KR20190058748A - Organic light-emitting compound and organic electroluminescent device using the same - Google Patents

Abstract

The present invention relates to a novel compound and an organic electroluminescent device comprising the same. A compound according to the present invention is used for an organic layer, preferably a light emitting layer, an electron transport layer, or a hole transport layer, of the organic electroluminescent device, thereby being able to improve luminous efficiency, driving voltage, lifespan and the like of the organic electroluminescent device.

Description

TECHNICAL FIELD [0001] The present invention relates to an organic electroluminescent compound, and an organic electroluminescent device using the same. BACKGROUND ART [0002]

The present invention relates to a novel organic compound that can be used as a material for an organic electroluminescence device and an organic electroluminescence device including the same.

The electroluminescent (EL) devices that led to blue electroluminescence using anthracene single crystals in 1965 were followed up with the observation of organic thin film emission from Bernanose in the 1950s. In 1987, And a functional layer of a light-emitting layer. Thereafter, in order to form a high efficiency and high number of organic electroluminescent devices, each organic material layer has been developed into a form in which each organic material layer has been introduced into the device, leading to the development of specialized materials used therefor.

In the organic electroluminescent device, when a voltage is applied between two electrodes, holes are injected into the organic layer in the anode, and electrons are injected into the organic layer in the cathode. When the injected holes and electrons meet, an exciton is formed. When the exciton falls to the ground state, light is emitted. At this time, the material used as the organic material layer can be classified into a light emitting material, a hole injecting material, a hole transporting material, an electron transporting material, an electron injecting material and the like depending on its function.

The luminescent material can be classified into blue, green and red luminescent materials according to luminescent colors and yellow and orange luminescent materials to realize better natural colors. Further, in order to increase the color purity and increase the luminous efficiency through energy transfer, a host / dopant system can be used as a light emitting material.

The dopant material can be divided into a fluorescent dopant using an organic material and a phosphorescent dopant using a metal complex compound containing heavy atoms such as Ir and Pt. At this time, since the development of the phosphorescent material can theoretically improve the luminous efficiency up to 4 times as compared with the fluorescence, the phosphorescent dopant as well as phosphorescent host materials are being studied extensively.

To date, NPB, BCP and Alq ₃ have been widely known as the hole injecting layer, the hole transporting layer, the hole blocking layer and the electron transporting layer material, and anthracene derivatives have been reported as the light emitting layer material. Particularly, metal complex compounds containing Ir such as Firpic, Ir (ppy) ₃ , (acac) Ir (btp) ₂ and the like having advantages in terms of efficiency improvement of the light emitting layer material are blue, green, 4,4-dicarbazolybiphenyl (CBP) is used as a phosphorescent dopant material for red phosphorescent dopants.

However, conventional organic material layers are advantageous from the viewpoint of light emitting properties, but their thermal stability is not very good due to their low glass transition temperature, and thus they are not satisfactory in terms of lifetime of the organic electroluminescent device. Therefore, development of an organic layer material having excellent performance is required.

It is an object of the present invention to provide a novel organic compound which can be applied to an organic electroluminescent device and which is excellent in hole, electron injection, transporting ability, and light emitting ability.

It is another object of the present invention to provide an organic electroluminescent device including the novel organic compound and exhibiting a low driving voltage and a high luminous efficiency and having an improved lifetime.

In order to achieve the above object, the present invention provides a compound represented by the following formula (1): < EMI ID =

[Chemical Formula 1]

In Formula 1,

m is an integer from 0 to 4;

n is an integer from 0 to 3;

L ₁ and L ₂ are each independently selected from the group consisting of a direct bond, a C ₆ to C ₁₈ arylene group and a heteroarylene group having 5 to 18 nucleus atoms;

Ar ₁ is selected from the group consisting of hydrogen, deuterium, halogen, cyano, nitro, C ₁ to C ₄₀ alkyl, C ₂ to C ₄₀ alkenyl, C ₂ to C ₄₀ alkynyl, C ₃ to C ₄₀ cycloalkyl, A cycloalkyl group having 3 to 40 nuclear atoms, an aryl group having ₆ to ₆₀ carbon atoms, a heteroaryl group having 5 to 60 nuclear atoms, a C ₁ to C ₄₀ alkyloxy group, a C ₆ to C ₆₀ aryloxy group , A C ₃ to C ₄₀ alkylsilyl group, a C ₆ to C ₆₀ arylsilyl group, a C ₁ to C ₄₀ alkylboron group, a C ₆ to C ₆₀ arylboron group, a C ₆ to C ₆₀ arylphosphate group, C ₆ ~ C ₆₀ mono or diaryl phosphine blood group and a C ₆ ~, or selected from the group consisting of C ₆₀ aryl amine, the combination group adjacent to form a condensed ring;

Ar ₂ is selected from the group consisting of a C ₆ to C ₃₀ aryl group and a heteroaryl group having 5 to 11 nuclear atoms;

R ₁ and R ₂ are each independently hydrogen, deuterium, a halogen, a cyano group, a nitro group, C ₁ ~ alkynyl group of C ₄₀ alkyl group, C ₂ ~ C ₄₀ alkenyl group, C ₂ ~ C ₄₀ of, C ₃ ~ C ₄₀ cycloalkyl group, a number of nuclear atoms of 3 to 40 heterocycloalkyl group, C ₆ ~ C ₆₀ aryl group, the number of nuclear atoms of 5 to 60 heteroaryl group, C ₁ ~ alkyloxy group of C _40, C ₆ ~ aryloxy group of C _60, C ₃ ~ C ₄₀ alkylsilyl group, C group ₆ ~ C ₆₀ aryl silyl, C ₁ ~ arylboronic of C ₄₀ group of an alkyl boron, C ₆ ~ C ₆₀ group, C ₆ ~ mono or diaryl phosphine of C ₆₀ aryl phosphazene group, C ₆ ~ C ₆₀ of the blood group and a C ₆ ~ C ₆₀ selected from the group consisting of an aryl amine or adjacent groups bond to which they are attached may form a fused ring, wherein When there are a plurality of R ₁ and R ₂ each, they are the same as or different from each other;

Wherein L _1, and arylene group of L ₂ and the hetero arylene group, said Ar ₂ in the aryl group and the heteroaryl group, the R _1, R ₂ and the alkyl group of Ar _1, an alkenyl group, an alkynyl group, an aryl group, heteroaryl group , An aryloxy group, an alkyloxy group, a cycloalkyl group, a heterocycloalkyl group, an arylamine group, an alkylsilyl group, an alkylboron group, an arylboron group, an arylphosphonyl group, a mono- or diarylphosphinyl group and an arylsilyl group are each independently A halogen atom, a cyano group, a nitro group, a C ₁ to C ₄₀ alkyl group, a C ₂ to C ₄₀ alkenyl group, a C ₂ to C ₄₀ alkynyl group, a C ₆ to C ₆₀ aryl group, to 60 heteroaryl group, C ₆ ~ aryloxy C _60, C ₁ ~ C ₄₀ alkyloxy group of, C ₆ ~ C ₆₀ aryl amine group, C ₃ ~ C ₄₀ cycloalkyl group, a nuclear atoms 3 to 40 heterocycloalkyl group, C ₁ ~ C ₄₀ alkyl silyl group, a boron alkyl of _{C 1 ~ C 40, C 6} ~ C ₆₀ aryl group of boron, C ₆ ~ C ₆₀ aryl phosphazene group, C Substituted with ₆ ~ C ₆₀ mono or diaryl phosphine blood group and one substituent at least one selected from the group consisting arylsilyl of C ₆ ~ C ₆₀ of or is unsubstituted, in the case where the substitution of a plurality of substituents, they are same or different, Do.

The present invention provides an organic electroluminescent device including a cathode, a cathode, and at least one organic layer interposed between the anode and the cathode, wherein at least one of the organic layers includes one or more compounds represented by Formula 1 .

"Alkyl" in the present invention is a monovalent substituent derived from a linear or branched saturated hydrocarbon having 1 to 40 carbon atoms, and examples thereof include methyl, ethyl, propyl, isobutyl, sec-butyl, pentyl, iso-amyl, hexyl And the like, but are not limited thereto.

As used herein, the term " alkenyl " is a monovalent substituent derived from a linear or branched unsaturated hydrocarbon having 2 to 40 carbon atoms and having at least one carbon-carbon double bond. Examples thereof include vinyl, But are not limited to, allyl, isopropenyl, 2-butenyl, and the like.

The term " alkynyl " in the present invention is a monovalent substituent derived from a straight or branched chain unsaturated hydrocarbon having 2 to 40 carbon atoms and having at least one carbon-carbon triple bond. Examples thereof include ethynyl, , 2-propynyl, and the like, but are not limited thereto.

&Quot; Aryl " in the present invention means a monovalent substituent derived from a C6-C60 aromatic hydrocarbon having a single ring or a combination of two or more rings. Further, it is preferable that two or more rings are condensed with each other and only carbon atoms are contained as the ring-forming atoms (for example, the number of carbon atoms may be from 8 to 60) and the whole molecule is a non-aromacity monovalent Substituents may also be included. Examples of such aryl include, but are not limited to, phenyl, naphthyl, phenanthryl, anthryl, fluorenyl, and the like.

"Heteroaryl" in the present invention means a monovalent substituent derived from a monoheterocyclic or polyheterocyclic aromatic hydrocarbon having 5 to 60 nuclear atoms. Wherein one or more carbons, preferably one to three carbons, of the ring are substituted with a heteroatom selected from N, O, P, S and Se. In addition, it is preferable that two or more rings are pendant or condensed with each other, and include hetero atoms selected from N, O, P, S and Se besides carbon as a ring-forming atom, < / RTI > aromacity). Examples of such heteroaryls include 6-membered monocyclic rings such as pyridyl, pyrazinyl, pyrimidinyl, pyridazinyl, and triazinyl; Such as phenoxathienyl, indolizinyl, indolyl, purinyl, quinolyl, benzothiazole, carbazolyl, and the like. ring; Imidazolyl, 2-isoxazolyl, 2-pyridinyl, 2-pyrimidinyl, and the like, but are not limited thereto.

In the present invention, " aryloxy " means a monovalent substituent represented by RO-, and R represents aryl having 5 to 60 carbon atoms. Examples of such aryloxy include, but are not limited to, phenyloxy, naphthyloxy, diphenyloxy, and the like.

The term " alkyloxy " in the present invention means a monovalent substituent group represented by R'O-, wherein R 'represents 1 to 40 alkyl, and may be linear, branched or cyclic . ≪ / RTI > Examples of such alkyloxy include, but are not limited to, methoxy, ethoxy, n-propoxy, 1-propoxy, t-butoxy, n-butoxy, pentoxy and the like.

&Quot; Arylamine " in the present invention means an amine substituted with aryl having 6 to 60 carbon atoms.

&Quot; Cycloalkyl " in the present invention means a monovalent substituent derived from a monocyclic or polycyclic non-aromatic hydrocarbon having 3 to 40 carbon atoms. Examples of such cycloalkyls include, but are not limited to, cyclopropyl, cyclopentyl, cyclohexyl, norbornyl, adamantine, and the like.

&Quot; Heterocycloalkyl " in the present invention means a monovalent substituent derived from a non-aromatic hydrocarbon having 3 to 40 nuclear atoms, wherein at least one of the carbons, preferably one to three carbons, S or Se. ≪ / RTI > Examples of such heterocycloalkyls include, but are not limited to, morpholine, piperazine, and the like.

&Quot; Alkylsilyl " in the present invention is silyl substituted with alkyl having 1 to 40 carbon atoms, and " arylsilyl " means silyl substituted with aryl having 5 to 60 carbon atoms.

The term "aromatic ring" in the present invention means a monovalent substituent derived from an aromatic hydrocarbon having 6 to 60 carbon atoms, which is a single ring or a combination of two or more rings. Examples of such aromatic rings include, but are not limited to, phenyl, naphthyl, phenanthrenyl, anthrenyl, and the like.

The term "non-aromic condensed polycyclic" in the present invention refers to a non-aromatic condensed polycyclic ring having two or more rings condensed with each other and containing only carbon as a ring-forming atom, and the whole molecule having a non-aromacity Quot; means a group (e.g., having from 8 to 60 carbon atoms). Examples of the non-aromatic condensed polycyclic ring may include, but are not limited to, a fluorenyl group and the like.

&Quot; Aromatic heterocycle " in the present invention means a monoheterocyclic or polyheterocyclic aromatic hydrocarbon having 5 to 60 nuclear atoms. Wherein one or more carbons, preferably one to three carbons, of the ring are substituted with a heteroatom selected from N, O, P, S and Se. Also, two or more rings are pendant or condensed with each other, and include hetero atoms selected from N, O, P, S and Se in addition to carbon as a ring forming atom. Examples of such heteroaryls include 6-membered monocyclic rings such as pyridyl, pyrazinyl, pyrimidinyl, pyridazinyl, and triazinyl; Such as phenoxathienyl, indolizinyl, indolyl, purinyl, quinolyl, benzothiazole, carbazolyl, and the like. ring; Imidazolyl, 2-isoxazolyl, 2-pyridinyl, 2-pyrimidinyl, and the like, but are not limited thereto.

In the present invention, the term "non-aromatic condensed heterocyclic ring" means that two or more rings are condensed with each other and contain heteroatoms selected from N, O, P and S in addition to carbon as a ring-forming atom, Means a group having non-aromacity (e.g., having from 2 to 60 carbon atoms). Examples of the non-aromatic condensed heterocyclic ring include, but are not limited to, a carbazolyl group and the like.

The "condensed rings" in the present invention means condensed aliphatic rings, condensed aromatic rings, condensed heteroaliphatic rings, condensed heteroaromatic rings, or a combination thereof.

The compound represented by the general formula (1) of the present invention has excellent thermal stability and luminescent properties and can be used as a material of an organic material layer of an organic electroluminescent device.

In particular, when the compound represented by Formula 1 of the present invention is used as a phosphorescent host material, it is possible to produce an organic electroluminescent device having excellent light emitting performance, low driving voltage, high efficiency, and long life time, A full color display panel having improved performance and lifetime can be manufactured.

1 is a cross-sectional view of an organic electroluminescent device according to an embodiment of the present invention.
2 is a cross-sectional view of an organic electroluminescent device according to an embodiment of the present invention.

Hereinafter, the present invention will be described in detail.

One. New organic compounds

The novel compounds of the present invention can be represented by the following formula

[Chemical Formula 1]

In Formula 1,

m is an integer from 0 to 4;

n is an integer from 0 to 3;

L ₁ and L ₂ are each independently selected from the group consisting of a direct bond, a C ₆ to C ₁₈ arylene group and a heteroarylene group having 5 to 18 nucleus atoms;

Ar ₁ is selected from the group consisting of hydrogen, deuterium, halogen, cyano, nitro, C ₁ to C ₄₀ alkyl, C ₂ to C ₄₀ alkenyl, C ₂ to C ₄₀ alkynyl, C ₃ to C ₄₀ cycloalkyl, A cycloalkyl group having 3 to 40 nuclear atoms, an aryl group having ₆ to ₆₀ carbon atoms, a heteroaryl group having 5 to 60 nuclear atoms, a C ₁ to C ₄₀ alkyloxy group, a C ₆ to C ₆₀ aryloxy group , A C ₃ to C ₄₀ alkylsilyl group, a C ₆ to C ₆₀ arylsilyl group, a C ₁ to C ₄₀ alkylboron group, a C ₆ to C ₆₀ arylboron group, a C ₆ to C ₆₀ arylphosphate group, C ₆ ~ C ₆₀ mono or diaryl phosphine blood group and a C ₆ ~, or selected from the group consisting of C ₆₀ aryl amine, the combination group adjacent to form a condensed ring;

Ar ₂ is selected from the group consisting of a C ₆ to C ₃₀ aryl group and a heteroaryl group having 5 to 11 nuclear atoms;

R ₁ and R ₂ are each independently hydrogen, deuterium, a halogen, a cyano group, a nitro group, C ₁ ~ alkynyl group of C ₄₀ alkyl group, C ₂ ~ C ₄₀ alkenyl group, C ₂ ~ C ₄₀ of, C ₃ ~ C ₄₀ cycloalkyl group, a number of nuclear atoms of 3 to 40 heterocycloalkyl group, C ₆ ~ C ₆₀ aryl group, the number of nuclear atoms of 5 to 60 heteroaryl group, C ₁ ~ alkyloxy group of C _40, C ₆ ~ aryloxy group of C _60, C ₃ ~ C ₄₀ alkylsilyl group, C group ₆ ~ C ₆₀ aryl silyl, C ₁ ~ arylboronic of C ₄₀ group of an alkyl boron, C ₆ ~ C ₆₀ group, C ₆ ~ mono or diaryl phosphine of C ₆₀ aryl phosphazene group, C ₆ ~ C ₆₀ of the blood group and a C ₆ ~ C ₆₀ selected from the group consisting of an aryl amine or adjacent groups bond to which they are attached may form a fused ring, wherein When there are a plurality of R ₁ and R ₂ each, they are the same as or different from each other;

Wherein L _1, and arylene group of L ₂ and the hetero arylene group, said Ar ₂ in the aryl group and the heteroaryl group, the R _1, R ₂ and the alkyl group of Ar _1, an alkenyl group, an alkynyl group, an aryl group, heteroaryl group , An aryloxy group, an alkyloxy group, a cycloalkyl group, a heterocycloalkyl group, an arylamine group, an alkylsilyl group, an alkylboron group, an arylboron group, an arylphosphonyl group, a mono- or diarylphosphinyl group and an arylsilyl group are each independently A halogen atom, a cyano group, a nitro group, a C ₁ to C ₄₀ alkyl group, a C ₂ to C ₄₀ alkenyl group, a C ₂ to C ₄₀ alkynyl group, a C ₆ to C ₆₀ aryl group, to 60 heteroaryl group, C ₆ ~ aryloxy C _60, C ₁ ~ C ₄₀ alkyloxy group of, C ₆ ~ C ₆₀ aryl amine group, C ₃ ~ C ₄₀ cycloalkyl group, a nuclear atoms 3 to 40 heterocycloalkyl group, C ₁ ~ C ₄₀ alkyl silyl group, a boron alkyl of _{C 1 ~ C 40, C 6} ~ C ₆₀ aryl group of boron, C ₆ ~ C ₆₀ aryl phosphazene group, C Substituted with ₆ ~ C ₆₀ mono or diaryl phosphine blood group and one substituent at least one selected from the group consisting arylsilyl of C ₆ ~ C ₆₀ of or is unsubstituted, in the case where the substitution of a plurality of substituents, they are same or different, Do.

The novel compounds provided in the present invention can be obtained by reacting a nitrogen-containing heterocycle (for example, a nitrogen-containing heterocycle) in a basic skeleton in which a multiaryl ring or the like is substituted at the ortho position of carbazole with phenanthrene, triphenylene, naphthyl, anthracene, pyrene, (EWG) having a high electron absorbing property such as a pyridine group, a pyrimidine group, and a triazine group are bonded to each other to enhance bipolar characteristics of the whole molecule, thereby enhancing the bonding force between holes and electrons.

Since the compound represented by the formula (1) has higher molecular weight than the conventional material for an organic electroluminescence device, the compound has a high glass transition temperature and thus is excellent in thermal stability, and excellent in carrier transport ability and light emitting performance. Accordingly, when the compound of Formula 1 is used in the production of an organic electroluminescent device, the driving voltage, efficiency, lifetime, etc. of the device can be improved.

In addition, the compound represented by the formula (1) is a compound in which a steric hindrance is formed by substitution of a multiple aryl ring such as phenanthrene, triphenylene, naphthyl, anthracene, pyrene, I have. As a result, it is possible to prevent the exciton generated in the light emitting layer from being diffused to the electron transporting layer or the hole transporting layer adjacent to the light emitting layer. The number of the excitons contributing to light emission in the light emitting layer can be increased to improve the light emitting efficiency of the device and the durability and stability of the device can be improved and the lifetime of the device can be efficiently increased.

Therefore, the compound represented by the general formula (1), which is a representative claim structure of the present invention, is excellent in luminescence characteristics, and therefore, it is preferable to use any one of the hole injection layer, the hole transporting layer, the light emitting layer, the electron transporting layer, It can be used as a material. Preferably used as the material of the light emitting layer of green phosphorescence and red phosphorescence.

In particular, when the compound represented by Formula 1 of the present invention is used as a phosphorescent green n-type host or phosphorescent red host, an organic electroluminescent device having a lower driving voltage, higher efficiency, Further, a full color display panel having improved high efficiency and long life characteristics can also be manufactured.

Preferably used as a material of any one of a light emitting layer of green phosphorescence, an electron transporting layer and an electron transporting layer which is further laminated on the electron transporting layer. In addition, since the electron transporting layer has high triplet energy, it can exhibit excellent efficiency due to the triplet-triplet fusion (TTF) effect.

Further, it is possible to prevent the excitons generated in the light emitting layer from diffusing into the electron transporting layer or the hole transporting layer adjacent to the light emitting layer. The number of the excitons contributing to light emission in the light emitting layer can be increased to improve the light emitting efficiency of the device and the durability and stability of the device can be improved and the lifetime of the device can be efficiently increased. Most of the developed materials exhibit physical characteristics that can be driven at low voltage, thereby improving lifetime.

According to a preferred embodiment of the present invention, Ar ₂ may be selected from C ₆ to C ₃₀ aryl groups, and more preferably C ₆ to C ₂₀ aryl groups.

According to one preferred embodiment of the present invention, the compound may be represented by any one of the following formulas 2 to 7:

(2)

(3)

[Chemical Formula 4]

[Chemical Formula 5]

[Chemical Formula 6]

(7)

In the above formulas 2 to 7

p is an integer from 0 to 9;

q is an integer from 0 to 11;

r is an integer from 0 to 7;

R ₃ is selected from the group consisting of hydrogen, deuterium, halogen, cyano, nitro, C ₁ to C ₄₀ alkyl, C ₂ to C ₄₀ alkenyl, C ₂ to C ₄₀ alkynyl, C ₃ to C ₄₀ cycloalkyl, A cycloalkyl group having 3 to 40 nuclear atoms, an aryl group having ₆ to ₆₀ carbon atoms, a heteroaryl group having 5 to 60 nuclear atoms, a C ₁ to C ₄₀ alkyloxy group, a C ₆ to C ₆₀ aryloxy group , A C ₃ to C ₄₀ alkylsilyl group, a C ₆ to C ₆₀ arylsilyl group, a C ₁ to C ₄₀ alkylboron group, a C ₆ to C ₆₀ arylboron group, a C ₆ to C ₆₀ arylphosphate group, C ₆ ~ C ₆₀ combines mono or diaryl phosphine blood group and a C ₆ ~ tile to selected or adjacent from the group consisting of an aryl amine of the C ₆₀ to which they are attached may form a fused ring of, when the R ₃ is a plurality individual They are the same or different from each other;

Alkyl group of the R _3, an alkenyl group, an alkynyl group, an aryl group, a heteroaryl group, an aryloxy group, an alkyloxy group, a cycloalkyl group, a heterocycloalkyl group, an arylamine group, an alkylsilyl group, an alkyl boron group, an aryl boron group, A halogen atom, a cyano group, a nitro group, a C ₁ to C ₄₀ alkyl group, a C ₂ to C ₄₀ alkenyl group, a C ₂ to C ₄₀ alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted aryl group, _A C ₆ to C ₆₀ aryl group, a heteroaryl group having 5 to 60 nuclear atoms, a C ₆ to C ₆₀ aryloxy group, a C ₁ to C ₄₀ alkyloxy group, a C ₆ to C ₆₀ C ₃ to C ₄₀ cycloalkyl groups, 3 to 40 nucleus atom heterocycloalkyl groups, C ₁ to C ₄₀ alkylsilyl groups, C ₁ to C ₄₀ alkylboron groups, C ₆ to C ₆₀ the arylboronic group, one member selected from the group consisting of C ₆ ~ C ₆₀ aryl phosphazene group, C ₆ ~ C ₆₀ mono or diaryl phosphine of blood group and a C ₆ ~ C ₆₀ aryl group in the silyl It substituted with a substituent being unsubstituted or, if substituted by a plurality of substituents, they are same or different to each other;

Each of R ₁ , R _2, m, n, L ₁ , L ₂ and Ar ₁ is as defined in the above formula (1).

According to one embodiment of the present invention, the compound may be represented by any one of the following formulas (2 ') to (7'):

[Formula 2 ']

[Chemical Formula 3 ']

[Chemical Formula 4 ']

[Chemical Formula 5 ']

[Chemical Formula 6 ']

[Formula 7 ']

In the above formulas 2 'to 7'

Each of R ₁ , R _2, R _3, m, n, p, q, r, L ₁ , L ₂ and Ar ₁ is as defined in the above formulas 1 to 7.

According to one preferred embodiment of the present invention, the compound may be represented by any one of the following formulas (8) to (11).

[Chemical Formula 8]

[Chemical Formula 9]

[Chemical formula 10]

(11)

In the above formulas 8 to 11,

Each of R _1, R _2, m, n, L ₁ , L _2, Ar ₁ and Ar ₂ is as defined in the above formula (1).

According to one preferred embodiment of the present invention, it is preferable that the compound is a compound represented by any one of the above-mentioned formulas (8) to (11) because the driving voltage can be lowered and the luminous efficiency can be increased.

According to a preferred embodiment of the present invention, each of R ₁ and R ₂ is independently selected from the group consisting of a C ₁ to C ₄₀ alkyl group, a C ₆ to C ₆₀ aryl group and a heteroaryl group having 5 to 60 nuclear atoms Selected,

The alkyl, aryl and heteroaryl groups of R ₁ and R ₂ are each independently selected from the group consisting of a C ₁ to C ₄₀ alkyl group, a C ₆ to C ₆₀ aryl group, and a heteroaryl group having 5 to 60 nuclear atoms. And when they are substituted with a plurality of substituents, they are the same as or different from each other.

According to a preferred embodiment of the present invention, R ₁ and R ₂ are each independently selected from the group consisting of methyl, ethyl, propyl, butyl, pentyl, phenyl, biphenyl, pyridinyl, pyrimidinyl and triazinyl groups ≪ / RTI >

Wherein R ₁ and methyl groups in R _2, an ethyl group, a propyl group, a butyl group, a pentyl group, a phenyl group, a biphenyl group, a pyridinyl group, a pyrimidinyl group and a triazinyl group each independently C alkyl group of ₁ ~ C _40, C ₆ ~ An aryl group of C ₆₀ , and a heteroaryl group having 5 to 60 nuclear atoms, and when they are substituted with a plurality of substituents, they are the same as or different from each other.

According to a preferred embodiment of the present invention, R ₁ and R ₂ are each independently selected from the group consisting of methyl, ethyl, propyl, butyl, pentyl, phenyl, biphenyl, pyridinyl, pyrimidinyl and triazinyl groups ≪ / RTI >

The methyl group, ethyl group, propyl group, butyl group, pentyl group, phenyl group, biphenyl group, pyridinyl group, pyrimidinyl group and triazinyl group of R ₁ and R ₂ are each independently a methyl group, A phenyl group, a biphenyl group, a pyridinyl group, a pyrimidinyl group and a triazinyl group, and when they are substituted with a plurality of substituents, they are the same as or different from each other.

According to a preferred embodiment of the present invention, L ₁ and L ₂ are each independently a direct bond or a linker represented by any one of the following formulas A-1 to A-4, more preferably a direct bond Lt; RTI ID = 0.0 > A-1 < / RTI > or A-2:

In the above Formulas A-1 to A-4,

* Means the part where the combination is made.

According to a preferred embodiment of the present invention, Ar ₁ is selected from the group consisting of a C ₁ to C ₄₀ alkyl group, a C ₆ to C ₆₀ aryl group and a heteroaryl group having 5 to 60 nuclear atoms,

The alkyl, aryl and heteroaryl groups of Ar ₁ are each independently substituted with at least one substituent selected from the group consisting of a C ₁ to C ₄₀ alkyl group, a C ₆ to C ₆₀ aryl group, and a heteroaryl group having 5 to 60 nuclear atoms , And when they are substituted with a plurality of substituents, they are the same as or different from each other.

According to a preferred embodiment of the present invention, Ar ₁ is a group selected from the group consisting of methyl, ethyl, propyl, butyl, pentyl, phenyl, biphenyl, pyridinyl, pyrimidinyl, A pyridinyl group, a quinolinyl group, an isoquinolinyl group, a cinolinyl group, a quinoxalinyl group, and a quinazolinyl group,

The aryl group of Ar ₁ may be substituted with at least one substituent selected from the group consisting of methyl, ethyl, propyl, butyl, pentyl, phenyl, biphenyl, pyridinyl, The norbornyl group, the cinnolinyl group, the quinoxalinyl group and the quinazolinyl group are each independently selected from the group consisting of a C ₁ to C ₄₀ alkyl group, a C ₆ to C ₆₀ aryl group, and a heteroaryl group having 5 to 60 nuclear atoms, And when they are substituted with a plurality of substituents, they are the same as or different from each other.

According to a preferred embodiment of the present invention, Ar ₁ is a group selected from the group consisting of methyl, ethyl, propyl, butyl, pentyl, phenyl, biphenyl, pyridinyl, pyrimidinyl, A pyridinyl group, a quinolinyl group, an isoquinolinyl group, a cinolinyl group, a quinoxalinyl group, and a quinazolinyl group,

The aryl group of Ar ₁ may be substituted with at least one substituent selected from the group consisting of methyl, ethyl, propyl, butyl, pentyl, phenyl, biphenyl, pyridinyl, The norbornyl group, the norbornyl group, the norbornyl group, the norbornyl group, the norbornyl group, the norbornyl group, the norbornyl group, the phenanthryl group, Substituted or unsubstituted with at least one substituent selected from the group consisting of a halogen atom, a cyano group, a cyano group, a cyano group, a cyano group, a cyano group, a cyano group, a cyano group, They are the same or different from each other.

According to a preferred embodiment of the present invention, Ar ₁ may be a substituent represented by any of the following formulas 12 to 14:

[Chemical Formula 12]

[Chemical Formula 13]

[Chemical Formula 14]

In the above Formulas 12 to 14,

* Denotes the part where the bond is made;

Z ₁ to Z ₅ are each independently N or C (R ₄ );

k is an integer from 0 to 4;

R ₄ is selected from the group consisting of hydrogen, deuterium, halogen, cyano, nitro, C ₁ to C ₄₀ alkyl, C ₂ to C ₄₀ alkenyl, C ₂ to C ₄₀ alkynyl, C ₃ to C ₄₀ cycloalkyl, A cycloalkyl group having 3 to 40 nuclear atoms, an aryl group having ₆ to ₆₀ carbon atoms, a heteroaryl group having 5 to 60 nuclear atoms, a C ₁ to C ₄₀ alkyloxy group, a C ₆ to C ₆₀ aryloxy group , A C ₃ to C ₄₀ alkylsilyl group, a C ₆ to C ₆₀ arylsilyl group, a C ₁ to C ₄₀ alkylboron group, a C ₆ to C ₆₀ arylboron group, a C ₆ to C ₆₀ arylphosphate group, C ₆ ~ C ₆₀ mono or diaryl the Phosphinicosuccinic selected from the group the group consisting of C ₆ ~ with an aryl amine of the C ₆₀ or, by combining groups of neighboring case form a condensed ring, and individual said R ₄ is a plurality, they Are the same or different from each other;

R ₅ is hydrogen, deuterium, halogen, cyano, nitro, C ₁ to C ₄₀ alkyl, C ₂ to C ₄₀ alkenyl, C ₂ to C ₄₀ alkynyl, C ₃ to C ₄₀ cycloalkyl, A cycloalkyl group having 3 to 40 nuclear atoms, an aryl group having ₆ to ₆₀ carbon atoms, a heteroaryl group having 5 to 60 nuclear atoms, a C ₁ to C ₄₀ alkyloxy group, a C ₆ to C ₆₀ aryloxy group , A C ₃ to C ₄₀ alkylsilyl group, a C ₆ to C ₆₀ arylsilyl group, a C ₁ to C ₄₀ alkylboron group, a C ₆ to C ₆₀ arylboron group, a C ₆ to C ₆₀ arylphosphate group, C ₆ ~ C ₆₀ mono or diaryl the Phosphinicosuccinic selected from the group the group consisting of C ₆ ~ with an aryl amine of the C ₆₀ or, by combining groups of neighboring case to form a condensed ring, individual said R ₅ is plural, they Are the same or different from each other;

Alkyl groups of the R ₄ and R _5, an alkenyl group, an alkynyl group, an aryl group, a heteroaryl group, an aryloxy group, an alkyloxy group, a cycloalkyl group, a heterocycloalkyl group, an arylamine group, an alkylsilyl group, an alkyl boron group, an aryl A halogen atom, a cyano group, a nitro group, a C ₁ to C ₄₀ alkyl group, a C ₂ to C ₄₀ alkenyl group, a C ₂ to C ₄₀ alkenyl group, a C ₂ to C ₄₀ alkenyl group, ₂ ~ C ₄₀ alkynyl group, C ₆ ~ C ₆₀ aryl group, the number of nuclear atoms of 5 to 60 heteroaryl group, C ₆ ~ aryloxy C _60, C ₁ ~ alkyloxy group of C ₄₀ of, C ₆ ~ C ₆₀ arylamine group, C ₃ ~ C ₄₀ cycloalkyl group, a number of nuclear atoms of 3 to 40 heterocycloalkyl group, C ₁ ~ alkyl silyl group of C _40, C ₁ ~ C ₄₀ group of an alkyl boron, C ₆ ~ C ₆₀ aryl group of boron, C ₆ ~ C ₆₀ aryl phosphazene group, C ₆ ~ C ₆₀ mono or diaryl phosphine blood group and a C ₆ ~ C ₆₀ aryl silyl group selected from the group consisting of 1 And when they are substituted with a plurality of substituents, they are the same as or different from each other.

According to a preferred embodiment of the present invention, R ₅ may be selected from the group consisting of a C ₁ to C ₃₀ alkyl group, a C ₆ to C ₃₀ aryl group, and a heteroaryl group having 5 to 30 nuclear atoms.

According to a preferred embodiment of the present invention, R ₅ may be selected from the group consisting of phenyl, biphenyl, naphthalenyl, pyridinyl, pyrimidinyl and triazinyl groups.

According to a preferred embodiment of the present invention, the substituent represented by the formula (12) may be a substituent represented by the following formula (15)

[Chemical Formula 15]

In Formula 15,

* Denotes the part where the bond is made;

R ₆ and R ₇ are each independently hydrogen, deuterium, a halogen, a cyano group, a nitro group, C ₁ ~ alkynyl group of C ₄₀ alkyl group, C ₂ ~ C ₄₀ alkenyl group, C ₂ ~ C ₄₀ of, C ₃ ~ C ₄₀ cycloalkyl group, a number of nuclear atoms of 3 to 40 heterocycloalkyl group, C ₆ ~ C ₆₀ aryl group, the number of nuclear atoms of 5 to 60 heteroaryl group, C ₁ ~ alkyloxy group of C _40, C ₆ ~ aryloxy group of C _60, C ₃ ~ C ₄₀ alkylsilyl group, C group ₆ ~ C ₆₀ aryl silyl, C ₁ ~ arylboronic of C ₄₀ group of an alkyl boron, C ₆ ~ C ₆₀ group, C ₆ ~ for C ₆₀ aryl phosphazene group, it said shed some light selected from the group consisting of an arylamine C ₆ ~ C ₆₀ mono or diaryl phosphine blood group and a C ₆ ~ C ₆₀ of;

Alkyl group of the R ₆ and R _7, an alkenyl group, an alkynyl group, an aryl group, a heteroaryl group, an aryloxy group, an alkyloxy group, a cycloalkyl group, a heterocycloalkyl group, an arylamine group, an alkylsilyl group, an alkyl boron group, an aryl A halogen atom, a cyano group, a nitro group, a C ₁ to C ₄₀ alkyl group, a C ₂ to C ₄₀ alkenyl group, a C ₂ to C ₄₀ alkenyl group, a C ₂ to C ₄₀ alkenyl group, ₂ ~ C ₄₀ alkynyl group, C ₆ ~ C ₆₀ aryl group, the number of nuclear atoms of 5 to 60 heteroaryl group, C ₆ ~ aryloxy C _60, C ₁ ~ alkyloxy group of C ₄₀ of, C ₆ ~ C ₆₀ arylamine group, C ₃ ~ C ₄₀ cycloalkyl group, a number of nuclear atoms of 3 to 40 heterocycloalkyl group, C ₁ ~ alkyl silyl group of C _40, C ₁ ~ C ₄₀ group of an alkyl boron, C ₆ ~ C ₆₀ aryl group of boron, C ₆ ~ C ₆₀ aryl phosphazene group, C ₆ ~ C ₆₀ mono or diaryl phosphine blood group and a C ₆ ~ C ₆₀ aryl silyl group selected from the group consisting of 1 When substituted with a plurality of substituents, they are the same as or different from each other;

Each of Z ₁ , Z ₃ and Z ₅ is as defined in the above formula (12).

