KR20220136183A - Fiber processing agent composition of spray type - Google Patents

Fiber processing agent composition of spray type Download PDF

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KR20220136183A
KR20220136183A KR1020220037333A KR20220037333A KR20220136183A KR 20220136183 A KR20220136183 A KR 20220136183A KR 1020220037333 A KR1020220037333 A KR 1020220037333A KR 20220037333 A KR20220037333 A KR 20220037333A KR 20220136183 A KR20220136183 A KR 20220136183A
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component
fiber treatment
agent composition
treatment agent
mass
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KR1020220037333A
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Korean (ko)
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미와코 사이토
신 우메자와
히토미 코바야시
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라이온 가부시키가이샤
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144Alcohols; Metal alcoholates
    • D06M13/148Polyalcohols, e.g. glycerol or glucose
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/005Compositions containing perfumes; Compositions containing deodorants
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/165Ethers
    • D06M13/17Polyoxyalkyleneglycol ethers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/17Natural resins, resinous alcohols, resinous acids, or derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/06Processes in which the treating agent is dispersed in a gas, e.g. aerosols

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The present invention provides a spray type fiber processing agent composition which is excellent in usability as a spray agent, and can impart a skin moisturizing function to fiber products while suppressing stickiness. The fiber processing agent composition of the present invention is obtained by mixing (A) glycerin, and (B) at least one selected from the group consisting of polyethylene glycol, isoprene glycol and dipropylene glycol. The content of the component (A) is 20 to 50 mass% and the content of the component (B) is 5 to 20 mass% with respect to the total mass of the fiber processing agent composition.

Description

스프레이형의 섬유 처리제 조성물{FIBER PROCESSING AGENT COMPOSITION OF SPRAY TYPE}Spray-type fiber treatment agent composition {FIBER PROCESSING AGENT COMPOSITION OF SPRAY TYPE}

본 발명은, 스프레이형의 섬유 처리제 조성물에 관한 것이다.The present invention relates to a spray-type fiber treatment agent composition.

스프레이형의 섬유 처리제는, 다양한 제품이 발매되고, 그 시장은 연년이 확대하고 있다. 스프레이형의 섬유 처리제가 소구(訴求)하는 기능으로서는, 제균, 소취(消臭), 향기 부여나, 주름 제거 등이 일반적이지만, 착용시의 청량감(凉感) 부여 등의 새로운 기능을 소구하는 제품도 등장하고 있다.As for the spray-type fiber treatment agent, various products are released and the market is expanding every year. As a function of a spray-type textile treatment agent, sterilization, deodorization, fragrance imparting, wrinkle removal, etc. are common, but a product that appeals to new functions such as imparting a refreshing feeling when worn is also appearing.

다른 한편, 화장품 분야에서는, 피부의 보습을 소구한 화장품(보습 화장품)이 다수 발매되고 있다(특허 문헌 1∼3). 보습 화장품에 관해서는, 끈적거림을 억제하면서 보습 효과를 발휘시키기 위한 기술이 존재한다(특허 문헌 1 및 3).On the other hand, in the cosmetic field, many cosmetics (moisturizing cosmetics) that appeal to skin moisturizing are on the market (Patent Documents 1 to 3). Regarding moisturizing cosmetics, there is a technique for exhibiting a moisturizing effect while suppressing stickiness (Patent Documents 1 and 3).

특허 문헌 1 : 특개2010-6725호 공보Patent Document 1: Japanese Patent Laid-Open No. 2010-6725 특허 문헌 2 : 특개2008-266254호 공보Patent Document 2: Japanese Patent Laid-Open No. 2008-266254 특허 문헌 3 : 특개2000-256148호 공보Patent Document 3: Japanese Patent Laid-Open No. 2000-256148

섬유 제품에의 피부 보습 기능 부여라는 새로운 가치를 갖는 섬유 처리제를 개발함에 있어서 글리세린을 사용한 바, 섬유 제품에 피부 보습 기능을 부여할 수 있던 것이지만, (1) 처리된 섬유 제품에서 끈적거림이 발생하고, 또한 (2) 섬유 제품의 스프레이에 의한 균일 처리(균일한 분무)가 어려워 사용성에 뒤떨어진다는 과제가 발견되었다.When glycerin was used in developing a fiber treatment agent having a new value of imparting a skin moisturizing function to a textile product, it was possible to impart a skin moisturizing function to the textile product, but (1) stickiness occurs in the treated textile product, Furthermore, (2) the subject that the uniform process (uniform spraying) by the spray of textile products was difficult and was inferior to usability was discovered.

상기 과제를 예의 검토한 결과, 본 발명자는, 글리세린과 폴리에틸렌글리콜 및/또는 이소프렌글리콜을 특정량으로 조합시키면, 끈적거림의 발생을 억제하면서 피부 보습 기능을 섬유 제품에 부여할 수 있고, 또한, 균일한 분무도 가능해지는 것을 발견했다. 본 발명은, 이 지견에 의거하여 이루어진 것이다.As a result of earnestly examining the said subject, this inventor can provide a skin moisturizing function to a textile product, suppressing generation|occurrence|production of stickiness, when glycerol, polyethyleneglycol and/or isoprene glycol are combined in a specific amount, and also uniformly It was found that even a single spray was possible. The present invention has been made based on this knowledge.

즉, 본 발명은, 이하의 [1]∼[8]에 관한 것이다.That is, the present invention relates to the following [1] to [8].

[1] 스프레이형의 섬유 처리제 조성물로서,[1] A spray-type fiber treatment composition comprising:

(A) 글리세린과, (B) 폴리에틸렌글리콜, 이소프렌글리콜 및 디프로필렌글리콜로 이루어지는 군에서 선택되는 1종 이상을 포함하고,(A) glycerin, (B) containing one or more selected from the group consisting of polyethylene glycol, isoprene glycol and dipropylene glycol,

상기 섬유 처리제 조성물의 총질량에 대해, (A)성분의 함량이 20∼50질량%이고, (B)성분의 함량이 5∼20질량%인 것을 특징으로 하는, 섬유 처리제 조성물.Content of (A) component is 20-50 mass % with respect to the gross mass of the said fiber treatment agent composition, Content of (B) component is 5-20 mass %, The fiber treatment agent composition characterized by the above-mentioned.

[2] (C) 비이온 계면활성제를 더 포함하는, 상기 [1]에 기재된 섬유 처리제 조성물.[2] (C) The fiber treatment composition according to [1], further comprising a nonionic surfactant.

[3] (C)성분이, 폴리옥시에틸렌경화피마자유인, 상기 [2]에 기재된 섬유 처리제 조성물.[3] The fiber treatment agent composition according to [2], wherein the component (C) is polyoxyethylene hydrogenated castor oil.

[4] (D) 향료를 더 포함하는, 상기 [1]∼[3]의 어느 한 항에 기재된 섬유 처리제 조성물.[4] (D) The fiber treatment composition according to any one of [1] to [3], further comprising a fragrance.

[5] (A)성분의 함량이, 섬유 처리제 조성물의 총질량에 대해 30∼45질량%인, 상기 [1]∼[4]의 어느 한 항에 기재된 섬유 처리제 조성물.[5] The fiber treatment agent composition as described in any one of said [1]-[4] whose content of (A) component is 30-45 mass % with respect to the gross mass of a fiber treatment agent composition.

