KR20200033248A - Hair enhancer - Google Patents
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- KR20200033248A KR20200033248A KR1020207000058A KR20207000058A KR20200033248A KR 20200033248 A KR20200033248 A KR 20200033248A KR 1020207000058 A KR1020207000058 A KR 1020207000058A KR 20207000058 A KR20207000058 A KR 20207000058A KR 20200033248 A KR20200033248 A KR 20200033248A
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- 239000003623 enhancer Substances 0.000 title description 3
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Images
Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
Abstract
본 발명은 모발 자체의 강도를 향상시킬 수 있는 모발강화제를 제공하는 것을 목적으로 한다. 본 발명은 글리옥실산으로 이루어지는 모발강화제, 상기 모발강화제를 포함하는 모발강화제 조성물, 및 (1) 상기 모발강화제 또는 상기 모발강화제 조성물을 모발에 도포하고, (2) 도포한 상태에서 모발을 방치하고, (3) 모발을 수세하고, (4) 모발을 건조시키는 공정을 포함하고, 임의로 (5) 헤어스타일링용 아이론으로 모발을 처리하는 공정을 더 포함해도 좋은 모발강화 처리 방법에 관한 것이다. 상기 조성물의 pH는 1.0∼3.0의 범위 내인 것이 바람직하다.An object of the present invention is to provide a hair strengthening agent capable of improving the strength of the hair itself. The present invention is a hair strengthening agent composed of glyoxylic acid, a hair strengthening agent composition comprising the hair strengthening agent, and (1) the hair strengthening agent or the hair strengthening agent composition is applied to the hair, and (2) the hair is left in the coated state. , (3) washing the hair, and (4) drying the hair, and optionally (5) hair styling. It is preferable that the pH of the composition is in the range of 1.0 to 3.0.
Description
본 발명은 모발강화제에 관한 것이다. 보다 상세하게는, 모발을 피막 등으로 피복하는 것이 아니라, 모발 자체를 강화할 수 있는 모발강화제에 관한 것이다. 또한 본 발명은 상기 모발강화제를 사용한 모발강화제 조성물 및 모발강화 처리 방법에도 관한 것이다.The present invention relates to a hair strengthening agent. More specifically, it does not coat the hair with a film or the like, but relates to a hair strengthening agent capable of strengthening the hair itself. In addition, the present invention also relates to a hair strengthening agent composition and a hair strengthening treatment method using the hair strengthening agent.
모발은 주성분인 케라틴의 폴리펩티드쇄가 여러가지 측쇄 결합으로 연결되면서 망목 구조를 취하고 있다(도 1 참조). 평상시는 α-헬릭스 구조(나선 형상)를 취하고 있는 모발 케라틴의 폴리펩티드 주쇄는, 잡아당겨짐으로써 β-케라틴(지그재그 형상)으로 변형함으로써 모발이 신장한다고 생각되고 있다. 건강한 모발에서는, 인장응력을 제거하면 원래의 길이로 회복하지만, 퍼머넌트 웨이브 처리나 브리칭(breaching) 등의 화학 처리나 자외선 등의 외적 자극에 의해 손상된 모발에서는 강도가 낮아 끊어지기 쉬운 경향이 있었다.The hair has a network structure in which the polypeptide chain of the main component keratin is linked by various side chain bonds (see FIG. 1). Normally, it is thought that the polypeptide main chain of hair keratin having an α-helix structure (helical shape) is stretched by being deformed into β-keratin (zigzag) by pulling. In healthy hair, when the tensile stress is removed, it recovers to its original length, but in hair damaged by external stimulation such as permanent wave treatment, chemical treatment such as broaching, or ultraviolet rays, there is a tendency to be easily broken.
종래부터, 손상된 모발을 수복하기 위해서, 케라틴 가수분해물 등의 단백질 유도체를 적용하는 것이 알려져 있다. 그러나, 케라틴 가수분해물 등은 모발 표면의 큐티클의 변형(박리) 등을 수복하는 효과는 갖지만, 모발 강도를 향상시키는 효과는 없었다.Conventionally, in order to repair damaged hair, it is known to apply protein derivatives such as keratin hydrolysates. However, the keratin hydrolyzate or the like has an effect of repairing deformation (peeling) of the cuticle on the surface of the hair, but has no effect of improving the hair strength.
