CA3132622C - A process for the production of a catalyst, a catalyst therefrom and a process for production of ethylenically unsaturated carboxylic acids or esters - Google Patents

A process for the production of a catalyst, a catalyst therefrom and a process for production of ethylenically unsaturated carboxylic acids or esters Download PDF

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Publication number
CA3132622C
CA3132622C CA3132622A CA3132622A CA3132622C CA 3132622 C CA3132622 C CA 3132622C CA 3132622 A CA3132622 A CA 3132622A CA 3132622 A CA3132622 A CA 3132622A CA 3132622 C CA3132622 C CA 3132622C
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Canada
Prior art keywords
catalyst
metal
modifier metal
intermediate according
mol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CA3132622A
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English (en)
French (fr)
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CA3132622A1 (en
Inventor
Adam CULLEN
Wataru Ninomiya
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Chemical UK Ltd
Original Assignee
Mitsubishi Chemical UK Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Chemical UK Ltd filed Critical Mitsubishi Chemical UK Ltd
Publication of CA3132622A1 publication Critical patent/CA3132622A1/en
Application granted granted Critical
Publication of CA3132622C publication Critical patent/CA3132622C/en
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0207—Pretreatment of the support
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B01J23/04—Alkali metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0209—Impregnation involving a reaction between the support and a fluid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C57/03—Monocarboxylic acids
    • C07C57/04—Acrylic acid; Methacrylic acid
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/54—Acrylic acid esters; Methacrylic acid esters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J6/00—Heat treatments such as Calcining; Fusing ; Pyrolysis
    • B01J6/001—Calcining

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CA3132622A 2019-03-13 2020-03-13 A process for the production of a catalyst, a catalyst therefrom and a process for production of ethylenically unsaturated carboxylic acids or esters Active CA3132622C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GBGB1903455.2A GB201903455D0 (en) 2019-03-13 2019-03-13 A process for the protection of a catalyst, a catalyst therefrom and a process for production of ethylenically unsaturated carboxlyic acids or esters
GB1903455.2 2019-03-13
PCT/GB2020/050644 WO2020183193A1 (en) 2019-03-13 2020-03-13 A process for the production of a catalyst, a catalyst therefrom and a process for production of ethylenically unsaturated carboxylic acids or esters

Publications (2)

Publication Number Publication Date
CA3132622A1 CA3132622A1 (en) 2020-09-17
CA3132622C true CA3132622C (en) 2024-05-14

Family

ID=66380370

Family Applications (1)

Application Number Title Priority Date Filing Date
CA3132622A Active CA3132622C (en) 2019-03-13 2020-03-13 A process for the production of a catalyst, a catalyst therefrom and a process for production of ethylenically unsaturated carboxylic acids or esters

Country Status (12)

Country Link
US (1) US20220184593A1 (https=)
EP (1) EP3938098A1 (https=)
JP (2) JP7730454B2 (https=)
KR (1) KR20210134396A (https=)
CN (1) CN113573807B (https=)
BR (1) BR112021017250A2 (https=)
CA (1) CA3132622C (https=)
GB (1) GB201903455D0 (https=)
MX (1) MX2021011035A (https=)
SG (1) SG11202109324SA (https=)
TW (1) TW202045253A (https=)
WO (1) WO2020183193A1 (https=)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022255368A1 (ja) 2021-06-01 2022-12-08 三菱ケミカル株式会社 触媒、触媒の製造方法、並びに不飽和カルボン酸及び／又は不飽和カルボン酸エステルの製造方法
CN117065751B (zh) * 2022-05-10 2025-10-31 国家能源投资集团有限责任公司 一种改性费托铁基催化剂
CN116920819A (zh) * 2023-04-04 2023-10-24 郑州大学 一种用于合成丙烯酸甲酯或甲基丙烯酸甲酯的高稳定性催化剂及其制备方法和应用

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4357451A (en) 1980-05-21 1982-11-02 Phillips Petroleum Company Chemical dehydroxylation of silica
US4308172A (en) 1980-05-21 1981-12-29 Phillips Petroleum Company Chemical dehydroxylation of silica
US5583085A (en) 1994-06-13 1996-12-10 W. R. Grace & Co.-Conn. Preparation of dehydroxylated supports
EP0775164B1 (en) * 1994-08-03 2001-11-07 ExxonMobil Chemical Patents Inc. Supported ionic catalyst composition
GB9807498D0 (en) 1998-04-08 1998-06-10 Ici Plc Production of unsaturated acids therfore and catalysts therfor
US6887822B2 (en) 2001-09-25 2005-05-03 Pq Corporation Method for making silica supported, crush-resistant catalysts
EP2173485A1 (en) * 2007-07-05 2010-04-14 Grace GmbH & Co. KG Method for making inorganic oxide supported catalysts
GB201011092D0 (en) * 2010-07-01 2010-08-18 Lucite Int Uk Ltd A catalyst system and a process for the production of ethylenically unsaturated carboxylic acids or esters
WO2013184345A1 (en) * 2012-06-04 2013-12-12 Rohm And Haas Company Process for production of methacrylic acid esters
FR2997397B1 (fr) * 2012-10-29 2014-11-07 Arkema France Procede de synthese directe d'aldehydes insatures a partir de melanges d'alcools
FR3019545B1 (fr) * 2014-04-04 2016-03-11 Arkema France Procede de synthese directe de (meth)acroleine a partir d'ethers et/ou acetals
CN108855238A (zh) * 2017-05-15 2018-11-23 中国石油化工股份有限公司 多孔氧化铝载体及其制备方法与银催化剂及应用
GB201714756D0 (en) * 2017-09-13 2017-10-25 Lucite Int Uk Ltd A catalyst and a process for the production of ethylenicallly unsaturated carboxylic acids or esters

Also Published As

Publication number Publication date
KR20210134396A (ko) 2021-11-09
JP2022526236A (ja) 2022-05-24
GB201903455D0 (en) 2019-04-24
WO2020183193A1 (en) 2020-09-17
CN113573807B (zh) 2025-07-25
CA3132622A1 (en) 2020-09-17
CN113573807A (zh) 2021-10-29
EP3938098A1 (en) 2022-01-19
US20220184593A1 (en) 2022-06-16
JP7730454B2 (ja) 2025-08-28
JP2025116211A (ja) 2025-08-07
TW202045253A (zh) 2020-12-16
SG11202109324SA (en) 2021-09-29
MX2021011035A (es) 2021-10-13
BR112021017250A2 (pt) 2021-11-09

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