KR20200030190A - Process Of producing Streaky pattern Melange Knit Using Regular Polyester Yarn - Google Patents
Process Of producing Streaky pattern Melange Knit Using Regular Polyester Yarn Download PDFInfo
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- KR20200030190A KR20200030190A KR1020180108705A KR20180108705A KR20200030190A KR 20200030190 A KR20200030190 A KR 20200030190A KR 1020180108705 A KR1020180108705 A KR 1020180108705A KR 20180108705 A KR20180108705 A KR 20180108705A KR 20200030190 A KR20200030190 A KR 20200030190A
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/10—Patterned fabrics or articles
- D04B1/12—Patterned fabrics or articles characterised by thread material
- D04B1/126—Patterned fabrics or articles characterised by thread material with colour pattern, e.g. intarsia fabrics
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- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02J—FINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
- D02J1/00—Modifying the structure or properties resulting from a particular structure; Modifying, retaining, or restoring the physical form or cross-sectional shape, e.g. by use of dies or squeeze rollers
- D02J1/08—Interlacing constituent filaments without breakage thereof, e.g. by use of turbulent air streams
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/14—Other fabrics or articles characterised primarily by the use of particular thread materials
- D04B1/16—Other fabrics or articles characterised primarily by the use of particular thread materials synthetic threads
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/14—Other fabrics or articles characterised primarily by the use of particular thread materials
- D04B1/18—Other fabrics or articles characterised primarily by the use of particular thread materials elastic threads
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
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Abstract
Description
본 발명은 폴리에스테르 ITY사와 스판덱스모노필라멘트를 공급하여 싱글플레인조직으로 환편하고 염색한 것을 특징으로 하는 레귤러 폴리에스터사를 사용한 선형멜란지 무늬발현 환편물의 제조방법에 관한 것이다. The present invention relates to a method for manufacturing a linear melange pattern expressing circular knitted fabric using a regular polyester yarn, characterized in that the polyester ITY yarn and the spandex monofilament are supplied to circular knit and dyed with a single plane structure.
멜란지(melange)란 프랑스어인 멜랑쥬에서 유래된 단어로서 혼합된, 섞인 등의 의미를 가지고 있어 색상에 있어서 하나의 색이 아니라 미묘하게 여러 색상이 뒤섞인 느낌을 주는 것을 일컬는다. Melange (melange) is a word derived from the French word melange, which has the meaning of mixed, mixed, and so on, rather than a single color in color.
통상 단색보다 따뜻한 느낌을 주기 때문에 아크릴, 울 소재 등의 가을, 겨울용 니트웨어나 모직 소재에 주로 적용되어 왔으나, 최근에는 방적사의 천연의, 부드럽고, 고급스러운 이미지의 차용 및 기능성을 겸비한 화섬소재를 활용하여 의류용 직물, 신발, 모자, 가방 등의 패션악세서리, 침구 등의 인테리어 소재, 유모차, 어반 아웃도어에까지 패션성과 기능성을 고루 갖춘 트렌디 한 멀티 소재로서 널리 적용되고 있는 추세이다.Since it usually feels warmer than a solid color, it has been mainly applied to knitted and wool materials for autumn and winter, such as acrylic and wool, but recently, it uses fabric materials that combine the functionality and borrowing of natural, soft, and high-quality images of spun yarn. Therefore, it is a trend that has been widely applied as a trendy multi-material that combines fashion and functionality even for clothing accessories, fashion accessories such as shoes, hats, bags, interior materials such as bedding, strollers, and urban outdoor.
다양한 복종에서 천연소재의 감성을 가지는 멜란지 소재의 국내외 시장 수요가 지속적으로 요구되고 있으나 편성물의 제조특성상 다양한 패턴의 멜란지 효과를 구현하기 어려움에 따라 제품 개발이 한정적인 실정이다.Domestic and foreign market demands of melange materials having the sensitivity of natural materials in various submissions are continuously demanded, but product development is limited due to the difficulty in realizing the melange effect of various patterns due to the manufacturing characteristics of knitted fabrics.