[6] (B)성분이, 수평균분자량이 200∼1000의 폴리에틸렌글리콜인, 상기 [1]∼[5]의 어느 한 항에 기재된 섬유 처리제 조성물.[6] The fiber treatment agent composition according to any one of [1] to [5], wherein the component (B) is polyethylene glycol having a number average molecular weight of 200 to 1000.

[7] (B)성분의 함량이, 섬유 처리제 조성물의 총질량에 대해 7∼15질량%인, 상기 [1]∼[6]의 어느 한 항에 기재된 섬유 처리제 조성물.[7] The fiber treatment agent composition as described in any one of said [1]-[6] whose content of (B) component is 7-15 mass % with respect to the gross mass of a fiber treatment agent composition.

[8] (A)성분과 (B)성분의 질량비(A/B)가 1∼10인, 상기 [1]∼[7]의 어느 한 항에 기재된 섬유 처리제 조성물.[8] The fiber treatment agent composition in any one of said [1]-[7] whose mass ratio (A/B) of (A) component and (B) component is 1-10.

후술하는 실시례에 나타내는 바와 같이, 본 발명의 섬유 처리제 조성물은, 스프레이제로서의 사용성에 우수하고, 또한, 끈적거림 발생을 억제하면서 피부 보습 기능을 섬유 제품에 부여할 수 있다. 따라서 본 발명은, 종래 제품에는 없는 부가가치를 갖는 스프레이형의 섬유 처리제를 제공할 수 있다.As shown in the Example mentioned later, the fiber treatment agent composition of this invention is excellent in usability as a spray agent, and can provide a skin moisturizing function to a textile product, suppressing stickiness generation|occurrence|production. Therefore, this invention can provide the spray-type fiber treatment agent which has the added value which conventional products do not have.

[(A)성분: 글리세린][(A) component: glycerin]

(A)성분은, 피부를 보습하는 기능(피부 보습성)을 섬유 제품에 부여하기 위해 배합한다.(A) A component is mix|blended in order to provide the function (skin moisturizing property) which moisturizes skin to a textile product.

(A)성분은 공지 물질이고, 시장에서 용이하게 입수 가능하거나, 또는 조제 가능하다.(A) A component is a well-known substance, it can obtain easily in a market, or can prepare it.

(A)성분의 함량은, 섬유 처리제 조성물의 총질량에 대해 20∼50질량%, 바람직하게는 30∼45질량%, 더욱 바람직하게는 35∼45질량%이다. (A)성분의 함량이 20질량% 이상이면 배합 목적을 달성할 수 있고, 50질량% 이하면, 처리된 섬유 제품에서의 끈적거림 발생의 억제와 균일한 분무를 달성할 수 있다.(A) Content of component is 20-50 mass % with respect to the gross mass of a fiber treatment agent composition, Preferably it is 30-45 mass %, More preferably, it is 35-45 mass %. (A) If the content of component is 20 mass % or more, the compounding objective can be achieved, and when it is 50 mass % or less, suppression of stickiness generation|occurrence|production in the treated textile product and uniform spraying can be achieved.

[(B)성분: 폴리에틸렌글리콜, 이소프렌글리콜 및 디프로필렌글리콜로 이루어지는 군에서 선택되는 1종 이상][(B) component: at least one selected from the group consisting of polyethylene glycol, isoprene glycol and dipropylene glycol]

(B)성분은, (A)성분을 단독으로 사용한 때에 일어나는 전술한 과제를 해결하기 위해 배합한다.(B) A component is mix|blended in order to solve the above-mentioned subject which arises when (A) component is used independently.

폴리에틸렌글리콜(PEG)은, 섬유 처리제 분야에서 공지의 것을 특히 제한 없이 사용할 수 있다. PEG의 수평균분자량은 특히 제한되지 않지만, 바람직하게는 200∼4000, 보다 바람직하게는 200∼1000, 더욱 바람직하게는 200∼600이다. 이 수평균분자량의 범위라면, 처리된 섬유 제품에서의 끈적거림 발생을 더욱 억제하고, 또한, 분무성을 더욱 향상시킬 수 있다.Polyethylene glycol (PEG), a well-known thing in the field of a fiber treatment agent can be used especially without limitation. Although the number average molecular weight of PEG is not specifically limited, Preferably it is 200-4000, More preferably, it is 200-1000, More preferably, it is 200-600. If it is this number average molecular weight range, generation|occurrence|production of stickiness in the treated textile product can be suppressed further and sprayability can further be improved.

PEG의 수평균분자량은, HPLC법에 따라 측정할 수 있다.The number average molecular weight of PEG can be measured according to HPLC method.

PEG는, 단일 종류를 사용해도 좋고, 복수 종류를 병용해도 좋다.A single type may be used for PEG, and may use multiple types together.

이소프렌글리콜(IPG)(이소펜틸디올이라고도 칭해진다)는, 섬유 처리제에 배합하는 것을 특히 제한 없이 사용할 수 있다.Isoprene glycol (IPG) (also referred to as isopentyldiol) can be used without any particular limitation when blended with a fiber treatment agent.

IPG는, 단일 종류를 사용해도 좋고, 복수 종류를 병용해도 좋다.A single type may be used for IPG, and may use multiple types together.

디프로필렌글리콜(DPG)는, 섬유 처리제에 배합하는 것을 특히 제한 없이 사용할 수 있다.As for dipropylene glycol (DPG), what mix|blends with a fiber treatment agent can be used especially without restriction|limiting.

DPG는, 단일 종류를 사용해도 좋고, 복수 종류를 병용해도 좋다.A single type may be used for DPG, and may use multiple types together.

(B)성분은 공지 물질이고, 시장에서 용이하게 입수 가능하거나, 또는 조제 가능하다.(B) A component is a well-known substance, it can obtain easily in a market, or can prepare it.

(B)성분은 단일 종류를 사용해도 좋고, 복수 종류를 병용(예를 들면, PEG와 IPG의 병용)해도 좋다.(B) A component may use a single type and may use multiple types together (for example, combined use of PEG and IPG).

(B)성분의 함량은, 섬유 처리제 조성물의 총질량에 대해 5∼20질량%, 바람직하게는 7∼15질량%, 더욱 바람직하게는 8∼13질량%이다. (B)성분의 함량이 5질량% 이상이면, 처리된 섬유 제품에서의 끈적거림의 발생을 억제할 수 있고, 20질량% 이하면 균일한 분무를 달성할 수 있다.(B) Content of component is 5-20 mass % with respect to the gross mass of a fiber treatment agent composition, Preferably it is 7-15 mass %, More preferably, it is 8-13 mass %. (B) Generation|occurrence|production of stickiness in the processed textile product as content of component is 5 mass % or more can be suppressed, and uniform spraying can be achieved if it is 20 mass % or less.

[(A)성분과 (B)성분과의 배합 비율][The blending ratio of (A) component and (B) component]

(A)성분과 (B)성분의 질량비(A/B)는, 바람직하게는 1∼10, 더욱 바람직하게는 2∼6, 특히 바람직하게는 3∼6이다. 상기한 질량비 범위라면 더욱 우수한 보습 효과와 끈적거림 발생 억제성이 얻어진다.(A) Mass ratio (A/B) of component and (B) component becomes like this. Preferably it is 1-10, More preferably, it is 2-6, Especially preferably, it is 3-6. If it is in the above mass ratio range, further excellent moisturizing effect and stickiness generation suppression are obtained.

[임의 성분][Optional Ingredients]

섬유 처리제 조성물에는, 본 발명의 효과를 손상시키지 않는 범위에서, 하기한 임의 성분을 배합해도 좋다.You may mix|blend the following arbitrary components with a fiber treatment agent composition in the range which does not impair the effect of this invention.

