JP2022156544A - Sprayable fiber treatment agent composition - Google Patents
Sprayable fiber treatment agent composition Download PDFInfo
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- JP2022156544A JP2022156544A JP2021060287A JP2021060287A JP2022156544A JP 2022156544 A JP2022156544 A JP 2022156544A JP 2021060287 A JP2021060287 A JP 2021060287A JP 2021060287 A JP2021060287 A JP 2021060287A JP 2022156544 A JP2022156544 A JP 2022156544A
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- 239000000835 fiber Substances 0.000 title claims abstract description 74
- 239000000203 mixture Substances 0.000 title claims abstract description 71
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 28
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 19
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 18
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 17
- XPFCZYUVICHKDS-UHFFFAOYSA-N 3-methylbutane-1,3-diol Chemical compound CC(C)(O)CCO XPFCZYUVICHKDS-UHFFFAOYSA-N 0.000 claims abstract description 11
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims abstract description 8
- -1 polyoxyethylene Polymers 0.000 claims description 21
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 11
- 239000002304 perfume Substances 0.000 claims description 10
- 239000004359 castor oil Substances 0.000 claims description 7
- 235000019438 castor oil Nutrition 0.000 claims description 7
- 235000011187 glycerol Nutrition 0.000 claims description 7
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 7
- 239000002736 nonionic surfactant Substances 0.000 claims description 4
- 239000004753 textile Substances 0.000 abstract description 35
- 239000007921 spray Substances 0.000 abstract description 19
- 230000003020 moisturizing effect Effects 0.000 abstract description 17
- 239000000047 product Substances 0.000 description 30
- 239000000126 substance Substances 0.000 description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 238000002156 mixing Methods 0.000 description 11
- 238000000034 method Methods 0.000 description 10
- 229920001214 Polysorbate 60 Polymers 0.000 description 9
- 230000000844 anti-bacterial effect Effects 0.000 description 9
- 239000004744 fabric Substances 0.000 description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- 239000003205 fragrance Substances 0.000 description 8
- 239000004615 ingredient Substances 0.000 description 7
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 239000002537 cosmetic Substances 0.000 description 6
- 238000005507 spraying Methods 0.000 description 6
- 239000003381 stabilizer Substances 0.000 description 6
- 229940121375 antifungal agent Drugs 0.000 description 5
- 239000003429 antifungal agent Substances 0.000 description 5
- 230000001877 deodorizing effect Effects 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 5
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 4
- 239000004677 Nylon Substances 0.000 description 4
- 239000003242 anti bacterial agent Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229920001778 nylon Polymers 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
- 239000003595 mist Substances 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- ASKIVFGGGGIGKH-UHFFFAOYSA-N 2,3-dihydroxypropyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(O)CO ASKIVFGGGGIGKH-UHFFFAOYSA-N 0.000 description 2
- 239000004375 Dextrin Substances 0.000 description 2
- 229920001353 Dextrin Polymers 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 238000000889 atomisation Methods 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000013065 commercial product Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000002781 deodorant agent Substances 0.000 description 2
- 235000019425 dextrin Nutrition 0.000 description 2
- 210000000245 forearm Anatomy 0.000 description 2
- 238000004128 high performance liquid chromatography Methods 0.000 description 2
- 229920000092 linear low density polyethylene Polymers 0.000 description 2
- 239000004707 linear low-density polyethylene Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229930014626 natural product Natural products 0.000 description 2
- 235000019645 odor Nutrition 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 239000002964 rayon Substances 0.000 description 2
- 230000000284 resting effect Effects 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 239000012209 synthetic fiber Substances 0.000 description 2
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
- JLHMJWHSBYZWJJ-UHFFFAOYSA-N 1,2-thiazole 1-oxide Chemical compound O=S1C=CC=N1 JLHMJWHSBYZWJJ-UHFFFAOYSA-N 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- JNAYPSWVMNJOPQ-UHFFFAOYSA-N 2,3-bis(16-methylheptadecanoyloxy)propyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCC(C)C)COC(=O)CCCCCCCCCCCCCCC(C)C JNAYPSWVMNJOPQ-UHFFFAOYSA-N 0.000 description 1
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- IJALWSVNUBBQRA-UHFFFAOYSA-N 4-Isopropyl-3-methylphenol Chemical compound CC(C)C1=CC=C(O)C=C1C IJALWSVNUBBQRA-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 229940123208 Biguanide Drugs 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 102000011782 Keratins Human genes 0.000 description 1
- 108010076876 Keratins Proteins 0.000 description 1
- 229920000433 Lyocell Polymers 0.000 description 1
- 229920001407 Modal (textile) Polymers 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229920000604 Polyethylene Glycol 200 Polymers 0.000 description 1
- 229920002565 Polyethylene Glycol 400 Polymers 0.000 description 1
- 229920002582 Polyethylene Glycol 600 Polymers 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 description 1
- GNVMUORYQLCPJZ-UHFFFAOYSA-M Thiocarbamate Chemical compound NC([S-])=O GNVMUORYQLCPJZ-UHFFFAOYSA-M 0.000 description 1
- PZQBWGFCGIRLBB-NJYHNNHUSA-N [(2r)-2-[(2s,3r,4s)-3,4-dihydroxyoxolan-2-yl]-2-octadecanoyloxyethyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCCCCCCCCCCCC)[C@H]1OC[C@H](O)[C@H]1O PZQBWGFCGIRLBB-NJYHNNHUSA-N 0.000 description 1
- DNTMJTROKXRBDM-UUWWDYFTSA-N [(2r,3r,4s)-2-[(1r)-1-hexadecanoyloxy-2-hydroxyethyl]-4-hydroxyoxolan-3-yl] hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)O[C@H](CO)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCCCCCCCCCC DNTMJTROKXRBDM-UUWWDYFTSA-N 0.000 description 1
- NVANJYGRGNEULT-BDZGGURLSA-N [(3s,4r,5r)-4-hexadecanoyloxy-5-[(1r)-1-hexadecanoyloxy-2-hydroxyethyl]oxolan-3-yl] hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)O[C@H](CO)[C@H]1OC[C@H](OC(=O)CCCCCCCCCCCCCCC)[C@H]1OC(=O)CCCCCCCCCCCCCCC NVANJYGRGNEULT-BDZGGURLSA-N 0.000 description 1
- MLDWGLQSBBCMMO-UHFFFAOYSA-N [Na].[Na].[Na].CNCC(=O)O Chemical compound [Na].[Na].[Na].CNCC(=O)O MLDWGLQSBBCMMO-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 229940051881 anilide analgesics and antipyretics Drugs 0.000 description 1
- 150000003931 anilides Chemical class 0.000 description 1
- 239000000058 anti acne agent Substances 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 229940124340 antiacne agent Drugs 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 150000004283 biguanides Chemical class 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 150000002019 disulfides Chemical class 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 229930003935 flavonoid Natural products 0.000 description 1
- 150000002215 flavonoids Chemical class 0.000 description 1
- 235000017173 flavonoids Nutrition 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 1
- 229940074052 glyceryl isostearate Drugs 0.000 description 1
- 229940094952 green tea extract Drugs 0.000 description 1
- 235000020688 green tea extract Nutrition 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- NFIDBGJMFKNGGQ-UHFFFAOYSA-N isopropylmethylphenol Natural products CC(C)CC1=CC=CC=C1O NFIDBGJMFKNGGQ-UHFFFAOYSA-N 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 239000006174 pH buffer Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920002523 polyethylene Glycol 1000 Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 235000010483 polyoxyethylene sorbitan monopalmitate Nutrition 0.000 description 1
- 239000000249 polyoxyethylene sorbitan monopalmitate Substances 0.000 description 1
- 235000010989 polyoxyethylene sorbitan monostearate Nutrition 0.000 description 1
- 239000001818 polyoxyethylene sorbitan monostearate Substances 0.000 description 1
- 239000001816 polyoxyethylene sorbitan tristearate Substances 0.000 description 1
- 235000010988 polyoxyethylene sorbitan tristearate Nutrition 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 150000008442 polyphenolic compounds Chemical class 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 150000004788 tropolones Chemical class 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
- D06M13/148—Polyalcohols, e.g. glycerol or glucose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/005—Compositions containing perfumes; Compositions containing deodorants
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/165—Ethers
- D06M13/17—Polyoxyalkyleneglycol ethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/17—Natural resins, resinous alcohols, resinous acids, or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/06—Processes in which the treating agent is dispersed in a gas, e.g. aerosols
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
本発明は、スプレー型の繊維処理剤組成物に関する。 The present invention relates to a spray type fiber treatment composition.