According to a preferred embodiment of the present invention, the substituent represented by the formula (12) may be a substituent represented by any one of the following formulas (B-1) to (B-3)

In the above Formulas B-1 to B-3,

* Denotes the part where the bond is made,

R ₆ and R ₇ are each independently hydrogen, deuterium, a halogen, a cyano group, a nitro group, C ₁ ~ alkynyl group of C ₄₀ alkyl group, C ₂ ~ C ₄₀ alkenyl group, C ₂ ~ C ₄₀ of, C ₃ ~ C ₄₀ cycloalkyl group, a number of nuclear atoms of 3 to 40 heterocycloalkyl group, C ₆ ~ C ₆₀ aryl group, the number of nuclear atoms of 5 to 60 heteroaryl group, C ₁ ~ alkyloxy group of C _40, C ₆ ~ aryloxy group of C _60, C ₃ ~ C ₄₀ alkylsilyl group, C group ₆ ~ C ₆₀ aryl silyl, C ₁ ~ arylboronic of C ₄₀ group of an alkyl boron, C ₆ ~ C ₆₀ group, C ₆ ~ for C ₆₀ aryl phosphazene group, C ₆ ~ C ₆₀ mono or diaryl phosphine blood group and a C ₆ ~ is selected from the group consisting of an aryl amine of the C ₆₀ of the;

Alkyl group of the R ₆ and R _7, an alkenyl group, an alkynyl group, an aryl group, a heteroaryl group, an aryloxy group, an alkyloxy group, a cycloalkyl group, a heterocycloalkyl group, an arylamine group, an alkylsilyl group, an alkyl boron group, an aryl A halogen atom, a cyano group, a nitro group, a C ₁ to C ₄₀ alkyl group, a C ₂ to C ₄₀ alkenyl group, a C ₂ to C ₄₀ alkenyl group, a C ₂ to C ₄₀ alkenyl group, ₂ ~ C ₄₀ alkynyl group, C ₆ ~ C ₆₀ aryl group, the number of nuclear atoms of 5 to 60 heteroaryl group, C ₆ ~ aryloxy C _60, C ₁ ~ alkyloxy group of C ₄₀ of, C ₆ ~ C ₆₀ arylamine group, C ₃ ~ C ₄₀ cycloalkyl group, a number of nuclear atoms of 3 to 40 heterocycloalkyl group, C ₁ ~ alkyl silyl group of C _40, C ₁ ~ C ₄₀ group of an alkyl boron, C ₆ ~ C ₆₀ aryl group of boron, C ₆ ~ C ₆₀ aryl phosphazene group, C ₆ ~ C ₆₀ mono or diaryl phosphine blood group and a C ₆ ~ C ₆₀ aryl silyl group selected from the group consisting of 1 And when they are substituted with a plurality of substituents, they are the same as or different from each other.

According to a preferred embodiment of the present invention, R ₆ and R ₇ are each independently selected from the group consisting of a C ₁ to C ₄₀ alkyl group, a C ₆ to C ₆₀ aryl group and a heteroaryl group having 5 to 60 nuclear atoms Selected;

The alkyl, aryl and heteroaryl groups of R ₆ and R ₇ are each independently selected from the group consisting of a C ₁ to C ₄₀ alkyl group, a C ₆ to C ₆₀ aryl group and a heteroaryl group having 5 to 60 nuclear atoms. And when they are substituted with a plurality of substituents, they are the same as or different from each other.

According to a preferred embodiment of the present invention, R ₆ and R ₇ are each independently selected from the group consisting of a C ₁ to C ₄₀ alkyl group, a C ₆ to C ₆₀ aryl group and a heteroaryl group having 5 to 60 nuclear atoms Selected;

The alkyl, aryl and heteroaryl groups of R ₆ and R ₇ are each independently selected from the group consisting of a C ₁ to C ₄₀ alkyl group, a C ₆ to C ₆₀ aryl group and a heteroaryl group having 5 to 60 nuclear atoms. And when they are substituted with a plurality of substituents, they are the same as or different from each other.

According to a preferred embodiment of the present invention, each of R ₆ and R ₇ may independently be selected from the group consisting of a phenyl group, a biphenyl group, a pyridinyl group, a pyrimidinyl group, a triazinyl group and a naphthalenyl group,

The phenyl group, biphenyl group, pyridinyl group, pyrimidinyl group, triazinyl group and naphthalenyl group of R ₆ and R ₇ are each independently a C ₁ to C ₄₀ alkyl group, a C ₆ to C ₆₀ aryl group, A substituted or unsubstituted heteroaryl group, a substituted or unsubstituted heteroaryl group, a substituted or unsubstituted heteroaryl group, a substituted or unsubstituted heteroaryl group, and a substituted or unsubstituted heteroaryl group;

According to a preferred embodiment of the present invention, R ₆ and R ₇ each independently may be selected from the group consisting of a phenyl group, a biphenyl group, a pyridinyl group, a pyrimidinyl group, a triazinyl group and a naphthalenyl group, Preferably a phenyl group, a biphenyl group, and a pyridinyl group,

The phenyl group, biphenyl group, pyridinyl group, pyrimidinyl group, triazinyl group and naphthalenyl group of R ₆ and R ₇ each independently represents a methyl group, an ethyl group, a butyl group, a propyl group, a pentyl group, And when they are substituted with a plurality of substituents, they are the same as or different from each other.

According to a preferred embodiment of the present invention, the substituent represented by the formula (13) may be a substituent represented by the following formula (C-1) or (C-2)

In the above formula (C-1) or (C-2)

* Denotes the part where the bond is made,

k, R ₄ and R ₅ are each as defined in the above formula (13).

According to a preferred embodiment of the present invention, R ₄ and R ₅ are each independently selected from the group consisting of a C ₁ to C ₄₀ alkyl group, a C ₆ to C ₆₀ aryl group and a heteroaryl group having 5 to 60 nuclear atoms Selected;

The alkyl, aryl and heteroaryl groups of R ₄ and R ₅ are each independently selected from the group consisting of a C ₁ to C ₄₀ alkyl group, a C ₆ to C ₆₀ aryl group and a heteroaryl group having 5 to 60 nuclear atoms. And when they are substituted with a plurality of substituents, they are the same as or different from each other.

According to a preferred embodiment of the present invention, R ₄ and R ₅ are each independently selected from the group consisting of a C ₁ to C ₄₀ alkyl group, a C ₆ to C ₆₀ aryl group and a heteroaryl group having 5 to 60 nuclear atoms Selected;

The alkyl, aryl and heteroaryl groups of R ₄ and R ₅ are each independently selected from the group consisting of a C ₁ to C ₄₀ alkyl group, a C ₆ to C ₆₀ aryl group and a heteroaryl group having 5 to 60 nuclear atoms. And when they are substituted with a plurality of substituents, they are the same as or different from each other.

According to a preferred embodiment of the present invention, R ₄ and R ₅ are each independently selected from the group consisting of a phenyl group, a biphenyl group, a pyridinyl group, a pyrimidinyl group, a triazinyl group and a naphthalenyl group,

The phenyl, biphenyl, pyridinyl, pyrimidinyl, triazinyl and naphthalenyl groups of R ₄ and R ₅ are each independently a C ₁ to C ₄₀ alkyl group, a C ₆ to C ₆₀ aryl group, A substituted or unsubstituted heteroaryl group, a substituted or unsubstituted heteroaryl group, a substituted or unsubstituted heteroaryl group, a substituted or unsubstituted heteroaryl group, and a substituted or unsubstituted heteroaryl group;

According to a preferred embodiment of the present invention, each of R ₄ and R ₅ may independently be selected from the group consisting of a phenyl group, a biphenyl group, a pyridinyl group, a pyrimidinyl group, a triazinyl group and a naphthalenyl group, Preferably a phenyl group, a biphenyl group, and a pyridinyl group,

The phenyl group, biphenyl group, pyridinyl group, pyrimidinyl group, triazinyl group and naphthalenyl group of R ₄ and R ₅ each independently represents a methyl group, an ethyl group, a butyl group, a propyl group, a pentyl group, And when they are substituted with a plurality of substituents, they are the same as or different from each other.

The compounds represented by formula (1) of the present invention can be represented by the following compounds, but are not limited thereto:

The compounds of formula 1 of the present invention can be synthesized according to the general synthetic methods ( Chem. Rev. , 60 : 313 (1960); J. Chem . SOC . 4482 (1955); Chem. Rev. 95: 2457 (1995 ). Detailed synthesis of the compound of the present invention will be described in detail in Synthesis Examples to be described later.

2. abandonment Field  Light emitting element

Another aspect of the present invention relates to an organic electroluminescent device (organic EL device) comprising the compound represented by the general formula (1) according to the present invention described above.

Specifically, the present invention is an organic electroluminescent device comprising an anode, a cathode, and one or more organic layers sandwiched between the anode and the cathode, wherein at least one of the one or more organic layers includes Include compounds represented by the above formula (1). At this time, the compounds may be used singly or in combination of two or more.

The at least one organic material layer may be at least one of a hole injecting layer, a hole transporting layer, a light emitting layer, a light emitting auxiliary layer, a life improving layer, an electron transporting layer, an electron transporting auxiliary layer and an electron injecting layer, 1 < / RTI >

The structure of the organic electroluminescent device according to the present invention is not particularly limited. For example, referring to FIG. 1, an anode 10 and a cathode 20 facing each other, 20). ≪ / RTI > Here, the organic layer 30 may include a hole transport layer 31, a light emitting layer 32, and an electron transport layer 34. A hole transporting auxiliary layer 33 may be interposed between the hole transporting layer 31 and the light emitting layer 32. An electron transporting auxiliary layer 35 may be interposed between the electron transporting layer 34 and the light emitting layer 32 can do.

2, the organic layer 30 may further include a hole injection layer 37 between the hole transport layer 31 and the anode 10, and the electron transport layer 34 and the cathode And an electron injection layer (36) may be further included between the first electrode (20) and the second electrode (20).

In the present invention, the hole injection layer 37 deposited between the hole transport layer 31 and the anode 10 improves the interfacial properties between the ITO used as the anode and the organic material used as the hole transport layer 31 But the surface of the ITO layer is applied to the upper surface of the ITO which is not planarized to soften the surface of the ITO. The layer can be used without any particular limitation as long as it is commonly used in the art. For example, an amine compound can be used But is not limited thereto.

The electron injection layer 36 is a layer which is stacked on the electron transport layer 34 to facilitate injection of electrons from the cathode to ultimately improve power efficiency and is commonly used in the art . For example, materials such as LiF, Liq, NaCl, CsF, Li2O, and BaO can be used.

In addition, although not shown in the drawings, the light emitting layer 32 may further include a light emitting auxiliary layer between the hole transporting auxiliary layer 33 and the light emitting layer 32. The light-emission-assisting layer may serve to adjust the thickness of the organic layer 30 while serving to transport holes to the light-emitting layer 32. The light-emission-assisting layer may include a hole-transporting material and may be made of the same material as the hole-transporting layer 31.

In addition, although not shown in the drawings, a life improving layer may be further included between the electron transporting auxiliary layer 35 and the light emitting layer 32. Holes moving in the organic light emitting device due to the ionization potential level in the light emitting layer 32 are blocked by the high energy barrier of the lifetime enhancing layer and do not diffuse or move to the electron transporting layer and consequently function to limit the holes to the light emitting layer . The function of restricting the holes to the light emitting layer prevents diffusion of holes to the electron transporting layer that transports electrons by reduction, thereby suppressing the lifetime degradation due to the irreversible decomposition reaction by oxidation and contributing to improvement in the lifetime of the organic light emitting device .

The novel compounds provided in the present invention can be obtained by reacting a nitrogen-containing heterocycle (for example, a nitrogen-containing heterocycle) in a basic skeleton in which a multiaryl ring or the like is substituted at the ortho position of carbazole with phenanthrene, triphenylene, naphthyl, anthracene, pyrene, (EWG) having a high electron absorbing property such as a pyridine group, a pyrimidine group, and a triazine group are bonded to each other to enhance bipolar characteristics of the whole molecule, thereby enhancing the bonding force between holes and electrons.

The materials represented by Formula 1 are structurally characteristic to be bonded with core core and EWG (electron withdrawing group), and have excellent electron mobility and excellent high glass transition temperature and thermal stability. In addition, the holes and electrons transferred to the light emitting layer have excellent charge balance in the materials having the structure of Formula 1, so that the exciton generation is excellent, and the energy transfer efficiency to the dopant is high, thereby improving the luminous efficiency of the device and improving the durability and stability of the device. So that the lifetime of the device can be efficiently increased. Most of the developed materials exhibit physical characteristics that enable low-voltage operation and thereby improve lifetime.

Therefore, the compound represented by the general formula (1), which is a representative claim structure of the present invention, is excellent in luminescence characteristics, and therefore, it is preferable to use any one of the hole injection layer, the hole transporting layer, the light emitting layer, the electron transporting layer, It can be used as a material. Preferably used as the material of the light emitting layer of green phosphorescence and red phosphorescence.

More preferably, it can be used as a material of any one of a light emitting layer of green or red phosphorescence, an electron transporting layer, and an electron transporting layer which is further laminated on the electron transporting layer. In addition, since the electron transporting layer has high triplet energy, it can exhibit excellent efficiency due to the triplet-triplet fusion (TTF) effect.

Further, it is possible to prevent the excitons generated in the light emitting layer from diffusing into the electron transporting layer or the hole transporting layer adjacent to the light emitting layer. The number of the excitons contributing to light emission in the light emitting layer can be increased to improve the light emitting efficiency of the device and the durability and stability of the device can be improved and the lifetime of the device can be efficiently increased. Most of the developed materials exhibit physical characteristics that can be driven at low voltage, thereby improving lifetime.

In addition, the organic electroluminescent device according to the present invention may further include an insulating layer or an adhesive layer at the interface between the electrode and the organic layer as well as the anode, one or more organic layers and the cathode sequentially laminated as described above.

The organic electroluminescent device of the present invention includes materials and methods known in the art, except that at least one or more of the organic material layers (for example, the electron transporting auxiliary layer) is formed to include the compound represented by Formula 1 To form another organic material layer and an electrode.

The organic material layer may be formed by a vacuum deposition method or a solution coating method. Examples of the solution coating method include, but are not limited to, spin coating, dip coating, doctor blading, inkjet printing, or thermal transfer.

The substrate usable in the present invention is not particularly limited, and a silicon wafer, quartz, a glass plate, a metal plate, a plastic film and a sheet can be used.

The anode material may be made of a conductor having a high work function to facilitate injection of holes, for example, metals such as vanadium, chromium, copper, zinc, and gold or alloys thereof; Metal oxides such as zinc oxide, indium oxide, indium tin oxide (ITO), and indium zinc oxide (IZO); ZnO: Al or SnO _2: a combination of a metal and an oxide such as Sb; Conductive polymers such as polythiophene, poly (3-methylthiophene), poly [3,4- (ethylene-1,2-dioxy) thiophene] (PEDT), polypyrrole or polyaniline; And carbon black, but are not limited thereto.

The negative electrode material may be made of a conductor having a low work function so as to facilitate electron injection and may be made of a material having a low work function such as magnesium, calcium, sodium, potassium, titanium, indium, yttrium, lithium, gadolinium, aluminum, silver, The same metal or an alloy thereof; And multi-layer structure materials such as LiF / Al or LiO ₂ / Al, but are not limited thereto.

Hereinafter, the present invention will be described in detail with reference to examples. However, the following examples are illustrative of the present invention, and the present invention is not limited by the following examples.

Example

[Preparation Example 1]

Synthesis of 1- (phenanthrene-9-yl) -9H-carbazole

(50 g, 203 mmol), 4,4,5,5-tetramethyl-2- (phenanthrene-9-yl) -1,3,2-dioxaborol (67.8 g, 223 mmol), K2CO3 (56.1 g, 406 mmol), Pd (PPh3) 4 (11.7 g, 10.15 mmol) and 200 ml / 200 ml / 40 ml of toluene / EtOH / H2O were stirred at 100 ° C for 8 hours . After completion of the reaction, the reaction mixture was extracted with methylene chloride, concentrated under reduced pressure, and then subjected to column chromatography to obtain 61.3 g (88%) of the target compound.

GC-Mass (theory: 343.14 g / mol, measured: 343.43 g / mol)

(M, 2H), 7.90 (d, 1H), 8.08 (d, 1H) 1H), 7.70-7.63 (m, 5H), 7.50-7.48 (m, 2H), 7.20 (t,

[Preparation Example 2]

Synthesis of 1- (triphenylene-2-yl) -9H-carbazole

The same procedure as in [Preparation Example 1] was repeated except that 4,4,5,5-tetramethyl-2- (triphenylene-2-yl) -1,3,2-dioxaborolane was used as a reactant To obtain 50 g of the target compound;

 GC-Mass (calculated: 393.15 g / mol, measured: 393.49 g / mol)

[Preparation Example 3]

Synthesis of 1- (naphthalen-1-yl) -9H-carbazole

The same procedure as in [Preparation Example 1] was carried out except that 4,4,5,5-tetramethyl-2- (naphthalen-1-yl) -1,3,2-dioxaborolane was used as a reactant To obtain 38 g of the target compound;

 GC-Mass (293.19 g / mol, measured: 293.37 g / mol)

[Preparation Example 4]

Synthesis of 1- (anthracene-9-yl) -9H-carbazole

The same procedure as in [Preparation Example 1] was carried out except that 2- (anthracene-9-yl) -4,4,5,5-tetramethyl-1,3,2-dioxaborolane was used as a reactant To obtain 47 g of the target compound;

 GC-Mass (theory: 343.14 g / mol, measured: 343.43 g / mol)

[Preparation Example 5]

Synthesis of 1- (pyrene-1-yl) -9H-carbazole

Except that 2- (3a1,6-dihydropyren-1-yl) -4,4,5,5-tetramethyl-1,3,2-dioxaborolane was used as a reactant in Preparation Example 1 ] To obtain 42 g of the target compound;

 GC-Mass (calculated: 367.14 g / mol, measured: 367.45 g / mol)

[Preparation Example 6]

Synthesis of 1- (fluoranthen-3-yl) -9H-carbazole

The same procedure as in [Preparation Example 1] was repeated except that 2- (fluoranthene-3-yl) -4,4,5,5-tetramethyl-1,3,2-dioxaborolane was used as a reactant To obtain 46 g of the desired compound;

 GC-Mass (calculated: 367.14 g / mol, measured: 367.45 g / mol)

[Preparation Example 7]

Synthesis of 1- (phenanthren-9-yl) -6-phenyl-9H-carbazole

The procedure of Preparation Example 1 was repeated except that 1-bromo-6-phenyl-9H-carbazole was used as a reactant, to obtain 46 g of the title compound;

 GC-Mass (theory: 419.17 g / mol, measured: 419.53 g / mol)

[Preparation Example 8]

Synthesis of 6-phenyl-1- (triphenylene-2-yl) -9H-carbazole

The procedure of Preparation Example 2 was repeated except that 1-bromo-6-phenyl-9H-carbazole was used as a reactant, to obtain 50 g of the target compound;

 GC-Mass (calculated: 469.18 g / mol, measured: 469.59 g / mol)

[Preparation Example 9]

Synthesis of 1- (naphthalen-1-yl) -6-phenyl-9H-carbazole

The procedure of Preparation Example 3 was repeated except that 1-bromo-6-phenyl-9H-carbazole was used as a reactant, to obtain 38 g of the target compound;

 GC-Mass (calculated: 369.15 g / mol, measured: 369.47 g / mol)

[Preparation Example 10]

Synthesis of 1- (anthracene-9-yl) -6-phenyl-9H-carbazole

The procedure of Preparation Example 4 was repeated except that 1-bromo-6-phenyl-9H-carbazole was used as a reactant to obtain 47 g of the target compound;

 GC-Mass (theory: 419.17 g / mol, measured: 419.53 g / mol)

[Preparation Example 11]

Synthesis of 6-phenyl-1- (pyrene-1-yl) -9H-carbazole

The procedure of Preparation Example 5 was repeated except that 1-bromo-6-phenyl-9H-carbazole was used as a reactant to obtain 42 g of the target compound;

 GC-Mass (calculated: 443.17 g / mol, measured: 443.55 g / mol)

[Preparation Example 12]

Synthesis of 1- (fluoranthen-3-yl) -6-phenyl-9H-carbazole

The procedure of Preparation Example 6 was repeated except that 1-bromo-6-phenyl-9H-carbazole was used as a reactant to obtain 46 g of the title compound;

 GC-Mass (calculated: 443.17 g / mol, measured: 443.55 g / mol)

[Preparation Example 13]

Synthesis of 1- (phenanthrene-9-yl) -3-phenyl-9H-carbazole

The procedure of Preparation Example 1 was repeated except that 1-bromo-3-phenyl-9H-carbazole was used as a reactant, to obtain 46 g of the title compound;

 GC-Mass (theory: 419.17 g / mol, measured: 419.53 g / mol)

[Preparation Example 14]

Synthesis of 3-phenyl-1- (triphenylene-2-yl) -9H-carbazole

The procedure of Preparation Example 2 was repeated except that 1-bromo-3-phenyl-9H-carbazole was used as a reactant to obtain 50 g of the target compound;

 GC-Mass (calculated: 469.18 g / mol, measured: 469.59 g / mol)

[Preparation Example 15]

Synthesis of 1- (naphthalen-1-yl) -3-phenyl-9H-carbazole

The procedure of Preparation Example 3 was repeated except that 1-bromo-3-phenyl-9H-carbazole was used as a reactant, to obtain 38 g of the title compound;

 GC-Mass (calculated: 369.15 g / mol, measured: 369.47 g / mol)

[Preparation Example 16]

Synthesis of 1- (anthracene-9-yl) -3-phenyl-9H-carbazole

The procedure of Preparation Example 4 was repeated except that 1-bromo-3-phenyl-9H-carbazole was used as the reactant, to thereby yield 47 g of the target compound.

 GC-Mass (theory: 419.17 g / mol, measured: 419.53 g / mol)

[Preparation Example 17]

Synthesis of 3-phenyl-1- (pyrene-1-yl) -9H-carbazole

The procedure of Preparation Example 5 was repeated except that 1-bromo-3-phenyl-9H-carbazole was used as a reactant to obtain 42 g of the target compound;

 GC-Mass (calculated: 443.17 g / mol, measured: 443.55 g / mol)

[Preparation Example 18]

Synthesis of 1- (fluoranthene-3-yl) -3-phenyl-9H-carbazole

The procedure of Preparation Example 6 was repeated except that 1-bromo-3-phenyl-9H-carbazole was used as a reactant, to obtain 46 g of the title compound;

 GC-Mass (calculated: 443.17 g / mol, measured: 443.55 g / mol)

[Preparation Example 19]

Synthesis of 1- (phenanthrene-9-yl) -3,6-diphenyl-9H-carbazole

The procedure of Preparation Example 1 was repeated except that 1-bromo-3,6-diphenyl-9H-carbazole was used as a reactant to obtain 46 g of the target compound;

 GC-Mass (theory: 495.20 g / mol, measured: 495.69 g / mol)

[Preparation Example 20]

Synthesis of 3,6-diphenyl-1- (triphenylene-2-yl) -9H-carbazole

The procedure of Preparation Example 2 was repeated except that 1-bromo-3,6-diphenyl-9H-carbazole was used as a reactant, to obtain 50 g of the target compound;

 GC-Mass (calculated: 545.21 g / mol, measured: 545.69 g / mol)

[Preparation Example 21]

Synthesis of 1- (naphthalen-1-yl) -3,6-diphenyl-9H-carbazole

The procedure of Preparation Example 3 was repeated except that 1-bromo-3,6-diphenyl-9H-carbazole was used as a reactant, to obtain 38 g of the title compound;

 GC-Mass (calculated: 445.18 g / mol, measured: 445.57 g / mol)

[Preparation Example 22]

Synthesis of 1- (anthracene-9-yl) -3,6-diphenyl-9H-carbazole

The procedure of Preparation Example 4 was repeated except that 1-bromo-3,6-diphenyl-9H-carbazole was used as a reactant to obtain 47 g of the target compound;

 GC-Mass (theory: 492.20 g / mol, measured: 492.63 g / mol)

[Preparation Example 23]

Synthesis of 3,6-diphenyl-1- (pyrene-1-yl) -9H-carbazole

The procedure of Preparation Example 5 was repeated except that 1-bromo-3,6-diphenyl-9H-carbazole was used as a reactant to obtain 42 g of the target compound;

 GC-Mass (theory: 519.20 g / mol, measurement: 519.65 g / mol)

[Preparation Example 24]

Synthesis of 1- (fluoranthen-3-yl) -3,6-diphenyl-9H-carbazole

The procedure of Preparation Example 6 was repeated except that 1-bromo-3,6-diphenyl-9H-carbazole was used as a reactant to obtain 46 g of the title compound;

 GC-Mass (theory: 519.20 g / mol, measurement: 519.65 g / mol)

[Preparation Example 25]

Synthesis of 6- (dibenzo [b, d] furan-4-yl) -1- (phenanthrene-9-yl) -9H-carbazole

The procedure of Preparation Example 1 was repeated except that 1-bromo-6- (dibenzo [b, d] furan-4-yl) -9H-carbazole was used as a reactant to obtain 46 g of the title compound .;

 GC-Mass (calculated: 509.18 g / mol, measured: 509.61 g / mol)

[Preparation Example 26]

Synthesis of 6- (dibenzo [b, d] furan-4-yl) -1- (triphenylene-2-yl) -9H-carbazole

The procedure of Preparation Example 2 was repeated except that 1-bromo-6- (dibenzo [b, d] furan-4-yl) -9H-carbazole was used as a reactant, .;

 GC-Mass (calculated: 599.19 g / mol, measured: 599.67 g / mol)

[Preparation Example 27]

Synthesis of 6- (dibenzo [b, d] furan-4-yl) -1- (naphthalen-1-yl) -9H-carbazole

The procedure of Preparation Example 3 was repeated except for using 1-bromo-6- (dibenzo [b, d] furan-4-yl) -carbazole as a reactant to obtain 38 g of the title compound .;

 GC-Mass (459.16 g / mol, measured: 459.55 g / mol)

[Preparation Example 28]

Synthesis of 1- (anthracene-9-yl) -6- (dibenzo [b, d] furan-4-yl) -9H-carbazole

The procedure of Preparation Example 4 was repeated except that 1-bromo-6- (dibenzo [b, d] furan-4-yl) -9H-carbazole was used as a reactant to obtain 47 g of the title compound .;

 GC-Mass (calculated: 509.18 g / mol, measured: 509.61 g / mol)

[Preparation Example 29]

Synthesis of 6- (dibenzo [b, d] furan-4-yl) -1- (pyrene- 1-yl) -9H-carbazole

The procedure of Preparation Example 5 was repeated except that 1-bromo-6- (dibenzo [b, d] furan-4-yl) -9H-carbazole was used as a reactant to obtain 42 g of the target compound .;

 GC-Mass (calculated: 533.18 g / mol, measured: 533.63 g / mol)

[Preparation Example 30]

Synthesis of 6- (dibenzo [b, d] furan-4-yl) -1- (fluoranthene-3-yl) -9H-carbazole

The procedure of Preparation Example 6 was repeated except that 1-bromo-6- (dibenzo [b, d] furan-4-yl) -9H-carbazole was used as a reactant to obtain 46 g of the title compound .;

 GC-Mass (calculated: 533.18 g / mol, measured: 533.63 g / mol)

[Preparation Example 31]

Synthesis of 8- (phenanthren-9-yl) -7H-benzo [c] carbazole

The procedure of Preparation Example 1 was repeated except that 8-bromo-7H-benzo [c] carbazole was used as a reactant to obtain 50 g of the target compound;

 GC-Mass (calculated: 393.15 g / mol, measured: 393.49 g / mol)

[Preparation Example 32]

Synthesis of 8- (triphenylene-2-yl) -7H-benzo [c] carbazole

The procedure of Preparation Example 2 was repeated except that 8-bromo-7H-benzo [c] carbazole was used as a reactant to obtain 50 g of the target compound;

 GC-Mass (calculated: 443.17 g / mol, measured: 443.55 g / mol)

[Preparation Example 33]

Synthesis of 8- (naphthalen-1-yl) -7H-benzo [c] carbazole

The procedure of Preparation Example 3 was repeated except that 8-bromo-7H-benzo [c] carbazole was used as the reactant, to obtain 38 g of the title compound;

 GC-Mass (theory: 343.14 g / mol, measured: 343.43 g / mol)

[Preparation Example 34]

Synthesis of 8- (anthracene-9-yl) -7H-benzo [c] carbazole

The procedure of Preparation Example 4 was repeated except that 8-bromo-7H-benzo [c] carbazole was used as a reactant, to obtain 47 g of the title compound;

 GC-Mass (calculated: 393.15 g / mol, measured: 393.49 g / mol)

[Preparation Example 35]

Synthesis of 8- (pyrene-1-yl) -7H-benzo [c] carbazole

The procedure of Preparation Example 5 was repeated except that 8-bromo-7H-benzo [c] carbazole was used as a reactant to obtain 42 g of the target compound;

 GC-Mass (theory: 417.15 g / mol, measured: 417.51 g / mol)

[Preparation Example 36]

Synthesis of 8- (fluoranthen-3-yl) -7H-benzo [c] carbazole

The procedure of Preparation Example 6 was repeated except that 8-bromo-7H-benzo [c] carbazole was used as a reactant, to obtain 46 g of the title compound;

 GC-Mass (theory: 417.15 g / mol, measured: 417.51 g / mol)

[Preparation Example 37]

Synthesis of 4- (phenanthrene-9-yl) -5H-benzo [b] carbazole

The procedure of Preparation Example 1 was repeated except that 4-bromo-5H-benzo [b] carbazole was used as a reactant to obtain 50 g of the target compound;

 GC-Mass (calculated: 393.15 g / mol, measured: 393.49 g / mol)

[Preparation Example 38]

Synthesis of 4- (triphenylene-2-yl) -5H-benzo [b] carbazole

The procedure of Preparation Example 2 was repeated except that 4-bromo-5H-benzo [b] carbazole was used as a reactant to obtain 50 g of the target compound;

 GC-Mass (calculated: 443.17 g / mol, measured: 443.55 g / mol)

[Preparation Example 39]

Synthesis of 4- (naphthalen-1-yl) -5H-benzo [b] carbazole

The procedure of Preparation Example 3 was repeated except that 4-bromo-5H-benzo [b] carbazole was used as a reactant to obtain 38 g of the target compound;

 GC-Mass (theory: 343.14 g / mol, measured: 343.43 g / mol)

[Preparation Example 40]

Synthesis of 4- (anthracene-9-yl) -5H-benzo [b] carbazole

The procedure of Preparation Example 4 was repeated except that 4-bromo-5H-benzo [b] carbazole was used as a reactant to obtain 47 g of the target compound;

 GC-Mass (calculated: 393.15 g / mol, measured: 393.49 g / mol)

[Preparation Example 41]

Synthesis of 4- (pyrene-1-yl) -5H-benzo [b] carbazole

The procedure of Preparation Example 5 was repeated except that 4-bromo-5H-benzo [b] carbazole was used as a reactant to obtain 42 g of the title compound;

 GC-Mass (theory: 417.15 g / mol, measured: 417.51 g / mol)

[Preparation Example 42]

Synthesis of 4- (fluoranthen-3-yl) -5H-benzo [b] carbazole

The procedure of Preparation Example 6 was repeated except that 4-bromo-5H-benzo [b] carbazole was used as a reactant to obtain 46 g of the target compound;

 GC-Mass (theory: 417.15 g / mol, measured: 417.51 g / mol)

[Preparation Example 43]

Synthesis of 10- (phenanthrene-9-yl) -11H-benzo [a] carbazole

The procedure of Preparation Example 1 was repeated except that 10-bromo-11H-benzo [a] carbazole was used as a reactant to obtain 50 g of the target compound;

 GC-Mass (calculated: 393.15 g / mol, measured: 393.49 g / mol)

[Preparation Example 44]

Synthesis of 10- (triphenylene-2-yl) -11H-benzo [a] carbazole

The procedure of Preparation Example 2 was repeated except that 10-bromo-11H-benzo [a] carbazole was used as the reactant, to obtain 50 g of the target compound;

 GC-Mass (calculated: 443.17 g / mol, measured: 443.55 g / mol)

[Preparation Example 45]

Synthesis of 10- (naphthalen-1-yl) -11H-benzo [a] carbazole

The procedure of Preparation Example 3 was repeated except that 10-bromo-11H-benzo [a] carbazole was used as a reactant, to obtain 38 g of the title compound;

 GC-Mass (theory: 343.14 g / mol, measured: 343.43 g / mol)

[Preparation Example 46]

Synthesis of 10- (anthracene-9-yl) -11H-benzo [a] carbazole

The procedure of Preparation Example 4 was repeated except that 10-bromo-11H-benzo [a] carbazole was used as the reactant, to obtain 47 g of the title compound;

 GC-Mass (calculated: 393.15 g / mol, measured: 393.49 g / mol)

[Preparation Example 47]

Synthesis of 10- (pyrene-1-yl) -11H-benzo [a] carbazole

The procedure of Preparation Example 5 was repeated except that 10-bromo-11H-benzo [a] carbazole was used as a reactant to obtain 42 g of the target compound;

 GC-Mass (theory: 417.15 g / mol, measured: 417.51 g / mol)

[Preparation Example 48]

Synthesis of 10- (fluoranthene-3-yl) -11H-benzo [a] carbazole

The procedure of Preparation Example 6 was repeated except that 10-bromo-11H-benzo [a] carbazole was used as a reactant, to obtain 46 g of the title compound;

 GC-Mass (theory: 417.15 g / mol, measured: 417.51 g / mol)

[Preparation Example 49]

Synthesis of 10- (phenanthren-9-yl) -9H-dibenzo [a, c] carbazole

The procedure of Preparation Example 1 was repeated except that 10-bromo-9H-dibenzo [a, c] carbazole was used as the reactant, to obtain 50 g of the target compound.

 GC-Mass (calculated: 443.17 g / mol, measured: 443.55 g / mol)

[Preparation Example 50]

Synthesis of 10- (triphenylene-2-yl) -9H-dibenzo [a, c]

The procedure of Preparation Example 2 was repeated except that 10-bromo-9H-dibenzo [a, c] carbazole was used as a reactant, to obtain 50 g of the title compound;

 GC-Mass (theory: 493.18 g / mol, measured: 493.61 g / mol)

[Preparation Example 51]

Synthesis of 10- (naphthalen-1-yl) -9H-dibenzo [a, c]

The procedure of Preparation Example 3 was repeated except that 10-bromo-9H-dibenzo [a, c] carbazole was used as a reactant, to obtain 38 g of the title compound.

 GC-Mass (calculated: 393.15 g / mol, measured: 393.49 g / mol)

[Preparation Example 52]

Synthesis of 10- (anthracene-9-yl) -9H-dibenzo [a, c] carbazole

The procedure of Preparation Example 4 was repeated except that 10-bromo-9H-dibenzo [a, c] carbazole was used as the reactant, to obtain 47 g of the target compound;

 GC-Mass (calculated: 443.17 g / mol, measured: 443.55 g / mol)

[Preparation Example 53]

Synthesis of 10- (pyrene-1-yl) -9H-dibenzo [a, c]

The procedure of Preparation Example 5 was repeated except that 10-bromo-9H-dibenzo [a, c] carbazole was used as a reactant, to obtain 42 g of the target compound;

 GC-Mass (calculated: 467.17 g / mol, measured: 467.57 g / mol)

[Preparation Example 54]

Synthesis of 10- (fluoranthene-3-yl) -9H-dibenzo [a, c]

The procedure of Preparation Example 6 was repeated except that 10-bromo-9H-dibenzo [a, c] carbazole was used as a reactant, to obtain 46 g of the target compound;

 GC-Mass (calculated: 467.17 g / mol, measured: 467.57 g / mol)

[Preparation Example 55]

Synthesis of 1- (3- (phenanthren-9-yl) phenyl) -9H-carbazole

Except that 4,4,5,5-tetramethyl-2- (3- (phenanthrene-9-yl) phenyl) -1,3,2-dioxaborolane was used as a reactant in Preparation Example 1 ] To obtain the title compound (50 g);

 GC-Mass (theory: 419.17 g / mol, measured: 419.53 g / mol)

[Preparation Example 56]

Synthesis of 9- (3- (triphenylene-2-yl) phenyl) -9H-carbazole

Except that 4,4,5,5-tetramethyl-2- (3- (triphenylene-2-yl) phenyl) -1,3,2-dioxaborolane was used as the reactant 1] was carried out to obtain 50 g of the objective compound;

 GC-Mass (calculated: 469.59 g / mol, measured: 469.59 g / mol)

[Preparation Example 57]

Synthesis of 1- (4- (phenanthren-9-yl) phenyl) -9H-carbazole

Except that 4,4,5,5-tetramethyl-2- (4- (phenanthrene-9-yl) phenyl) -1,3,2-dioxaborolane was used as a reactant in Preparation Example 1 ] To obtain the title compound (50 g);

 GC-Mass (theory: 419.17 g / mol, measured: 419.53 g / mol)

[Preparation Example 58]

Synthesis of 9- (4- (triphenylene-2-yl) phenyl) -9H-carbazole

Except that 4,4,5,5-tetramethyl-2- (4- (triphenylene-2-yl) phenyl) -1,3,2-dioxaborolane was used as a reactant 1] was carried out to obtain 50 g of the objective compound;

 GC-Mass (calculated: 469.59 g / mol, measured: 469.59 g / mol)

[Preparation Example 59]

Synthesis of 1- (3- (naphthalen-1-yl) phenyl) -9H-carbazole

Except that 4,4,5,5-tetramethyl-2- (3- (triphenylene-2-yl) phenyl) -1,3,2-dioxaborolane was used as the reactant 1] to obtain the title compound (38 g);

 GC-Mass (calculated: 469.18 g / mol, measured: 469.59 g / mol)

[Preparation Example 60]

Synthesis of 1- (3- (anthracen-9-yl) phenyl) -9H-carbazole

[Preparation Example 1] Except that 2- (3- (anthracen-9-yl) phenyl) -4,4,5,5-tetramethyl-1,3,2-dioxaborolane was used as a reactant, , The desired compound (47 g) was obtained.

 GC-Mass (theory: 419.17 g / mol, measured: 419.53 g / mol)

[Preparation Example 61]

Synthesis of 9- (3- (pyrene-1-yl) phenyl) -9H-carbazole

Except that 2- (3- (1,5a1-dihydropyren-1-yl) phenyl) -4,4,5,5-tetramethyl-1,3,2-dioxaborolane was used as a reactant Was subjected to the same procedure as in [Preparation Example 1] to obtain 42 g of the desired compound;

 GC-Mass (calculated: 443.17 g / mol, measured: 443.55 g / mol)

[Preparation Example 62]

Synthesis of 1- (3- (fluoranthen-3-yl) phenyl) -9H-carbazole

Except that 2- (3- (fluoranthene-3-yl) phenyl) -4,4,5,5-tetramethyl-1,3,2-dioxaborolane was used as the reactant in Preparation Example 1] to obtain 46 g of the target compound;

 GC-Mass (calculated: 443.17 g / mol, measured: 443.55 g / mol)

[Preparation Example 63]

Synthesis of 1- (phenanthren-9-yl) -6-phenyl-9H-carbazole

Except that 4,4,5,5-tetramethyl-2- (3- (phenanthrene-9-yl) phenyl) -1,3,2-dioxaborolane was used as a reactant in Preparation Example 7 ] To obtain 46 g of the target compound.

