합성[Synthesis Example 1141] Synthesis of Mat 1141

Figure pat01235
Figure pat01235

반응물로 [준비예25]을 사용한 것을 제외하고는 [합성예 5]과 동일한 과정을 수행하여 목적 화합물 15.8g을 얻었다.; HRMS [M]+: 869.32Except for using [Preparation Example 25] as a reactant, the same procedure as in [Synthesis Example 5] was performed to obtain 15.8 g of the target compound; HRMS [M]+: 869.32

[합성예 1142] Mat 1142의 합성[Synthesis Example 1142] Synthesis of Mat 1142

Figure pat01236
Figure pat01236

반응물로 [준비26]을 사용한 것을 제외하고는 [합성예 5]과 동일한 과정을 수행하여 목적 화합물 16.5g을 얻었다.; HRMS [M]+: 945.3516.5 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 5] except that [Preparation 26] was used as a reactant; HRMS [M]+: 945.35

[합성예 1143] Mat 1143의 합성[Synthesis Example 1143] Synthesis of Mat 1143

Figure pat01237
Figure pat01237

반응물로 [준비예27]을 사용한 것을 제외하고는 [합성예 1129]과 동일한 과정을 수행하여 목적 화합물 13.5g을 얻었다.; HRMS [M]+: 733.24Except for using [Preparation Example 27] as a reactant, the same procedure as in [Synthesis Example 1129] was performed to obtain 13.5 g of the target compound; HRMS [M]+: 733.24

[합성예 1144] Mat 1144의 합성[Synthesis Example 1144] Synthesis of Mat 1144

Figure pat01238
Figure pat01238

반응물로 [준비예28]을 사용한 것을 제외하고는 [합성예 1130]과 동일한 과정을 수행하여 목적 화합물 13.8g을 얻었다.; HRMS [M]+: 733.24Except for using [Preparation Example 28] as a reactant, the same procedure as in [Synthesis Example 1130] was performed to obtain 13.8 g of the target compound; HRMS [M]+: 733.24

[합성예 1145] Mat 1145의 합성[Synthesis Example 1145] Synthesis of Mat 1145

Figure pat01239
Figure pat01239

반응물로 [준비예29]을 사용한 것을 제외하고는 [합성예 1131]과 동일한 과정을 수행하여 목적 화합물 15.5g을 얻었다.; HRMS [M]+: 809.27Except for using [Preparation Example 29] as a reactant, the same procedure as in [Synthesis Example 1131] was performed to obtain 15.5 g of the target compound; HRMS [M]+: 809.27

[합성예 1146] Mat 1146의 합성[Synthesis Example 1146] Synthesis of Mat 1146

Figure pat01240
Figure pat01240

반응물로 [준비예30]을 사용한 것을 제외하고는 [합성예 1132]과 동일한 과정을 수행하여 목적 화합물 16.3g을 얻었다.; HRMS [M]+: 849.30Except for using [Preparation Example 30] as a reactant, the same procedure as in [Synthesis Example 1132] was performed to obtain 16.3 g of the target compound; HRMS [M]+: 849.30

[합성예 1147] Mat 1147의 합성[Synthesis Example 1147] Synthesis of Mat 1147

Figure pat01241
Figure pat01241

반응물로 [준비예31]을 사용한 것을 제외하고는 [합성예 1133]과 동일한 과정을 수행하여 목적 화합물 12.4g을 얻었다.; HRMS [M]+: 733.24Except for using [Preparation Example 31] as a reactant, the same procedure as in [Synthesis Example 1133] was performed to obtain 12.4 g of the target compound; HRMS [M]+: 733.24

[합성예 1148] Mat 1148의 합성[Synthesis Example 1148] Synthesis of Mat 1148

Figure pat01242
Figure pat01242

반응물로 [준비예32]을 사용한 것을 제외하고는 [합성예 1134]과 동일한 과정을 수행하여 목적 화합물 13.5g을 얻었다.; HRMS [M]+: 809.27Except for using [Preparation Example 32] as a reactant, 13.5 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 1134]; HRMS [M]+: 809.27