특허문헌 1에는, 양이온화 단백 유도체 및 중성 아미노산으로 이루어지는 모발 수복 조성물 및, 상기 조성물에 피막 형성 고분자 화합물을 함유하는 모발강화제가 개시되어 있다. 특허문헌 2에는, 완충액인 A제와, D,L-피롤리돈카르복실산, 아미노산, 및 글루타티온으로부터 선택되는 적어도 1종과 히드록시프로필셀룰로오스를 함유하는 수용액인 B제로 이루어지는 2액의 모발강화제가 개시되고, 상기 A제와 B제가 모발 상에서 물에 불용성인 검 형상 물질을 형성해서 모발을 강화한다고 기재되어 있다. 즉, 이들 종래 기술은 모발 표면을 고분자 피막이나 검 형상 물질로 덮음으로써 모발 강도를 향상시키는 기술이다.
한편, 글리옥실산은 곱슬머리의 억제나 축모의 교정을 위한 모발 처리제에 있어서 사용되고 있고, 예를 들면 특허문헌 3에는, 글리옥실산을 포함하는 수용액을 모발에 도포해서 방치하고, 헤어 드라이어로 모발을 건조시킨 후, 약200℃의 고온에서 모발 교정 아이론을 이용하여 모발을 교정하는 방법이 개시되어 있다. 또한, 특허문헌 4에는, 글리옥실산에 추가해서 구아니딘염 및/또는 요소를 함유하는 모발 처리제가 개시되어, 뛰어난 모발 신장(곱슬 억제) 효과를 갖는 것이 기재되어 있다. 그러나, 글리옥실산의 모발 강도를 향상시키는 기능에 대해서는 전혀 알려져 있지 않았다.On the other hand, glyoxylic acid is used in hair treatment agents for the inhibition of curly hair or correction of hair shafts. For example, in Patent Document 3, an aqueous solution containing glyoxylic acid is applied to the hair and left to stand, and the hair is dried with a hair dryer. After drying, a method of straightening hair using a hair straightening iron at a high temperature of about 200 ° C is disclosed. In addition, Patent Document 4 discloses a hair treatment agent containing guanidine salt and / or urea in addition to glyoxylic acid, and has excellent hair elongation (curls suppression) effect. However, no function is known about the ability to improve hair strength of glyoxylic acid.
본 발명은 상기 종래 기술을 감안하여 이루어진 것으로서, 모발 자체의 강도를 향상시킬 수 있는 모발강화제를 제공하는 것을 목적으로 한다.The present invention has been made in view of the above prior art, and aims to provide a hair strengthening agent capable of improving the strength of the hair itself.
본 발명자들은 상기 과제를 해결하기 위해 예의 연구를 거듭한 결과, 종래는 모발 신장(축모 교정)에 사용되고 있던 글리옥실산이, 모발 자체의 강도를 향상시키는 기능을 갖는 것을 처음으로 발견하여 본 발명을 완성하기에 이르렀다.As a result of repeated studies of the inventors in order to solve the above problems, the present inventors first discovered that glyoxylic acid, which was conventionally used for hair extension (scalp correction), has a function of improving the strength of the hair itself, and completed the present invention. I came to Hagi.
즉, 본 발명은 글리옥실산으로 이루어지는 모발강화제, 상기 모발강화제를 포함하는 모발강화제 조성물, 및 상기 모발강화제를 사용한 모발강화 처리 방법을 제공한다.That is, the present invention provides a hair strengthening agent composed of glyoxylic acid, a hair strengthening agent composition comprising the hair strengthening agent, and a hair strengthening treatment method using the hair strengthening agent.
본 발명에 따른 모발강화제는 모발 등의 케라틴 섬유를 구성하는 폴리펩티드쇄의 사이에 새로운 결합을 형성함으로써 케라틴 섬유의 강도를 향상시킬 수 있다. The hair strengthening agent according to the present invention can improve the strength of keratin fibers by forming new bonds between polypeptide chains constituting keratin fibers such as hair.
본 발명에 있어서의 「모발강화」 또는 「모발의 강도 향상」이란, 모발 자체의 강도를 향상시키는 것을 의미하지만, 손상된 모발을 강화하는 것은 손상된 모발을 보수하는 것도 포함하고, 그 결과로서 모발에 「텐션」이나 「탄력」을 부여하게 된다. 따라서, 본 발명에 있어서의 「모발강화」는 「모발의 보수」 및 「모발에의 텐션, 탄력 부여」도 포함하는 것으로 해석한다. 한편, 상기 특허문헌 3 및 4에 개시되어 있는 「축모 교정」은 모발에 데미지를 주는 것으로 인식되고 있다. 따라서, 축모 교정에 유효한 물질이 모발강화 작용을 갖는 것은 당업자에게는 예측할 수 없는 놀랄만한 효과이다.The term "hair strengthening" or "increasing hair strength" in the present invention means improving the strength of the hair itself, but strengthening the damaged hair includes repairing the damaged hair, and as a result, the hair Tension ”or“ Elasticity ”. Therefore, it is interpreted that the term "hair strengthening" in the present invention also includes "hair repair" and "tension to hair and imparting elasticity". On the other hand, "pattern correction" disclosed in Patent Documents 3 and 4 is recognized as damaging the hair. Therefore, it is a surprising effect unpredictable to a person skilled in the art that a substance effective for correcting hair growth has a hair strengthening effect.