スプレー型の繊維処理剤は、様々な製品が発売され、その市場は年々拡大している。スプレー型の繊維処理剤が訴求する機能としては、除菌、消臭、香り付けや、しわとり等が一般的であるが、着用時の涼感付与等の新しい機能を訴求する製品も登場している。
他方、化粧品分野では、肌の保湿を訴求した化粧品（保湿化粧品）が多数発売されている（特許文献１～３）。保湿化粧品に関しては、べたつきを抑制しつつ保湿効果を発揮させるための技術が存在する（特許文献１及び３）。
A variety of spray-type fiber treatment agents have been released, and the market for them is expanding year by year. Generally, spray-type textile treatment agents have functions such as sterilization, deodorization, fragrance, and wrinkle removal. there is
On the other hand, in the field of cosmetics, a large number of cosmetics (moisturizing cosmetics) appealing for moisturizing the skin have been sold (Patent Documents 1 to 3). Regarding moisturizing cosmetics, there are techniques for exhibiting moisturizing effects while suppressing stickiness (Patent Documents 1 and 3).
繊維製品への肌保湿機能付与という新しい価値を持つ繊維処理剤を開発するにあたりグリセリンを使用したところ、繊維製品へ肌保湿機能を付与できたものの、（１）処理された繊維製品でべたつきが発生し、更に（２）繊維製品のスプレーによる均一処理（均一な噴霧）が難しく使用性に劣るという課題が見出された。 When glycerin was used to develop a textile treatment agent with new value of imparting skin moisturizing function to textile products, although it was possible to impart skin moisturizing function to textile products, (1) the treated textile product became sticky. In addition, (2) uniform treatment (uniform spraying) of textile products by spraying is difficult, resulting in inferior usability.
前記の課題を鋭意検討した結果、本発明者は、グリセリンとポリエチレングリコール及び／又はイソプレングリコールとを特定量で組み合わせると、べたつきの発生を抑制しつつ肌保湿機能を繊維製品に付与でき、更に、均一な噴霧も可能になることを見出した。本発明は、この知見に基づいてなされたものである。 As a result of intensive studies on the above problems, the inventors of the present invention found that a combination of glycerin and polyethylene glycol and/or isoprene glycol in a specific amount can impart a skin moisturizing function to textile products while suppressing the occurrence of stickiness. It was found that uniform spraying is also possible. The present invention has been made based on this finding.
すなわち、本発明は、以下の〔１〕～〔８〕に関するものである。
〔１〕スプレー型の繊維処理剤組成物であって、
（Ａ）グリセリンと、（Ｂ）ポリエチレングリコール、イソプレングリコール及びジプロピレングリコールからなる群から選ばれる１種以上とを含み、
前記繊維処理剤組成物の総質量に対して、（Ａ）成分の含量が２０～５０質量％であり、（Ｂ）成分の含量が５～２０質量％であることを特徴とする、繊維処理剤組成物。
〔２〕（Ｃ）ノニオン界面活性剤を更に含む、前記〔１〕に記載の繊維処理剤組成物。
〔３〕（Ｃ）成分が、ポリオキシエチレン硬化ひまし油である、前記〔２〕に記載の繊維処理剤組成物。
〔４〕（Ｄ）香料を更に含む、前記〔１〕～〔３〕のいずれか一項に記載の繊維処理剤組成物。
〔５〕（Ａ）成分の含量が、繊維処理剤組成物の総質量に対して３０～４５質量％である、前記〔１〕～〔４〕のいずれか一項に記載の繊維処理剤組成物。
〔６〕（Ｂ）成分が、数平均分子量が２００～１０００のポリエチレングリコールである、前記〔１〕～〔５〕のいずれか一項に記載の繊維処理剤組成物。
〔７〕（Ｂ）成分の含量が、繊維処理剤組成物の総質量に対して７～１５質量％である、前記〔１〕～〔６〕のいずれか一項に記載の繊維処理剤組成物。
〔８〕（Ａ）成分と（Ｂ）成分との質量比（Ａ／Ｂ）が１～１０である、前記〔１〕～〔７〕のいずれか一項に記載の繊維処理剤組成物。
That is, the present invention relates to the following [1] to [8].
[1] A spray-type fiber treatment composition comprising:
(A) glycerin and (B) one or more selected from the group consisting of polyethylene glycol, isoprene glycol and dipropylene glycol,
A fiber treatment characterized in that the content of component (A) is 20 to 50% by mass and the content of component (B) is 5 to 20% by mass with respect to the total mass of the fiber treatment composition. agent composition.
[2] The fiber treatment composition according to [1] above, further comprising (C) a nonionic surfactant.
[3] The fiber treatment composition according to [2] above, wherein the component (C) is polyoxyethylene hydrogenated castor oil.
[4] The fiber treatment composition according to any one of [1] to [3], further comprising (D) a perfume.
[5] The fiber treatment composition according to any one of [1] to [4] above, wherein the content of component (A) is 30 to 45% by mass relative to the total weight of the fiber treatment composition. thing.
[6] The fiber treatment composition according to any one of [1] to [5] above, wherein component (B) is polyethylene glycol having a number average molecular weight of 200 to 1,000.
[7] The fiber treatment composition according to any one of [1] to [6] above, wherein the content of component (B) is 7 to 15% by mass relative to the total weight of the fiber treatment composition. thing.
[8] The fiber treatment composition according to any one of [1] to [7], wherein the mass ratio (A/B) of component (A) to component (B) is 1 to 10.
後述の実施例に示すように、本発明の繊維処理剤組成物は、スプレー剤としての使用性に優れ、かつ、べたつき発生を抑制しつつ肌保湿機能を繊維製品へ付与できる。したがって、本発明は、従来製品にはない付加価値を持つスプレー型の繊維処理剤を提供できる。 As shown in the examples below, the textile treatment composition of the present invention is excellent in usability as a spray agent, and can impart a skin moisturizing function to textile products while suppressing the occurrence of stickiness. Therefore, the present invention can provide a spray-type fiber treatment agent with added value not found in conventional products.