[합성예 1149] Mat 1149의 합성[Synthesis Example 1149] Synthesis of Mat 1149

Figure pat01243
Figure pat01243

반응물로 [준비예33]을 사용한 것을 제외하고는 [합성예 1135]과 동일한 과정을 수행하여 목적 화합물 14.3g을 얻었다.; HRMS [M]+: 733.24 Except for using [Preparation Example 33] as a reactant, the same procedure as in [Synthesis Example 1135] was performed to obtain 14.3 g of the target compound; HRMS [M]+: 733.24

[합성예 1150] Mat 1150의 합성[Synthesis Example 1150] Synthesis of Mat 1150

Figure pat01244
Figure pat01244

반응물로 [준비예34]을 사용한 것을 제외하고는 [합성예 1136]과 동일한 과정을 수행하여 목적 화합물 16.6g을 얻었다.; HRMS [M]+: 885.30Except for using [Preparation Example 34] as a reactant, the same procedure as in [Synthesis Example 1136] was performed to obtain 16.6 g of the target compound; HRMS [M]+: 885.30

[합성예 1151] Mat 1151의 합성[Synthesis Example 1151] Synthesis of Mat 1151

Figure pat01245
Figure pat01245

반응물로 [준비예35]을 사용한 것을 제외하고는 [합성예 1137]과 동일한 과정을 수행하여 목적 화합물 17.6g을 얻었다.; HRMS [M]+: 961.33Except for using [Preparation Example 35] as a reactant, the same procedure as in [Synthesis Example 1137] was performed to obtain 17.6 g of the target compound; HRMS [M]+: 961.33

[합성예 1152] Mat 1152의 합성[Synthesis Example 1152] Synthesis of Mat 1152

Figure pat01246
Figure pat01246

반응물로 [준비예36]을 사용한 것을 제외하고는 [합성예 1138]과 동일한 과정을 수행하여 목적 화합물 15.5g을 얻었다.; HRMS [M]+: 809.27Except for using [Preparation Example 36] as a reactant, the same procedure as in [Synthesis Example 1138] was performed to obtain 15.5 g of the target compound; HRMS [M]+: 809.27

[합성예 1153] Mat 1153의 합성[Synthesis Example 1153] Synthesis of Mat 1153

Figure pat01247
Figure pat01247

반응물로 [준비예37]을 사용한 것을 제외하고는 [합성예 1139]과 동일한 과정을 수행하여 목적 화합물 13.1g을 얻었다.; HRMS [M]+: 733.24Except for using [Preparation Example 37] as a reactant, the same procedure as in [Synthesis Example 1139] was performed to obtain 13.1 g of the target compound; HRMS [M]+: 733.24

[합성예 1154] Mat 1154의 합성[Synthesis Example 1154] Synthesis of Mat 1154

Figure pat01248
Figure pat01248

반응물로 [준비예38]을 사용한 것을 제외하고는 [합성예 1140]과 동일한 과정을 수행하여 목적 화합물 12.7g을 얻었다.; HRMS [M]+: 809.27Except for using [Preparation Example 38] as a reactant, the same procedure as in [Synthesis Example 1140] was performed to obtain 12.7 g of the target compound; HRMS [M]+: 809.27

[합성예 1155] Mat 1155의 합성[Synthesis Example 1155] Synthesis of Mat 1155

Figure pat01249
Figure pat01249

반응물로 [준비예39]을 사용한 것을 제외하고는 [합성예1141]과 동일한 과정을 수행하여 목적 화합물 15.8g을 얻었다.; HRMS [M]+: 885.3015.8 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 1141] except that [Preparation Example 39] was used as a reactant; HRMS [M]+: 885.30

[합성예 1156] Mat 1156의 합성[Synthesis Example 1156] Synthesis of Mat 1156

Figure pat01250
Figure pat01250

반응물로 [준비40]을 사용한 것을 제외하고는 [합성예 1142]과 동일한 과정을 수행하여 목적 화합물 16.5g을 얻었다.; HRMS [M]+: 961.3316.5 g of the target compound was obtained by performing the same procedure as in [Synthesis Example 1142] except that [Preparation 40] was used as a reactant; HRMS [M]+: 961.33

[실시예 1 ~ 21] 녹색 유기 EL 소자의 제작[Examples 1 to 21] Fabrication of green organic EL device

합성예 1~1156에서 합성한 화합물 Mat 1 ~ Mat 1156를 통상적으로 알려진 방법으로 고순도 승화정제를 한 후 아래의 과정에 따라 녹색 유기 EL 소자를 제작하였다.Compounds Mat 1 to Mat 1156 synthesized in Synthesis Examples 1 to 1156 were subjected to high-purity sublimation purification by a conventionally known method, and then green organic EL devices were manufactured according to the following process.

