KR20210134396A - 촉매의 제조 방법, 이로부터 제조된 촉매, 및 에틸렌성 불포화 카르복실산 또는 에스테르의 제조 방법 - Google Patents

촉매의 제조 방법, 이로부터 제조된 촉매, 및 에틸렌성 불포화 카르복실산 또는 에스테르의 제조 방법 Download PDF

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KR20210134396A
KR20210134396A KR1020217032793A KR20217032793A KR20210134396A KR 20210134396 A KR20210134396 A KR 20210134396A KR 1020217032793 A KR1020217032793 A KR 1020217032793A KR 20217032793 A KR20217032793 A KR 20217032793A KR 20210134396 A KR20210134396 A KR 20210134396A
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South Korea
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catalyst
mol
metal
modifier metal
modifier
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Korean (ko)
Inventor
애덤 컬런
와타루 니노미야
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미쓰비시 케미컬 유케이 리미티드
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Publication of KR20210134396A publication Critical patent/KR20210134396A/ko
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • B01J37/0207Pretreatment of the support
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08Silica
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B01J23/04Alkali metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63Pore volume
    • B01J35/633Pore volume less than 0.5 ml/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63Pore volume
    • B01J35/6350.5-1.0 ml/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • B01J37/0209Impregnation involving a reaction between the support and a fluid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/09Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C57/03Monocarboxylic acids
    • C07C57/04Acrylic acid; Methacrylic acid
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/30Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/54Acrylic acid esters; Methacrylic acid esters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J6/00Heat treatments such as Calcining; Fusing ; Pyrolysis
    • B01J6/001Calcining

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1020217032793A 2019-03-13 2020-03-13 촉매의 제조 방법, 이로부터 제조된 촉매, 및 에틸렌성 불포화 카르복실산 또는 에스테르의 제조 방법 Pending KR20210134396A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GBGB1903455.2A GB201903455D0 (en) 2019-03-13 2019-03-13 A process for the protection of a catalyst, a catalyst therefrom and a process for production of ethylenically unsaturated carboxlyic acids or esters
GB1903455.2 2019-03-13
PCT/GB2020/050644 WO2020183193A1 (en) 2019-03-13 2020-03-13 A process for the production of a catalyst, a catalyst therefrom and a process for production of ethylenically unsaturated carboxylic acids or esters

Publications (1)

Publication Number Publication Date
KR20210134396A true KR20210134396A (ko) 2021-11-09

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Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020217032793A Pending KR20210134396A (ko) 2019-03-13 2020-03-13 촉매의 제조 방법, 이로부터 제조된 촉매, 및 에틸렌성 불포화 카르복실산 또는 에스테르의 제조 방법

Country Status (12)

Country Link
US (1) US20220184593A1 (https=)
EP (1) EP3938098A1 (https=)
JP (2) JP7730454B2 (https=)
KR (1) KR20210134396A (https=)
CN (1) CN113573807B (https=)
BR (1) BR112021017250A2 (https=)
CA (1) CA3132622C (https=)
GB (1) GB201903455D0 (https=)
MX (1) MX2021011035A (https=)
SG (1) SG11202109324SA (https=)
TW (1) TW202045253A (https=)
WO (1) WO2020183193A1 (https=)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022255368A1 (ja) 2021-06-01 2022-12-08 三菱ケミカル株式会社 触媒、触媒の製造方法、並びに不飽和カルボン酸及び/又は不飽和カルボン酸エステルの製造方法
CN117065751B (zh) * 2022-05-10 2025-10-31 国家能源投资集团有限责任公司 一种改性费托铁基催化剂
CN116920819A (zh) * 2023-04-04 2023-10-24 郑州大学 一种用于合成丙烯酸甲酯或甲基丙烯酸甲酯的高稳定性催化剂及其制备方法和应用

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4357451A (en) 1980-05-21 1982-11-02 Phillips Petroleum Company Chemical dehydroxylation of silica
US4308172A (en) 1980-05-21 1981-12-29 Phillips Petroleum Company Chemical dehydroxylation of silica
US5583085A (en) 1994-06-13 1996-12-10 W. R. Grace & Co.-Conn. Preparation of dehydroxylated supports
EP0775164B1 (en) * 1994-08-03 2001-11-07 ExxonMobil Chemical Patents Inc. Supported ionic catalyst composition
GB9807498D0 (en) 1998-04-08 1998-06-10 Ici Plc Production of unsaturated acids therfore and catalysts therfor
US6887822B2 (en) 2001-09-25 2005-05-03 Pq Corporation Method for making silica supported, crush-resistant catalysts
EP2173485A1 (en) * 2007-07-05 2010-04-14 Grace GmbH & Co. KG Method for making inorganic oxide supported catalysts
GB201011092D0 (en) * 2010-07-01 2010-08-18 Lucite Int Uk Ltd A catalyst system and a process for the production of ethylenically unsaturated carboxylic acids or esters
WO2013184345A1 (en) * 2012-06-04 2013-12-12 Rohm And Haas Company Process for production of methacrylic acid esters
FR2997397B1 (fr) * 2012-10-29 2014-11-07 Arkema France Procede de synthese directe d'aldehydes insatures a partir de melanges d'alcools
FR3019545B1 (fr) * 2014-04-04 2016-03-11 Arkema France Procede de synthese directe de (meth)acroleine a partir d'ethers et/ou acetals
CN108855238A (zh) * 2017-05-15 2018-11-23 中国石油化工股份有限公司 多孔氧化铝载体及其制备方法与银催化剂及应用
GB201714756D0 (en) * 2017-09-13 2017-10-25 Lucite Int Uk Ltd A catalyst and a process for the production of ethylenicallly unsaturated carboxylic acids or esters

Also Published As

Publication number Publication date
JP2022526236A (ja) 2022-05-24
GB201903455D0 (en) 2019-04-24
WO2020183193A1 (en) 2020-09-17
CN113573807B (zh) 2025-07-25
CA3132622A1 (en) 2020-09-17
CN113573807A (zh) 2021-10-29
EP3938098A1 (en) 2022-01-19
CA3132622C (en) 2024-05-14
US20220184593A1 (en) 2022-06-16
JP7730454B2 (ja) 2025-08-28
JP2025116211A (ja) 2025-08-07
TW202045253A (zh) 2020-12-16
SG11202109324SA (en) 2021-09-29
MX2021011035A (es) 2021-10-13
BR112021017250A2 (pt) 2021-11-09

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