JP7454337B2 - Treatment agent composition for textile products - Google Patents
Treatment agent composition for textile products Download PDFInfo
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- JP7454337B2 JP7454337B2 JP2019082559A JP2019082559A JP7454337B2 JP 7454337 B2 JP7454337 B2 JP 7454337B2 JP 2019082559 A JP2019082559 A JP 2019082559A JP 2019082559 A JP2019082559 A JP 2019082559A JP 7454337 B2 JP7454337 B2 JP 7454337B2
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- agent composition
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- 239000000203 mixture Substances 0.000 title claims description 79
- 239000004753 textile Substances 0.000 title claims description 65
- 239000000178 monomer Substances 0.000 claims description 64
- 239000003795 chemical substances by application Substances 0.000 claims description 53
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 39
- 239000004332 silver Substances 0.000 claims description 39
- 229910052709 silver Inorganic materials 0.000 claims description 37
- 238000012545 processing Methods 0.000 claims description 35
- -1 alkyl methacrylates Chemical class 0.000 claims description 29
- 229920000642 polymer Polymers 0.000 claims description 27
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 21
- 239000003205 fragrance Substances 0.000 claims description 20
- 150000003839 salts Chemical class 0.000 claims description 18
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 13
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 10
- 239000002775 capsule Substances 0.000 claims description 10
- 229920001577 copolymer Polymers 0.000 claims description 10
- CIEZZGWIJBXOTE-UHFFFAOYSA-N 2-[bis(carboxymethyl)amino]propanoic acid Chemical compound OC(=O)C(C)N(CC(O)=O)CC(O)=O CIEZZGWIJBXOTE-UHFFFAOYSA-N 0.000 claims description 9
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 9
- 125000005250 alkyl acrylate group Chemical group 0.000 claims description 8
- 239000002738 chelating agent Substances 0.000 claims description 8
- 239000004599 antimicrobial Substances 0.000 claims 1
- 239000004744 fabric Substances 0.000 description 23
- 230000000844 anti-bacterial effect Effects 0.000 description 22
- 229910052708 sodium Inorganic materials 0.000 description 22
- 239000011734 sodium Substances 0.000 description 22
- 125000000217 alkyl group Chemical group 0.000 description 20
- 229920001296 polysiloxane Polymers 0.000 description 19
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 18
- 239000003242 anti bacterial agent Substances 0.000 description 17
- 238000012360 testing method Methods 0.000 description 17
- 235000019645 odor Nutrition 0.000 description 16
- 125000000623 heterocyclic group Chemical group 0.000 description 15
- 239000007921 spray Substances 0.000 description 15
- 229920002125 Sokalan® Polymers 0.000 description 14
- 230000001877 deodorizing effect Effects 0.000 description 14
- 238000003860 storage Methods 0.000 description 14
- 239000000126 substance Substances 0.000 description 14
- 125000004432 carbon atom Chemical group C* 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 11
- 150000001875 compounds Chemical class 0.000 description 11
- 238000011156 evaluation Methods 0.000 description 11
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 10
- 229910052783 alkali metal Inorganic materials 0.000 description 10
- 210000004243 sweat Anatomy 0.000 description 9
- 241000894006 Bacteria Species 0.000 description 8
- 239000002253 acid Substances 0.000 description 8
- 150000001340 alkali metals Chemical class 0.000 description 8
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 8
- 238000002156 mixing Methods 0.000 description 8
- 239000002245 particle Substances 0.000 description 8
- 239000003431 cross linking reagent Substances 0.000 description 7
- 238000002845 discoloration Methods 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical class C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 6
- 229920000742 Cotton Polymers 0.000 description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 5
- 241000191967 Staphylococcus aureus Species 0.000 description 5
- 230000000845 anti-microbial effect Effects 0.000 description 5
- 239000002736 nonionic surfactant Substances 0.000 description 5
- 125000006353 oxyethylene group Chemical group 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- PQHYOGIRXOKOEJ-UHFFFAOYSA-N 2-(1,2-dicarboxyethylamino)butanedioic acid Chemical compound OC(=O)CC(C(O)=O)NC(C(O)=O)CC(O)=O PQHYOGIRXOKOEJ-UHFFFAOYSA-N 0.000 description 4
- XFCMNSHQOZQILR-UHFFFAOYSA-N 2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOC(=O)C(C)=C XFCMNSHQOZQILR-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 239000004677 Nylon Substances 0.000 description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 4
- 125000002947 alkylene group Chemical group 0.000 description 4
- 229940121375 antifungal agent Drugs 0.000 description 4
- 239000003429 antifungal agent Substances 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 229920001778 nylon Polymers 0.000 description 4
- 239000003002 pH adjusting agent Substances 0.000 description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- 150000005846 sugar alcohols Chemical class 0.000 description 4
- 230000037303 wrinkles Effects 0.000 description 4
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 3
- JPGSFSFMINKKJZ-UHFFFAOYSA-N 2-[1,2-dicarboxyethyl(hydroxy)amino]butanedioic acid Chemical compound OC(=O)CC(C(O)=O)N(O)C(CC(O)=O)C(O)=O JPGSFSFMINKKJZ-UHFFFAOYSA-N 0.000 description 3
- 229920001817 Agar Polymers 0.000 description 3
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000008272 agar Substances 0.000 description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 3
- 150000001342 alkaline earth metals Chemical class 0.000 description 3
- 125000003342 alkenyl group Chemical group 0.000 description 3
- 125000004450 alkenylene group Chemical group 0.000 description 3
- 239000001506 calcium phosphate Substances 0.000 description 3
- 150000001735 carboxylic acids Chemical class 0.000 description 3
- 125000004122 cyclic group Chemical group 0.000 description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 3
- 239000000284 extract Substances 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000002304 perfume Substances 0.000 description 3
- 239000002504 physiological saline solution Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 239000004584 polyacrylic acid Substances 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 150000003378 silver Chemical class 0.000 description 3
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 239000008399 tap water Substances 0.000 description 3
- 235000020679 tap water Nutrition 0.000 description 3
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 description 2
- LEJBBGNFPAFPKQ-UHFFFAOYSA-N 2-(2-prop-2-enoyloxyethoxy)ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOC(=O)C=C LEJBBGNFPAFPKQ-UHFFFAOYSA-N 0.000 description 2
- HCLJOFJIQIJXHS-UHFFFAOYSA-N 2-[2-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethoxy]ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOCCOCCOC(=O)C=C HCLJOFJIQIJXHS-UHFFFAOYSA-N 0.000 description 2
- DXYYSGDWQCSKKO-UHFFFAOYSA-N 2-methylbenzothiazole Chemical compound C1=CC=C2SC(C)=NC2=C1 DXYYSGDWQCSKKO-UHFFFAOYSA-N 0.000 description 2
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 2
- UWRBFYBQPCJRRL-UHFFFAOYSA-N 3-[bis(carboxymethyl)amino]propanoic acid Chemical compound OC(=O)CCN(CC(O)=O)CC(O)=O UWRBFYBQPCJRRL-UHFFFAOYSA-N 0.000 description 2
- 101100219283 Amycolatopsis orientalis cyp165C4 gene Proteins 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 229920000877 Melamine resin Polymers 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 2
- 241000282320 Panthera leo Species 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 2
- LCTONWCANYUPML-UHFFFAOYSA-N Pyruvic acid Chemical compound CC(=O)C(O)=O LCTONWCANYUPML-UHFFFAOYSA-N 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 description 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- WDJHALXBUFZDSR-UHFFFAOYSA-N acetoacetic acid Chemical compound CC(=O)CC(O)=O WDJHALXBUFZDSR-UHFFFAOYSA-N 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- 235000001014 amino acid Nutrition 0.000 description 2
- 150000001413 amino acids Chemical class 0.000 description 2
- 229920003180 amino resin Polymers 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 238000000149 argon plasma sintering Methods 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical compound C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- DDRJAANPRJIHGJ-UHFFFAOYSA-N creatinine Chemical compound CN1CC(=O)NC1=N DDRJAANPRJIHGJ-UHFFFAOYSA-N 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 125000004386 diacrylate group Chemical group 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 125000005842 heteroatom Chemical group 0.000 description 2
- 150000002460 imidazoles Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 239000003094 microcapsule Substances 0.000 description 2
- 239000012452 mother liquor Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 2
- 229920000053 polysorbate 80 Polymers 0.000 description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 2
- 230000001603 reducing effect Effects 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 229940019931 silver phosphate Drugs 0.000 description 2
- 229910000161 silver phosphate Inorganic materials 0.000 description 2
- YPNVIBVEFVRZPJ-UHFFFAOYSA-L silver sulfate Chemical compound [Ag+].[Ag+].[O-]S([O-])(=O)=O YPNVIBVEFVRZPJ-UHFFFAOYSA-L 0.000 description 2
- 229910000367 silver sulfate Inorganic materials 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 239000012209 synthetic fiber Substances 0.000 description 2
- 229940078499 tricalcium phosphate Drugs 0.000 description 2
- 229910000391 tricalcium phosphate Inorganic materials 0.000 description 2
- 235000019731 tricalcium phosphate Nutrition 0.000 description 2
- MDYOLVRUBBJPFM-UHFFFAOYSA-N tropolone Chemical compound OC1=CC=CC=CC1=O MDYOLVRUBBJPFM-UHFFFAOYSA-N 0.000 description 2
- 239000000341 volatile oil Substances 0.000 description 2
- 239000003021 water soluble solvent Substances 0.000 description 2
- 210000002268 wool Anatomy 0.000 description 2
- VKZRWSNIWNFCIQ-WDSKDSINSA-N (2s)-2-[2-[[(1s)-1,2-dicarboxyethyl]amino]ethylamino]butanedioic acid Chemical compound OC(=O)C[C@@H](C(O)=O)NCCN[C@H](C(O)=O)CC(O)=O VKZRWSNIWNFCIQ-WDSKDSINSA-N 0.000 description 1
- DCCWEYXHEXDZQW-BYPYZUCNSA-N (2s)-2-[bis(carboxymethyl)amino]butanedioic acid Chemical compound OC(=O)C[C@@H](C(O)=O)N(CC(O)=O)CC(O)=O DCCWEYXHEXDZQW-BYPYZUCNSA-N 0.000 description 1
- NWRZGFYWENINNX-UHFFFAOYSA-N 1,1,2-tris(ethenyl)cyclohexane Chemical compound C=CC1CCCCC1(C=C)C=C NWRZGFYWENINNX-UHFFFAOYSA-N 0.000 description 1
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 description 1
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
- WVAFEFUPWRPQSY-UHFFFAOYSA-N 1,2,3-tris(ethenyl)benzene Chemical compound C=CC1=CC=CC(C=C)=C1C=C WVAFEFUPWRPQSY-UHFFFAOYSA-N 0.000 description 1
- MYWOJODOMFBVCB-UHFFFAOYSA-N 1,2,6-trimethylphenanthrene Chemical compound CC1=CC=C2C3=CC(C)=CC=C3C=CC2=C1C MYWOJODOMFBVCB-UHFFFAOYSA-N 0.000 description 1
- ZJQIXGGEADDPQB-UHFFFAOYSA-N 1,2-bis(ethenyl)-3,4-dimethylbenzene Chemical group CC1=CC=C(C=C)C(C=C)=C1C ZJQIXGGEADDPQB-UHFFFAOYSA-N 0.000 description 1
- QLLUAUADIMPKIH-UHFFFAOYSA-N 1,2-bis(ethenyl)naphthalene Chemical compound C1=CC=CC2=C(C=C)C(C=C)=CC=C21 QLLUAUADIMPKIH-UHFFFAOYSA-N 0.000 description 1
- JLHMJWHSBYZWJJ-UHFFFAOYSA-N 1,2-thiazole 1-oxide Chemical compound O=S1C=CC=N1 JLHMJWHSBYZWJJ-UHFFFAOYSA-N 0.000 description 1
- VDYWHVQKENANGY-UHFFFAOYSA-N 1,3-Butyleneglycol dimethacrylate Chemical compound CC(=C)C(=O)OC(C)CCOC(=O)C(C)=C VDYWHVQKENANGY-UHFFFAOYSA-N 0.000 description 1
- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 description 1
- SAMJGBVVQUEMGC-UHFFFAOYSA-N 1-ethenoxy-2-(2-ethenoxyethoxy)ethane Chemical compound C=COCCOCCOC=C SAMJGBVVQUEMGC-UHFFFAOYSA-N 0.000 description 1
- QWENRTYMTSOGBR-UHFFFAOYSA-N 1H-1,2,3-Triazole Chemical compound C=1C=NNN=1 QWENRTYMTSOGBR-UHFFFAOYSA-N 0.000 description 1
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 1
- NQIGCLPMTVXOHS-UHFFFAOYSA-N 1h-1,2,4-triazole;2h-triazole Chemical compound C1=CNN=N1.C=1N=CNN=1 NQIGCLPMTVXOHS-UHFFFAOYSA-N 0.000 description 1