먼저, ITO (Indium tin oxide)가 1500Å 두께로 박막 코팅된 유리 기판을 증류수 초음파로 세척하였다. 증류수 세척이 끝나면 이소프로필 알코올, 아세톤, 메탄올 등의 용제로 초음파 세척을 하고 건조시킨 후 UV OZONE 세정기 (Power sonic 405, 화신테크)로 이송시킨 다음 UV를 이용하여 상기 기판을 5분간 세정하고 진공 증착기로 기판을 이송하였다.First, a glass substrate coated with ITO (Indium tin oxide) to a thickness of 1500 Å was washed with distilled water and ultrasonic waves. After washing with distilled water, it is ultrasonically washed with solvents such as isopropyl alcohol, acetone, and methanol, dried, transferred to a UV OZONE cleaner (Power Sonic 405, Hwashin Tech), and then cleaned by using UV for 5 minutes and vacuum evaporator The substrate was transferred to

이렇게 준비된 ITO 투명 전극 위에 m-MTDATA (60 nm)/TCTA (80 nm)/ Mat 1 ~ Mat 1156의 각각의 화합물 + 10 % Ir(ppy)3 (30nm)/BCP (10 nm)/Alq3 (30 nm)/LiF (1 nm)/Al (200 nm) 순으로 적층하여 유기 EL 소자를 제작하였다. m-MTDATA (60 nm)/TCTA (80 nm)/ Mat 1 ~ Mat 1156 + 10% Ir(ppy) 3 (30 nm)/BCP (10 nm)/Alq 3 ( 30 nm)/LiF (1 nm)/Al (200 nm) were laminated in this order to fabricate an organic EL device.

m-MTDATA, TCTA, Ir(ppy)3, CBP, C-3-F, C-2-F 및 BCP의 구조는 하기와 같다.The structures of m-MTDATA, TCTA, Ir(ppy) 3 , CBP, C-3-F, C-2-F and BCP are as follows.

Figure pat01251
Figure pat01251

Figure pat01252
Figure pat01252

[비교예 1] 녹색 유기 EL 소자의 제작[Comparative Example 1] Fabrication of green organic EL device

발광층 형성시 발광 호스트 물질로서 화합물 Mat 2 대신 CBP, C-3-F, C-2-F를 사용하는 것을 제외하고는 실시예 1과 동일한 과정으로 녹색 유기 EL 소자를 제작하였다.A green organic EL device was fabricated in the same manner as in Example 1 except for using CBP, C-3-F, and C-2-F instead of the compound Mat 2 as the light emitting host material when forming the light emitting layer.

[평가예][Evaluation example]

실시예 1 ~ 21 및 비교예 1에서 제작한 각각의 녹색 유기 EL 소자에 대하여 전류밀도 (10) mA/㎠에서의 구동전압, 전류효율 및 발광 피크를 측정하고, 그 결과를 하기 표 1에 나타내었다.For each of the green organic EL devices manufactured in Examples 1 to 21 and Comparative Example 1, driving voltage, current efficiency, and emission peak at current density (10) mA/cm 2 were measured, and the results are shown in Table 1 below. was