도 1은 모발 내에 존재하는 결합의 종류를 예시하는 모식도이다.(출전: 「신화장품학」 제2판, 미츠이 타케오편, 난잔도, 2001년, 제66쪽)
도 2는 실시예 1/비교예 1의 조성물로 처리한 모발의 강도 측정 결과를 나타내는 그래프이다.
도 3은 실시예 2/비교예 2의 조성물로 처리한 모발의 강도 측정 결과를 나타내는 그래프이다.Fig. 1 is a schematic diagram illustrating the types of bonds present in the hair.
2 is a graph showing the results of measuring the strength of hair treated with the composition of Example 1 / Comparative Example 1.
3 is a graph showing the results of measuring the strength of hair treated with the composition of Example 2 / Comparative Example 2.
본 발명의 모발강화제는 글리옥실산으로 이루어진다. 글리옥실산은 하기 식 (I)로 나타내어지는 구조를 갖는 화합물이다.The hair strengthening agent of the present invention consists of glyoxylic acid. Glyoxylic acid is a compound having a structure represented by the following formula (I).
도 1에 모식적으로 나타내는 바와 같이, 모발 내에는 여러가지 측쇄 결합이 존재하고, 이들 결합을 통해서 케라틴의 폴리펩티드쇄가 연결됨으로써 모발의 구조가 유지되어 있다. 도 1의 (염 결합)은, 리신이나 아르기닌 잔기 등의 (+)에 하전(荷電)한 암모늄 이온과 아스파르트산 잔기 등의 (-)에 하전한 카르복실레이트 이온의 상호의 정전적 결합을 나타내고, (펩티드 결합)은 글루탐산 등의 -COOH기와 리신 잔기 등의 -NH2기의 탈수 결합(-CONH-)을 나타내고, (시스틴 결합)은 황(S)을 포함하는 단백질에 특유한 결합이며, 다른 섬유에는 보여지지 않는 디술피드 결합을 나타내고, (수소 결합)은 아미드기와 그것에 근접하는 카르복실기의 결합이다(「신화장품학」 제2판, 미츠이 타케오편, 난잔도, 2001년, 제66∼67쪽 참조).As schematically shown in Fig. 1, various side chain bonds exist in the hair, and the keratin polypeptide chain is connected through these bonds, thereby maintaining the structure of the hair. FIG. 1 (salt bond) represents electrostatic bonding between ammonium ions charged to (+) such as lysine and arginine residues and carboxylate ions charged to (-) such as aspartic acid residues. , (Peptide bond) represents the dehydration bond (-CONH-) of a -NH2 group such as a lysine residue and a -COOH group such as glutamic acid, and (cystine bond) is a bond unique to proteins containing sulfur (S), and other fibers Represents a disulfide bond not shown in (Hydrogen bond), which is a bond between an amide group and a carboxyl group adjacent thereto (2nd edition of `` Mythology '', Mitsui Takeo, Nanzando, 2001, pp. 66-67) .
예를 들면, 퍼머넌트 웨이브를 형성할 때는 상기 측쇄결합 중에서의 디술피드 결합(시스틴 결합)을 환원제에 의해 절단하고, 웨이브 형성한 상태에서 산화제 를 이용하여 새로운 디술피드 결합을 형성한다. 그러나, 한번 절단된 디술피드 결합의 전부가 재결합하지 않아 모발 내의 측쇄결합의 총 수가 감소하기 때문에, 모발의 강도가 저하한다고 생각된다. 또한, 모발에 대하여 산화 염색이나 브리칭 등의 화학 처리를 행했을 경우나, 자외선 등의 외적 자극에 의해서도 측쇄결합의 일부가 절단되어, 모발의 강도 저하가 생기고 있다고도 생각된다.For example, when forming a permanent wave, a disulfide bond (cystine bond) in the side chain bond is cut by a reducing agent, and a new disulfide bond is formed using an oxidizing agent in the wave-formed state. However, since the total number of side chain bonds in the hair decreases because all of the disulfide bonds once cut do not recombine, it is considered that the strength of the hair decreases. In addition, it is considered that when the hair is subjected to chemical treatment such as oxidation dyeing or bridging, or part of the side chain bonds are also cut by external stimuli such as ultraviolet rays, resulting in a decrease in the strength of the hair.