 GC-Mass (theory: 495.20 g / mol, measured: 495.63 g / mol)

[Preparation Example 64]

Synthesis of 6-phenyl-1- (3- (triphenylene-2-yl) phenyl) -9H-carbazole

Except that 4,4,5,5-tetramethyl-2- (3- (triphenylene-2-yl) phenyl) -1,3,2-dioxaborolane was used as the reactant 7] to obtain the target compound (50 g).

 GC-Mass (calculated: 545.21 g / mol, measured: 545.69 g / mol)

[Preparation Example 65]

Synthesis of 1- (3- (naphthalen-1-yl) phenyl) -6-phenyl-9H-carbazole

[Preparation Example 7] Except that 4,4,5,5-tetramethyl-2- (3- (naphthalen-1-yl) phenyl) -1,3,2-dioxaborolane was used as a reactant, , The target compound (38 g) was obtained.

 GC-Mass (calculated: 445.17 g / mol, measured: 445.55 g / mol)

[Preparation Example 66]

Synthesis of 1- (3- (anthracen-9-yl) phenyl) -6-phenyl-9H-carbazole

[Preparation Example 7] Except that 2- (3- (anthracen-9-yl) phenyl) -4,4,5,5-tetramethyl-1,3,2-dioxaborolane was used as a reactant, , The desired compound (47 g) was obtained.

 GC-Mass (theory: 495.20 g / mol, measured: 495.63 g / mol)

[Preparation Example 67]

Synthesis of 6-phenyl-1- (3- (pyrene-1-yl) phenyl) -9H-carbazole

Except that 2- (3- (3a1,6-dihydropyren-1-yl) phenyl) -4,4,5,5-tetramethyl-1,3,2-dioxaborolane was used as a reactant Was subjected to the same procedure as in [Preparation Example 7] to obtain 42 g of the desired compound.

 GC-Mass (calculated: 443.17 g / mol, measured: 443.55 g / mol)

[Preparation Example 68]

Synthesis of 1- (fluoranthen-3-yl) -6-phenyl-9H-carbazole

The procedure of Preparation Example 7 was repeated except that 1-bromo-6-phenyl-9H-carbazole was used as a reactant to obtain 46 g of the title compound.

 GC-Mass (theory: 519.20 g / mol, measurement: 519.65 g / mol)

[Preparation Example 69]

Synthesis of 1- (3- (phenanthren-9-yl) phenyl) -3-phenyl-9H-carbazole

Except that 4,4,5,5-tetramethyl-2- (3- (phenanthrene-9-yl) phenyl) -1,3,2-dioxaborolane was used as a reactant in Preparation Example 13 ] To obtain 46 g of the target compound.

 GC-Mass (theory: 495.20 g / mol, measured: 495.63 g / mol)

[Preparation Example 70]

Synthesis of 3-phenyl-1- (3- (triphenylene-2-yl) phenyl) -9H-carbazole

Except that 4,4,5,5-tetramethyl-2- (3- (triphenylene-2-yl) phenyl) -1,3,2-dioxaborolane was used as the reactant 13] to obtain the target compound (50 g).

 GC-Mass (calculated: 545.21 g / mol, measured: 545.69 g / mol)

[Preparation Example 71]

Synthesis of 1- (3- (naphthalen-1-yl) phenyl) -3-phenyl-9H-carbazole

[Preparation Example 13] Except that 4,4,5,5-tetramethyl-2- (3- (naphthalen-1-yl) phenyl) -1,3,2-dioxaborolane was used as a reactant, , The target compound (38 g) was obtained.

 GC-Mass (calculated: 445.18 g / mol, measured: 445.57 g / mol)

[Preparation Example 72]

Synthesis of 1- (3- (anthracen-9-yl) phenyl) -3-phenyl-9H-carbazole

[Preparation Example 13] Except that 2- (3- (anthracen-9-yl) phenyl) -4,4,5,5-tetramethyl-1,3,2-dioxaborolane was used as a reactant, , The desired compound (47 g) was obtained.

 GC-Mass (theory: 495.20 g / mol, measured: 495.63 g / mol)

[Preparation Example 73]

Synthesis of 3-phenyl-1- (3- (pyrene-1-yl) phenyl) -9H-carbazole

Except that 2- (3- (3a1,6-dihydropyren-1-yl) phenyl) -4,4,5,5-tetramethyl-1,3,2-dioxaborolane was used as a reactant Was subjected to the same procedure as in [Preparation Example 13] to obtain 42 g of the desired compound;

 GC-Mass (theory: 519.20 g / mol, measurement: 519.65 g / mol)

[Preparation Example 74]

Synthesis of 1- (3- (fluoranthen-3-yl) phenyl) -3-phenyl-9H-carbazole

Except that 2- (3- (fluoranthene-3-yl) phenyl) -4,4,5,5-tetramethyl-1,3,2-dioxaborolane was used as the reactant in Preparation Example 13] to obtain 46 g of the target compound.

 GC-Mass (theory: 519.20 g / mol, measurement: 519.65 g / mol)

[Preparation Example 75]

Synthesis of 1- (3- (phenanthren-9-yl) phenyl) -3,6-diphenyl-9H-carbazole

Except that 4,4,5,5-tetramethyl-2- (3- (phenanthrene-9-yl) phenyl) -1,3,2-dioxaborolane was used as a reactant in Preparation Example 19 ] To obtain 46 g of the target compound;

 GC-Mass (calculated: 571.23 g / mol, measured: 571.72 g / mol)

[Preparation Example 76]

Synthesis of 3,6-diphenyl-1- (3- (triphenylene-2-yl) phenyl) -9H-carbazole

Except that 4,4,5,5-tetramethyl-2- (3- (triphenylene-2-yl) phenyl) -1,3,2-dioxaborolane was used as the reactant 19] to obtain the target compound (50 g);

 GC-Mass (calculated: 621.25 g / mol, measured: 621.78 g / mol)

[Preparation Example 77]

Synthesis of 1- (3- (naphthalen-1-yl) phenyl) -3,6-diphenyl-9H-carbazole

[Preparation Example 19] Except that 4,4,5,5-tetramethyl-2- (3- (naphthalen-1-yl) phenyl) -1,3,2-dioxaborolane was used as a reactant, , The title compound (38 g) was obtained.

 GC-Mass (calculated: 521.21 g / mol, measured: 521.66 g / mol)

[Preparation Example 78]

Synthesis of 1- (3- (anthracen-9-yl) phenyl) -3,6-diphenyl-9H-carbazole

[Preparation Example 19] Except that 2- (3- (anthracen-9-yl) phenyl) -4,4,5,5-tetramethyl-1,3,2-dioxaborolane was used as a reactant, , The desired compound (47 g) was obtained.

 GC-Mass (calculated: 571.23 g / mol, measured: 571.72 g / mol)

[Preparation Example 79]

Synthesis of 3,6-diphenyl-1- (3- (pyrene-1-yl) phenyl) -9H-carbazole

Except that 2- (3- (3a1,6-dihydropyren-1-yl) phenyl) -4,4,5,5-tetramethyl-1,3,2-dioxaborolane was used as a reactant Was subjected to the same procedure as in [Preparation Example 19] to give 42 g of the desired compound;

 GC-Mass (calculated: 595.23 g / mol, measured: 595.75 g / mol)

[Preparation Example 80]

Synthesis of 1- (3- (fluoranthen-3-yl) phenyl) -3,6-diphenyl-9H-carbazole

Except that 2- (3- (fluoranthene-3-yl) phenyl) -4,4,5,5-tetramethyl-1,3,2-dioxaborolane was used as the reactant in Preparation Example 19] to obtain 46 g of the target compound;

 GC-Mass (calculated: 595.23 g / mol, measured: 595.75 g / mol)

[Preparation Example 81]

Synthesis of 6- (dibenzo [b, d] furan-4-yl) -1- (3- (phenanthren-9-yl) phenyl) -9H-carbazole

Except that 4,4,5,5-tetramethyl-2- (3- (phenanthrene-9-yl) phenyl) -1,3,2-dioxaborolane was used as a reactant in Preparation Example 25 ] To obtain 46 g of the target compound;

 GC-Mass (calculated: 585.21 g / mol, measured: 585.71 g / mol)

[Preparation Example 82]

Synthesis of 6- (dibenzo [b, d] furan-4-yl) -1- (3- (triphenylen-2-yl) phenyl) -9H-carbazole

Except that 4,4,5,5-tetramethyl-2- (3- (triphenylene-2-yl) phenyl) -1,3,2-dioxaborolane was used as the reactant 25] to obtain the target compound (50 g);

 GC-Mass (calculated: 635.22 g / mol, measured: 635.77 g / mol)

[Preparation Example 83]

Synthesis of 6- (dibenzo [b, d] furan-4-yl) -1- (3- (naphthalen-1-yl) phenyl) -9H-carbazole

[Preparation Example 25] Except that 4,4,5,5-tetramethyl-2- (3- (naphthalen-1-yl) phenyl) -1,3,2-dioxaborolane was used as a reactant, , The title compound (38 g) was obtained.

 GC-Mass (calculated: 535.19 g / mol, measured: 535.65 g / mol)

[Preparation Example 84]

Synthesis of 1- (3- (anthracen-9-yl) phenyl) -6- (dibenzo [b, d] furan-4-yl) -9H-carbazole

[Preparation Example 25] Except that 2- (3- (anthracen-9-yl) phenyl) -4,4,5,5-tetramethyl-1,3,2-dioxaborolane was used as a reactant, , The desired compound (47 g) was obtained.

 GC-Mass (calculated: 585.21 g / mol, measured: 585.71 g / mol)

[Preparation Example 85]

Synthesis of 6- (dibenzo [b, d] furan-4-yl) -1- (3- (pyrene- 1-yl) phenyl) -9H-carbazole

Except that 2- (3- (3a1,6-dihydropyren-1-yl) phenyl) -4,4,5,5-tetramethyl-1,3,2-dioxaborolane was used as a reactant Was subjected to the same procedure as in [Preparation Example 25] to obtain 42 g of the target compound;

 GC-Mass (theory: 609.21 g / mol, measurement: 609.73 g / mol)

[Preparation Example 86]

Synthesis of 6- (dibenzo [b, d] furan-4-yl) -1- (3- (fluoranthene-3-yl) phenyl) -9H-carbazole

Except that 2- (3- (fluoranthene-3-yl) phenyl) -4,4,5,5-tetramethyl-1,3,2-dioxaborolane was used as the reactant in Preparation Example 25] to obtain 46 g of the target compound;

 GC-Mass (theory: 609.21 g / mol, measurement: 609.73 g / mol)

[Preparation Example 87]

Synthesis of 8- (3- (phenanthren-9-yl) phenyl) -7H-benzo [c]

Except that 4,4,5,5-tetramethyl-2- (3- (phenanthrene-9-yl) phenyl) -1,3,2-dioxaborolane was used as a reactant [Preparation Example 31 ] To obtain the title compound (50 g);

 GC-Mass (calculated: 469.18 g / mol, measured: 469.59 g / mol)

[Preparation Example 88]

Synthesis of 8- (3- (triphenylene-2-yl) phenyl) -7H-benzo [c]

Except that 4,4,5,5-tetramethyl-2- (3- (triphenylene-2-yl) phenyl) -1,3,2-dioxaborolane was used as the reactant 31] to obtain the title compound (50 g);

 GC-Mass (theory: 519.20 g / mol, measurement: 519.65 g / mol)

[Preparation Example 89]

Synthesis of 8- (3- (naphthalen-1-yl) phenyl) -7H-benzo [c]

[Preparation Example 31] Except that 4,4,5,5-tetramethyl-2- (3- (naphthalen-1-yl) phenyl) -1,3,2-dioxaborolane was used as a reactant, , The title compound (38 g) was obtained.

 GC-Mass (theory: 419.17 g / mol, measured: 419.53 g / mol)

[Preparation Example 90]

Synthesis of 8- (3- (anthracene-9-yl) phenyl) -7H-benzo [c]

[Preparation Example 31] Except that 2- (3- (anthracen-9-yl) phenyl) -4,4,5,5-tetramethyl-1,3,2-dioxaborolane was used as a reactant, , The desired compound (47 g) was obtained.

 GC-Mass (calculated: 469.18 g / mol, measured: 469.59 g / mol)

[Preparation Example 91]

Synthesis of 8- (3- (pyrene-1-yl) phenyl) -7H-benzo [c]

Except that 2- (3- (3a1,6-dihydropyren-1-yl) phenyl) -4,4,5,5-tetramethyl-1,3,2-dioxaborolane was used as a reactant Was subjected to the same procedure as in [Preparation Example 31] to give 42 g of the desired compound;

 GC-Mass (theory: 493.18 g / mol, measured: 493.61 g / mol)

[Preparation Example 92]

Synthesis of 8- (3- (fluoranthen-3-yl) phenyl) -7H-benzo [c]

Except that 2- (3- (fluoranthene-3-yl) phenyl) -4,4,5,5-tetramethyl-1,3,2-dioxaborolane was used as the reactant in Preparation Example 31] to obtain 46 g of the target compound;

 GC-Mass (theory: 493.18 g / mol, measured: 493.61 g / mol)

[Preparation Example 93]

Synthesis of 4- (3- (phenanthren-9-yl) phenyl) -5H-benzo [b]

Except that 4,4,5,5-tetramethyl-2- (3- (phenanthrene-9-yl) phenyl) -1,3,2-dioxaborolane was used as a reactant [Preparation Example 37 ] To obtain the title compound (50 g);

 GC-Mass (calculated: 469.18 g / mol, measured: 469.59 g / mol)

[Preparation Example 94]

Synthesis of 4- (3- (triphenylene-2-yl) phenyl) -5H-benzo [b]

Except that 4,4,5,5-tetramethyl-2- (3- (triphenylene-2-yl) phenyl) -1,3,2-dioxaborolane was used as the reactant 37] to obtain the target compound (50 g);

 GC-Mass (theory: 519.20 g / mol, measurement: 519.65 g / mol)

[Preparation Example 95]

Synthesis of 4- (3- (naphthalen-1-yl) phenyl) -5H-benzo [b]

[Preparation Example 37] Except that 4,4,5,5-tetramethyl-2- (3- (naphthalen-1-yl) phenyl) -1,3,2-dioxaborolane was used as a reactant, , The title compound (38 g) was obtained.

 GC-Mass (theory: 419.17 g / mol, measured: 419.53 g / mol)

[Preparation Example 96]

Synthesis of 4- (3- (anthracen-9-yl) phenyl) -5H-benzo [b]

[Preparation Example 37] Except that 2- (3- (anthracen-9-yl) phenyl) -4,4,5,5-tetramethyl-1,3,2-dioxaborolane was used as a reactant, , The desired compound (47 g) was obtained.

 GC-Mass (calculated: 469.18 g / mol, measured: 469.59 g / mol)

[Preparation Example 97]

Synthesis of 4- (3- (pyrene-1-yl) phenyl) -5H-benzo [b]

Except that 2- (3- (3a1,6-dihydropyren-1-yl) phenyl) -4,4,5,5-tetramethyl-1,3,2-dioxaborolane was used as a reactant Was subjected to the same procedure as in [Preparation Example 37] to obtain 42 g of the desired compound;

 GC-Mass (theory: 493.18 g / mol, measured: 493.61 g / mol)

[Preparation Example 98]

Synthesis of 4- (3- (fluoranthen-3-yl) phenyl) -5H-benzo [b]

Except that 2- (3- (fluoranthene-3-yl) phenyl) -4,4,5,5-tetramethyl-1,3,2-dioxaborolane was used as the reactant in Preparation Example 37] to obtain 46 g of the target compound;

 GC-Mass (theory: 493.18 g / mol, measured: 493.61 g / mol)

[Preparation Example 99]

Synthesis of 10- (3- (phenanthren-9-yl) phenyl) -11H-benzo [a] carbazole

Except that 4,4,5,5-tetramethyl-2- (3- (phenanthrene-9-yl) phenyl) -1,3,2-dioxaborolane was used as a reactant in Preparation Example 43 ] To obtain the title compound (50 g);

 GC-Mass (calculated: 469.18 g / mol, measured: 469.59 g / mol)

[Preparation Example 100]

Synthesis of 10- (3- (triphenylene-2-yl) phenyl) -11H-benzo [a]

Except that 4,4,5,5-tetramethyl-2- (3- (triphenylene-2-yl) phenyl) -1,3,2-dioxaborolane was used as the reactant 43] to obtain the target compound (50 g);

 GC-Mass (theory: 519.20 g / mol, measurement: 519.65 g / mol)

[Preparation Example 101]

Synthesis of 10- (3- (naphthalen-1-yl) phenyl) -11H-benzo [a] carbazole

[Preparation Example 43] Except that 4,4,5,5-tetramethyl-2- (3- (naphthalen-1-yl) phenyl) -1,3,2-dioxaborolane was used as a reactant, , The title compound (38 g) was obtained.

 GC-Mass (theory: 419.17 g / mol, measured: 419.53 g / mol)

[Preparation Example 102]

Synthesis of 10- (3- (anthracen-9-yl) phenyl) -11H-benzo [a] carbazole

[Preparation Example 43] Except that 2- (3- (anthracen-9-yl) phenyl) -4,4,5,5-tetramethyl-1,3,2-dioxaborolane was used as a reactant, , The desired compound (47 g) was obtained.

 GC-Mass (calculated: 469.18 g / mol, measured: 469.59 g / mol)

[Preparation Example 103]

Synthesis of 10- (3- (pyrene-1-yl) phenyl) -11H-benzo [a] carbazole

Except that 2- (3- (3a1,6-dihydropyren-1-yl) phenyl) -4,4,5,5-tetramethyl-1,3,2-dioxaborolane was used as a reactant Was subjected to the same procedure as in [Preparation Example 43] to obtain 42 g of the target compound;

 GC-Mass (theory: 493.18 g / mol, measured: 493.61 g / mol)

[Preparation Example 104]

Synthesis of 10- (3- (fluoranthen-3-yl) phenyl) -11H-benzo [a] carbazole

Except that 2- (3- (fluoranthene-3-yl) phenyl) -4,4,5,5-tetramethyl-1,3,2-dioxaborolane was used as the reactant in Preparation Example 43] to obtain 46 g of the target compound;

 GC-Mass (theory: 493.18 g / mol, measured: 493.61 g / mol)

[Preparation Example 105]

Synthesis of 10- (3- (phenanthren-9-yl) phenyl) -9H-dibenzo [a, c]

Except that 4,4,5,5-tetramethyl-2- (3- (phenanthrene-9-yl) phenyl) -1,3,2-dioxaborolane was used as a reactant [Preparation Example 49 ] To obtain the title compound (50 g);

 GC-Mass (theory: 519.20 g / mol, measurement: 519.65 g / mol)

[Preparation Example 106]

Synthesis of 10- (3- (triphenylene-2-yl) phenyl) -9H-dibenzo [a, c]

Except that 4,4,5,5-tetramethyl-2- (3- (triphenylene-2-yl) phenyl) -1,3,2-dioxaborolane was used as the reactant 49] to obtain the target compound (50 g);

 GC-Mass (calculated: 569.21 g / mol, measured: 569.71 g / mol)

[Preparation Example 107]

Synthesis of 10- (3- (naphthalen-1-yl) phenyl) -9H-dibenzo [a, c]

[Preparation Example 49] Except that 4,4,5,5-tetramethyl-2- (3- (naphthalen-1-yl) phenyl) -1,3,2-dioxaborolane was used as a reactant, , The title compound (38 g) was obtained.

 GC-Mass (calculated: 469.18 g / mol, measured: 469.59 g / mol)

[Preparation Example 108]

Synthesis of 10- (3- (anthracen-9-yl) phenyl) -9H-dibenzo [a, c]

[Preparation Example 49] Except that 2- (3- (anthracen-9-yl) phenyl) -4,4,5,5-tetramethyl-1,3,2-dioxaborolane was used as a reactant, , The desired compound (47 g) was obtained.

 GC-Mass (theory: 519.20 g / mol, measurement: 519.65 g / mol)

[Preparation Example 109]

Synthesis of 10- (3- (pyrene-1-yl) phenyl) -9H-dibenzo [a, c]

Except that 2- (3- (3a1,6-dihydropyren-1-yl) phenyl) -4,4,5,5-tetramethyl-1,3,2-dioxaborolane was used as a reactant Was subjected to the same procedure as in [Preparation Example 49] to obtain 42 g of the target compound;

 GC-Mass (calculated: 543.20 g / mol, measured: 543.67 g / mol)

[Preparation Example 110]

Synthesis of 10- (3- (fluoranthen-3-yl) phenyl) -9H-dibenzo [a, c]

Except that 2- (3- (fluoranthene-3-yl) phenyl) -4,4,5,5-tetramethyl-1,3,2-dioxaborolane was used as the reactant in Preparation Example 49] to obtain 46 g of the target compound;

 GC-Mass (calculated: 543.20 g / mol, measured: 543.67 g / mol)

[Preparation Example 111]

Synthesis of 8- (phenanthrene-9-yl) -9H-3,9'-bicarbazole

The procedure of Preparation Example 1 was repeated except that 8-bromo-9H-3,9'-bicarbazole was used as the reactant, to obtain 46 g of the target compound;

 GC-Mass (calculated: 509.19 g / mol, measured: 509.62 g / mol)

[Preparation Example 112]

Synthesis of 8- (triphenylene-2-yl) -9H-3,9'-bicarbazole

The procedure of Preparation Example 2 was repeated except that 8-bromo-9H-3,9'-bicarbazole was used as a reactant, to obtain 50 g of the target compound;

 GC-Mass (theory: 558.21 g / mol, measurement: 558.68 g / mol)

[Preparation Example 113]

Synthesis of 8- (3- (triphenylene-2-yl) phenyl) -9H-3,9'-bicarbazole

The same procedure as in [Preparation Example 56] was conducted except that 8-bromo-9H-3,9'-bicarbazole was used as a reactant, to obtain 50 g of the title compound;

 GC-Mass (theory: 634.24 g / mol, measurement: 634.78 g / mol)

[Synthesis Example 1] Synthesis of Mat 1

250 mL of xylene was added to 5.14 g (14.99 mmol) of [Preparation Example 1] and 5.6 g (17.99 mmol) of 4-bromo-2,6-diphenylpyrimidine under a nitrogen stream. 0.68 g (0.75 mmol) of Pd 2 (dba) 3, 0.3 g (1.499 mmol) of P (t-Bu) 3 and 3.59 g (37.47 mol) of NaOtBu were added and the mixture was refluxed at 120 ° C for 24 hours. The reaction solution was cooled to room temperature and the reaction was terminated with 500 mL of an aqueous ammonium chloride solution. The mixture was extracted with 500 mL of M.C, and then washed with distilled water. The obtained organic layer was dried over anhydrous MgSO 4, distilled under reduced pressure, and purified by silica gel column chromatography to obtain 7.7 g (yield: 85%) of the desired compound. (M, 2H), 7.94 (d, IH), 8.08 (d, IH) 1H), 7.24 (s, 1H), 7.16 (t, 1H); 7.90 (m, 1H); HRMS [M] < + >: 574.22

[Synthesis Example 2] Synthesis of Mat 2

The procedure of Synthesis Example 1 was repeated except for using 4 - ([1,1'-biphenyl] -4-yl) -6-bromo-2-phenylpyrimidine as a reaction product, g; HRMS [M] < + >: 650.26

[Synthesis Example 3] Synthesis of Mat 3

The procedure of Synthesis Example 1 was repeated except that 4-bromo-6- (dibenzo [b, d] furan-3-yl) -2-phenylpyrimidine pyrimidine was used as a reactant, 14.7 g; HRMS [M] < + >: 664.23

[Synthesis Example 4] Synthesis of Mat 4

[Preparative Example 1] (10.26 g, 29.9 mmol) was dissolved in 100 ml of DMF in a nitrogen stream, and NaH (1.07 g, 44.9 mmol) was slowly added dropwise at room temperature. After sufficient stirring for 1 hour, slowly add 2-chloro-4,6-diphenyl-1,3,5-triazine (9.6 g, 35.88 mmol). The mixture was stirred at room temperature for 4 hours. After completion of the reaction, the reaction mixture was extracted with methylene chloride, concentrated under reduced pressure, and 6.24 g (76%) of the target compound was obtained by column chromatography. (M, 2H), 7.94-7.90 (m, 2H), 8.04-7.90 (m, 2H) , 7.70-7.63 (m, 4H), 7.50-7.40 (m, 7H), 7.35 (t, 1H), 7.16 (t, 1H); HRMS [M] < + >: 575.22

[Synthesis Example 5] Synthesis of Mat 5

The same procedure as in [Synthesis Example 4] was repeated except that 2 - ([1,1'-biphenyl] -4-yl) -4-chloro-6-phenyl-1,3,5- To give 14.2 g of the title compound; HRMS [M] < + >: 651.25

[Synthesis Example 6] Synthesis of Mat 6

The same procedure as in [Synthesis Example 4] was carried out except that 2-chloro-4-phenyl-6- (4- (pyridin-3-yl) phenyl) 14.2 g of the aimed compound were obtained; HRMS [M] < + >: 652.25

[Synthesis Example 7] Synthesis of Mat 7

As a reactant, 2 - ([1,1'-biphenyl] -3-yl) -4 - ([1,1'-biphenyl] The procedure of Synthesis Example 4 was repeated except that 14.0 g of the target compound was obtained; HRMS [M] < + >: 727.28

[Synthesis Example 8] Synthesis of Mat 8

Synthesis was carried out except that 2 - ([1,1'-biphenyl] -4-yl) -4-chloro-6- (naphthalen- Example 4] was carried out to obtain 14.6 g of the target compound; HRMS [M] < + >: 700.27

[Synthesis Example 9] Synthesis of Mat 9

The same procedure as in [Synthesis Example 4] was carried out except that 2-chloro-4- (dibenzo [b, d] furan-3-yl) -6-phenyl-1,3,5- To obtain 15.1 g of the target compound; HRMS [M] < + >: 665.23

[Synthesis Example 10] Synthesis of Mat 10

4-chloro-6- (dibenzo [b, d] furan-3-yl) -1,3,5-triazine as a reactant, The same procedure as in [Synthesis Example 4] was carried out except for using 15.1 g of the target compound; HRMS [M] < + >: 741.26

[Synthesis Example 11] Synthesis of Mat 11

The same procedure as in [Synthesis Example 4] was carried out except that 2-chloro-4,6-bis (dibenzo [b, d] furan-3-yl) -1,3,5-triazine was used as a reactant To obtain 15.3 g of the target compound; HRMS [M] < + >: 755.24

[Synthesis Example 12] Synthesis of Mat 12

(Dibenzo [b, d] furan-3-yl) -1,3,5-triazine was used as the reactant , The same procedure as in [Synthesis Example 4] was conducted to obtain 14.7 g of the title compound; HRMS [M] < + >: 755.24

[Synthesis Example 13] Synthesis of Mat 13

The same procedure as in [Synthesis Example 4] was conducted except that 2-chloro-4-phenylquinazoline was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 548.21

[Synthesis Example 14] Synthesis of Mat 14

The same procedure as in [Synthesis Example 4] was conducted except that 2-chloro-4-phenylbenzo [4,5] thieno [3,2-d] pyrimidine was used as a reactant, to obtain the desired compound (14.6 g). ; HRMS [M] < + >: 604.18

[Synthesis Example 15] Synthesis of Mat 15

The procedure of Synthetic Example 4 was repeated except that 2-chloro-3-phenylquinoxaline was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 548.21

[Synthesis Example 16] Synthesis of Mat 16

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 2] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 624.24

[Synthesis Example 17] Synthesis of Mat 17

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 2] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 700.27

[Synthesis Example 18] Synthesis of Mat 18

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 2] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 714.25

[Synthesis Example 19] Synthesis of Mat 19

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 2] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 625.23

[Synthesis Example 20] Synthesis of Mat 20

The same procedure as in [Synthesis Example 5] was conducted except that [Preparation Example 2] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 701.27

[Synthesis Example 21] Synthesis of Mat 21

The same procedure as in [Synthesis Example 6] was conducted except that [Preparation Example 2] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 702.26

[Synthesis Example 22] Synthesis of Mat 22

The same procedure as in [Synthesis Example 7] was conducted except that [Preparation Example 2] was used as a reactant, to obtain 14.0 g of the target compound; HRMS [M] < + >: 777.30

[Synthesis Example 23] Synthesis of Mat 23

The same procedure as in [Synthesis Example 8] was carried out except that [Preparation Example 2] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 751.28

[Synthesis Example 24] Synthesis of Mat 24

The same procedure as in [Synthesis Example 9] was conducted except that [Preparation Example 2] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 715.25

[Synthesis Example 25] Synthesis of Mat 25

The same procedure as in [Synthesis Example 10] was conducted except that [Preparation Example 2] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 791.28

[Synthesis Example 26] Synthesis of Mat 26

The same procedure as in [Synthesis Example 11] was carried out except that [Preparation Example 2] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 805.26

[Synthesis Example 27] Synthesis of Mat 27

The same procedure as in [Synthesis Example 12] was conducted except that [Preparation Example 2] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 805.26

[Synthesis Example 28] Synthesis of Mat 28

The same procedure as in [Synthesis Example 13] was carried out except that [Preparation Example 2] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 598.22

[Synthesis Example 29] Synthesis of Mat 29

The same procedure as in [Synthesis Example 14] was carried out except that [Preparation Example 2] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 654.20

[Synthesis Example 30] Synthesis of Mat 30

The same procedure as in [Synthesis Example 15] was conducted except that [Preparation Example 2] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 654.20

[Synthesis Example 31] Synthesis of Mat 31

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 3] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 524.21

[Synthesis Example 32] Synthesis of Mat 32

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 3] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 600.24

[Synthesis Example 33] Synthesis of Mat 33

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 3] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 614.22

[Synthesis Example 34] Synthesis of Mat 34

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 3] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 525.20

[Synthesis Example 35] Synthesis of Mat 35

The same procedure as in [Synthesis Example 5] was conducted except that [Preparation Example 3] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 601.23

[Synthesis Example 36] Synthesis of Mat 36

The same procedure as in [Synthesis Example 6] was conducted except that [Preparation Example 3] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 602.23

[Synthesis Example 37] Synthesis of Mat 37

The same procedure as in [Synthesis Example 7] was carried out except that [Preparation Example 3] was used as a reactant, to obtain 14.0 g of the desired compound; HRMS [M] < + >: 677.27

[Synthesis Example 38] Synthesis of Mat 38

The same procedure as in [Synthesis Example 8] was conducted except that [Preparation Example 3] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 651.25

[Synthesis Example 39] Synthesis of Mat 39

The same procedure as in [Synthesis Example 9] was conducted except that [Preparation Example 3] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 615.21

[Synthesis Example 40] Synthesis of Mat 40

The same procedure as in [Synthesis Example 10] was conducted except that [Preparation Example 3] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 691.25

[Synthesis Example 41] Synthesis of Mat 41

The same procedure as in [Synthesis Example 11] was conducted except that [Preparation Example 3] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 705.22

[Synthesis Example 42] Synthesis of Mat 42

The same procedure as in [Synthesis Example 12] was conducted except that [Preparation Example 3] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 705.22

[Synthesis Example 43] Synthesis of Mat 43

The same procedure as in [Synthesis Example 13] was carried out except that [Preparation Example 3] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 498.19

[Synthesis Example 44] Synthesis of Mat 44

The same procedure as in [Synthesis Example 14] was carried out except that [Preparation Example 3] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 554.16

[Synthesis Example 45] Synthesis of Mat 45

The same procedure as in [Synthesis Example 15] was conducted except that [Preparation Example 3] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 498.19

[Synthesis Example 46] Synthesis of Mat 46

The same procedure as in [Synthesis Example 1] was carried out except that [Preparation Example 4] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 755.24

[Synthesis Example 47] Synthesis of Mat 47

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 4] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 650.26

[Synthesis Example 48] Synthesis of Mat 48

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 4] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 664.23

[Synthesis Example 49] Synthesis of Mat 49

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 4] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 755.24

[Synthesis Example 50] Synthesis of Mat 50

The same procedure as in [Synthesis Example 5] was carried out except that [Preparation Example 4] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 651.25

[Synthesis Example 51] Synthesis of Mat 51

The same procedure as in [Synthesis Example 6] was conducted except that [Preparation Example 4] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 652.25

[Synthesis Example 52] Synthesis of Mat 52

The same procedure as in [Synthesis Example 7] was conducted except that [Preparation Example 4] was used as a reactant, to obtain 14.0 g of the target compound; HRMS [M] < + >: 727.28

[Synthesis Example 53] Synthesis of Mat 53

The same procedure as in [Synthesis Example 8] was carried out except that [Preparation Example 4] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 700.27

[Synthesis Example 54] Synthesis of Mat 54

The same procedure as in [Synthesis Example 9] was conducted except that [Preparation Example 4] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 665.23

[Synthesis Example 55] Synthesis of Mat 55

The same procedure as in [Synthesis Example 10] was conducted except that [Preparation Example 4] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 741.26

[Synthesis Example 56] Synthesis of Mat 56

The same procedure as in [Synthesis Example 11] was conducted except that [Preparation Example 4] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 755.24

[Synthesis Example 57] Synthesis of Mat 57

The same procedure as in [Synthesis Example 12] was conducted except that [Preparation Example 4] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 755.24

[Synthesis Example 58] Synthesis of Mat 58

The same procedure as in [Synthesis Example 13] was carried out except that [Preparation Example 4] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 548.21

[Synthesis Example 59] Synthesis of Mat 59

The same procedure as in [Synthesis Example 14] was carried out except that [Preparation Example 4] was used as a reactant, to obtain 14.6 g of the desired compound; HRMS [M] < + >: 604.18

[Synthesis Example 60] Synthesis of Mat 60

The same procedure as in [Synthesis Example 15] was carried out except that [Preparation Example 4] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 548.21

[Synthesis Example 61] Synthesis of Mat 61

The same procedure as in [Synthesis Example 1] was carried out except that [Preparation Example 5] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 624.24

[Synthesis Example 62] Synthesis of Mat 62

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 5] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 700.27

[Synthesis Example 63] Synthesis of Mat 63

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 5] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 714.25

[Synthesis Example 64] Synthesis of Mat 64

The same procedure as in [Synthesis Example 4] was conducted except that [Preparation Example 5] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 625.23

[Synthesis Example 65] Synthesis of Mat 65

The same procedure as in [Synthesis Example 5] was conducted except that [Preparation Example 5] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 701.27

[Synthesis Example 66] Synthesis of Mat 66

The same procedure as in [Synthesis Example 6] was conducted except that [Preparation Example 5] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 702.26

[Synthesis Example 67] Synthesis of Mat 67

The same procedure as in [Synthesis Example 7] was carried out except that [Preparation Example 5] was used as a reactant, to obtain 14.0 g of the title compound; HRMS [M] < + >: 777.30

[Synthesis Example 68] Synthesis of Mat 68

The same procedure as in [Synthesis Example 8] was conducted except that [Preparation Example 5] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 751.28

[Synthesis Example 69] Synthesis of Mat 69

The same procedure as in [Synthesis Example 9] was conducted except that [Preparation Example 5] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 715.25

[Synthesis Example 70] Synthesis of Mat 70

The same procedure as in [Synthesis Example 10] was conducted except that [Preparation Example 5] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 791.28

[Synthesis Example 71] Synthesis of Mat 71

The same procedure as in [Synthesis Example 11] was conducted except that [Preparation Example 5] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 805.26

[Synthesis Example 72] Synthesis of Mat 72

The same procedure as in [Synthesis Example 12] was conducted except that [Preparation Example 5] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 805.26

[Synthesis Example 73] Synthesis of Mat 73

The same procedure as in [Synthesis Example 13] was conducted except that [Preparation Example 5] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 598.22

[Synthesis Example 74] Synthesis of Mat 74

The same procedure as in [Synthesis Example 14] was conducted except that [Preparation Example 5] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 654.20

[Synthesis Example 75] Synthesis of Mat 75

The same procedure as in [Synthesis Example 15] was carried out except that [Preparation Example 5] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 654.20

[Synthesis Example 76] Synthesis of Mat 76

The same procedure as in [Synthesis Example 1] was carried out except that [Preparation Example 6] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 598.22

[Synthesis Example 77] Synthesis of Mat 77

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 6] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 674.26

[Synthesis Example 78] Synthesis of Mat 78

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 6] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 688.23

[Synthesis Example 79] Synthesis of Mat 79

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 6] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 599.22

[Synthesis Example 80] Synthesis of Mat 80

The same procedure as in [Synthesis Example 5] was conducted except that [Preparation Example 6] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 675.25

[Synthesis Example 81] Synthesis of Mat 81

The same procedure as in [Synthesis Example 6] was conducted except that [Preparation Example 6] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 676.25

[Synthesis Example 82] Synthesis of Mat 82

The same procedure as in [Synthesis Example 7] was carried out except that [Preparation Example 6] was used as a reactant, to obtain 14.0 g of the title compound; HRMS [M] < + >: 751.28

[Synthesis Example 83] Synthesis of Mat 83

The same procedure as in [Synthesis Example 8] was conducted except that [Preparation Example 6] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 725.27

[Synthesis Example 84] Synthesis of Mat 84

The same procedure as in [Synthesis Example 9] was carried out except that [Preparation Example 6] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 689.23

[Synthesis Example 85] Synthesis of Mat 85

The same procedure as in [Synthesis Example 10] was carried out except that [Preparation Example 6] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 765.26

[Synthesis Example 86] Synthesis of Mat 86

The same procedure as in [Synthesis Example 11] was carried out except that [Preparation Example 6] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 779.24

[Synthesis Example 87] Synthesis of Mat 87

The same procedure as in [Synthesis Example 12] was conducted except that [Preparation Example 6] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 779.24

[Synthesis Example 88] Synthesis of Mat 88

The same procedure as in [Synthesis Example 13] was carried out except that [Preparation Example 6] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 572.21

[Synthesis Example 89] Synthesis of Mat 89

The same procedure as in [Synthesis Example 14] was carried out except that [Preparation Example 6] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 628.18

[Synthesis Example 90] Synthesis of Mat 90

The same procedure as in [Synthesis Example 15] was conducted except that [Preparation Example 6] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 572.21

[Synthesis Example 91] Synthesis of Mat 91

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 7] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 726.29

[Synthesis Example 92] Synthesis of Mat 92

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 7] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 740.27

[Synthesis Example 93] Synthesis of Mat 93

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 7] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 651.25

