KR20220033584A - Method of preparing anti-bacterial, sterilizing and deodorant using antibacterial ion metal, and method of manufacturing the same - Google Patents
Method of preparing anti-bacterial, sterilizing and deodorant using antibacterial ion metal, and method of manufacturing the same Download PDFInfo
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Abstract
Description
본 발명은 생활환경 및 생산 공장 등에서, 생활환경속에서 발생되는 각종 바이러스와 생활속의 악취들은 육체에 미치는 영향으로 인한 정신적 스트레스 때문에 이를 매우 생활중 혐오물질중의 하나로 여기고 있다.According to the present invention, various viruses and odors generated in living environments, such as living environments and production plants, are regarded as one of the most disgusting substances in life because of the mental stress caused by their effects on the body.
우리 생활 주변에서 발생되는 악취는 식욕을 잃게 하고, 호흡을 곤란하게 하며, 멀미와 구토 등을 일으켜 정신의 혼란을 초래하는 물질들이다.Bad odors generated around our lives are substances that cause loss of appetite, difficulty breathing, motion sickness and vomiting, etc., causing mental confusion.
악취를 관능시험법, 기기분석법 등을 이용하여 배출구 또는 부지경계선상에서 측정한다. 관능시험법의 경우 직접 관능법, 공기희석관능법이 있는데 규제기준은 2도(度) 이하로 규제하고 있다.Measure the odor at the outlet or on the site boundary using the sensory test method, instrumental analysis method, etc. In the case of sensory test methods, there are direct sensory methods and air dilution sensory methods, but the regulation standard is regulated to 2 degrees or less.
악취물질을 제거하는 물리적 방법으로는 수세법, 활성탄흡착법 및 공기희석법이 있고, 화학적 방법으로는 오존산화법이나 염소산화법, 약액세정법, 이온교환수지법, 연소법, 은폐법 등이 있다. 미생물을 이용한 처리법으로는 바이오필터법이 있다. 발생원은 석유화학제품 제조, 생활하수, 산업폐수, 가축사육장, 식품가공, 페인트 제조, 주물 제조, 석유정제, 분뇨처리장, 도살장, 비료 제조, 플라스틱 제조 연소시설, 도장, 도금공정 등.. 이다.Physical methods to remove odor substances include water washing, activated carbon adsorption, and air dilution, and chemical methods include ozone oxidation, chlorine oxidation, chemical cleaning, ion exchange resin method, combustion method, and concealment method. As a treatment method using microorganisms, there is a biofilter method. The sources of generation are petrochemical manufacturing, domestic sewage, industrial wastewater, livestock breeding grounds, food processing, paint manufacturing, casting manufacturing, petroleum refining, manure treatment plant, slaughterhouse, fertilizer manufacturing, plastic manufacturing combustion facility, painting, plating process, etc..
일반적으로, 악취의 발생원을 없애거나 감소시키는 방법으로 개방되어 있는 발생시설을 밀폐식으로 바꾼다든지 악취물질의 사용이나 발생을 억제하는 것은 근본적인 방법이 된다. 그러나 이 방법을 모든 발생원에 적용할 수는 없고 가능한한 장치를 개조하거나 작업조건의 개선에 의하여 발생이나 배출을 억제하는 것이 발생원에서의 대책이다.In general, it is a fundamental method to change an open generation facility to a closed type or to suppress the use or generation of odor substances as a way to eliminate or reduce the source of odor. However, this method cannot be applied to all sources, and it is a countermeasure at the source to control the generation or emission by modifying the equipment or improving the working conditions as much as possible.
악취물질은 황이나 질소를 함유하는 유기물질이 많고 대부분 가연성이기 때문에 적당한 온도에서 연소시키면 이산화탄소와 물, 기타 무취성 기체로 된다.There are many organic substances containing sulfur or nitrogen and most odorous substances are flammable, so when burned at an appropriate temperature, carbon dioxide, water, and other odorless gases are formed.