샘플Sample 호스트host 구동 전압
(V)driving voltage
(V) EL 피크
(nm)EL peak
(nm) 전류효율
(cd/A)current efficiency
(cd/A) 실시예 1Example 1 Mat 2Mat 2 6.806.80 516516 41.241.2 실시예 2Example 2 Mat 5Mat 5 6.776.77 516516 42.342.3 실시예 3Example 3 Mat 6Mat 6 6.836.83 516516 40.740.7 실시예 4Example 4 Mat 13Mat 13 6.806.80 516516 40.840.8 실시예 5Example 5 Mat 36Mat 36 6.826.82 516516 41.541.5 실시예 6Example 6 Mat 67Mat 67 6.796.79 516516 41.541.5 실시예 7Example 7 Mat 129Mat 129 6.816.81 516516 40.640.6 실시예 8Example 8 Mat 160Mat 160 6.806.80 516516 40.240.2 실시예 9Example 9 Mat 191Mat 191 6.806.80 516516 40.140.1 실시예 10Example 10 Mat 253Mat 253 6.816.81 516516 41.341.3 실시예 11Example 11 Mat 254Mat 254 6.806.80 516516 40.640.6 실시예 12Example 12 Mat 284Mat 284 6.806.80 516516 41.541.5 실시예 13Example 13 Mat 346Mat 346 6.806.80 516516 40.640.6 실시예 14Example 14 Mat 389Mat 389 6.826.82 516516 40.240.2 실시예 15Example 15 Mat 399Mat 399 6.796.79 516516 40.140.1 실시예 16Example 16 Mat 521Mat 521 6.816.81 516516 41.341.3 실시예 17Example 17 Mat 653Mat 653 6.806.80 516516 40.240.2 실시예 18Example 18 Mat 1130Mat 1130 6.806.80 516516 40.140.1 실시예 19Example 19 Mat 1131Mat 1131 6.816.81 516516 41.341.3 실시예 20Example 20 Mat 1134Mat 1134 6.806.80 516516 40.640.6 실시예 21Example 21 Mat 1144Mat 1144 6.806.80 516516 41.541.5 비교예 1Comparative Example 1 CBPCBP 6.93 6.93 516 516 38.2 38.2 비교예 2Comparative Example 2 C-3-FC-3-F 6.806.80 516516 40.240.2 비교예 3Comparative Example 3 C-2-FC-2-F 6.836.83 516516 39.939.9

상기 표1에 나타낸 바와 같이, 본 발명에 따른 화합물 (Mat 2 ~ Mat 1144)을 녹색 유기 EL 소자의 발광층으로 사용하였을 경우(실시예 1-21) 종래 CBP, C-3-F, C-2-F를 사용한 녹색 유기 EL 소자(비교예1)와 비교해 볼 때 효율 및 구동전압 면에서 보다 우수한 성능을 나타내는 것을 알 수 있다.As shown in Table 1, when the compound (Mat 2 to Mat 1144) according to the present invention was used as a light emitting layer of a green organic EL device (Example 1-21), conventional CBP, C-3-F, C-2 It can be seen that compared to the green organic EL device (Comparative Example 1) using -F, it exhibits better performance in terms of efficiency and driving voltage.

10: 양극 20: 음극
30: 유기층 31: 정공 수송층
32: 발광층 33: 정공 수송 보조층
34: 전자 수송층 35: 전자 수송 보조층
36: 전자 주입층 37: 정공 주입층10: anode 20: cathode
30: organic layer 31: hole transport layer
32: light emitting layer 33: hole transport auxiliary layer
34: electron transport layer 35: electron transport auxiliary layer
36: electron injection layer 37: hole injection layer

Claims (7)

하기 화학식 1로 표시되는 화합물:
[화학식 1]
Figure pat01253

상기 화학식 1에서,
m은 0 내지 4의 정수이고;
n은 0 내지 3의 정수이며;
Y는 S, O 및 C(R5)(R6)로 이루어진 군에서 선택되고;
L은 직접결합, C6~C18의 아릴렌기 및 핵원자수 5 내지 18개의 헤테로아릴렌기로 이루어진 군에서 선택되며;
R1 내지 R6는 각각 독립적으로 수소, 중수소, 할로겐, 시아노기, 니트로기, C1~C40의 알킬기, C2~C40의 알케닐기, C2~C40의 알키닐기, C3~C40의 시클로알킬기, 핵원자수 3 내지 40개의 헤테로시클로알킬기, C6~C60의 아릴기, 핵원자수 5 내지 60개의 헤테로아릴기, C1~C40의 알킬옥시기, C6~C60의 아릴옥시기, C3~C40의 알킬실릴기, C6~C60의 아릴실릴기, C1~C40의 알킬보론기, C6~C60의 아릴보론기, C6~C60의 아릴포스파닐기, C6~C60의 모노 또는 디아릴포스피닐기 및 C6~C60의 아릴아민기로 이루어진 군에서 선택되며; 상기 R1 내지 R4 각각이 복수 개인 경우 이들은 서로 동일하거나 상이하며;
Ar1은 하기 화학식 12로 표시되는 치환기이고;
[화학식 12]
Figure pat01254