[Synthesis Example 94] Synthesis of Mat 94

The same procedure as in [Synthesis Example 5] was carried out except that [Preparation Example 7] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 727.28

[Synthesis Example 95] Synthesis of Mat 95

The same procedure as in [Synthesis Example 9] was conducted except that [Preparation Example 7] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 741.26

[Synthesis Example 96] Synthesis of Mat 96

The same procedure as in [Synthesis Example 11] was conducted except that [Preparation Example 7] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 831.27

[Synthesis Example 97] Synthesis of Mat 97

The same procedure as in [Synthesis Example 12] was carried out except that [Preparation Example 7] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 831.27

[Synthesis Example 98] Synthesis of Mat 98

The same procedure as in [Synthesis Example 13] was conducted except that [Preparation Example 7] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 624.24

[Synthesis Example 99] Synthesis of Mat 99

The same procedure as in [Synthesis Example 14] was conducted except that [Preparation Example 7] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 680.21

[Synthesis Example 100] Synthesis of Mat 100

The same procedure as in [Synthesis Example 15] was conducted except that [Preparation Example 7] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 624.24

[Synthesis Example 101] Synthesis of Mat 101

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 8] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 776.30

[Synthesis Example 102] Synthesis of Mat 102

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 8] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 790.28

[Synthesis Example 103] Synthesis of Mat 103

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 8] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 701.27

[Synthesis Example 104] Synthesis of Mat 104

The same procedure as in [Synthesis Example 5] was carried out except that [Preparation Example 8] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 777.30

[Synthesis Example 105] Synthesis of Mat 105

The same procedure as in [Synthesis Example 9] was conducted except that [Preparation Example 8] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 791.28

[Synthesis Example 106] Synthesis of Mat 106

The same procedure as in [Synthesis Example 11] was conducted except that [Preparation Example 8] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 881.29

[Synthesis Example 107] Synthesis of Mat 107

The same procedure as in [Synthesis Example 12] was conducted except that [Preparation Example 8] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 881.29

[Synthesis Example 108] Synthesis of Mat 108

The same procedure as in [Synthesis Example 13] was carried out except that [Preparation Example 8] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 674.26

[Synthesis Example 109] Synthesis of Mat 109

The same procedure as in [Synthesis Example 14] was conducted except that [Preparation Example 8] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 730.23

[Synthesis Example 110] Synthesis of Mat 110

The same procedure as in [Synthesis Example 15] was carried out except that [Preparation Example 8] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 674.26

[Synthesis Example 111] Synthesis of Mat 111

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 9] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 676.27

[Synthesis Example 112] Synthesis of Mat 112

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 9] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 690.25

[Synthesis Example 113] Synthesis of Mat 113

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 9] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 601.23

[Synthesis Example 114] Synthesis of Mat 114

The same procedure as in [Synthesis Example 5] was conducted except that [Preparation Example 9] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 677.27

[Synthesis Example 115] Synthesis of Mat 115

The same procedure as in [Synthesis Example 9] was conducted except that [Preparation Example 9] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 691.25

[Synthesis Example 116] Synthesis of Mat 116

The same procedure as in [Synthesis Example 11] was conducted except that [Preparation Example 9] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 781.26

[Synthesis Example 117] Synthesis of Mat 117

The same procedure as in [Synthesis Example 12] was conducted except that [Preparation Example 9] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 781.26

[Synthesis Example 118] Synthesis of Mat 118

The same procedure as in [Synthesis Example 13] was conducted except that [Preparation Example 9] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 574.22

[Synthesis Example 119] Synthesis of Mat 119

The same procedure as in [Synthesis Example 14] was carried out except that [Preparation Example 9] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 630.20

[Synthesis Example 120] Synthesis of Mat 120

The same procedure as in [Synthesis Example 15] was carried out except that [Preparation Example 9] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 574.22

[Synthesis Example 121] Synthesis of Mat 121

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 10] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 726.29

[Synthesis Example 122] Synthesis of Mat 122

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 10] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 740.27

[Synthesis Example 123] Synthesis of Mat 123

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 10] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 651.25

[Synthesis Example 124] Synthesis of Mat 124

The same procedure as in [Synthesis Example 5] was conducted except that [Preparation Example 10] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 727.28

[Synthesis Example 125] Synthesis of Mat 125

The same procedure as in [Synthesis Example 9] was conducted except that [Preparation Example 10] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 741.26

[Synthesis Example 126] Synthesis of Mat 126

The same procedure as in [Synthesis Example 11] was conducted except that [Preparation Example 10] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 831.27

[Synthesis Example 127] Synthesis of Mat 127

The same procedure as in [Synthesis Example 12] was carried out except that [Preparation Example 10] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 831.27

[Synthesis Example 128] Synthesis of Mat 128

The same procedure as in [Synthesis Example 13] was conducted except that [Preparation Example 10] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 624.24

[Synthesis Example 129] Synthesis of Mat 129

The same procedure as in [Synthesis Example 14] was carried out except that [Preparation Example 10] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 680.21

[Synthesis Example 130] Synthesis of Mat 130

The same procedure as in [Synthesis Example 15] was carried out except that [Preparation Example 10] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 624.24

 [Synthesis Example 131] Synthesis of Mat 131

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 11] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 750.29

[Synthesis Example 132] Synthesis of Mat 132

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 11] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 764.27

[Synthesis Example 133] Synthesis of Mat 133

The same procedure as in [Synthesis Example 4] was conducted except that [Preparation Example 11] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 675.25

[Synthesis Example 134] Synthesis of Mat 134

The same procedure as in [Synthesis Example 5] was carried out except that [Preparation Example 11] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 751.28

[Synthesis Example 135] Synthesis of Mat 135

The same procedure as in [Synthesis Example 9] was conducted except that [Preparation Example 11] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 765.26

 [Synthesis Example 136] Synthesis of Mat 136

The same procedure as in [Synthesis Example 11] was carried out except that [Preparation Example 11] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 855.27

[Synthesis Example 137] Synthesis of Mat 137

The same procedure as in [Synthesis Example 12] was carried out except that [Preparation Example 11] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 855.27

[Synthesis Example 138] Synthesis of Mat 138

The same procedure as in [Synthesis Example 13] was carried out except that [Preparation Example 11] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 648.24

[Synthesis Example 139] Synthesis of Mat 139

The same procedure as in [Synthesis Example 14] was carried out except that [Preparation Example 11] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 704.21

[Synthesis Example 140] Synthesis of Mat 140

The same procedure as in [Synthesis Example 15] was carried out except that [Preparation Example 11] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 648.24

 [Synthesis Example 141] Synthesis of Mat 141

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 12] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 750.29

[Synthesis Example 142] Synthesis of Mat 142

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 12] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 664.27

[Synthesis Example 143] Synthesis of Mat 143

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 12] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 675.25

[Synthesis Example 144] Synthesis of Mat 144

The same procedure as in [Synthesis Example 5] was carried out except that [Preparation Example 12] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 751.28

[Synthesis Example 145] Synthesis of Mat 145

The same procedure as in [Synthesis Example 9] was conducted except that [Preparation Example 12] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 765.26

 [Synthesis Example 146] Synthesis of Mat 146

The same procedure as in [Synthesis Example 11] was carried out except that [Preparation Example 12] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 855.27

[Synthesis Example 147] Synthesis of Mat 147

The same procedure as in [Synthesis Example 12] was conducted except that [Preparation Example 12] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 855.27

[Synthesis Example 148] Synthesis of Mat 148

The same procedure as in [Synthesis Example 13] was carried out except that [Preparation Example 12] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 648.24

[Synthesis Example 149] Synthesis of Mat 149

The same procedure as in [Synthesis Example 14] was carried out except that [Preparation Example 12] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 704.21

[Synthesis Example 150] Synthesis of Mat 150

The same procedure as in [Synthesis Example 15] was carried out except that [Preparation Example 12] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 648.24

[Synthesis Example 151] Synthesis of Mat 151

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 13] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 726.29

[Synthesis Example 152] Synthesis of Mat 152

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 13] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 740.27

[Synthesis Example 153] Synthesis of Mat 153

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 13] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 651.25

[Synthesis Example 154] Synthesis of Mat 154

The same procedure as in [Synthesis Example 5] was carried out except that [Preparation Example 13] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 727.28

[Synthesis Example 155] Synthesis of Mat 155

The same procedure as in [Synthesis Example 9] was conducted except that [Preparation Example 13] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 741.26

[Synthesis Example 156] Synthesis of Mat 156

The same procedure as in [Synthesis Example 11] was carried out except that [Preparation Example 13] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 831.27

[Synthesis Example 157] Synthesis of Mat 157

The same procedure as in [Synthesis Example 12] was conducted except that [Preparation Example 13] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 831.27

[Synthesis Example 158] Synthesis of Mat 158

The same procedure as in [Synthesis Example 13] was conducted except that [Preparation Example 13] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 624.24

[Synthesis Example 159] Synthesis of Mat 159

The same procedure as in [Synthesis Example 14] was carried out except that [Preparation Example 13] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 680.21

[Synthesis Example 160] Synthesis of Mat 160

The same procedure as in [Synthesis Example 15] was carried out except that [Preparation Example 13] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 624.24

[Synthesis Example 161] Synthesis of Mat 161

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 14] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 776.30

[Synthesis Example 162] Synthesis of Mat 162

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 14] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 790.28

[Synthesis Example 163] Synthesis of Mat 163

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 14] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 701.27

[Synthesis Example 164] Synthesis of Mat 164

The same procedure as in [Synthesis Example 5] was carried out except that [Preparation Example 14] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 777.30

[Synthesis Example 165] Synthesis of Mat 165

The same procedure as in [Synthesis Example 9] was conducted except that [Preparation Example 14] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 791.28

[Synthesis Example 166] Synthesis of Mat 166

The same procedure as in [Synthesis Example 11] was carried out except that [Preparation Example 14] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 881.29

[Synthesis Example 167] Synthesis of Mat 167

The same procedure as in [Synthesis Example 12] was carried out except that [Preparation Example 14] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 881.29

[Synthesis Example 168] Synthesis of Mat 168

The same procedure as in [Synthesis Example 13] was conducted except that [Preparation Example 14] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 674.26

[Synthesis Example 169] Synthesis of Mat 169

The same procedure as in [Synthesis Example 14] was carried out except that [Preparation Example 14] was used as a reactant, to obtain 14.6 g of the desired compound; HRMS [M] < + >: 730.23

[Synthesis Example 170] Synthesis of Mat 170

The same procedure as in [Synthesis Example 15] was carried out except that [Preparation Example 14] was used as a reactant, to obtain the desired compound (13.7 g; HRMS [M] < + >: 674.26

[Synthesis Example 171] Synthesis of Mat 171

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 15] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 676.27

[Synthesis Example 172] Synthesis of Mat 172

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 15] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 690.25

[Synthesis Example 173] Synthesis of Mat 173

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 15] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 601.23

[Synthesis Example 174] Synthesis of Mat 174

The same procedure as in [Synthesis Example 5] was carried out except that [Preparation Example 15] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 677.27

[Synthesis Example 175] Synthesis of Mat 175

The same procedure as in [Synthesis Example 9] was conducted except that [Preparation Example 15] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 691.25

[Synthesis Example 176] Synthesis of Mat 176

The same procedure as in [Synthesis Example 11] was carried out except that [Preparation Example 15] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 781.26

[Synthesis Example 177] Synthesis of Mat 177

The same procedure as in [Synthesis Example 12] was carried out except that [Preparation Example 15] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 781.26

[Synthesis Example 178] Synthesis of Mat 178

The same procedure as in [Synthesis Example 13] was carried out except that [Preparation Example 15] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 574.22

[Synthesis Example 179] Synthesis of Mat 179

The same procedure as in [Synthesis Example 14] was carried out except that [Preparation Example 15] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 630.20

[Synthesis Example 180] Synthesis of Mat 180

The same procedure as in [Synthesis Example 15] was carried out except that [Preparation Example 15] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 574.22

[Synthesis Example 181] Synthesis of Mat 181

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 16] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 726.29

[Synthesis Example 182] Synthesis of Mat 182

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 16] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 740.27

[Synthesis Example 183] Synthesis of Mat 183

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 16] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 651.25

[Synthesis Example 184] Synthesis of Mat 184

The same procedure as in [Synthesis Example 5] was carried out except that [Preparation Example 16] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 727.28

[Synthesis Example 185] Synthesis of Mat 185

The same procedure as in [Synthesis Example 9] was conducted except that [Preparation Example 16] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 741.26

[Synthesis Example 186] Synthesis of Mat 186

The same procedure as in [Synthesis Example 11] was carried out except that [Preparation Example 16] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 831.27

[Synthesis Example 187] Synthesis of Mat 187

The same procedure as in [Synthesis Example 12] was carried out except that [Preparation Example 16] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 831.27

[Synthesis Example 188] Synthesis of Mat 188

The same procedure as in [Synthesis Example 13] was carried out except that [Preparation Example 16] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 624.24

[Synthesis Example 189] Synthesis of Mat 189

The same procedure as in [Synthesis Example 14] was conducted except that [Preparation Example 16] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 680.21

[Synthesis Example 190] Synthesis of Mat 190

The same procedure as in [Synthesis Example 15] was carried out except that [Preparation Example 16] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 624.24

 [Synthesis Example 191] Synthesis of Mat 191

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 17] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 750.29

[Synthesis Example 192] Synthesis of Mat 192

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 17] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 764.27

[Synthesis Example 193] Synthesis of Mat 193

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 17] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 675.25

[Synthesis Example 194] Synthesis of Mat 194

The same procedure as in [Synthesis Example 5] was conducted except that [Preparation Example 17] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 751.28

[Synthesis Example 195] Synthesis of Mat 195

The same procedure as in [Synthesis Example 9] was conducted except that [Preparation Example 17] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 765.26

 [Synthesis Example 196] Synthesis of Mat 196

The same procedure as in [Synthesis Example 11] was conducted except that [Preparation Example 17] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 855.27

[Synthesis Example 197] Synthesis of Mat 197

The same procedure as in [Synthesis Example 12] was conducted except that [Preparation Example 17] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 855.27

[Synthesis Example 198] Synthesis of Mat 198

The same procedure as in [Synthesis Example 13] was conducted except that [Preparation Example 17] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 648.24

[Synthesis Example 199] Synthesis of Mat 199

The same procedure as in [Synthesis Example 14] was carried out except that [Preparation Example 17] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 704.21

[Synthesis Example 200] Synthesis of Mat 200

The same procedure as in [Synthesis Example 15] was carried out except that [Preparation Example 17] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 648.24

 [Synthesis Example 201] Synthesis of Mat 201

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 18] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 750.29

[Synthesis Example 202] Synthesis of Mat 202

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 18] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 664.27

[Synthesis Example 203] Synthesis of Mat 203

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 18] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 675.25

[Synthesis Example 204] Synthesis of Mat 204

The same procedure as in [Synthesis Example 5] was conducted except that [Preparation Example 18] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 751.28

[Synthesis Example 205] Synthesis of Mat 205

The same procedure as in [Synthesis Example 9] was conducted except that [Preparation Example 18] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 765.26

 [Synthesis Example 206] Synthesis of Mat 206

The same procedure as in [Synthesis Example 11] was carried out except that [Preparation Example 18] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 855.27

[Synthesis Example 207] Synthesis of Mat 207

The same procedure as in [Synthesis Example 12] was conducted except that [Preparation Example 18] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 855.27

[Synthesis Example 208] Synthesis of Mat 208

The same procedure as in [Synthesis Example 13] was conducted except that [Preparation Example 18] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 648.24

[Synthesis Example 209] Synthesis of Mat 209

The same procedure as in [Synthesis Example 14] was conducted except that [Preparation Example 18] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 704.21

[Synthesis Example 210] Synthesis of Mat 210

The same procedure as in [Synthesis Example 15] was conducted except that [Preparation Example 18] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 648.24

[Synthesis Example 211] Synthesis of Mat 211

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 19] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 802.32

[Synthesis Example 212] Synthesis of Mat 212

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 19] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 816.30

[Synthesis Example 213] Synthesis of Mat 213

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 19] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 727.28

[Synthesis Example 214] Synthesis of Mat 214

The same procedure as in [Synthesis Example 5] was conducted except that [Preparation Example 19] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 803.31

[Synthesis Example 215] Synthesis of Mat 215

The same procedure as in [Synthesis Example 9] was conducted except that [Preparation Example 19] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 817.29

[Synthesis Example 216] Synthesis of Mat 216

The same procedure as in [Synthesis Example 11] was carried out except that [Preparation Example 19] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 907.30

[Synthesis Example 217] Synthesis of Mat 217

The same procedure as in [Synthesis Example 12] was carried out except that [Preparation Example 19] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 907.30

[Synthesis Example 218] Synthesis of Mat 218

The same procedure as in [Synthesis Example 13] was carried out except that [Preparation Example 19] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 700.27

[Synthesis Example 219] Synthesis of Mat 219

The same procedure as in [Synthesis Example 14] was carried out except that [Preparation Example 19] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 756.24

[Synthesis Example 220] Synthesis of Mat 220

The same procedure as in [Synthesis Example 15] was conducted except that [Preparation Example 19] was used as a reactant, to obtain the desired compound (13.7 g; HRMS [M] < + >: 700.27

[Synthesis Example 221] Synthesis of Mat 221

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 20] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 852.33

[Synthesis Example 222] Synthesis of Mat 222

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 20] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 866.31

[Synthesis Example 223] Synthesis of Mat 223

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 20] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 777.30

[Synthesis Example 224] Synthesis of Mat 224

The same procedure as in [Synthesis Example 5] was conducted except that [Preparation Example 20] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 853.33

[Synthesis Example 225] Synthesis of Mat 225

The same procedure as in [Synthesis Example 9] was conducted except that [Preparation Example 20] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 867.31

[Synthesis Example 226] Synthesis of Mat 226

The same procedure as in [Synthesis Example 11] was carried out except that [Preparation Example 20] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 957.32

[Synthesis Example 227] Synthesis of Mat 227

The procedure of Synthesis Example 12 was repeated except that [Preparation Example 20] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 957.32

[Synthesis Example 228] Synthesis of Mat 228

The same procedure as in [Synthesis Example 13] was carried out except that [Preparation Example 20] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 750.29

[Synthesis Example 229] Synthesis of Mat 229

The same procedure as in [Synthesis Example 14] was conducted except that [Preparation Example 20] was used as a reactant, to obtain 14.6 g of the target compound; HRMS [M] < + >: 806.26

[Synthesis Example 230] Synthesis of Mat 230

The same procedure as in [Synthesis Example 15] was carried out, except that [Preparation Example 20] was used as a reactant, to obtain the desired compound (13.7 g; HRMS [M] < + >: 750.29

[Synthesis Example 231] Synthesis of Mat 231

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 21] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 752.30

[Synthesis Example 232] Synthesis of Mat 232

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 21] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 766.28

[Synthesis Example 233] Synthesis of Mat 233

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 21] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 677.27

[Synthesis Example 234] Synthesis of Mat 234

The same procedure as in [Synthesis Example 5] was conducted except that [Preparation Example 21] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 753.30

[Synthesis Example 235] Synthesis of Mat 235

The same procedure as in [Synthesis Example 9] was carried out except that [Preparation Example 21] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 767.28

[Synthesis Example 236] Synthesis of Mat 236

The same procedure as in [Synthesis Example 11] was carried out except that [Preparation Example 21] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 857.29

[Synthesis Example 237] Synthesis of Mat 237

The same procedure as in [Synthesis Example 12] was repeated except that [Preparation Example 21] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 857.29

[Synthesis Example 238] Synthesis of Mat 238

The same procedure as in [Synthesis Example 13] was carried out except that [Preparation Example 21] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 650.26

[Synthesis Example 239] Synthesis of Mat 239

The same procedure as in [Synthesis Example 14] was carried out except that [Preparation Example 21] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 706.23

[Synthesis Example 240] Synthesis of Mat 240

The same procedure as in [Synthesis Example 15] was conducted except that [Preparation Example 21] was used as a reactant, to obtain 13.7 g of the desired compound; HRMS [M] < + >: 650.26

[Synthesis Example 241] Synthesis of Mat 241

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 22] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 802.32

[Synthesis Example 242] Synthesis of Mat 242

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 22] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 816.30

[Synthesis Example 243] Synthesis of Mat 243

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 22] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 727.28

[Synthesis Example 244] Synthesis of Mat 244

The same procedure as in [Synthesis Example 5] was carried out except that [Preparation Example 22] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 803.31

[Synthesis Example 245] Synthesis of Mat 245

The same procedure as in [Synthesis Example 9] was conducted except that [Preparation Example 22] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 817.29

[Synthesis Example 246] Synthesis of Mat 246

The same procedure as in [Synthesis Example 11] was carried out except that [Preparation Example 22] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 907.30

[Synthesis Example 247] Synthesis of Mat 247

The same procedure as in [Synthesis Example 12] was carried out except that [Preparation Example 22] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 907.30

[Synthesis Example 248] Synthesis of Mat 248

The same procedure as in [Synthesis Example 13] was carried out except that [Preparation Example 22] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 700.27

[Synthesis Example 249] Synthesis of Mat 249

The same procedure as in [Synthesis Example 14] was carried out except that [Preparation Example 22] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 756.24

[Synthesis Example 250] Synthesis of Mat 250

The same procedure as in [Synthesis Example 15] was conducted except that [Preparation Example 22] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 700.27

 [Synthesis Example 251] Synthesis of Mat 251

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 23] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 826.32

[Synthesis Example 252] Synthesis of Mat 252

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 23] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 840.30

[Synthesis Example 253] Synthesis of Mat 253

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 23] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 751.28

[Synthesis Example 254] Synthesis of Mat 254

The same procedure as in [Synthesis Example 5] was carried out except that [Preparation Example 23] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 827.31

[Synthesis Example 255] Synthesis of Mat 255

The same procedure as in [Synthesis Example 9] was conducted except that [Preparation Example 23] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 841.29

 [Synthesis Example 256] Synthesis of Mat 256

The same procedure as in [Synthesis Example 11] was carried out except that [Preparation Example 23] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 831.30

[Synthesis Example 257] Synthesis of Mat 257

The same procedure as in [Synthesis Example 12] was conducted except that [Preparation Example 23] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 831.30

[Synthesis Example 258] Synthesis of Mat 258

The same procedure as in [Synthesis Example 13] was carried out except that [Preparation Example 23] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 724.27

[Synthesis Example 259] Synthesis of Mat 259

The same procedure as in [Synthesis Example 14] was carried out except that [Preparation Example 23] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 780.24

[Synthesis Example 260] Synthesis of Mat 260

The same procedure as in [Synthesis Example 15] was conducted except that [Preparation Example 23] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 724.27

 [Synthesis Example 261] Synthesis of Mat 261

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 24] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 826.32

[Synthesis Example 262] Synthesis of Mat 262

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 24] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 840.30

[Synthesis Example 263] Synthesis of Mat 263

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 24] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 751.28

[Synthesis Example 264] Synthesis of Mat 264

The same procedure as in [Synthesis Example 5] was carried out except that [Preparation Example 24] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 827.31

[Synthesis Example 265] Synthesis of Mat 265

The same procedure as in [Synthesis Example 9] was conducted except that [Preparation Example 24] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 841.29

 [Synthesis Example 266] Synthesis of Mat 266

The same procedure as in [Synthesis Example 11] was carried out except that [Preparation Example 24] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 931.30

[Synthesis Example 267] Synthesis of Mat 267

The same procedure as in [Synthesis Example 12] was conducted except that [Preparation Example 24] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 931.30

[Synthesis Example 268] Synthesis of Mat 268

The same procedure as in [Synthesis Example 13] was carried out except that [Preparation Example 24] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 724.27

[Synthesis Example 269] Synthesis of Mat 269

The same procedure as in [Synthesis Example 14] was conducted except that [Preparation Example 24] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 780.24

[Synthesis Example 270] Synthesis of Mat 270

The same procedure as in [Synthesis Example 15] was carried out except that [Preparation Example 24] was used as a reactant, to obtain the desired compound (13.7 g; HRMS [M] < + >: 724.27

[Synthesis Example 271] Synthesis of Mat 271

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 25] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 802.32

[Synthesis Example 272] Synthesis of Mat 272

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 25] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 816.30

[Synthesis Example 273] Synthesis of Mat 273

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 25] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 727.28

[Synthesis Example 274] Synthesis of Mat 274

The same procedure as in [Synthesis Example 5] was carried out except that [Preparation Example 25] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 803.31

[Synthesis Example 275] Synthesis of Mat 275

The same procedure as in [Synthesis Example 9] was conducted except that [Preparation Example 25] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 817.29

[Synthesis Example 276] Synthesis of Mat 276

The same procedure as in [Synthesis Example 11] was carried out except that [Preparation Example 25] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 907.30

[Synthesis Example 277] Synthesis of Mat 277

The same procedure as in [Synthesis Example 12] was conducted except that [Preparation Example 25] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 907.30

[Synthesis Example 278] Synthesis of Mat 278

The same procedure as in [Synthesis Example 13] was carried out except that [Preparation Example 25] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 700.27

[Synthesis Example 279] Synthesis of Mat 279

The same procedure as in [Synthesis Example 14] was carried out except that [Preparation Example 25] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 756.24

[Synthesis Example 280] Synthesis of Mat 280

The same procedure as in [Synthesis Example 15] was carried out, except that [Preparation Example 25] was used as a reactant, to obtain the desired compound (13.7 g; HRMS [M] < + >: 700.27

[Synthesis Example 281] Synthesis of Mat 281

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 26] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 852.33

[Synthesis Example 282] Synthesis of Mat 282

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 26] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 866.31

[Synthesis Example 283] Synthesis of Mat 283

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 26] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 777.30

[Synthesis Example 284] Synthesis of Mat 284

The same procedure as in [Synthesis Example 5] was carried out except that [Preparation Example 26] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 853.33

[Synthesis Example 285] Synthesis of Mat 285

The same procedure as in [Synthesis Example 9] was carried out except that [Preparation Example 26] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 867.31

[Synthesis Example 286] Synthesis of Mat 286

The same procedure as in [Synthesis Example 11] was conducted except that [Preparation Example 26] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 957.32

[Synthesis Example 287] Synthesis of Mat 287

The same procedure as in [Synthesis Example 12] was carried out except that [Preparation Example 26] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 957.32

[Synthesis Example 288] Synthesis of Mat 288

The same procedure as in [Synthesis Example 13] was carried out except that [Preparation Example 26] was used as a reactant, to obtain 14.4 g of the desired compound; HRMS [M] < + >: 750.29

[Synthesis Example 289] Synthesis of Mat 289

The same procedure as in [Synthesis Example 14] was conducted except that [Preparation Example 26] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 806.26

[Synthesis Example 290] Synthesis of Mat 290

The same procedure as in [Synthesis Example 15] was carried out except that [Preparation Example 26] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 750.29

[Synthesis Example 291] Synthesis of Mat 291

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 27] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 752.30

[Synthesis Example 292] Synthesis of Mat 292

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 27] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 766.28

[Synthesis Example 293] Synthesis of Mat 293

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 27] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 677.27

[Synthesis Example 294] Synthesis of Mat 294

The same procedure as in [Synthesis Example 5] was carried out except that [Preparation Example 27] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 753.30

[Synthesis Example 295] Synthesis of Mat 295

The same procedure as in [Synthesis Example 9] was conducted except that [Preparation Example 27] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 767.28

[Synthesis Example 296] Synthesis of Mat 296

The same procedure as in [Synthesis Example 11] was conducted except that [Preparation Example 27] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 857.29

[Synthesis Example 297] Synthesis of Mat 297

The same procedure as in [Synthesis Example 12] was carried out except that [Preparation Example 27] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 857.29

[Synthesis Example 298] Synthesis of Mat 298

The same procedure as in [Synthesis Example 13] was carried out except that [Preparation Example 27] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 650.26

[Synthesis Example 299] Synthesis of Mat 299

The same procedure as in [Synthesis Example 14] was carried out except that [Preparation Example 27] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 706.23

[Synthesis Example 300] Synthesis of Mat 300

The same procedure as in [Synthesis Example 15] was carried out except that [Preparation Example 27] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 650.26

[Synthesis Example 301] Synthesis of Mat 301

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 28] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 802.32

[Synthesis Example 302] Synthesis of Mat 302

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 28] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 816.30

[Synthesis Example 303] Synthesis of Mat 303

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 28] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 727.28

[Synthesis Example 304] Synthesis of Mat 304

The same procedure as in [Synthesis Example 5] was carried out except that [Preparation Example 28] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 803.31

[Synthesis Example 305] Synthesis of Mat 305

The same procedure as in [Synthesis Example 9] was carried out except that [Preparation Example 28] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 817.29

[Synthesis Example 306] Synthesis of Mat 306

The same procedure as in [Synthesis Example 11] was carried out except that [Preparation Example 28] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 907.30

[Synthesis Example 307] Synthesis of Mat 307

The same procedure as in [Synthesis Example 12] was carried out except that [Preparation Example 28] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 907.30

[Synthesis Example 308] Synthesis of Mat 308

The same procedure as in [Synthesis Example 13] was carried out except that [Preparation Example 28] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 700.27

[Synthesis Example 309] Synthesis of Mat 309

The same procedure as in [Synthesis Example 14] was carried out except that [Preparation Example 28] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 756.24

[Synthesis Example 310] Synthesis of Mat 310

The same procedure as in [Synthesis Example 15] was carried out except that [Preparation Example 28] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 700.27

 [Synthesis Example 311] Synthesis of Mat 311

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 29] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 826.32

[Synthesis Example 312] Synthesis of Mat 312

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 29] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 840.30

[Synthesis Example 313] Synthesis of Mat 313

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 29] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 751.28

[Synthesis Example 314] Synthesis of Mat 314

The same procedure as in [Synthesis Example 5] was carried out except that [Preparation Example 29] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 827.31

[Synthesis Example 315] Synthesis of Mat 315

The same procedure as in [Synthesis Example 9] was conducted except that [Preparation Example 29] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 841.29

 [Synthesis Example 316] Synthesis of Mat 316

The same procedure as in [Synthesis Example 11] was conducted except that [Preparation Example 29] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 831.30

[Synthesis Example 317] Synthesis of Mat 317

The same procedure as in [Synthesis Example 12] was conducted except that [Preparation Example 29] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 831.30

[Synthesis Example 318] Synthesis of Mat 318

The same procedure as in [Synthesis Example 13] was carried out except that [Preparation Example 29] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 724.27

[Synthesis Example 319] Synthesis of Mat 319

The same procedure as in [Synthesis Example 14] was carried out except that [Preparation Example 29] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 780.24

[Synthesis Example 320] Synthesis of Mat 320

The same procedure as in [Synthesis Example 15] was carried out except that [Preparation Example 29] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 724.27

 [Synthesis Example 321] Synthesis of Mat 321

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 30] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 826.32

[Synthesis Example 322] Synthesis of Mat 322

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 30] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 840.30

[Synthesis Example 323] Synthesis of Mat 323

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 30] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 751.28

[Synthesis Example 324] Synthesis of Mat 324

The same procedure as in [Synthesis Example 5] was carried out except that [Preparation Example 30] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 827.31

[Synthesis Example 325] Synthesis of Mat 325

The same procedure as in [Synthesis Example 9] was conducted except that [Preparation Example 30] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 841.29

 [Synthesis Example 326] Synthesis of Mat 326

The same procedure as in [Synthesis Example 11] was conducted except that [Preparation Example 30] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 931.30

[Synthesis Example 327] Synthesis of Mat 327

The same procedure as in [Synthesis Example 12] was carried out except that [Preparation Example 30] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 931.30

[Synthesis Example 328] Synthesis of Mat 328

The same procedure as in [Synthesis Example 13] was carried out except that [Preparation Example 30] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 724.27

[Synthesis Example 329] Synthesis of Mat 329

The same procedure as in [Synthesis Example 14] was carried out except that [Preparation Example 30] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 780.24

[Synthesis Example 330] Synthesis of Mat 330

The same procedure as in [Synthesis Example 15] was conducted except that [Preparation Example 30] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 724.27

[Synthesis Example 331] Synthesis of Mat 331

The same procedure as in [Synthesis Example 1] was carried out except that [Preparation Example 31] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 624.24

[Synthesis Example 332] Synthesis of Mat 332

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 31] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 700.27

[Synthesis Example 333] Synthesis of Mat 333

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 31] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 714.25

[Synthesis Example 334] Synthesis of Mat 334

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 31] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 625.23

[Synthesis Example 335] Synthesis of Mat 335

The same procedure as in [Synthesis Example 5] was carried out except that [Preparation Example 31] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 701.27

[Synthesis Example 336] Synthesis of Mat 336

The same procedure as in [Synthesis Example 6] was conducted except that [Preparation Example 31] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 702.26

[Synthesis Example 337] Synthesis of Mat 337

The same procedure as in [Synthesis Example 7] was carried out except that [Preparation Example 31] was used as a reactant, to obtain 14.0 g of the target compound; HRMS [M] < + >: 777.30

[Synthesis Example 338] Synthesis of Mat 338

The same procedure as in [Synthesis Example 8] was conducted except that [Preparation Example 31] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 751.28

[Synthesis Example 339] Synthesis of Mat 339

The same procedure as in [Synthesis Example 9] was conducted except that [Preparation Example 31] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 715.25

[Synthesis Example 340] Synthesis of Mat 340

The same procedure as in [Synthesis Example 10] was conducted except that [Preparation Example 31] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 791.28

[Synthesis Example 341] Synthesis of Mat 341

The same procedure as in [Synthesis Example 11] was conducted except that [Preparation Example 31] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 805.26

[Synthesis Example 342] Synthesis of Mat 342

The same procedure as in [Synthesis Example 12] was conducted except that [Preparation Example 31] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 805.26

[Synthesis Example 343] Synthesis of Mat 343

The same procedure as in [Synthesis Example 13] was carried out except that [Preparation Example 31] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 598.22

[Synthesis Example 344] Synthesis of Mat 344

The same procedure as in [Synthesis Example 14] was carried out except that [Preparation Example 31] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 654.20

[Synthesis Example 345] Synthesis of Mat 345

The same procedure as in [Synthesis Example 15] was carried out except that [Preparation Example 31] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 598.22

[Synthesis Example 346] Synthesis of Mat 346

The same procedure as in [Synthesis Example 1] was carried out except that [Preparation Example 32] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 674.26

[Synthesis Example 347] Synthesis of Mat 347

The procedure of [Synthesis Example 2] was repeated except that [Preparation Example 32] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 750.29

[Synthesis Example 348] Synthesis of Mat 348

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 32] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 764.27

[Synthesis Example 349] Synthesis of Mat 349

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 32] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 675.25

[Synthesis Example 350] Synthesis of Mat 350

The same procedure as in [Synthesis Example 5] was carried out except that [Preparation Example 32] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 751.28

[Synthesis Example 351] Synthesis of Mat 351

The same procedure as in [Synthesis Example 6] was carried out except that [Preparation Example 32] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 752.28

[Synthesis Example 352] Synthesis of Mat 352

The same procedure as in [Synthesis Example 7] was carried out except that [Preparation Example 32] was used as a reactant, to obtain 14.0 g of the title compound; HRMS [M] < + >: 827.31

[Synthesis Example 353] Synthesis of Mat 353

The same procedure as in [Synthesis Example 8] was carried out except that [Preparation Example 32] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 801.30

[Synthesis Example 354] Synthesis of Mat 354

The same procedure as in [Synthesis Example 9] was conducted except that [Preparation Example 32] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 765.26

[Synthesis Example 355] Synthesis of Mat 355

The same procedure as in [Synthesis Example 10] was conducted except that [Preparation Example 32] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 841.29

[Synthesis Example 356] Synthesis of Mat 356

The same procedure as in [Synthesis Example 11] was carried out except that [Preparation Example 32] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 855.27

[Synthesis Example 357] Synthesis of Mat 357

The same procedure as in [Synthesis Example 12] was carried out except that [Preparation Example 32] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 855.27

[Synthesis Example 358] Synthesis of Mat 358

The same procedure as in [Synthesis Example 13] was carried out except that [Preparation Example 32] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 648.24

[Synthesis Example 359] Synthesis of Mat 359

The same procedure as in [Synthesis Example 14] was carried out except that [Preparation Example 32] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 704.21

[Synthesis Example 360] Synthesis of Mat 360

The same procedure as in [Synthesis Example 15] was conducted except that [Preparation Example 32] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 648.24

[Synthesis Example 361] Synthesis of Mat 361

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 33] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 574.22

[Synthesis Example 362] Synthesis of Mat 362

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 33] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 650.26

[Synthesis Example 363] Synthesis of Mat 363

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 33] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 664.23

[Synthesis Example 364] Synthesis of Mat 364

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 33] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 575.22

[Synthesis Example 365] Synthesis of Mat 365

The same procedure as in [Synthesis Example 5] was carried out except that [Preparation Example 33] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 651.25

[Synthesis Example 366] Synthesis of Mat 366

The same procedure as in [Synthesis Example 6] was carried out except that [Preparation Example 33] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 652.25

[Synthesis Example 367] Synthesis of Mat 367

The same procedure as in [Synthesis Example 7] was carried out except that [Preparation Example 33] was used as a reactant, to obtain 14.0 g of the target compound; HRMS [M] < + >: 627.28

[Synthesis Example 368] Synthesis of Mat 368

The same procedure as in [Synthesis Example 8] was carried out except that [Preparation Example 33] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 701.27

[Synthesis Example 369] Synthesis of Mat 369

The same procedure as in [Synthesis Example 9] was carried out except that [Preparation Example 33] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 665.23

[Synthesis Example 370] Synthesis of Mat 370

The same procedure as in [Synthesis Example 10] was carried out except that [Preparation Example 33] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 741.26

[Synthesis Example 371] Synthesis of Mat 371

The same procedure as in [Synthesis Example 11] was carried out except that [Preparation Example 33] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 755.24

[Synthesis Example 372] Synthesis of Mat 372

The same procedure as in [Synthesis Example 12] was carried out except that [Preparation Example 33] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 755.24

[Synthesis Example 373] Synthesis of Mat 373

The same procedure as in [Synthesis Example 13] was carried out except that [Preparation Example 33] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 548.21

[Synthesis Example 374] Synthesis of Mat 374

The same procedure as in [Synthesis Example 14] was carried out except that [Preparation Example 33] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 604.18