기존의 악취를 제거를 하기 위하여 가격이 매우 비싼 촉매로는 백금을 주로 사용한다. 흡착법은 충진탑과 같은 형태에 활성탄과 같은 흡착제를 충진 시켜 악취가스를 통과시켜 제거하는 방법으로 처리 효율이 높으나 활성탄 등을 재생하여야 하며, 처리비용도 높은 단점이 있다.In order to remove the existing odor, platinum is mainly used as a very expensive catalyst. The adsorption method is a method in which an adsorbent such as activated carbon is filled in the same form as a packed tower to remove the odor gas by passing it through.
또한 미생물 탈취법은 담체에 부착된 미생물을 사용하여 악취물질을 이산화탄소, 물 그리고 광물염으로 전환시키는 방법이다. 고농도 탄화수소 증기의 배출 시와 같은 경우는 증기를 냉각, 응축하여 회수함과 동시에 배출가스 중의 탄화수소 농도를 저감시키는 응축법을 이용하고 있다.In addition, the microbial deodorization method is a method of converting odor substances into carbon dioxide, water and mineral salts using microorganisms attached to the carrier. In the case of discharging high-concentration hydrocarbon vapors, a condensation method is used to reduce the concentration of hydrocarbons in the exhaust gas while cooling, condensing, and recovering the vapor.
또한 오존 산화법은 기체상태의 악취물질에 오존을 작용시켜 상온 산화에 의하여 탈취하는 방법으로 분뇨처리장과 같은 곳에서 많이 이용되고 있다. 그러나 꼭 필요한 양의 오존만을 발생시켜 주지 않으면 과량의 오존자체가 문제가 된다. 소극적인 방법으로는 악취를 직접 제거하는 대신에 방향이 강한 물질로 악취를 마스킹(masking)하는 방법도 많이 이용되고 있는 실정이다.In addition, ozone oxidation is a method of deodorizing by oxidation at room temperature by acting ozone on odorous substances in gaseous state, and it is widely used in places such as manure treatment plants. However, if only a necessary amount of ozone is not generated, excess ozone itself becomes a problem. As a passive method, instead of directly removing the odor, a method of masking the odor with a material having a strong fragrance is also widely used.
따라서 본 발명은 이러한 종래의 결점을 해소하기 위하여 안출된 것으로, 본 발명의 해결과제는, 인간에게 불쾌감을 주는 악취를 갖는 물질.Therefore, the present invention has been devised in order to solve these conventional drawbacks, and the object of the present invention is to provide a substance having an unpleasant odor to humans.
원인별로는 식품에 원래 함유되고 있는 것과 보존 과정에서 발행하는 것으로 나뉘어진다. 전자에는 동물의 지방에 포함되는 단쇄지방산, 두리안(durian, 과실)의 악취 등이 있다. 후자에는 원래 무취의 물질이 효소나 미생물의 활동으로 악취물질로 변하는 것과 산화에 의해 악취물질로 변하는 것이 있다. 전자의 예는 생선의 부패취로 물고기에 함유된 아미노산이 악취의 아민으로 변한다. 후자의 예는 불포화지방산으로부터 카보닐 화합물의 생성이다. 악취물질을 화학구조로 분류하면 함질소화합물의 아민, 함황산화합물의 메르캅탄, 함산소화합물의 carbonyl 등으로 나누어진다. 식품의 가공과정에서는 부차 반응에 의해 악취물질이 발생하는 예가 많다. 그 발생은 제품의 품질을 떨어뜨릴 뿐 아니라 작업 환경의 악화나 공해요인으로도 되기 때문에 주의가 필요하다.According to the cause, it is divided into those originally contained in food and those issued during the preservation process. The former includes short-chain fatty acids contained in animal fat, and the smell of durian (fruit). In the latter, there are those that are originally odorless substances that are converted into odor substances due to the activity of enzymes or microorganisms, and those that are odorless substances that are oxidized. An example of the former is the rotten odor of fish, in which amino acids contained in fish are converted into odorous amines. An example of the latter is the production of carbonyl compounds from unsaturated fatty acids. When odorous substances are classified by chemical structure, they are divided into amines of nitrogen-containing compounds, mercaptans of sulfur-containing compounds, and carbonyl of oxygen-containing compounds. There are many cases in which odor substances are generated by side reactions in the processing of food. Its occurrence not only deteriorates the quality of the product, but also deteriorates the working environment or causes pollution, so caution is required.