[(C)성분: 비이온 계면활성제][(C) component: nonionic surfactant]

(C)성분은, 섬유 처리제 조성물의 안정성(구체적으로는, 분산 안정성)을 향상시키기 위해 배합한다.(C) A component is mix|blended in order to improve stability (specifically, dispersion stability) of a fiber treatment agent composition.

비이온 계면활성제로서는, 섬유 처리제 분야에서 공지의 물질을 특히 제한 없이 사용할 수 있다. 예로서는, 폴리옥시에틸렌모노스테아레이트, 폴리옥시에틸렌모노팔미테이트, 폴리옥시에틸렌모노미리스테이트, 폴리옥시에틸렌디스테아레이트, 폴리옥시에틸렌디팔미테이트, 폴리옥시에틸렌디미리스테이트, 폴리옥시에틸렌트리스테아레이트, 폴리옥시에틸렌트리팔미테이트, 폴리옥시에틸렌트리미리스테이트, 모노스테아린산폴리에틸렌글리콜, 모노스테아린산폴리옥시에틸렌소르비탄, 모노팔미틴산폴리옥시에틸렌소르비탄, 모노미리스틴산폴리옥시에틸렌소르비탄, 모노라우린산폴리옥시에틸렌소르비탄, 디스테아린산폴리옥시에틸렌소르비탄, 디팔미틴산폴리옥시에틸렌소르비탄, 디미리스틴산폴리옥시에틸렌소르비탄, 디라우린산폴리옥시에틸렌소르비탄, 트리스테아린산폴리옥시에틸렌소르비탄, 트리팔미틴산폴리옥시에틸렌소르비탄, 트리미리스틴산폴리옥시에틸렌소르비탄, 트리라우린산폴리옥시에틸렌소르비탄, 테트라올레인산폴리옥시에틸렌소르비트, 모노라우린산폴리옥시에틸렌소르비트, 폴리옥시에틸렌경화피마자유, 폴리옥시에틸렌폴리옥시프로필렌세틸에테르, 모노스테아린산폴리글리세릴, 모노올레인산폴리글리세릴, 디스테아린산폴리글리세릴, 트리이소스테아린산폴리옥시에틸렌글리세릴, 이소스테아린산폴리옥시에틸렌글리세릴, 트리스테아린산데카글리세릴, 트리올레인산폴리글리세릴이나, 폴리옥시에틸렌·메틸폴리실록산 공중합체 등을 들 수 있다.As the nonionic surfactant, substances known in the field of fiber treatment agents can be used without particular limitation. Examples include polyoxyethylene monostearate, polyoxyethylene monopalmitate, polyoxyethylene monomyristate, polyoxyethylene distearate, polyoxyethylene dipalmitate, polyoxyethylene dimyristate, polyoxyethylene tristearate , polyoxyethylene tripalmitate, polyoxyethylene trimyristate, polyethylene glycol monostearate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monopalmitate, polyoxyethylene sorbitan monomyristate, monolauric acid Polyoxyethylene sorbitan, distearic acid polyoxyethylene sorbitan, dipalmitate polyoxyethylene sorbitan, dimyristate polyoxyethylene sorbitan, dilaurate polyoxyethylene sorbitan, tristearate polyoxyethylene sorbitan, tristearate Palmitate polyoxyethylene sorbitan, trimyristate polyoxyethylene sorbitan, trilaurate polyoxyethylene sorbitan, tetraoleate polyoxyethylene sorbit, monolaurate polyoxyethylene sorbit, polyoxyethylene hydrogenated castor Free, polyoxyethylene polyoxypropylene cetyl ether, polyglyceryl monostearate, polyglyceryl monooleate, polyglyceryl distearate, polyoxyethylene glyceryl triisostearate, polyoxyethylene glyceryl isostearate, decaglyceryl tristearate Reel, polyglyceryl trioleate, polyoxyethylene-methylpolysiloxane copolymer, etc. are mentioned.

(C)성분으로서는, 폴리옥시에틸렌경화피마자유가 바람직하고, 그 중에서도, 에틸렌옥시드(EO)의 평균부가몰수가 20∼100, 바람직하게는 40∼60의 폴리옥시에틸렌경화피마자유가 더욱 바람직하다.(C) As a component, polyoxyethylene hydrogenated castor oil is preferable, Especially, the average added mole number of ethylene oxide (EO) is 20-100, Preferably the polyoxyethylene hydrogenated castor oil of 40-60 is still more preferable.

(C)성분은 공지 물질이고, 시장에서 용이하게 입수 가능하거나, 또는 조제 가능하다.(C) A component is a well-known substance, it can obtain easily in a market, or can prepare it.

(C)성분은 단일 종류를 사용해도 좋고, 복수 종류를 병용해도 좋다.(C) A component may use a single type and may use multiple types together.

(C)성분의 함량은, 배합 목적을 달성할 수 있는 양인 한 특히 한정되지 않지만, 섬유 처리제 조성물의 총질량에 대해, 바람직하게는 0.1∼10질량%, 더욱 바람직하게는 0.5∼5질량%이다. 상기한 함량 범위라면 보다 높은 배합 효과를 얻을 수 있다.(C) Although content of component is although it does not specifically limit as long as it is quantity which can achieve the compounding objective, With respect to the total mass of a fiber treatment agent composition, Preferably it is 0.1-10 mass %, More preferably, it is 0.5-5 mass %. . If it is in the above content range, a higher compounding effect can be obtained.

[(D)성분: 향료][(D)Ingredient: Fragrance]

(D)성분은, 섬유 처리제 조성물 자체의 향기 부여, 및/또는, 동 조성물에 의한 처리 후의 섬유 제품의 향기 부여를 위해 배합한다.(D) A component is mix|blended for fragrance provision of fiber processing agent composition itself, and/or fragrance provision of the textile product after the process by the same composition.

(D)성분으로서는, 섬유 처리제 분야에서 공지의 물질을 특히 제한 없이 사용할 수 있는데, 사용할 수 있는 향료 원료의 리스트는, 다양한 문헌, 예를 들면 「Perfume and Flavor Chemicals」, Vol. I and Ⅱ, Steffen Arctander, Allured Pub. Co.(1994) 및 「합성향료 화학과 상품 지식」, 인도우모토이치저, 화학공업일보사(1996) 및 「Perfume and Flavor Materials of Natural Origin」, Steffen Arctander, Allured Pub. Co.(1994) 및 「향기의 백과」, 일본향료협회편, 아사쿠라서점(1989) 및 「Perfumery Material Performance V. 3.3」, Boelens Aroma Chemical Information Service(1996) 및 「Flower oils and Floral Compounds In Perfumery」, Danute Lajaujis Anonis, Allured Pub. Co.(1993) 등에 기재되어 있다.(D) As a component, although a well-known substance in the field of a fiber treatment agent can be used without restriction|limiting in particular, The list of the fragrance|flavor raw material which can be used is various documents, for example, "Perfume and Flavor Chemicals", Vol. I and II, Steffen Arctander, Allured Pub. Co. (1994) and 「Synthetic Fragrance Chemistry and Product Knowledge」, Ichiji Indo, Chemical Industry Daily (1996) and 「Perfume and Flavor Materials of Natural Origin」, Steffen Arctander, Allured Pub. Co. (1994) and 「Encyclopedia of Fragrance」, edited by the Japanese Perfume Association, Asakura Branch (1989) and 「Perfumery Material Performance V. 3.3」, Boelens Aroma Chemical Information Service (1996) and 「Flower oils and Floral Compounds In Perfumery」 , Danute Lajaujis Anonis, Allured Pub. Co. (1993) et al.