본 발명자들은 모발을 글리옥실산으로 처리함으로써 케라틴의 폴리펩티드쇄간에 카르복시메틸렌기를 개재한 새로운 결합을 발생시켜서 모발 강도를 향상시킬 수 있는 것을 처음으로 찾아냈다. 이 새로운 결합은 케라틴의 폴리펩티드쇄를 구성하는 리신(Lys) 잔기, 티로신(Tyr) 잔기, 및 아르기닌(Arg) 잔기로부터 선택되는 아미노산 잔기간(즉, Lys-Lys간, Lys-Arg간, Lys-Tyr간, Tys-Tyr간, Atg-Tyr간, 또는 Arg-Arg간)에 형성되는 가교결합이라고 추측된다.The present inventors have found for the first time that the hair strength can be improved by generating a new bond through a carboxymethylene group between keratin polypeptide chains by treating the hair with glyoxylic acid. This new bond is between amino acid residues selected from lysine (Lys) residues, tyrosine (Tyr) residues, and arginine (Arg) residues constituting the polypeptide chain of keratin (i.e., between Lys-Lys, between Lys-Args, Lys- It is presumed to be a crosslink formed between Tyr, Tys-Tyr, Atg-Tyr, or Arg-Arg).
본 발명은 상기 모발강화제(즉, 글리옥실산)를 함유하는 모발강화제 조성물에도 관한 것이다.The present invention also relates to a hair strengthening agent composition containing the hair strengthening agent (ie, glyoxylic acid).
본 발명의 모발강화제 조성물은 수성 매체 중에 글리옥실산을 함유하는 형태 로 하는 것이 바람직하다. 수성 매체란 물, 또는 물과 수용성 또는 친수성의 매체(예를 들면, 탄소수 3 이하의 저급 알코올 등)의 혼합물이다. It is preferable that the hair strengthening composition of the present invention is in a form containing glyoxylic acid in an aqueous medium. The aqueous medium is water or a mixture of water and a water-soluble or hydrophilic medium (for example, lower alcohol having 3 or less carbon atoms).
본 발명의 모발강화제 조성물에 있어서의 글리옥실산의 배합량은, 특별하게 한정되지 않지만, 바람직하게는 조성물 전체에 대하여 1∼30질량%, 보다 바람직하게는 3∼20질량%. 더 바람직하게는 5∼15질량%이다. 배합량이 1질량% 미만이면 모발의 강도 향상 효과이 얻어지기 어렵고, 30질량%를 초과해서 배합해도 효과의 더나은 향상은 없으며, 조성물의 산성이 지나치게 강해지므로 바람직하지 못하다.The blending amount of glyoxylic acid in the hair strengthening agent composition of the present invention is not particularly limited, but is preferably 1 to 30% by mass, more preferably 3 to 20% by mass relative to the total composition. More preferably, it is 5-15 mass%. If the blending amount is less than 1% by mass, the effect of improving the strength of the hair is difficult to obtain, and even if the blending amount exceeds 30% by mass, there is no further improvement in the effect, and the acidity of the composition becomes too strong, which is not preferable.
본 발명의 모발강화제 조성물은, 그 pH를 3 이하, 바람직하게는 2.5 이하, 보다 바람직하게는 2 이하로 조제하는 것이 바람직하다. 조성물 pH값의 하한값은 특별하게 한정되지 않지만, 통상은 1.0 이상으로 조제된다. 조성물의 pH는 글리옥실산의 산성을 중화함으로써 적당하게 조정할 수 있다. 중화제(pH 조정제)로서는, 수산화나트륨이나 수산화칼륨 등의 무기염기, 트리에탄올아민이나 이소프로판올아민, 염기성 아미노산 등의 유기염기를 들 수 있지만, 이것들에 한정되지 않는다.It is preferable to prepare the hair strengthening agent composition of the present invention at a pH of 3 or less, preferably 2.5 or less, and more preferably 2 or less. Although the lower limit of the composition pH value is not particularly limited, it is usually prepared at 1.0 or higher. The pH of the composition can be appropriately adjusted by neutralizing the acidity of glyoxylic acid. Examples of the neutralizing agent (pH regulator) include inorganic bases such as sodium hydroxide and potassium hydroxide, and organic bases such as triethanolamine, isopropanolamine, and basic amino acids, but are not limited to these.