그래서 본 금속이온 탈취제는 강한 탈취력을 갖는 아온 금속들은 각종 정화이온성과 광촉매의 역할들을 최대로 생성하여 공기 중의 각종악취 및 세균, 바이러스를 살균하여 청정하게 만들어주는 원리의 악취제거제이다.Therefore, this metal ion deodorant is a deodorizing agent with the principle of making it clean by sterilizing various odors, bacteria, and viruses in the air by maximally generating various purification ions and the roles of photocatalysts with the strong deodorizing power of Aon metals.
또한 냄새분자 고리를 끊어주는 정화 이온들의 화학반응으로 인해 휘발성 유기화합물(VOCs)을 화학적으로 완전 분해하여 인체 유해물질을 제거하며, 악취의 근원인 각종 냄새분자를 최고의 산화제인 H2O2, O2, OH래디칼과 정화이온들로 완전 분해하여 악취 또한 제거를 하는 메커니즘이다.In addition, it chemically completely decomposes volatile organic compounds (VOCs) due to the chemical reaction of purifying ions that break the cycle of odor molecules to remove harmful substances to the human body. It is a mechanism that completely decomposes into purifying ions and also removes odors.
본 발명품은 건강 문제, 각종 생활환경, 산업환경의 문제들을 친환경 악취제거제 개발로 인한 오염원들을 새로운 친환경 물질을 통하여 정화해 나아가 우리생활주변의 환경을 깨끗하고도 맑은 공기를 제공을 하는 것을 목표로하는 발명품인 것이다.The present invention aims to provide clean and clean air to the environment around our lives by purifying the pollutants caused by the development of an eco-friendly odor remover through new eco-friendly materials for health problems, various living environments, and industrial environment problems. It is an invention.
본 발명은 우리 생활 주변에서 발생되는 악취들을 살펴보면 음식물 쓰레기 냄새, 생활하수의 냄새, 공장폐수의 냄새, 가축분뇨의 냄새, 쓰레기매립장냄새, 공동어시장내에서의 냄새 등.. 수많은 곳에서 발생되는 냄새들을 제거를 하는 시스템을 유기 및 무기물질을 융 복합시켜 대기 중으로 비신 되는 냄새입자들을 광촉매의 메커니즘과, 식물에서 추출한 인체에 무해성 유기 항균제를 융 복합화시켜줌으로서 입체적으로 냄새와 박테리아를 제거를 시켜주는 방식의 제조의 공정으로서 Copper chloride, platinum chloride, silver chloride, silver nitrate, titanium chloride, zinc chloride, tungsten chloride, cobalt chloride, iron chloride, chloride, yttrium chloride 중에서 한가지 이상을 선택을 하여 3~40중량 부를 일반 물 100중량부에 서서히 첨가를 gkduu 현탁액으로 만들어 주는 제조의 공정과,In the present invention, looking at the odors generated around our lives, the smell of food waste, the smell of domestic sewage, the smell of factory wastewater, the smell of livestock excreta, the smell of a landfill site, the smell in a common fish market, etc. Odors generated in numerous places It is a system that removes odors and bacteria three-dimensionally by integrating organic and inorganic substances into a system that removes odors by fusion with the mechanism of photocatalyst for odor particles in the air and organic antibacterial agents that are harmless to the human body extracted from plants. 3 to 40 parts by weight by selecting one or more from copper chloride, platinum chloride, silver chloride, silver nitrate, titanium chloride, zinc chloride, tungsten chloride, cobalt chloride, iron chloride, chloride, and yttrium chloride as a manufacturing process The manufacturing process of gradually adding to 100 parts by weight of water to make a gkduu suspension,