[Synthesis Example 375] Synthesis of Mat 375

The same procedure as in [Synthesis Example 15] was carried out except that [Preparation Example 33] was used as a reactant, to obtain the desired compound (13.7 g; HRMS [M] < + >: 548.21

[Synthesis Example 376] Synthesis of Mat 376

The same procedure as in [Synthesis Example 1] was carried out except that [Preparation Example 34] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 624.24

[Synthesis Example 377] Synthesis of Mat 377

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 34] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 700.27

[Synthesis Example 378] Synthesis of Mat 378

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 34] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 714.25

[Synthesis Example 379] Synthesis of Mat 379

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 34] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 625.23

[Synthesis Example 380] Synthesis of Mat 380

The same procedure as in [Synthesis Example 5] was carried out except that [Preparation Example 34] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 701.27

[Synthesis Example 381] Synthesis of Mat 381

The same procedure as in [Synthesis Example 6] was conducted except that [Preparation Example 34] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 701.26

[Synthesis Example 382] Synthesis of Mat 382

The same procedure as in [Synthesis Example 7] was carried out except that [Preparation Example 34] was used as a reactant, to obtain 14.0 g of the title compound; HRMS [M] < + >: 777.30

[Synthesis Example 383] Synthesis of Mat 383

The procedure of Synthesis Example 8 was repeated except that [Preparation Example 34] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 751.28

[Synthesis Example 384] Synthesis of Mat 384

The same procedure as in [Synthesis Example 9] was carried out except that [Preparation Example 34] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 715.25

[Synthesis Example 385] Synthesis of Mat 385

The same procedure as in [Synthesis Example 10] was conducted except that [Preparation Example 34] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 791.28

[Synthesis Example 386] Synthesis of Mat 386

The same procedure as in [Synthesis Example 11] was conducted except that [Preparation Example 34] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 805.26

[Synthesis Example 387] Synthesis of Mat 387

The same procedure as in [Synthesis Example 12] was conducted except that [Preparation Example 34] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 805.26

[Synthesis Example 388] Synthesis of Mat 388

The same procedure as in [Synthesis Example 13] was carried out except that [Preparation Example 34] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 598.22

[Synthesis Example 389] Synthesis of Mat 389

The same procedure as in [Synthesis Example 14] was carried out except that [Preparation Example 34] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 654.20

[Synthesis Example 390] Synthesis of Mat 390

The same procedure as in [Synthesis Example 15] was conducted except that [Preparation Example 34] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 598.22

[Synthesis Example 391] Synthesis of Mat 391

The same procedure as in [Synthesis Example 1] was carried out except that [Preparation Example 35] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 648.24

[Synthesis Example 392] Synthesis of Mat 392

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 35] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 724.27

[Synthesis Example 393] Synthesis of Mat 393

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 35] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 738.25

[Synthesis Example 394] Synthesis of Mat 394

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 35] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 649.23

[Synthesis Example 395] Synthesis of Mat 395

The same procedure as in [Synthesis Example 5] was carried out except that [Preparation Example 35] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 725.27

[Synthesis Example 396] Synthesis of Mat 396

The same procedure as in [Synthesis Example 6] was conducted except that [Preparation Example 35] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 726.26

[Synthesis Example 397] Synthesis of Mat 397

The same procedure as in [Synthesis Example 7] was carried out except that [Preparation Example 35] was used as a reactant, to obtain 14.0 g of the title compound; HRMS [M] < + >: 801.30

[Synthesis Example 398] Synthesis of Mat 398

The same procedure as in [Synthesis Example 8] was carried out except that [Preparation Example 35] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 775.28

[Synthesis Example 399] Synthesis of Mat 399

The same procedure as in [Synthesis Example 9] was carried out except that [Preparation Example 35] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 739.25

[Synthesis Example 400] Synthesis of Mat 400

The same procedure as in [Synthesis Example 10] was carried out except that [Preparation Example 35] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 815.28

[Synthesis Example 401] Synthesis of Mat 401

The same procedure as in [Synthesis Example 11] was carried out except that [Preparation Example 35] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 829.26

[Synthesis Example 402] Synthesis of Mat 402

The same procedure as in [Synthesis Example 12] was carried out except that [Preparation Example 35] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 829.26

[Synthesis Example 403] Synthesis of Mat 403

The same procedure as in [Synthesis Example 13] was conducted except that [Preparation Example 35] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 622.22

[Synthesis Example 404] Synthesis of Mat 404

The same procedure as in [Synthesis Example 14] was conducted except that [Preparation Example 35] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 628.18

[Synthesis Example 405] Synthesis of Mat 405

The same procedure as in [Synthesis Example 15] was conducted except that [Preparation Example 35] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 622.22

[Synthesis Example 406] Synthesis of Mat 406

The same procedure as in [Synthesis Example 1] was carried out except that [Preparation Example 36] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 648.24

[Synthesis Example 407] Synthesis of Mat 407

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 36] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 724.27

[Synthesis Example 408] Synthesis of Mat 408

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 36] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 738.25

[Synthesis Example 409] Synthesis of Mat 409

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 36] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 649.23

[Synthesis Example 410] Synthesis of Mat 410

The same procedure as in [Synthesis Example 5] was carried out except that [Preparation Example 36] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 725.27

[Synthesis Example 411] Synthesis of Mat 411

The same procedure as in [Synthesis Example 6] was conducted except that [Preparation Example 36] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 726.26

[Synthesis Example 412] Synthesis of Mat 412

The same procedure as in [Synthesis Example 7] was carried out except that [Preparation Example 36] was used as a reactant, to obtain 14.0 g of the title compound; HRMS [M] < + >: 801.30

[Synthesis Example 413] Synthesis of Mat 413

The same procedure as in [Synthesis Example 8] was carried out except that [Preparation Example 36] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 775.28

[Synthesis Example 414] Synthesis of Mat 414

The same procedure as in [Synthesis Example 9] was conducted except that [Preparation Example 36] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 739.25

[Synthesis Example 415] Synthesis of Mat 415

The same procedure as in [Synthesis Example 10] was conducted except that [Preparation Example 36] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 815.28

[Synthesis Example 416] Synthesis of Mat 416

The same procedure as in [Synthesis Example 11] was carried out except that [Preparation Example 36] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 829.26

[Synthesis Example 417] Synthesis of Mat 417

The same procedure as in [Synthesis Example 12] was repeated except that [Preparation Example 36] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 829.26

[Synthesis Example 418] Synthesis of Mat 418

The same procedure as in [Synthesis Example 13] was carried out except that [Preparation Example 36] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 622.22

[Synthesis Example 419] Synthesis of Mat 419

The same procedure as in [Synthesis Example 14] was carried out except that [Preparation Example 36] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 678.20

[Synthesis Example 420] Synthesis of Mat 420

The same procedure as in [Synthesis Example 15] was carried out except that [Preparation Example 36] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 622.22

[Synthesis Example 421] Synthesis of Mat 421

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 37] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 700.27

[Synthesis Example 422] Synthesis of Mat 422

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 37] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 714.25

[Synthesis Example 423] Synthesis of Mat 423

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 37] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 625.23

[Synthesis Example 424] Synthesis of Mat 424

The same procedure as in [Synthesis Example 5] was carried out except that [Preparation Example 37] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 701.27

[Synthesis Example 425] Synthesis of Mat 425

The same procedure as in [Synthesis Example 9] was conducted except that [Preparation Example 37] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 715.25

[Synthesis Example 426] Synthesis of Mat 426

The same procedure as in [Synthesis Example 11] was conducted except that [Preparation Example 37] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 805.26

[Synthesis Example 427] Synthesis of Mat 427

The same procedure as in [Synthesis Example 12] was carried out except that [Preparation Example 37] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 805.26

[Synthesis Example 428] Synthesis of Mat 428

The same procedure as in [Synthesis Example 13] was carried out except that [Preparation Example 37] was used as a reactant, to obtain 14.4 g of the desired compound; HRMS [M] < + >: 598.22

[Synthesis Example 429] Synthesis of Mat 429

The same procedure as in [Synthesis Example 14] was carried out except that [Preparation Example 37] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 654.20

[Synthesis Example 430] Synthesis of Mat 430

The same procedure as in [Synthesis Example 15] was conducted except that [Preparation Example 37] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 598.22

[Synthesis Example 431] Synthesis of Mat 431

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 38] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 750.29

[Synthesis Example 432] Synthesis of Mat 432

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 38] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 764.27

[Synthesis Example 433] Synthesis of Mat 433

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 38] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 675.25

[Synthesis Example 434] Synthesis of Mat 434

The same procedure as in [Synthesis Example 5] was carried out except that [Preparation Example 38] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 751.28

[Synthesis Example 435] Synthesis of Mat 435

The same procedure as in [Synthesis Example 9] was carried out except that [Preparation Example 38] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 765.26

[Synthesis Example 436] Synthesis of Mat 436

The same procedure as in [Synthesis Example 11] was conducted except that [Preparation Example 38] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 855.27

[Synthesis Example 437] Synthesis of Mat 437

The same procedure as in [Synthesis Example 12] was carried out except that [Preparation Example 38] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 855.27

[Synthesis Example 438] Synthesis of Mat 438

The same procedure as in [Synthesis Example 13] was carried out except that [Preparation Example 38] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 648.24

[Synthesis Example 439] Synthesis of Mat 439

The same procedure as in [Synthesis Example 14] was carried out except that [Preparation Example 38] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 704.21

[Synthesis Example 440] Synthesis of Mat 440

The same procedure as in [Synthesis Example 15] was carried out except that [Preparation Example 38] was used as a reactant, to obtain the desired compound (13.7 g; HRMS [M] < + >: 648.24

[Synthesis Example 441] Synthesis of Mat 441

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 39] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 650.26

[Synthesis Example 442] Synthesis of Mat 442

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 39] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 664.23

[Synthesis Example 443] Synthesis of Mat 443

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 39] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 575.22

[Synthesis Example 444] Synthesis of Mat 444

The same procedure as in [Synthesis Example 5] was carried out except that [Preparation Example 39] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 651.25

[Synthesis Example 445] Synthesis of Mat 445

The same procedure as in [Synthesis Example 9] was carried out except that [Preparation Example 39] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 665.23

[Synthesis Example 446] Synthesis of Mat 446

The same procedure as in [Synthesis Example 11] was carried out except that [Preparation Example 39] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 755.24

[Synthesis Example 447] Synthesis of Mat 447

The same procedure as in [Synthesis Example 12] was carried out except that [Preparation Example 39] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 755.24

[Synthesis Example 448] Synthesis of Mat 448

The same procedure as in [Synthesis Example 13] was carried out except that [Preparation Example 39] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 548.21

[Synthesis Example 449] Synthesis of Mat 449

The same procedure as in [Synthesis Example 14] was carried out except that [Preparation Example 39] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 604.18

[Synthesis Example 450] Synthesis of Mat 450

The same procedure as in [Synthesis Example 15] was conducted except that [Preparation Example 39] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 548.21

[Synthesis Example 451] Synthesis of Mat 451

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 40] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 700.27

[Synthesis Example 452] Synthesis of Mat 452

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 40] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 714.25

[Synthesis Example 453] Synthesis of Mat 453

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 40] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 625.23

[Synthesis Example 454] Synthesis of Mat 454

The same procedure as in [Synthesis Example 5] was carried out except that [Preparation Example 40] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 701.27

[Synthesis Example 455] Synthesis of Mat 455

The same procedure as in [Synthesis Example 9] was carried out except that [Preparation Example 40] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 715.25

[Synthesis Example 456] Synthesis of Mat 456

The same procedure as in [Synthesis Example 11] was carried out except that [Preparation Example 40] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 805.26

[Synthesis Example 457] Synthesis of Mat 457

The same procedure as in [Synthesis Example 12] was carried out except that [Preparation Example 40] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 805.26

[Synthesis Example 458] Synthesis of Mat 458

The same procedure as in [Synthesis Example 13] was carried out except that [Preparation Example 40] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 598.22

[Synthesis Example 459] Synthesis of Mat 459

The same procedure as in [Synthesis Example 14] was conducted except that [Preparation Example 40] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 654.20

[Synthesis Example 460] Synthesis of Mat 460

The same procedure as in [Synthesis Example 15] was carried out except that [Preparation Example 40] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 598.22

[Synthesis Example 461] Synthesis of Mat 461

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 41] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 724.27

[Synthesis Example 462] Synthesis of Mat 462

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 41] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 738.25

[Synthesis Example 463] Synthesis of Mat 463

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 41] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 649.23

[Synthesis Example 464] Synthesis of Mat 464

The same procedure as in [Synthesis Example 5] was conducted except that [Preparation Example 41] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 725.27

[Synthesis Example 465] Synthesis of Mat 465

The same procedure as in [Synthesis Example 9] was carried out except that [Preparation Example 41] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 739.25

[Synthesis Example 466] Synthesis of Mat 466

The same procedure as in [Synthesis Example 11] was conducted except that [Preparation Example 41] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 829.26

[Synthesis Example 467] Synthesis of Mat 467

The same procedure as in [Synthesis Example 12] was carried out except that [Preparation Example 41] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 829.26

[Synthesis Example 468] Synthesis of Mat 468

The same procedure as in [Synthesis Example 13] was carried out except that [Preparation Example 41] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 622.22

[Synthesis Example 469] Synthesis of Mat 469

The same procedure as in [Synthesis Example 14] was carried out except that [Preparation Example 41] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 628.18

[Synthesis Example 470] Synthesis of Mat 470

The same procedure as in [Synthesis Example 15] was conducted except that [Preparation Example 41] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 622.22

[Synthesis Example 471] Synthesis of Mat 471

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 42] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 724.27

[Synthesis Example 472] Synthesis of Mat 472

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 42] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 738.25

[Synthesis Example 473] Synthesis of Mat 473

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 42] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 649.23

[Synthesis Example 474] Synthesis of Mat 474

The same procedure as in [Synthesis Example 5] was conducted except that [Preparation Example 42] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 725.27

[Synthesis Example 475] Synthesis of Mat 475

The same procedure as in [Synthesis Example 9] was conducted except that [Preparation Example 42] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 739.25

[Synthesis Example 476] Synthesis of Mat 476

The same procedure as in [Synthesis Example 11] was conducted except that [Preparation Example 42] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 829.26

[Synthesis Example 477] Synthesis of Mat 477

The same procedure as in [Synthesis Example 12] was carried out except that [Preparation Example 42] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 829.26

[Synthesis Example 478] Synthesis of Mat 478

The same procedure as in [Synthesis Example 13] was carried out except that [Preparation Example 42] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 622.22

[Synthesis Example 479] Synthesis of Mat 479

The same procedure as in [Synthesis Example 14] was conducted except that [Preparation Example 42] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 678.20

[Synthesis Example 480] Synthesis of Mat 480

The same procedure as in [Synthesis Example 15] was carried out except that [Preparation Example 42] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 622.22

[Synthesis Example 481] Synthesis of Mat 481

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 43] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 700.27

[Synthesis Example 482] Synthesis of Mat 482

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 43] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 714.25

[Synthesis Example 483] Synthesis of Mat 483

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 43] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 625.23

[Synthesis Example 484] Synthesis of Mat 484

The same procedure as in [Synthesis Example 5] was carried out except that [Preparation Example 43] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 701.27

[Synthesis Example 485] Synthesis of Mat 485

The same procedure as in [Synthesis Example 9] was conducted except that [Preparation Example 43] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 715.25

[Synthesis Example 486] Synthesis of Mat 486

The same procedure as in [Synthesis Example 11] was carried out except that [Preparation Example 43] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 805.26

[Synthesis Example 487] Synthesis of Mat 487

The procedure of Synthesis Example 12 was repeated except that [Preparation Example 43] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 805.26

[Synthesis Example 488] Synthesis of Mat 488

The same procedure as in [Synthesis Example 13] was carried out except that [Preparation Example 43] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 598.22

[Synthesis Example 489] Synthesis of Mat 489

The same procedure as in [Synthesis Example 14] was conducted except that [Preparation Example 43] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 654.20

[Synthesis Example 490] Synthesis of Mat 490

The same procedure as in [Synthesis Example 15] was carried out, except that [Preparation Example 43] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 598.22

[Synthesis Example 491] Synthesis of Mat 491

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 44] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 750.29

[Synthesis Example 492] Synthesis of Mat 492

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 44] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 764.27

[Synthesis Example 493] Synthesis of Mat 493

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 44] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 675.25

[Synthesis Example 494] Synthesis of Mat 494

The same procedure as in [Synthesis Example 5] was carried out except that [Preparation Example 44] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 751.28

[Synthesis Example 495] Synthesis of Mat 495

The same procedure as in [Synthesis Example 9] was conducted except that [Preparation Example 44] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 765.26

[Synthesis Example 496] Synthesis of Mat 496

The same procedure as in [Synthesis Example 11] was carried out except that [Preparation Example 44] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 855.27

[Synthesis Example 497] Synthesis of Mat 497

The same procedure as in [Synthesis Example 12] was carried out except that [Preparation Example 44] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 855.27

[Synthesis Example 498] Synthesis of Mat 498

The same procedure as in [Synthesis Example 13] was carried out except that [Preparation Example 44] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 648.24

[Synthesis Example 499] Synthesis of Mat 499

The same procedure as in [Synthesis Example 14] was carried out except that [Preparation Example 44] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 704.21

[Synthesis Example 500] Synthesis of Mat 500

The same procedure as in [Synthesis Example 15] was conducted except that [Preparation Example 44] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 648.24

[Synthesis Example 501] Synthesis of Mat 501

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 45] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 650.26

[Synthesis Example 502] Synthesis of Mat 502

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 45] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 664.23

[Synthesis Example 503] Synthesis of Mat 503

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 45] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 575.22

[Synthesis Example 504] Synthesis of Mat 504

The same procedure as in [Synthesis Example 5] was carried out except that [Preparation Example 45] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 651.25

[Synthesis Example 505] Synthesis of Mat 505

The same procedure as in [Synthesis Example 9] was conducted except that [Preparation Example 45] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 665.23

[Synthesis Example 506] Synthesis of Mat 506

The same procedure as in [Synthesis Example 11] was conducted except that [Preparation Example 45] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 755.24

[Synthesis Example 507] Synthesis of Mat 507

The same procedure as in [Synthesis Example 12] was conducted except that [Preparation Example 45] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 755.24

[Synthesis Example 508] Synthesis of Mat 508

The same procedure as in [Synthesis Example 13] was carried out except that [Preparation Example 45] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 548.21

[Synthesis Example 509] Synthesis of Mat 509

The same procedure as in [Synthesis Example 14] was carried out except that [Preparation Example 45] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 604.18

[Synthesis Example 510] Synthesis of Mat 510

The same procedure as in [Synthesis Example 15] was conducted except that [Preparation Example 45] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 548.21

[Synthesis Example 511] Synthesis of Mat 511

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 46] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 700.27

[Synthesis Example 512] Synthesis of Mat 512

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 46] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 714.25

[Synthesis Example 513] Synthesis of Mat 513

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 46] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 625.23

[Synthesis Example 514] Synthesis of Mat 514

The same procedure as in [Synthesis Example 5] was carried out except that [Preparation Example 46] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 701.27

[Synthesis Example 515] Synthesis of Mat 515

The same procedure as in [Synthesis Example 9] was conducted except that [Preparation Example 46] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 715.25

[Synthesis Example 516] Synthesis of Mat 516

The same procedure as in [Synthesis Example 11] was carried out except that [Preparation Example 46] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 805.26

[Synthesis Example 517] Synthesis of Mat 517

The same procedure as in [Synthesis Example 12] was conducted except that [Preparation Example 46] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 805.26

[Synthesis Example 518] Synthesis of Mat 518

The same procedure as in [Synthesis Example 13] was carried out except that [Preparation Example 46] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 598.22

[Synthesis Example 519] Synthesis of Mat 519

The same procedure as in [Synthesis Example 14] was conducted except that [Preparation Example 46] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 654.20

[Synthesis Example 520] Synthesis of Mat 520

The same procedure as in [Synthesis Example 15] was carried out except that [Preparation Example 46] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 598.22

[Synthesis Example 521] Synthesis of Mat 521

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 47] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 724.27

[Synthesis Example 522] Synthesis of Mat 522

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 47] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 738.25

[Synthesis Example 523] Synthesis of Mat 523

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 47] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 649.23

[Synthesis Example 524] Synthesis of Mat 524

The same procedure as in [Synthesis Example 5] was carried out except that [Preparation Example 47] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 725.27

[Synthesis Example 525] Synthesis of Mat 525

The same procedure as in [Synthesis Example 9] was carried out except that [Preparation Example 47] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 739.25

[Synthesis Example 526] Synthesis of Mat 526

The same procedure as in [Synthesis Example 11] was conducted except that [Preparation Example 47] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 829.26

[Synthesis Example 527] Synthesis of Mat 527

The procedure of Synthesis Example 12 was repeated except that [Preparation Example 47] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 829.26

[Synthesis Example 528] Synthesis of Mat 528

The same procedure as in [Synthesis Example 13] was carried out except that [Preparation Example 47] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 622.22

[Synthesis Example 529] Synthesis of Mat 529

The same procedure as in [Synthesis Example 14] was conducted except that [Preparation Example 47] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 628.18

[Synthesis Example 530] Synthesis of Mat 530

The same procedure as in [Synthesis Example 15] was carried out except that [Preparation Example 47] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 622.22

[Synthesis Example 531] Synthesis of Mat 531

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 48] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 724.27

[Synthesis Example 532] Synthesis of Mat 532

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 48] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 738.25

[Synthesis Example 533] Synthesis of Mat 533

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 48] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 649.23

[Synthesis Example 534] Synthesis of Mat 534

The same procedure as in [Synthesis Example 5] was carried out except that [Preparation Example 48] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 725.27

[Synthesis Example 535] Synthesis of Mat 535

The same procedure as in [Synthesis Example 9] was carried out except that [Preparation Example 48] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 739.25

[Synthesis Example 536] Synthesis of Mat 536

The same procedure as in [Synthesis Example 11] was carried out except that [Preparation Example 48] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 829.26

[Synthesis Example 537] Synthesis of Mat 537

The procedure of Synthesis Example 12 was repeated except that [Preparation Example 48] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 829.26

[Synthesis Example 538] Synthesis of Mat 538

The same procedure as in [Synthesis Example 13] was carried out except that [Preparation Example 48] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 622.22

[Synthesis Example 539] Synthesis of Mat 539

The same procedure as in [Synthesis Example 14] was conducted except that [Preparation Example 48] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 678.20

[Synthesis Example 540] Synthesis of Mat 540

The same procedure as in [Synthesis Example 15] was carried out, except that [Preparation Example 48] was used as the reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 622.22

[Synthesis Example 541] Synthesis of Mat 541

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 49] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 750.29

[Synthesis Example 542] Synthesis of Mat 542

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 49] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 764.27

[Synthesis Example 543] Synthesis of Mat 543

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 49] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 675.25

[Synthesis Example 544] Synthesis of Mat 544

The same procedure as in [Synthesis Example 5] was conducted except that [Preparation Example 49] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 751.28

[Synthesis Example 545] Synthesis of Mat 545

The same procedure as in [Synthesis Example 9] was conducted except that [Preparation Example 49] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 765.26

[Synthesis Example 546] Synthesis of Mat 546

The same procedure as in [Synthesis Example 11] was carried out except that [Preparation Example 49] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 855.27

[Synthesis Example 547] Synthesis of Mat 547

The same procedure as in [Synthesis Example 12] was carried out except that [Preparation Example 49] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 855.27

[Synthesis Example 548] Synthesis of Mat 548

The same procedure as in [Synthesis Example 13] was carried out except that [Preparation Example 49] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 648.24

[Synthesis Example 549] Synthesis of Mat 549

The same procedure as in [Synthesis Example 14] was carried out except that [Preparation Example 49] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 704.21

[Synthesis Example 550] Synthesis of Mat 550

The same procedure as in [Synthesis Example 15] was carried out except that [Preparation Example 49] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 648.24

[Synthesis Example 551] Synthesis of Mat 551

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 50] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 800.30

[Synthesis Example 552] Synthesis of Mat 552

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 50] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 814.28

[Synthesis Example 553] Synthesis of Mat 553

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 50] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 725.27

[Synthesis Example 554] Synthesis of Mat 554

The same procedure as in [Synthesis Example 5] was conducted except that [Preparation Example 50] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 801.30

[Synthesis Example 555] Synthesis of Mat 555

The same procedure as in [Synthesis Example 9] was conducted except that [Preparation Example 50] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 815.28

[Synthesis Example 556] Synthesis of Mat 556

The same procedure as in [Synthesis Example 11] was conducted except that [Preparation Example 50] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 905.29

[Synthesis Example 557] Synthesis of Mat 557

The same procedure as in [Synthesis Example 12] was conducted except that [Preparation Example 50] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 905.29

[Synthesis Example 558] Synthesis of Mat 558

The same procedure as in [Synthesis Example 13] was carried out except that [Preparation Example 50] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 698.26

[Synthesis Example 559] Synthesis of Mat 559

The same procedure as in [Synthesis Example 14] was conducted except that [Preparation Example 50] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 754.23

[Synthesis Example 560] Synthesis of Mat 560

The same procedure as in [Synthesis Example 15] was carried out except that [Preparation Example 50] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 698.26

[Synthesis Example 561] Synthesis of Mat 561

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 51] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 700.27

[Synthesis Example 562] Synthesis of Mat 562

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 51] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 714.25

[Synthesis Example 563] Synthesis of Mat 563

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 51] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 625.23

[Synthesis Example 564] Synthesis of Mat 564

The same procedure as in [Synthesis Example 5] was carried out except that [Preparation Example 51] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 701.27

[Synthesis Example 565] Synthesis of Mat 565

The same procedure as in [Synthesis Example 9] was conducted except that [Preparation Example 51] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 715.25

[Synthesis Example 566] Synthesis of Mat 566

The same procedure as in [Synthesis Example 11] was carried out except that [Preparation Example 51] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 805.26

[Synthesis Example 567] Synthesis of Mat 567

The same procedure as in [Synthesis Example 12] was carried out except that [Preparation Example 51] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 805.26

[Synthesis Example 568] Synthesis of Mat 568

The same procedure as in [Synthesis Example 13] was conducted except that [Preparation Example 51] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 598.29

[Synthesis Example 569] Synthesis of Mat 569

The same procedure as in [Synthesis Example 14] was carried out except that [Preparation Example 51] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 654.20

[Synthesis Example 570] Synthesis of Mat 570

The same procedure as in [Synthesis Example 15] was conducted except that [Preparation Example 51] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 598.29

[Synthesis Example 571] Synthesis of Mat 571

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 52] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 750.29

[Synthesis Example 572] Synthesis of Mat 572

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 52] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 764.27

[Synthesis Example 573] Synthesis of Mat 573

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 52] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 675.25

[Synthesis Example 574] Synthesis of Mat 574

The same procedure as in [Synthesis Example 5] was carried out except that [Preparation Example 52] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 751.28

[Synthesis Example 575] Synthesis of Mat 575

The same procedure as in [Synthesis Example 9] was conducted except that [Preparation Example 52] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 765.26

[Synthesis Example 576] Synthesis of Mat 376

The same procedure as in [Synthesis Example 11] was conducted except that [Preparation Example 52] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 855.27

[Synthesis Example 577] Synthesis of Mat 577

The same procedure as in [Synthesis Example 12] was carried out except that [Preparation Example 52] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 855.27

[Synthesis Example 578] Synthesis of Mat 578

The same procedure as in [Synthesis Example 13] was carried out except that [Preparation Example 52] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 649.24

[Synthesis Example 579] Synthesis of Mat 579

The same procedure as in [Synthesis Example 14] was carried out except that [Preparation Example 52] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 704.21

[Synthesis Example 580] Synthesis of Mat 580

The same procedure as in [Synthesis Example 15] was carried out except that [Preparation Example 52] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 649.24

[Synthesis Example 581] Synthesis of Mat 581

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 53] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 774.29

[Synthesis Example 582] Synthesis of Mat 582

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 53] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 788.27

[Synthesis Example 583] Synthesis of Mat 583

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 53] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 699.25

[Synthesis Example 584] Synthesis of Mat 584

The same procedure as in [Synthesis Example 5] was carried out except that [Preparation Example 53] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 775.28

[Synthesis Example 585] Synthesis of Mat 585

The same procedure as in [Synthesis Example 9] was carried out except that [Preparation Example 53] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 789.26

[Synthesis Example 586] Synthesis of Mat 586

The same procedure as in [Synthesis Example 11] was carried out except that [Preparation Example 53] was used as a reactant, to obtain 15.3 g of the target compound; HRMS [M] < + >: 879.27

[Synthesis Example 587] Synthesis of Mat 587

The same procedure as in [Synthesis Example 12] was carried out except that [Preparation Example 53] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 879.27

[Synthesis Example 588] Synthesis of Mat 588

The same procedure as in [Synthesis Example 13] was carried out except that [Preparation Example 53] was used as a reactant, to obtain 14.4 g of the desired compound; HRMS [M] < + >: 672.24

[Synthesis Example 589] Synthesis of Mat 589

The same procedure as in [Synthesis Example 14] was conducted except that [Preparation Example 53] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 728.21

[Synthesis Example 590] Synthesis of Mat 590

The same procedure as in [Synthesis Example 15] was carried out except that [Preparation Example 53] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 672.24

[Synthesis Example 591] Synthesis of Mat 591

The same procedure as in [Synthesis Example 2] was carried out except that [Preparation Example 54] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 774.29

[Synthesis Example 592] Synthesis of Mat 592

The same procedure as in [Synthesis Example 3] was carried out except that [Preparation Example 54] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 788.27

[Synthesis Example 593] Synthesis of Mat 593

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 54] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 699.25

[Synthesis Example 594] Synthesis of Mat 594

The same procedure as in [Synthesis Example 5] was carried out except that [Preparation Example 54] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 775.28

[Synthesis Example 595] Synthesis of Mat 595

The same procedure as in [Synthesis Example 9] was conducted except that [Preparation Example 54] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 789.26

[Synthesis Example 596] Synthesis of Mat 596

The same procedure as in [Synthesis Example 11] was carried out except that [Preparation Example 54] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 879.27

[Synthesis Example 597] Synthesis of Mat 597

The procedure of Synthesis Example 12 was repeated except that [Preparation Example 54] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 879.27

[Synthesis Example 598] Synthesis of Mat 598

The same procedure as in [Synthesis Example 13] was carried out except that [Preparation Example 54] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 672.24

[Synthesis Example 599] Synthesis of Mat 599

The same procedure as in [Synthesis Example 14] was carried out except that [Preparation Example 54] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 728.21

[Synthesis Example 600] Synthesis of Mat 600

The same procedure as in [Synthesis Example 15] was conducted except that [Preparation Example 54] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 672.24

[Synthesis Example 601] Synthesis of Mat 601

The procedure of Synthesis Example 4 was repeated except that 4- (3-bromophenyl) -2,6-diphenylpyrimidine was used as the reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 650.26

[Synthesis Example 602] Synthesis of Mat 602

The same procedure as in [Synthesis Example 4] was carried out except that 4 - ([1,1'-biphenyl] -4-yl) -6- (3-bromophenyl) To obtain 14.7 g of the target compound; HRMS [M] < + >: 726.29

[Synthesis Example 603] Synthesis of Mat 603

The same procedure as in [Synthesis Example 4] was carried out except that 4- (3-bromophenyl) -6- (dibenzo [b, d] furan-3-yl) -2-phenylpyrimidine was used as a reactant To obtain 14.7 g of the desired compound; HRMS [M] < + >: 740.27

[Synthesis Example 604] Synthesis of Mat 604

The procedure of Synthesis Example 4 was repeated except for using 2- (3-bromophenyl) -4,6-diphenyl-1,3,5-triazine as a reactant, to obtain 14.7 g of the desired compound .; HRMS [M] < + >: 651.25

[Synthesis Example 605] Synthesis of Mat 605

Except that 2 - ([1,1'-biphenyl] -4-yl) -4- (3-bromophenyl) -6-phenyl-1,3,5-triazine was used as the reactant The procedure of Example 4] was repeated to obtain 14.2 g of the target compound; HRMS [M] < + >: 727.28

[Synthesis Example 606] Synthesis of Mat 606

[Synthesis Example 4] Synthesis was carried out except that 2- (3-bromophenyl) -4-phenyl-6- (4- (pyridin-3- , The target compound (14.2 g) was obtained. HRMS [M] < + >: 728.28

[Synthesis Example 607] Synthesis of Mat 607

The reaction was carried out in the same manner as in Example 1 except that 2 - ([1,1'-biphenyl] -3-yl) -4 - ([1,1'-biphenyl] The same procedure as in [Synthesis Example 4] was carried out except that 3,5-triazine was used to obtain 14.0 g of the target compound; HRMS [M] < + >: 803.31

[Synthesis Example 608] Synthesis of Mat 608

The reaction was carried out using 2 - ([1,1'-biphenyl] -4-yl) -4- (3-bromophenyl) -6- (naphthalen- The procedure of Synthesis Example 4 was followed except that 14.6 g of the desired compound was obtained; HRMS [M] < + >: 777.30

[Synthesis Example 609] Synthesis of Mat 609

Except that 2- (3-bromophenyl) -4- (dibenzo [b, d] furan-3-yl) -6-phenyl-1,3,5-triazine was used as a reaction product. 4] to obtain the desired compound (15.1 g); HRMS [M] < + >: 741.26

[Synthesis Example 610] Synthesis of Mat 610

Dibenzo [b, d] furan-3-yl) -1, 3-dihydro- , 5-triazine was used in place of 5-thiazine, to obtain 15.1 g of the title compound; HRMS [M] < + >: 817.29

[Synthesis Example 611] Synthesis of Mat 611

Except that [2- (3-bromophenyl) -4,6-bis (dibenzo [b, d] furan-3-yl) -1,3,5-triazine was used as a reactant. ] To obtain the target compound (15.3 g); HRMS [M] < + >: 831.27

[Synthesis Example 612] Synthesis of Mat 612

Dibenzo [b, d] furan-2-yl) -6- (dibenzo [b, The same procedure as in [Synthesis Example 4] was conducted except that 5-triazine was used to obtain 14.7 g of the title compound; HRMS [M] < + >: 831.27

[Synthesis Example 613] Synthesis of Mat 613

The same procedure as in [Synthesis Example 4] was carried out except that 4- (4-bromophenyl) -6- (dibenzo [b, d] furan-3-yl) -2-phenylpyrimidine was used as a reactant To obtain 14.4 g of the desired compound; HRMS [M] < + >: 740.27

[Synthesis Example 614] Synthesis of Mat 614

As a reaction product, 2 - ([1,1'-biphenyl] -4-yl) -4- (3'-bromo- [ The same procedure as in [Synthesis Example 4] was conducted except that 3,5-triazine was used to obtain 14.6 g of the target compound; HRMS [M] < + >: 803.31

[Synthesis Example 615] Synthesis of Mat 615

Dibenzo [b, d] furan-3-yl) -6-phenyl-1,3-dihydro- , 5-triazine was used instead of 5-thiophene, the procedure of Synthetic Example 4 was repeated to give the desired compound (13.7 g); HRMS [M] < + >: 817.29

[Synthesis Example 616] Synthesis of Mat 616

The procedure of Synthesis Example 601 was repeated except that [Preparation Example 2] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 700.27

[Synthesis Example 617] Synthesis of Mat 617

The same procedure as in [Synthesis Example 602] was repeated except that [Preparation Example 2] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 776.30

[Synthesis Example 618] Synthesis of Mat 618

The same procedure as in [Synthesis Example 603] was repeated except that [Preparation Example 2] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 790.28

[Synthesis Example 619] Synthesis of Mat 619

The same procedure as in [Synthesis Example 604] was repeated except that [Preparation Example 2] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 701.27

[Synthesis Example 620] Synthesis of Mat 620

The same procedure as in [Synthesis Example 605] was conducted except that [Preparation Example 2] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 777.30

[Synthesis Example 621] Synthesis of Mat 621

The same procedure as in [Synthesis Example 606] was conducted except that [Preparation Example 2] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 778.29

[Synthesis Example 622] Synthesis of Mat 622

The procedure of Synthesis Example 607 was repeated except that [Preparation Example 2] was used as a reactant, to obtain 14.0 g of the desired compound; HRMS [M] < + >: 853.33

[Synthesis Example 623] Synthesis of Mat 623

The same procedure as in [Synthesis Example 608] was repeated except that [Preparation Example 2] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 827.31

[Synthesis Example 624] Synthesis of Mat 624

The same procedure as in [Synthesis Example 609] was conducted except that [Preparation Example 2] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 791.28

[Synthesis Example 625] Synthesis of Mat 625

The procedure of Synthesis Example 610 was repeated except that [Preparation Example 2] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 867.31

[Synthesis Example 626] Synthesis of Mat 626

The same procedure as in [Synthesis Example 611] was repeated except that [Preparation Example 2] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 881.29

[Synthesis Example 627] Synthesis of Mat 627

The procedure of Synthesis Example 612 was repeated except that [Preparation Example 2] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 881.29

[Synthesis Example 628] Synthesis of Mat 628

The same procedure as in [Synthesis Example 613] was repeated except that [Preparation Example 2] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 791.28

[Synthesis Example 629] Synthesis of Mat 629

The procedure of Synthesis Example 614 was repeated except that [Preparation Example 2] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 853.33

[Synthesis Example 630] Synthesis of Mat 630

The same procedure as in [Synthesis Example 615] was repeated except that [Preparation Example 2] was used as a reactant, to obtain the desired compound (13.7 g; HRMS [M] < + >: 867.31

[Synthesis Example 631] Synthesis of Mat 631

The procedure of Synthesis Example 601 was repeated except that [Preparation Example 3] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 600.24

[Synthesis Example 632] Synthesis of Mat 632

The same procedure as in [Synthesis Example 602] was repeated except that [Preparation Example 3] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 676.27

[Synthesis Example 633] Synthesis of Mat 633

The same procedure as in [Synthesis Example 603] was repeated except that [Preparation Example 3] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 690.25

[Synthesis Example 634] Synthesis of Mat 634

The same procedure as in [Synthesis Example 604] was repeated except that [Preparation Example 3] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 601.23

[Synthesis Example 635] Synthesis of Mat 635

The procedure of Synthetic Example 605 was repeated except that [Preparation Example 3] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 677.27

[Synthesis Example 636] Synthesis of Mat 636

The same procedure as in [Synthesis Example 606] was conducted except that [Preparation Example 3] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 678.26