상기 화학식 12에서,
*은 결합이 이루어지는 부분을 의미하고;
Z1, Z3 및 Z5는 N이며;
R10 및 R11은 각각 독립적으로 수소, C6~C60의 아릴기, 핵원자수 5 내지 60개의 헤테로아릴기로 이루어진 군에서 선택되나, Y가 C(R5)(R6)인 경우 R10 및 R11 중 적어도 어느 하나는 디벤조퓨란기, 디벤조싸이오펜기, 함질소 헤테로아릴기 또는 함질소 헤테로아릴기로 치환된 아릴기이며;
상기 R10 및 R11의 아릴기, 헤테로아릴기는 각각 독립적으로 중수소, 할로겐, 시아노기, 니트로기, C1~C40의 알킬기, C2~C40의 알케닐기, C2~C40의 알키닐기, C6~C60의 아릴기, 핵원자수 5 내지 60개의 헤테로아릴기, C6~C60의 아릴옥시기, C1~C40의 알킬옥시기, C6~C60의 아릴아민기, C3~C40의 시클로알킬기, 핵원자수 3 내지 40개의 헤테로시클로알킬기, C1~C40의 알킬실릴기, C1~C40의 알킬보론기, C6~C60의 아릴보론기, C6~C60의 아릴포스파닐기, C6~C60의 모노 또는 디아릴포스피닐기 및 C6~C60의 아릴실릴기로 이루어진 군에서 선택된 1종 이상의 치환기로 치환되거나 비치환되고, 복수 개의 치환기로 치환되는 경우, 이들은 서로 동일하거나 상이하며;
상기 R1 내지 R6의 알킬기, 알케닐기, 알키닐기, 아릴기, 헤테로아릴기, 아릴옥시기, 알킬옥시기, 시클로알킬기, 헤테로시클로알킬기, 아릴아민기, 알킬실릴기, 알킬보론기, 아릴보론기, 아릴포스파닐기, 모노 또는 디아릴포스피닐기 및 아릴실릴기는 각각 독립적으로 중수소, 할로겐, 시아노기, 니트로기, C1~C40의 알킬기, C2~C40의 알케닐기, C2~C40의 알키닐기, C6~C60의 아릴기, 핵원자수 5 내지 60개의 헤테로아릴기, C6~C60의 아릴옥시기, C1~C40의 알킬옥시기, C6~C60의 아릴아민기, C3~C40의 시클로알킬기, 핵원자수 3 내지 40개의 헤테로시클로알킬기, C1~C40의 알킬실릴기, C1~C40의 알킬보론기, C6~C60의 아릴보론기, C6~C60의 아릴포스파닐기, C6~C60의 모노 또는 디아릴포스피닐기 및 C6~C60의 아릴실릴기로 이루어진 군에서 선택된 1종 이상의 치환기로 치환되거나 비치환되고, 복수 개의 치환기로 치환되는 경우, 이들은 서로 동일하거나 상이하며;
단, Y가 S이고 L이 페닐렌기인 경우 R10 및 R11이 모두 비치환된 페닐기인 것은 제외하며, Y가 O이고 L이 직접결합 또는 페닐렌기인 경우, R10 및 R11이 모두 비치환된 페닐기인 것은 제외한다.A compound represented by Formula 1 below:
[Formula 1]
Figure pat01253

In Formula 1,
m is an integer from 0 to 4;
n is an integer from 0 to 3;
Y is selected from the group consisting of S, O and C(R 5 )(R 6 );
L is selected from the group consisting of a direct bond, a C 6 ~ C 18 arylene group, and a heteroarylene group having 5 to 18 nuclear atoms;
R 1 to R 6 are each independently hydrogen, deuterium, halogen, cyano group, nitro group, C 1 ~ C 40 alkyl group, C 2 ~ C 40 alkenyl group, C 2 ~ C 40 alkynyl group, C 3 ~ C 40 cycloalkyl group, 3 to 40 nuclear atoms heterocycloalkyl group, C 6 ~ C 60 aryl group, 5 to 60 nuclear atoms heteroaryl group, C 1 ~ C 40 alkyloxy group, C 6 ~ C 60 aryloxy group, C 3 ~ C 40 alkylsilyl group, C 6 ~ C 60 arylsilyl group, C 1 ~ C 40 alkylboron group, C 6 ~ C 60 arylboron group, C 6 ~ It is selected from the group consisting of a C 60 arylphosphanyl group, a C 6 ~ C 60 mono- or diarylphosphinyl group, and a C 6 ~ C 60 arylamine group; When each of R 1 to R 4 is plural, they are identical to or different from each other;
Ar 1 is a substituent represented by Formula 12;
[Formula 12]
Figure pat01254