〔（Ａ）成分：グリセリン〕
（Ａ）成分は、肌を保湿する機能（肌保湿性）を繊維製品へ付与するために配合する。
（Ａ）成分は公知物質であり、市場で容易に入手可能であるか、又は調製可能である。
（Ａ）成分の含量は、繊維処理剤組成物の総質量に対して２０～５０質量％、好ましくは３０～４５質量％、更に好ましくは３５～４５質量％である。（Ａ）成分の含量が２０質量％以上であると配合目的を達成でき、５０質量％以下であると、処理された繊維製品におけるべたつき発生の抑制と均一な噴霧とを達成できる。
[(A) component: glycerin]
The component (A) is blended in order to impart a function of moisturizing the skin (skin moisturizing property) to the textile product.
Component (A) is a known substance and is readily available on the market or can be prepared.
The content of component (A) is 20 to 50% by mass, preferably 30 to 45% by mass, more preferably 35 to 45% by mass, based on the total mass of the fiber treatment composition. When the content of component (A) is 20% by mass or more, the purpose of blending can be achieved.
〔（Ｂ）成分：ポリエチレングリコール、イソプレングリコール及びジプロピレングリコールからなる群より選ばれる１種以上〕
（Ｂ）成分は、（Ａ）成分を単独で使用したときに起こる前述の課題を解決するために配合する。
ポリエチレングリコール（ＰＥＧ）は、繊維処理剤分野で公知のものを特に制限なく使用できる。ＰＥＧの数平均分子量は特に制限されないが、好ましくは２００～４０００、より好ましくは２００～１０００、更に好ましくは２００～６００である。この数平均分子量の範囲であると、処理された繊維製品におけるべたつき発生を更に抑制し、また、噴霧性を更に向上させることができる。
ＰＥＧの数平均分子量は、ＨＰＬＣ法に従い測定できる。
ＰＥＧは、単一種類を使用してもよく、複数種類を併用してもよい。
[(B) component: one or more selected from the group consisting of polyethylene glycol, isoprene glycol and dipropylene glycol]
Component (B) is blended in order to solve the aforementioned problems that occur when component (A) is used alone.
As polyethylene glycol (PEG), those known in the field of fiber treatment agents can be used without particular limitation. Although the number average molecular weight of PEG is not particularly limited, it is preferably 200-4000, more preferably 200-1000, still more preferably 200-600. Within this number-average molecular weight range, it is possible to further suppress the occurrence of stickiness in the treated textile product and further improve the sprayability.
The number average molecular weight of PEG can be measured according to the HPLC method.
A single type of PEG may be used, or multiple types may be used in combination.
イソプレングリコール（ＩＰＧ）（イソペンチルジオールとも称される）は、繊維処理剤に配合なものを特に制限なく使用できる。
ＩＰＧは、単一種類を使用してもよく、複数種類を併用してもよい。
Isoprene glycol (IPG) (also referred to as isopentyl diol) can be used without any particular limitation if it is blended with the fiber treatment agent.
A single type of IPG may be used, or a plurality of types may be used together.
ジプロピレングリコール（ＤＰＧ）は、繊維処理剤に配合なものを特に制限なく使用できる。
ＤＰＧは、単一種類を使用してもよく、複数種類を併用してもよい。
Dipropylene glycol (DPG) can be used without any particular limitation as long as it is blended with the fiber treatment agent.
A single type of DPG may be used, or a plurality of types may be used together.
（Ｂ）成分は公知物質であり、市場で容易に入手可能であるか、又は調製可能である。
（Ｂ）成分は単一種類を使用してもよく、複数種類を併用（例えば、ＰＥＧとＩＰＧの併用）してもよい。
（Ｂ）成分の含量は、繊維処理剤組成物の総質量に対して５～２０質量％、好ましくは７～１５質量％、更に好ましくは８～１３質量％である。（Ｂ）成分の含量が５質量％以上であると、処理された繊維製品におけるべたつきの発生を抑制でき、２０質量％以下であると均一な噴霧を達成できる。
Component (B) is a known substance and is readily available on the market or can be prepared.
A single type of component (B) may be used, or a combination of multiple types (for example, a combination of PEG and IPG) may be used.
The content of component (B) is 5 to 20% by mass, preferably 7 to 15% by mass, more preferably 8 to 13% by mass, based on the total mass of the fiber treatment composition. When the content of component (B) is 5% by mass or more, stickiness of the treated textile product can be suppressed, and when it is 20% by mass or less, uniform spraying can be achieved.
〔（Ａ）成分と（Ｂ）成分との配合比率〕
（Ａ）成分と（Ｂ）成分との質量比（Ａ／Ｂ）は、好ましくは１～１０、更に好ましくは２～６、特に好ましくは３～６である。前記の質量比範囲であると更に優れた保湿効果とべたつき発生抑制性とが得られる。
[Mixing ratio of component (A) and component (B)]
The mass ratio (A/B) of component (A) to component (B) is preferably 1-10, more preferably 2-6, and particularly preferably 3-6. Within the above mass ratio range, a more excellent moisturizing effect and stickiness prevention can be obtained.
〔任意成分〕
繊維処理剤組成物には、本発明の効果を損なわない範囲で、下記の任意成分を配合してもよい。
[Optional component]
The following optional components may be added to the fiber treatment composition as long as the effects of the present invention are not impaired.
〔（Ｃ）成分：ノニオン界面活性剤〕
（Ｃ）成分は、繊維処理剤組成物の安定性（具体的には、分散安定性）を向上させるために配合する。
ノニオン界面活性剤としては、繊維処理剤分野で公知の物質を特に制限なく使用できる。例としては、ポリオキシエチレンモノステアレート、ポリオキシエチレンモノパルミテート、ポリオキシエチレンモノミリステート、ポリオキシエチレンジステアレート、ポリオキシエチレンジパルミテート、ポリオキシエチレンジミリステート、ポリオキシエチレントリステアレート、ポリオキシエチレントリパルミテート、ポリオキシエチレントリミリステート、モノステアリン酸ポリエチレングリコール、モノステアリン酸ポリオキシエチレンソルビタン、モノパルミチン酸ポリオキシエチレンソルビタン、モノミリスチン酸ポリオキシエチレンソルビタン、モノラウリン酸ポリオキシエチレンソルビタン、ジステアリン酸ポリオキシエチレンソルビタン、ジパルミチン酸ポリオキシエチレンソルビタン、ジミリスチン酸ポリオキシエチレンソルビタン、ジラウリン酸ポリオキシエチレンソルビタン、トリステアリン酸ポリオキシエチレンソルビタン、トリパルミチン酸ポリオキシエチレンソルビタン、トリミリスチン酸ポリオキシエチレンソルビタン、トリラウリン酸ポリオキシエチレンソルビタン、テトラオレイン酸ポリオキシエチレンソルビット、モノラウリン酸ポリオキシエチレンソルビット、ポリオキシエチレン硬化ヒマシ油、ポリオキシエチレンポリオキシプロピレンセチルエーテル、モノステアリン酸ポリグリセリル、モノオレイン酸ポリグリセリル、ジステアリン酸ポリグリセリル、トリイソステアリン酸ポリオキシエチレングリセリル、イソステアリン酸ポリオキシエチレングリセリル、トリステアリン酸デカグリセリル、トリオレイン酸ポリグリセリルや、ポリオキシエチレン・メチルポリシロキサン共重合体等が挙げられる。
（Ｃ）成分としては、ポリオキシエチレン硬化ヒマシ油が好ましく、なかでも、エチレンオキシド（ＥＯ）の平均付加モル数が２０～１００、好ましくは４０～６０のポリオキシエチレン硬化ヒマシ油が更に好ましい。
[(C) component: nonionic surfactant]
The component (C) is blended to improve the stability (specifically, dispersion stability) of the fiber treatment composition.