특히 멜란지 소재에 주로 사용되는 CDP(Cationic Dyeable Polyester) 활용한 사가공 접목 기법의 경우, cdp사와 레귤러 폴리에스터 염색시 cdp사가 진색으로 염색되어야 하기에 색상의 제약이 있고, two side 염색으로 염가공료 상승등의 제한요인들로 인해 가격경쟁력 확보가 어려움에 따라 생산공정의 단순화 및 가격경쟁력 확보에 대한 니즈가 지속적으로 제기되고 있다.In particular, in the case of the private graft technique using CDP (Cationic Dyeable Polyester), which is mainly used for melange materials, when cdp and regular polyester are dyed, the cdp yarn must be dyed in dark color, and there is a color limitation. As it is difficult to secure price competitiveness due to limited factors such as rising, the need for simplifying the production process and securing price competitiveness has been continuously raised.
이러한 CDP(Cationic Dyeable Polyester) 활용한 사가공에서 탈피하여 멜란지 편성물을 제조하기 위해 연신차에 의한 배향도가 다른 이종의 레귤러 PET를 사용한 ITY사를 사용하는 경우가 있었으나, 원사가 루프를 형성하면서 직조되는 편성물에 있어서는 원사가 직교하여 형성되는 직물에 비해 루프의 존재로 인해 선형패턴 발현이 상대적으로 어렵고, 제어된 규칙성을 통해 하나의 패턴으로 나타나기 때문에 지속적인 재현성 확보가 어려운 문제점을 안고 있어 dot패턴의 멜란지 효과밖에 얻을 수 없는 문제점이 있었다. There was a case in which ITY yarns using different types of regular PETs with different orientations by the drawer were used to fabricate melange knitted fabrics by stripping from the CDP (Cationic Dyeable Polyester) processing, but the yarns were woven while forming a loop. In the case of knitted fabrics, linear patterns are relatively difficult to express due to the presence of loops compared to fabrics formed by orthogonal yarns, and it is difficult to secure continuous reproducibility because it appears as one pattern through controlled regularity. There was a problem that could only be obtained.
그러므로 본 발명에 의하면, 기존의 캐치온염색사(CDP)를 활용한 공정보다 상대적으로 가격경쟁력이 있는 레귤러 폴리에스테르사인 POY와 SDY 또는 HOY의 연신(배향도)차에 의한 염색성 차를 활용하여 선형멜란지효과를 편직물에도 발현할 수 있도록 하는 것을 기술적과제로 한다.Therefore, according to the present invention, the linear melange effect by utilizing the dyeability difference by the stretching (orientation) difference between POY and SDY or HOY, which are regular polyester yarns having comparatively higher price competitiveness, than the process using the conventional catch-on dyeing yarn (CDP). It is a technical task to make it possible to be expressed in knitted fabric.
그러므로 본 발명에 의하면, 폴리에스테르 ITY사와 스판덱스모노필라멘트를 공급하여 루프장 140~145㎜, 환편속도 18~20rpm의 조건으로 싱글환편기로 싱글플레인조직으로 환편하고 염색한 것을 특징으로 하는 레귤러 폴리에스터사를 사용한 선형멜란지 무늬발현 환편물의 제조방법이 제공된다.Therefore, according to the present invention, the polyester polyester yarn and the spandex monofilament are supplied, and the loop polyester is a regular polyester yarn characterized in that it is knitted and dyed in a single plane structure with a single circular knitting machine under conditions of 140 to 145 mm and a circular knitting speed of 18 to 20 rpm. A method of manufacturing a linear melange-patterned circular knitted fabric using the present invention is provided.
이하 본 발명을 보다 상세히 설명하기로 한다.Hereinafter, the present invention will be described in more detail.