본 발명의 모발강화제 조성물은 글리옥실산 및 임의의 중화제에 추가해서, 모발 처리용의 화장품이나 의약품 등에 통상 사용되는 다른 임의 성분을, 본 발명의 효과를 손상하지 않는 범위 내에서 첨가할 수 있다. 이러한 임의 성분으로서는, 예를 들면 양이온성 고분자, 아미노산, 펩티드, 단백질, 금속 이온 봉쇄제, 유분, 분말 성분, 계면활성제, 증점제, 분말 성분, 향료, 분말 성분, 색소 등을 함유할 수 있다.In addition to glyoxylic acid and an optional neutralizing agent, the hair strengthening agent composition of the present invention can be added within the range that does not impair the effects of the present invention, other optional ingredients commonly used in cosmetics or pharmaceuticals for hair treatment. Examples of such optional components may include cationic polymers, amino acids, peptides, proteins, metal ion blockers, oils, powder components, surfactants, thickeners, powder components, fragrances, powder components, and pigments.
본 발명에 따른 모발강화제 조성물의 제형은, 소망의 효과가 충분히 발휘되는 것이라면 특별하게 한정되지 않지만, 예를 들면 액상, 유액상, 겔상, 폼상, 크림상 등의 제형을 채택할 수 있다.The formulation of the hair strengthening agent composition according to the present invention is not particularly limited as long as the desired effect is sufficiently exhibited, but, for example, formulations such as liquid, latex, gel, foam, and cream may be adopted.
본 발명은 상기 모발강화제 조성물을 사용한 모발강화 처리 방법도 제공한다. 본 발명의 모발강화 처리 방법은, (1) 상기 모발강화제 또는 모발강화제 조성물을 모발에 도포하고, (2) 도포한 상태에서 모발을 방치하고, (3) 모발을 수세하고, (4) 모발을 건조시켜, (5) 임의으로 헤어스타일링용 아이론으로 모발을 처리하는 공정을 포함한다.The present invention also provides a method for treating hair strengthening using the composition for strengthening hair. The hair strengthening treatment method of the present invention comprises: (1) applying the above-mentioned hair-enhancing agent or hair-enhancing composition to the hair, (2) leaving the hair in the applied state, (3) washing the hair, and (4) washing the hair. Drying, (5) optionally includes a step of treating hair with an iron for hair styling.
(1) 도포 공정(1) Application process
본 발명의 모발강화제 조성물은 샴푸 전의 건조 모발에 적용하는 것도 가능하지만, 모발강화제(글리옥실산)가 모발에 침투하기 쉽기 때문에 샴푸로 미리 세정해 수분을 제거한 웨트 케어나, 부착된 수분을 타올로 제거한 타올 건조 헤어에 적용하는 것이 바람직하다.The hair strengthening composition of the present invention can also be applied to dry hair before shampooing, but since the hair strengthening agent (glyoxylic acid) is easily permeated into the hair, wet care removes moisture by washing with shampoo in advance, or attached moisture with a towel. It is preferred to apply the removed towel to dry hair.
(2) 방치 공정(2) neglect process
모발강화제 조성물의 도포 후, 실온(약 25℃)에서 10∼30분간, 보다 바람직하게는 15∼20분간 방치하여 모발강화제를 모발에 작용시킨다. 방치 시간이 10분간 미만에서는 모발을 충분하게 강화할 수 없고, 한편, 방치 시간이 30분간을 초과해도 방치 시간에 알맞은 모발강화 효과의 더나은 향상은 기대할 수 없다.After application of the hair enhancer composition, the hair enhancer is allowed to act on the hair by standing at room temperature (about 25 ° C) for 10 to 30 minutes, more preferably 15 to 20 minutes. When the standing time is less than 10 minutes, the hair cannot be sufficiently strengthened. On the other hand, even if the standing time exceeds 30 minutes, a further improvement in the hair strengthening effect suitable for the standing time cannot be expected.
(3) 수세 공정(3) Water washing process
모발을 물 또는 미지근한 물로 헹구고, 모발강화제 조성물을 모발로부터 씻어낸다. 모발로부터 모발강화제 조성물을 씻어냄으로써, 그 후의 모발의 건조나, 취급이 용이해진다.The hair is rinsed with water or lukewarm water, and the hair strengthening composition is washed off the hair. By washing the hair strengthening composition from the hair, drying and handling of the subsequent hair become easy.