- FCMUPMSEVHVOSE-UHFFFAOYSA-N 2,3-bis(ethenyl)pyridine Chemical compound C=CC1=CC=CN=C1C=C FCMUPMSEVHVOSE-UHFFFAOYSA-N 0.000 description 1
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- NZIDBRBFGPQCRY-UHFFFAOYSA-N octyl 2-methylprop-2-enoate Chemical compound CCCCCCCCOC(=O)C(C)=C NZIDBRBFGPQCRY-UHFFFAOYSA-N 0.000 description 1
- 229940065472 octyl acrylate Drugs 0.000 description 1
- ANISOHQJBAQUQP-UHFFFAOYSA-N octyl prop-2-enoate Chemical compound CCCCCCCCOC(=O)C=C ANISOHQJBAQUQP-UHFFFAOYSA-N 0.000 description 1
- 239000002420 orchard Substances 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 description 1
- OTCVAHKKMMUFAY-UHFFFAOYSA-N oxosilver Chemical class [Ag]=O OTCVAHKKMMUFAY-UHFFFAOYSA-N 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- DSQPRECRRGZSCV-UHFFFAOYSA-N penta-1,4-dien-3-yl(phenyl)silane Chemical compound C=CC([SiH2]c1ccccc1)C=C DSQPRECRRGZSCV-UHFFFAOYSA-N 0.000 description 1
- DBSDMAPJGHBWAL-UHFFFAOYSA-N penta-1,4-dien-3-ylbenzene Chemical compound C=CC(C=C)C1=CC=CC=C1 DBSDMAPJGHBWAL-UHFFFAOYSA-N 0.000 description 1
- VYRLHRGPAOAVTO-UHFFFAOYSA-N penta-1,4-dien-3-ylsilane Chemical compound [SiH3]C(C=C)C=C VYRLHRGPAOAVTO-UHFFFAOYSA-N 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 229960003330 pentetic acid Drugs 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003009 phosphonic acids Chemical class 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229940113115 polyethylene glycol 200 Drugs 0.000 description 1
- 229940057847 polyethylene glycol 600 Drugs 0.000 description 1
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
- 229940068968 polysorbate 80 Drugs 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- DOKHEARVIDLSFF-UHFFFAOYSA-N prop-1-en-1-ol Chemical group CC=CO DOKHEARVIDLSFF-UHFFFAOYSA-N 0.000 description 1
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 1
- NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 150000003216 pyrazines Chemical class 0.000 description 1
- PBMFSQRYOILNGV-UHFFFAOYSA-N pyridazine Chemical compound C1=CC=NN=C1 PBMFSQRYOILNGV-UHFFFAOYSA-N 0.000 description 1
- 150000003230 pyrimidines Chemical class 0.000 description 1
- 229940107700 pyruvic acid Drugs 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 229910001923 silver oxide Inorganic materials 0.000 description 1
- PDIOQTZFYGBGHQ-UHFFFAOYSA-M sodium 2-(tetradecylamino)propanoate Chemical compound C(CCCCCCCCCCCCC)NC(C(=O)[O-])C.[Na+] PDIOQTZFYGBGHQ-UHFFFAOYSA-M 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- INTUQOSSEHSSKT-UHFFFAOYSA-M sodium;2-(decylamino)propanoate Chemical compound [Na+].CCCCCCCCCCNC(C)C([O-])=O INTUQOSSEHSSKT-UHFFFAOYSA-M 0.000 description 1
- FRHOIPVLDOWSFE-UHFFFAOYSA-M sodium;2-(dodecylamino)acetate Chemical compound [Na+].CCCCCCCCCCCCNCC([O-])=O FRHOIPVLDOWSFE-UHFFFAOYSA-M 0.000 description 1
- LHKHNDVWESBUHO-UHFFFAOYSA-M sodium;2-(octylamino)acetate Chemical compound [Na+].CCCCCCCCNCC([O-])=O LHKHNDVWESBUHO-UHFFFAOYSA-M 0.000 description 1
- HOEOLRWNNOQQPL-UHFFFAOYSA-M sodium;2-(octylamino)propanoate Chemical compound [Na+].CCCCCCCCNC(C)C([O-])=O HOEOLRWNNOQQPL-UHFFFAOYSA-M 0.000 description 1
- WODKRKDGMWZLCP-UHFFFAOYSA-M sodium;2-(tetradecylamino)acetate Chemical compound [Na+].CCCCCCCCCCCCCCNCC([O-])=O WODKRKDGMWZLCP-UHFFFAOYSA-M 0.000 description 1
- HWCHICTXVOMIIF-UHFFFAOYSA-M sodium;3-(dodecylamino)propanoate Chemical compound [Na+].CCCCCCCCCCCCNCCC([O-])=O HWCHICTXVOMIIF-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000001593 sorbitan monooleate Substances 0.000 description 1
- 229940035049 sorbitan monooleate Drugs 0.000 description 1
- 235000011069 sorbitan monooleate Nutrition 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 150000003536 tetrazoles Chemical class 0.000 description 1
- 125000000437 thiazol-2-yl group Chemical group [H]C1=C([H])N=C(*)S1 0.000 description 1
- 125000004495 thiazol-4-yl group Chemical group S1C=NC(=C1)* 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- PKRKCDBTXBGLKV-UHFFFAOYSA-N tris(ethenyl)-methylsilane Chemical compound C=C[Si](C)(C=C)C=C PKRKCDBTXBGLKV-UHFFFAOYSA-N 0.000 description 1
- BNCOGDMUGQWFQE-UHFFFAOYSA-N tris(ethenyl)silicon Chemical compound C=C[Si](C=C)C=C BNCOGDMUGQWFQE-UHFFFAOYSA-N 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- 229940038773 trisodium citrate Drugs 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical compound [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
- 229910000166 zirconium phosphate Inorganic materials 0.000 description 1
- LEHFSLREWWMLPU-UHFFFAOYSA-B zirconium(4+);tetraphosphate Chemical compound [Zr+4].[Zr+4].[Zr+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LEHFSLREWWMLPU-UHFFFAOYSA-B 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
本発明は、繊維製品用処理剤組成物に関する。詳細には、本発明は、保存安定性、抗菌性及び／又は消臭性が良好な繊維製品用処理剤組成物に関する。 The present invention relates to a treatment agent composition for textile products. In particular, the present invention relates to a treatment composition for textile products that has good storage stability, antibacterial properties, and/or deodorizing properties.
近年、除菌、消臭、防臭、香り、しわとりなど、家庭用の繊維製品用スプレーが多数発売されており、その市場は年々増加している。その中でも、ニオイに対する関心や衛生意識の高まりから、いずれの繊維製品用スプレーにおいても抗菌性能や消臭性能は必須性能である。
しかしながら、抗菌性能や消臭性能の付与を目的として、抗菌剤である銀やカチオン性界面活性剤と消臭剤であるキレート剤とを配合する方法が挙げられるものの（特許文献１～３）、銀とキレート剤の組み合わせは保存安定性の悪化（変色）が著しく、店頭での販売場面やお客様の実使用場面において不具合が生じる可能性がある。
In recent years, many household sprays for textile products, such as disinfecting, deodorizing, deodorizing, fragrance, and anti-wrinkle sprays, have been released, and the market for them is increasing year by year. Among these, antibacterial and deodorizing properties are essential for any spray for textile products due to the growing concern about odors and hygiene awareness.
However, for the purpose of imparting antibacterial and deodorizing properties, there are methods of blending antibacterial agents such as silver or cationic surfactants with deodorants such as chelating agents (Patent Documents 1 to 3); The combination of silver and chelating agent has a significant deterioration in storage stability (discoloration), which may cause problems when sold at stores or when used by customers.
上記に鑑みて、本発明は、保存安定性、抗菌性及び消臭性が良好な繊維製品用処理剤組成物を提供することを目的とする。 In view of the above, an object of the present invention is to provide a treatment agent composition for textile products that has good storage stability, antibacterial properties, and deodorizing properties.
このような課題に対し、特定のアクリル酸系高分子を銀系抗菌剤及びキレート剤と組み合わせて用いることで、保存安定性、抗菌性及び消臭性を満たす組成を見出した。
即ち、本発明は、下記〔１〕～〔５〕に関するものである。
〔１〕（Ａ）錯体銀、担体に担持された銀、及び無機銀塩から選ばれる少なくとも１種の銀系抗菌剤、
（Ｂ）キレート剤、及び
（Ｃ）アクリル酸アルキル及びメタクリル酸アルキルから選ばれるモノマーに由来する１種以上のモノマー単位と、アクリル酸及びメタクリル酸から選ばれるモノマーに由来する１種以上のモノマー単位とを含有する共重合体（銀と錯体化したものを除く）
を含む、繊維製品用処理剤組成物。
〔２〕（Ａ）成分が、ポリマーと錯体化された銀である、前記〔１〕に記載の繊維製品用処理剤組成物。
〔３〕（Ｂ）成分が、メチルグリシンジ酢酸もしくはクエン酸、又はそれらの塩である、前記〔１〕又は〔２〕に記載の繊維製品用処理剤組成物。
〔４〕（Ａ）成分として、ポリマーと錯体化された銀を０．００１～１質量％、（Ｂ）成分として、メチルグリシンジ酢酸もしくはクエン酸、又はそれらの塩を０．０１～１質量％、（Ｃ）成分として、アクリル酸アルキル及びメタクリル酸アルキルから選ばれるモノマーに由来する１種以上のモノマー単位と、アクリル酸及びメタクリル酸から選ばれるモノマーに由来する１種以上のモノマー単位とを含有する架橋型共重合体（銀と錯体化したものを除く）を０．０２～５．０質量％含む、前記〔１〕～〔３〕のいずれか１項に記載の繊維製品用処理剤組成物。
〔５〕（Ｄ）カプセル香料を更に含む、前記〔１〕～〔４〕のいずれか１項に記載の繊維製品用処理剤組成物。
To address these issues, we have discovered a composition that satisfies storage stability, antibacterial properties, and deodorizing properties by using a specific acrylic acid-based polymer in combination with a silver-based antibacterial agent and a chelating agent.
That is, the present invention relates to the following [1] to [5].
[1] (A) at least one silver-based antibacterial agent selected from complex silver, silver supported on a carrier, and inorganic silver salts;
(B) a chelating agent, and (C) one or more monomer units derived from a monomer selected from alkyl acrylates and alkyl methacrylates, and one or more monomer units derived from monomers selected from acrylic acid and methacrylic acid. Copolymers containing (excluding those complexed with silver)
A treatment agent composition for textile products, comprising:
[2] The textile processing agent composition according to [1] above, wherein the component (A) is silver complexed with a polymer.
[3] The textile processing agent composition according to [1] or [2] above, wherein the component (B) is methylglycine diacetic acid, citric acid, or a salt thereof.
[4] As component (A), 0.001 to 1% by mass of silver complexed with a polymer; as component (B), 0.01 to 1% by mass of methylglycine diacetic acid or citric acid, or a salt thereof %, as component (C), one or more monomer units derived from a monomer selected from alkyl acrylates and alkyl methacrylates, and one or more monomer units derived from monomers selected from acrylic acid and methacrylic acid. The processing agent for textile products according to any one of [1] to [3] above, which contains 0.02 to 5.0% by mass of a crosslinked copolymer (excluding those complexed with silver). Composition.
[5] The textile product treatment composition according to any one of [1] to [4] above, further comprising (D) a capsule fragrance.
本発明の一態様によれば、保存安定性が良好な繊維製品用処理剤組成物を提供することができる。
本発明の一態様によれば、抗菌性が良好な繊維製品用処理剤組成物を提供することができる。
本発明の一態様によれば、消臭性が良好な繊維製品用処理剤組成物を提供することができる。
本発明の一態様によれば、保存安定性、抗菌性及び消臭性が良好な繊維製品用処理剤組成物を提供することができる。
According to one aspect of the present invention, it is possible to provide a treatment agent composition for textile products that has good storage stability.
According to one aspect of the present invention, it is possible to provide a textile processing agent composition with good antibacterial properties.
According to one aspect of the present invention, it is possible to provide a treatment agent composition for textile products that has good deodorizing properties.
According to one aspect of the present invention, it is possible to provide a treatment agent composition for textile products that has good storage stability, antibacterial properties, and deodorizing properties.
［（Ａ）成分］
本発明の繊維製品用処理剤組成物は、（Ａ）成分として、錯体銀、担体に担持された銀、及び無機銀塩から選ばれる少なくとも１種の銀系抗菌剤を含有する。（Ａ）成分は、主に抗菌性能付与のために配合される。
[(A) Component]
The textile processing agent composition of the present invention contains, as component (A), at least one silver-based antibacterial agent selected from complex silver, silver supported on a carrier, and inorganic silver salts. Component (A) is mainly blended to impart antibacterial performance.
〈（Ａ－１）成分：錯体銀〉
（Ａ－１）成分としては、銀とアミノ酸（ヒスチジン、アルギニン、クレアチニン等）との錯体、銀とカルボン酸（ピルビン酸、グリコール酸、酢酸、酪酸、サリチル酸等）との錯体、銀とカルボン酸とアミノ酸との錯体、銀とイミダゾール誘導体との錯体等が挙げられる。このような錯体銀は市販品を使用することができ、例えば、大和化学工業株式会社製ＡＡ－１２５Ａｇを使用することができる。
なお、（Ａ－１）成分は、１種を単独で又は２種以上を混合して用いることができる。
<(A-1) Component: Complex silver>
(A-1) Components include complexes of silver and amino acids (histidine, arginine, creatinine, etc.), complexes of silver and carboxylic acids (pyruvic acid, glycolic acid, acetic acid, butyric acid, salicylic acid, etc.), silver and carboxylic acids, etc. Examples include a complex between silver and an amino acid, and a complex between silver and an imidazole derivative. A commercially available product can be used as such complex silver, and for example, AA-125Ag manufactured by Daiwa Chemical Industry Co., Ltd. can be used.
Note that component (A-1) can be used alone or in a mixture of two or more.
（Ａ－１）成分としては、また、ポリマーと錯体化した銀を用いることができる。このような場合、ポリマーと錯体化した銀中の銀元素の含有量は、その総質量に対し、例えば、０．１～６０質量％、あるいは０．５～１５質量％、あるいは２０～１００，０００ｐｐｍ、あるいは少なくとも２０ｐｐｍ、あるいは２０～４，０００ｐｐｍ、あるいは２０～１，５００ｐｐｍ、あるいは３０～７５ｐｐｍ、あるいは少なくとも５０ｐｐｍである。
ポリマーと錯体化した銀としては、下式（１）で表される単位Ａ、下式（２）で表される単位Ｂ、及び下式（３）で表される単位Ｃからなる群から選ばれる少なくとも１種のモノマー単位を含有するポリマーが挙げられる（但し、前記ポリマーの総質量に対し、前記単位Ｂの割合は９９．５質量％以下である）。
As component (A-1), silver complexed with a polymer can also be used. In such a case, the content of silver element in the silver complexed with the polymer is, for example, 0.1 to 60% by mass, or 0.5 to 15% by mass, or 20 to 100% by mass, based on the total mass. 000 ppm, alternatively at least 20 ppm, alternatively from 20 to 4,000 ppm, alternatively from 20 to 1,500 ppm, alternatively from 30 to 75 ppm, alternatively at least 50 ppm.
The silver complexed with the polymer is selected from the group consisting of unit A represented by the following formula (1), unit B represented by the following formula (2), and unit C represented by the following formula (3). (However, the proportion of the unit B is 99.5% by mass or less based on the total mass of the polymer.)