[Synthesis Example 637] Synthesis of Mat 637

The same procedure as in [Synthesis Example 607] was conducted except that [Preparation Example 3] was used as a reactant, to obtain 14.0 g of the desired compound; HRMS [M] < + >: 753.30

[Synthesis Example 638] Synthesis of Mat 638

The same procedure as in [Synthesis Example 608] was repeated except that [Preparation Example 3] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 727.28

[Synthesis Example 639] Synthesis of Mat 639

The procedure of Synthetic Example 609 was repeated except that [Preparation Example 3] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 691.25

[Synthesis Example 640] Synthesis of Mat 640

The procedure of Synthesis Example 610 was repeated except that [Preparation Example 3] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 767.28

[Synthesis Example 641] Synthesis of Mat 641

The procedure of Synthesis Example 611 was repeated except that [Preparation Example 3] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 781.26

[Synthesis Example 642] Synthesis of Mat 642

The same procedure as in [Synthesis Example 612] was repeated except that [Preparation Example 3] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 781.26

[Synthesis Example 643] Synthesis of Mat 643

The same procedure as in [Synthesis Example 613] was repeated except that [Preparation Example 3] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 691.25

[Synthesis Example 644] Synthesis of Mat 644

The procedure of Synthesis Example 614 was repeated except that [Preparation Example 3] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 753.30

[Synthesis Example 645] Synthesis of Mat 645

The same procedure as in [Synthesis Example 615] was repeated except that [Preparation Example 3] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 767.28

[Synthesis Example 646] Synthesis of Mat 646

The procedure of Synthesis Example 601 was repeated except that [Preparation Example 4] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 650.26

[Synthesis Example 647] Synthesis of Mat 647

The procedure of Synthesis Example 602 was repeated except that [Preparation Example 4] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 726.29

[Synthesis Example 648] Synthesis of Mat 648

The same procedure as in [Synthesis Example 603] was repeated except that [Preparation Example 4] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 740.27

[Synthesis Example 649] Synthesis of Mat 649

The same procedure as in [Synthesis Example 604] was repeated except that [Preparation Example 4] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 651.25

[Synthesis Example 650] Synthesis of Mat 650

The procedure of Synthesis Example 605 was repeated except that [Preparation Example 4] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 727.28

[Synthesis Example 651] Synthesis of Mat 651

The procedure of Synthetic Example 606 was repeated except that [Preparation Example 4] was used as a reactant, to obtain 14.2 g of the target compound; HRMS [M] < + >: 728.28

[Synthesis Example 652] Synthesis of Mat 652

The same procedure as in [Synthesis Example 607] was repeated except that [Preparation Example 4] was used as a reactant, to obtain 14.0 g of the title compound; HRMS [M] < + >: 803.31

[Synthesis Example 653] Synthesis of Mat 653

The procedure of Synthesis Example 608 was repeated except that [Preparation Example 4] was used as a reactant, to thereby yield 14.6 g of the desired compound; HRMS [M] < + >: 777.30

[Synthesis Example 654] Synthesis of Mat 654

The procedure of Synthetic Example 609 was repeated except that [Preparation Example 4] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 741.26

[Synthesis Example 655] Synthesis of Mat 655

The procedure of Synthesis Example 610 was repeated except that [Preparation Example 4] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 817.29

[Synthesis Example 656] Synthesis of Mat 656

The procedure of Synthesis Example 611 was repeated except that [Preparation Example 4] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 831.27

[Synthesis Example 657] Synthesis of Mat 657

The same procedure as in [Synthesis Example 612] was repeated except that [Preparation Example 4] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 831.27

[Synthesis Example 658] Synthesis of Mat 658

The same procedure as in [Synthesis Example 613] was conducted except that [Preparation Example 4] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 740.27

[Synthesis Example 659] Synthesis of Mat 659

The same procedure as in [Synthesis Example 614] was conducted except that [Preparation Example 4] was used as a reactant, to obtain 14.6 g of the desired compound; HRMS [M] < + >: 803.31

[Synthesis Example 660] Synthesis of Mat 660

The same procedure as in [Synthesis Example 615] was repeated except that [Preparation Example 4] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 817.29

[Synthesis Example 661] Synthesis of Mat 661

The procedure of Synthesis Example 601 was repeated except that [Preparation Example 5] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 700.27

[Synthesis Example 662] Synthesis of Mat 662

The same procedure as in [Synthesis Example 602] was repeated except that [Preparation Example 5] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 776.30

[Synthesis Example 663] Synthesis of Mat 663

The procedure of Synthetic Example 603 was repeated except that [Preparation Example 5] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 790.28

[Synthesis Example 664] Synthesis of Mat 664

The same procedure as in [Synthesis Example 604] was repeated except that [Preparation Example 5] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 701.27

[Synthesis Example 665] Synthesis of Mat 665

The procedure of Synthetic Example 605 was repeated except that [Preparation Example 5] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 777.30

[Synthesis Example 666] Synthesis of Mat 666

The procedure of Synthesis Example 606 was repeated except that [Preparation Example 5] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 778.29

[Synthesis Example 667] Synthesis of Mat 667

The procedure of Synthesis Example 607 was repeated except that [Preparation Example 5] was used as a reactant, to obtain 14.0 g of the target compound; HRMS [M] < + >: 853.33

[Synthesis Example 668] Synthesis of Mat 668

The same procedure as in [Synthesis Example 608] was repeated except that [Preparation Example 5] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 827.31

[Synthesis Example 669] Synthesis of Mat 669

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 5] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 791.28

[Synthesis Example 670] Synthesis of Mat 670

The procedure of Synthesis Example 610 was repeated except that [Preparation Example 5] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 867.31

[Synthesis Example 671] Synthesis of Mat 671

The same procedure as in [Synthesis Example 611] was conducted except that [Preparation Example 5] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 881.29

[Synthesis Example 672] Synthesis of Mat 672

The procedure of Synthesis Example 612 was repeated except that [Preparation Example 5] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 881.29

[Synthesis Example 673] Synthesis of Mat 673

The same procedure as in [Synthesis Example 613] was repeated except that [Preparation Example 5] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 791.28

[Synthesis Example 674] Synthesis of Mat 674

The same procedure as in [Synthesis Example 614] was conducted except that [Preparation Example 5] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 853.33

[Synthesis Example 675] Synthesis of Mat 675

The same procedure as in [Synthesis Example 615] was repeated except that [Preparation Example 5] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 867.31

[Synthesis Example 676] Synthesis of Mat 676

The procedure of Synthesis Example 601 was repeated except that [Preparation Example 6] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 674.26

[Synthesis Example 677] Synthesis of Mat 677

The same procedure as in [Synthesis Example 602] was repeated except that [Preparation Example 6] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 750.29

[Synthesis Example 678] Synthesis of Mat 678

The same procedure as in [Synthesis Example 603] was repeated except that [Preparation Example 6] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 764.27

[Synthesis Example 679] Synthesis of Mat 679

The same procedure as in [Synthesis Example 604] was repeated except that [Preparation Example 6] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 675.25

[Synthesis Example 680] Synthesis of Mat 680

The same procedure as in [Synthesis Example 605] was repeated except that [Preparation Example 6] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 751.28

[Synthesis Example 681] Synthesis of Mat 681

The same procedure as in [Synthesis Example 606] was repeated except that [Preparation Example 6] was used as a reactant, to obtain 14.2 g of the target compound; HRMS [M] < + >: 752.28

[Synthesis Example 682] Synthesis of Mat 682

The procedure of Synthesis Example 607 was repeated except that [Preparation Example 6] was used as a reactant, to obtain 14.0 g of the title compound; HRMS [M] < + >: 827.31

[Synthesis Example 683] Synthesis of Mat 683

The same procedure as in [Synthesis Example 608] was repeated except that [Preparation Example 6] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 801.30

[Synthesis Example 684] Synthesis of Mat 684

The same procedure as in [Synthesis Example 609] was repeated except that [Preparation Example 6] was used as a reactant, to obtain the title compound (15.1 g); HRMS [M] < + >: 765.26

[Synthesis Example 685] Synthesis of Mat 685

The procedure of Synthesis Example 610 was repeated except that [Preparation Example 6] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 841.29

[Synthesis Example 686] Synthesis of Mat 686

The same procedure as in [Synthesis Example 611] was repeated except that [Preparation Example 6] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 855.27

[Synthesis Example 687] Synthesis of Mat 687

The procedure of Synthesis Example 612 was repeated except that [Preparation Example 6] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 765.26

[Synthesis Example 688] Synthesis of Mat 688

The procedure of Synthesis Example 613 was repeated except that [Preparation Example 6] was used as a reactant, to thereby yield 14.4 g of the desired compound; HRMS [M] < + >: 791.28

[Synthesis Example 689] Synthesis of Mat 689

The procedure of Synthesis Example 614 was repeated except that [Preparation Example 6] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 827.31

[Synthesis Example 690] Synthesis of Mat 690

The same procedure as in [Synthesis Example 615] was repeated except that [Preparation Example 6] was used as a reactant, to obtain the desired compound (13.7 g; HRMS [M] < + >: 841.29

[Synthesis Example 691] Synthesis of Mat 691

The same procedure as in [Synthesis Example 603] was repeated except that [Preparation Example 7] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 816.30

[Synthesis Example 692] Synthesis of Mat 692

The same procedure as in [Synthesis Example 604] was repeated except that [Preparation Example 7] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 727.28

[Synthesis Example 693] Synthesis of Mat 693

The procedure of Synthetic Example 605 was repeated except that [Preparation Example 7] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 803.31

[Synthesis Example 694] Synthesis of Mat 694

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 7] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 817.29

[Synthesis Example 695] Synthesis of Mat 695

The same procedure as in [Synthesis Example 611] was repeated except that [Preparation Example 7] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 907.30

[Synthesis Example 696] Synthesis of Mat 696

The procedure of Synthesis Example 613 was repeated except that [Preparation Example 7] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 816.30

[Synthesis Example 697] Synthesis of Mat 697

The procedure of Synthesis Example 615 was repeated except that [Preparation Example 7] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 893.32

[Synthesis Example 698] Synthesis of Mat 698

The same procedure as in [Synthesis Example 603] was repeated except that [Preparation Example 8] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 866.31

[Synthesis Example 699] Synthesis of Mat 699

The procedure of Synthesis Example 604 was repeated except that [Preparation Example 8] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 777.30

[Synthesis Example 700] Synthesis of Mat 700

The procedure of Synthetic Example 605 was repeated except that [Preparation Example 8] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 853.33

[Synthesis Example 701] Synthesis of Mat 701

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 8] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 867.31

[Synthesis Example 702] Synthesis of Mat 702

The procedure of Synthesis Example 611 was repeated except that [Preparation Example 8] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 957.32

[Synthesis Example 703] Synthesis of Mat 703

The procedure of Synthesis Example 613 was repeated except that [Preparation Example 8] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 867.31

[Synthesis Example 704] Synthesis of Mat 704

The procedure of Synthesis Example 615 was repeated except that [Preparation Example 8] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 943.34

[Synthesis Example 705] Synthesis of Mat 705

The procedure of Synthesis Example 603 was repeated except that [Preparation Example 9] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 766.28

[Synthesis Example 706] Synthesis of Mat 706

The same procedure as in [Synthesis Example 604] was repeated except that [Preparation Example 9] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 677.27

[Synthesis Example 707] Synthesis of Mat 707

The procedure of Synthesis Example 605 was repeated except that [Preparation Example 9] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 753.30

[Synthesis Example 708] Synthesis of Mat 708

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 9] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 767.28

[Synthesis Example 709] Synthesis of Mat 709

The same procedure as in [Synthesis Example 611] was conducted except that [Preparation Example 9] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 857.29

[Synthesis Example 710] Synthesis of Mat 710

The same procedure as in [Synthesis Example 613] was repeated except that [Preparation Example 9] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 767.28

[Synthesis Example 711] Synthesis of Mat 711

The procedure of Synthesis Example 615 was repeated except that [Preparation Example 9] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 843.31

[Synthesis Example 712] Synthesis of Mat 712

The procedure of Synthesis Example 603 was repeated except that [Preparation Example 10] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 816.30

[Synthesis Example 713] Synthesis of Mat 713

The same procedure as in [Synthesis Example 604] was repeated except that [Preparation Example 10] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 727.28

[Synthesis Example 714] Synthesis of Mat 714

The same procedure as in [Synthesis Example 605] was conducted except that [Preparation Example 10] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 803.31

[Synthesis Example 715] Synthesis of Mat 715

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 10] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 817.29

[Synthesis Example 716] Synthesis of Mat 716

The procedure of Synthesis Example 611 was repeated except that [Preparation Example 10] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 907.30

[Synthesis Example 717] Synthesis of Mat 717

The procedure of Synthesis Example 613 was repeated except that [Preparation Example 10] was used as a reactant, to thereby yield 14.4 g of the title compound; HRMS [M] < + >: 803.31

[Synthesis Example 718] Synthesis of Mat 718

The procedure of Synthesis Example 615 was repeated except that [Preparation Example 10] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 893.32

[Synthesis Example 719] Synthesis of Mat 719

The procedure of Synthesis Example 603 was repeated except that [Preparation Example 11] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 840.30

[Synthesis Example 720] Synthesis of Mat 720

The procedure of Synthesis Example 604 was repeated except that [Preparation Example 11] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 751.28

[Synthesis Example 721] Synthesis of Mat 721

The procedure of Synthesis Example 605 was repeated except that [Preparation Example 11] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 827.31

[Synthesis Example 722] Synthesis of Mat 722

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 11] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 841.29

[Synthesis Example 723] Synthesis of Mat 723

The procedure of Synthesis Example 611 was repeated except that [Preparation Example 11] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 931.30

[Synthesis Example 724] Synthesis of Mat 724

The procedure of Synthesis Example 613 was repeated except that [Preparation Example 11] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 841.29

[Synthesis Example 725] Synthesis of Mat 725

The procedure of Synthesis Example 615 was repeated except that [Preparation Example 11] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 917.32

[Synthesis Example 726] Synthesis of Mat 726

The procedure of Synthesis Example 603 was repeated except that [Preparation Example 12] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 840.30

[Synthesis Example 727] Synthesis of Mat 727

The procedure of Synthesis Example 604 was repeated except that [Preparation Example 12] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 751.28

[Synthesis Example 728] Synthesis of Mat 728

The procedure of Synthetic Example 605 was repeated except that [Preparation Example 12] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 827.31

[Synthesis Example 729] Synthesis of Mat 729

The same procedure as in [Synthesis Example 609] was conducted except that [Preparation Example 12] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 841.29

[Synthesis Example 730] Synthesis of Mat 730

The same procedure as in [Synthesis Example 611] was repeated except that [Preparation Example 12] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 931.30

[Synthesis Example 731] Synthesis of Mat 731

The procedure of Synthesis Example 613 was repeated except that [Preparation Example 12] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 841.29

[Synthesis Example 732] Synthesis of Mat 732

The procedure of Synthesis Example 615 was repeated except that [Preparation Example 12] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 917.32

[Synthesis Example 733] Synthesis of Mat 733

The same procedure as in [Synthesis Example 603] was repeated except that [Preparation Example 13] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 816.30

[Synthesis Example 734] Synthesis of Mat 734

The same procedure as in [Synthesis Example 604] was repeated except that [Preparation Example 13] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 727.28

[Synthesis Example 735] Synthesis of Mat 735

The same procedure as in [Synthesis Example 605] was conducted except that [Preparation Example 13] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 803.31

[Synthesis Example 736] Synthesis of Mat 736

The procedure of Synthetic Example 609 was repeated except that [Preparation Example 13] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 817.29

[Synthesis Example 737] Synthesis of Mat 737

The same procedure as in [Synthesis Example 611] was conducted except that [Preparation Example 13] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 907.30

[Synthesis Example 738] Synthesis of Mat 738

The procedure of Synthesis Example 613 was repeated except that [Preparation Example 13] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 816.30

[Synthesis Example 739] Synthesis of Mat 739

The procedure of Synthesis Example 615 was repeated except that [Preparation Example 13] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 893.32

[Synthesis Example 740] Synthesis of Mat 740

The same procedure as in [Synthesis Example 603] was repeated except that [Preparation Example 14] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 866.31

[Synthesis Example 741] Synthesis of Mat 741

The procedure of Synthesis Example 604 was repeated except that [Preparation Example 14] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 777.30

[Synthesis Example 742] Synthesis of Mat 742

The same procedure as in [Synthesis Example 605] was repeated except that [Preparation Example 14] was used as a reactant, to obtain 14.2 g of the desired compound; HRMS [M] < + >: 853.33

[Synthesis Example 743] Synthesis of Mat 743

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 14] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 867.31

[Synthesis Example 744] Synthesis of Mat 744

The same procedure as in [Synthesis Example 611] was repeated except that [Preparation Example 14] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 957.32

[Synthesis Example 745] Synthesis of Mat 745

The procedure of Synthesis Example 613 was repeated except that [Preparation Example 14] was used as a reactant, to thereby yield 14.4 g of the title compound; HRMS [M] < + >: 867.31

[Synthesis Example 746] Synthesis of Mat 746

The same procedure as in [Synthesis Example 615] was repeated except that [Preparation Example 14] was used as a reactant, to obtain the desired compound (13.7 g; HRMS [M] < + >: 943.34

[Synthesis Example 747] Synthesis of Mat 747

The procedure of Synthesis Example 603 was repeated except that [Preparation Example 15] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 766.28

[Synthesis Example 748] Synthesis of Mat 748

The procedure of Synthesis Example 604 was repeated except that [Preparation Example 15] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 677.27

[Synthesis Example 749] Synthesis of Mat 749

The procedure of Synthetic Example 605 was repeated except that [Preparation Example 15] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 753.30

[Synthesis Example 750] Synthesis of Mat 750

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 15] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 767.28

[Synthesis Example 751] Synthesis of Mat 751

The procedure of Synthesis Example 611 was repeated except that [Preparation Example 15] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 857.29

[Synthesis Example 752] Synthesis of Mat 752

The procedure of Synthesis Example 613 was repeated except that [Preparation Example 15] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 767.28

[Synthesis Example 753] Synthesis of Mat 753

The same procedure as in [Synthesis Example 615] was repeated except that [Preparation Example 15] was used as a reactant, to obtain the desired compound (13.7 g; HRMS [M] < + >: 843.31

[Synthesis Example 754] Synthesis of Mat 754

The procedure of Synthesis Example 603 was repeated except that [Preparation Example 16] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 816.30

[Synthesis Example 755] Synthesis of Mat 755

The procedure of Synthesis Example 604 was repeated except that [Preparation Example 16] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 727.28

[Synthesis Example 756] Synthesis of Mat 756

The procedure of Synthesis Example 605 was repeated except that [Preparation Example 16] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 803.31

[Synthesis Example 757] Synthesis of Mat 757

The procedure of Synthetic Example 609 was repeated except that [Preparation Example 16] was used as a reactant, to obtain 15.1 g of the desired compound; HRMS [M] < + >: 817.29

[Synthesis Example 758] Synthesis of Mat 758

The same procedure as in [Synthesis Example 611] was repeated except that [Preparation Example 16] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 907.30

[Synthesis Example 759] Synthesis of Mat 759

The procedure of Synthesis Example 613 was repeated except that [Preparation Example 16] was used as a reactant, to obtain 14.4 g of the desired compound; HRMS [M] < + >: 803.31

[Synthesis Example 760] Synthesis of Mat 760

The same procedure as in [Synthesis Example 615] was repeated except that [Preparation Example 16] was used as a reactant, to obtain the desired compound (13.7 g; HRMS [M] < + >: 893.32

[Synthesis Example 761] Synthesis of Mat 761

The procedure of Synthesis Example 603 was repeated except that [Preparation Example 17] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 840.30

[Synthesis Example 762] Synthesis of Mat 762

The same procedure as in [Synthesis Example 604] was repeated except that [Preparation Example 17] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 751.28

[Synthesis Example 763] Synthesis of Mat 763

The procedure of Synthesis Example 605 was repeated except that [Preparation Example 17] was used as a reactant, to obtain 14.2 g of the target compound; HRMS [M] < + >: 827.31

[Synthesis Example 764] Synthesis of Mat 764

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 17] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 841.29

[Synthesis Example 765] Synthesis of Mat 765

The same procedure as in [Synthesis Example 611] was conducted except that [Preparation Example 17] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 931.30

[Synthesis Example 766] Synthesis of Mat 766

The procedure of Synthesis Example 613 was repeated except that [Preparation Example 17] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 841.29

[Synthesis Example 767] Synthesis of Mat 767

The procedure of Synthesis Example 615 was repeated except that [Preparation Example 17] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 917.32

[Synthesis Example 768] Synthesis of Mat 768

The procedure of Synthesis Example 603 was repeated except that [Preparation Example 18] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 840.30

[Synthesis Example 769] Synthesis of Mat 769

The procedure of Synthesis Example 604 was repeated except that [Preparation Example 18] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 751.28

[Synthesis Example 770] Synthesis of Mat 770

The procedure of Synthesis Example 605 was repeated except that [Preparation Example 18] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 827.31

[Synthesis Example 771] Synthesis of Mat 771

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 18] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 841.29

[Synthesis Example 772] Synthesis of Mat 772

The procedure of Synthesis Example 611 was repeated except that [Preparation Example 18] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 931.30

[Synthesis Example 773] Synthesis of Mat 773

The procedure of Synthesis Example 613 was repeated except that [Preparation Example 18] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 841.29

[Synthesis Example 774] Synthesis of Mat 774

The procedure of Synthesis Example 615 was repeated except that [Preparation Example 18] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 917.32

[Synthesis Example 775] Synthesis of Mat 775

The procedure of Synthesis Example 603 was repeated except that [Preparation Example 19] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 892.33

[Synthesis Example 776] Synthesis of Mat 776

The procedure of Synthesis Example 604 was repeated except that [Preparation Example 19] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 803.31

[Synthesis Example 777] Synthesis of Mat 777

The procedure of Synthetic Example 605 was repeated except that [Preparation Example 19] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 879.34

[Synthesis Example 778] Synthesis of Mat 778

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 19] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 893.32

[Synthesis Example 779] Synthesis of Mat 779

The procedure of Synthesis Example 611 was repeated except that [Preparation Example 19] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 983.33

[Synthesis Example 780] Synthesis of Mat 780

The procedure of Synthesis Example 613 was repeated except that [Preparation Example 19] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 892.33

[Synthesis Example 781] Synthesis of Mat 781

The procedure of Synthesis Example 615 was repeated except that [Preparation Example 19] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 969.35

[Synthesis Example 782] Synthesis of Mat 782

The same procedure as in [Synthesis Example 603] was repeated except that [Preparation Example 20] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 942.33

[Synthesis Example 783] Synthesis of Mat 783

The procedure of Synthesis Example 604 was repeated except that [Preparation Example 20] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 853.33

[Synthesis Example 784] Synthesis of Mat 784

The procedure of Synthesis Example 605 was repeated except that [Preparation Example 20] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 929.36

[Synthesis Example 785] Synthesis of Mat 785

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 20] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 943.34

[Synthesis Example 786] Synthesis of Mat 786

The same procedure as in [Synthesis Example 611] was repeated except that [Preparation Example 20] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 1033.35

[Synthesis Example 787] Synthesis of Mat 787

The procedure of Synthesis Example 613 was repeated except that [Preparation Example 20] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 943.34

[Synthesis Example 788] Synthesis of Mat 788

The procedure of Synthesis Example 615 was repeated except that [Preparation Example 20] was used as a reactant, to obtain 13.7 g of the desired compound; HRMS [M] < + >: 1019.37

[Synthesis Example 789] Synthesis of Mat 789

The procedure of Synthetic Example 603 was repeated except that [Preparation Example 21] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 842.31

[Synthesis Example 790] Synthesis of Mat 790

The procedure of Synthesis Example 604 was repeated except that [Preparation Example 21] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 753.30

[Synthesis Example 791] Synthesis of Mat 791

The procedure of Synthesis Example 605 was repeated except that [Preparation Example 21] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 829.33

[Synthesis Example 792] Synthesis of Mat 792

The same procedure as in [Synthesis Example 609] was conducted except that [Preparation Example 21] was used as a reactant, to obtain the title compound (15.1 g); HRMS [M] < + >: 843.31

[Synthesis Example 793] Synthesis of Mat 793

The same procedure as in [Synthesis Example 611] was conducted except that [Preparation Example 21] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 933.32

[Synthesis Example 794] Synthesis of Mat 794

The procedure of Synthesis Example 613 was repeated except that [Preparation Example 21] was used as a reactant, to obtain 14.4 g of the desired compound; HRMS [M] < + >: 843.31

[Synthesis Example 795] Synthesis of Mat 795

The procedure of Synthesis Example 615 was repeated except that [Preparation Example 21] was used as a reactant, to obtain 13.7 g of the desired compound; HRMS [M] < + >: 919.34

[Synthesis Example 796] Synthesis of Mat 796

The procedure of Synthesis Example 603 was repeated except that [Preparation Example 22] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 892.33

[Synthesis Example 797] Synthesis of Mat 797

The procedure of Synthesis Example 604 was repeated except that [Preparation Example 22] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 803.31

[Synthesis Example 798] Synthesis of Mat 798

The procedure of Synthesis Example 605 was repeated except that [Preparation Example 22] was used as a reactant, to obtain 14.2 g of the desired compound; HRMS [M] < + >: 879.34

[Synthesis Example 799] Synthesis of Mat 799

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 22] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 893.32

[Synthesis Example 800] Synthesis of Mat 800

The procedure of Synthesis Example 611 was repeated except that [Preparation Example 22] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 893.33

[Synthesis Example 801] Synthesis of Mat 801

The procedure of Synthesis Example 613 was repeated except that [Preparation Example 22] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 879.34

[Synthesis Example 802] Synthesis of Mat 802

The procedure of Synthesis Example 615 was repeated except that [Preparation Example 22] was used as a reactant, to obtain 13.7 g of the desired compound; HRMS [M] < + >: 969.35

[Synthesis Example 803] Synthesis of Mat 803

The procedure of Synthesis Example 603 was repeated except that [Preparation Example 22] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 916.33

[Synthesis Example 804] Synthesis of Mat 804

The same procedure as in [Synthesis Example 604] was repeated except that [Preparation Example 23] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 827.31

[Synthesis Example 805] Synthesis of Mat 805

The procedure of Synthetic Example 605 was repeated except that [Preparation Example 23] was used as a reactant, to obtain 14.2 g of the target compound; HRMS [M] < + >: 903.34

[Synthesis Example 806] Synthesis of Mat 806

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 23] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 917.32

[Synthesis Example 807] Synthesis of Mat 807

The same procedure as in [Synthesis Example 611] was repeated except that [Preparation Example 23] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 1007.34

[Synthesis Example 808] Synthesis of Mat 808

The procedure of Synthesis Example 613 was repeated except that [Preparation Example 23] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 917.32

[Synthesis Example 809] Synthesis of Mat 809

The procedure of Synthesis Example 615 was repeated except that [Preparation Example 23] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 993.35

[Synthesis Example 810] Synthesis of Mat 810

The same procedure as in [Synthesis Example 603] was repeated except that [Preparation Example 24] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 916.33

[Synthesis Example 811] Synthesis of Mat 811

The same procedure as in [Synthesis Example 604] was repeated except that [Preparation Example 24] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 827.31

[Synthesis Example 812] Synthesis of Mat 812

The procedure of Synthesis Example 605 was repeated except that [Preparation Example 24] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 903.34

[Synthesis Example 813] Synthesis of Mat 813

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 24] was used as a reactant, to obtain 15.1 g of the desired compound; HRMS [M] < + >: 917.32

[Synthesis Example 814] Synthesis of Mat 814

The procedure of Synthesis Example 611 was repeated except that [Preparation Example 24] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 1007.33

[Synthesis Example 815] Synthesis of Mat 815

The procedure of Synthesis Example 613 was repeated except that [Preparation Example 24] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 917.32

[Synthesis Example 816] Synthesis of Mat 816

The procedure of Synthesis Example 615 was repeated except that [Preparation Example 24] was used as a reactant, to obtain 13.7 g of the desired compound; HRMS [M] < + >: 993.35

[Synthesis Example 817] Synthesis of Mat 817

The procedure of Synthesis Example 603 was repeated except that [Preparation Example 25] was used as a reactant, to obtain 14.7 g of the desired compound; HRMS [M] < + >: 906.31

[Synthesis Example 818] Synthesis of Mat 818

The same procedure as in [Synthesis Example 604] was repeated except that [Preparation Example 25] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 817.29

[Synthesis Example 819] Synthesis of Mat 819

The procedure of Synthesis Example 605 was repeated except that [Preparation Example 25] was used as a reactant, to obtain 14.2 g of the desired compound; HRMS [M] < + >: 893.32

[Synthesis Example 820] Synthesis of Mat 820

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 25] was used as a reactant, to obtain the title compound (15.1 g); HRMS [M] < + >: 907.30

[Synthesis Example 821] Synthesis of Mat 821

The procedure of Synthesis Example 611 was repeated except that [Preparation Example 25] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 997.31

[Synthesis Example 822] Synthesis of Mat 822

The procedure of Synthesis Example 613 was repeated except that [Preparation Example 25] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 907.30

[Synthesis Example 823] Synthesis of Mat 823

The procedure of Synthesis Example 615 was repeated except that [Preparation Example 25] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 983.33

[Synthesis Example 824] Synthesis of Mat 824

The procedure of Synthesis Example 603 was repeated except that [Preparation Example 26] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 956.32

[Synthesis Example 825] Synthesis of Mat 825

The procedure of Synthesis Example 604 was repeated except that [Preparation Example 26] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 867.31

[Synthesis Example 826] Synthesis of Mat 826

The same procedure as in [Synthesis Example 605] was repeated except that [Preparation Example 26] was used as a reactant, to obtain 14.2 g of the target compound; HRMS [M] < + >: 943.34

[Synthesis Example 827] Synthesis of Mat 827

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 26] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 957.32

[Synthesis Example 828] Synthesis of Mat 828

The procedure of Synthesis Example 611 was repeated except that [Preparation Example 26] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 1047.33

[Synthesis Example 829] Synthesis of Mat 829

The procedure of Synthesis Example 613 was repeated except that [Preparation Example 26] was used as a reactant, to obtain 14.4 g of the desired compound; HRMS [M] < + >: 957.32

[Synthesis Example 830] Synthesis of Mat 830

The procedure of Synthesis Example 615 was repeated except that [Preparation Example 26] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 1123.36

[Synthesis Example 831] Synthesis of Mat 831

The procedure of Synthesis Example 603 was repeated except that [Preparation Example 27] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 856.29

[Synthesis Example 832] Synthesis of Mat 832

The procedure of Synthesis Example 604 was repeated except that [Preparation Example 27] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 767.28

[Synthesis Example 833] Synthesis of Mat 833

The same procedure as in [Synthesis Example 605] was repeated except that [Preparation Example 27] was used as a reactant, to obtain 14.2 g of the desired compound; HRMS [M] < + >: 943.31

[Synthesis Example 834] Synthesis of Mat 834

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 27] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 857.29

[Synthesis Example 835] Synthesis of Mat 835

The procedure of Synthesis Example 611 was repeated except that [Preparation Example 27] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 947.30

[Synthesis Example 836] Synthesis of Mat 836

The same procedure as in [Synthesis Example 613] was repeated except that [Preparation Example 27] was used as a reactant, to obtain 14.4 g of the desired compound; HRMS [M] < + >: 857.29

[Synthesis Example 837] Synthesis of Mat 837

The procedure of Synthesis Example 615 was repeated except that [Preparation Example 27] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 933.32

[Synthesis Example 838] Synthesis of Mat 838

The procedure of Synthesis Example 603 was repeated except that [Preparation Example 28] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 906.31

[Synthesis Example 839] Synthesis of Mat 839

The same procedure as in [Synthesis Example 604] was repeated except that [Preparation Example 28] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 817.29

[Synthesis Example 840] Synthesis of Mat 840

The procedure of Synthesis Example 605 was repeated except that [Preparation Example 28] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 893.32

[Synthesis Example 841] Synthesis of Mat 841

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 28] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 907.30

[Synthesis Example 842] Synthesis of Mat 842

The procedure of Synthesis Example 611 was repeated except that [Preparation Example 28] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 997.31

[Synthesis Example 843] Synthesis of Mat 843

The same procedure as in [Synthesis Example 613] was repeated except that [Preparation Example 28] was used as a reactant, to obtain 14.4 g of the desired compound; HRMS [M] < + >: 907.30

[Synthesis Example 844] Synthesis of Mat 844

The procedure of Synthesis Example 615 was repeated except that [Preparation Example 28] was used as a reactant, to obtain 13.7 g of the desired compound; HRMS [M] < + >: 983.33

[Synthesis Example 845] Synthesis of Mat 845

The same procedure as in [Synthesis Example 603] was repeated except that [Preparation Example 29] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 930.31

[Synthesis Example 846] Synthesis of Mat 846

The same procedure as in [Synthesis Example 604] was repeated except that [Preparation Example 29] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 841.29

[Synthesis Example 847] Synthesis of Mat 847

The procedure of Synthesis Example 605 was repeated except that [Preparation Example 29] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 917.32

[Synthesis Example 848] Synthesis of Mat 848

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 29] was used as a reactant, to obtain 15.1 g of the desired compound; HRMS [M] < + >: 931.30

[Synthesis Example 849] Synthesis of Mat 849

The procedure of Synthesis Example 611 was repeated except that [Preparation Example 29] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 1021.31

[Synthesis Example 850] Synthesis of Mat 850

The procedure of Synthesis Example 613 was repeated except that [Preparation Example 29] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 931.30

[Synthesis Example 851] Synthesis of Mat 851

The procedure of Synthesis Example 615 was repeated except that [Preparation Example 29] was used as a reactant, to obtain 13.7 g of the desired compound; HRMS [M] < + >: 1007.33

[Synthesis Example 852] Synthesis of Mat 852

The same procedure as in [Synthesis Example 603] was repeated except that [Preparation Example 30] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 930.31

[Synthesis Example 853] Synthesis of Mat 853

The procedure of Synthetic Example 604 was repeated except that [Preparation Example 30] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 841.29

[Synthesis Example 854] Synthesis of Mat 854

The same procedure as in [Synthesis Example 605] was repeated except that [Preparation Example 30] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 917.32

[Synthesis Example 855] Synthesis of Mat 855

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 30] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 931.30

[Synthesis Example 856] Synthesis of Mat 856

The procedure of Synthesis Example 611 was repeated except that [Preparation Example 30] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 1021.31

[Synthesis Example 857] Synthesis of Mat 857

The procedure of Synthesis Example 613 was repeated except that [Preparation Example 30] was used as a reactant, to obtain 14.4 g of the desired compound; HRMS [M] < + >: 931.30

[Synthesis Example 858] Synthesis of Mat 858

The procedure of Synthesis Example 615 was repeated except that [Preparation Example 30] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 1007.33

[Synthesis Example 859] Synthesis of Mat 859

The procedure of Synthesis Example 601 was repeated except that [Preparation Example 31] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 700.27

[Synthesis Example 860] Synthesis of Mat 860

The procedure of Synthesis Example 602 was repeated except that [Preparation Example 31] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 776.30

[Synthesis Example 861] Synthesis of Mat 861

The procedure of Synthesis Example 603 was repeated except that [Preparation Example 31] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 790.28

[Synthesis Example 862] Synthesis of Mat 862

The same procedure as in [Synthesis Example 604] was repeated except that [Preparation Example 31] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 701.27

[Synthesis Example 863] Synthesis of Mat 863

The procedure of Synthesis Example 605 was repeated except that [Preparation Example 31] was used as a reactant, to obtain 14.2 g of the target compound; HRMS [M] < + >: 777.30

[Synthesis Example 864] Synthesis of Mat 864

The procedure of Synthesis Example 606 was repeated except that [Preparation Example 31] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 778.29

[Synthesis Example 865] Synthesis of Mat 865

The procedure of Synthesis Example 607 was repeated except that [Preparation Example 31] was used as a reactant, to obtain 14.0 g of the title compound; HRMS [M] < + >: 853.33

[Synthesis Example 866] Synthesis of Mat 866

The same procedure as in [Synthesis Example 608] was repeated except that [Preparation Example 31] was used as a reactant, to obtain 14.6 g of the desired compound; HRMS [M] < + >: 827.31

[Synthesis Example 867] Synthesis of Mat 867

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 31] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 791.28

[Synthesis Example 868] Synthesis of Mat 868

The procedure of Synthesis Example 610 was repeated except that [Preparation Example 31] was used as a reactant, to obtain 15.1 g of the desired compound; HRMS [M] < + >: 867.31

[Synthesis Example 869] Synthesis of Mat 869

The same procedure as in [Synthesis Example 611] was repeated except that [Preparation Example 31] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 881.29

[Synthesis Example 870] Synthesis of Mat 870

The procedure of Synthesis Example 612 was repeated except that [Preparation Example 31] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 881.29

[Synthesis Example 871] Synthesis of Mat 871

The procedure of Synthesis Example 613 was repeated except that [Preparation Example 31] was used as a reactant, to obtain 14.4 g of the desired compound; HRMS [M] < + >: 790.28

[Synthesis Example 872] Synthesis of Mat 872

The procedure of Synthesis Example 614 was repeated except that [Preparation Example 31] was used as a reactant, to obtain 14.6 g of the desired compound; HRMS [M] < + >: 853.33

[Synthesis Example 873] Synthesis of Mat 873

The procedure of Synthesis Example 615 was repeated except that [Preparation Example 31] was used as a reactant, to obtain 13.7 g of the desired compound; HRMS [M] < + >: 867.31

[Synthesis Example 874] Synthesis of Mat 874

The procedure of Synthesis Example 601 was repeated except that [Preparation Example 32] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 750.29

[Synthesis Example 875] Synthesis of Mat 875

The procedure of Synthesis Example 602 was repeated except that [Preparation Example 32] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 826.32

[Synthesis Example 876] Synthesis of Mat 876

The procedure of Synthesis Example 603 was repeated except that [Preparation Example 32] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 840.30

[Synthesis Example 877] Synthesis of Mat 877

The same procedure as in [Synthesis Example 604] was repeated except that [Preparation Example 32] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 751.28

[Synthesis Example 878] Synthesis of Mat 878

The procedure of Synthetic Example 605 was repeated except that [Preparation Example 32] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 827.31

