KR20220015455A - Composite yarns and fabrics and textile products - Google Patents

Composite yarns and fabrics and textile products Download PDF

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Publication number
KR20220015455A
KR20220015455A KR1020217042904A KR20217042904A KR20220015455A KR 20220015455 A KR20220015455 A KR 20220015455A KR 1020217042904 A KR1020217042904 A KR 1020217042904A KR 20217042904 A KR20217042904 A KR 20217042904A KR 20220015455 A KR20220015455 A KR 20220015455A
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South Korea
Prior art keywords
yarn
composite yarn
tick
thin
composite
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KR1020217042904A
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Korean (ko)
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소노미 시바타
노부아키 오가타
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데이진 프론티아 가부시키가이샤
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Publication of KR20220015455A publication Critical patent/KR20220015455A/en

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    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00Materials specially adapted for outerwear
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G1/00Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics
    • D02G1/02Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics by twisting, fixing the twist and backtwisting, i.e. by imparting false twist
    • D02G1/0206Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics by twisting, fixing the twist and backtwisting, i.e. by imparting false twist by false-twisting
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G1/00Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics
    • D02G1/16Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics using jets or streams of turbulent gases, e.g. air, steam
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04Blended or other yarns or threads containing components made from different materials
    • D02G3/042Blended or other yarns or threads containing components made from different materials all components being made from natural material
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04Blended or other yarns or threads containing components made from different materials
    • D02G3/045Blended or other yarns or threads containing components made from different materials all components being made from artificial or synthetic material
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • D02G3/36Cored or coated yarns or threads
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02JFINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
    • D02J1/00Modifying the structure or properties resulting from a particular structure; Modifying, retaining, or restoring the physical form or cross-sectional shape, e.g. by use of dies or squeeze rollers
    • D02J1/08Interlacing constituent filaments without breakage thereof, e.g. by use of turbulent air streams
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/283Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/40Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
    • D03D15/43Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads with differing diameters
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/40Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
    • D03D15/49Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads textured; curled; crimped
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B1/00Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/14Other fabrics or articles characterised primarily by the use of particular thread materials
    • D04B1/16Other fabrics or articles characterised primarily by the use of particular thread materials synthetic threads
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2501/00Wearing apparel
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2503/00Domestic or personal
    • D10B2503/06Bed linen
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2505/00Industrial
    • D10B2505/08Upholstery, mattresses

Abstract

과제는, 코튼조 외관, 질감 및 항스내깅(snagging)성이 우수하고, 바람직하게는 방투성 및 물기 흡수 신속 건조성도 우수한 복합사 및 포백 및 섬유 제품을 제공하는 것이며, 해결 수단은, 틱앤씬얀과 권축사를 사용하여 복합사를 얻고 필요에 따라서 포백을 얻는 것이다.An object of the present invention is to provide a composite yarn, fabric, and textile products that are excellent in cotton-like appearance, texture, and anti-snagging properties, and are preferably excellent in permeability and moisture absorption and quick drying properties. Composite yarns are obtained by using crimp yarns and, if necessary, fabrics are obtained.

Description

복합사 및 포백 및 섬유 제품Composite yarns and fabrics and textile products

본 발명은, 코튼조 외관, 질감 및 항스내깅성이 우수하고, 바람직하게는 방투성 및 물기 흡수 신속 건조성(吸水速乾性)도 우수한 복합사 및 포백 및 섬유 제품에 관한 것이다.The present invention relates to a composite yarn, a fabric, and a fiber product having excellent cotton-like appearance, texture, and anti-snagging properties, and preferably also excellent permeability and moisture absorption and quick drying properties.

폴리에틸렌테레프탈레이트(PET)로 대표되는 폴리에스테르 장섬유는, 의료용, 산업 자재용 등에 폭넓게 사용되고 있다. 그러나, 그 제조 방법의 특성에 의해, 천연 섬유나 방적사에 비해 굵기 불균일(太斑)이 작고, 질감이나 외관 변화가 부족하다는 결점을 갖고 있다.Polyester filaments typified by polyethylene terephthalate (PET) are widely used for medical purposes, industrial materials, and the like. However, due to the characteristics of the manufacturing method, there are drawbacks in that the thickness non-uniformity is small compared to natural fibers or spun yarns, and changes in texture and appearance are insufficient.

그러한 결점을 해소하기 위해서, 폴리에스테르 고배향 미연신사의 미연신 부분의 길이를 컨트롤함으로써 폴리에스테르 섬유에 굵기 불균일을 부여하고, 포백에 임의의 잔무늬(飛白)상 외관을 부여하는 방법이 제안되어 있다(예를 들어, 특허문헌 1, 특허문헌 2).In order to solve such a drawback, a method of imparting thickness unevenness to the polyester fiber by controlling the length of the undrawn portion of the polyester highly oriented undrawn yarn and imparting an arbitrary fine-pattern appearance to the fabric has been proposed. (For example, patent document 1, patent document 2).

그러나, 이들 포백에서는, 코튼조 외관이나 항스내깅성 등의 점에서 아직 충분하다고는 말할 수 없었다.However, in these fabrics, it cannot be said that it is still sufficient in points, such as a cotton-like appearance and anti-snagging property.