(4) 건조 공정(4) Drying process
수세 후, 수분을 타올로 닦아낸 후에, 헤어 드라이어로 건조시킨다.After washing, the moisture is wiped off with a towel, and then dried with a hair dryer.
(5) 아이론 공정(임의)(5) Iron process (random)
상기 (4)에서 건조시킨 모발은 이미 강도가 향상되어 있지만, 임의로 140∼200℃, 바람직하게는 약 180℃로 가열한 헤어스타일링용 아이론으로 모발에 기계력 및 열을 가하면서 모발을 펴는 공정을 실시해도 좋다.The hair dried in the above (4) has already improved strength, but optionally, a hair styling iron heated to 140 to 200 ° C, preferably about 180 ° C, is subjected to a process of straightening the hair while applying mechanical force and heat to the hair. It is also good.
본 발명에 따른 모발강화 처리 방법에 의하면, 글리옥실산의 작용에 의해서 케라틴을 구성하는 폴리펩티드쇄의 리신, 티로신, 및 아르기닌 잔기간에 가교결합이 새롭게 형성되어, 모발의 강도가 격단적으로 향상된다.According to the hair strengthening treatment method according to the present invention, crosslinking is newly formed between the lysine, tyrosine, and arginine residues of the polypeptide chain constituting keratin by the action of glyoxylic acid, thereby dramatically improving the strength of the hair.
(실시예)(Example)
이하에 구체예를 들어서 본 발명을 더욱 상세하게 설명하지만, 본 발명은 이하의 실시예에 한정되는 것은 아니다. 또한, 이하의 실시예 등에 있어서의 배합량은 특별히 언급하지 않는 한 질량%를 나타낸다.The present invention will be described in more detail with reference to specific examples below, but the present invention is not limited to the following examples. In addition, the compounding quantity in the following Examples etc. shows mass% unless there is particular notice.
하기의 표 1에 예시한 조성을 갖는 모발 처리용 조성물을 조제했다. 실시예 1은 본 발명에 따른 모발강화제 조성물이며, 비교예 1은 범용되고 있는 퍼머넌트 처리제(환원제) 조성물이다.A composition for treating hair having a composition exemplified in Table 1 below was prepared. Example 1 is a hair strengthening composition according to the present invention, and Comparative Example 1 is a general-purpose permanent treatment agent (reducing agent) composition.
건강한 모발의 다발(동량)에, 실시예 1 및 비교예 1의 조성물을 도포하고, 15분간 방치한 후, 수세하여, 드라이어로 건조시켰다. 이어서, 180℃로 설정한 헤어스타일링용 아이론을 이용하여 스루법으로 3회 아이론 처리를 행하였다. The composition of Example 1 and Comparative Example 1 was applied to a bundle (equal amount) of healthy hair, left to stand for 15 minutes, washed with water, and dried with a dryer. Subsequently, the iron for hair styling set at 180 ° C was used to perform the iron treatment three times through the through method.
상기 처리 사이클을 1회 또는 3회 실시했다.The treatment cycle was carried out once or three times.
상기 처리를 실시한 모발 다발의 일단을 고정해서 수직 방향으로 인장응력을 부가했을 때의, 모발의 신장률(가로축)과 응력(세로축)의 관계를 도 2의 그래프에 나타낸다. 또한, 모발의 길이가 3% 늘어나는데 요한 응력값, 모발이 파단했을 때의 응력값을 이하의 표 2에 나타낸다.The relationship between the elongation rate (horizontal axis) and the stress (vertical axis) of the hair when the end of the hair bundle subjected to the above treatment is fixed and tensile stress is applied in the vertical direction is shown in the graph of FIG. 2. In addition, the stress value required for the length of the hair to increase by 3% and the stress value when the hair breaks are shown in Table 2 below.
도 2 및 표 2에 나타낸 결과로부터 분명하게 나타나 있는 바와 같이, 퍼머넌트 웨이브 처리에서 사용되는 환원제인 티오글리콜산을 배합한 비교예 1의 조성물 로 처리한 모발은, 미처리의 모발에 비해서 강도가 저하되어 있고, 처리 사이클수를 3회로 했을 경우에는 더욱 강도 저하했다. 이것에 대하여, 글리옥실산을 포함하는 실시예 1의 조성물로 처리하면, 미처리의 모발에 비교해서 분명하게 강도가 향상되어 있고, 처리 사이클수를 3회로 하면 더욱 강화된 것을 알 수 있다.As is evident from the results shown in Fig. 2 and Table 2, the hair treated with the composition of Comparative Example 1 in which thioglycolic acid, a reducing agent used in the permanent wave treatment, is blended, has lower strength compared to untreated hair. When the number of treatment cycles was three, the strength was further reduced. On the other hand, when it was treated with the composition of Example 1 containing glyoxylic acid, it was found that the strength was clearly improved compared to the untreated hair, and it was found that the number of treatment cycles was increased to 3 times.