ｎは、０又は１であり、
Ｒ1は、Ｈ、ＣＨ3、及びＣＯ2Ｒ4から選択され、
Ｒ4は、Ｈ、ＣＨ3、Ｃ2Ｈ5、及びＣ3～Ｃ24アルキル基から選択され、
Ｒ2は、Ｈ、ＣＨ3、Ｃ2Ｈ5、フェニル基、ＣＨ2ＣＯ2Ｒ5、及びＣＯ2Ｒ5から選択され、
Ｒ5は、Ｈ、グリシジル基、（ＣＨ2ＣＨＲ11Ｏ）mＨ、（ＣＨ2ＣＨＲ11Ｏ）m－ＣＯＣＨ2ＣＯＣＨ3、及びＣＨ2ＣＨ（ＯＨ）ＣＨ2Ｑから選択され、
Ｒ11は、Ｈ、ＣＨ3、及びフェニル基から選択され、
ｍは、１～２０の整数であり、
Ｑは、ＯＨ、ＳＯ3Ｚ、及びＸから選択され、
Ｚは、Ｈ、Ｎａ、Ｋ、及びＮＨ4
+から選択され、
Ｒ3は、Ｈ、ＣＨ3、フェニル基、スルホン化フェニル基、ヒドロキシフェニル基、アセテート基、ヒドロキシ基、フラグメントＯ－Ｒ1、ＣＯ2Ｒ12、及びＣＯＮＲ6Ｒ7から選択され、
Ｒ12は、Ｈ、ＣＨ3、Ｃ2Ｈ5、及びＣ3～Ｃ24アルキル基から選択され、
Ｒ6及びＲ7は、それぞれ独立に、Ｈ、ＣＨ3、Ｃ2Ｈ5、Ｃ（ＣＨ3）2ＣＨ2ＳＯ3Ｚ、及びＣ3～Ｃ8アルキル基から選択され、
Ｒ8及びＲ9は、それぞれ独立に、Ｈ、ＣＨ3、Ｃ2Ｈ5、及びＣ3～Ｃ24アルキル基から選択され、
Ｒ10は、Ｃ1～Ｃ8アルキレン基、Ｃ2～Ｃ8アルケニレン基、Ｃ6～Ｃ10不飽和非環式基、Ｃ6～Ｃ10環式基、Ｃ6～Ｃ10の芳香族基、オキシＣ2～Ｃ4アルキレン基、及びポリ（オキシＣ2～Ｃ4アルキレン）b基から選択され、
ｂは、２～２０の整数であり、
但し、前記ポリマーに前記単位Ｂ及び前記単位Ｃが含有されていない場合、Ｒ2はＣＨ2ＣＯ2Ｒ5又はＣＯ2Ｒ5であり、Ｒ5はＣＨ2ＣＨ（ＯＨ）ＣＨ2Ｑであり、ＱはＸである。
n is 0 or 1,
R 1 is selected from H, CH 3 and CO 2 R 4 ,
R 4 is selected from H, CH 3 , C 2 H 5 , and C 3 -C 24 alkyl groups;
R2 is selected from H, CH3 , C2H5 , phenyl group , CH2CO2R5 , and CO2R5 ;
R 5 is selected from H, a glycidyl group, (CH 2 CHR 11 O) m H, (CH 2 CHR 11 O) m -COCH 2 COCH 3 , and CH 2 CH(OH)CH 2 Q;
R 11 is selected from H, CH 3 and phenyl group,
m is an integer from 1 to 20,
Q is selected from OH, SO 3 Z, and X;
Z is selected from H, Na, K, and NH4 + ;
R 3 is selected from H, CH 3 , phenyl group, sulfonated phenyl group, hydroxyphenyl group, acetate group, hydroxy group, fragment O-R 1 , CO 2 R 12 , and CONR 6 R 7 ;
R 12 is selected from H, CH 3 , C 2 H 5 , and C 3 -C 24 alkyl groups;
R 6 and R 7 are each independently selected from H, CH 3 , C 2 H 5 , C(CH 3 ) 2 CH 2 SO 3 Z, and a C 3 -C 8 alkyl group;
R 8 and R 9 are each independently selected from H, CH 3 , C 2 H 5 , and C 3 -C 24 alkyl groups;
R 10 is a C 1 to C 8 alkylene group, a C 2 to C 8 alkenylene group, a C 6 to C 10 unsaturated acyclic group, a C 6 to C 10 cyclic group, a C 6 to C 10 aromatic group , oxyC 2 -C 4 alkylene groups, and poly(oxyC 2 -C 4 alkylene) b groups,
b is an integer from 2 to 20,
However, when the polymer does not contain the unit B and the unit C, R 2 is CH 2 CO 2 R 5 or CO 2 R 5 , and R 5 is CH 2 CH(OH)CH 2 Q. , Q is X.
上記式（１）～（３）において、「アルキル」には、直鎖、分枝鎖及び環式アルキル基が含まれ、「アルキレン」には、直鎖、分枝鎖及び環式アルキレン基が含まれ、「アルケニレン」には、直鎖及び分枝鎖アルケニレン基が含まれる。
不飽和又は芳香族複素環には、例えば、不飽和結合を有する５員～７員の複素環；Ｎ、Ｏ及びＳからなる群から選択される少なくとも１種のヘテロ原子を有する芳香族複素環；このような複素環の異性体及びこれらの組合せが含まれる。更に、適切な複素環には、例えば、一緒に縮合して、少なくとも１個のＮ、Ｏ又はＳ原子を有する、より大きな９員～１４員の複素環を形成する５員～７員の複素環；このような複素環の異性体及びこれらの組合せを含むことができる。
In the above formulas (1) to (3), "alkyl" includes straight chain, branched chain, and cyclic alkyl groups, and "alkylene" includes straight chain, branched chain, and cyclic alkylene groups. "Alkenylene" includes straight chain and branched alkenylene groups.
Unsaturated or aromatic heterocycles include, for example, 5- to 7-membered heterocycles having an unsaturated bond; aromatic heterocycles having at least one heteroatom selected from the group consisting of N, O, and S; ; includes isomers of such heterocycles and combinations thereof. Furthermore, suitable heterocycles include, for example, 5- to 7-membered heterocycles fused together to form larger 9- to 14-membered heterocycles having at least one N, O or S atom. Ring; can include isomers of such heterocycles and combinations thereof.
（Ａ－１）成分中のポリマーは、複素環含有ポリマーを含むものであってよい。
複素環としては、例えば、イミダゾール、チオフェン、ピロール、オキサゾール、チアゾール及びそれらのそれぞれの異性体（例えば、チアゾール－４－イル、チアゾール－３－イル及びチアゾール－２－イル）、テトラゾール、ピリジン、ピリダジン、ピリミジン、ピラジン、アゾール、インダゾール、トリアゾール及びそれらのそれぞれの異性体（例えば、１，２，３－トリアゾール及び１，２，４－トリアゾール）、並びにイミダゾール１，２，３－トリアゾール－１，２，４－トリアゾールのようなこれらの組合せ、ベンゾトリアゾール、メチルベンゾトリアゾール、ベンゾチアゾール、メチルベンゾチアゾール、ベンズイミダゾール並びにメチルベンズイミダゾールが挙げられる。
複素環含有ポリマーとしては、例えば、複素環含有モノマーに由来する単位を含有するポリマーが挙げられる。複素環含有モノマーとしては、例えば、ビニルイミダゾールやビニルピリジンが挙げられる。
複素環含有ポリマーは、複素環含有モノマーに由来する単位のほかに、非複素環含有モノマーに由来する単位を含有していてもよい。
The polymer in component (A-1) may include a heterocycle-containing polymer.
Heterocycles include, for example, imidazole, thiophene, pyrrole, oxazole, thiazole and their respective isomers (for example thiazol-4-yl, thiazol-3-yl and thiazol-2-yl), tetrazole, pyridine, pyridazine. , pyrimidines, pyrazines, azoles, indazoles, triazoles and their respective isomers (e.g. 1,2,3-triazole and 1,2,4-triazole), and imidazoles 1,2,3-triazole-1,2 , 4-triazole, benzotriazole, methylbenzotriazole, benzothiazole, methylbenzothiazole, benzimidazole and methylbenzimidazole.
Examples of the heterocycle-containing polymer include polymers containing units derived from heterocycle-containing monomers. Examples of the heterocycle-containing monomer include vinylimidazole and vinylpyridine.
The heterocycle-containing polymer may contain units derived from a non-heterocycle-containing monomer in addition to units derived from a heterocycle-containing monomer.
（Ａ－１）成分中のポリマーは、典型的には、架橋剤に由来する単位を含む。架橋剤に由来する単位の割合は、ポリマーの総質量に対し、０．５～６０質量％が好ましく、２～１０質量％がより好ましく、５～８質量％がさらに好ましい。
架橋剤としては、通常使用されるものであればよく、例えば、ジ－、トリ－、テトラ－及びより高級の多官能性エチレン性不飽和モノマーが挙げられる。より具体的には、トリビニルベンゼン；ジビニルトルエン；ジビニルピリジン；ジビニルナフタレン；ジビニルキシレン；エチレングリコールジアクリレート；トリメチロールプロパントリアクリレート；ジエチレングリコールジビニルエーテル；トリビニルシクロヘキサン；アリルメタクリレート（「ＡＬＭＡ」）；エチレングリコールジメタクリレート（「ＥＧＤＭＡ」）；ジエチレングリコールジメタクリレート（「ＤＥＧＤＭＡ」）；プロピレングリコールジメタクリレート；プロピレングリコールジアクリレート；トリメチロールプロパントリメタクリレート（「ＴＭＰＴＭＡ」）；ジビニルベンゼン（「ＤＶＢ」）；２，２－ジメチルプロパン－１，３－ジアクリレート；１，３－ブチレングリコールジアクリレート；１，３－ブチレングリコールジメタクリレート；１，４－ブタンジオールジアクリレート；ジエチレングリコールジアクリレート；ジエチレングリコールジメタクリレート；１，６－ヘキサンジオールジアクリレート；１，６－ヘキサンジオールジメタクリレート；トリプロピレングリコールジアクリレート；トリエチレングリコールジメタクリレート；テトラエチレングリコールジアクリレート；ポリエチレングリコール２００ジアクリレート；テトラエチレングリコールジメタクリレート；ポリエチレングリコールジメタクリレート；エトキシル化ビスフェノールＡジアクリレート；エトキシル化ビスフェノールＡジメタクリレート；ポリエチレングリコール６００ジメタクリレート；ポリ（ブタンジオール）ジアクリレート；ペンタエリスリトールトリアクリレート；トリメチロールプロパントリエトキシトリアクリレート；グリセリルプロポキシトリアクリレート；ペンタエリスリトールテトラアクリレート；ペンタエリスリトールテトラメタクリレート；ジペンタエリスリトールモノヒドロキシペンタアクリレート；ジビニルシラン；トリビニルシラン；ジメチルジビニルシラン；ジビニルメチルシラン；メチルトリビニルシラン；ジフェニルジビニルシラン；ジビニルフェニルシラン；トリビニルフェニルシラン；ジビニルメチルフェニルシラン；テトラビニルシラン；ジメチルビニルジシロキサン；ポリ（メチルビニルシロキサン）；ポリ（ビニルヒドロシロキサン）；ポリ（フェニルビニルシロキサン）及びこれらの２種以上の混合物が挙げられる。
The polymer in component (A-1) typically contains units derived from a crosslinking agent. The proportion of units derived from the crosslinking agent is preferably 0.5 to 60% by weight, more preferably 2 to 10% by weight, and even more preferably 5 to 8% by weight, based on the total weight of the polymer.
The crosslinking agent may be any commonly used crosslinking agent, such as di-, tri-, tetra-, and higher polyfunctional ethylenically unsaturated monomers. More specifically, trivinylbenzene; divinyltoluene; divinylpyridine; divinylnaphthalene; divinylxylene; ethylene glycol diacrylate; trimethylolpropane triacrylate; diethylene glycol divinyl ether; trivinylcyclohexane; allyl methacrylate (“ALMA”); ethylene Glycol dimethacrylate (“EGDMA”); diethylene glycol dimethacrylate (“DEGDMA”); propylene glycol dimethacrylate; propylene glycol diacrylate; trimethylolpropane trimethacrylate (“TMPTMA”); divinylbenzene (“DVB”); 2,2 -dimethylpropane-1,3-diacrylate; 1,3-butylene glycol diacrylate; 1,3-butylene glycol dimethacrylate; 1,4-butanediol diacrylate; diethylene glycol diacrylate; diethylene glycol dimethacrylate; 1,6- Hexanediol diacrylate; 1,6-hexanediol dimethacrylate; tripropylene glycol diacrylate; triethylene glycol dimethacrylate; tetraethylene glycol diacrylate; polyethylene glycol 200 diacrylate; tetraethylene glycol dimethacrylate; polyethylene glycol dimethacrylate; ethoxyl ethoxylated bisphenol A diacrylate; polyethylene glycol 600 dimethacrylate; poly(butanediol) diacrylate; pentaerythritol triacrylate; trimethylolpropane triethoxy triacrylate; glyceryl propoxy triacrylate; pentaerythritol tetraacrylate; Pentaerythritol tetramethacrylate; dipentaerythritol monohydroxypentaacrylate; divinylsilane; trivinylsilane; dimethyldivinylsilane; divinylmethylsilane; methyltrivinylsilane; diphenyldivinylsilane; divinylphenylsilane; trivinylphenylsilane; divinylmethylphenylsilane; tetra Examples include vinylsilane; dimethylvinyldisiloxane; poly(methylvinylsiloxane); poly(vinylhydrosiloxane); poly(phenylvinylsiloxane) and mixtures of two or more thereof.
（Ａ－１）成分中のポリマーは、典型的には、粒子状である。ポリマーの平均粒子径は１～２００ｎｍが好ましく、１～５０ｎｍがより好ましく、１０ｎｍ未満がさらに好ましい。平均粒子径は、光散乱法により測定される数平均粒子径である。ポリマーの分子量は、例えば５００～５０００である。
本発明の一態様において、（Ａ－１）成分は、架橋剤に由来する単位の割合が１０質量％未満で、複素環含有モノマーとしてビニルイミダゾールを含み、平均粒子径が１０ｎｍ未満であるポリマーと錯体化された銀が好ましい。
（Ａ－１）成分の具体例としては、例えば、ダウケミカル・ジャパン株式会社から提供されているＳＩＬＶＡＤＵＲ（登録商標）９００ Ａｎｔｉｍｉｃｒｏｂｉａｌ、ＳＩＬＶＡＤＵＲ（登録商標）９３０ Ａｎｔｉｍｉｃｒｏｂｉａｌ、ＳＩＬＶＡＤＵＲ（登録商標）９３０ＦＬＥＸ Ａｎｔｉｍｉｃｒｏｂｉａｌ；Ｇｏｕｌｓｔｏｎ Ｔｅｃｈｎｏｌｏｇｉｅｓ，Ｉｎｃ．から提供されているＬｕｒｏｌ（登録商標）Ａｇ－１５００；松本油脂製薬株式会社から提供されているブリアンＢＧ－１（登録商標）が挙げられ、ＳＩＬＶＡＤＵＲ（登録商標）９３０ＦＬＥＸがより好ましい。
The polymer in component (A-1) is typically particulate. The average particle diameter of the polymer is preferably 1 to 200 nm, more preferably 1 to 50 nm, and even more preferably less than 10 nm. The average particle diameter is a number average particle diameter measured by a light scattering method. The molecular weight of the polymer is, for example, 500 to 5,000.