일본 특허 공개 소60-199941호 공보Japanese Patent Laid-Open No. 60-199941 일본 특허 공개 평7-229030호 공보Japanese Patent Laid-Open No. 7-229030

본 발명은 상기 배경을 감안하여 이루어진 것이며, 그 목적은, 코튼조 외관, 질감 및 항스내깅성이 우수하고, 바람직하게는 방투성 및 물기 흡수 신속 건조성도 우수한 복합사 및 포백 및 섬유 제품을 제공하는 데 있다.The present invention has been made in view of the above background, and its object is to provide a composite yarn, fabric, and textile products that are excellent in cotton-like appearance, texture and anti-snagging properties, and preferably have excellent permeability and moisture absorption and quick drying properties. there is

본 발명자들은 상기 과제를 달성하기 위해 예의 검토한 결과, 본 발명을 완성하기에 이르렀다.MEANS TO SOLVE THE PROBLEM The present inventors came to complete this invention, as a result of earnestly examining in order to achieve the said subject.

이리하여, 본 발명에 따르면 「틱앤씬얀(thick and thin yarn)과 권축사를 포함하는 것을 특징으로 하는 복합사.」가 제공된다.Thus, according to the present invention, "a composite yarn comprising a thick and thin yarn and a crimped yarn." is provided.

그 때, 상기 틱앤씬얀이 비권축사인 것이 바람직하다. 또한, 복합사가 상기 틱앤씬얀을 복합사 중량 대비 30 내지 85중량%의 범위 내에서 포함하는 것이 바람직하다. 또한, 복합사에 있어서 교락의 개수 120개/m 이하로 인터레이스 가공이 실시되어 있는 것이 바람직하다. 또한, 복합사에 있어서, 틱앤씬얀과 권축사가 교락되거나, 또는 틱앤씬얀이 중심에 위치하고 권축사가 시스에 위치하는 비병행부와, 틱앤씬얀과 권축사가 병행 형상이 된 병행부가 혼재하고 있는 것이 바람직하다. 또한, 복합사에 있어서, 복합사의 길이에 대하여 비병행부 40 내지 95%인 것이 바람직하다. 또한, 복합사에 있어서, 복합사의 길이에 대하여 병행 부분 5 내지 40%인 것이 바람직하다. 또한, 상기 틱앤씬얀의 단섬유 섬도가 1.5dtex 이상인 것이 바람직하다. 또한, 상기 권축사의 단섬유 섬도가 1.0dtex 이하인 것이 바람직하다. 또한, 상기 틱앤씬얀 및/또는 권축사가 폴리에스테르 섬유 또는 나일론 섬유를 포함하는 것이 바람직하다. 또한, 상기 틱앤씬얀 및/또는 권축사가 케미컬 또는 머티리얼 리사이클된 폴리머를 포함하는 것이 바람직하다. 또한, 상기 틱앤씬얀 및/또는 권축사가 양이온 가염성 폴리에스테르를 포함하는 것이 바람직하다. 또한, 상기 틱앤씬얀 및/또는 권축사에 있어서, 소광제의 함유율이 0.1질량% 이상인 것이 바람직하다.In that case, it is preferable that the tick and thin yarn is a non-crimped yarn. In addition, it is preferable that the composite yarn contains the tick and thin yarn within the range of 30 to 85% by weight based on the weight of the composite yarn. In addition, in the composite yarn, it is preferable that interlacing is performed at a number of entanglements of 120 pieces/m or less. In addition, in the composite yarn, the tick and thin yarn and the crimp yarn are intertwined, or the non-parallel portion in which the tick and thin yarn is centered and the crimp yarn is located in the sheath, and the parallel portion in which the tick and thin yarn and the crimp yarn are in a parallel shape are mixed. it is preferable Further, in the composite yarn, it is preferable that the non-parallel portion is 40 to 95% of the length of the composite yarn. Further, in the composite yarn, it is preferable that the parallel portion is 5 to 40% with respect to the length of the composite yarn. In addition, it is preferable that the single fiber fineness of the tick and thin yarn is 1.5 dtex or more. In addition, it is preferable that the single fiber fineness of the crimped yarn is 1.0 dtex or less. In addition, it is preferable that the tick and thin yarn and/or the crimp yarn include polyester fiber or nylon fiber. In addition, it is preferable that the tick and thin yarn and/or the crimp yarn include a chemically or material recycled polymer. In addition, it is preferable that the tick and thin yarn and/or the crimp yarn include a cationic dyeable polyester. Further, in the tick and thin yarn and/or crimped yarn, the content of the matting agent is preferably 0.1% by mass or more.

본 발명에 따르면, 상기의 복합사를 포함하는 포백이 제공된다. 그 때, 포백이 35 내지 100코스/2.54cm 또한 30 내지 100웨일/2.54cm의 밀도를 갖는 편물인 것이 바람직하다. 또한, JIS L 1058-1995 D3법의 쇠톱에 의해 15시간 테스트하여, 항스내깅성이 3급 이상인 것이 바람직하다.According to the present invention, there is provided a fabric comprising the above composite yarn. In that case, it is preferable that the fabric is a knitted fabric having a density of 35 to 100 courses/2.54 cm and 30 to 100 wales/2.54 cm. Moreover, it is tested for 15 hours with the hacksaw of JIS L 1058-1995 D3 method, and it is preferable that anti-snagging property is 3rd grade or more.