In Formula 12,
* indicates the part where the bond is made;
Z 1 , Z 3 and Z 5 are N;
R 10 and R 11 are each independently selected from the group consisting of hydrogen, a C 6 ~ C 60 aryl group, and a heteroaryl group having 5 to 60 nuclear atoms, but when Y is C(R 5 )(R 6 ) R at least one of 10 and R 11 is an aryl group substituted with a dibenzofuran group, a dibenzothiophene group, a nitrogen-containing heteroaryl group, or a nitrogen-containing heteroaryl group;
The aryl group and heteroaryl group of R 10 and R 11 are each independently deuterium, halogen, cyano group, nitro group, C 1 ~ C 40 alkyl group, C 2 ~ C 40 alkenyl group, C 2 ~ C 40 alky Nyl group, C 6 ~ C 60 aryl group, heteroaryl group having 5 to 60 nuclear atoms, C 6 ~ C 60 aryloxy group, C 1 ~ C 40 alkyloxy group, C 6 ~ C 60 arylamine group, C 3 ~ C 40 cycloalkyl group, heterocycloalkyl group having 3 to 40 nuclear atoms, C 1 ~ C 40 alkylsilyl group, C 1 ~ C 40 alkyl boron group, C 6 ~ C 60 arylboron group, C 6 ~ C 60 arylphosphanyl group, C 6 ~ C 60 mono or diarylphosphinyl group, and C 6 ~ C 60 substituted or unsubstituted with one or more substituents selected from the group consisting of arylsilyl group, , When substituted with a plurality of substituents, they are the same as or different from each other;
Alkyl group, alkenyl group, alkynyl group, aryl group, heteroaryl group, aryloxy group, alkyloxy group, cycloalkyl group, heterocycloalkyl group, arylamine group, alkylsilyl group, alkyl boron group, aryl of R 1 to R 6 A boron group, an arylphosphanyl group, a mono- or diarylphosphinyl group, and an arylsilyl group are each independently deuterium, halogen, cyano group, nitro group, C 1 ~ C 40 alkyl group, C 2 ~ C 40 alkenyl group, C 2 ~ C 40 alkynyl group, C 6 ~ C 60 aryl group, heteroaryl group having 5 to 60 nuclear atoms, C 6 ~ C 60 aryloxy group, C 1 ~ C 40 alkyloxy group, C 6 ~C 60 arylamine group, C 3 ~C 40 cycloalkyl group, 3 to 40 nuclear atoms heterocycloalkyl group, C 1 ~C 40 alkylsilyl group, C 1 ~C 40 alkyl boron group, C 6 ~ C 60 arylboron group, C 6 ~ C 60 arylphosphanyl group, C 6 ~ C 60 mono or diarylphosphinyl group, and C 6 ~ C 60 arylsilyl group at least one selected from the group consisting of When substituted or unsubstituted with , and substituted with a plurality of substituents, they are the same as or different from each other;
However, when Y is S and L is a phenylene group, excluding R 10 and R 11 are both unsubstituted phenyl groups, and when Y is O and L is a direct bond or a phenylene group, both R 10 and R 11 are provided Ringed phenyl groups are excluded. 제1항에 있어서,
상기 화합물은 하기 화학식 2 내지 5 중 어느 하나로 표시되는, 화합물:
[화학식 2]
Figure pat01255

[화학식 3]
Figure pat01256

[화학식 4]
Figure pat01257

[화학식 5]
Figure pat01258

상기 화학식 2 내지 5에서,
R1 내지 R4, m, n, Y, L 및 Ar1은 제1항에서 정의된 바와 같다.According to claim 1,
The compound is represented by any one of Formulas 2 to 5, a compound:
[Formula 2]
Figure pat01255