다음에, 하기의 표 3에 예시한 조성을 갖는 모발 처리용 조성물을 조제했다. 실시예 2는 본 발명에 따른 모발강화제 조성물이며, 비교예 2는 종래부터 손상 헤어의 보수에 사용되고 있는 가수분해 단백질을 배합한 처리제 조성물이다.Next, a composition for treating hair having a composition illustrated in Table 3 below was prepared. Example 2 is a hair strengthening composition according to the present invention, and Comparative Example 2 is a treatment composition containing a hydrolysis protein conventionally used for repair of damaged hair.
건강한 모발의 다발을, 브리칭제(PRIMIENCE CL13(시세이도 프로페셔널(주)제)를 이용하여 1회의 브리치 처리를 행하였다. 계속해서, 축모 교정제(크리스탈라이징 스트레이트 EX(시세이도 프로페셔널(주)제)를 이용하여 축모 교정 처리를 2회 행하였다.A bundle of healthy hairs was subjected to a one-time brich treatment using a bridging agent (PRIMIENCE CL13 (manufactured by Shiseido Professional Co., Ltd.). Using it, the hair growth correction treatment was performed twice.
상기와 같이 해서 조제한 손상 헤어의 다발(동량)에, 실시예 1 및 비교예 1의 조성물을 도포하고, 15분간 방치한 후, 수세하고, 드라이어로 건조시켰다. The composition of Example 1 and Comparative Example 1 was applied to the bundle (equal amount) of damaged hair prepared as described above, left to stand for 15 minutes, washed with water and dried with a dryer.
상기 처리를 실시한 모발 다발의 일단을 고정해서 수직 방향으로 인장응력을 부가했다. 모발이 파단했을 때의 응력값(파단점 응력)을, 미처리의 손상 헤어와 비교해서 도 3에 나타낸다. One end of the hair bundle subjected to the above treatment was fixed, and a tensile stress was added in the vertical direction. The stress value (breaking point stress) when the hair breaks is shown in Fig. 3 in comparison with the untreated damaged hair.
도 3의 그래프로부터 분명하게 나타나 있는 바와 같이, 화학 처리에 의해 손상을 받아서 강도 저하한 모발을, 본 발명에 따른 실시예 2의 조성물로 처리하면 강도가 현격하게 향상되고, 처리 사이클수를 3회로 하면 더욱 강화되었다. 종래의 보수제인 비교예 2로도 어느 정도의 강도 향상은 보여졌지만, 그 정도는 본 발명에는 미치치 못하고, 처리 사이클을 늘려도 강도의 더나은 향상은 관찰되지 않았다.As is evident from the graph of FIG. 3, when the hair which has been damaged by chemical treatment and has decreased strength is treated with the composition of Example 2 according to the present invention, the strength is significantly improved, and the number of treatment cycles is three times. It was further strengthened. In Comparative Example 2, which is a conventional water-retaining agent, a degree of strength improvement was observed, but the degree did not reach the present invention, and no further improvement in strength was observed even by increasing the treatment cycle.
Claims (4)
상기 조성물의 pH가 1.0∼3.0의 범위 내인 모발강화제 조성물.According to claim 2,
A hair strengthening composition having a pH in the range of 1.0 to 3.0.