또한, 본 발명에 따르면, 상기의 복합사 또는 포백을 사용하여 이루어지는, 스포츠 웨어, 아우터 웨어, 이너 웨어, 신사 의료(衣料), 부인 의료, 개호용 의료, 작업복, 카시트 표피재 및 침구로 이루어지는 군에서 선택되는 어느 하나의 섬유 제품이 제공된다.In addition, according to the present invention, sportswear, outerwear, innerwear, menswear, gynecological care, nursing care, work clothes, car seat cover material and bedding, which are made using the above composite yarn or fabric, are group consisting of Any one of the textile products selected from is provided.

본 발명에 따르면, 코튼조 외관, 질감 및 항스내깅성이 우수하고, 바람직하게는 방투성 및 물기 흡수 신속 건조성도 우수한 복합사 및 포백 및 섬유 제품이 얻어진다.Advantageous Effects of Invention According to the present invention, a composite yarn, fabric, and fiber products having excellent cotton-like appearance, texture and anti-snagging properties, and preferably excellent permeability and moisture absorption and quick drying properties are obtained.

이하, 본 발명의 실시 형태에 대하여 상세하게 설명한다. 먼저, 본 발명의 복합사는 틱앤씬얀과 권축사를 포함하는 복합사이다.EMBODIMENT OF THE INVENTION Hereinafter, embodiment of this invention is described in detail. First, the composite yarn of the present invention is a composite yarn including a tick and thin yarn and a crimp yarn.

여기서, 복합사가 상기 틱앤씬얀을 복합사 중량 대비 30 내지 85중량%(보다 바람직하게는 51 내지 80중량%)의 범위 내에서 포함하는 것이 바람직하다. 또한, 권축사의 중량비(대 복합사 중량)로서는, 15 내지 70중량%(보다 바람직하게는 30 내지 48중량%)의 범위 내인 것이 바람직하다. 상기 틱앤씬얀의 중량비(대 복합사 중량)가 해당 범위보다 작은 경우, 우수한 코튼조 외관을 얻지 못할 우려가 있다. 또한, 상기 틱앤씬얀의 중량비가 해당 범위보다도 큰 경우, 포백의 항스내깅성이 저하될 우려가 있다.Here, the composite yarn preferably contains the tick and thin yarn within the range of 30 to 85% by weight (more preferably 51 to 80% by weight) based on the weight of the composite yarn. Further, the weight ratio of the crimped yarn (to the weight of the composite yarn) is preferably within the range of 15 to 70 wt% (more preferably 30 to 48 wt%). If the weight ratio of the tick and thin yarn (to the weight of the composite yarn) is less than the corresponding range, there is a fear that an excellent cotton-like appearance may not be obtained. In addition, when the weight ratio of the tick and thin yarn is larger than the corresponding range, there is a fear that the anti-snagging properties of the fabric may be lowered.

여기서, 상기 틱앤씬얀은 권축사여도 되지만, 비권축사인 것이 바람직하다. 상기 틱앤씬얀이 비권축사이면, 틱앤씬얀과 권축사의 권축차가 큼으로써, 복합사 중에서의 굵기 불균일이 커지고, 코튼조 외관 및 질감이 우수하다. 또한, 또한 복합사의 코어부에 비권축사를 배치하고, 시스부에 권축사를 배치한 경우, 모세관 현상에 의해 물기 흡수 신속 건조성이 향상된다.Here, the tick and thin yarn may be a crimped yarn, but is preferably a non-crimped yarn. When the tick and thin yarn is a non-crimped yarn, the difference in crimping between the tick and thin yarn and the crimped yarn is large, so that the thickness non-uniformity in the composite yarn is increased, and the cotton-like appearance and texture are excellent. In addition, when the non-crimped yarn is disposed in the core portion of the composite yarn and the crimped yarn is disposed in the sheath portion, the quick drying property of water absorption is improved due to the capillary phenomenon.

상기 틱앤씬얀으로서는, 일본 특허 공개 제2000-234232호 공보에 기재된 바와 같은 방적사와 같은 정도의 굵기 불균일을 갖고 단섬유간에도 랜덤한 굵기 불균일을 갖는 틱앤씬얀이나, 일본 특허 공개 평7-324237호 공보에 기재된 바와 같은 마찰 저항체를 사용하여 불균일 연신하여 얻어진 틱앤씬얀 등이 예시된다.As the tick and thin yarn, a tick and thin yarn having the same thickness unevenness as spun yarn as described in Japanese Patent Laid-Open No. 2000-234232 and random thickness unevenness even between single fibers, as described in Japanese Patent Laid-Open No. 7-324237 Tick and thin yarns obtained by non-uniform stretching using a friction resistor as described above are exemplified.

한편, 권축사로서는, 사이드 바이 사이드형 복합 섬유의 잠재 권축을 현재화시킨 권축사 등이어도 되지만, 가연 권축 가공사가 바람직하다.On the other hand, the crimped yarn may be a crimped yarn in which the potential crimping of the side-by-side type composite fiber is realized, but false twist crimped yarn is preferable.