In one aspect of the present invention, component (A-1) is a polymer having a proportion of units derived from a crosslinking agent of less than 10% by mass, containing vinylimidazole as a heterocycle-containing monomer, and having an average particle size of less than 10 nm. Complexed silver is preferred.
Specific examples of the component (A-1) include SILVADUR (registered trademark) 900 Antimicrobial, SILVADUR (registered trademark) 930 Antimicrobial, and SILVADUR (registered trademark) 930FLEX Antimicrobial provided by Dow Chemical Japan Co., Ltd. stone Technologies, Inc. Lurol (registered trademark) Ag-1500 provided by Matsumoto Yushi Pharmaceutical Co., Ltd.; Briand BG-1 (registered trademark) provided by Matsumoto Yushi Pharmaceutical Co., Ltd., and SILVADUR (registered trademark) 930FLEX is more preferred.
〈（Ａ－２）成分：担体に担持された銀〉
（Ａ－２）成分において、担体の具体例としては、リン酸塩類（リン酸ジルコニウム、リン酸カルシウム等）、金属酸化物（酸化ケイ素、酸化アルミニウム、酸化チタン、酸化亜鉛、酸化鉄、酸化ジリコニウム等）、無機化合物（ゼオライト、粘土鉱物、シリカゲル等）等が挙げられる。これらの担体は、単独または２種以上を用いてもよい。
（Ａ－２）成分は粒子状であり得る。その平均粒子径は０．１～１００μｍが好ましく、１～５０μｍがより好ましく、２～４μｍがさらに好ましい。平均粒子径は、光散乱法により測定される数平均粒子径である。
本発明の一態様において、（Ａ－２）成分は、多孔質球状シリカに銀及びリン酸３カルシウムを担持させたものが好ましい。更に、（Ａ－２）成分は、多孔質球状シリカに銀及びリン酸３カルシウムを担持させたものであって、銀含有量が０．０１～０．２質量％であり、平均粒子径が２～４μｍのものがより好ましい。
（Ａ－２）成分の具体例としては、例えば、鈴木油脂工業株式会社製のＰＣボールＡＧ－６Ｈが挙げられる。
<(A-2) Component: Silver supported on carrier>
In component (A-2), specific examples of carriers include phosphates (zirconium phosphate, calcium phosphate, etc.), metal oxides (silicon oxide, aluminum oxide, titanium oxide, zinc oxide, iron oxide, zirconium oxide, etc.) , inorganic compounds (zeolite, clay minerals, silica gel, etc.). These carriers may be used alone or in combination of two or more.
Component (A-2) may be in particulate form. The average particle diameter is preferably 0.1 to 100 μm, more preferably 1 to 50 μm, and even more preferably 2 to 4 μm. The average particle diameter is a number average particle diameter measured by a light scattering method.
In one embodiment of the present invention, component (A-2) is preferably one in which silver and tricalcium phosphate are supported on porous spherical silica. Furthermore, component (A-2) is a material in which silver and tricalcium phosphate are supported on porous spherical silica, the silver content is 0.01 to 0.2% by mass, and the average particle diameter is A thickness of 2 to 4 μm is more preferable.
A specific example of component (A-2) is, for example, PC Ball AG-6H manufactured by Suzuki Yushi Kogyo Co., Ltd.
〈（Ａ－３）成分：無機銀塩〉
（Ａ－３）成分としては、銀の酸化物、塩化物、硝酸塩及び硫酸塩等が挙げられる。このような無機銀塩は市販品を使用することができ、例えば、東洋化学工業株式会社から提供されている硫酸銀等の市販品を使用することができる。
なお、（Ａ－３）成分は、１種を単独で又は２種以上を混合して用いることができる。
<(A-3) Component: Inorganic silver salt>
Examples of the component (A-3) include silver oxides, chlorides, nitrates, and sulfates. Commercial products such as silver sulfate provided by Toyo Kagaku Kogyo Co., Ltd. can be used as such inorganic silver salts.
Note that component (A-3) can be used alone or in a mixture of two or more.
（Ａ）成分としては、ポリマーと錯体化された銀がより好ましく、具体的な製品としてはＳＩＬＶＡＤＵＲ（登録商標）９３０ＦＬＥＸ等が挙げられる。
（Ａ）成分の含量は、配合目的を達成できる量である限り特に限定されないが、繊維製品用処理剤組成物の総質量に対し、例えば、０．００１質量％～１質量％であり、好ましくは０．０１質量％～０．８質量％、より好ましくは０．０５質量％～０．５質量％である。（Ａ）成分の含量が０．００１質量％以上であると抗菌性能を良好に付与し得、１質量％以下であると（Ｃ）成分による保存安定性の向上が得られやすい。
As component (A), silver complexed with a polymer is more preferable, and specific products include SILVADUR (registered trademark) 930FLEX and the like.
The content of component (A) is not particularly limited as long as it can achieve the purpose of blending, but is preferably, for example, 0.001% to 1% by mass based on the total mass of the textile processing agent composition. is 0.01% to 0.8% by weight, more preferably 0.05% to 0.5% by weight. When the content of component (A) is 0.001% by mass or more, antibacterial performance can be imparted favorably, and when the content of component (C) is 1% by mass or less, improvement in storage stability by component (C) is likely to be obtained.
［（Ｂ）成分］
本発明の繊維製品用処理剤組成物は、（Ｂ）成分として、キレート剤を含有する。（Ｂ）成分は、主に消臭性能付与のために配合される。
本発明において用いることのできるキレート剤としては、１－ヒドロキシエタン－１，１－ジホスホン酸、アミノトリメチレンホスホン酸、エチレンジアミンテトラホスフォニックアシッド、ジエチレントリアミン－Ｎ，Ｎ，Ｎ’，Ｎ”，Ｎ”－ペンタキス（メタンホスホネート）等の有機フォスフォン酸化合物、エチレンジアミン四酢酸、ジエチレントリアミン五酢酸、ニトリロトリ酢酸、Ｎ－ヒドロキシエチルエチレンジアミントリアセテート、エチレンジアミンテトラプロピオネート、エチレンジアミン－Ｎ，Ｎ’－ジグルタメート、２－ヒドロキシプロピレンジアミン－Ｎ，Ｎ’－ジスクシネート、トリエチレンテトラアミンヘキサアセテート、ジエチレントリアミンペンタアセテート、エチレンジアミンジコハク酸、メチルグリシンジ酢酸、イミノジコハク酸、ヒドロキシイミノジコハク酸、アスパラギン酸等のアミノカルボン酸化合物、クエン酸、カプトカテキュ酸、及びそれらの塩、例えばそれらのアルカリ金属塩、アンモニウム塩、及び置換アンモニウム塩のようなそれらの水溶性の塩等が挙げられる。
[(B) Component]
The textile processing agent composition of the present invention contains a chelating agent as the component (B). Component (B) is mainly blended to impart deodorizing performance.
Chelating agents that can be used in the present invention include 1-hydroxyethane-1,1-diphosphonic acid, aminotrimethylenephosphonic acid, ethylenediaminetetraphosphonic acid, diethylenetriamine-N,N,N',N",N" -Organic phosphonic acid compounds such as pentakis (methanephosphonate), ethylenediaminetetraacetic acid, diethylenetriaminepentaacetic acid, nitrilotriacetic acid, N-hydroxyethylethylenediaminetriacetate, ethylenediaminetetrapropionate, ethylenediamine-N,N'-diglutamate, 2- Aminocarboxylic acid compounds such as hydroxypropylene diamine-N,N'-disuccinate, triethylenetetraamine hexaacetate, diethylenetriamine pentaacetate, ethylenediamine disuccinic acid, methylglycine diacetic acid, iminodisuccinic acid, hydroxyiminodisuccinic acid, aspartic acid, Citric acid, captocatechuic acid, and salts thereof, such as water-soluble salts thereof, such as alkali metal salts, ammonium salts, and substituted ammonium salts, etc., are included.
また、（Ｂ）成分は、下記式（Ｉ）～（III）で表される化合物から選択され得る。（Ｂ）成分は、１種単独で又は２種以上を適宜組み合わせて用いることができる。
ＭIは、互いに同一でも異なっていてもよく、それぞれ水素原子、アルカリ金属、アルカリ土類金属、カチオン性アンモニウム基、アルカノールアミンからなる群より選ばれる１種を示す。アルカリ金属としては、ナトリウム、カリウムが好ましい。アルカノールアミンとしては、モノエタノールアミン、ジエタノールアミン、トリエタノールアミンが好ましい。ＭIとしては、アルカリ金属が好ましく、ナトリウムが特に好ましい。
ｍI及びｎIは、それぞれ０～２の整数である。ｍIは、好ましくは０又は１である。ｎIは、好ましくは０又は１である。ｍIとｎIとがいずれも０の場合、ＡIは、ＣＨ3である。
前記式（I）で表される化合物のなかで好適なものとしては、メチルグリシンジ酢酸（ＭＧＤＡ）、アスパラギン酸ジ酢酸（ＡＳＤＡ）、イソセリンジ酢酸（ＩＳＤＡ）、β－アラニンジ酢酸（ＡＤＡＡ）、セリンジ酢酸（ＳＤＡ）、グルタミン酸ジ酢酸（ＧＬＤＡ）、又はこれらの塩が挙げられる。なかでもＭＧＤＡ又はその塩が好ましい。
Furthermore, component (B) may be selected from compounds represented by the following formulas (I) to (III). Component (B) can be used alone or in an appropriate combination of two or more.
M I may be the same or different, and each represents one selected from the group consisting of a hydrogen atom, an alkali metal, an alkaline earth metal, a cationic ammonium group, and an alkanolamine. As the alkali metal, sodium and potassium are preferred. As the alkanolamine, monoethanolamine, diethanolamine, and triethanolamine are preferred. As M I , an alkali metal is preferable, and sodium is particularly preferable.
m I and n I are each integers from 0 to 2. m I is preferably 0 or 1. n I is preferably 0 or 1. When m I and n I are both 0, A I is CH 3 .
Among the compounds represented by formula (I), methylglycine diacetic acid (MGDA), aspartic acid diacetic acid (ASDA), isoserine diacetic acid (ISDA), β-alanine diacetic acid (ADAA), and serine diacetic acid are preferable. Examples include acetic acid (SDA), glutamic acid diacetic acid (GLDA), or salts thereof. Among them, MGDA or a salt thereof is preferred.
ＱIIは、水素原子又は炭素数８～２２の直鎖又は分岐アルキル基を表す。
ＲIIは、水素原子又は水酸基を表す。
ｎIIは、０又は１を表す。
前記式（II）で表される化合物のなかで好適なものとしては、イミノジコハク酸（ＩＤＳ）、ヒドロキシイミノジコハク酸（ＨIＤＳ）、又はこれらの塩が挙げられ、なかでもＩＤＳ又はその塩が好ましい。
Q II represents a hydrogen atom or a straight chain or branched alkyl group having 8 to 22 carbon atoms.
R II represents a hydrogen atom or a hydroxyl group.
n II represents 0 or 1.
Among the compounds represented by the formula (II), preferred examples include iminodisuccinic acid (IDS), hydroxyiminodisuccinic acid (HIDS), or salts thereof, with IDS or a salt thereof being preferred. .
ＡIIIは、Ｈ、メチル基又は（ＣＨ2）ｍIII－ＣＯＯＸIIIを表す。ＡIIIとしては、（ＣＨ2）ｍIII－ＣＯＯＸIIIが好ましい。
ｍIIIは、１～３のいずれかの数を表す。
ＸIIIは、Ｈ、アルカリ金属、アルカリ土類金属、アルカノールアミン又はＮＨ4
+を表わす。アルカリ金属としては、ナトリウム、カリウムが好ましい。アルカノールアミンとしては、モノエタノールアミン、ジエタノールアミン、トリエタノールアミンが好ましい。
ｎIIIは、１～３のいずれかの数を表す。
A III represents H, a methyl group, or (CH 2 )m III -COOX III . As A III , (CH 2 ) m III -COOX III is preferable.
m III represents any number from 1 to 3.
X III represents H, an alkali metal, an alkaline earth metal, an alkanolamine or NH 4 + . As the alkali metal, sodium and potassium are preferred. As the alkanolamine, monoethanolamine, diethanolamine, and triethanolamine are preferred.
n III represents any number from 1 to 3.
前記式（III）で表わされる化合物の具体例としては、オクチルアミノ酢酸ナトリウム、ラウリルアミノ酢酸ナトリウム、ミリスチルアミノ酢酸ナトリウム、パルミチルアミノ酢酸ナトリウム、オレイルアミノ酢酸ナトリウム等のアルキル及びアルケニルアミノ酢酸塩；
オクチルアミノプロピオン酸ナトリウム、デシルアミノプロピオン酸ナトリウム、ラウリルアミノプロピオン酸ナトリウム、ミリスチルアミノプロピオン酸ナトリウム、パルミチルアミノプロピオン酸ナトリウム、オレイルアミノプロピオン酸ナトリウム等のアルキル及びアルケニルアミノプロピオン酸塩；
Ｎ‐オクチルグリシンナトリウム、Ｎ‐デシルグリシンナトリウム、Ｎ‐ラウリルグリシンナトリウム、Ｎ‐ミリスチルグリシンナトリウム、Ｎ‐パルミチルグリシンナトリウム、Ｎ‐オレイルグリシンナトリウム等のＮ‐アルキル及びアルケニルグリシン塩；
Ｎ‐オクチル‐Ｎ‐メチル‐β‐アラニンナトリウム、Ｎ‐デシル‐Ｎ‐メチル‐β‐アラニンナトリウム、Ｎ‐ドデシル‐Ｎ‐メチル‐β‐アラニンナトリウム、Ｎ‐ミリスチル‐Ｎ‐メチル‐β‐アラニンナトリウム、Ｎ‐パルミチル‐Ｎ‐メチル‐β‐アラニンナトリウム、Ｎ‐オレイル‐Ｎ‐メチル‐β‐アラニンナトリウム等のＮ‐アルキル及びアルケニル‐Ｎ‐メチル‐β‐アラニン塩；
オクチルアミノジ酢酸ナトリウム、デシルアミノジ酢酸ナトリウム、ラウリルアミノジ酢酸ナトリウム、ミリスチルアミノジ酢酸ナトリウム、パルミチルアミノジ酢酸ナトリウム、オレイルアミノジ酢酸ナトリウム等のアルキル及びアルケニルアミノジ酢酸塩；及び オクチルアミノジプロピオン酸ナトリウム、デシルアミノジプロピオン酸ナトリウム、ラウリルアミノジプロピオン酸ナトリウム、ミリスチルアミノジプロピオン酸ナトリウム、パルミチルアミノジプロピオン酸ナトリウム、オレイルアミノジプロピオン酸ナトリウム等のアルキル及びアルケニルアミノジプロピオン酸塩等が挙げられる。
これらの中では、保存安定性から考えて、アルキル及びアルケニルアミノジ酢酸塩が好ましく、その中でもデシルアミノジ酢酸、ラウリルアミノジ酢酸、ミリスチルアミノジ酢酸、パルミチルアミノジ酢酸又はその塩が好ましく、特にラウリルアミノジ酢酸、ミリスチルアミノジ酢酸、パルミチルアミノジ酢酸又はその塩がより好ましい。
Specific examples of the compound represented by the formula (III) include alkyl and alkenylaminoacetates such as sodium octylaminoacetate, sodium laurylaminoacetate, sodium myristylaminoacetate, sodium palmitylaminoacetate, and sodium oleylaminoacetate;
Alkyl and alkenylaminopropionate salts such as sodium octylaminopropionate, sodium decylaminopropionate, sodium laurylaminopropionate, sodium myristylaminopropionate, sodium palmitylaminopropionate, sodium oleylaminopropionate;
N-alkyl and alkenylglycine salts such as N-octylglycine sodium, N-decylglycine sodium, N-laurylglycine sodium, N-myristylglycine sodium, N-palmitylglycine sodium, N-oleylglycine sodium;
N-octyl-N-methyl-β-alanine sodium, N-decyl-N-methyl-β-alanine sodium, N-dodecyl-N-methyl-β-alanine sodium, N-myristyl-N-methyl-β-alanine N-alkyl and alkenyl-N-methyl-β-alanine salts such as sodium, N-palmityl-N-methyl-β-alanine sodium, N-oleyl-N-methyl-β-alanine sodium;
Alkyl and alkenylaminodiacetates such as sodium octylaminodiacetate, sodium decylaminodiacetate, sodium laurylaminodiacetate, sodium myristylaminodiacetate, sodium palmitylaminodiacetate, sodium oleylaminodiacetate; and octylaminodiacetate; Examples include alkyl and alkenylamino dipropionate salts such as sodium, sodium decylamino dipropionate, sodium lauryl amino dipropionate, sodium myristylamino dipropionate, sodium palmitylamino dipropionate, and sodium oleylamino dipropionate. It will be done.