(D)성분은 단일 종류를 사용해도 좋고, 복수 종류를 병용한 향료 조성물로서 사용해도 좋다.(D) A component may use a single type, and may use it as a fragrance|flavor composition which used multiple types together.

(D)성분의 함량은, 배합 목적을 달성할 수 있는 양인 한 특히 한정되지 않지만, 섬유 처리제 조성물의 총질량에 대해, 바람직하게는 0.01∼1질량%, 더욱 바람직하게는 0.05∼0.5질량%이다.(D) Although content of component is not specifically limited as long as it is the quantity which can achieve the compounding objective, With respect to the total mass of a fiber treatment agent composition, Preferably it is 0.01-1 mass %, More preferably, it is 0.05-0.5 mass %. .

[(C)성분 이외의 안정화제][stabilizers other than (C)component]

안정화제는, 섬유 처리제 조성물의 안정성(구체적으로는, 방부 성능)을 향상시키기 위해 배합한다. (C)성분 이외의 안정화제로서는, 섬유 처리제 분야에서 공지의 물질을 특히 제한 없이 사용할 수 있다. 예로서는, 안식향산나트륨, 구연산이나, 페녹시에탄올 등을 들 수 있다.A stabilizer is mix|blended in order to improve stability (specifically, antiseptic|preservative performance) of a fiber treatment agent composition. (C) As a stabilizer other than component, a well-known substance in the field|area of a fiber treatment agent can be used especially without a restriction|limiting. As an example, sodium benzoate, citric acid, phenoxyethanol, etc. are mentioned.

안정화제는 공지 물질이고, 시장에서 용이하게 입수 가능하거나, 또는 조제 가능하다.Stabilizers are known substances and are readily available on the market or can be prepared.

안정화제는 단일 종류를 사용해도 좋고, 복수 종류를 병용해도 좋다.A single type may be used for a stabilizer, and may use multiple types together.

안정화제의 함량은, 배합 목적을 달성할 수 있는 양인 한 특히 한정되지 않지만, 섬유 처리제 조성물의 총질량에 대해, 바람직하게는 0.2∼5질량%, 더욱 바람직하게는 0.5∼2질량%이다.Although content of a stabilizer is not specifically limited as long as it is the quantity which can achieve the compounding objective, With respect to the total mass of a fiber treatment agent composition, Preferably it is 0.2-5 mass %, More preferably, it is 0.5-2 mass %.

[휘발성 알코올][Volatile Alcohol]

휘발성 알코올은, 섬유 제품에 분무된 후의 건조성을 향상시키기 위해 배합한다.Volatile alcohol is blended to improve drying properties after spraying on textile products.

휘발성 알코올로서는, 섬유 처리제 분야에서 공지의 물질을 특히 제한 없이 사용할 수 있다. 예로서는, 탄소수 1∼3(바람직하게는 1∼2)의 알코올을 들 수 있고, 그 중에서도 에탄올이 바람직하다.As the volatile alcohol, substances known in the field of textile treatment agents can be used without particular limitation. As an example, C1-C3 (preferably 1-2) alcohol is mentioned, Especially, ethanol is preferable.

휘발성 알코올은 공지 물질이고, 시장에서 용이하게 입수 가능하거나, 또는 조제 가능하다.Volatile alcohols are known substances and are readily available on the market or can be prepared.

휘발성 알코올은 단일 종류를 사용해도 좋고, 복수 종류를 병용해도 좋다.A single type may be used for a volatile alcohol, and may use multiple types together.

휘발성 알코올의 함량은, 배합 목적을 달성할 수 있는 양인 한 특히 한정되지 않지만, 섬유 처리제 조성물의 총질량에 대해, 바람직하게는 1∼20질량%, 더욱 바람직하게는 5∼10질량%이다.Although content of a volatile alcohol is not specifically limited as long as it is the quantity which can achieve the compounding objective, With respect to the total mass of a fiber treatment agent composition, Preferably it is 1-20 mass %, More preferably, it is 5-10 mass %.

[소취(消臭) 성분][Deodorant (消臭) ingredients]

소취 성분은, 섬유 제품에 소취성을 부여하기 위해 배합한다.A deodorizing component is mix|blended in order to provide deodorizing property to a textile product.

소취 성분으로서는, 섬유 처리제 분야에서 공지의 물질을 특히 제한 없이 사용할 수 있다. 예로서는, 고도분기 환상덱스트린(예를 들면, 글리코 영양식품주식회사제 상품명: 클러스터덱스트린)), 메틸글리신디아세트산3나트륨, 산화아연, 산화마그네슘, 폴리페놀이나, 플라보노이드를 포함하는 천연물(녹차 엑기스) 등을 들 수 있다.As the deodorizing component, a substance known in the field of fiber treatment agents can be used without particular limitation. Examples include highly branched cyclic dextrin (eg, Glyco Nutrition Foods Co., Ltd. trade name: Clusterdextrin), methylglycine diacetate trisodium, zinc oxide, magnesium oxide, polyphenols, natural products containing flavonoids (green tea extract), etc. can be heard

소취 성분은 공지 물질이고, 시장에서 용이하게 입수 가능하거나, 또는 조제 가능하다.The deodorizing component is a known substance and is readily available in the market or can be prepared.

소취 성분은 단일 종류를 사용해도 좋고, 복수 종류를 병용해도 좋다.A single type may be used for a deodorizing component, and may use multiple types together.

소취 성분의 함량은, 배합 목적을 달성할 수 있는 양인 한 특히 한정되지 않지만, 섬유 처리제 조성물의 총질량에 대해, 바람직하게는 0.1∼3질량%, 더욱 바람직하게는 0.1∼1.5질량%이다.Although the content of a deodorizing component is not specifically limited as long as it is the quantity which can achieve the compounding objective, With respect to the total mass of a fiber treatment agent composition, Preferably it is 0.1-3 mass %, More preferably, it is 0.1-1.5 mass %.

[항균 성분][Antibacterial ingredient]

항균 성분은, 처리된 섬유 제품성에서의 세균의 증식을 억제하여, 불쾌취의 발생을 억제하기 위해 배합한다.The antibacterial component is blended in order to suppress the growth of bacteria in the treated textile properties and to suppress the occurrence of unpleasant odors.

항균 성분으로서는, 섬유 처리제 분야에서 공지의 물질을 특히 제한 없이 사용할 수 있다. 예로서는, 유기계 방균 방미제나 무기계 방균 방미제 등을 들 수 있다. 유기계 방균 방미제의 예로서는, 알코올계, 페놀계(예를 들면, 이소프로필메틸페놀), 알데히드계, 카르본산계, 에스테르계, 에테르계, 니트릴계, 과산화물·에폭시계, 할로겐계, 피리딘·퀴놀린계, 트리아진계, 이소티아졸론계, 이미다졸·티아졸계, 아닐리드계, 비구아나이드계, 디술피드계, 티오카르바메이트계, 당질계, 트로폴론계, 유기금속계의 것을 들 수 있다. 무기계 방균 방미제의 예로서는, 금속 산화물이나, 은계(銀系)의 것을 들 수 있다.As the antibacterial component, substances known in the field of textile treatment agents can be used without particular limitation. Examples include organic antibacterial and antifungal agents and inorganic antibacterial and antifungal agents. Examples of organic antibacterial and mildew inhibitors include alcohol, phenol (eg, isopropylmethylphenol), aldehyde, carboxylic acid, ester, ether, nitrile, peroxide/epoxy, halogen, pyridine/quinoline and triazine-based, isothiazolone-based, imidazole/thiazole-based, anilide-based, biguanide-based, disulfide-based, thiocarbamate-based, carbohydrate-based, tropolone-based, and organometallic compounds. As an example of an inorganic type antibacterial and antifungal agent, a metal oxide and a silver type thing are mentioned.