상기 틱앤씬얀 및/또는 권축사를 형성하는 폴리머의 종류로서는, 폴리에스테르나 지방족 폴리아미드(나일론 6, 나일론 66 등)가 바람직하다. 그 중에서도, 폴리에틸렌테레프탈레이트나 폴리트리메틸렌테레프탈레이트, 폴리부틸렌테레프탈레이트, 폴리락트산, 제3 성분을 공중합시킨 폴리에스테르 등이 보다 바람직하게 예시된다. 이러한 폴리에스테르로서는, 머티리얼 리사이클 또는 케미컬 리사이클된 폴리에스테르여도 된다. 나아가, 일본 특허 공개 제2004-270097호 공보나 일본 특허 공개 제2004-211268호 공보에 기재되어 있는 것과 같은, 특정한 인 화합물 및 티타늄 화합물을 포함하는 촉매를 사용하여 얻어진 폴리에스테르여도 된다. 해당 폴리머 중에는, 본 발명의 목적을 손상시키지 않는 범위 내에서 필요에 따라서, 미세 구멍 형성제, 양이온 염료 가염제, 착색 방지제, 열 안정제, 형광 증백제, 소광제, 착색제, 흡습제, 무기 미립자가 1종 또는 2종 이상 포함되어 있어도 된다. 특히 소광제가 폴리머 중량 대비 0.1중량% 이상(보다 바람직하게는 0.3 내지 2.0중량%) 포함되어 있으면, 방투성이 향상되어 바람직하다. 구체적으로는, 세미덜(semi-dull) 폴리에스테르나 풀덜(full-dull) 폴리에스테르가 바람직하다. 또한, 양이온 염료 가염제(에스테르 형성성 술폰산 금속염 화합물 등)가 포함되어 있으면, 국제 공개 제2011/048888호 팸플릿에 기재되어 있는 바와 같이 산성 처리함으로써 항균 방취성이 부가되어 바람직하다.As the kind of the polymer forming the tick and thin yarn and/or the crimped yarn, polyester or aliphatic polyamide (nylon 6, nylon 66, etc.) is preferable. Especially, polyethylene terephthalate, polytrimethylene terephthalate, polybutylene terephthalate, polylactic acid, polyester etc. which copolymerized the 3rd component are illustrated more preferably. As such polyester, material recycled or chemically recycled polyester may be sufficient. Furthermore, polyester obtained using the catalyst containing a specific phosphorus compound and a titanium compound as described in Unexamined-Japanese-Patent No. 2004-270097 or 2004-211268 may be sufficient. Among the polymers, micropore formers, cationic dye dyestuffs, color inhibitors, heat stabilizers, optical brighteners, matting agents, colorants, moisture absorbents, and inorganic fine particles may be added as needed within the scope not impairing the object of the present invention. Species or 2 or more types may be included. In particular, when 0.1 wt% or more (more preferably 0.3 to 2.0 wt%) of the matting agent is included relative to the weight of the polymer, permeability is improved, which is preferable. Specifically, semi-dull polyester or full-dull polyester is preferable. In addition, if a cationic dye dyeing agent (such as an ester-forming sulfonic acid metal salt compound) is contained, antibacterial and deodorizing properties are added by acid treatment as described in International Publication No. 2011/048888 pamphlet, which is preferable.

또한, 상기 틱앤씬얀에 있어서, 총 섬도는 22 내지 400dtex(보다 바람직하게는 30 내지 60dtex)인 것이 바람직하다. 또한, 단섬유 섬도가 1.5dtex 이상(보다 바람직하게는 1.5 내지 3.0dtex)인 것이 바람직하다. 또한, 필라멘트수가 12 내지 200개(보다 바람직하게는 20 내지 60개)인 것이 바람직하다.In addition, in the tick and thin yarn, the total fineness is preferably 22 to 400 dtex (more preferably 30 to 60 dtex). In addition, it is preferable that the single fiber fineness is 1.5 dtex or more (more preferably 1.5 to 3.0 dtex). Further, it is preferable that the number of filaments is 12 to 200 (more preferably 20 to 60).

또한, 상기 권축사에 있어서, 우수한 코튼조의 외관과 항스내깅성을 얻기 위해, 총 섬도는 상기 틱앤씬얀보다 작은 것이 바람직하다. 특히 총 섬도가 18 내지 333dtex(보다 바람직하게는 20 내지 50dtex)인 것이 바람직하다. 또한, 단섬유 섬도가 1.0dtex 이하(보다 바람직하게는 0.1 내지 1.0dtex)인 것이 바람직하다. 또한, 필라멘트수 12 내지 200개(보다 바람직하게는 20 내지 60개)인 것이 바람직하다. 또한, 권축률로서는 2 내지 40%(보다 바람직하게는 5 내지 35%)의 범위 내인 것이 바람직하다.In addition, in the crimped yarn, in order to obtain an excellent cotton-like appearance and anti-snagging properties, it is preferable that the total fineness is smaller than that of the tick and thin yarn. In particular, it is preferable that the total fineness is 18 to 333 dtex (more preferably 20 to 50 dtex). In addition, it is preferable that the single fiber fineness is 1.0 dtex or less (more preferably 0.1 to 1.0 dtex). Further, the number of filaments is preferably 12 to 200 (more preferably 20 to 60). Moreover, as a crimp rate, it is preferable to exist in the range of 2 to 40 % (more preferably 5 to 35 %).