[Formula 3]
Figure pat01256

[Formula 4]
Figure pat01257

[Formula 5]
Figure pat01258

In Formulas 2 to 5,
R 1 to R 4, m, n, Y, L and Ar 1 are as defined in claim 1. 제1항에 있어서,
상기 R1 내지 R4는 각각 독립적으로 C1~C40의 알킬기, C6~C60의 아릴기 및 핵원자수 5 내지 60개의 헤테로아릴기로 이루어진 군에서 선택되고,
상기 R1 내지 R4의 알킬기, 아릴기 및 헤테로아릴기는 각각 독립적으로 C1~C40의 알킬기, C6~C60의 아릴기 및 핵원자수 5 내지 60개의 헤테로아릴기로 이루어진 군에서 선택된 1종 이상의 치환기로 치환되거나 비치환되고, 복수 개의 치환기로 치환되는 경우, 이들은 서로 동일하거나 상이한 화합물. According to claim 1,
The R 1 to R 4 are each independently selected from the group consisting of a C 1 ~ C 40 alkyl group, a C 6 ~ C 60 aryl group, and a heteroaryl group having 5 to 60 nuclear atoms;
The alkyl group, aryl group and heteroaryl group of R 1 to R 4 are each independently selected from the group consisting of a C 1 ~ C 40 alkyl group, a C 6 ~ C 60 aryl group, and a heteroaryl group having 5 to 60 nuclear atoms. A compound which is unsubstituted or substituted with one or more substituents and, when substituted with a plurality of substituents, which are the same as or different from each other. 제1항에 있어서,
상기 L은 직접결합이거나, 하기 화학식 A-1 내지 A-4로 이루어진 군에서 선택된 링커인, 화합물:
Figure pat01259

상기 화학식 A-1 내지 A-4에서,
*는 결합이 이루어지는 부분을 의미한다.According to claim 1,
Wherein L is a direct bond or a linker selected from the group consisting of the following formulas A-1 to A-4:
Figure pat01259

In the above formulas A-1 to A-4,
* indicates the part where the coupling is made. 제1항에 있어서,
상기 화합물은 아래의 화합물로 이루어진 군에서 선택되는 것을 특징으로 하는 화합물:
Figure pat01260

Figure pat01261

Figure pat01262

Figure pat01263

Figure pat01264

Figure pat01265

Figure pat01266

Figure pat01267

Figure pat01268

Figure pat01269

Figure pat01270

Figure pat01271

Figure pat01272

Figure pat01273


Figure pat01274

Figure pat01275

Figure pat01276

Figure pat01277



Figure pat01278

Figure pat01279

Figure pat01280

Figure pat01281

Figure pat01282

Figure pat01283

Figure pat01284
According to claim 1,
A compound characterized in that the compound is selected from the group consisting of the following compounds:
Figure pat01260

Figure pat01261

Figure pat01262

Figure pat01263

Figure pat01264

Figure pat01265

Figure pat01266

Figure pat01267

Figure pat01268

Figure pat01269

Figure pat01270

Figure pat01271

Figure pat01272

Figure pat01273


Figure pat01274

Figure pat01275

Figure pat01276

Figure pat01277



Figure pat01278

Figure pat01279

Figure pat01280

Figure pat01281

Figure pat01282

Figure pat01283

Figure pat01284
 (i) 양극, (ii) 음극, 및 (iii) 상기 양극과 음극 사이에 개재(介在)된 1층 이상의 유기물층을 포함하는 유기 전계 발광 소자로서,
상기 1층 이상의 유기물층 중에서 적어도 하나는 제1항의 화학식 1로 표시되는 화합물을 포함하는 것을 특징으로 하는 유기 전계 발광 소자.(i) an anode, (ii) a cathode, and (iii) an organic electroluminescent device comprising one or more organic material layers interposed between the anode and the cathode,
An organic electroluminescent device characterized in that at least one of the one or more organic material layers includes a compound represented by Chemical Formula 1 of claim 1. 제6항에 있어서,
상기 유기물층은 정공 주입층, 정공 수송층, 정공 수송 보조층, 전자 수송층, 전자 수송 보조층 및 발광층으로 이루어진 군에서 선택되는 하나 이상의 층을 포함하는, 유기 전계 발광 소자.According to claim 6,
The organic material layer includes at least one layer selected from the group consisting of a hole injection layer, a hole transport layer, a hole transport auxiliary layer, an electron transport layer, an electron transport auxiliary layer, and a light emitting layer.
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