이를 중화의 공정을 Potassium hydroxide, sodium hydroxide, magnesium hydroxide, ammonia 중에서 한가지 이상을 선택을 하여 5~50중량부를 일반 물 100중량부에 서서히 첨가를 하여 현탁액으로 만들어서 이를 서서히 상기 현탁액에 부어주어서 뿌연한 침전물을 수득을 하는 제조의 공정과. 이를 염소(Cl)를 떼어버리기 위해서 수세의 공정을 3회 이상 진행을 해주는 공정과. 수세를 마친 용액에 분산을 시켜주기 위하여 펩타이저, 계면활성제, 무기산 중에서 한 가지 이상을 선택을 하여 0.1~5중량부를 넣고 3000rpm이상 고속으로 교반을 시켜주는 제조의 공정과, 우리 몸과 각종 동물들의 호흡기관에 들어가도 무해한 치자를 천연안료로 사용하기 위하여 끓는 물 100중량부에 0.01~5중량부를 넣어서 100중량부에 30%까지 되도록 물을 증발시킨 농축액을 안료로서 이용을 하는 제조의 공정과,In the neutralization process, at least one of potassium hydroxide, sodium hydroxide, magnesium hydroxide, and ammonia is selected, 5-50 parts by weight is gradually added to 100 parts by weight of general water to form a suspension, and this is slowly poured into the suspension to form a cloudy precipitate. To obtain the manufacturing process and. In order to remove chlorine (Cl), the process of washing with water is performed three or more times. The manufacturing process of selecting one or more of peptizers, surfactants, and inorganic acids to disperse in the solution after washing, adding 0.1 to 5 parts by weight, and stirring at high speed over 3000 rpm, our body and various animals In order to use gardenia, which is harmless even if it enters their respiratory organs, as a natural pigment, 0.01 to 5 parts by weight are added to 100 parts by weight of boiling water, and the concentrated solution obtained by evaporating water up to 30% in 100 parts by weight is used as a pigment.
유기물 천연항균제를 사용하기 위하여 끓는 물 100중량부에 고심 0.1~20중량부를 넣어서 100중량부 물에 30%까지 되도록 물을 증발시킨 농축액을 수득을 하는 제조의 공정으로서 위의 공정들로부터 얻은 물질들을 함께 브랜딩을 하여 멀티타입 악취탈취제를 얻는 발명품이다.In order to use an organic natural antibacterial agent, 0.1 to 20 parts by weight of bitter gourd is put in 100 parts by weight of boiling water to obtain a concentrate obtained by evaporating water up to 30% in 100 parts by weight of water. It is an invention that obtains a multi-type odor deodorant by branding together.
본 발명은 각종 냄새들을 탈취, 분자 고리를 Ep어버리기 위해서 어떤 물질이 광 에너지를 받았을 때 광에 의해 화학반응을 촉진할 수 있거나 촉매작용을 갖게 되는 물질을 말한다. 이 경우의 대표적인 촉매반응으로 물분자 분해 촉매반응, 유기물질분해 촉매반응, 친수성표면 개질반응, self cleaning 반응 등이 있다.The present invention refers to a material that can promote a chemical reaction by light or has a catalytic action when a certain material receives light energy in order to deodorize various odors and Ep molecular rings. Representative catalytic reactions in this case include water molecule decomposition catalytic reaction, organic material decomposition catalytic reaction, hydrophilic surface modification reaction, and self-cleaning reaction.
광화학반응을 촉진시키는 물질을 말하며 반도체·색소·엽록소도 그 중 하나이다. 반도체의 금속산화물에 의한 효과는 환경문제 해결에도 도움이 되는 기초기술의 하나이다. 금속산화물이 유해물질을 산화 분해하는 기능을 이용하여 환경정화(환경오염을 제거하고 항균, 탈취하는 등의 효과)하는 데 이용되거나, 초친수성 기능(표면이 젖어도 물방울을 만들지 않고 엷은 막을 만들어 내는 성질)을 응용하여 셀프크리닝 효과가 있는 유리와 타일, 청소기, 공기청정기, 냉장고, 도로포장, 커튼, 벽지, 인공관엽식물 등 다양한 제품에 적용되고 있다. 금속 산화물은 자외선에 반응하지만 가시광선의 영역에도 반응하는 기술력을 포함시켜서 광역략을 가질 수 있도록 하였다.It refers to a substance that promotes a photochemical reaction, and semiconductors, pigments, and chlorophyll are one of them. The effect of metal oxides in semiconductors is one of the basic technologies that help solve environmental problems. Metal oxide uses the function of oxidatively decomposing harmful substances to purify the environment (removal of environmental pollution, antibacterial and deodorizing effects, etc.) It is applied to various products such as glass, tiles, vacuum cleaners, air purifiers, refrigerators, road pavements, curtains, wallpaper, artificial houseplants, etc. with self-cleaning effect. Metal oxide reacts to ultraviolet light, but includes technology that responds to visible light so that it can have a wide range of strategies.