본 발명의 복합사는 상기의 틱앤씬얀과 권축사만으로 구성되는 것이 바람직하지만, 다른 섬유를 포함하고 있어도 된다. 또한, 복합 방법은 특별히 한정되지 않지만, 상기 틱앤씬얀 및 권축사를 병행하여 인터레이스 가공(공기 혼섬 가공)을 실시하는 것이 바람직하다.The composite yarn of the present invention is preferably composed of only the tick and thin yarn and the crimp yarn, but may contain other fibers. In addition, the composite method is not particularly limited, but it is preferable to perform interlacing (air mixed fiber processing) in parallel with the tick and thin yarn and the crimped yarn.

그 때, 교락 개수로서는, 200개/m 이하(보다 바람직하게는 120개/m 이하, 특히 바람직하게는 20 내지 120개/m)의 범위 내인 것이 바람직하다.In that case, as the number of bridges, it is preferable to exist in the range of 200 pieces/m or less (More preferably 120 pieces/m or less, Especially preferably, 20-120 pieces/m).

또한, 복합사에 있어서, 틱앤씬얀과 권축사가 교락되거나, 또는 틱앤씬얀이 중심에 위치하고 권축사가 시스에 위치하는 비병행부와, 틱앤씬얀과 권축사가 병행 형상이 된 병행부가 혼재하고 있는 것이 바람직하다. 또한, 이러한 복합사는, 예를 들어 일본 특허 공개 제2000-234232호 공보의 실시예 1에 기재된 방법에 따라서, 방적사와 같은 정도의 굵기 불균일을 갖고 단섬유간에도 랜덤한 굵기 불균일을 갖는 틱앤씬얀을 얻은 후, 해당 틱앤씬얀과 권축사를 병행하여 인터레이스 가공을 실시함으로써 얻어진다.In addition, in the composite yarn, the tick and thin yarn and the crimp yarn are intertwined, or the non-parallel portion in which the tick and thin yarn is centered and the crimp yarn is located in the sheath, and the parallel portion in which the tick and thin yarn and the crimp yarn are in a parallel shape are mixed. it is preferable In addition, such a composite yarn, for example, according to the method described in Example 1 of Japanese Patent Application Laid-Open No. 2000-234232, has the same thickness unevenness as the spun yarn and a tick and thin yarn having a random thickness unevenness even between single fibers. Then, it is obtained by performing interlacing processing in parallel with the tick and thin yarn and the crimped yarn.

여기서, 복합사에 있어서, 복합사의 길이에 대하여 비병행부가 40 내지 95%인 것이 바람직하다. 또한, 복합사에 있어서, 복합사의 길이에 대하여 병행 부분 이 5 내지 40%인 것이 바람직하다. 단, 각각의 비율은 포백으로부터 복합사(20cm)를 10개 발출하고, 복합사(20cm)에 대한 각각의 비율을 산출하여, 10개의 평균을 구하는 것으로 한다.Here, in the composite yarn, it is preferable that the non-parallel portion is 40 to 95% with respect to the length of the composite yarn. Further, in the composite yarn, it is preferable that the parallel portion is 5 to 40% with respect to the length of the composite yarn. However, for each ratio, 10 composite yarns (20 cm) are extracted from the fabric, each ratio to the composite yarn (20 cm) is calculated, and the average of 10 is calculated.

본 발명의 포백은 상기의 복합사를 포함한다. 이러한 포백에 있어서, 포백의 조직은 한정되지 않고 통상의 방법으로 제편직된 것이면 된다. 예를 들어, 직 조직으로서는, 평직, 사문직, 새틴 직물 등의 삼원 조직, 변화 조직, 변화 사문직 등의 변화 조직, 경이중직, 위이중직 등의 편이중 조직, 경빌로드 등이 예시된다. 또한, 편물로서는, 천축이나, 2장 바디 또는 3장 바디를 사용한, 하프 조직, 하프 베이스 조직, 새틴 조직 등이 예시된다. 특히, 물기 흡수 신속 건조성의 점에서 35 내지 100코스/2.54cm 또한 30 내지 100웨일/2.54cm의 밀도를 갖는 편물이 바람직하다.The fabric of the present invention includes the above composite yarn. In such a fabric, the structure of the fabric is not limited and may be knitted by a conventional method. For example, as a weave organization, a three-way structure such as plain weave, a serpentine weave, and a satin weave, a change organization, a change organization such as a change weave weave, a side-weight structure such as a light double weave and a super double weave, and a light velvet are exemplified. Further, examples of the knitted fabric include a fabric fabric, a half fabric using a two-piece body or a three-piece body, a half base fabric, a satin fabric, and the like. In particular, a knitted fabric having a density of 35 to 100 courses/2.54 cm and 30 to 100 wales/2.54 cm from the viewpoint of water absorption and rapid drying is preferable.

또한, 포백의 단위 면적당 중량으로서는, 70 내지 130g/m2의 범위 내인 것이 바람직하다.In addition, the weight per unit area of the fabric is preferably in the range of 70 to 130 g/m 2 .