As the nonionic surfactant, substances known in the field of fiber treatment agents can be used without particular limitation. Examples include polyoxyethylene monostearate, polyoxyethylene monopalmitate, polyoxyethylene monomyristate, polyoxyethylene distearate, polyoxyethylene dipalmitate, polyoxyethylene dimyristate, polyoxyethylene tri Stearate, polyoxyethylene tripalmitate, polyoxyethylene trimyristate, polyethylene glycol monostearate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monopalmitate, polyoxyethylene sorbitan monomyristate, polymonolaurate oxyethylene sorbitan, polyoxyethylene sorbitan distearate, polyoxyethylene sorbitan dipalmitate, polyoxyethylene sorbitan dimyristate, polyoxyethylene sorbitan dilaurate, polyoxyethylene sorbitan tristearate, polyoxyethylene sorbitan tripalmitate, Polyoxyethylene sorbitan trimyristate, polyoxyethylene sorbitan trilaurate, polyoxyethylene sorbitan tetraoleate, polyoxyethylene sorbit monolaurate, polyoxyethylene hydrogenated castor oil, polyoxyethylene polyoxypropylene cetyl ether, polyglyceryl monostearate , polyglyceryl monooleate, polyglyceryl distearate, polyoxyethylene glyceryl triisostearate, polyoxyethylene glyceryl isostearate, decaglyceryl tristearate, polyglyceryl trioleate, polyoxyethylene/methylpolysiloxane copolymer, etc. be done.
Component (C) is preferably polyoxyethylene hydrogenated castor oil, more preferably polyoxyethylene hydrogenated castor oil having an average added mole number of ethylene oxide (EO) of 20 to 100, preferably 40 to 60.
（Ｃ）成分は公知物質であり、市場で容易に入手可能であるか、又は調製可能である。
（Ｃ）成分は単一種類を使用してもよく、複数種類を併用してもよい。
（Ｃ）成分の含量は、配合目的を達成できる量である限り特に限定されないが、繊維処理剤組成物の総質量に対して、好ましくは０．１～１０質量％、更に好ましくは０．５～５質量％である。前記の含量範囲であるとより高い配合効果が得られる。
Component (C) is a known substance and is readily available on the market or can be prepared.
(C) A component may use a single type and may use multiple types together.
The content of component (C) is not particularly limited as long as it is an amount that can achieve the purpose of blending, but is preferably 0.1 to 10% by mass, more preferably 0.5%, based on the total mass of the fiber treatment composition. ~5% by mass. If the content is in the above range, a higher blending effect can be obtained.
〔（Ｄ）成分：香料〕
（Ｄ）成分は、繊維処理剤組成物自体の香り付け、及び／又は、同組成物による処理後の繊維製品の香り付けのために配合する。
（Ｄ）成分としては、繊維処理剤分野で公知の物質を特に制限なく使用できるが、使用できる香料原料のリストは、様々な文献、例えば「Ｐｅｒｆｕｍｅ ａｎｄ Ｆｌａｖｏｒ Ｃｈｅｍｉｃａｌｓ」，Ｖｏｌ．Ｉ ａｎｄ II，Ｓｔｅｆｆｅｎ Ａｒｃｔａｎｄｅｒ，Ａｌｌｕｒｅｄ Ｐｕｂ．Ｃｏ．（１９９４）および「合成香料 化学と商品知識」、印藤元一著、化学工業日報社（１９９６）および「Ｐｅｒｆｕｍｅ ａｎｄ Ｆｌａｖｏｒ Ｍａｔｅｒｉａｌｓ ｏｆ Ｎａｔｕｒａｌ Ｏｒｉｇｉｎ」，Ｓｔｅｆｆｅｎ Ａｒｃｔａｎｄｅｒ，Ａｌｌｕｒｅｄ Ｐｕｂ．Ｃｏ．（１９９４）および「香りの百科」、日本香料協会編、朝倉書店（１９８９）および「Ｐｅｒｆｕｍｅｒｙ Ｍａｔｅｒｉａｌ Ｐｅｒｆｏｒｍａｎｃｅ Ｖ．３．３」，Ｂｏｅｌｅｎｓ Ａｒｏｍａ Ｃｈｅｍｉｃａｌ Ｉｎｆｏｒｍａｔｉｏｎ Ｓｅｒｖｉｃｅ（１９９６）および「Ｆｌｏｗｅｒ ｏｉｌｓ ａｎｄ Ｆｌｏｒａｌ Ｃｏｍｐｏｕｎｄｓ Ｉｎ Ｐｅｒｆｕｍｅｒｙ」，Ｄａｎｕｔｅ Ｌａｊａｕｊｉｓ Ａｎｏｎｉｓ，Ａｌｌｕｒｅｄ Ｐｕｂ．Ｃｏ．（１９９３）等に記載されている。
[(D) component: perfume]
The component (D) is blended to impart fragrance to the textile treatment composition itself and/or to impart fragrance to textile products treated with the composition.
As component (D), substances known in the field of fiber treatment agents can be used without particular limitation. I and II, Steffen Arctander, Allured Pub. Co. (1994) and "Synthetic Perfume Chemistry and Product Knowledge", Genichi Indo, Chemical Daily (1996) and "Perfume and Flavor Materials of Natural Origin", Steffen Arctander, Allured Pub. Co. (1994) and "Encyclopedia of Fragrance", edited by Japan Perfume Association, Asakura Shoten (1989) and "Perfumery Material Performance V.3.3", Boelens Aroma Chemical Information Service (1996) and "Flower oils and Floral Compounds" In , Danute Lajaujis Anonis, Allured Pub. Co. (1993) and others.
（Ｄ）成分は単一種類を使用してもよく、複数種類を併用した香料組成物として使用してもよい。
（Ｄ）成分の含量は、配合目的を達成できる量である限り特に限定されないが、繊維処理剤組成物の総質量に対して、好ましくは０．０１～１質量％、更に好ましくは０．０５～０．５質量％である。
Component (D) may be used either singly or as a fragrance composition in which multiple types are used in combination.
The content of component (D) is not particularly limited as long as it is an amount that can achieve the purpose of blending, but it is preferably 0.01 to 1% by mass, more preferably 0.05, based on the total mass of the fiber treatment composition. ~0.5% by mass.
〔（Ｃ）成分以外の安定化剤〕
安定化剤は、繊維処理剤組成物の安定性（具体的には、防腐性能）を向上させるために配合する。（Ｃ）成分以外の安定化剤としては、繊維処理剤分野で公知の物質を特に制限なく使用できる。例としては、安息香酸ナトリウム、クエン酸や、フェノキシエタノール等が挙げられる。
安定化剤は公知物質であり、市場で容易に入手可能であるか、又は調製可能である。
安定化剤は単一種類を使用してもよく、複数種類を併用してもよい。
安定化剤の含量は、配合目的を達成できる量である限り特に限定されないが、繊維処理剤組成物の総質量に対して、好ましくは０．２～５質量％、更に好ましくは０．５～２質量％である。
[Stabilizers other than component (C)]
Stabilizers are blended in order to improve the stability (specifically, antiseptic performance) of the fiber treatment composition. As stabilizers other than the component (C), substances known in the field of fiber treatment agents can be used without particular limitations. Examples include sodium benzoate, citric acid, phenoxyethanol, and the like.