Among these, from the viewpoint of storage stability, alkyl and alkenylaminodiacetic acid salts are preferable, and among these, decylaminodiacetic acid, lauryl aminodiacetic acid, myristylaminodiacetic acid, palmitylaminodiacetic acid or a salt thereof is preferable, and lauryl aminodiacetic acid or a salt thereof is particularly preferable. More preferred are aminodiacetic acid, myristylaminodiacetic acid, palmitylaminodiacetic acid, or a salt thereof.
（Ｂ）成分としては、式（I）で表される化合物及び式（II）で表される化合物が特に好ましい。また、組成物の変色を抑制する効果が高いことから、ＭＤＧＡ、クエン酸又はそれらの塩がより好ましい。
（Ｂ）成分の含量は、配合目的を達成できる量である限り特に限定されないが、繊維製品用処理剤組成物の総質量に対し、例えば、０．０１質量％～１質量％であり、好ましくは０．０５質量％～１質量％、より好ましくは０．１質量％～１質量％である。（Ｂ）成分の含量が０．０１質量％以上であると消臭性能を良好に付与し得、１質量％以下であると（Ｃ）成分による保存安定性の向上が得られやすい。
As component (B), compounds represented by formula (I) and compounds represented by formula (II) are particularly preferred. Furthermore, MDGA, citric acid, or their salts are more preferred since they are highly effective in suppressing discoloration of the composition.
The content of component (B) is not particularly limited as long as it can achieve the purpose of blending, but is preferably, for example, 0.01% to 1% by mass based on the total mass of the textile treatment agent composition. is 0.05% to 1% by weight, more preferably 0.1% to 1% by weight. When the content of component (B) is 0.01% by mass or more, good deodorizing performance can be imparted, and when the content of component (C) is 1% by mass or less, improvement in storage stability by component (C) is likely to be obtained.
［（Ｃ）成分］
本発明の繊維製品用処理剤組成物は、（Ｃ）成分として、アクリル酸アルキル及びメタクリル酸アルキルから選ばれるモノマーに由来する１種以上のモノマー単位と、アクリル酸及びメタクリル酸から選ばれるモノマーに由来する１種以上のモノマー単位とを含む共重合体を含有する。但し、（Ｃ）成分には、銀と錯体化したものは含まれない。（Ｃ）成分は、主に保存安定性の向上（変色抑制）のために配合され、また、構造粘性付与にも有益である。
（Ｃ）成分としては、下記式（ｃ２）で表されるモノマーに由来する１種以上のモノマー単位と、下記式（ｃ１）で表されるモノマーに由来する１種以上のモノマー単位とを含む共重合体であることが好ましい。
式（ｃ２）中、Ｒ7は水素原子又はメチル基であり、Ｒ8は炭素数１～４０のアルキル基である。Ｒ8におけるアルキル基は、直鎖状であっても分岐鎖状であってもよく、又は環状の構造（シクロアルキル環または芳香族環）を含んでいてもよい。Ｒ8におけるアルキル基の炭素数は１～４０であり、炭素数１～２０が好ましく、炭素数１～１０がより好ましい。
[(C) Component]
The textile processing agent composition of the present invention contains, as component (C), one or more monomer units derived from a monomer selected from alkyl acrylates and alkyl methacrylates, and a monomer selected from acrylic acid and methacrylic acid. Contains a copolymer containing one or more monomer units derived from. However, component (C) does not include anything complexed with silver. Component (C) is mainly blended to improve storage stability (inhibit discoloration), and is also useful for imparting structural viscosity.
The component (C) includes one or more monomer units derived from a monomer represented by the following formula (c2) and one or more monomer units derived from a monomer represented by the following formula (c1). A copolymer is preferred.
In formula (c2), R 7 is a hydrogen atom or a methyl group, and R 8 is an alkyl group having 1 to 40 carbon atoms. The alkyl group in R 8 may be linear or branched, or may include a cyclic structure (cycloalkyl ring or aromatic ring). The alkyl group in R 8 has 1 to 40 carbon atoms, preferably 1 to 20 carbon atoms, and more preferably 1 to 10 carbon atoms.
式（ｃ１）で表されるモノマーから誘導された繰り返し単位は、式（ｃ１）で表されるモノマーを含むモノマー成分を重合したときに、式（ｃ１）で表されるモノマーに由来する繰り返し単位である。
式（ｃ１）で表されるモノマーとしては、例えば、アクリル酸、メタクリル酸が挙げられる。式（ｃ１）で表されるモノマーは、いずれか１種を単独で用いてもよく、２種以上を併用してもよい。
式（ｃ２）で表されるモノマーから誘導された繰り返し単位は、式（ｃ２）で表されるモノマーを含むモノマー成分を重合したときに、式（ｃ２）で表されるモノマーに由来する繰り返し単位である。
式（ｃ２）で表されるモノマーとしては、例えば、アクリル酸メチル、アクリル酸エチル、アクリル酸ｎ－プロピル、アクリル酸ｎ－ブチル、アクリル酸オクチル、アクリル酸デシル、アクリル酸ドデシル、アクリル酸イコシル等のアクリル酸エステルや、メタクリル酸メチル、メタクリル酸エチル、メタクリル酸ｎ－プロピル、メタクリル酸ｎ－ブチル、メタクリル酸オクチル、メタクリル酸デシル、メタクリル酸ドデシル、メタクリル酸イコシル等のメタクリル酸エステルが挙げられる。式（ｃ２）で表されるモノマーは、いずれか１種を単独で用いてもよく、２種以上を併用してもよい。
The repeating unit derived from the monomer represented by formula (c1) is a repeating unit derived from the monomer represented by formula (c1) when a monomer component containing the monomer represented by formula (c1) is polymerized. It is.
Examples of the monomer represented by formula (c1) include acrylic acid and methacrylic acid. Any one type of monomer represented by formula (c1) may be used alone, or two or more types may be used in combination.
The repeating unit derived from the monomer represented by formula (c2) is a repeating unit derived from the monomer represented by formula (c2) when a monomer component containing the monomer represented by formula (c2) is polymerized. It is.
Examples of the monomer represented by formula (c2) include methyl acrylate, ethyl acrylate, n-propyl acrylate, n-butyl acrylate, octyl acrylate, decyl acrylate, dodecyl acrylate, icosyl acrylate, etc. and methacrylic esters such as methyl methacrylate, ethyl methacrylate, n-propyl methacrylate, n-butyl methacrylate, octyl methacrylate, decyl methacrylate, dodecyl methacrylate, and icosyl methacrylate. Any one type of monomer represented by formula (c2) may be used alone, or two or more types may be used in combination.
（Ｃ）成分は、架橋されているものでもよく、架橋されていないものでもよいが、架橋されているものが好ましい。（Ｃ）成分の架橋されているものとしては、例えば、架橋剤により架橋されているもの（高分子架橋体）が挙げられる。
前記の架橋剤としては、例えばアリルエーテル化合物が好適に挙げられる。
アリルエーテル化合物としては、アリルエーテル、糖のアリルエーテル、糖アルコールのアリルエーテル等が挙げられる。
糖のアリルエーテルにおける糖としては、例えばスクロース等が挙げられる。
糖アルコールのアリルエーテルにおける糖アルコールとしては、例えばペンタエリスリトール等が挙げられる。
（Ｃ）成分は、いずれか１種を単独で用いてもよく、２種以上を併用してもよい。
また、（Ｃ）成分は、式（ｃ１）で表されるモノマーから誘導された繰り返し単位及び式（ｃ２）で表されるモノマーから誘導された繰り返し単位以外の繰り返し単位（他の繰り返し単位）を有していてもよい。他の繰り返し単位としては、他のモノマーから誘導された繰り返し単位が挙げられる。他のモノマーとしては、式（ｃ１）で表されるモノマー及び式（ｃ２）で表されるモノマーと共重合可能であれば特に制限されず、１種以上を用いることができる。
Component (C) may be crosslinked or non-crosslinked, but preferably crosslinked. Examples of the crosslinked component (C) include those crosslinked with a crosslinking agent (crosslinked polymer).
Preferred examples of the crosslinking agent include allyl ether compounds.
Examples of the allyl ether compound include allyl ether, sugar allyl ether, sugar alcohol allyl ether, and the like.
Examples of the sugar in the sugar allyl ether include sucrose.
Examples of the sugar alcohol in the allyl ether of sugar alcohol include pentaerythritol.
Component (C) may be used alone or in combination of two or more.
In addition, component (C) contains repeating units (other repeating units) other than the repeating unit derived from the monomer represented by formula (c1) and the repeating unit derived from the monomer represented by formula (c2). may have. Other repeating units include repeating units derived from other monomers. Other monomers are not particularly limited as long as they can be copolymerized with the monomer represented by formula (c1) and the monomer represented by formula (c2), and one or more types can be used.
（Ｃ）成分の具体例としては、例えば以下の商品名が挙げられる。
架橋タイプの（Ｃ）成分の市販品としては、例えば、Ｌｕｂｒｉｚｏｌ社製のアクリル酸アルキル及びメタクリル酸アルキルから選ばれるモノマーに由来する１種以上のモノマー単位と、アクリル酸及びメタクリル酸から選ばれるモノマーに由来する１種以上のモノマー単位とからなる架橋型共重合体である商品名「Ｃａｒｂｏｐｏｌ Ａｑｕａ３０」；Ｌｕｂｒｉｚｏｌ社製のアクリル酸アルキル（Ｃ１～Ｃ４及びＣ８）及びメタクリル酸アルキル（Ｃ１～Ｃ４及びＣ８）から選ばれるモノマーに由来する１種以上のモノマー単位と、アクリル酸及びメタクリル酸から選ばれるモノマーに由来する１種以上のモノマー単位とからなる架橋型共重合体である「Ｃａｒｂｏｐｏｌ Ａｑｕａ ＳＦ－１」；Ｌｕｂｒｉｚｏｌ社製のアクリル酸アルキル（Ｃ１０～Ｃ３０）及びメタクリル酸アルキル（Ｃ１０～Ｃ３０）から選ばれるモノマーに由来する１種以上のモノマー単位と、アクリル酸のモノマー単位とからなる架橋型共重合体である商品名「Ｃａｒｂｏｐｏｌ ＥＺ－４」；ＤＯＷ社製のアクリル酸アルキルから選ばれるモノマーに由来する１種以上のモノマー単位と、アクリル酸及びメタクリル酸から選ばれるモノマーに由来する１種以上のモノマー単位とからなる架橋型共重合体である商品名「ＡＣＵＳＯＬ８３０」等が挙げられる。
Specific examples of component (C) include the following trade names.
Commercially available crosslinked type component (C) includes, for example, one or more monomer units derived from monomers selected from alkyl acrylates and alkyl methacrylates manufactured by Lubrizol, and monomers selected from acrylic acid and methacrylic acid. The trade name "Carbopol Aqua30" is a crosslinked copolymer consisting of one or more monomer units derived from "Carbopol Aqua SF-1" is a crosslinked copolymer consisting of one or more monomer units derived from monomers selected from ) and one or more monomer units derived from monomers selected from acrylic acid and methacrylic acid. "; A crosslinked copolymer consisting of one or more monomer units derived from monomers selected from alkyl acrylates (C10 to C30) and alkyl methacrylates (C10 to C30) manufactured by Lubrizol, and monomer units of acrylic acid. The product name "Carbopol EZ-4" is a combination of one or more monomer units derived from a monomer selected from alkyl acrylates manufactured by DOW, and one or more monomer units derived from a monomer selected from acrylic acid and methacrylic acid. Examples include the trade name "ACUSOL830" which is a crosslinked copolymer consisting of monomer units.
（Ｃ）成分の含量は、配合目的を達成できる量である限り特に限定されないが、繊維製品用処理剤組成物の総質量に対し、例えば、０．０２質量％～５質量％、好ましくは０．０３質量％～３質量％、より好ましくは０．３質量％～２．７質量％である。（Ｃ）成分の含量が０．０２質量％以上であると、構造化の面で良好であり、５質量％以下であると、増粘による配合性の悪化を防止し得る。
（Ａ）成分と（Ｃ）成分の配合割合は、（Ｃ）成分／（Ａ）成分で表される質量比が、０．３～１１００が好ましく、１．５～３００がより好ましい。
The content of component (C) is not particularly limited as long as it can achieve the purpose of blending, but is, for example, 0.02% by mass to 5% by mass, preferably 0.02% by mass to 5% by mass, based on the total mass of the textile treatment agent composition. 03% to 3% by weight, more preferably 0.3% to 2.7% by weight. When the content of component (C) is 0.02% by mass or more, it is good in terms of structuring, and when it is 5% by mass or less, deterioration of blendability due to thickening can be prevented.