이러한 포백에는, 염색 가공, 흡수 가공, 엠보스 가공, 착색 프린트, 발수 가공, 자외선 차폐제, 항균제, 소취제, 방충제, 축광제, 재귀반사제, 마이너스 이온 발생제 등의 기능을 부여하는 각종 가공을 부가 적용해도 된다.These fabrics are subjected to dyeing processing, absorption processing, embossing processing, colored printing, water repellency processing, UV shielding agent, antibacterial agent, deodorant, insect repellent, photoluminescent agent, retroreflecting agent, and various processing that impart functions such as anion generator. may apply.

이렇게 하여 얻어진 포백은 우수한 코튼조 외관, 우수한 질감, 우수한 질감, 항스내깅성, 방투성 및 물기 흡수 신속 건조성을 갖는다. 그 때, JIS L 1058-1995 D3법의 쇠톱에 의해 15시간 테스트하여, 항스내깅성이 3급 이상인 것이 바람직하다.The fabric thus obtained has excellent cotton-like appearance, excellent texture, excellent texture, anti-snagging properties, permeability and quick drying properties for water absorption. In that case, it is tested for 15 hours with the hacksaw of JIS L 1058-1995 D3 method, and it is preferable that anti-snagging property is 3rd grade or more.

이어서, 본 발명의 섬유 제품은, 상기의 포백을 사용하여 이루어지는, 스포츠 웨어, 아우터 웨어, 이너 웨어, 신사 의료, 부인 의료, 개호용 의료, 작업복, 카시트 표피재 및 침구로 이루어지는 군에서 선택되는 어느 하나의 섬유 제품이다.Next, the textile product of the present invention is any selected from the group consisting of sportswear, outerwear, innerwear, menswear, gynecological clothing, nursing care, work clothes, car seat cover material and bedding, which are made using the above fabric. It is a textile product.

이러한 섬유 제품은 상기의 포백을 사용하고 있으므로, 코튼조 외관, 항스내깅성, 방투성 및 물기 흡수 신속 건조성이 우수하다.Since the above fabric is used for these textile products, it is excellent in a cotton-like appearance, anti-snagging properties, permeability and moisture absorption and quick drying properties.

실시예Example

이어서, 실시예를 들어 본 발명을 상세하게 설명하지만, 본 발명이 이들에 의해 한정되는 것은 전혀 아니다.Next, although an Example is given and this invention is demonstrated in detail, this invention is not limited by these at all.

(1) 단위 면적당 중량(1) Weight per unit area

JIS L1096-2010에 의해 직물의 단위 면적당 중량(g/m2)을 측정하였다.The weight per unit area of the fabric (g/m 2 ) was measured according to JIS L1096-2010.

(2) 항스내깅성(2) Anti-snagging properties

JIS L 1058-1995 D3법의 쇠톱에 의해 15시간 테스트하였다.It was tested for 15 hours with the hacksaw of JIS L 1058-1995 D3 method.

(3) 권축률(3) crimp rate

이하의 방법에 의해 권축률을 측정하였다.The crimp rate was measured by the following method.

즉, 공시 필라멘트 사조를, 둘레 길이가 1.125m인 검척기의 둘레에 둘러 감아, 건섬도가 3333dtex인 실패를 조제한다.That is, the test filament thread is wound around the perimeter of the Geomcheokgi having a circumference of 1.125 m to prepare a spool having a dryness of 3333 dtex.

상기 실패를 스케일판의 걸이못에 현수하여, 그 하측 부분에 6g의 초기 하중을 부가하고, 또한 600g의 하중을 부가하였을 때의 실패 길이 L0을 측정한다. 그 후, 즉시 상기 실패로부터 하중을 제거하고, 스케일판의 걸이못으로부터 떼고, 이 실패를 비등수 중에 30분간 침지하여, 권축을 발현시킨다. 비등수 처리 후의 실패를 비등수로부터 취출하고, 실패에 포함되는 수분을 여과지에 의해 흡수 제거하고, 실온에서 24시간 풍건시킨다. 이 풍건된 실패를, 스케일판의 걸이못에 현수하고, 그 하측 부분에, 600g의 하중을 가하여, 1분 후에 실패의 길이 L1a를 측정하고, 그 후 실패로부터 하중을 떼고, 1분 후에 실패의 길이 L2a를 측정한다. 공시 필라멘트 사조의 권축률(CP)을 하기 식에 의해 산출한다.The spool is suspended on the hook nail of the scale plate, an initial load of 6 g is applied to the lower portion thereof, and the spool length L0 when a load of 600 g is applied is measured. Thereafter, the load is immediately removed from the spool, the spool is removed from the nail of the scale plate, and the spool is immersed in boiling water for 30 minutes to develop crimping. The spool after boiling water treatment is taken out from the boiling water, the moisture contained in the spool is absorbed and removed with filter paper, and it is air-dried at room temperature for 24 hours. This air-dried spool is suspended on a hook nail of a scale plate, a load of 600 g is applied to the lower part of the spool, and the length L1a of the spool is measured after 1 minute, and then the load is removed from the spool, and after 1 minute, the length of the spool is removed. Measure the length L2a. The crimp rate (CP) of the test filament yarn is calculated by the following formula.