Stabilizers are known substances and are readily available on the market or can be prepared.
A single type of stabilizer may be used, or a plurality of types may be used in combination.
The content of the stabilizer is not particularly limited as long as it is an amount that can achieve the purpose of blending, but it is preferably 0.2 to 5% by mass, more preferably 0.5 to 5% by mass, based on the total mass of the fiber treatment composition. It is 2% by mass.
〔揮発性アルコール〕
揮発性アルコールは、繊維製品へ噴霧された後の乾燥性を向上させるために配合する。
揮発性アルコールとしては、繊維処理剤分野で公知の物質を特に制限なく使用できる。例としては、炭素数１～３（好ましくは１～２）のアルコールが挙げられ、なかでもエタノールが好ましい。
揮発性アルコールは公知物質であり、市場で容易に入手可能であるか、又は調製可能である。
揮発性アルコールは単一種類を使用してもよく、複数種類を併用してもよい。
揮発性アルコールの含量は、配合目的を達成できる量である限り特に限定されないが、繊維処理剤組成物の総質量に対して、好ましくは１～２０質量％、更に好ましくは５～１０質量％である。
[Volatile alcohol]
Volatile alcohol is blended in order to improve the drying property after being sprayed onto textile products.
As the volatile alcohol, substances known in the field of fiber treatment agents can be used without particular limitation. Examples include alcohols having 1 to 3 carbon atoms (preferably 1 to 2 carbon atoms), with ethanol being preferred.
Volatile alcohols are known substances and are readily commercially available or can be prepared.
A single type of volatile alcohol may be used, or a plurality of types may be used in combination.
The content of the volatile alcohol is not particularly limited as long as the purpose of blending can be achieved. be.
〔消臭成分〕
消臭成分は、繊維製品へ消臭性を付与するために配合する。
消臭成分としては、繊維処理剤分野で公知の物質を特に制限なく使用できる。例としては、高度分岐環状デキストリン（例えば、グリコ栄養食品株式会社製 商品名：クラスターデキストリン））、メチルグリシンジ酢酸３ナトリウム、酸化亜鉛、酸化マグネシウム、ポリフェノールや、フラボノイドを含む天然物（緑茶エキス）などが挙げられる。
消臭成分は公知物質であり、市場で容易に入手可能であるか、又は調製可能である。
消臭成分は単一種類を使用してもよく、複数種類を併用してもよい。
消臭成分の含量は、配合目的を達成できる量である限り特に限定されないが、繊維処理剤組成物の総質量に対して、好ましくは０．１～３質量％、更に好ましくは０．１～１．５質量％である。
[Deodorant ingredient]
The deodorizing component is blended to impart deodorizing properties to textile products.
As the deodorizing component, substances known in the field of fiber treatment agents can be used without particular limitation. Examples include highly branched cyclic dextrin (eg, product name: cluster dextrin manufactured by Glico Nutrient Foods Co., Ltd.), trisodium methylglycine diacetate, zinc oxide, magnesium oxide, polyphenols, and natural products containing flavonoids (green tea extract). etc.
Deodorant ingredients are known substances and are readily available on the market or can be prepared.
A single type of deodorizing component may be used, or a plurality of types may be used in combination.
The content of the deodorizing component is not particularly limited as long as it is an amount that can achieve the purpose of blending. It is 1.5% by mass.
〔抗菌成分〕
抗菌成分は、処理された繊維製品上での菌の増殖を抑制して、不快臭の発生を抑制するために配合する。
抗菌成分としては、繊維処理剤分野で公知の物質を特に制限なく使用できる。例としては、有機系防菌防黴剤や無機系防菌防黴剤等が挙げられる。有機系防菌防黴剤の例としては、アルコール系、フェノール系（例えば、イソプロピルメチルフェノール）、アルデヒド系、カルボン酸系、エステル系、エーテル系、ニトリル系、過酸化物・エポキシ系、ハロゲン系、ピリジン・キノリン系、トリアジン系、イソチアゾロン系、イミダゾール・チアゾール系、アニリド系、ビグアナイド系、ジスルフィド系、チオカーバメート系、糖質系、トロポロン系、有機金属系のものが挙げられる。無機系防菌防黴剤の例としては、金属酸化物や、銀系のものが挙げられる。
抗菌成分は、市場で容易に入手可能であるか、又は調製可能である。
抗菌成分は単一種類を使用してもよく、複数種類を併用してもよい。
抗菌成分の含量は、配合目的を達成できる量である限り特に限定されないが、繊維処理剤組成物の総質量に対して、好ましくは０．０５～１質量％、更に好ましくは０．１～０．７質量％である。
[Antibacterial ingredient]
The antibacterial component is added to suppress the growth of bacteria on the treated textile product and to suppress the generation of unpleasant odors.
As the antibacterial component, substances known in the field of fiber treatment agents can be used without particular limitation. Examples thereof include organic antibacterial and antifungal agents and inorganic antibacterial and antifungal agents. Examples of organic antibacterial and antifungal agents include alcohol-based, phenol-based (e.g., isopropylmethylphenol), aldehyde-based, carboxylic acid-based, ester-based, ether-based, nitrile-based, peroxide/epoxy-based, and halogen-based agents. , pyridine/quinoline, triazine, isothiazolone, imidazole/thiazole, anilides, biguanides, disulfides, thiocarbamate, carbohydrates, tropolones, and organic metals. Examples of inorganic antibacterial and antifungal agents include metal oxides and silver-based agents.
Antimicrobial ingredients are readily commercially available or can be prepared.
A single type of antibacterial component may be used, or a plurality of types may be used in combination.
The content of the antibacterial component is not particularly limited as long as it is an amount that can achieve the purpose of blending, but it is preferably 0.05 to 1% by mass, more preferably 0.1 to 0%, based on the total mass of the fiber treatment composition. .7 mass %.
〔水〕
繊維処理剤組成物は、好ましくは水を含む水性組成物である。
水としては水道水、イオン交換水、純水や蒸留水等を使用できるが、イオン交換水が好ましい。
水の含量は特に限定されないが、繊維処理剤組成物の総質量に対して、好ましくは１０質量％以上、更に好ましくは４０質量％以上である。含量が４０質量％以上であると、使用性がより良好となる。
〔water〕
The fiber treatment composition is preferably an aqueous composition containing water.
As water, tap water, ion-exchanged water, pure water, distilled water, or the like can be used, and ion-exchanged water is preferred.
Although the content of water is not particularly limited, it is preferably 10% by mass or more, more preferably 40% by mass or more, relative to the total mass of the fiber treatment composition. When the content is 40% by mass or more, usability becomes better.
〔その他の任意成分〕
前記の任意成分以外にも、繊維処理剤や化粧料へ配合可能な公知の成分を適宜配合できる。例としては、機能性成分（シリコーン（繊維製品の感触向上）、腋臭防止剤、抗にきび剤、美白剤、角質軟化剤等）、ｐＨ緩衝剤、紫外線吸収剤、有機溶剤、防腐剤、キレート剤、再汚染防止剤、高分子、防カビ剤、忌避剤、天然物等のエキス、分散剤や、酸化防止剤等が挙げられる。
[Other optional ingredients]
In addition to the optional components described above, known components that can be blended into fiber treatment agents and cosmetics can be blended as appropriate. Examples include functional ingredients (silicone (improving the feel of textile products), anti-armpit odor agents, anti-acne agents, whitening agents, keratin softeners, etc.), pH buffers, UV absorbers, organic solvents, preservatives, chelating agents. , redeposition inhibitors, polymers, antifungal agents, repellents, extracts of natural products, dispersants, antioxidants, and the like.