..
이하에서 본 발명의 바람직한 실시예를 첨부시킨 도면에 따라서 보다 상세하게 설명하기로 한다.Hereinafter, preferred embodiments of the present invention will be described in more detail with reference to the accompanying drawings.
본 발명은 우리 생활 주변에서 발생되는 악취들을 살펴보면 음식물 쓰레기 냄새, 생활하수의 냄새, 공장폐수의 냄새, 가축분뇨의 냄새, 쓰레기매립장냄새, 공동어시장내에서의 냄새 등.. 수많은 곳에서 발생되는 냄새들을 제거를 하는 시스템을 유기 및 무기물질을 융 복합시켜 대기 중으로 비신 되는 냄새입자들을 광촉매의 메커니즘과, 식물에서 추출한 인체에 무해성 유기 항균제를 융 복합화 시켜줌으로서 입체적으로 냄새와 박테리아를 제거를 시켜주는 방식의 제조의 공정으로서 Copper chloride, platinum chloride, silver chloride, silver nitrate, titanium chloride, zinc chloride, tungsten chloride, cobalt chloride, iron chloride, chloride, yttrium chloride 중에서 한가지 이상을 선택을 하여 3~40중량 부를 일반 물 100중량부에 서서히 첨가를 gkduu 현탁액으로 만들어 주는 제조의 공정과,In the present invention, looking at the odors generated around our lives, the smell of food waste, the smell of domestic sewage, the smell of factory wastewater, the smell of livestock excreta, the smell of a landfill site, the smell in a common fish market, etc. Odors generated in numerous places It is a system that removes odors and bacteria three-dimensionally by fusion of organic and inorganic substances in a system that removes odors by fusion of organic and inorganic substances with a photocatalyst mechanism and organic antibacterial agents that are harmless to the human body extracted from plants. 3 to 40 parts by weight by selecting one or more from copper chloride, platinum chloride, silver chloride, silver nitrate, titanium chloride, zinc chloride, tungsten chloride, cobalt chloride, iron chloride, chloride, and yttrium chloride as a manufacturing process The manufacturing process of gradually adding to 100 parts by weight of water to make a gkduu suspension,
이를 중화의 공정을 Potassium hydroxide, sodium hydroxide, magnesium hydroxide, ammonia 중에서 한가지 이상을 선택을 하여 5~50중량부를 일반 물 100중량부에 서서히 첨가를 하여 현탁액으로 만들어서 이를 서서히 상기 현탁액에 부어주어서 뿌연한 침전물을 수득을 하는 제조의 공정과. 이를 염소(Cl)를 떼어버리기 위해서 수세의 공정을 3회 이상 진행을 해주는 공정과. 수세를 마친 용액에 분산을 시켜주기 위하여 펩타이저, 계면활성제, 무기산 중에서 한 가지 이상을 선택을 하여 0.1~5중량부를 넣고 3000rpm이상 고속으로 교반을 시켜주는 제조의 공정과, 우리 몸과 각종 동물들의 호흡기관에 들어가도 무해한 치자를 천연안료로 사용하기 위하여 끓는 물 100중량부에 0.01~5중량부를 넣어서 100중량부에 30%까지 되도록 물을 증발시킨 농축액을 안료로서 이용을 하는 제조의 공정과,In the neutralization process, at least one of potassium hydroxide, sodium hydroxide, magnesium hydroxide, and ammonia is selected, 5-50 parts by weight is gradually added to 100 parts by weight of general water to form a suspension, and this is slowly poured into the suspension to form a cloudy precipitate. To obtain the manufacturing process and. In order to remove chlorine (Cl), the process of washing with water is performed three or more times. The manufacturing process of selecting one or more of peptizers, surfactants, and inorganic acids to disperse in the solution after washing, adding 0.1 to 5 parts by weight, and stirring at high speed over 3000 rpm, our body and various animals In order to use gardenia, which is harmless even if it enters their respiratory organs, as a natural pigment, 0.01 to 5 parts by weight are added to 100 parts by weight of boiling water, and the concentrated solution obtained by evaporating water up to 30% in 100 parts by weight is used as a pigment.