Regarding the blending ratio of component (A) and component (C), the mass ratio represented by component (C)/component (A) is preferably 0.3 to 1100, more preferably 1.5 to 300.
［（Ｄ）成分］
本発明の繊維製品用処理剤組成物は、（Ｄ）成分としてカプセル香料を含有してもよい。（Ｄ）成分は、香りを持続させる目的で配合され得る。
カプセル香料は、芯物質と、当該芯物質を覆う壁物質とから構成されるマイクロカプセルであり、芯物質は香料や精油を含む。このような芯物質の香料及び精油は、本発明の技術分野において周知の成分を用いることができ、それら１種を単独又は２種以上を適宜併用することができる。
カプセル香料の壁物質は、高分子物質から構成され、繊維製品用処理剤組成物等に含有されるカプセルに一般的に使用される材料を用いることができる。壁物質として、例えば、ゼラチン、寒天等の天然系高分子、油脂、ワックス等の油性膜形成物質、ポリアクリル酸系、ポリビニル系、ポリメタクリル酸系、ポリウレア系、メラミン系、ウレタン系等の合成高分子物質などを挙げることができ、それら１種を単独又は２種以上を適宜併用することができる。壁物質は、カプセルが破壊された際の発香性の観点から、メラミン－ホルムアルデヒド樹脂或いは尿素－ホルムアルデヒド樹脂からなるアミノプラストポリマー、ポリアクリル酸系或いはポリメタクリル酸系ポリマーであることが好ましい。特に、特開２０１０－５２０９２８号に記載されているようなアミノプラストポリマーが好ましい。具体的には、ポリアミン由来の部分／芳香族ポリフェノール由来の部分／メチレン単位、ジメトキシメチレン及びジメトキシメチレンを有するアルキレンおよびアルキレンオキシ部分からなるターポリマーであることが好ましい。
マイクロカプセルの表面電荷は正電荷、負電荷のどちらでもよく、２種以上を組み合わせても良い。
[(D) Component]
The textile processing agent composition of the present invention may contain a capsule fragrance as the component (D). Component (D) may be blended for the purpose of sustaining the fragrance.
A capsule fragrance is a microcapsule composed of a core substance and a wall substance covering the core substance, and the core substance contains a fragrance and an essential oil. For such core substance fragrances and essential oils, components well known in the technical field of the present invention can be used, and one type thereof can be used alone or two or more types can be used in combination as appropriate.
The wall material of the capsule fragrance is composed of a polymeric substance, and materials commonly used for capsules contained in textile processing agent compositions and the like can be used. Examples of wall materials include natural polymers such as gelatin and agar, oil film-forming substances such as oil and wax, polyacrylic acid-based, polyvinyl-based, polymethacrylic acid-based, polyurea-based, melamine-based, urethane-based, etc. Examples include polymeric substances, and one type thereof can be used alone or two or more types can be used in combination as appropriate. The wall material is preferably an aminoplast polymer made of a melamine-formaldehyde resin or a urea-formaldehyde resin, a polyacrylic acid-based polymer, or a polymethacrylic acid-based polymer, from the viewpoint of odor generation when the capsule is broken. In particular, aminoplast polymers such as those described in JP-A No. 2010-520928 are preferred. Specifically, a terpolymer consisting of a polyamine-derived moiety/aromatic polyphenol-derived moiety/methylene unit, dimethoxymethylene, and an alkylene and alkyleneoxy moiety having dimethoxymethylene is preferable.
The surface charge of the microcapsules may be either positive or negative, or two or more types may be combined.
カプセル香料は、市販の製品から適宜選択することができるが、具体的には、フィルメニッヒ社製のＢＬＵＥＦＬＯＷＥＲＰＯＰ「ＦＦＭＨＮ２８１４」、ＩＭＰＡＣＴＰＯＰＳＣＥＮＴ「１９７５９３ＢＭＨＮ２９１１」、及びＡＰＰＬＥＰＯＰＳＣＥＮＴ「１１３２８５ＦＢＭＨＮ２９１１」；ジボダン社製のＧＲＥＥＮ ＢＲＥＥＺＥ ＣＡＰＳ、ＯＲＣＨＡＲＤ ＧＡＲＤＥＮ ＣＡＰＳ、ＲＡＩＮＢＯＷ ＣＡＰＳ、ＶＥＬＶＥＴ ＣＡＰＳ、ＡＵＲＯＲＡＣＡＰＳ、及びＣＯＳＭＩＣＣＡＰＳ；ＩＦＦ社製のＵＮＩＣＡＰ１０１、及びＵＮＩＣＡＰ５０３等が挙げられる。
（Ｄ）成分は、１種単独で用いてもよく、２種以上を組み合わせてもよい。
（Ｄ）成分の含量は、配合目的を達成できる量である限り特に限定されないが、繊維製品用処理剤組成物の総質量に対し、例えば、０．００５～５質量％、好ましくは０．０１～５質量％、より好ましくは０．０１～２質量％である。（Ｄ）成分の含量が０．００５質量％以上であると充分な発香性が達成でき、５質量以上であってもコスト面から考えてメリットは少ない。（Ｄ）成分の含量が０．０１～５質量％の範囲内であると、発香性、費用対効果の点で好ましい。
Capsule fragrances can be appropriately selected from commercially available products, but specifically, BLUE FLOWERPOP "FFMHN2814" manufactured by Firmenich, IMPACT POPSCENT "197593BMHN2911", and APPLE POPSCENT "113285FBMHN2911" manufactured by Givaudan; GREEN BREEZE CAPS, ORCHARD Examples include GARDEN CAPS, RAINBOW CAPS, VELVET CAPS, AURORACAPS, and COSMICCAPS; UNICAP101 and UNICAP503 manufactured by IFF.
Component (D) may be used alone or in combination of two or more.
The content of component (D) is not particularly limited as long as it can achieve the purpose of blending, but is, for example, 0.005 to 5% by mass, preferably 0.01% by mass based on the total mass of the textile treatment agent composition. ~5% by weight, more preferably 0.01~2% by weight. When the content of component (D) is 0.005% by mass or more, sufficient fragrance can be achieved, and even when the content is 5% by mass or more, there is little merit from a cost perspective. It is preferable for the content of component (D) to be within the range of 0.01 to 5% by mass in terms of fragrance and cost effectiveness.
［任意成分］
繊維製品用処理剤組成物には、本発明の効果を損なわない範囲で、必要に応じて前記（Ａ）、（Ｂ）、（Ｃ）成分、及び（Ｄ）成分以外の任意成分を配合してもよい。
任意成分としては、各種界面活性剤、シリコーン化合物、再汚染防止剤、高分子、防腐剤、（Ａ）成分以外の抗菌剤、防カビ剤、忌避剤、天然物などのエキス、分散剤、色素、酸化防止剤、増粘剤、減粘剤、紫外線吸収剤など、安全性が高くしかも通常の繊維製品用処理剤に使用されるものであればどのようなものでもよく、特に限定されるものではない。本発明における任意成分の配合量は、上限が好ましくは５質量％以下、より好ましくは３質量％以下である。
界面活性剤としては、非イオン性界面活性剤、アニオン性界面活性剤、カチオン性界面活性剤、両性界面活性剤を配合できる。本発明の繊維製品用処理剤組成物の安定性を高めるために、非イオン性界面活性剤が好ましい。
本発明において使用できる非イオン性界面活性剤としては、炭素数10～22のアルキル基又はアルケニル基を有し、オキシエチレン基の平均付加モル数が10～100モルであるポリオキシエチレンアルキルエーテル、ポリオキシエチレン脂肪酸アルキル（Ｃ1～3）エステルや、オキシエチレン基の平均付加モル数が10～100モルであるポリオキシエチレンアルキルアミン、炭素数8～18のアルキル基又はアルケニル基を有するアルキルポリグルコシド、オキシエチレン基の平均付加モル数が20～100モルである硬化ヒマシ油、などが挙げられる。中でも、炭素数10～14のアルキル基を有し、オキシエチレン基の平均付加モル数が5～20モルのポリオキシエチレンアルキルエーテル、オキシエチレン基の平均付加モル数が30～50モルである硬化ヒマシ油が好ましい。
本発明の繊維製品用処理剤組成物における非イオン性界面活性剤の配合量は、好ましくは0.01～5質量％、より好ましくは0.1～3質量％である。この範囲にあると、繊維製品用処理剤組成物の分散安定性を高めることができる。
[Optional ingredients]
Optional components other than the above-mentioned components (A), (B), (C), and (D) may be blended into the textile processing agent composition as necessary to the extent that the effects of the present invention are not impaired. You can.
Optional ingredients include various surfactants, silicone compounds, anti-recontamination agents, polymers, preservatives, antibacterial agents other than component (A), antifungal agents, repellents, extracts of natural products, dispersants, and pigments. , antioxidants, thickeners, thinners, ultraviolet absorbers, etc., any substances that are highly safe and commonly used in textile processing agents may be used, but there are no particular limitations. isn't it. The upper limit of the amount of optional components blended in the present invention is preferably 5% by mass or less, more preferably 3% by mass or less.
As the surfactant, nonionic surfactants, anionic surfactants, cationic surfactants, and amphoteric surfactants can be blended. In order to enhance the stability of the textile processing agent composition of the present invention, nonionic surfactants are preferred.
Nonionic surfactants that can be used in the present invention include polyoxyethylene alkyl ethers having an alkyl group or alkenyl group having 10 to 22 carbon atoms and an average number of added moles of oxyethylene groups of 10 to 100 moles; Polyoxyethylene fatty acid alkyl (C1-3) esters, polyoxyethylene alkylamines having an average number of added moles of oxyethylene groups of 10 to 100 moles, and alkyl polyglucosides having alkyl groups or alkenyl groups having 8 to 18 carbon atoms. , hydrogenated castor oil in which the average number of moles of oxyethylene groups added is 20 to 100 moles. Among them, polyoxyethylene alkyl ether having an alkyl group having 10 to 14 carbon atoms and an average number of added moles of oxyethylene group is 5 to 20 moles, and a cured product having an average number of added moles of oxyethylene group of 30 to 50 moles. Castor oil is preferred.
The blending amount of the nonionic surfactant in the textile processing agent composition of the present invention is preferably 0.01 to 5% by mass, more preferably 0.1 to 3% by mass. Within this range, the dispersion stability of the textile processing agent composition can be improved.
例えば、繊維製品上での菌の増殖を抑制し、不快臭の発生を抑制する観点から、有機系防菌防カビ剤、無機系防菌防カビ剤の中から１種を単独で又は２種以上を混合して用いることができる。有機系防菌防カビ剤としては、アルコール系、フェノール系、アルデヒド系、カルボン酸系、エステル系、エーテル系、ニトリル系、過酸化物・エポキシ系、ハロゲン系、ピリジン・キノリン系、トリアジン系、イソチアゾロン系、イミダゾール・チアゾール系、アニリド系、ビグアナイド系、ジスルフィド系、チオカーバメート系、糖質系、トロポロン系、有機金属系のものが挙げられる。また、無機系防菌防カビ剤としては、金属酸化物が挙げられる。例えばダイクロサン、イソプロピルメチルフェノールなどの抗菌剤或いは除菌剤を繊維製品用処理剤組成物中に０．０５～１質量％の範囲で配合することができる。
シリコーン化合物としては、ジメチルシリコーン、ポリエーテル変性シリコーン、メチルフェニルシリコーン、アルキル変性シリコーン、高級脂肪酸変性シリコーン、メチルハイドロジェンシリコーン、フッ素変性シリコーン、エポキシ変性シリコーン、カルボキシ変性シリコーン、カルビノール変性シリコーン及びアミノ変性シリコーンなどが挙げられる。シリコーン化合物としては、ポリエーテル変性シリコーンが好ましく、なかでもＨＬＢが１３以下、好ましくは１０以下、更に好ましくは７以下のポリエーテル変性シリコーンが、着用じわを減少させる観点から好ましい。具体的には東レ・ダウコーニング社製のSH3775C、SH3772CやSH3775Mなどの化合物が好適である。
シリコーン化合物の含量は、配合目的を達成できる量である限り特に限定されないが、繊維製品用処理剤組成物の総質量に対して、好ましくは０．０１～５質量％であり、しわ減少効果と経済性の観点からより好ましくは０．１～１質量％である。
For example, from the viewpoint of suppressing the growth of bacteria on textile products and suppressing the generation of unpleasant odors, one type or two types of organic antibacterial and antifungal agents and inorganic antibacterial and antifungal agents may be used alone or in combination. A mixture of the above can be used. Organic antibacterial and fungicidal agents include alcohol-based, phenol-based, aldehyde-based, carboxylic acid-based, ester-based, ether-based, nitrile-based, peroxide/epoxy-based, halogen-based, pyridine/quinoline-based, triazine-based, Examples include isothiazolone-based, imidazole/thiazole-based, anilide-based, biguanide-based, disulfide-based, thiocarbamate-based, carbohydrate-based, tropolone-based, and organometallic-based. Furthermore, examples of inorganic antibacterial and antifungal agents include metal oxides. For example, an antibacterial agent or a disinfectant such as diclosan or isopropylmethylphenol can be incorporated into the textile treatment composition in an amount of 0.05 to 1% by mass.
Silicone compounds include dimethyl silicone, polyether-modified silicone, methylphenyl silicone, alkyl-modified silicone, higher fatty acid-modified silicone, methylhydrogen silicone, fluorine-modified silicone, epoxy-modified silicone, carboxy-modified silicone, carbinol-modified silicone, and amino-modified silicone. Examples include silicone. As the silicone compound, polyether-modified silicones are preferred, and among them, polyether-modified silicones with an HLB of 13 or less, preferably 10 or less, and more preferably 7 or less are preferred from the viewpoint of reducing wear wrinkles. Specifically, compounds such as SH3775C, SH3772C, and SH3775M manufactured by Dow Corning Toray are suitable.
The content of the silicone compound is not particularly limited as long as it can achieve the purpose of blending, but it is preferably 0.01 to 5% by mass based on the total mass of the textile treatment agent composition, and has a wrinkle reducing effect. From the economic point of view, it is more preferably 0.1 to 1% by mass.