〔繊維処理剤組成物のｐＨ〕
繊維処理剤組成物のｐＨは特に限定されないが、保存安定性の観点から、２５℃におけるｐＨを、好ましくは４．５～７、更に好ましくは５～６の範囲へ調整する。
ｐＨは、公知のｐＨ調整剤（例えば、クエン酸等）の添加により調整できる。
ｐＨは、ｐＨメーター（例えば、Mettler Toledo社製 型番MP230）で測定できる。
[pH of Fiber Treatment Composition]
Although the pH of the fiber treatment composition is not particularly limited, the pH at 25°C is preferably adjusted to the range of 4.5 to 7, more preferably 5 to 6, from the viewpoint of storage stability.
The pH can be adjusted by adding a known pH adjusting agent (eg, citric acid, etc.).
The pH can be measured with a pH meter (eg Model No. MP230 manufactured by Mettler Toledo).
〔製造方法〕
製造方法に特に制限はなく、（Ａ）成分と（Ｂ）成分とを混合することで繊維処理剤組成物を製造できる。
例えば、（Ｃ）成分及び（Ｄ）成分を水へ添加して混合し、更に（Ａ）成分及び（Ｂ）成分を添加して混合し、必要により他の任意成分を添加して混合した後、ｐＨを調整し、バランス量の水を添加することで、繊維処理剤組成物を製造できる。
〔Production method〕
The production method is not particularly limited, and the fiber treatment composition can be produced by mixing the components (A) and (B).
For example, the components (C) and (D) are added to water and mixed, then the components (A) and (B) are added and mixed, and if necessary other optional components are added and mixed. By adjusting the pH and adding a balanced amount of water, a fiber treatment composition can be produced.
〔使用方法〕
繊維処理剤組成物は、従来のスプレー型の繊維処理剤と同様に使用できるが、噴霧機構を持つ容器（スプレー容器）から繊維製品へ噴霧して使用する方法が好ましい。
スプレー容器としては、トリガースプレー容器（直圧型又は蓄圧型）や、ディスペンサースプレー容器等が挙げられる。トリガースプレー容器の例は、特開平９-２６８４７３号公報、特開平９-２５６２７２号公報や、特開平１０-７６１９６号公報等に記載されている。ディスペンサースプレー容器の例は、特開平９-２５６２７２号公報等に記載されている。
繊維処理剤組成物は、噴霧機構を持たないプラスチック製容器（ボトル容器や詰替え用のスタンディングパウチ等）に収納されていてもよい。スタンディングパウチの例は、特開２０００-７２１８１号公報等に記載されている。スタンディングパウチは、繊維処理剤組成物の保存安定性の観点から、二層構造（内層：１００～２５０μｍの線状低密度ポリエチレン。外層：１５～３０μｍの延伸ナイロン）又は三層構造（内層：１００～２５０μｍの線状低密度ポリエチレン。中間層：１５μｍの延伸ナイロン。外層：１５μｍの延伸ナイロン）を有することが好ましい。
〔how to use〕
The fiber treatment agent composition can be used in the same manner as conventional spray-type fiber treatment agents, but it is preferable to use a method in which the composition is sprayed onto textile products from a container having a spray mechanism (spray container).
Examples of spray containers include trigger spray containers (direct pressure type or pressure accumulation type), dispenser spray containers, and the like. Examples of the trigger spray container are described in JP-A-9-268473, JP-A-9-256272, JP-A-10-76196, and the like. An example of a dispenser spray container is described in JP-A-9-256272.
The fiber treatment composition may be housed in a plastic container (a bottle container, a standing pouch for refilling, etc.) that does not have a spray mechanism. Examples of standing pouches are described in JP-A-2000-72181. The standing pouch has a two-layer structure (inner layer: linear low-density polyethylene of 100 to 250 μm, outer layer: stretched nylon of 15 to 30 μm) or a three-layer structure (inner layer: 100 μm) from the viewpoint of storage stability of the fiber treatment composition. ˜250 μm linear low density polyethylene, middle layer: 15 μm oriented nylon, outer layer: 15 μm oriented nylon).
処理される繊維製品の種類は特に限定されない。繊維製品の例としては、Ｙシャツ、Ｔシャツ、ポロシャツ、ブラウス、肌着、インナー（機能性インナーを含む）、チノパン、スーツ、スラックス、スカート、ストッキング、タイツ、ジャケット、コート、ニット、ジーンズ、パジャマ、クッション、座布団、ソファ、枕カバー、シーツ、ベッドパッド、枕、布団、ベッドカバー、毛布、マットレス、布マスクや、靴等が挙げられる。なかでも、肌に直接触れる肌着やインナー類では繊維処理剤組成物の効果が顕著に発現する。
繊維製品の素材も特に限定されない。素材の例としては、天然繊維（綿、ウール、麻等）、合成繊維（ポリエステル、ナイロン、アクリル等）、半合成繊維（アセテート等）、再生繊維（レーヨン、テンセル、ポリノジック等）、これらの混紡品、混織品や、混編品等が挙げられる。
The type of textile to be treated is not particularly limited. Examples of textile products include Y-shirts, T-shirts, polo shirts, blouses, underwear, innerwear (including functional innerwear), chino pants, suits, slacks, skirts, stockings, tights, jackets, coats, knitwear, jeans, pajamas, Cushions, floor cushions, sofas, pillowcases, sheets, bed pads, pillows, futons, bedspreads, blankets, mattresses, cloth masks, shoes, and the like. In particular, the effect of the fiber treatment composition is remarkably exhibited in underwear and innerwear that come into direct contact with the skin.
The material of the textile product is also not particularly limited. Examples of materials include natural fibers (cotton, wool, linen, etc.), synthetic fibers (polyester, nylon, acrylic, etc.), semi-synthetic fibers (acetate, etc.), regenerated fibers (rayon, tencel, polynosic, etc.), and blends of these. products, mixed woven products, and mixed knitted products.
以下、実施例により本発明を更に詳細に説明するが、本発明はこれに限定されるものではない。
尚、実施例及び比較例において、各成分の配合量（％）はすべて質量％（指定のある場合を除き、純分換算）を示す。
EXAMPLES The present invention will be described in more detail below with reference to examples, but the present invention is not limited to these examples.
In the examples and comparative examples, the blending amount (%) of each component is expressed in mass % (converted to pure content unless otherwise specified).
〔（Ａ）成分〕
下記のＡ－１を使用した。
Ａ－１：グリセリン（商品名：化粧品用グリセリン（８５質量％）。阪本薬品工業(株)製）
[(A) Component]
A-1 below was used.
A-1: Glycerin (trade name: cosmetic glycerin (85% by mass), manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.)