CP(%)=((L1a-L2a)/L0)×100CP(%)=((L1a-L2a)/L0)×100

(4) 인터레이스도(4) Interlace diagram

교락사를 8.82mN×표시 텍스(0.1g/de)의 하중 하에서 1m의 길이를 취하고, 제중 후, 실온에서 24시 방축 후의 결절점의 수를 판독하고, 개/m로 표시한다.After taking the length of 1 m under the load of 8.82 mN x display text (0.1 g/de), the number of nodal points after de-weighting and shrinking at room temperature for 24 hours is read, and expressed in pieces/m.

(5) 복합사에 있어서의, 비병행부 및 병행부의 비율(5) Ratio of non-parallel parts and parallel parts in composite yarn

포백으로부터 복합사(20cm)를 10개 발출하고, 복합사(20cm)에 대한 각각의 비율을 산출하고, 10개의 평균을 구하였다.Ten composite yarns (20 cm) were extracted from the fabric, the ratio of each of the composite yarns (20 cm) was calculated, and the average of ten was obtained.

(6) 스판조 외관(6) Spanjo exterior

시험자의 육안 판정에 의해 「○」(우수하다.), 「△」(보통이다.), 「×」(열악하다.)의 3단계로 스판조 외관을 평가하였다.According to the tester's visual judgment, "○" (excellent.), "Δ" (normal.), and "x" (poor.) Span-like appearance was evaluated in three stages.

[실시예 1 내지 5, 비교예 1 내지 2][Examples 1 to 5, Comparative Examples 1 to 2]

일본 특허 공개 제2000-234232호 공보의 실시예 1에 기재된 방법에 따라서, 표 1에 나타내는 바와 같은, 방적사와 같은 정도의 굵기 불균일을 갖고 단섬유간에도 랜덤한 굵기 불균일을 갖는, 비권축의 틱앤씬얀을 얻었다. 또한, 실시예 1 내지 5에서는, 표 1에 나타내는 바와 같은 가연 권축 가공사를 통상의 방법에 의해 얻었다. 또한, 표 1 중에서, 「FD」는 케미컬 리사이클된 풀덜 폴리에스테르, 「SD」는 케미컬 리사이클된 세미덜 폴리에스테르, 「CD」는 케미컬 리사이클된 양이온 가염성 폴리에스테르를 나타낸다. 또한, 예를 들어 「44T36」은 총 섬도 44dtex, 필라멘트수 36개를 의미한다.According to the method described in Example 1 of Japanese Patent Application Laid-Open No. 2000-234232, as shown in Table 1, non-crimped tick and thin yarn having the same thickness unevenness as spun yarn and random thickness unevenness even between single fibers got In Examples 1 to 5, false twist crimped yarns as shown in Table 1 were obtained by a conventional method. In addition, in Table 1, "FD" represents chemically recycled full polyester, "SD" represents chemically recycled semi-derived polyester, and "CD" represents chemically recycled cationic dyeable polyester. In addition, for example, "44T36" means a total fineness of 44 dtex, and 36 filaments.

이어서, 실시예 1 내지 5에서는, 틱앤씬얀과 가연 권축 가공사를 병행하여 인터레이스 가공을 실시하고, 틱앤씬얀과 권축사가 교락되거나, 또는 틱앤씬얀이 중심에 위치하고 권축사가 시스에 위치하는 비병행부와, 틱앤씬얀과 권축사가 병행 형상이 된 병행부가 혼재하고 있는 복합사를 얻었다. 이어서, 표 1에 나타내는 바와 같이 환편기를 사용하여 편물을 얻었다.Next, in Examples 1 to 5, interlacing is performed in parallel with the tick and thin yarn and the false twist crimped yarn, and the tick and thin yarn and the crimp yarn are interlaced, or the tick and thin yarn is located in the center and the crimp yarn is located in the sheath. Wow, a composite yarn in which tick and thin yarns and crimp yarns have a parallel shape are mixed. Then, as shown in Table 1, knitted fabrics were obtained using a circular knitting machine.

실시예 1에 있어서, 비병행부 74%, 병행부 26%였다. 실시예 1 내지 5 및 비교예 1 내지 2의 평가 결과를 표 1에 나타낸다.In Example 1, non-parallel parts were 74% and parallel parts were 26%. Table 1 shows the evaluation results of Examples 1 to 5 and Comparative Examples 1 to 2.

Figure pct00001
Figure pct00001

본 발명에 따르면, 코튼조 외관, 질감 및 항스내깅성이 우수하고, 바람직하게는 방투성 및 물기 흡수 신속 건조성도 우수한 복합사 및 포백 및 섬유 제품이 제공되고, 그 공업적 가치는 매우 크다.According to the present invention, there is provided a composite yarn, a fabric, and a fiber product having excellent cotton-like appearance, texture and anti-snagging properties, and preferably excellent permeability and moisture absorption and quick drying properties, and the industrial value thereof is very high.