(2) 도포한 상태에서 모발을 방치하고,
(3) 모발을 수세하고,
(4) 모발을 건조시키는 공정을 포함하는 모발강화 처리 방법.(1) The hair strengthening agent of claim 1 or the hair strengthening composition of claim 2 or 3 is applied to the hair,
(2) The hair is left in the applied state,
(3) washing the hair,
(4) A hair strengthening treatment method comprising the step of drying the hair.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
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| JP2017145500A JP2019026574A (en) | 2017-07-27 | 2017-07-27 | Hair strengthening agent |
| JPJP-P-2017-145500 | 2017-07-27 | ||
| PCT/JP2018/026654 WO2019021875A1 (en) | 2017-07-27 | 2018-07-17 | Hair strengthening agent |
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| KR20200033248A true KR20200033248A (en) | 2020-03-27 |
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| KR1020207000058A KR20200033248A (en) | 2017-07-27 | 2018-07-17 | Hair enhancer |
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| KR (1) | KR20200033248A (en) |
| CN (1) | CN110944620B (en) |
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| JP6548350B1 (en) * | 2019-02-07 | 2019-07-24 | 株式会社ナンバースリー | Hair repair composition and hair repair method |
| JP6877856B2 (en) * | 2019-07-17 | 2021-05-26 | アゼリスジャパン株式会社 | Glyoxylic acid-containing hair composition |
| WO2022112961A1 (en) * | 2020-11-30 | 2022-06-02 | Jean Paul Myne' Srl | Cosmetic composition for the treatment of keratinic fibers and method comprising the application of said composition to the keratinic fibers |
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| JPH10175824A (en) | 1996-12-12 | 1998-06-30 | Lion Corp | Hair restoring agent composition and hair cosmetic and hair strengtening agent using the same |
| JP2010189286A (en) | 2009-02-16 | 2010-09-02 | Torrents Co Ltd | Hair-reinforcing agent |
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| JP5086539B2 (en) * | 2005-12-27 | 2012-11-28 | ライオン株式会社 | Hair cosmetics |
| JP5228338B2 (en) * | 2007-02-27 | 2013-07-03 | ライオン株式会社 | Hair cleanser |
| IT1398503B1 (en) * | 2010-02-24 | 2013-03-01 | Alderan S A S Di Alderano Mannozzi & C Ora Alderan S A S Di D Ottavi Adele & C | USE OF TAMPONANT SUBSTANCES TO MAKE THE CURLY HAIR, SMOOTH OR CORRUGATED. |
| IT1401087B1 (en) * | 2010-07-20 | 2013-07-12 | Alderan S A S Di Alderano Mannozzi & C Ora Alderan S A S Di D Ottavi Adele & C | USE OF ALPHA KETO ACIDS, OR THEIR DERIVATIVES, TO MAKE THE CURLY HAIR LISCIO, CRESPO OR ONDULATO. |
| JP5947340B2 (en) * | 2014-07-11 | 2016-07-06 | 株式会社 資生堂 | Hair treatment agent |
| JP6316790B2 (en) * | 2014-12-05 | 2018-04-25 | 花王株式会社 | Hair deformation treatment agent |
| JP6873994B2 (en) * | 2015-11-24 | 2021-05-19 | ロレアル | Composition for treating hair |
| JP6882315B2 (en) * | 2015-11-24 | 2021-06-02 | ロレアル | Composition for treating hair |
| US11213470B2 (en) * | 2015-11-24 | 2022-01-04 | L'oreal | Compositions for treating the hair |
| BR112018010344B1 (en) * | 2015-11-24 | 2021-08-10 | L'oreal | HAIR COMPOSITION, HAIR TREATMENT SYSTEM AND METHOD, METHODS FOR CHANGING HAIR COLOR AND HAIR SHAPE, AND, MULTICOMPARTMENT KITS |
-
2017
- 2017-07-27 JP JP2017145500A patent/JP2019026574A/en active Pending
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2018
- 2018-07-17 CN CN201880048188.3A patent/CN110944620B/en active Active
- 2018-07-17 WO PCT/JP2018/026654 patent/WO2019021875A1/en active Application Filing
- 2018-07-17 KR KR1020207000058A patent/KR20200033248A/en not_active Application Discontinuation
- 2018-07-26 TW TW107125847A patent/TW201909882A/en unknown
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| JPS5947340B2 (en) | 1978-06-06 | 1984-11-19 | 日本電信電話株式会社 | error check correction circuit |
| JPS5919267B2 (en) | 1980-02-20 | 1984-05-04 | 東芝コ−ルドチエ−ン株式会社 | Operation control device for refrigeration equipment |
| JPH10175824A (en) | 1996-12-12 | 1998-06-30 | Lion Corp | Hair restoring agent composition and hair cosmetic and hair strengtening agent using the same |
| JP2010189286A (en) | 2009-02-16 | 2010-09-02 | Torrents Co Ltd | Hair-reinforcing agent |
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| CN110944620A (en) | 2020-03-31 |
| JP2022168056A (en) | 2022-11-04 |
| JP2019026574A (en) | 2019-02-21 |
| TW201909882A (en) | 2019-03-16 |
| CN110944620B (en) | 2024-02-02 |
| WO2019021875A1 (en) | 2019-01-31 |
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