〔（Ｂ）成分〕
下記のＢ－１～Ｂ－７を使用した。Ｂ－１～Ｂ－４のＰＥＧの数平均分子量は、ＨＰＬＣ法に従い測定した値である。
Ｂ－１：数平均分子量が２００のＰＥＧ（商品名：PEG-200。三洋化成工業(株)製）
Ｂ－２：数平均分子量が４００のＰＥＧ（商品名：PEG-400。三洋化成工業(株)製）
Ｂ－３：数平均分子量が６００のＰＥＧ（商品名：PEG-600。三洋化成工業(株)製）
Ｂ－４：数平均分子量が１０００のＰＥＧ（商品名：PEG-1000。三洋化成工業(株)製）
Ｂ－５：イソプレングリコール（(株)クラレ製）
Ｂ－６：ジプロピレングリコール（旭硝子(株)製）
Ｂ－７：１，３－ブチレングリコール（(株)ダイセル製）（比較例で使用）
[(B) component]
The following B-1 to B-7 were used. The number average molecular weights of PEGs B-1 to B-4 are values measured according to the HPLC method.
B-1: PEG with a number average molecular weight of 200 (trade name: PEG-200, manufactured by Sanyo Chemical Industries, Ltd.)
B-2: PEG with a number average molecular weight of 400 (trade name: PEG-400, manufactured by Sanyo Chemical Industries, Ltd.)
B-3: PEG with a number average molecular weight of 600 (trade name: PEG-600, manufactured by Sanyo Chemical Industries, Ltd.)
B-4: PEG with a number average molecular weight of 1000 (trade name: PEG-1000, manufactured by Sanyo Chemical Industries Co., Ltd.)
B-5: Isoprene glycol (manufactured by Kuraray Co., Ltd.)
B-6: Dipropylene glycol (manufactured by Asahi Glass Co., Ltd.)
B-7: 1,3-butylene glycol (manufactured by Daicel Co., Ltd.) (used in Comparative Examples)
〔（Ｃ）成分〕
下記のＣ－１～Ｃ－２を使用した。
Ｃ－１：ＥＯの平均付加モル数が４０のポリオキシエチレン硬化ヒマシ油（商品名：ブラウノンＲＣＷ－４０。青木油脂(株)製）
Ｃ－２：ＥＯの平均付加モル数が６０のポリオキシエチレン硬化ヒマシ油（商品名：ブラウノンＲＣＷ－６０。青木油脂(株)製）
[(C) component]
The following C-1 to C-2 were used.
C-1: Polyoxyethylene hydrogenated castor oil with an average number of added moles of EO of 40 (trade name: Braunon RCW-40, manufactured by Aoki Yushi Co., Ltd.)
C-2: Polyoxyethylene hydrogenated castor oil with an average number of added moles of EO of 60 (trade name: Braunon RCW-60, manufactured by Aoki Yushi Co., Ltd.)
〔（Ｄ）成分：香料〕
下記表に示された組成を有する香料組成物Ｄ－１～Ｄ－７を使用した。表中の各香料成分の数値は、香料組成物の総質量に対する質量％である。
[(D) component: perfume]
Perfume compositions D-1 to D-7 having the compositions shown in the table below were used. The numerical value of each perfume component in the table is mass % with respect to the total mass of the perfume composition.
〔その他の成分〕
下記の共通成分Ａ～Ｂを使用した。表中の含量は、液体柔軟剤組成物の総質量に対する値である。
[Other ingredients]
Common components A to B below were used. The contents in the table are values relative to the total mass of the liquid softener composition.
共通成分Ａ
共通成分Ｂ
〔液体繊維処理剤組成物の調製方法〕
後記の表１に示す組成を有する繊維処理剤組成物を調製した。表１中、各成分の数値の単位（％）は、繊維処理剤組成物の総質量に対する質量％である。
表１中の「Ａ／Ｂ比」は、（Ａ）成分と（Ｂ）成分との質量比を示す。
[Method for preparing liquid fiber treatment composition]
A fiber treatment composition having the composition shown in Table 1 below was prepared. In Table 1, the unit (%) of the numerical value of each component is % by mass with respect to the total mass of the fiber treatment composition.
"A/B ratio" in Table 1 indicates the mass ratio between the (A) component and the (B) component.
繊維処理剤組成物を、次の手順により調製した。
（Ｃ）成分及び（Ｄ）成分をイオン交換水１０ｇへ添加して混合し、更に（Ａ）成分及び（Ｂ）成分を添加して均一になるまで混合した。得られた混合液へ共通成分を添加して混合してｐＨ５．０（２５℃）に調整し、更に全体質量が１００ｇとなるようにイオン交換水を添加混合して繊維処理剤組成物を得た。
A fiber treatment composition was prepared by the following procedure.
Components (C) and (D) were added to 10 g of deionized water and mixed, then components (A) and (B) were added and mixed until uniform. A common component is added to the resulting mixed solution and mixed to adjust the pH to 5.0 (25° C.), and ion-exchanged water is added and mixed so that the total mass becomes 100 g to obtain a fiber treatment composition. rice field.
繊維処理剤組成物の評価
繊維処理剤組成物を、「肌保湿機能の繊維製品への付与」、「処理された繊維製品のべたつき」及び「噴霧性状（均一な噴霧のしやすさ）」の観点で評価した。
Evaluation of the textile treatment composition The textile treatment composition was evaluated for “impartment of skin moisturizing function to textile products”, “stickiness of treated textile products” and “spray property (ease of uniform spraying)”. evaluated from that point of view.
１．肌保湿機能の繊維製品への付与
肌の保湿性を、その水分量の変化を指標として評価した。
はじめに、評価者の「肌水分量（初期）」を下記手順に従い測定した。被験者の前腕部を洗浄剤で洗浄し、流水ですすいだ後、タオルで十分に水分を吸い取った。その後、恒温室（２０℃、４０％ＲＨ）内で１０分間安静にした後、コルネオメーター（(株)インテグラル製）で肌水分量を測定した。
次に、繊維処理剤で処理した繊維製品を６時間適用した後の評価者の「肌水分量（６時間後）」を下記手順に従い測定した。化学繊維（ポリエステル３８％、アクリル３２％、レーヨン２１％、ポリウレタン９％）製のヒートテックインナー（(株)ユニクロ製）から試験布（１０ｃｍ×１０ｃｍ）を調製した。市販品（アロマリッチ香りミスト。ライオン(株)製）のディスペンサーボトル（噴霧機構付）を用いて、繊維処理剤組成物０．２ｇを試験布へ均一に噴霧し、３０分間以上乾燥させて、処理済試験布を調製した。処理済試験布を評価者の前腕部に貼付して６時間経過後、貼付部の肌水分量を測定した。測定は、恒温室（２０℃、４０％ＲＨ）内で１０分間安静にした後、コルネオメーター（(株)インテグラル製）を用いて行った。
前記の手順を評価者４名の左右の腕にて実施した。測定値を下記式に当てはめて肌の水分変化率（％）を算出した。
水分変化率（％）＝肌水分量（６時間後）／肌水分量（初期）×１００
評価者４名の水分変化率（％）の平均値を下記の判定基準へ適用して、「肌保湿機能を繊維製品へ付与する性能」の評価とした。結果を、表１の「保湿性」欄に示す。◎及び○を合格とした。
＜判定基準＞
◎：平均値が１３０％以上
○：平均値が１１０％以上１３０％未満
×：平均値が１１０％未満
1. Addition of skin moisturizing function to textile products The moisturizing properties of the skin were evaluated using the change in the water content as an index.
First, the evaluator's "skin moisture content (initial)" was measured according to the following procedure. The subject's forearm was washed with a cleanser, rinsed with running water, and then thoroughly soaked with a towel. After resting for 10 minutes in a constant temperature room (20° C., 40% RH), the skin moisture content was measured with a corneometer (manufactured by Integral Co., Ltd.).