항균 성분은, 시장에서 용이하게 입수 가능하거나, 또는 조제 가능하다.The antibacterial component is readily available in the market or can be prepared.

항균 성분은 단일 종류를 사용해도 좋고, 복수 종류를 병용해도 좋다.A single type may be used for an antibacterial component, and may use multiple types together.

항균 성분의 함량은, 배합 목적을 달성할 수 있는 양인 한 특히 한정되지 않지만, 섬유 처리제 조성물의 총질량에 대해, 바람직하게는 0.05∼1질량%, 더욱 바람직하게는 0.1∼0.7질량%이다.Although content of an antibacterial component is not specifically limited as long as it is the quantity which can achieve the compounding objective, With respect to the total mass of a fiber treatment agent composition, Preferably it is 0.05-1 mass %, More preferably, it is 0.1-0.7 mass %.

[물(水)][Water]

섬유 처리제 조성물은, 바람직하게는 물을 포함하는 수성 조성물이다.The fiber treatment agent composition is preferably an aqueous composition containing water.

물로서는 수도물, 이온교환수, 순수나 증류수 등을 사용할 수 있는데, 이온교환수가 바람직하다.Although tap water, ion-exchanged water, pure water, distilled water, etc. can be used as water, ion-exchange water is preferable.

물의 함량은 특히 한정되지 않지만, 섬유 처리제 조성물의 총질량에 대해, 바람직하게는 10질량% 이상, 더욱 바람직하게는 40질량% 이상이다. 함량이 40질량% 이상이면, 사용성이 보다 양호해진다.Although content of water is not specifically limited, Preferably it is 10 mass % or more with respect to the gross mass of a fiber treatment agent composition, More preferably, it is 40 mass % or more. Usability becomes more favorable that content is 40 mass % or more.

[기타의 임의 성분][Other optional ingredients]

상기한 임의 성분 이외에도, 섬유 처리제나 화장료에 배합 가능한 공지의 성분을 적절히 배합할 수 있다. 예로서는, 기능성 성분(실리콘(섬유 제품의 촉감 향상), 액취(腋臭) 방지제, 항여드름제, 미백제, 각질 연화제 등), pH 완충제, 자외선 흡수제, 유기 용제, 방부제, 킬레이트제, 재오염 방지제, 고분자, 방곰팡이제, 기피제, 천연물 등의 엑기스, 분산제나 , 산화방지제 등을 들 수 있다.A well-known component which can be mix|blended with a fiber treatment agent and cosmetics other than said arbitrary component can be mix|blended suitably. Examples include functional ingredients (silicone (improving the texture of textile products), odor control agent, anti-acne agent, whitening agent, keratin emollient, etc.), pH buffer, UV absorber, organic solvent, preservative, chelating agent, anti-redeposition agent, polymer , fungicides, repellents, extracts such as natural products, dispersants, antioxidants, and the like.

[섬유 처리제 조성물의 pH][PH of Textile Treatment Agent Composition]

섬유 처리제 조성물의 pH는 특히 한정되지 않지만, 보존 안정성의 관점에서, 25℃에서의 pH를, 바람직하게는 4.5∼7, 더욱 바람직하게는 5∼6의 범위로 조정한다. pH는, 공지의 pH 조정제(예를 들면, 구연산 등)의 첨가에 의해 조정할 수 있다.Although the pH of a fiber treatment agent composition is not specifically limited, From a viewpoint of storage stability, pH in 25 degreeC becomes like this. Preferably it is 4.5-7, More preferably, it adjusts to the range of 5-6. pH can be adjusted by addition of a well-known pH adjuster (for example, citric acid etc.).

pH는, pH 미터(예를 들면, Mettler Toledo사제 형번 MP230)로 측정할 수 있다.The pH can be measured with a pH meter (eg, model number MP230 manufactured by Mettler Toledo).

[제조 방법][Manufacturing method]

제조 방법에 특히 제한은 없고, (A)성분과 (B)성분을 혼합함으로써 섬유 처리제 조성물을 제조할 수 있다.There is no restriction|limiting in particular in a manufacturing method, A fiber processing agent composition can be manufactured by mixing (A) component and (B) component.

예를 들면, (C)성분 및 (D)성분을 물에 첨가하여 혼합하고, 또한 (A)성분 및 (B)성분을 첨가하여 혼합하고, 필요에 의해 다른 임의 성분을 첨가하여 혼합한 후, pH를 조정하고, 밸런스량의 물을 첨가함으로써, 섬유 처리제 조성물을 제조할 수 있다.For example, after adding and mixing (C)component and (D)component to water, adding and mixing (A)component and (B)component further, adding and mixing another arbitrary component as needed, A fiber treatment agent composition can be manufactured by adjusting pH and adding a balance amount of water.

[사용 방법][How to use]

섬유 처리제 조성물은, 종래의 스프레이형의 섬유 처리제와 마찬가지로 사용할 수 있는데, 분무 기구를 갖는 용기(스프레이 용기)로부터 섬유 제품에 분무하여 사용하는 방법이 바람직하다.Although a fiber treatment agent composition can be used similarly to the conventional spray type fiber treatment agent, the method of spraying and using to textile products from the container (spray container) which has a spray mechanism is preferable.

스프레이 용기로서는, 트리거 스프레이 용기(직압형 또는 축압형)나, 디스펜서 스프레이 용기 등을 들 수 있다. 트리거 스프레이 용기의 예는, 특개평9-268473호 공보, 특개평9-256272호 공보나, 특개평10-76196호 공보 등에 기재되어 있다. 디스펜서 스프레이 용기의 예는, 특개평9-256272호 공보 등에 기재되어 있다.As a spray container, a trigger spray container (direct pressure type or accumulating pressure type), a dispenser spray container, etc. are mentioned. Examples of the trigger spray container are described in Japanese Patent Application Laid-Open Nos. Hei 9-268473, Hei 9-256272, and Hei 10-76196. An example of a dispenser spray container is described in Japanese Patent Application Laid-Open No. 9-256272 or the like.

섬유 처리제 조성물은, 분무기구를 갖지 않는 플라스틱제 용기(보틀 용기나 갈아 채움용의 스탠딩 파우치 등)에 수납되어 있어도 좋다. 스탠딩 파우치의 예는, 특개2000-72181호 공보 등에 기재되어 있다. 스탠딩 파우치는, 섬유 처리제 조성물의 보존 안정성의 관점에서, 2층 구조(내층: 100∼250㎛의 선상(線狀) 저밀도 폴리에틸렌. 외층: 15∼30㎛의 연신 나일론) 또는 3층 구조(내층: 100∼250㎛의 선상 저밀도 폴리에틸렌. 중간층: 15㎛의 연신 나일론. 외층: 15㎛의 연신 나일론)를 갖는 것이 바람직하다.The fiber treatment agent composition may be accommodated in a plastic container (a bottle container, a standing pouch for refilling, etc.) which does not have a spray mechanism. An example of a standing pouch is described in Japanese Patent Application Laid-Open No. 2000-72181 or the like. The standing pouch has a two-layer structure (inner layer: 100-250 µm linear low-density polyethylene, outer layer: 15-30 µm stretched nylon) or a three-layer structure (inner layer: It is preferable to have a linear low-density polyethylene of 100 to 250 µm, an intermediate layer: stretched nylon of 15 µm, and an outer layer: stretched nylon of 15 µm).