また、繊維製品用処理剤組成物中に含まれる成分の保存安定性を確保するために、ｐＨ調整剤を繊維製品用処理剤組成物に配合してもよい。酸として、例えば塩酸、硫酸等の無機酸、酢酸、クエン酸等のカルボン酸が挙げられる。アルカリとして、例えば水酸化ナトリウム等のアルカリ金属塩、トリエタノールアミン等のアルカノールアミン等が挙げられる。
さらに、繊維製品用処理剤組成物そのもの、または繊維製品用処理剤組成物により処理された繊維製品に香り付けをするために、香料を繊維製品用処理剤組成物に配合してもよい。本発明の分野において通常使用されているいかなる香料も使用でき、例えば特開２００８－７８７２号公報に記載されているような香料成分、溶剤、安定化剤を含有する香料組成物が挙げられる。香料は、繊維製品用処理剤組成物中に０．００５～５質量％配合することができ、香り付けの効果と経済性の観点から、０．０１～１質量％配合することが好ましい。
本発明の繊維製品用処理剤組成物は、好ましくは水性組成物であり、水を含むことが好ましい。水としては、水道水、イオン交換水、純水、蒸留水など、いずれも用いることができる。中でもイオン交換水が好適である。
水は、本発明の繊維製品用処理剤組成物中に、好ましくは５０質量％以上、より好ましくは６０質量％以上配合される。水の含有割合が前記下限値以上であれば、ハンドリング性が良好となる。
本発明の繊維製品用処理剤組成物は、水に加えて、水溶性溶剤を含むことが好ましい。水溶性溶剤としては、低級（炭素数１～４）アルコール、グリコールエーテル系溶剤、多価アルコールからなる群から選ばれる１種又は２種以上が好ましく、エタノール、エチレングリコール、ブチルカルビトール、プロピレングリコール、ジプロピレングリコールモノメチルエーテル、ジエチレングリコールモノブチルエーテル等がより好ましい。
Further, in order to ensure the storage stability of the components contained in the textile processing agent composition, a pH adjuster may be added to the textile processing agent composition. Examples of acids include inorganic acids such as hydrochloric acid and sulfuric acid, and carboxylic acids such as acetic acid and citric acid. Examples of the alkali include alkali metal salts such as sodium hydroxide, alkanolamines such as triethanolamine, and the like.
Furthermore, a fragrance may be added to the textile processing agent composition in order to impart fragrance to the textile processing agent composition itself or to textile products treated with the textile processing agent composition. Any perfume commonly used in the field of the present invention can be used, including a perfume composition containing a perfume component, a solvent, and a stabilizer as described in JP-A No. 2008-7872. The fragrance can be blended in the textile processing agent composition in an amount of 0.005 to 5% by mass, and preferably in an amount of 0.01 to 1% by mass from the viewpoint of fragrance effect and economical efficiency.
The textile processing agent composition of the present invention is preferably an aqueous composition and preferably contains water. As water, tap water, ion exchange water, pure water, distilled water, etc. can all be used. Among them, ion-exchanged water is preferred.
Water is preferably blended in the textile processing agent composition of the present invention in an amount of 50% by mass or more, more preferably 60% by mass or more. If the water content is equal to or higher than the lower limit, the handling property will be good.
The textile processing agent composition of the present invention preferably contains a water-soluble solvent in addition to water. The water-soluble solvent is preferably one or more selected from the group consisting of lower (1 to 4 carbon atoms) alcohols, glycol ether solvents, and polyhydric alcohols, including ethanol, ethylene glycol, butyl carbitol, and propylene glycol. , dipropylene glycol monomethyl ether, diethylene glycol monobutyl ether and the like are more preferred.
［繊維製品用処理剤組成物の製造方法］
本発明の繊維製品用処理剤組成物の製造方法は特に限定されず、本発明の繊維製品用処理剤組成物は定法により製造することができる。
例えば、水に（Ｂ）成分及び（Ｃ）成分を加え、ｐＨ調整剤を用いて組成物のｐＨを中性にし、混合する。その後、任意成分を添加して混合後、必要であれば水酸化ナトリウムや塩酸、硫酸等のｐＨ調整剤を用い、ｐＨメーター（例えば、Ｍｅｔｔｌｅｒ Ｔｏｌｅｄｏ社製 型番ＭＰ２３０）で、配合物をスターラーにて攪拌したままｐＨを調整した後、（Ａ）成分を添加することにより製造することができる。
本発明の繊維製品用処理剤組成物のｐＨは、保存安定性を確保するために６以上～９以下であると好ましく、６．５以上～８以下であるとより好ましい。
また、本発明の繊維製品用処理剤組成物の粘度は、２００ｍＰａ・ｓ以下であることが好ましい。本発明の繊維製品用処理剤組成物をスプレー容器に入れて使用する場合には、１５０ｍＰａ・ｓ以下であることがより好ましい。なお、本明細書で示す粘度はＢ型粘度計（トキメック社製）を用いて、原液を２５℃で測定した場合の数値である。
[Method for producing a treatment agent composition for textile products]
The method for producing the textile processing agent composition of the present invention is not particularly limited, and the textile processing agent composition of the present invention can be produced by a conventional method.
For example, components (B) and (C) are added to water, the pH of the composition is made neutral using a pH adjuster, and the mixture is mixed. After that, optional ingredients are added and mixed, and if necessary, using a pH adjuster such as sodium hydroxide, hydrochloric acid, or sulfuric acid, the mixture is stirred using a pH meter (for example, model number MP230 manufactured by Mettler Toledo). It can be produced by adjusting the pH while stirring and then adding component (A).
The pH of the textile processing agent composition of the present invention is preferably 6 or more and 9 or less, more preferably 6.5 or more and 8 or less, in order to ensure storage stability.
Further, the viscosity of the textile processing agent composition of the present invention is preferably 200 mPa·s or less. When the textile processing agent composition of the present invention is used in a spray container, the pressure is more preferably 150 mPa·s or less. Note that the viscosity shown in this specification is a value when the stock solution is measured at 25° C. using a B-type viscometer (manufactured by Tokimec).
［繊維製品用処理剤組成物の使用方法］
本発明の繊維製品用処理剤組成物を、繊維製品に使用する方法としては、組成物をスプレー容器に収納し、繊維製品に噴霧して使用する方法が好ましい。
スプレー容器としては、トリガースプレー容器（直圧型あるいは蓄圧型）、ディスペンサースプレー容器等が挙げられる。トリガースプレー容器の例としては、特開平９－２６８４７３号公報、特開平９－２５６２７２号公報、特開平１０－７６１９６号公報等に記載のものが挙げられる。ディスペンサースプレー容器の例としては、特開平９－２５６２７２号公報等に記載のものが挙げられる。
また、本発明の繊維製品用処理剤組成物は、プラスチック製容器に収納することができる。プラスチック製容器としては、ボトル容器や詰替え用のスタンディングパウチ等が挙げられる。スタンディングパウチとしては、例えば、特開２０００－７２１８１号公報に記載のものが挙げられるが、材質としては、内層に１００～２５０μｍの線状低密度ポリエチレン、外層に１５～３０μｍの延伸ナイロンの二層構造又は１５μｍの延伸ナイロンを中間層、１５μｍの延伸ナイロンを外層にした三層構造のスタンディングパウチが保存安定性の点から好ましい。
本発明の繊維製品用処理剤組成物を使用する対象の繊維製品としては、特に限定されないが、例えば、Ｙシャツ、Ｔシャツ、ポロシャツ、ブラウス、チノパン、スーツ、スラックス、スカート、ジャケット、コート、ニット、ジーンズ、パジャマ、テーブルクロス、ランチョンマット、カーテン、クッション、座布団、ソファ、枕カバー、シーツ、ベッドパッド、枕、布団、ベッドカバー、毛布、マットレス、靴、トイレマット、バスマット、玄関マット、カーペット、ラグ、絨毯等が挙げられる。また、対象とする繊維製品の素材も、特に限定されないが、例えば、綿、ウール、麻等の天然繊維、ポリエステル、ナイロン、アクリル等の合成繊維、アセテート等の半合成繊維、レーヨン、テンセル、ポリノジック等の再生繊維及びこれら各種繊維の混紡品、混織品、混編品等が挙げられ、その中でも、普段の手入れが困難なウール及びその混紡品において、本発明の組成物の効果が顕著に発揮される。
[How to use the treatment agent composition for textile products]
A preferred method for using the textile processing agent composition of the present invention on textile products is to store the composition in a spray container and spray it onto the textile product.
Examples of the spray container include trigger spray containers (direct pressure type or pressure accumulation type), dispenser spray containers, and the like. Examples of trigger spray containers include those described in JP-A-9-268473, JP-A-9-256272, JP-A-10-76196, and the like. Examples of dispenser spray containers include those described in JP-A-9-256272 and the like.
Moreover, the textile processing agent composition of the present invention can be stored in a plastic container. Examples of plastic containers include bottle containers and standing pouches for refilling. Examples of standing pouches include those described in Japanese Patent Application Laid-Open No. 2000-72181, and the material is a two-layered inner layer of linear low-density polyethylene with a thickness of 100 to 250 μm and an outer layer of stretched nylon with a thickness of 15 to 30 μm. From the viewpoint of storage stability, a standing pouch with a three-layer structure, in which an intermediate layer is made of 15 μm drawn nylon and an outer layer is made of 15 μm drawn nylon, is preferable.
The textile products to which the textile product treatment composition of the present invention is applied are not particularly limited, but include, for example, Y-shirts, T-shirts, polo shirts, blouses, chinos, suits, slacks, skirts, jackets, coats, knitwear. , jeans, pajamas, tablecloths, placemats, curtains, cushions, cushions, sofas, pillow cases, sheets, bed pads, pillows, futons, bedspreads, blankets, mattresses, shoes, toilet mats, bath mats, entrance mats, carpets, Examples include rugs and carpets. In addition, the materials of target textile products are not particularly limited, but include, for example, natural fibers such as cotton, wool, and linen, synthetic fibers such as polyester, nylon, and acrylic, semi-synthetic fibers such as acetate, rayon, Tencel, and polynosic. and other recycled fibers, and blends, woven products, and knitted products of these various fibers.Among them, the effect of the composition of the present invention is remarkable in wool and its blend products, which are difficult to care for on a daily basis. be done.
以下、実施例により本発明を更に詳細に説明するが、本発明はこれに限定されるものではない。尚、実施例において、成分配合量はすべて質量％（指定のある場合を除き、純分換算）を示す。 EXAMPLES Hereinafter, the present invention will be explained in more detail with reference to Examples, but the present invention is not limited thereto. In the examples, all component amounts are expressed in mass % (unless otherwise specified, in terms of pure content).
［（Ａ）成分］
下記の銀系抗菌剤を使用した。
・Ａ－１：錯体銀
（Ａ－１－１）：抗菌剤「ＳＩＬＶＡＤＵＲ ９３０ ＦＬＥＸ Ａｎｔｉｍｉｃｒｏｂｉａｌ」（ダウケミカル・ジャパン株式会社製）
（Ａ－１－２）：抗菌剤「ＳＩＬＶＡＤＵＲ ９３０ Ａｎｔｉｍｉｃｒｏｂｉａｌ」（ダウケミカル・ジャパン株式会社製）
（Ａ－１－３）：抗菌剤「Ｌｕｒｏｌ Ａｇ－１５００」（Ｇｏｕｌｓｔｏｎ Ｔｅｃｈｎｏｌｏｇｉｅｓ，Ｉｎｃ．製）
（Ａ－１－４）：抗菌剤「ＡＡ－１２５Ａｇ」（大和化学工業株式会社製）
・Ａ－２：担体に担持された銀
（Ａ－２）：抗菌剤「ＰＣボール ＡＧ－６Ｈ」（鈴木油脂工業株式会社製）
・Ａ－３：無機銀塩
（Ａ－３）：抗菌剤「硫酸銀」（東洋化学工業株式会社製）
[(A) Component]
The following silver-based antibacterial agent was used.
・A-1: Complex silver (A-1-1): Antibacterial agent "SILVADUR 930 FLEX Antimicrobial" (manufactured by Dow Chemical Japan Co., Ltd.)
(A-1-2): Antibacterial agent "SILVADUR 930 Antimicrobial" (manufactured by Dow Chemical Japan Co., Ltd.)
(A-1-3): Antibacterial agent “Lurol Ag-1500” (manufactured by Goulston Technologies, Inc.)
(A-1-4): Antibacterial agent "AA-125Ag" (manufactured by Daiwa Chemical Industry Co., Ltd.)
・A-2: Silver supported on a carrier (A-2): Antibacterial agent "PC Ball AG-6H" (manufactured by Suzuki Yushi Kogyo Co., Ltd.)
・A-3: Inorganic silver salt (A-3): Antibacterial agent "silver sulfate" (manufactured by Toyo Kagaku Kogyo Co., Ltd.)
［（Ｂ）成分］
下記のキレート剤を使用した。
（Ｂ－１）：メチルグリシンジ酢酸３ナトリウム「ＭＧＤＡ」（ＢＡＳＦ社製）
（Ｂ－２）：クエン酸３ナトリウム（関東化学株式会社製）
（Ｂ－３）：エチレンジアミン４酢酸「ＥＤＴＡ」（関東化学株式会社製）
[(B) Component]
The following chelating agent was used.
(B-1): Trisodium methylglycine diacetate "MGDA" (manufactured by BASF)
(B-2): Trisodium citrate (manufactured by Kanto Chemical Co., Ltd.)
(B-3): Ethylenediaminetetraacetic acid “EDTA” (manufactured by Kanto Chemical Co., Ltd.)
［（Ｃ）成分］
下記のアクリル酸系ポリマーを使用した。
（Ｃ－１）：架橋型アクリル酸系高分子「Ｃａｒｂｏｐｏｌ ＡＱＵＡ ３０」（Ｌｕｂｒｉｚｏｌ社製）
（Ｃ－２）：架橋型アクリル酸系高分子「Ｃａｒｂｏｐｏｌ ＡＱＵＡ ＳＦ－１」（Ｌｕｂｒｉｚｏｌ社製）
（Ｃ－３）：架橋型アクリル酸系高分子「Ｃａｒｂｏｐｏｌ ＥＺ４」（Ｌｕｂｒｉｚｏｌ社製）
比較例として下記のＣ－４を使用した。
（Ｃ－４）：ポリアクリル酸「ｓｏｋａｌａｎ ＣＰ１０」（ＢＡＳＦ社製）
[(C) Component]
The following acrylic acid polymer was used.
(C-1): Cross-linked acrylic acid polymer “Carbopol AQUA 30” (manufactured by Lubrizol)
(C-2): Cross-linked acrylic acid polymer “Carbopol AQUA SF-1” (manufactured by Lubrizol)
(C-3): Cross-linked acrylic acid polymer “Carbopol EZ4” (manufactured by Lubrizol)
The following C-4 was used as a comparative example.
(C-4): Polyacrylic acid "sokalan CP10" (manufactured by BASF)
［（Ｄ）成分］
下記のカプセル香料を使用した。
（Ｄ－１）：カプセル香料「ＶＥＬＶＥＴ ＵＰ」（Ｇｉｖａｕｄａｎ社製）
[(D) Component]
The following capsule fragrances were used.