Next, the evaluator's "skin moisture level (after 6 hours)" after applying the textile product treated with the textile treatment agent for 6 hours was measured according to the following procedure. A test cloth (10 cm×10 cm) was prepared from a heat tech inner (manufactured by Uniqlo Co., Ltd.) made of chemical fibers (38% polyester, 32% acrylic, 21% rayon, 9% polyurethane). 0.2 g of the textile treatment composition was evenly sprayed onto the test cloth using a commercial product (Aroma Rich Fragrance Mist, manufactured by Lion Co., Ltd.) using a dispenser bottle (with a spray mechanism), and dried for 30 minutes or longer. A treated test cloth was prepared. The treated test cloth was attached to the forearm of the evaluator, and after 6 hours had passed, the skin moisture content of the attached area was measured. The measurement was performed using a corneometer (manufactured by Integral Co., Ltd.) after resting for 10 minutes in a constant temperature room (20° C., 40% RH).
The above procedure was performed on the left and right arms of four evaluators. The skin moisture change rate (%) was calculated by applying the measured values to the following formula.
Moisture change rate (%) = skin moisture content (after 6 hours) / skin moisture content (initial) x 100
The average value of the rate of moisture change (%) of the 4 evaluators was applied to the following criteria for evaluation of "ability to impart skin moisturizing function to textile products". The results are shown in the "moisturizing property" column of Table 1. ⊚ and ◯ were regarded as passed.
<Judgment Criteria>
◎: Average value is 130% or more ○: Average value is 110% or more and less than 130% ×: Average value is less than 110%
２．処理された繊維製品のべたつき
前記１に記載の手順に従い試験布（１０ｃｍ×１０ｃｍ。１．４ｇ）を調製した。市販品（アロマリッチ香りミスト。ライオン(株)製）のディスペンサーボトル（噴霧機構付）を用いて、繊維処理剤組成物を試験布へ噴霧（噴霧量：１５％ｏ.ｗ.ｆ）して、処理済試験布を調製した。
噴霧した繊維処理剤組成物が乾燥する前に処理済試験布を手で触り、手になじませたときに評価者が感じるべたつき感を、下記の基準に従い官能評価した。評価者４名の平均点（小数点第１位まで算出）を、下記の判定基準に適用して、「処理された繊維製品のべたつき」の評価とした。結果を、表１の「べたつき」欄に示す。◎及び○を合格とした。
＜評価基準＞
５点：非常にべたつきがある
４点：かなりべたつきがある
３点：べたつきがある
２点：ややべたつきがある
１点：べたつきがない
＜判定基準＞
◎：平均点が２．０点未満
○：平均点が２．０点以上３．０点未満
×：平均点が３．０点以上
2. Tackiness of Treated Textiles Test fabrics (10 cm x 10 cm; 1.4 g) were prepared according to the procedure described in 1 above. Using a commercial product (Aroma Rich Fragrance Mist, manufactured by Lion Co., Ltd.) dispenser bottle (with a spray mechanism), the fiber treatment composition was sprayed onto the test cloth (spray amount: 15% o.w.f). , to prepare the treated test fabrics.
Before the sprayed fiber treatment composition dried, the treated test cloth was touched with a hand, and the stickiness felt by the evaluator when it was applied to the hand was sensory evaluated according to the following criteria. The average score of the four evaluators (calculated to the first decimal place) was applied to the following criteria to evaluate the "stickiness of the treated textile product". The results are shown in the "stickiness" column of Table 1. ⊚ and ◯ were regarded as passed.
<Evaluation Criteria>
5 points: very sticky 4 points: fairly sticky 3 points: sticky 2 points: slightly sticky 1 point: no stickiness
<Judgment Criteria>
◎: Average score is less than 2.0 points ○: Average score is 2.0 points or more and less than 3.0 points ×: Average score is 3.0 points or more
３．繊維処理剤組成物の噴霧性状
市販品（アロマリッチ香りミスト。ライオン(株)製）のディスペンサーボトル（噴霧機構付）を用いて、繊維処理剤組成物を、カラーブロード（青色。２０cm×２０cm）の中心部に１回全引き噴霧した。噴霧は、カラーブロードから２０ｃｍ離れた距離から行った。
均一な噴霧という観点からの噴霧性状を、下記の基準に従い評価した。評価者４名の平均点（小数点第１位まで算出）を、下記の判定基準に適用して、「繊維処理剤組成物の噴霧性状」の評価とした。結果を、表１の「噴霧性状」欄に示す。◎及び○を合格とした。
＜評価基準＞
２点：均一に噴霧できる
１点：やや均一に噴霧できる
０点：均一に噴霧できない
＜判定基準＞
◎：平均点が２．０点○：平均点が１．０点以上２．０点未満
×：平均点が１．０点未満
3. Atomization properties of the fiber treatment composition Using a dispenser bottle (with a spray mechanism) of a commercially available product (Aroma Rich Fragrance Mist, manufactured by Lion Co., Ltd.), the fiber treatment composition was applied to a color broad (blue, 20 cm x 20 cm). It was sprayed once in the center of the whole. Spraying was done from a distance of 20 cm from the color broad.
The spray property from the viewpoint of uniform spray was evaluated according to the following criteria. The average score of the four evaluators (calculated to the first decimal place) was applied to the following criteria to evaluate the "spray property of the fiber treatment composition". The results are shown in Table 1, "Atomization property" column. ⊚ and ◯ were regarded as passed.
<Evaluation Criteria>
2 points: can be sprayed uniformly 1 point: can be sprayed somewhat uniformly 0 points: cannot be sprayed uniformly
<Judgment Criteria>
◎: average score is 2.0 points ○: average score is 1.0 points or more and less than 2.0 points ×: average score is less than 1.0 points
４．その他の評価 4. Other evaluation
本発明は、繊維処理剤分野で利用可能である。 INDUSTRIAL APPLICABILITY The present invention can be used in the field of textile treatment agents.
Claims (8)
（Ａ）グリセリンと、（Ｂ）ポリエチレングリコール、イソプレングリコール及びジプロピレングリコールからなる群から選ばれる１種以上とを含み、
前記繊維処理剤組成物の総質量に対して、（Ａ）成分の含量が２０～５０質量％であり、（Ｂ）成分の含量が５～２０質量％であることを特徴とする、繊維処理剤組成物。 A spray-type fiber treatment composition,
(A) glycerin and (B) one or more selected from the group consisting of polyethylene glycol, isoprene glycol and dipropylene glycol,
A fiber treatment characterized in that the content of component (A) is 20 to 50% by mass and the content of component (B) is 5 to 20% by mass with respect to the total mass of the fiber treatment composition. agent composition.
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| JP2021060287A JP2022156544A (en) | 2021-03-31 | 2021-03-31 | Sprayable fiber treatment agent composition |
| KR1020220037333A KR20220136183A (en) | 2021-03-31 | 2022-03-25 | Fiber processing agent composition of spray type |
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| JP2000256148A (en) | 1999-03-12 | 2000-09-19 | Nippon Starch Chemical Co Ltd | Hair cosmetic |
| JP4892400B2 (en) | 2007-04-24 | 2012-03-07 | ライオン株式会社 | Moisturizing agent composition and method for modifying moisturizing property of soft solid surface |
| JP2010006725A (en) | 2008-06-25 | 2010-01-14 | Kao Corp | Skin cosmetic |
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