처리되는 섬유 제품의 종류는 특히 한정되지 않는다. 섬유 제품의 예로서는, Y셔츠, T셔츠, 폴로셔츠, 블라우스, 속옷, 이너(기능성 이너를 포함한다), 치노 팬츠, 슈트, 슬랙스, 스커트, 스타킹, 타이츠, 재킷, 코트, 니트, 진스, 파자마, 쿠션, 방석(座布團), 소파, 베개 커버, 시트, 베드 패드, 베개, 이불, 베드 커버 , 모포, 매트리스, 천 마스크나, 신발 등을 들 수 있다. 그 중에서도, 피부에 직접 접촉하는 속옷이나 이너류에서는 섬유 처리제 조성물의 효과가 현저하게 발현된다.The type of textile product to be treated is not particularly limited. Examples of textile products include Y-shirts, T-shirts, polo shirts, blouses, underwear, inners (including functional inners), chino pants, suits, slacks, skirts, stockings, tights, jackets, coats, knits, jeans, pajamas, cushions, cushions, sofas, pillow covers, sheets, bed pads, pillows, duvets, bed covers, blankets, mattresses, cloth masks, and shoes. Among them, the effect of the fiber treatment composition is remarkably expressed in underwear and inners that come into direct contact with the skin.

섬유 제품의 소재도 특히 한정되지 않는다. 소재의 예로서는, 천연 섬유(면, 울, 마(麻) 등), 합성 섬유(폴리에스테르, 나일론, 아크릴 등), 반합성 섬유(아세테이트 등), 재생 섬유(레이온, 텐셀, 폴리노직 등), 이들의 혼방품, 혼직품이나, 혼편품 등을 들 수 있다.The material of the textile product is not specifically limited, either. Examples of the material include natural fibers (cotton, wool, hemp, etc.), synthetic fibers (polyester, nylon, acrylic, etc.), semi-synthetic fibers (acetate, etc.), regenerated fibers (rayon, tencel, polynosic, etc.), these blended products, mixed weave products, mixed knit products, and the like.

[실시례][Example]

이하, 실시례에 의해 본 발명을 더욱 상세히 설명하지만, 본 발명은 이것으로 한정되는 것이 아니다.Hereinafter, although an Example demonstrates this invention further in detail, this invention is not limited to this.

또한, 실시례 및 비교례에서, 각 성분의 배합량(%)은 전부 질량%(지정이 있는 경우를 제외하고, 순분 환산)를 나타낸다.In addition, in an Example and a comparative example, the compounding quantity (%) of each component shows all mass % (except when there exists a designation, conversion of pure part).

[(A)성분][(A) component]

하기한 A-1을 사용했다.The following A-1 was used.

A-1: 글리세린(상품명: 화장품용 글리세린(85질량%). 사카모토약품공업(주)제)A-1: glycerin (brand name: glycerin for cosmetics (85 mass %) manufactured by Sakamoto Pharmaceutical Co., Ltd.)

[(B)성분][(B) component]

하기한 B-1∼B-7을 사용했다. B-1∼B-4의 PEG의 수평균분자량은, HPLC법에 따라 측정한 값이다.The following B-1 to B-7 were used. The number average molecular weights of the PEGs of B-1 to B-4 are values measured according to the HPLC method.

B-1: 수평균분자량이 200의 PEG(상품명: PEG-200. 산요화성공업(주)제)B-1: PEG having a number average molecular weight of 200 (trade name: PEG-200, manufactured by Sanyo Chemical Industry Co., Ltd.)

B-2: 수평균분자량이 400의 PEG(상품명: PEG-400. 산요화성공업(주)제)B-2: PEG having a number average molecular weight of 400 (trade name: PEG-400, manufactured by Sanyo Chemical Industry Co., Ltd.)

B-3: 수평균분자량이 600의 PEG(상품명: PEG-600. 산요화성공업(주)제)B-3: PEG having a number average molecular weight of 600 (trade name: PEG-600, manufactured by Sanyo Chemical Industry Co., Ltd.)

B-4: 수평균분자량이 1000의 PEG(상품명: PEG-1000. 산요화성공업(주)제)B-4: PEG having a number average molecular weight of 1000 (trade name: PEG-1000, manufactured by Sanyo Chemical Industry Co., Ltd.)

B-5: 이소프렌글리콜 ((주)쿠라레제)B-5: isoprene glycol (Kurarese Co., Ltd.)

B-6: 디프로필렌글리콜(아사히유리(주)제)B-6: dipropylene glycol (manufactured by Asahi Glass Co., Ltd.)

B-7: 1,3-부틸렌글리콜((주)다이셀제)(비교례에서 사용)B-7: 1,3-butylene glycol (manufactured by Daicel Co., Ltd.) (used in comparative example)

[(C)성분][(C)component]

하기한 C-1∼C-2를 사용했다.The following C-1 to C-2 were used.

C-1: EO의 평균부가몰수가 40인 폴리옥시에틸렌경화피마자유(상품명: 부라우논RCW-40. 아오키유지(주)제)C-1: Polyoxyethylene hydrogenated castor oil having an average added mole number of EO of 40 (trade name: Burunon RCW-40, manufactured by Aoki Oil Co., Ltd.)

C-2: EO의 평균부가몰수가 60인 폴리옥시에틸렌경화피마자유(상품명: 부라우논RCW-60. 아오키유지(주)제)C-2: Polyoxyethylene hydrogenated castor oil having an average added mole number of EO of 60 (trade name: Burunon RCW-60, manufactured by Aoki Oil Co., Ltd.)

[(D)성분: 향료][(D)Ingredient: Fragrance]

하기 표에 표시된 조성을 갖는 향료 조성물 D-1∼D-7을 사용했다. 표 중의 각 향료 성분의 수치는, 향료 조성물의 총질량에 대한 질량%이다.Fragrance compositions D-1 to D-7 having the compositions shown in the table below were used. The numerical value of each fragrance|flavor component in a table|surface is mass % with respect to the total mass of a fragrance|flavor composition.

Figure pat00001
Figure pat00001

Figure pat00002
Figure pat00002

Figure pat00003
Figure pat00003

Figure pat00004
Figure pat00004

Figure pat00005
Figure pat00005

Figure pat00006
Figure pat00006

Figure pat00007
Figure pat00007

[기타의 성분][Other ingredients]

하기한 공통 성분 A∼B를 사용했다. 표 중의 함량은, 액체 유연제 조성물의 총질량에 대한 값이다.The following common components A to B were used. Content in a table|surface is a value with respect to the total mass of a liquid softening agent composition.

공통 성분 Acommon component A

Figure pat00008
Figure pat00008

공통 성분 Bcommon component B

Figure pat00009
Figure pat00009

[액체 섬유 처리제 조성물의 조제 방법][Method for preparing liquid fiber treatment agent composition]

후기하는 표 1에 표시하는 조성을 갖는 섬유 처리제 조성물을 조제했다. 표 1 중, 각 성분의 수치의 단위(%)는, 섬유 처리제 조성물의 총질량에 대한 질량%이다. 표 1 중의 「A/B비」는, (A)성분과 (B)성분의 질량비를 나타낸다.The fiber treatment agent composition which has a composition shown in Table 1 below was prepared. In Table 1, the unit (%) of the numerical value of each component is mass % with respect to the gross mass of the fiber treatment agent composition. "A/B ratio" in Table 1 shows mass ratio of (A) component and (B) component.