[Synthesis Example 879] Synthesis of Mat 879

The same procedure as in [Synthesis Example 606] was repeated except that [Preparation Example 32] was used as a reactant, to obtain 14.2 g of the target compound; HRMS [M] < + >: 828.31

[Synthesis Example 880] Synthesis of Mat 880

The same procedure as in [Synthesis Example 607] was conducted except that [Preparation Example 32] was used as a reactant, to obtain 14.0 g of the target compound; HRMS [M] < + >: 903.34

[Synthesis Example 881] Synthesis of Mat 881

The same procedure as in [Synthesis Example 608] was repeated except that [Preparation Example 32] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 877.33

[Synthesis Example 882] Synthesis of Mat 882

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 32] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 841.29

[Synthesis Example 883] Synthesis of Mat 883

The procedure of Synthesis Example 610 was repeated except that [Preparation Example 32] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 917.32

[Synthesis Example 884] Synthesis of Mat 884

The procedure of Synthesis Example 611 was repeated except that [Preparation Example 32] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 931.30

[Synthesis Example 885] Synthesis of Mat 885

The procedure of Synthesis Example 612 was repeated except that [Preparation Example 32] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 931.30

[Synthesis Example 886] Synthesis of Mat 886

The same procedure as in [Synthesis Example 613] was conducted except that [Preparation Example 32] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 841.29

[Synthesis Example 887] Synthesis of Mat 887

The same procedure as in [Synthesis Example 614] was repeated except that [Preparation Example 32] was used as a reactant, to obtain 14.6 g of the target compound; HRMS [M] < + >: 903.34

[Synthesis Example 888] Synthesis of Mat 888

The procedure of Synthesis Example 615 was repeated except that [Preparation Example 32] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 917.32

[Synthesis Example 889] Synthesis of Mat 889

The procedure of Synthesis Example 601 was repeated except that [Preparation Example 33] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 650.26

[Synthesis Example 890] Synthesis of Mat 890

The procedure of Synthesis Example 602 was repeated except that [Preparation Example 33] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 726.29

[Synthesis Example 891] Synthesis of Mat 891

The same procedure as in [Synthesis Example 603] was repeated except that [Preparation Example 33] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 940.27

[Synthesis Example 892] Synthesis of Mat 892

The same procedure as in [Synthesis Example 604] was conducted except that [Preparation Example 33] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 651.25

[Synthesis Example 893] Synthesis of Mat 893

The same procedure as in [Synthesis Example 605] was repeated except that [Preparation Example 33] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 727.28

[Synthesis Example 894] Synthesis of Mat 894

The same procedure as in [Synthesis Example 606] was repeated except that [Preparation Example 33] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 728.28

[Synthesis Example 895] Synthesis of Mat 895

The same procedure as in [Synthesis Example 607] was repeated except that [Preparation Example 33] was used as a reactant, to obtain 14.0 g of the desired compound; HRMS [M] < + >: 803.31

[Synthesis Example 896] Synthesis of Mat 896

The same procedure as in [Synthesis Example 608] was repeated except that [Preparation Example 33] was used as a reactant, to obtain 14.6 g of the target compound; HRMS [M] < + >: 777.30

[Synthesis Example 897] Synthesis of Mat 897

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 33] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 741.26

[Synthesis Example 898] Synthesis of Mat 898

The procedure of Synthesis Example 610 was repeated except that [Preparation Example 33] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 817.29

[Synthesis Example 899] Synthesis of Mat 899

The procedure of Synthesis Example 611 was repeated except that [Preparation Example 33] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 831.27

[Synthesis Example 900] Synthesis of Mat 900

The procedure of Synthesis Example 612 was repeated except that [Preparation Example 33] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 831.27

[Synthesis Example 901] Synthesis of Mat 901

The procedure of Synthesis Example 613 was repeated except that [Preparation Example 33] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 741.26

[Synthesis Example 902] Synthesis of Mat 902

The procedure of Synthesis Example 614 was repeated except that [Preparation Example 33] was used as the reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 801.31

[Synthesis Example 903] Synthesis of Mat 903

The same procedure as in [Synthesis Example 615] was repeated except that [Preparation Example 33] was used as a reactant, to obtain the desired compound (13.7 g; HRMS [M] < + >: 817.29

[Synthesis Example 904] Synthesis of Mat 904

The procedure of Synthesis Example 601 was repeated except that [Preparation Example 34] was used as a reactant, to obtain 14.7 g of the desired compound; HRMS [M] < + >: 700.27

[Synthesis Example 905] Synthesis of Mat 905

The procedure of Synthesis Example 602 was repeated except that [Preparation Example 34] was used as the reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 776.30

[Synthesis Example 906] Synthesis of Mat 906

The same procedure as in [Synthesis Example 603] was repeated except that [Preparation Example 34] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 790.28

[Synthesis Example 907] Synthesis of Mat 907

The same procedure as in [Synthesis Example 604] was repeated except that [Preparation Example 34] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 701.27

[Synthesis Example 908] Synthesis of Mat 908

The procedure of Synthesis Example 605 was repeated except that [Preparation Example 34] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 777.30

[Synthesis Example 909] Synthesis of Mat 909

The same procedure as in [Synthesis Example 606] was repeated except that [Preparation Example 34] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 778.29

[Synthesis Example 910] Synthesis of Mat 910

The procedure of Synthesis Example 607 was repeated except that [Preparation Example 34] was used as a reactant, to obtain 14.0 g of the target compound; HRMS [M] < + >: 853.33

[Synthesis Example 911] Synthesis of Mat 911

The procedure of Synthesis Example 608 was repeated except that [Preparation Example 34] was used as a reactant, to thereby yield 14.6 g of the desired compound; HRMS [M] < + >: 827.31

[Synthesis Example 912] Synthesis of Mat 912

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 34] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 791.28

[Synthesis Example 913] Synthesis of Mat 913

The procedure of Synthesis Example 610 was repeated except that [Preparation Example 34] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 867.31

[Synthesis Example 914] Synthesis of Mat 914

The procedure of Synthesis Example 611 was repeated except that [Preparation Example 34] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 881.29

[Synthesis Example 915] Synthesis of Mat 915

The procedure of Synthesis Example 612 was repeated except that [Preparation Example 34] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 881.29

[Synthesis Example 916] Synthesis of Mat 916

The procedure of Synthesis Example 613 was repeated except that [Preparation Example 34] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 777.30

[Synthesis Example 917] Synthesis of Mat 917

The procedure of Synthesis Example 614 was repeated except that [Preparation Example 34] was used as a reactant, to obtain 14.6 g of the title compound; HRMS [M] < + >: 853.33

[Synthesis Example 918] Synthesis of Mat 918

The same procedure as in [Synthesis Example 615] was repeated except that [Preparation Example 34] was used as a reactant, to obtain the desired compound (13.7 g; HRMS [M] < + >: 867.31

[Synthesis Example 919] Synthesis of Mat 919

The procedure of Synthesis Example 601 was repeated except that [Preparation Example 35] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 724.27

[Synthesis Example 920] Synthesis of Mat 920

The procedure of Synthesis Example 602 was repeated except that [Preparation Example 35] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 800.30

[Synthesis Example 921] Synthesis of Mat 921

The procedure of Synthesis Example 603 was repeated except that [Preparation Example 35] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 814.28

[Synthesis Example 922] Synthesis of Mat 922

The same procedure as in [Synthesis Example 604] was repeated except that [Preparation Example 35] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 725.27

[Synthesis Example 923] Synthesis of Mat 923

The procedure of Synthesis Example 605 was repeated except that [Preparation Example 35] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 801.30

[Synthesis Example 924] Synthesis of Mat 924

The same procedure as in [Synthesis Example 606] was conducted except that [Preparation Example 35] was used as a reactant, to obtain 14.2 g of the target compound; HRMS [M] < + >: 802.29

[Synthesis Example 925] Synthesis of Mat 925

The procedure of Synthesis Example 607 was repeated except that [Preparation Example 35] was used as a reactant, to obtain 14.0 g of the target compound; HRMS [M] < + >: 877.33

[Synthesis Example 926] Synthesis of Mat 926

The same procedure as in [Synthesis Example 608] was repeated except that [Preparation Example 35] was used as a reactant, to obtain 14.6 g of the target compound; HRMS [M] < + >: 851.31

[Synthesis Example 927] Synthesis of Mat 927

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 35] was used as a reactant, to obtain 15.1 g of the desired compound; HRMS [M] < + >: 815.30

[Synthesis Example 928] Synthesis of Mat 928

The procedure of Synthesis Example 610 was repeated except that [Preparation Example 35] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 891.31

[Synthesis Example 929] Synthesis of Mat 929

The same procedure as in [Synthesis Example 611] was repeated except that [Preparation Example 35] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 905.29

[Synthesis Example 930] Synthesis of Mat 930

The procedure of Synthesis Example 612 was repeated except that [Preparation Example 35] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 905.29

[Synthesis Example 931] Synthesis of Mat 931

The same procedure as in [Synthesis Example 613] was conducted except that [Preparation Example 35] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 815.28

[Synthesis Example 932] Synthesis of Mat 932

The procedure of Synthesis Example 614 was repeated except that [Preparation Example 35] was used as a reactant, to obtain 14.6 g of the desired compound; HRMS [M] < + >: 877.33

[Synthesis Example 933] Synthesis of Mat 933

The same procedure as in [Synthesis Example 615] was repeated except that [Preparation Example 35] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 891.31

[Synthesis Example 934] Synthesis of Mat 934

The procedure of Synthesis Example 601 was repeated except that [Preparation Example 36] was used as the reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 727.27

[Synthesis Example 935] Synthesis of Mat 935

The same procedure as in [Synthesis Example 602] was repeated except that [Preparation Example 36] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 800.30

[Synthesis Example 936] Synthesis of Mat 936

The same procedure as in [Synthesis Example 603] was repeated except that [Preparation Example 36] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 814.28

[Synthesis Example 937] Synthesis of Mat 937

The same procedure as in [Synthesis Example 604] was repeated except that [Preparation Example 36] was used as the reactant, to obtain 14.7 g of the target compound; HRMS [M] < + >: 725.27

[Synthesis Example 938] Synthesis of Mat 938

The procedure of Synthesis Example 605 was repeated except that [Preparation Example 36] was used as a reactant, to obtain 14.2 g of the desired compound; HRMS [M] < + >: 801.30

[Synthesis Example 939] Synthesis of Mat 939

The same procedure as in [Synthesis Example 606] was repeated except that [Preparation Example 36] was used as a reactant, to obtain 14.2 g of the target compound; HRMS [M] < + >: 802.29

[Synthesis Example 940] Synthesis of Mat 940

The procedure of Synthesis Example 607 was repeated except that [Preparation Example 36] was used as the reactant, to obtain 14.0 g of the desired compound; HRMS [M] < + >: 877.33

[Synthesis Example 941] Synthesis of Mat 941

The procedure of Synthesis Example 608 was repeated except that [Preparation Example 36] was used as the reactant, to obtain 14.6 g of the target compound; HRMS [M] < + >: 851.31

[Synthesis Example 942] Synthesis of Mat 942

The same procedure as in [Synthesis Example 609] was conducted except that [Preparation Example 36] was used as a reactant, to obtain 15.1 g of the desired compound; HRMS [M] < + >: 815.28

[Synthesis Example 943] Synthesis of Mat 943

The procedure of Synthesis Example 610 was repeated except that [Preparation Example 36] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 891.31

[Synthesis Example 944] Synthesis of Mat 944

The procedure of Synthesis Example 611 was repeated except that [Preparation Example 36] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 905.29

[Synthesis Example 945] Synthesis of Mat 945

The procedure of Synthesis Example 612 was repeated except that [Preparation Example 36] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 905.29

[Synthesis Example 946] Synthesis of Mat 946

The procedure of Synthesis Example 613 was repeated except that [Preparation Example 36] was used as the reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 815.28

[Synthesis Example 947] Synthesis of Mat 947

The procedure of Synthesis Example 614 was repeated except that [Preparation Example 36] was used as a reactant, to obtain 14.6 g of the desired compound; HRMS [M] < + >: 877.31

[Synthesis Example 948] Synthesis of Mat 948

The procedure of Synthesis Example 615 was repeated except that [Preparation Example 36] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 891.31

[Synthesis Example 949] Synthesis of Mat 949

The procedure of Synthetic Example 603 was repeated except that [Preparation Example 37] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 790.28

[Synthesis Example 950] Synthesis of Mat 950

The procedure of Synthesis Example 604 was repeated except that [Preparation Example 37] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 701.27

[Synthesis Example 951] Synthesis of Mat 951

The procedure of Synthetic Example 605 was repeated except that [Preparation Example 37] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 777.30

[Synthesis Example 952] Synthesis of Mat 952

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 37] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 791.28

[Synthesis Example 953] Synthesis of Mat 953

The same procedure as in [Synthesis Example 611] was repeated except that [Preparation Example 37] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 881.29

[Synthesis Example 954] Synthesis of Mat 954

The same procedure as in [Synthesis Example 613] was repeated except that [Preparation Example 37] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 790.28

[Synthesis Example 955] Synthesis of Mat 955

The same procedure as in [Synthesis Example 615] was repeated except that [Preparation Example 37] was used as a reactant, to obtain the desired compound (13.7 g; HRMS [M] < + >: 867.31

[Synthesis Example 956] Synthesis of Mat 956

The procedure of Synthesis Example 603 was repeated except that [Preparation Example 38] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 840.30

[Synthesis Example 957] Synthesis of Mat 957

The same procedure as in [Synthesis Example 604] was repeated except that [Preparation Example 38] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 751.28

[Synthesis Example 958] Synthesis of Mat 958

The same procedure as in [Synthesis Example 605] was repeated except that [Preparation Example 38] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 827.31

[Synthesis Example 959] Synthesis of Mat 959

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 38] was used as a reactant, to obtain 15.1 g of the desired compound; HRMS [M] < + >: 841.29

[Synthesis Example 960] Synthesis of Mat 960

The same procedure as in [Synthesis Example 611] was repeated except that [Preparation Example 38] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 931.30

[Synthesis Example 961] Synthesis of Mat 961

The procedure of Synthesis Example 613 was repeated except that [Preparation Example 38] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 841.29

[Synthesis Example 962] Synthesis of Mat 962

The same procedure as in [Synthesis Example 615] was repeated except that [Preparation Example 38] was used as a reactant, to obtain the desired compound (13.7 g; HRMS [M] < + >: 917.32

[Synthesis Example 963] Synthesis of Mat 963

The procedure of Synthesis Example 603 was repeated except that [Preparation Example 39] was used as a reactant, to obtain 14.7 g of the desired compound; HRMS [M] < + >: 940.27

[Synthesis Example 964] Synthesis of Mat 964

The procedure of Synthesis Example 604 was repeated except that [Preparation Example 39] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 651.25

[Synthesis Example 965] Synthesis of Mat 965

The procedure of Synthesis Example 605 was repeated except that [Preparation Example 39] was used as a reactant, to obtain 14.2 g of the desired compound; HRMS [M] < + >: 727.28

[Synthesis Example 966] Synthesis of Mat 966

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 39] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 741.26

[Synthesis Example 967] Synthesis of Mat 967

The procedure of Synthesis Example 611 was repeated except that [Preparation Example 39] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 831.27

[Synthesis Example 968] Synthesis of Mat 968

The procedure of Synthesis Example 613 was repeated except that [Preparation Example 39] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 741.26

[Synthesis Example 969] Synthesis of Mat 969

The procedure of Synthesis Example 615 was repeated except that [Preparation Example 39] was used as a reactant, to obtain 13.7 g of the desired compound; HRMS [M] < + >: 817.29

[Synthesis Example 970] Synthesis of Mat 970

The same procedure as in [Synthesis Example 603] was repeated except that [Preparation Example 40] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 790.28

[Synthesis Example 971] Synthesis of Mat 971

The procedure of Synthesis Example 604 was repeated except that [Preparation Example 40] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 701.27

[Synthesis Example 972] Synthesis of Mat 972

The same procedure as in [Synthesis Example 605] was repeated except that [Preparation Example 40] was used as a reactant, to obtain 14.2 g of the target compound; HRMS [M] < + >: 777.30

[Synthesis Example 973] Synthesis of Mat 973

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 40] was used as a reactant, to obtain 15.1 g of the desired compound; HRMS [M] < + >: 791.28

[Synthesis Example 974] Synthesis of Mat 974

The procedure of Synthesis Example 611 was repeated except that [Preparation Example 40] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 881.29

[Synthesis Example 975] Synthesis of Mat 975

The procedure of Synthesis Example 613 was repeated except that [Preparation Example 40] was used as a reactant, to obtain 14.4 g of the desired compound; HRMS [M] < + >: 777.30

[Synthesis Example 976] Synthesis of Mat 976

The same procedure as in [Synthesis Example 615] was repeated except that [Preparation Example 40] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 867.31

[Synthesis Example 977] Synthesis of Mat 977

The same procedure as in [Synthesis Example 603] was repeated except that [Preparation Example 41] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 814.28

[Synthesis Example 978] Synthesis of Mat 978

The procedure of Synthesis Example 604 was repeated except that [Preparation Example 41] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 725.27

[Synthesis Example 979] Synthesis of Mat 979

The procedure of Synthesis Example 605 was repeated except that [Preparation Example 41] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 801.30

[Synthesis Example 980] Synthesis of Mat 980

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 41] was used as a reactant, to obtain 15.1 g of the desired compound; HRMS [M] < + >: 815.30

[Synthesis Example 981] Synthesis of Mat 981

The same procedure as in [Synthesis Example 611] was repeated except that [Preparation Example 41] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 905.29

[Synthesis Example 982] Synthesis of Mat 982

The procedure of Synthesis Example 613 was repeated except that [Preparation Example 41] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 815.28

[Synthesis Example 983] Synthesis of Mat 983

The procedure of Synthesis Example 615 was repeated except that [Preparation Example 41] was used as a reactant, to obtain 13.7 g of the desired compound; HRMS [M] < + >: 891.31

[Synthesis Example 984] Synthesis of Mat 984

The procedure of Synthesis Example 603 was repeated except that [Preparation Example 42] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 814.28

[Synthesis Example 985] Synthesis of Mat 985

The procedure of Synthesis Example 604 was repeated except that [Preparation Example 42] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 725.27

[Synthesis Example 986] Synthesis of Mat 986

The procedure of Synthesis Example 605 was repeated except that [Preparation Example 42] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 801.30

[Synthesis Example 987] Synthesis of Mat 987

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 42] was used as a reactant, to obtain 15.1 g of the desired compound; HRMS [M] < + >: 815.28

[Synthesis Example 988] Synthesis of Mat 988

The procedure of Synthesis Example 611 was repeated except that [Preparation Example 42] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 905.29

[Synthesis Example 989] Synthesis of Mat 989

The procedure of Synthesis Example 613 was repeated except that [Preparation Example 42] was used as a reactant, to obtain 14.4 g of the desired compound; HRMS [M] < + >: 815.28

[Synthesis Example 990] Synthesis of Mat 990

The procedure of Synthesis Example 615 was repeated except that [Preparation Example 42] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 891.31

[Synthesis Example 991] Synthesis of Mat 991

The same procedure as in [Synthesis Example 603] was repeated except that [Preparation Example 43] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 790.28

[Synthesis Example 992] Synthesis of Mat 992

The same procedure as in [Synthesis Example 604] was repeated except that [Preparation Example 43] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 701.27

[Synthesis Example 993] Synthesis of Mat 993

The same procedure as in [Synthesis Example 605] was repeated except that [Preparation Example 43] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 777.30

[Synthesis Example 994] Synthesis of Mat 994

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 43] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 791.28

[Synthesis Example 995] Synthesis of Mat 995

The procedure of Synthesis Example 611 was repeated except that [Preparation Example 43] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 881.29

[Synthesis Example 996] Synthesis of Mat 996

The same procedure as in [Synthesis Example 613] was conducted except that [Preparation Example 43] was used as a reactant, to obtain 14.4 g of the desired compound; HRMS [M] < + >: 790.28

[Synthesis Example 997] Synthesis of Mat 997

The same procedure as in [Synthesis Example 615] was repeated except that [Preparation Example 43] was used as a reactant, to obtain the desired compound (13.7 g); HRMS [M] < + >: 867.31

[Synthesis Example 998] Synthesis of Mat 998

The same procedure as in [Synthesis Example 603] was repeated except that [Preparation Example 44] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 840.30

[Synthesis Example 999] Synthesis of Mat 999

The same procedure as in [Synthesis Example 604] was repeated except that [Preparation Example 44] was used as the reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 751.28

[Synthesis Example 1000] Synthesis of Mat 1000

The same procedure as in [Synthesis Example 605] was repeated except that [Preparation Example 44] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 827.31

[Synthesis Example 1001] Synthesis of Mat 1001

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 44] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 841.29

[Synthesis Example 1002] Synthesis of Mat 1002

The same procedure as in [Synthesis Example 611] was repeated except that [Preparation Example 44] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 931.30

[Synthesis Example 1003] Synthesis of Mat 1003

The procedure of Synthesis Example 613 was repeated except that [Preparation Example 44] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 841.29

[Synthesis Example 1004] Synthesis of Mat 1004

The same procedure as in [Synthesis Example 615] was repeated except that [Preparation Example 44] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 917.32

[Synthesis Example 1005] Synthesis of Mat 1005

The procedure of Synthesis Example 603 was repeated except that [Preparation Example 45] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 940.27

[Synthesis Example 1006] Synthesis of Mat 1006

The procedure of Synthesis Example 604 was repeated except that [Preparation Example 45] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 651.25

[Synthesis Example 1007] Synthesis of Mat 1007

The procedure of Synthesis Example 605 was repeated except that [Preparation Example 45] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 727.28

[Synthesis Example 1008] Synthesis of Mat 1008

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 45] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 741.26

[Synthesis Example 1009] Synthesis of Mat 1009

The procedure of Synthesis Example 611 was repeated except that [Preparation Example 45] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 831.27

[Synthesis Example 1010] Synthesis of Mat 1010

The procedure of Synthesis Example 613 was repeated except that [Preparation Example 45] was used as a reactant, to thereby yield 14.4 g of the title compound; HRMS [M] < + >: 741.26

[Synthesis Example 1011] Synthesis of Mat 1011

The same procedure as in [Synthesis Example 615] was repeated except that [Preparation Example 45] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 817.29

[Synthesis Example 1012] Synthesis of Mat 1012

The procedure of Synthesis Example 603 was repeated except that [Preparation Example 46] was used as the reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 790.28

[Synthesis Example 1013] Synthesis of Mat 1013

The procedure of Synthesis Example 604 was repeated except that [Preparation Example 46] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 701.27

[Synthesis Example 1014] Synthesis of Mat 1014

The procedure of Synthesis Example 605 was repeated except that [Preparation Example 46] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 777.30

[Synthesis Example 1015] Synthesis of Mat 1015

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 46] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 791.28

[Synthesis Example 1016] Synthesis of Mat 1016

The procedure of Synthesis Example 611 was repeated except that [Preparation Example 46] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 881.29

[Synthesis Example 1017] Synthesis of Mat 1017

The procedure of Synthesis Example 613 was repeated except that [Preparation Example 46] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 777.30

[Synthesis Example 1018] Synthesis of Mat 1018

The procedure of Synthesis Example 615 was repeated except that [Preparation Example 46] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 867.31

[Synthesis Example 1019] Synthesis of Mat 1019

The same procedure as in [Synthesis Example 603] was repeated except that [Preparation Example 47] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 814.28

[Synthesis Example 1020] Synthesis of Mat 1020

The same procedure as in [Synthesis Example 604] was repeated except that [Preparation Example 47] was used as a reactant, to obtain 14.7 g of the target compound; HRMS [M] < + >: 725.27

[Synthesis Example 1021] Synthesis of Mat 1021

The same procedure as in [Synthesis Example 605] was repeated except that [Preparation Example 47] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 801.30

[Synthesis Example 1022] Synthesis of Mat 1022

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 47] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 815.30

[Synthesis Example 1023] Synthesis of Mat 1023

The procedure of Synthesis Example 611 was repeated except that [Preparation Example 47] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 905.29

[Synthesis Example 1024] Synthesis of Mat 1024

The same procedure as in [Synthesis Example 613] was repeated except that [Preparation Example 47] was used as a reactant, to obtain 14.4 g of the desired compound; HRMS [M] < + >: 815.28

[Synthesis Example 1025] Synthesis of Mat 1025

The same procedure as in [Synthesis Example 615] was repeated except that [Preparation Example 47] was used as a reactant, to obtain the desired compound (13.7 g); HRMS [M] < + >: 891.31

[Synthesis Example 1026] Synthesis of Mat 1026

The procedure of Synthesis Example 603 was repeated except that [Preparation Example 48] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 814.28

[Synthesis Example 1027] Synthesis of Mat 1027

The procedure of Synthesis Example 604 was repeated except that [Preparation Example 48] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 725.27

[Synthesis Example 1028] Synthesis of Mat 1028

The procedure of Synthesis Example 605 was repeated except that [Preparation Example 48] was used as a reactant, to obtain 14.2 g of the target compound; HRMS [M] < + >: 801.30

[Synthesis Example 1029] Synthesis of Mat 1029

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 48] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 815.28

[Synthesis Example 1030] Synthesis of Mat 1030

The same procedure as in [Synthesis Example 611] was repeated except that [Preparation Example 48] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 905.29

[Synthesis Example 1031] Synthesis of Mat 1031

The same procedure as in [Synthesis Example 613] was repeated except that [Preparation Example 48] was used as a reactant, to obtain 14.4 g of the target compound; HRMS [M] < + >: 815.28

[Synthesis Example 1032] Synthesis of Mat 1032

The same procedure as in [Synthesis Example 615] was repeated except that [Preparation Example 48] was used as a reactant, to obtain the desired compound (13.7 g; HRMS [M] < + >: 891.31

[Synthesis Example 1033] Synthesis of Mat 1033

The same procedure as in [Synthesis Example 603] was repeated except that [Preparation Example 49] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 840.30

[Synthesis Example 1034] Synthesis of Mat 1034

The same procedure as in [Synthesis Example 604] was repeated except that [Preparation Example 49] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 751.28

[Synthesis Example 1035] Synthesis of Mat 1035

The procedure of Synthetic Example 605 was repeated except that [Preparation Example 49] was used as the reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 827.31

[Synthesis Example 1036] Synthesis of Mat 1036

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 49] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 841.29

[Synthesis Example 1037] Synthesis of Mat 1037

The procedure of Synthesis Example 611 was repeated except that [Preparation Example 49] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 931.30

[Synthesis Example 1038] Synthesis of Mat 1038

The procedure of Synthesis Example 613 was repeated except that [Preparation Example 49] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 840.30

[Synthesis Example 1039] Synthesis of Mat 1039

The procedure of Synthesis Example 615 was repeated except that [Preparation Example 49] was used as a reactant, to obtain 13.7 g of the desired compound; HRMS [M] < + >: 917.32

[Synthesis Example 1040] Synthesis of Mat 1040

The same procedure as in [Synthesis Example 603] was repeated except that [Preparation Example 50] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 890.31

[Synthesis Example 1041] Synthesis of Mat 1041

The same procedure as in [Synthesis Example 604] was repeated except that [Preparation Example 50] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 801.30

[Synthesis Example 1042] Synthesis of Mat 1042

The procedure of Synthetic Example 605 was repeated except that [Preparation Example 50] was used as the reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 877.33

[Synthesis Example 1043] Synthesis of Mat 1043

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 50] was used as a reactant, to obtain 15.1 g of the desired compound; HRMS [M] < + >: 891.31

[Synthesis Example 1044] Synthesis of Mat 1044

The same procedure as in [Synthesis Example 611] was repeated except that [Preparation Example 50] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 981.32

[Synthesis Example 1045] Synthesis of Mat 1045

The same procedure as in [Synthesis Example 613] was repeated except that [Preparation Example 50] was used as a reactant, to obtain 14.4 g of the target compound; HRMS [M] < + >: 891.31

[Synthesis Example 1046] Synthesis of Mat 1046

The same procedure as in [Synthesis Example 615] was repeated except that [Preparation Example 50] was used as a reactant, to obtain the desired compound (13.7 g; HRMS [M] < + >: 967.34

[Synthesis Example 1047] Synthesis of Mat 1047

The procedure of Synthesis Example 603 was repeated except that [Preparation Example 51] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 790.28

[Synthesis Example 1048] Synthesis of Mat 1048

The procedure of Synthesis Example 604 was repeated except that [Preparation Example 51] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 701.27

[Synthesis Example 1049] Synthesis of Mat 1049

The procedure of Synthetic Example 605 was repeated except that [Preparation Example 51] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 777.30

[Synthesis Example 1050] Synthesis of Mat 1050

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 51] was used as a reactant, to obtain 15.1 g of the desired compound; HRMS [M] < + >: 791.28

[Synthesis Example 1051] Synthesis of Mat 1051

The same procedure as in [Synthesis Example 611] was conducted except that [Preparation Example 51] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 881.29

[Synthesis Example 1052] Synthesis of Mat 1052

The procedure of Synthesis Example 613 was repeated except that [Preparation Example 51] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 791.28

[Synthesis Example 1053] Synthesis of Mat 1053

The procedure of Synthesis Example 615 was repeated except that [Preparation Example 51] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 867.31

[Synthesis Example 1054] Synthesis of Mat 1054

The same procedure as in [Synthesis Example 603] was conducted except that [Preparation Example 52] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 840.30

[Synthesis Example 1055] Synthesis of Mat 1055

The same procedure as in [Synthesis Example 604] was repeated except that [Preparation Example 52] was used as the reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 751.28

[Synthesis Example 1056] Synthesis of Mat 1056

The procedure of Synthesis Example 605 was repeated except that [Preparation Example 52] was used as a reactant, to obtain 14.2 g of the desired compound; HRMS [M] < + >: 827.31

[Synthesis Example 1057] Synthesis of Mat 1057

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 52] was used as a reactant, to obtain 15.1 g of the desired compound; HRMS [M] < + >: 841.29

[Synthesis Example 1058 Synthesis of Mat 1058

The procedure of Synthesis Example 611 was repeated except that [Preparation Example 52] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 931.30

[Synthesis Example 1059] Synthesis of Mat 1059

The procedure of Synthesis Example 613 was repeated except that [Preparation Example 52] was used as a reactant, to obtain 14.4 g of the desired compound; HRMS [M] < + >: 827.31

[Synthesis Example 1060] Synthesis of Mat 1060

The same procedure as in [Synthesis Example 615] was repeated except that [Preparation Example 52] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 917.32

[Synthesis Example 1061] Synthesis of Mat 1061

The procedure of Synthetic Example 603 was repeated except that [Preparation Example 53] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 864.30

[Synthesis Example 1062] Synthesis of Mat 1062

The same procedure as in [Synthesis Example 604] was repeated except that [Preparation Example 53] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 775.28

[Synthesis Example 1063] Synthesis of Mat 1063

The procedure of Synthesis Example 605 was repeated except that [Preparation Example 53] was used as a reactant, to obtain 14.2 g of the target compound; HRMS [M] < + >: 851.31

[Synthesis Example 1064] Synthesis of Mat 1064

The same procedure as in [Synthesis Example 609] was repeated except that [Preparation Example 53] was used as a reactant, to obtain 15.1 g of the desired compound; HRMS [M] < + >: 865.29

[Synthesis Example 1065] Synthesis of Mat 1065

The same procedure as in [Synthesis Example 611] was repeated except that [Preparation Example 53] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 955.30

[Synthesis Example 1066] Synthesis of Mat 1066

The procedure of Synthesis Example 613 was repeated except that [Preparation Example 53] was used as a reactant, to obtain 14.4 g of the desired compound; HRMS [M] < + >: 865.29

[Synthesis Example 1067] Synthesis of Mat 1067

The same procedure as in [Synthesis Example 615] was repeated except that [Preparation Example 53] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 941.32

[Synthesis Example 1068] Synthesis of Mat 1068

The procedure of Synthesis Example 603 was repeated except that [Preparation Example 54] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 864.30

[Synthesis Example 1069] Synthesis of Mat 1069

The procedure of Synthesis Example 604 was repeated except that [Preparation Example 54] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 775.28

[Synthesis Example 1070] Synthesis of Mat 1070

The procedure of Synthesis Example 605 was repeated except that [Preparation Example 54] was used as a reactant, to thereby yield 14.2 g of the target compound; HRMS [M] < + >: 851.31

[Synthesis Example 1071] Synthesis of Mat 1071

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 54] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 865.29

[Synthesis Example 1072] Synthesis of Mat 1072

The procedure of Synthesis Example 611 was repeated except that [Preparation Example 54] was used as a reactant, to obtain 15.3 g of the desired compound; HRMS [M] < + >: 955.30

[Synthesis Example 1073] Synthesis of Mat 1073

The procedure of Synthesis Example 613 was repeated except that [Preparation Example 54] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 865.29

[Synthesis Example 1074] Synthesis of Mat 1074

The procedure of Synthesis Example 615 was repeated except that [Preparation Example 54] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 941.32

[Synthesis Example 1075] Synthesis of Mat 1075

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 55] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 651.25

[Synthesis Example 1076] Synthesis of Mat 1076

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 55] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 727.28

[Synthesis Example 1077] Synthesis of Mat 1077

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 55] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 741.26

[Synthesis Example 1078] Synthesis of Mat 1078

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 55] was used as a reactant, to obtain 15.1 g of the title compound; HRMS [M] < + >: 831,27

[Synthesis Example 1079] Synthesis of Mat 1079

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 55] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 624.24

[Synthesis Example 1080] Synthesis of Mat 1080

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 56] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 741.26

[Synthesis Example 1081] Synthesis of Mat 1081

The same procedure as in [Synthesis Example 4] was carried out except that [Preparation Example 57] was used as a reactant, to obtain 13.7 g of the title compound; HRMS [M] < + >: 817.29

[Synthesis Example 1082] Synthesis of Mat 1082

The same procedure as in [Synthesis Example 1075] was repeated except that [Preparation Example 58] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 701.27

[Synthesis Example 1083] Synthesis of Mat 1083

The same procedure as in [Synthesis Example 1076] was conducted except that [Preparation Example 58] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 777.30

[Synthesis Example 1084] Synthesis of Mat 10784

The same procedure as in [Synthesis Example 1077] was conducted except that [Preparation Example 58] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 791.28

[Synthesis Example 1085] Synthesis of Mat 1085

The procedure of Synthesis Example 1078 was repeated except that [Preparation Example 58] was used as the reactant, to obtain the title compound (15.1 g; HRMS [M] < + >: 881.29

[Synthesis Example 1086] Synthesis of Mat 1086

The procedure of Synthesis Example 1079 was repeated except that [Preparation Example 58] was used as a reactant, to obtain 15.3 g of the title compound; HRMS [M] < + >: 674.26

[Synthesis Example 1087] Synthesis of Mat 1087

The same procedure as in [Synthesis Example 1080] was repeated except that [Preparation Example 59] was used as a reactant, to obtain 14.4 g of the title compound; HRMS [M] < + >: 791.28

[Synthesis Example 1088] Synthesis of Mat 1088

The same procedure as in [Synthesis Example 1077] was conducted except that [Preparation Example 60] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 691.25

[Synthesis Example 1089] Synthesis of Mat 1089

The procedure of [Synthesis Example 1077] was repeated except that [Preparation Example 61] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 741.26

[Synthesis Example 1090] Synthesis of Mat 1090

The same procedure as in [Synthesis Example 1077] was conducted except that [Preparation Example 62] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 765.26

[Synthesis Example 1091] Synthesis of Mat 1091

The same procedure as in [Synthesis Example 1077] was carried out except that [Preparation Example 63] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 765.26

[Synthesis Example 1092] Synthesis of Mat 1092

The same procedure as in [Synthesis Example 1077] was conducted except that [Preparation Example 64] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 817.29

[Synthesis Example 1093] Synthesis of Mat 1093

The same procedure as in [Synthesis Example 1077] was conducted except that [Preparation Example 65] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 867.31

[Synthesis Example 1094] Synthesis of Mat 1094

The same procedure as in [Synthesis Example 1077] was conducted except that [Preparation Example 66] was used as a reactant, to obtain 14.2 g of the target compound; HRMS [M] < + >: 767.28

[Synthesis Example 1095] Synthesis of Mat 1095

The procedure of [Synthesis Example 1077] was repeated except that [Preparation Example 67] was used as a reactant, to obtain 14.2 g of the target compound; HRMS [M] < + >: 817.29

[Synthesis Example 1096] Synthesis of Mat 1096

The procedure of [Synthesis Example 1077] was repeated except that [Preparation Example 68] was used as the reactant, to obtain 14.2 g of the target compound; HRMS [M] < + >: 841.29

[Synthesis Example 1097] Synthesis of Mat 1097

The same procedure as in [Synthesis Example 1077] was conducted except that [Preparation Example 69] was used as a reactant, to obtain 14.2 g of the target compound; HRMS [M] < + >: 841.29

[Synthesis Example 1098] Synthesis of Mat 1098

The procedure of [Synthesis Example 1077] was repeated except that [Preparation Example 70] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 817.29

[Synthesis Example 1099] Synthesis of Mat 1099

The same procedure as in [Synthesis Example 1077] was conducted except that [Preparation Example 71] was used as a reactant, to obtain 14.2 g of the target compound; HRMS [M] < + >: 867.31

[Synthesis Example 1100] Synthesis of Mat 1100

The same procedure as in [Synthesis Example 1077] was conducted except that [Preparation Example 72] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 767.28

[Synthesis Example 1101] Synthesis of Mat 1101

The same procedure as in [Synthesis Example 1077] was carried out except that [Preparation Example 73] was used as a reactant, to obtain 14.2 g of the desired compound; HRMS [M] < + >: 817.29

[Synthesis Example 1102] Synthesis of Mat 1102

The procedure of [Synthesis Example 1077] was repeated except that [Preparation Example 74] was used as a reactant, to obtain 14.2 g of the target compound; HRMS [M] < + >: 841.29

[Synthesis Example 1103] Synthesis of Mat 1103

The procedure of Synthesis Example 1077 was repeated except that [Preparation Example 75] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 841.29

[Synthesis Example 1104] Synthesis of Mat 1104

The procedure of [Synthesis Example 1077] was repeated except that [Preparation Example 76] was used as a reactant, to obtain 14.2 g of the target compound; HRMS [M] < + >: 893.32