(D-1): Capsule fragrance "VELVET UP" (manufactured by Givaudan)
［共通成分］
共通成分Ａ
・９５％合成エタノール（日本アルコール販売製） １０％
・ポリエーテル変性シリコーン（ＳＨ３７７５Ｍ）（東レ・ダウコーニング株式会社製） ０．５％
・下記表１で示される香料組成物 ０．０３％
Common component A
・95% synthetic ethanol (manufactured by Nippon Alcohol Sales) 10%
・Polyether modified silicone (SH3775M) (manufactured by Toray Dow Corning Co., Ltd.) 0.5%
-Fragrance composition shown in Table 1 below 0.03%
［繊維製品用処理剤組成物の調製方法］
下記手順に従って、表２及び３に示される組成を有する実施例１～１８及び比較例１～７の組成物をそれぞれ調製した。
水（残部に相当）、エタノール、表１で示される香料組成物、ポリエーテル変性シリコーン、（Ｂ）成分、（Ｃ）成分を混合し十分に攪拌後、ｐＨ調整剤を用いて所定のｐＨに調整し、（Ａ）成分、（Ｄ）成分を混合し繊維製品用処理剤組成物を調製した。
[Method for preparing treatment agent composition for textile products]
Compositions of Examples 1 to 18 and Comparative Examples 1 to 7 having the compositions shown in Tables 2 and 3 were prepared according to the following procedure, respectively.
Water (corresponding to the remainder), ethanol, the fragrance composition shown in Table 1, polyether-modified silicone, component (B), and component (C) are mixed and stirred thoroughly, and the pH is adjusted to a predetermined value using a pH adjuster. Component (A) and component (D) were mixed to prepare a treatment agent composition for textile products.
［評価方法］
＜保存安定性＞
上記のとおり調製した繊維製品用処理剤組成物を軽量ＰＳガラスビン（ＰＳ－Ｎｏ．６、田辺硝子工業所製）に５０ｍｌ入れて密栓して５０℃条件下で２週間保管し、液色を下記評価基準に従って目視で評価を行った。結果を下記表２及び３に示す。
≪評価基準≫
◎◎：液色の変色が全く認められない
◎：極わずかに液色に変色が認められる
○：やや液色に変色が認められる
×：液色に明らかな変色が認められる
[Evaluation method]
<Storage stability>
Pour 50ml of the textile processing agent composition prepared as above into a lightweight PS glass bottle (PS-No. 6, manufactured by Tanabe Glass Industries), seal it, and store it at 50°C for 2 weeks. Visual evaluation was performed according to evaluation criteria. The results are shown in Tables 2 and 3 below.
≪Evaluation criteria≫
◎◎: No discoloration is observed in the liquid color ◎: Very slight discoloration is observed in the liquid color ○: Some discoloration is observed in the liquid color ×: Obvious discoloration is observed in the liquid color
＜抗菌性＞
（１）処理方法
綿布（１５cm×１５cm）に対して、上記のとおり調製した繊維製品用処理剤組成物をディスペンサーポンプスプレー（スタイルガード しわもニオイもすっきりスプレー、ライオン（株）製）を用いて一定量噴霧した後、乾燥させた。乾燥後、該綿布を試験布として抗菌効果の評価に用いた。また、未処理布は組成物を噴霧していない綿布を用いた。
<Antibacterial>
(1) Treatment method A cotton fabric (15 cm x 15 cm) was coated with the textile treatment agent composition prepared as above using a dispenser pump spray (Style Guard Wrinkle and Odor Removal Spray, manufactured by Lion Co., Ltd.). After spraying a certain amount, it was dried. After drying, the cotton cloth was used as a test cloth to evaluate the antibacterial effect. In addition, the untreated cloth used was a cotton cloth that was not sprayed with the composition.
（２）黄色ブドウ球菌に対する抗菌性の評価
本評価に用いた器具、水などは、予めオートクレーブにより滅菌処理を施したものを用いた。また、本評価では、菌として黄色ブドウ球菌（Ｓｔａｐｈｙｌｏｃｏｃｃｕｓ ａｕｒｅｕｓ）を用いた。
ＪＩＳ Ｌ１９０２に準じて培養を行った黄色ブドウ球菌を用い、ニュートリエント培地を２０倍に希釈し、菌数が１±０．３×１０5個／ｍＬとなるように、黄色ブドウ球菌母液を調製した。
前記試験布０．４ｇに、前記黄色ブドウ球菌母液２００μＬずつを接種し、３７℃の恒温槽にて１８時間培養して、試験布上で増殖又は静菌した。
その後、抽出液（ＪＩＳ Ｌ１９０２に記載の洗い出し用生理食塩水）にて試験布から菌を抽出し、その抽出液を生理食塩水によって１０倍に希釈した。得られた希釈液をさらに１０倍に希釈する操作を４回繰り返し、１００，０００倍の希釈液を得た。なお、「洗い出し用生理食塩水」とは、精製水１，０００ｍＬに対し、塩化ナトリウム８．５ｇを採取し、これらをフラスコに入れて充分に溶解させ、さらに非イオン界面活性剤としてポリオキシエチレンソルビタンモノオレート（関東化学社製、商品名「ポリソルベート８０、Ｔｗｅｅｎ８０」）２ｇを加えて溶解させた後、高圧蒸気殺菌（オートクレーブ処理）したものである。
(2) Evaluation of antibacterial properties against Staphylococcus aureus The instruments, water, etc. used in this evaluation were sterilized in advance by autoclaving. Furthermore, in this evaluation, Staphylococcus aureus was used as the bacterium.
Using Staphylococcus aureus cultured according to JIS L1902, dilute the nutrient medium 20 times and prepare Staphylococcus aureus mother liquor so that the number of bacteria is 1 ± 0.3 × 10 5 cells/mL. did.
Each 0.4 g of the test cloth was inoculated with 200 μL of the Staphylococcus aureus mother liquor, and cultured in a constant temperature bath at 37° C. for 18 hours to allow growth or bacteriostasis on the test cloth.
Thereafter, bacteria were extracted from the test cloth using an extract solution (physiological saline for washing as specified in JIS L1902), and the extract was diluted 10 times with physiological saline. The operation of further diluting the obtained diluted solution 10 times was repeated four times to obtain a 100,000 times diluted solution. In addition, "physiological saline for washing" refers to 8.5 g of sodium chloride taken from 1,000 mL of purified water, put into a flask and sufficiently dissolved, and then added with polyoxyethylene as a nonionic surfactant. After adding and dissolving 2 g of sorbitan monooleate (manufactured by Kanto Kagaku Co., Ltd., trade name "Polysorbate 80, Tween 80"), high-pressure steam sterilization (autoclave treatment) was performed.
次いで、ＳＣＤＬＰ寒天培地（日本製薬株式会社製）上に、得られた１００，０００倍の希釈液から１ｍＬを採取し、予めオートクレーブにより滅菌処理し４８℃に保温したＳＣＤＬＰ寒天培地１５ｍＬをシャーレ上で混釈し、３７℃の恒温槽内で１～２日間培養した後、コロニー数をカウントし、生菌数を求めた。未処理布についても試験布と同様の操作を行って生菌数を測定し、これらの測定値を用いて抗菌活性値を下記式（ｉｉ）より算出した。
抗菌活性値＝ｌｏｇ10（未処理布の生菌数／試験布の生菌数） ・・・（ｉｉ）
下記基準により抗菌性付与効果の評価を行った。結果を下記表２及び３に示す。
≪評価基準≫
◎：抗菌活性値が２．０以上であった。
○：抗菌活性値が１．０以上～２．０未満であった。
×：抗菌活性値が１．０未満であった。
Next, 1 mL of the obtained 100,000-fold diluted solution was collected onto an SCDLP agar medium (manufactured by Nippon Pharmaceutical Co., Ltd.), and 15 mL of the SCDLP agar medium, which had been previously sterilized by autoclaving and kept at 48°C, was placed on a petri dish. After the mixture was mixed and cultured in a constant temperature bath at 37°C for 1 to 2 days, the number of colonies was counted to determine the number of viable bacteria. The untreated cloth was also subjected to the same operation as the test cloth to measure the number of viable bacteria, and the antibacterial activity value was calculated using the following formula (ii) using these measured values.
Antibacterial activity value = log 10 (number of viable bacteria on untreated cloth/number of viable bacteria on test cloth) ...(ii)
The antibacterial effect was evaluated according to the following criteria. The results are shown in Tables 2 and 3 below.
≪Evaluation criteria≫
◎: Antibacterial activity value was 2.0 or more.
○: Antibacterial activity value was 1.0 or more and less than 2.0.
×: Antibacterial activity value was less than 1.0.
＜消臭性＞
（１）試験用布の前処理
試験用布として、市販の肌シャツ（綿１００％、白色、丸首、ＢＶＤ社製）を用いた。家庭用の二槽式洗濯機（ＶＨ－３０Ｓ、東芝株式会社製）に２０℃の水道水３０Ｌを入れ、ここに市販の衣類用粉末洗剤（消臭ブルーダイヤ（商品名）、ライオン株式会社製）１５ｇを加え、よく分散させた後、試験用布５枚を投入し、１５分間洗浄した。洗剤液を排水後、試験用布を脱水機で１分間脱水し、２０℃の水道水３０Ｌで３分間濯ぐという脱水・濯ぎ工程を２度行なった後、３分間脱水しハンガーで吊り干しにて一晩風乾した。
<Deodorizing property>
(1) Pretreatment of test fabric A commercially available skin shirt (100% cotton, white, round neck, manufactured by BVD) was used as the test fabric. Pour 30L of tap water at 20°C into a household two-tub washing machine (VH-30S, manufactured by Toshiba Corporation), and add a commercially available powder laundry detergent (Deodorizing Blue Diamond (trade name), manufactured by Lion Corporation) to it. ) was added and well dispersed, and then five test cloths were added and washed for 15 minutes. After draining the detergent solution, the test cloth was dehydrated for 1 minute in a dehydrator, and then rinsed twice with 30 L of tap water at 20°C for 3 minutes. After that, the cloth was dehydrated for 3 minutes and hung to dry on a hanger. and air-dried overnight.
（２）汗臭消臭評価
４０歳代の男性２名が、前処理を施した試験用布を着用し、晴天時にランニングを３０分間行った。ランニング後に試験用布を回収し、背中部分及び前部分からそれぞれ７ｃｍ×７ｃｍ（０．８５ｇ／枚）を２７枚採取し、採取した試験用布をチャック付きポリ袋に入れ一晩放置した（試験用布の採取処理）。これを汗臭モデル試験用布とした。
この汗臭モデル試験用布に対し、上記のとおり調製した繊維製品用処理剤組成物をディスペンサースプレー容器（「スタイルガード しわもニオイもすっきりスプレー」（ライオン株式会社製）用の容器）を用いて０．２ｇ／枚噴霧し、噴霧直後に、１０人のパネラーにより以下に示す評価基準で臭気の評価を行った。その後、試験用布を洗濯ばさみで１枚ずつ物干し竿に吊るして風乾し、噴霧２時間後に臭気評価を行った。１０人のパネラーの点数の平均が３点未満のものを合格（◎、○）とした。平均値が低いほど、消臭効果が高いと評価できる。結果を下記表２及び３に示す。
≪評価基準≫
×：
５点：汗臭が非常に強い。
４点：汗臭がかなりある。
○：
３点：汗臭がわかる。
２点：汗臭がややわかる。
◎：
１点：汗臭がかすかにわかる。
０点：まったく汗臭がしない。
(2) Sweat odor deodorization evaluation Two men in their 40s wore the pretreated test cloth and ran for 30 minutes on a sunny day. After running, the test cloth was collected, and 27 pieces of 7 cm x 7 cm (0.85 g/piece) were collected from the back and front parts, and the collected test cloth was placed in a zippered plastic bag and left overnight (test Collecting and processing of cloth for use). This was used as a sweat odor model test cloth.
The textile treatment agent composition prepared as above was applied to this sweat odor model test cloth using a dispenser spray container (container for "Style Guard Wrinkle and Odor Refreshing Spray" (manufactured by Lion Corporation)). 0.2 g/sheet was sprayed, and immediately after spraying, odor was evaluated by 10 panelists according to the evaluation criteria shown below. Thereafter, the test fabrics were hung one by one on a clothesline using clothespins to air dry, and the odor was evaluated 2 hours after spraying. Those with an average score of less than 3 points from the 10 panelists were deemed to have passed (◎, ○). It can be evaluated that the lower the average value, the higher the deodorizing effect. The results are shown in Tables 2 and 3 below.
≪Evaluation criteria≫
×：
5 points: Very strong sweat odor.
4 points: There is considerable sweat odor.
○:
3 points: Sweat odor is noticeable.
2 points: Sweat odor is slightly noticeable.
◎：
1 point: Slight odor of sweat.
0 points: No sweat odor at all.
Claims (4)
（Ｂ）キレート剤、及び
（Ｃ）アクリル酸アルキル及びメタクリル酸アルキルから選ばれるモノマーに由来する１種以上のモノマー単位と、アクリル酸及びメタクリル酸から選ばれるモノマーに由来する１種以上のモノマー単位とを含有する共重合体（銀と錯体化したものを除く）
を含み、
（Ａ）成分の含量が０．００１質量％～１質量％であり、（Ｃ）成分／（Ａ）成分で表される質量比が５～３００である、繊維製品用処理剤組成物。 (A) at least one silver-based antimicrobial agent that is silver complexed with a polymer ;
(B) a chelating agent, and (C) one or more monomer units derived from a monomer selected from alkyl acrylates and alkyl methacrylates, and one or more monomer units derived from monomers selected from acrylic acid and methacrylic acid. Copolymers containing (excluding those complexed with silver)
including;
A treatment agent composition for textile products, in which the content of component (A) is 0.001% by mass to 1% by mass, and the mass ratio represented by component (C)/component (A) is 5 to 300.
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|---|---|---|---|---|
| JP2000073277A (en) | 1998-08-28 | 2000-03-07 | Natl Inst Of Sericultural & Entomological Science | Antimicrobial polymer material and its production |
| JP2007289452A (en) | 2006-04-26 | 2007-11-08 | Shiseido Co Ltd | Deodorant composition |
| JP2011042642A (en) | 2009-08-24 | 2011-03-03 | Csl:Kk | Durable antimicrobial agent for fiber product having antiviral effect |
| JP2013023774A (en) | 2011-07-15 | 2013-02-04 | Lion Corp | Liquid softener composition and method for producing the same |
| JP2017505838A (en) | 2014-01-29 | 2017-02-23 | ユニリーバー・ナームローゼ・ベンノートシヤープ | Detergent composition containing trace action metal and potency enhancer |
| JP2016124984A (en) | 2014-12-29 | 2016-07-11 | ライオン株式会社 | Liquid detergent for fiber product |
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