섬유 처리제 조성물을, 다음 순서에 의해 조제했다.The fiber treatment agent composition was prepared by the following procedure.

(C)성분 및 (D)성분을 이온교환수 10g에 첨가하여 혼합하고, 또한 (A)성분 및 (B)성분을 첨가하여 균일하게 될 때까지 혼합했다. 얻어진 혼합액에 공통 성분을 첨가하여 혼합해 pH 5.0(25℃)로 조정하고, 또한 전체 질량이 100g이 되도록 이온교환수를 첨가 혼합하여 섬유 처리제 조성물을 얻었다.(C)component and (D)component were added and mixed to 10 g of ion-exchange water, and (A)component and (B)component were further added and mixed until it became uniform. A common component was added and mixed to the obtained liquid mixture, it adjusted to pH 5.0 (25 degreeC), and ion-exchange water was added and mixed so that total mass might be 100 g, and the fiber treatment agent composition was obtained.

섬유 처리제 조성물의 평가Evaluation of fiber treatment composition

섬유 처리제 조성물을, 「피부 보습 기능의 섬유 제품에의 부여」, 「처리된 섬유 제품이 끈적거림」 및 「분무 성상(균일한 분무의 용이성)」의 관점에서 평가했다.The fiber treatment agent composition was evaluated from the viewpoints of "provide to the textile product of a skin moisturizing function", "the treated textile product is sticky", and "spray property (ease of uniform spraying)".

1. 피부 보습 기능의 섬유 제품에의 부여1. Provision of skin moisturizing function to textile products

피부의 보습성을, 그 수분량의 변화를 지표로 하여 평가했다.The moisture content of the skin was evaluated using the change in the moisture content as an index.

처음에, 평가자의 「피부 수분량(초기)」을 하기 순서에 따라 측정했다. 피험자의 팔뚝부를 세정제로 세정하고, 흐르는 물로 헹군 후, 타월로 충분히 수분을 빨아들였다. 그 후, 항온실(20℃, 40% RH) 내에서 10분간 안정하게 한 후, 코네오 미터((주)인테그럴제)로 피부 수분량을 측정했다.First, the "skin moisture content (initial)" of the evaluator was measured according to the following procedure. After washing the subject's forearm with a detergent and rinsing with running water, the subject's forearm was sufficiently absorbed with a towel. Then, after making it stable for 10 minutes in a constant temperature room (20 degreeC, 40%RH), the skin moisture content was measured with the coneometer (made by Integral Co., Ltd.).

다음에, 섬유 처리제로 처리한 섬유 제품을 6시간 적용한 후의 평가자의 「피부 수분량(6시간 후)」를 하기 순서에 따라 측정했다. 화학섬유(폴리에스테르 38%, 아크릴 32%, 레이온 21%, 폴리우레탄 9%)제의 히트텍 이너((주)유니클로제)로부터 시험포(10㎝×10㎝)를 조제했다. 시판품(아로마 리치 향기 미스트. 라이온(주)제)의 디스펜서 보틀(분무 기구 부착)을 이용하여, 섬유 처리제 조성물 0.2g를 시험포에 균일하게 분무하고, 30분간 이상 건조시켜서, 처리제 시험포를 조제했다. 처리제 시험포를 평가자의 팔뚝부에 첩부(貼付)하고 6시간 경과 후, 첩부부의 피부 수분량을 측정했다. 측정은, 항온실(20℃, 40% RH) 내에서 10분간 안정하게 한 후, 코네오 미터((주)인테그럴제)를 이용하여 행했다.Next, the "skin moisture content (after 6 hours)" of the evaluator after applying the textile product treated with the fiber treatment agent for 6 hours was measured according to the following procedure. A test cloth (10 cm x 10 cm) was prepared from a chemical fiber (38% polyester, 32% acrylic, 21% rayon, 9% polyurethane) heattech inner (manufactured by UNIQLO). Using the dispenser bottle (with a spray mechanism) of a commercial item (aroma rich fragrance mist. Lion Co., Ltd. product), 0.2 g of fiber treatment agent composition was sprayed uniformly to a test cloth, and it was made to dry for 30 minutes or more, and the treatment agent test cloth was prepared. The treatment agent test cloth was affixed to the forearm of the evaluator, and the skin moisture content of the affixed part was measured after the lapse of 6 hours. The measurement was performed using a coneometer (manufactured by Integral Co., Ltd.) after being stabilized for 10 minutes in a constant temperature room (20°C, 40% RH).

상기한 순서를 평가자 4명의 좌우의 팔에 실시했다. 측정치를 하기 식에 적용시켜서 피부의 수분 변화율(%)을 산출했다.The above procedure was applied to the left and right arms of four evaluators. The measured value was applied to the following formula to calculate the skin moisture change rate (%).

수분 변화율(%)=피부 수분량(6시간 후)/피부 수분량(초기)×100Moisture change rate (%) = skin moisture content (after 6 hours) / skin moisture content (initial) x 100

평가자 4명의 수분 변화율(%)의 평균치를 하기한 판정 기준에 적용하여, 「피부 보습 기능을 섬유 제품에 부여하는 성능」의 평가로 하였다. 결과를, 표 1의 「보습성」난에 나타낸다. ◎ 및 ○을 합격으로 했다.The average value of the water change rate (%) of the four evaluators was applied to the following criterion, and it was set as evaluation of "the performance which provides a skin moisturizing function to a textile product". A result is shown in the "moisture retention" column of Table 1. (double-circle) and (circle) were made into pass.

<판정 기준><Judgment Criteria>

◎: 평균치가 130% 이상◎: average value of 130% or more

○: 평균치가 110% 이상 130% 미만○: Average value is 110% or more and less than 130%

×: 평균치가 110% 미만x: average value is less than 110%

2. 처리된 섬유 제품이 끈적거림2. Treated textile products are sticky

상기 1에 기재된 순서에 따라 시험포(10㎝×10㎝. 1.4g)를 조제했다. 시판품(아로마 리치 향기 미스트. 라이온(주)제)의 디스펜서 보틀(분무 기구 부착)을 이용하여, 섬유 처리제 조성물을 시험포에 분무(분무량: 15% o.w.f)하여, 처리제 시험포를 조제했다.According to the procedure described in 1 above, a test cloth (10 cm × 10 cm. 1.4 g) was prepared. Using the dispenser bottle (with a spray mechanism) of a commercial item (aroma rich fragrance mist. Lion Co., Ltd. product), the fiber treatment composition was sprayed to the test cloth (spray amount: 15% o.w.f), and the treatment agent test cloth was prepared.

분무한 섬유 처리제 조성물이 건조하기 전에 처리제 시험포를 손으로 만지고, 손에 비볐을 때에 평가자가 느끼는 끈적거림 느낌을, 하기한 기준에 따라 관능 평가 했다. 평가자 4명의 평균점(소수점 제1위까지 산출)을, 하기한 판정 기준에 적용하여, 「처리된 섬유 제품의 끈적거림」의 평가로 했다. 결과를, 표 1의 「끈적거림」난에 나타낸다. ◎ 및 ○를 합격으로 했다.Before the sprayed fiber treatment composition dried, the treatment agent test cloth was touched by hand, and the sticky feeling felt by the evaluator when rubbed against the hand was sensory evaluated according to the following criteria. The average point (calculated to the first decimal place) of four evaluators was applied to the following criterion, and it was set as evaluation of "the stickiness of the processed textile product." A result is shown in the "stickiness" column of Table 1. (double-circle) and (circle) were made into pass.