[Synthesis Example 1105] Synthesis of Mat 1105

The procedure of [Synthesis Example 1077] was repeated except that [Preparation Example 77] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 943.34

[Synthesis Example 1106] Synthesis of Mat 1106

The procedure of [Synthesis Example 1077] was repeated except that [Preparation Example 78] was used as a reactant, to obtain 14.2 g of the desired compound; HRMS [M] < + >: 843.31

[Synthesis Example 1107] Synthesis of Mat 1107

The procedure of [Synthesis Example 1077] was repeated except that [Preparation Example 79] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 893.32

[Synthesis Example 1108] Synthesis of Mat 1108

The same procedure as in [Synthesis Example 1077] was conducted except that [Preparation Example 80] was used as a reactant, to obtain 14.2 g of the target compound; HRMS [M] < + >: 917.32

[Synthesis Example 1109] Synthesis of Mat 1109

The procedure of [Synthesis Example 1077] was repeated except that [Preparation Example 81] was used as a reactant, to obtain 14.2 g of the target compound; HRMS [M] < + >: 917.32

[Synthesis Example 1110] Synthesis of Mat 1110

The same procedure as in [Synthesis Example 1077] was conducted except that [Preparation Example 82] was used as a reactant, to obtain 14.2 g of the target compound; HRMS [M] < + >: 907.30

[Synthesis Example 1111] Synthesis of Mat 1111

The same procedure as in [Synthesis Example 1077] was conducted except that [Preparation Example 83] was used as a reactant, to obtain 14.2 g of the target compound; HRMS [M] < + >: 957.32

[Synthesis Example 1112] Synthesis of Mat 1112

The procedure of [Synthesis Example 1077] was repeated except that [Preparation Example 84] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 857.29

[Synthesis Example 1113] Synthesis of Mat 1113

The same procedure as in [Synthesis Example 1077] was conducted except that [Preparation Example 85] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 907.30

[Synthesis Example 1114] Synthesis of Mat 1114

The procedure of [Synthesis Example 1077] was repeated except that [Preparation Example 86] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 911.30

[Synthesis Example 1115] Synthesis of Mat 1115

The procedure of [Synthesis Example 1077] was repeated except that [Preparation Example 87] was used as a reactant, to obtain 14.2 g of the target compound; HRMS [M] < + >: 931.30

[Synthesis Example 1116] Synthesis of Mat 1116

The procedure of [Synthesis Example 1077] was repeated except that [Preparation Example 88] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 791.28

[Synthesis Example 1117] Synthesis of Mat 1117

The procedure of [Synthesis Example 1077] was repeated except that [Preparation Example 89] was used as the reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 841.29

[Synthesis Example 1118] Synthesis of Mat 1118

The same procedure as in [Synthesis Example 1077] was conducted except that [Preparation Example 90] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 741.26

[Synthesis Example 1119] Synthesis of Mat 1019

The same procedure as in [Synthesis Example 1077] was carried out except that [Preparation Example 91] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 791.28

[Synthesis Example 1120] Synthesis of Mat 1120

The procedure of [Synthesis Example 1077] was repeated except that [Preparation Example 92] was used as the reactant, to obtain 14.2 g of the target compound; HRMS [M] < + >: 815.28

[Synthesis Example 1121] Synthesis of Mat 1121

The same procedure as in [Synthesis Example 1077] was conducted except that [Preparation Example 93] was used as a reactant, to obtain 14.2 g of the target compound; HRMS [M] < + >: 815.28

[Synthesis Example 1122] Synthesis of Mat 1122

The same procedure as in [Synthesis Example 1077] was conducted except that [Preparation Example 94] was used as a reactant, to obtain 14.2 g of the target compound; HRMS [M] < + >: 791.28

[Synthesis Example 1123] Synthesis of Mat 1123

The procedure of [Synthesis Example 1077] was repeated except that [Preparation Example 95] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 841.29

[Synthesis Example 1124] Synthesis of Mat 1124

The procedure of [Synthesis Example 1077] was repeated except that [Preparation Example 96] was used as a reactant, to obtain 14.2 g of the target compound; HRMS [M] < + >: 741.26

[Synthesis Example 1125] Synthesis of Mat 1025

The procedure of [Synthesis Example 1077] was repeated except that [Preparation Example 97] was used as a reactant, to obtain 14.2 g of the target compound; HRMS [M] < + >: 791.28

[Synthesis Example 1126] Synthesis of Mat 1126

The same procedure as in [Synthesis Example 1077] was conducted except that [Preparation Example 98] was used as a reactant, to obtain 14.2 g of the target compound; HRMS [M] < + >: 815.28

[Synthesis Example 1127] Synthesis of Mat 1127

The procedure of [Synthesis Example 1077] was repeated except that [Preparation Example 99] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 815.28

[Synthesis Example 1128] Synthesis of Mat 1128

The procedure of [Synthesis Example 1077] was repeated except that [Preparation Example 99] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 791.28

[Synthesis Example 1129] Synthesis of Mat 1129

The procedure of [Synthesis Example 1077] was repeated except that [Preparation Example 100] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 841.29

[Synthesis Example 1130] Synthesis of Mat 1130

The same procedure as in [Synthesis Example 1077] was conducted except that [Preparation Example 101] was used as a reactant, to obtain 14.2 g of the target compound; HRMS [M] < + >: 741.26

[Synthesis Example 1131] Synthesis of Mat 1031

The procedure of [Synthesis Example 1077] was repeated except that [Preparation Example 102] was used as a reactant, to obtain 14.2 g of the target compound; HRMS [M] < + >: 791.28

[Synthesis Example 1132] Synthesis of Mat 1132

The procedure of [Synthesis Example 1077] was repeated except that [Preparation Example 103] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 815.28

[Synthesis Example 1133] Synthesis of Mat 1133

The same procedure as in [Synthesis Example 1077] was conducted except that [Preparation Example 104] was used as a reactant, to obtain 14.2 g of the target compound; HRMS [M] < + >: 815.28

[Synthesis Example 1134] Synthesis of Mat 1134

The procedure of [Synthesis Example 1077] was repeated except that [Preparation Example 105] was used as a reactant, to obtain 14.2 g of the desired compound; HRMS [M] < + >: 841.29

[Synthesis Example 1135] Synthesis of Mat 1135

The same procedure as in [Synthesis Example 1077] was conducted except that [Preparation Example 106] was used as a reactant, to obtain 14.2 g of the target compound; HRMS [M] < + >: 891.31

[Synthesis Example 1136] Synthesis of Mat 1136

The same procedure as in [Synthesis Example 1077] was conducted except that [Preparation Example 107] was used as a reactant, to obtain 14.2 g of the desired compound; HRMS [M] < + >: 791.28

[Synthesis Example 1137] Synthesis of Mat 1037

The procedure of [Synthesis Example 1077] was repeated except that [Preparation Example 108] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 841.29

[Synthesis Example 1138] Synthesis of Mat 1138

The procedure of Synthesis Example 1077 was repeated except that [Preparation Example 109] was used as a reactant, to obtain 14.2 g of the desired compound; HRMS [M] < + >: 865.29

[Synthesis Example 1139] Synthesis of Mat 1139

The procedure of [Synthesis Example 1077] was repeated except that [Preparation Example 110] was used as a reactant, to obtain 14.2 g of the title compound; HRMS [M] < + >: 865.29

[Synthesis Example 1140] Synthesis of Mat 1140

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 55] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 816.30

[Synthesis Example 1141] Synthesis of Mat 1141

The same procedure as in [Synthesis Example 1140] was repeated except that [Preparation Example 63] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 892.33

[Synthesis Example 1142] Synthesis of Mat 1142

The procedure of Synthesis Example 1140 was repeated except that [Preparation Example 69] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 892.33

[Synthesis Example 1143] Synthesis of Mat 1143

The procedure of Synthesis Example 1140 was repeated except that [Preparation Example 75] was used as the reactant, to thereby yield 14.7 g of the target compound; HRMS [M] < + >: 968.36

[Synthesis Example 1144] Synthesis of Mat 1144

The procedure of [Synthesis Example 1140] was repeated except that [Preparation Example 81] was used as a reactant, to obtain 14.7 g of the desired compound; HRMS [M] < + >: 982.34

[Synthesis Example 1145] Synthesis of Mat 1145

The procedure of [Synthesis Example 1140] was repeated except that [Preparation Example 87] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 856.31

[Synthesis Example 1146] Synthesis of Mat 1146

The procedure of [Synthesis Example 1140] was repeated except that [Preparation Example 93] was used as a reactant, to obtain 14.7 g of the desired compound; HRMS [M] < + >: 856.31

[Synthesis Example 1147] Synthesis of Mat 1147

The procedure of Synthesis Example 1140 was repeated except that [Preparation Example 99] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 856.31

[Synthesis Example 1148] Synthesis of Mat 1148

The procedure of Synthesis Example 1140 was repeated except that [Preparation Example 105] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 916.33

[Synthesis Example 1149] Synthesis of Mat 1149

The procedure of Synthesis Example 609 was repeated except that [Preparation Example 56] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 866.31

[Synthesis Example 1150] Synthesis of Mat 1150

The procedure of Synthesis Example 1140 was repeated except that [Preparation Example 64] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 943.34

[Synthesis Example 1151] Synthesis of Mat 1151

The procedure of [Synthesis Example 1140] was repeated except that [Preparation Example 70] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 943.34

[Synthesis Example 1152] Synthesis of Mat 1152

The procedure of [Synthesis Example 1140] was repeated except that [Preparation Example 76] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 1019.37

[Synthesis Example 1153] Synthesis of Mat 1153

The procedure of [Synthesis Example 1140] was repeated except that [Preparation Example 82] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 1033.35

[Synthesis Example 1154] Synthesis of Mat 1154

The procedure of Synthesis Example 1140 was repeated except that [Preparation Example 88] was used as the reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 917.32

[Synthesis Example 1155] Synthesis of Mat 1155

The procedure of Synthesis Example 1140 was repeated except that [Preparation Example 94] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 917.32

[Synthesis Example 1156] Synthesis of Mat 1156

The same procedure as in [Synthesis Example 1140] was repeated except that [Preparation Example 100] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 917.32

[Synthesis Example 1157] Synthesis of Mat 1157

The procedure of Synthesis Example 1140 was repeated except that [Preparation Example 106] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 967.34

[Synthesis Example 1158] Synthesis of Mat 1158

The same procedure as in [Synthesis Example 9] was carried out except that [Preparation Example 111] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 830.29

[Synthesis Example 1159] Synthesis of Mat 1159

The same procedure as in [Synthesis Example 9] was carried out except that [Preparation Example 112] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 880.30

[Synthesis Example 1160] Synthesis of Mat 1160

The procedure of Synthesis Example 9 was repeated except that [Preparation Example 113] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 956.33

[Synthesis Example 1161] Synthesis of Mat 1161

The procedure of Synthesis Example 1140 was repeated except that [Preparation Example 113] was used as a reactant, to obtain 14.7 g of the title compound; HRMS [M] < + >: 1032.37

[ Example  1 to 35] Fabrication of green organic EL device

Compounds Mat-3 to Mat-1160 synthesized in Synthesis Examples 1 to 1160 were subjected to high purity sublimation purification by a conventionally known method, and then a green organic EL device was produced according to the following procedure.

First, a glass substrate coated with ITO (Indium Tin Oxide) with a thickness of 1500 Å was washed with distilled water ultrasonic waves. After the distilled water was washed, the substrate was ultrasonically washed with a solvent such as isopropyl alcohol, acetone, or methanol, dried and transferred to a UV OZONE cleaner (Power Sonic 405, Hoshin Tech), the substrate was cleaned using UV for 5 minutes, The substrate was transferred.

Each compound of m-MTDATA (60 nm) / TCTA (80 nm) / MAt-3 to Mat-1160 + 10% Ir (ppy) ₃ (30 nm) / BCP (10 nm) / Alq ₃ (30 nm) / LiF (1 nm) / Al (200 nm) in that order.

The structures of m-MTDATA, TCTA, Ir (ppy) ₃ , C-3-P, C-2-P, CBP and BCP are as follows.

[ Comparative Example  1 to 3] Fabrication of green organic EL device

A green organic EL device was fabricated in the same manner as in Example 1, except that CBP or C-3-P and C-2-P were used instead of the compound Mat-3 as a luminescent host material in the formation of the light emitting layer.

[ Evaluation example ]

The driving voltage, current efficiency and emission peak at the current density (10) mA / cm < 2 > were measured for each of the green organic EL devices manufactured in Examples 1 to 35 and Comparative Example 1, .

Sample Host Driving voltage
(V) EL peak
(nm) Current efficiency
(cd / A) Example 1 Mat 3 6.80 516 41.2 Example 2 Mat 4 6.77 516 42.3 Example 3 Mat 5 6.83 516 40.7 Example 4 Mat 9 6.80 516 40.8 Example 5 Mat 11 6.87 516 41.5 Example 6 Mat 17 6.79 516 41.5 Example 7 Mat 24 6.81 516 40.6 Example 8 Mat 39 6.80 516 40.2 Example 9 Mat 55 6.80 516 40.1 Example 10 Mat 69 6.81 516 41.3 Example 11 Mat 85 6.80 516 40.6 Example 12 Mat 95 6.80 516 41.5 Example 13 Mat 105 6.80 516 40.6 Example 14 Mat 155 6.71 516 40.2 Example 15 Mat 165 6.79 516 40.1 Example 16 Mat 275 6.81 516 41.3 Example 17 Mat 285 6.80 516 40.2 Example 18 Mat 605 6.80 516 40.1 Example 19 Mat 615 6.77 516 41.3 Example 20 Mat 628 6.83 516 41.2 Example 21 Mat 694 6.80 516 42.3 Example 22 Mat 701 6.80 516 40.7 Example 23 Mat 819 6.79 516 40.8 Example 24 Mat 827 6.81 516 41.5 Example 25 Mat 868 6.80 516 41.5 Example 26 Mat 1077 6.80 516 40.6 Example 27 Mat 1084 6.81 516 40.2 Example 28 Mat 1087 6.80 516 40.1 Example 29 Mat 1093 6.80 516 41.3 Example 30 Mat 1099 6.80 516 40.6 Example 31 Mat 1144 6.71 516 41.5 Example 32 Mat 1150 6.79 516 40.6 Example 33 Mat 1158 6.81 516 40.2 Example 34 Mat 1159 6.80 516 40.1 Example 35 Mat 1160 6.77 516 41.3 Comparative Example 1 CBP 6.93 516 38.2 Comparative Example 2 B-3-F 6.88 516 37.8 Comparative Example 3 B-2-F 6.86 516 38.9

As shown in Table 1, when CBP, C-3-P, and C-3 were used when the compound (Mat-3 to MAt-1160) according to the present invention was used as a light emitting layer of a green organic EL device -2-P (Comparative Examples 1 to 3), the organic EL device of the present invention exhibits better performance in terms of efficiency and driving voltage.

[ Example  36 to 55] Production of red organic EL device

The compound synthesized in Synthesis Example was subjected to high purity sublimation purification by a conventionally known method, and a red organic electroluminescent device was fabricated according to the following procedure.

First, a glass substrate coated with ITO (Indium Tin Oxide) with a thickness of 1500 Å was washed with distilled water ultrasonic waves. After the distilled water was washed, the substrate was ultrasonically washed with a solvent such as isopropyl alcohol, acetone, or methanol, dried and transferred to a UV OZONE cleaner (Power Sonic 405, Hoshin Tech), the substrate was cleaned using UV for 5 minutes, The substrate was transferred.

Thus prepared ITO transparent electrode on the m-MTDATA (60 nm) / TCTA (80 nm) / Mat 4 ~ Mat 1087 compound + 10% (piq) of _{2 Ir (acac) (30nm)} / BCP (10 nm) / Alq 3 (30 nm) / LiF (1 nm) / Al (200 nm) were stacked in this order to fabricate an organic electroluminescent device.

[ Comparative Example  4 To 6] Production of red organic EL device

A red organic electroluminescent device was fabricated in the same manner as in Example 36 except that CBP was used instead of the compound of Synthesis Example 4 as a luminescent host material in forming the light emitting layer.

The structures of m-MTDATA, (piq) ₂ Ir (acac), C-3-Q, C-2-Q, CBP and BCP used in Examples 36 to 55 and Comparative Examples 4 to 6 are as follows.

[ Evaluation example ]

The driving voltage and the current efficiency at the current density of 10 mA / cm 2 were measured for each of the organic electroluminescent devices manufactured in Examples 36 to 55 and Comparative Examples 4 to 6, and the results are shown in Table 2 below.

Sample Host The driving voltage (V) Current efficiency (cd / A) Example 36 Mat 4 5.11 9.0 Example 37 Mat 13 4.99 8.6 Example 38 Mat 14 4.98 9.0 Example 39 Mat 15 5.14 8.6 Example 40 Mat 28 5.00 9.4 Example 41 Mat 43 5.12 9.5 Example 42 Mat 58 4.80 9.1 Example 43 Mat 73 5.12 8.9 Example 44 Mat 88 4.80 8.9 Example 45 Mat 98 5.11 9.1 Example 46 Mat 108 4.99 9.0 Example 47 Mat 158 4.98 8.6 Example 48 Mat 168 5.00 9.3 Example 49 Mat 278 5.00 9.0 Example 50 Mat 334 5.12 8.8 Example 51 Mat 343 4.98 8.9 Example 52 Mat 349 5.14 9.1 Example 53 Mat 358 5.11 9.0 Example 54 Mat 1082 4.99 8.6 Example 55 Mat 1087 4.98 8.9 Comparative Example 4 CBP 5.25 8.2 Comparative Example 5 C-3-Q 5.31 7.8 Comparative Example 6 C-2-Q 5.27 8.0

As shown in Table 2, when CBP, C-3-Q and C-2-Q were used as the material of the light emitting layer of the red organic electroluminescent device (Examples 36 to 55) (Comparative Examples 4 to 6) used as the material of the organic electroluminescent device of the present invention.

10: anode 20: cathode
30: organic layer 31: hole transport layer
32: light emitting layer 33: hole transporting auxiliary layer
34: Electron transport layer 35: Electron transport layer
36: electron injection layer 37: hole injection layer

Claims (15)

A compound represented by the following formula (1):
[Chemical Formula 1]

In Formula 1,
m is an integer from 0 to 4;
n is an integer from 0 to 3;
L ₁ and L ₂ are each independently selected from the group consisting of a direct bond, a C ₆ to C ₁₈ arylene group and a heteroarylene group having 5 to 18 nucleus atoms;
Ar ₁ is selected from the group consisting of hydrogen, deuterium, halogen, cyano, nitro, C ₁ to C ₄₀ alkyl, C ₂ to C ₄₀ alkenyl, C ₂ to C ₄₀ alkynyl, C ₃ to C ₄₀ cycloalkyl, A cycloalkyl group having 3 to 40 nuclear atoms, an aryl group having ₆ to ₆₀ carbon atoms, a heteroaryl group having 5 to 60 nuclear atoms, a C ₁ to C ₄₀ alkyloxy group, a C ₆ to C ₆₀ aryloxy group , A C ₃ to C ₄₀ alkylsilyl group, a C ₆ to C ₆₀ arylsilyl group, a C ₁ to C ₄₀ alkylboron group, a C ₆ to C ₆₀ arylboron group, a C ₆ to C ₆₀ arylphosphate group, C ₆ ~ C ₆₀ mono or diaryl phosphine blood group and a C ₆ ~, or selected from the group consisting of C ₆₀ aryl amine, the combination group adjacent to form a condensed ring;
Ar ₂ is selected from the group consisting of a C ₆ to C ₃₀ aryl group and a heteroaryl group having 5 to 11 nuclear atoms;
R ₁ and R ₂ are each independently hydrogen, deuterium, a halogen, a cyano group, a nitro group, C ₁ ~ alkynyl group of C ₄₀ alkyl group, C ₂ ~ C ₄₀ alkenyl group, C ₂ ~ C ₄₀ of, C ₃ ~ C ₄₀ cycloalkyl group, a number of nuclear atoms of 3 to 40 heterocycloalkyl group, C ₆ ~ C ₆₀ aryl group, the number of nuclear atoms of 5 to 60 heteroaryl group, C ₁ ~ alkyloxy group of C _40, C ₆ ~ aryloxy group of C _60, C ₃ ~ C ₄₀ alkylsilyl group, C group ₆ ~ C ₆₀ aryl silyl, C ₁ ~ arylboronic of C ₄₀ group of an alkyl boron, C ₆ ~ C ₆₀ group, C ₆ ~ mono or diaryl phosphine of C ₆₀ aryl phosphazene group, C ₆ ~ C ₆₀ of the blood group and a C ₆ ~ C ₆₀ selected from the group consisting of an aryl amine or adjacent groups bond to which they are attached may form a fused ring, wherein When there are a plurality of R ₁ and R ₂ each, they are the same as or different from each other;
Wherein L _1, and arylene group of L ₂ and the hetero arylene group, said Ar ₂ in the aryl group and the heteroaryl group, the R _1, R ₂ and the alkyl group of Ar _1, an alkenyl group, an alkynyl group, an aryl group, heteroaryl group , An aryloxy group, an alkyloxy group, a cycloalkyl group, a heterocycloalkyl group, an arylamine group, an alkylsilyl group, an alkylboron group, an arylboron group, an arylphosphonyl group, a mono- or diarylphosphinyl group and an arylsilyl group are each independently A halogen atom, a cyano group, a nitro group, a C ₁ to C ₄₀ alkyl group, a C ₂ to C ₄₀ alkenyl group, a C ₂ to C ₄₀ alkynyl group, a C ₆ to C ₆₀ aryl group, to 60 heteroaryl group, C ₆ ~ aryloxy C _60, C ₁ ~ C ₄₀ alkyloxy group of, C ₆ ~ C ₆₀ aryl amine group, C ₃ ~ C ₄₀ cycloalkyl group, a nuclear atoms 3 to 40 heterocycloalkyl group, C ₁ ~ C ₄₀ alkyl silyl group, a boron alkyl of _{C 1 ~ C 40, C 6} ~ C ₆₀ aryl group of boron, C ₆ ~ C ₆₀ aryl phosphazene group, C Substituted with ₆ ~ C ₆₀ mono or diaryl phosphine blood group and one substituent at least one selected from the group consisting arylsilyl of C ₆ ~ C ₆₀ of or is unsubstituted, in the case where the substitution of a plurality of substituents, they are same or different, Do. The method according to claim 1,
Wherein said compound is represented by any one of the following Chemical Formulas 2 to 7:
(2)

(3)

[Chemical Formula 4]

[Chemical Formula 5]

[Chemical Formula 6]

(7)

In the above formulas 2 to 7
p is an integer from 0 to 9;
q is an integer from 0 to 11;
r is an integer from 0 to 7;
R ₃ is selected from the group consisting of hydrogen, deuterium, halogen, cyano, nitro, C ₁ to C ₄₀ alkyl, C ₂ to C ₄₀ alkenyl, C ₂ to C ₄₀ alkynyl, C ₃ to C ₄₀ cycloalkyl, A cycloalkyl group having 3 to 40 nuclear atoms, an aryl group having ₆ to ₆₀ carbon atoms, a heteroaryl group having 5 to 60 nuclear atoms, a C ₁ to C ₄₀ alkyloxy group, a C ₆ to C ₆₀ aryloxy group , A C ₃ to C ₄₀ alkylsilyl group, a C ₆ to C ₆₀ arylsilyl group, a C ₁ to C ₄₀ alkylboron group, a C ₆ to C ₆₀ arylboron group, a C ₆ to C ₆₀ arylphosphate group, C ₆ ~ C ₆₀ combines mono or diaryl phosphine blood group and a C ₆ ~ tile to selected or adjacent from the group consisting of an aryl amine of the C ₆₀ to which they are attached may form a fused ring of, when the R ₃ is a plurality individual They are the same or different from each other;
Alkyl group of the R _3, an alkenyl group, an alkynyl group, an aryl group, a heteroaryl group, an aryloxy group, an alkyloxy group, a cycloalkyl group, a heterocycloalkyl group, an arylamine group, an alkylsilyl group, an alkyl boron group, an aryl boron group, A halogen atom, a cyano group, a nitro group, a C ₁ to C ₄₀ alkyl group, a C ₂ to C ₄₀ alkenyl group, a C ₂ to C ₄₀ alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted aryl group, _A C ₆ to C ₆₀ aryl group, a heteroaryl group having 5 to 60 nuclear atoms, a C ₆ to C ₆₀ aryloxy group, a C ₁ to C ₄₀ alkyloxy group, a C ₆ to C ₆₀ C ₃ to C ₄₀ cycloalkyl groups, 3 to 40 nucleus atom heterocycloalkyl groups, C ₁ to C ₄₀ alkylsilyl groups, C ₁ to C ₄₀ alkylboron groups, C ₆ to C ₆₀ the arylboronic group, one member selected from the group consisting of C ₆ ~ C ₆₀ aryl phosphazene group, C ₆ ~ C ₆₀ mono or diaryl phosphine of blood group and a C ₆ ~ C ₆₀ aryl group in the silyl It substituted with a substituent being unsubstituted or, if substituted by a plurality of substituents, they are same or different to each other;
Each of R ₁ , R _2, m, n, L ₁ , L ₂ and Ar ₁ is as defined in claim ₁ . The method according to claim 1,
Wherein said compound is represented by any one of the following formulas (8) to (11):
[Chemical Formula 8]

[Chemical Formula 9]

[Chemical formula 10]

(11)

In the above formulas 8 to 11,
Each of R _1, R _2, m, n, L ₁ , L _2, Ar ₁ and Ar ₂ is as defined in claim 1. The method according to claim 1,
Each of R ₁ and R ₂ is independently selected from the group consisting of a C ₁ to C ₄₀ alkyl group, a C ₆ to C ₆₀ aryl group, and a heteroaryl group having 5 to 60 nuclear atoms,
The alkyl, aryl and heteroaryl groups of R ₁ and R ₂ are each independently selected from the group consisting of a C ₁ to C ₄₀ alkyl group, a C ₆ to C ₆₀ aryl group, and a heteroaryl group having 5 to 60 nuclear atoms. And when they are substituted with a plurality of substituents, they are the same as or different from each other. The method according to claim 1,
Wherein L ₁ and L ₂ are each independently a direct bond or a linker selected from the group consisting of the following formulas A-1 to A-4:

In the above Formulas A-1 to A-4,
* Means the part where the combination is made. The method according to claim 1,
Wherein Ar ₁ is selected from the group consisting of a C ₁ to C ₄₀ alkyl group, a C ₆ to C ₆₀ aryl group, and a heteroaryl group having 5 to 60 nuclear atoms,
The alkyl, aryl and heteroaryl groups of Ar ₁ are each independently substituted with at least one substituent selected from the group consisting of a C ₁ to C ₄₀ alkyl group, a C ₆ to C ₆₀ aryl group, and a heteroaryl group having 5 to 60 nuclear atoms And when they are substituted with a plurality of substituents, they are the same as or different from each other. The method according to claim 1,
Wherein Ar < ₁ > is a substituent represented by any one of the following general formulas (12) to (14):
[Chemical Formula 12]

[Chemical Formula 13]

[Chemical Formula 14]

In the above Formulas 12 to 14,
* Denotes the part where the bond is made;
Z ₁ to Z ₅ are each independently N or C (R ₄ );
k is an integer from 0 to 4;
R ₄ is selected from the group consisting of hydrogen, deuterium, halogen, cyano, nitro, C ₁ to C ₄₀ alkyl, C ₂ to C ₄₀ alkenyl, C ₂ to C ₄₀ alkynyl, C ₃ to C ₄₀ cycloalkyl, A cycloalkyl group having 3 to 40 nuclear atoms, an aryl group having ₆ to ₆₀ carbon atoms, a heteroaryl group having 5 to 60 nuclear atoms, a C ₁ to C ₄₀ alkyloxy group, a C ₆ to C ₆₀ aryloxy group , A C ₃ to C ₄₀ alkylsilyl group, a C ₆ to C ₆₀ arylsilyl group, a C ₁ to C ₄₀ alkylboron group, a C ₆ to C ₆₀ arylboron group, a C ₆ to C ₆₀ arylphosphate group, C ₆ ~ C ₆₀ mono or diaryl the Phosphinicosuccinic selected from the group the group consisting of C ₆ ~ with an aryl amine of the C ₆₀ or, by combining groups of neighboring case form a condensed ring, and individual said R ₄ is a plurality, they Are the same or different from each other;
R ₅ is hydrogen, deuterium, halogen, cyano, nitro, C ₁ to C ₄₀ alkyl, C ₂ to C ₄₀ alkenyl, C ₂ to C ₄₀ alkynyl, C ₃ to C ₄₀ cycloalkyl, A cycloalkyl group having 3 to 40 nuclear atoms, an aryl group having ₆ to ₆₀ carbon atoms, a heteroaryl group having 5 to 60 nuclear atoms, a C ₁ to C ₄₀ alkyloxy group, a C ₆ to C ₆₀ aryloxy group , A C ₃ to C ₄₀ alkylsilyl group, a C ₆ to C ₆₀ arylsilyl group, a C ₁ to C ₄₀ alkylboron group, a C ₆ to C ₆₀ arylboron group, a C ₆ to C ₆₀ arylphosphate group, C ₆ ~ C ₆₀ mono or diaryl the Phosphinicosuccinic selected from the group the group consisting of C ₆ ~ with an aryl amine of the C ₆₀ or, by combining groups of neighboring case to form a condensed ring, individual said R ₅ is plural, they Are the same or different from each other;
Alkyl groups of the R ₄ and R _5, an alkenyl group, an alkynyl group, an aryl group, a heteroaryl group, an aryloxy group, an alkyloxy group, a cycloalkyl group, a heterocycloalkyl group, an arylamine group, an alkylsilyl group, an alkyl boron group, an aryl A halogen atom, a cyano group, a nitro group, a C ₁ to C ₄₀ alkyl group, a C ₂ to C ₄₀ alkenyl group, a C ₂ to C ₄₀ alkenyl group, a C ₂ to C ₄₀ alkenyl group, ₂ ~ C ₄₀ alkynyl group, C ₆ ~ C ₆₀ aryl group, the number of nuclear atoms of 5 to 60 heteroaryl group, C ₆ ~ aryloxy C _60, C ₁ ~ alkyloxy group of C ₄₀ of, C ₆ ~ C ₆₀ arylamine group, C ₃ ~ C ₄₀ cycloalkyl group, a number of nuclear atoms of 3 to 40 heterocycloalkyl group, C ₁ ~ alkyl silyl group of C _40, C ₁ ~ C ₄₀ group of an alkyl boron, C ₆ ~ C ₆₀ aryl group of boron, C ₆ ~ C ₆₀ aryl phosphazene group, C ₆ ~ C ₆₀ mono or diaryl phosphine blood group and a C ₆ ~ C ₆₀ aryl silyl group selected from the group consisting of 1 And when they are substituted with a plurality of substituents, they are the same as or different from each other. 8. The method of claim 7,
Wherein the substituent represented by the formula (12) is a substituent represented by the following formula (15):
[Chemical Formula 15]

In Formula 15,
* Denotes the part where the bond is made;
R ₆ and R ₇ are each independently hydrogen, deuterium, a halogen, a cyano group, a nitro group, C ₁ ~ alkynyl group of C ₄₀ alkyl group, C ₂ ~ C ₄₀ alkenyl group, C ₂ ~ C ₄₀ of, C ₃ ~ C ₄₀ cycloalkyl group, a number of nuclear atoms of 3 to 40 heterocycloalkyl group, C ₆ ~ C ₆₀ aryl group, the number of nuclear atoms of 5 to 60 heteroaryl group, C ₁ ~ alkyloxy group of C _40, C ₆ ~ aryloxy group of C _60, C ₃ ~ C ₄₀ alkylsilyl group, C group ₆ ~ C ₆₀ aryl silyl, C ₁ ~ arylboronic of C ₄₀ group of an alkyl boron, C ₆ ~ C ₆₀ group, C ₆ ~ for C ₆₀ aryl phosphazene group, it said shed some light selected from the group consisting of an arylamine C ₆ ~ C ₆₀ mono or diaryl phosphine blood group and a C ₆ ~ C ₆₀ of;
Alkyl group of the R ₆ and R _7, an alkenyl group, an alkynyl group, an aryl group, a heteroaryl group, an aryloxy group, an alkyloxy group, a cycloalkyl group, a heterocycloalkyl group, an arylamine group, an alkylsilyl group, an alkyl boron group, an aryl A halogen atom, a cyano group, a nitro group, a C ₁ to C ₄₀ alkyl group, a C ₂ to C ₄₀ alkenyl group, a C ₂ to C ₄₀ alkenyl group, a C ₂ to C ₄₀ alkenyl group, ₂ ~ C ₄₀ alkynyl group, C ₆ ~ C ₆₀ aryl group, the number of nuclear atoms of 5 to 60 heteroaryl group, C ₆ ~ aryloxy C _60, C ₁ ~ alkyloxy group of C ₄₀ of, C ₆ ~ C ₆₀ arylamine group, C ₃ ~ C ₄₀ cycloalkyl group, a number of nuclear atoms of 3 to 40 heterocycloalkyl group, C ₁ ~ alkyl silyl group of C _40, C ₁ ~ C ₄₀ group of an alkyl boron, C ₆ ~ C ₆₀ aryl group of boron, C ₆ ~ C ₆₀ aryl phosphazene group, C ₆ ~ C ₆₀ mono or diaryl phosphine blood group and a C ₆ ~ C ₆₀ aryl silyl group selected from the group consisting of 1 When substituted with a plurality of substituents, they are the same as or different from each other;
Each of Z ₁ , Z ₃ and Z ₅ is as defined in claim 7. 8. The method of claim 7,
Wherein the substituent represented by the formula (12) is a substituent represented by any one of the following formulas (B-1) to (B-3):

In the above Formulas B-1 to B-3,
* Denotes the part where the bond is made,
R ₆ and R ₇ are each independently hydrogen, deuterium, a halogen, a cyano group, a nitro group, C ₁ ~ alkynyl group of C ₄₀ alkyl group, C ₂ ~ C ₄₀ alkenyl group, C ₂ ~ C ₄₀ of, C ₃ ~ C ₄₀ cycloalkyl group, a number of nuclear atoms of 3 to 40 heterocycloalkyl group, C ₆ ~ C ₆₀ aryl group, the number of nuclear atoms of 5 to 60 heteroaryl group, C ₁ ~ alkyloxy group of C _40, C ₆ ~ aryloxy group of C _60, C ₃ ~ C ₄₀ alkylsilyl group, C group ₆ ~ C ₆₀ aryl silyl, C ₁ ~ arylboronic of C ₄₀ group of an alkyl boron, C ₆ ~ C ₆₀ group, C ₆ ~ for C ₆₀ aryl phosphazene group, C ₆ ~ C ₆₀ mono or diaryl phosphine blood group and a C ₆ ~ is selected from the group consisting of an aryl amine of the C ₆₀ of the;
Alkyl group of the R ₆ and R _7, an alkenyl group, an alkynyl group, an aryl group, a heteroaryl group, an aryloxy group, an alkyloxy group, a cycloalkyl group, a heterocycloalkyl group, an arylamine group, an alkylsilyl group, an alkyl boron group, an aryl A halogen atom, a cyano group, a nitro group, a C ₁ to C ₄₀ alkyl group, a C ₂ to C ₄₀ alkenyl group, a C ₂ to C ₄₀ alkenyl group, a C ₂ to C ₄₀ alkenyl group, ₂ ~ C ₄₀ alkynyl group, C ₆ ~ C ₆₀ aryl group, the number of nuclear atoms of 5 to 60 heteroaryl group, C ₆ ~ aryloxy C _60, C ₁ ~ alkyloxy group of C ₄₀ of, C ₆ ~ C ₆₀ arylamine group, C ₃ ~ C ₄₀ cycloalkyl group, a number of nuclear atoms of 3 to 40 heterocycloalkyl group, C ₁ ~ alkyl silyl group of C _40, C ₁ ~ C ₄₀ group of an alkyl boron, C ₆ ~ C ₆₀ aryl group of boron, C ₆ ~ C ₆₀ aryl phosphazene group, C ₆ ~ C ₆₀ mono or diaryl phosphine blood group and a C ₆ ~ C ₆₀ aryl silyl group selected from the group consisting of 1 And when they are substituted with a plurality of substituents, they are the same as or different from each other. 10. The method of claim 9,
Each of R ₆ and R ₇ is independently selected from the group consisting of a C ₁ to C ₄₀ alkyl group, a C ₆ to C ₆₀ aryl group, and a heteroaryl group having 5 to 60 nuclear atoms;
The alkyl, aryl and heteroaryl groups of R ₆ and R ₇ are each independently selected from the group consisting of a C ₁ to C ₄₀ alkyl group, a C ₆ to C ₆₀ aryl group and a heteroaryl group having 5 to 60 nuclear atoms. And when they are substituted with a plurality of substituents, they are the same as or different from each other. 8. The method of claim 7,
Wherein the substituent represented by the formula (13) is a substituent represented by the following formula (C-1) or (C-2):

In the above formula (C-1) or (C-2)
* Denotes the part where the bond is made,
k, R < ₄ > and R < ₅ > are as defined in claim 7. 11. The method of claim 10,
Each of R ₄ and R ₅ is independently selected from the group consisting of a C ₁ to C ₄₀ alkyl group, a C ₆ to C ₆₀ aryl group, and a heteroaryl group having 5 to 60 nuclear atoms;
The alkyl, aryl and heteroaryl groups of R ₄ and R ₅ are each independently selected from the group consisting of a C ₁ to C ₄₀ alkyl group, a C ₆ to C ₆₀ aryl group and a heteroaryl group having 5 to 60 nuclear atoms. And when they are substituted with a plurality of substituents, they are the same as or different from each other. The method according to claim 1,
Wherein said compound is selected from the group consisting of:

1. An organic electroluminescent device comprising: (i) an anode, (ii) a cathode, and (iii) one or more organic layers sandwiched between the anode and the cathode,
Wherein at least one of the one or more organic layers includes a compound represented by the general formula (1). 15. The method of claim 14,
Wherein the organic material layer comprises at least one layer selected from the group consisting of a hole injection layer, a hole transport layer, a hole transporting auxiliary layer, an electron transporting layer, an electron transporting auxiliary layer and a light emitting layer.

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