Claims (17)

틱앤씬얀(thick and thin yarn)과 권축사를 포함하는 것을 특징으로 하는 복합사.A composite yarn comprising a thick and thin yarn and a crimp yarn. 제1항에 있어서, 상기 틱앤씬얀이 비권축사인 복합사.The composite yarn according to claim 1, wherein the tick and thin yarn is a non-crimp yarn. 제1항 또는 제2항에 있어서, 복합사가 상기 틱앤씬얀을 복합사 중량 대비 30 내지 85중량%의 범위 내에서 포함하는 복합사.The composite yarn according to claim 1 or 2, wherein the composite yarn contains the tick and thin yarn within the range of 30 to 85 wt% based on the weight of the composite yarn. 제1항 내지 제3항 중 어느 한 항에 있어서, 복합사에 있어서 교락의 개수 120개/m 이하로 인터레이스 가공이 실시되어 있는 복합사.The composite yarn according to any one of claims 1 to 3, wherein in the composite yarn, interlacing is performed at a number of entanglements of 120 pieces/m or less. 제1항 내지 제4항 중 어느 한 항에 있어서, 복합사에 있어서, 틱앤씬얀과 권축사가 교락되거나, 또는 틱앤씬얀이 중심에 위치하고 권축사가 시스에 위치하는 비병행부와, 틱앤씬얀과 권축사가 병행(Paralleled) 형상이 된 병행부가 혼재하고 있는 복합사. 5. The composite yarn according to any one of claims 1 to 4, wherein in the composite yarn, tick and thin yarns and crimp yarns are intertwined, or non-parallel portions in which tick and thin yarns are centered and the crimp yarns are located in the sheath, tick and thin yarns and Composite yarn in which parallel sections in which the crimp yarns are paralleled are mixed. 제5항에 있어서, 복합사에 있어서, 복합사의 길이에 대하여 비병행부 40 내지 95%인 복합사.The composite yarn according to claim 5, wherein in the composite yarn, the non-parallel portion is 40 to 95% with respect to the length of the composite yarn. 제5항에 있어서, 복합사에 있어서, 복합사의 길이에 대하여 병행 부분 5 내지 40%인 복합사.The composite yarn according to claim 5, wherein in the composite yarn, the parallel portion is 5 to 40% with respect to the length of the composite yarn. 제1항 내지 제7항 중 어느 한 항에 있어서, 상기 틱앤씬얀의 단섬유 섬도가 1.0dtex 이상인 복합사.The composite yarn according to any one of claims 1 to 7, wherein the single fiber fineness of the tick and thin yarn is 1.0 dtex or more. 제1항 내지 제8항 중 어느 한 항에 있어서, 상기 권축사의 단섬유 섬도가 1.5dtex 이하인 복합사.The composite yarn according to any one of claims 1 to 8, wherein the single fiber fineness of the crimped yarn is 1.5 dtex or less. 제1항 내지 제9항 중 어느 한 항에 있어서, 상기 틱앤씬얀 및/또는 권축사가 폴리에스테르 섬유 또는 나일론 섬유를 포함하는 복합사.10. The composite yarn according to any one of claims 1 to 9, wherein the tick and thin yarn and/or the crimp yarn comprises a polyester fiber or a nylon fiber. 제1항 내지 제10항 중 어느 한 항에 있어서, 상기 틱앤씬얀 및/또는 권축사가 케미컬 또는 머티리얼 리사이클된 폴리머를 포함하는 복합사.The composite yarn according to any one of claims 1 to 10, wherein the tick and thin yarn and/or crimp yarn comprises a chemically or material recycled polymer. 제1항 내지 제11항 중 어느 한 항에 있어서, 상기 틱앤씬얀 및/또는 권축사가 양이온 가염성 폴리에스테르를 포함하는 복합사.The composite yarn according to any one of claims 1 to 11, wherein the tick and thin yarn and/or the crimp yarn comprises a cationic dyeable polyester. 제1항 내지 제12항 중 어느 한 항에 있어서, 상기 틱앤씬얀 및/또는 권축사에 있어서, 소광제의 함유율이 0.1질량% 이상인 복합사.The composite yarn according to any one of claims 1 to 12, wherein in the tick and thin yarn and/or the crimped yarn, the content of the matting agent is 0.1% by mass or more. 제1항 내지 제13항 중 어느 한 항에 기재된 복합사를 포함하는 포백.A fabric comprising the composite yarn according to any one of claims 1 to 13. 제14항에 있어서, 포백이 35 내지 100코스/2.54cm 또한 30 내지 100웨일/2.54cm의 밀도를 갖는 편물인 포백.The fabric according to claim 14, wherein the fabric is a knitted fabric having a density of 35 to 100 courses/2.54 cm and 30 to 100 wales/2.54 cm. 제14항 또는 제15항에 있어서, JIS L 1058-1995 D3법의 쇠톱에 의해 15시간 테스트하여, 항스내깅성이 3급 이상인 포백.16. The fabric according to claim 14 or 15, wherein the anti-snagging property is class 3 or higher after testing for 15 hours using a hacksaw in accordance with JIS L 1058-1995 D3 method. 제1항 내지 제16항 중 어느 한 항에 기재된 복합사 또는 포백을 사용하여 이루어지는, 스포츠 웨어, 아우터 웨어, 이너 웨어, 신사 의료, 부인 의료, 개호용 의료, 작업복, 카시트 표피재 및 침구로 이루어지는 군에서 선택되는 어느 하나의 섬유 제품.
The composite yarn or fabric according to any one of claims 1 to 16, comprising sportswear, outerwear, innerwear, menswear, gynecological care, nursing care, work clothes, car seat cover material, and bedding. Any one textile product selected from the group.
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