<평가기준><Evaluation criteria>

5점: 매우 끈적거림이 있다5 points: very sticky

4점: 꽤 끈적거림이 있다4 points: quite sticky

3점: 끈적거림이 있다3 points: there is stickiness

2점: 약간 끈적거림이 있다2 points|pieces: There is little stickiness

1점: 끈적거림이 없다1 point: No stickiness

<판정 기준><Judgment Criteria>

◎: 평균점이 2.0점 미만◎: average score less than 2.0

○: 평균점이 2.0점 이상 3.0점 미만○: average score of 2.0 or more but less than 3.0

×: 평균점이 3.0점 이상x: average score of 3.0 or more

3. 섬유 처리제 조성물의 분무 성상(性狀)3. Spray properties of fiber treatment composition

시판품(아로마 리치 향기 미스트. 라이온(주)제)의 디스펜서 보틀(분무 기구 부착)을 이용하여, 섬유 처리제 조성물을, 컬러 브로드(청색. 20㎝×20㎝)의 중심부에 1회 끝까지 당겨(全引き) 분무했다. 분무는, 컬러 브로드로부터 20㎝ 떨어진 거리에서 행했다. 균일한 분무라는 관점에서의 분무 성상을, 하기한 기준에 따라 평가했다. 평가자 4명의 평균점(소수점 제1위(位)까지 산출)을, 하기한 판정 기준에 적용하여, 「섬유 처리제 조성물의 분무 성상」의 평가로 했다. 결과를, 표 1의 「분무 성상」난에 나타낸다. ◎ 및 ○를 합격으로 했다.Using a commercial product (Aroma Rich Fragrance Mist. Lion Co., Ltd.) dispenser bottle (with a spray device), pull the fiber treatment composition to the center of the color broad (blue, 20 cm x 20 cm) once all the way to the end.引Ki) was sprayed. Spraying was performed at a distance of 20 cm from the color broad. The spray properties from the viewpoint of uniform spraying were evaluated according to the following criteria. The average point (computed to the first decimal place) of four evaluators was applied to the following criterion, and it was set as evaluation of "spray property of a fiber treatment agent composition." A result is shown in the "spray property" column of Table 1. (double-circle) and (circle) were made into pass.

<평가 기준><Evaluation criteria>

2점: 균일하게 분무할 수 있다2 points|pieces: It can spray uniformly

1점: 약간 균일하게 분무할 수 있다1 point|piece: It can spray slightly uniformly

0점: 균일하게 분무할 수 없다0 point: Unable to spray uniformly

<판정 기준><Judgment Criteria>

◎: 평균점이 2.0점◎: average score of 2.0

○: 평균점이 1.0점 이상 2.0점 미만○: average score of 1.0 or more and less than 2.0

×: 평균점이 1.0점 미만x: average point less than 1.0

4. 기타의 평가4. Other evaluation

[산업상의 이용 가능성][Industrial Applicability]

본 발명은, 섬유 처리제 분야에서 이용 가능하다.INDUSTRIAL APPLICATION This invention can be utilized in the field of a fiber treatment agent.

[표 1][Table 1]

Figure pat00010
Figure pat00010

Claims (8)

스프레이형의 섬유 처리제 조성물로서,
(A) 글리세린과,
(B) 폴리에틸렌글리콜, 이소프렌글리콜 및 디프로필렌글리콜로 이루어지는 군에서 선택되는 1종 이상을 포함하고,
상기 섬유 처리제 조성물의 총질량에 대해, (A)성분의 함량이 20∼50질량%이고, (B)성분의 함량이 5∼20질량%인 것을 특징으로 하는 섬유 처리제 조성물.
A spray-type fiber treatment composition comprising:
(A) glycerin;
(B) containing at least one selected from the group consisting of polyethylene glycol, isoprene glycol and dipropylene glycol,
With respect to the gross mass of the said fiber treatment agent composition, content of (A) component is 20-50 mass %, and content of (B) component is 5-20 mass %, The fiber treatment agent composition characterized by the above-mentioned.
제1항에 있어서,
(C) 비이온 계면활성제를 더 포함하는 것을 특징으로 하는 섬유 처리제 조성물.
The method of claim 1,
(C) Nonionic surfactant is further included, The fiber treatment composition characterized by the above-mentioned.
제2항에 있어서,
(C)성분이, 폴리옥시에틸렌경화피마자유인 것을 특징으로 하는 섬유 처리제 조성물.
3. The method of claim 2,
(C) Component is polyoxyethylene hydrogenated castor oil, The fiber treatment agent composition characterized by the above-mentioned.
제1항 내지 제3항 중 어느 한 항에 있어서,
(D) 향료를 더 포함하는 것을 특징으로 하는 섬유 처리제 조성물.
4. The method according to any one of claims 1 to 3,
(D) A fragrance|flavor is further included, The fiber treatment composition characterized by the above-mentioned.
제1항 내지 제4항 중 어느 한 항에 있어서,
(A)성분의 함량이, 섬유 처리제 조성물의 총질량에 대해 30∼45질량%인 것을 특징으로 하는 섬유 처리제 조성물.
5. The method according to any one of claims 1 to 4,
(A) Content of component is 30-45 mass % with respect to the gross mass of fiber treatment agent composition, The fiber treatment agent composition characterized by the above-mentioned.
제1항 내지 제5항 중 어느 한 항에 있어서,
(B)성분이, 수평균분자량이 200∼1000의 폴리에틸렌글리콜인 것을 특징으로 하는 섬유 처리제 조성물.
6. The method according to any one of claims 1 to 5,
(B) Component is polyethylene glycol of 200-1000 number average molecular weights, The fiber treatment agent composition characterized by the above-mentioned.
제1항 내지 제6항 중 어느 한 항에 있어서,
(B)성분의 함량이, 섬유 처리제 조성물의 총질량에 대해 7∼15질량%인 것을 특징으로 하는 섬유 처리제 조성물.
7. The method according to any one of claims 1 to 6,
(B) Content of component is 7-15 mass % with respect to the gross mass of fiber treatment agent composition, The fiber treatment agent composition characterized by the above-mentioned.
제1항 내지 제7항 중 어느 한 항에 있어서,
(A)성분과 (B)성분의 질량비(A/B)가 1∼10인 것을 특징으로 하는 섬유 처리제 조성물.
8. The method according to any one of claims 1 to 7,
(A) Mass ratio (A/B) of component and (B) component is 1-10, The fiber treatment agent composition characterized by the above-mentioned.
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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000256148A (en) 1999-03-12 2000-09-19 Nippon Starch Chemical Co Ltd Hair cosmetic
JP2008266254A (en) 2007-04-24 2008-11-06 Lion Corp Moisturizer composition and method for modifying moisture retaining property of soft solid surface
JP2010006725A (en) 2008-06-25 2010-01-14 Kao Corp Skin cosmetic

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000256148A (en) 1999-03-12 2000-09-19 Nippon Starch Chemical Co Ltd Hair cosmetic
JP2008266254A (en) 2007-04-24 2008-11-06 Lion Corp Moisturizer composition and method for modifying moisture retaining property of soft solid surface
JP2010006725A (en) 2008-06-25 2010-01-14 Kao Corp Skin cosmetic

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