유기물 천연항균제를 사용하기 위하여 끓는 물 100중량부에 고심 0.1~20중량부를 넣어서 100중량부 물에 30%까지 되도록 물을 증발시킨 농축액을 수득을 하는 제조의 공정으로서 위의 공정들로부터 얻은 물질들을 함께 브랜딩을 하여 멀티타입 악취탈취제를 얻는 발명품이다.In order to use an organic natural antibacterial agent, 0.1 to 20 parts by weight of bitter gourd is put in 100 parts by weight of boiling water to obtain a concentrate obtained by evaporating water up to 30% in 100 parts by weight of water. It is an invention that obtains a multi-type odor deodorant by branding together.
본 발명은 새집증후군용, 하수구냄새제거제, 축산분뇨냄새제거제, 공장폐수냄새제거제, 하수종말처리장, 쓰레기장, 침출수, 음식물스레기 등..The present invention is for sick house syndrome, sewer odor remover, livestock manure odor remover, factory wastewater odor remover, sewage treatment plant, garbage yard, leachate, food waste, etc.
Claims (9)
Potassium hydroxide, sodium hydroxide, magnesium hydroxide, ammonia 중에서 한 가지 이상을 선택을 하여 5~50중량부,
펩타이저, 계면활성제, 무기산 중에서 한가지 이상을 선택을 하여 0.1~5중량부, 천연안료 0.01~5중량부,
고삼 추출물 0.1~20중량부,3 to 40 parts by weight of one or more selected from copper chloride, platinum chloride, silver chloride, silver nitrate, titanium chloride, zinc chloride, tungsten chloride, cobalt chloride, iron chloride, chloride, and yttrium chloride;
5 to 50 parts by weight of one or more of potassium hydroxide, sodium hydroxide, magnesium hydroxide, and ammonia,
0.1 to 5 parts by weight of one or more selected from peptizer, surfactant, and inorganic acid, 0.01 to 5 parts by weight of natural pigment,
0.1 to 20 parts by weight of ginseng extract,
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KR100824907B1 (en) | 2006-11-09 | 2008-04-23 | 최세영 | Visible-light photocatalyst manufacturing method of antimicrobial and deodorizer |
KR20080100535A (en) | 2007-05-14 | 2008-11-19 | (주)자연과 생명 | Manufacturing method for a bad smell remover using organic material and microorganism |
KR100878253B1 (en) | 2007-06-19 | 2009-01-15 | 정경환 | Preparation Method of Odor Remover combined Photocatalysts with Wood Bamboo Vinegars |
KR101570824B1 (en) | 2014-05-22 | 2015-11-24 | (주)원드림 | Method for production of environment-friendly composition removal of odor and there from |
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KR100824907B1 (en) | 2006-11-09 | 2008-04-23 | 최세영 | Visible-light photocatalyst manufacturing method of antimicrobial and deodorizer |
KR20080100535A (en) | 2007-05-14 | 2008-11-19 | (주)자연과 생명 | Manufacturing method for a bad smell remover using organic material and microorganism |
KR100878253B1 (en) | 2007-06-19 | 2009-01-15 | 정경환 | Preparation Method of Odor Remover combined Photocatalysts with Wood Bamboo Vinegars |
KR101570824B1 (en) | 2014-05-22 | 2015-11-24 | (주)원드림 | Method for production of environment-friendly composition removal of odor and there from |
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