본 발명은 폴리에스테르 ITY사와 스판덱스모노필라멘트를 공급하여 양면인터록조직으로 환편하고 염색한 것을 특징으로 하는 레귤러 폴리에스터사를 사용한 선형멜란지 무늬발현 환편물의 제조방법에 관한 것이다.The present invention relates to a method for manufacturing a linear melange pattern expressing circular knitted fabric using a regular polyester yarn, characterized in that it is knitted and dyed with a double-sided interlock structure by supplying polyester ITY yarn and spandex monofilament.
본 발명의 환편물의 제조방법에서 사용되는 원사는 폴리에스테르 ITY사와 스판덱스모노필라멘트를 사용한다. The yarn used in the manufacturing method of the circular knitted fabric of the present invention uses polyester ITY yarn and spandex monofilament.
상기 폴리에스테르 ITY사는 폴리에스테르 부분연신사 또는 폴리에스테르 스핀드로오사 중 어느 하나와 폴리에스테르 미연신사를 공급하여 공기압 0.1~0.5kgf로 인터레이스한 후 권취한 폴리에스테르 ITY사인 것을 사용하는 것이 최소한의 교락으로 포집성은 가지되 제조된 편물 표면에 선형으로 ITY사가 드러나 선형멜란지 무늬(Streaky pattern)를 표현할 수 있도록 할 수 있다. 본 발명에서는 최소한의 포집성을 주어 원활한 편성 공정을 가능하게 하되 원사의 교락(혼합)이 최소화되도록 하였다. 공기압 0.1kgf미만에서는 필라멘트 간 포합성이 약해져 편성과정에서 분리가 발생하는 문제점이 있으며, 공기압 0.5kgf초과시에는 폴리에스테르 부분연신사 또는 폴리에스테르 스핀드로오사 중 어느 하나와 폴리에스테르 미연신사가 복합사단면상으로 골고루 혼재되어 편성시 dot 멜란지가 형성되는 문제점이 있다.The polyester ITY yarn is one of the polyester partial stretch yarn or the polyester spin draw yarn, and the polyester unstretched yarn is interlaced with air pressure of 0.1 to 0.5 kgf, and then the one wound with the polyester ITY yarn is used. Collectability, but it is possible to express a linear melange pattern by revealing the ITY yarn linearly on the manufactured knitted fabric surface. In the present invention, a minimal knitting property is given to enable a smooth knitting process, but to minimize the disruption (mixing) of the yarn. When the air pressure is less than 0.1 kgf, the composition between the filaments is weak, and separation occurs during the knitting process. When the air pressure exceeds 0.5 kgf, either the polyester partial stretch yarn or the polyester spin draw yarn and the polyester unstretched yarn have a complex cross section. As a result, evenly mixed, there is a problem that a dot melange is formed upon knitting.
특히, 선형멜란지 무늬(Streaky pattern)를 표현하는 소재는 직물형태에서는 적용 사례를 쉽게 찾아 볼 수 있으나, 편직물의 경우에는 루프의 형성에 의해 선형멜란지 무늬를 형성하기가 어려웠다. 본 발명에서는 기존의 캐치온염색사(CDP)를 활용한 공정보다 상대적으로 가격경쟁력이 있는 Regular Polyester사인 POY와 SDY 또는 HOY의 연신(배향도)차에 의한 염색성 차를 활용하여 선형멜란지 효과를 발현하도록 하는 것이다.In particular, the material expressing the linear melange pattern (Streaky pattern) can be easily found in the application example in the form of a fabric, but in the case of a knitted fabric, it was difficult to form a linear melange pattern by the formation of a loop. In the present invention, the linear melange effect is expressed by utilizing the dyeability difference caused by the stretching (orientation) difference between POY and SDY or HOY, which are regular polyester yarns that have comparatively more cost competitiveness than the process using the conventional Catch-On Dyeing yarn (CDP). will be.
본 발명에서 사용되는 폴리에스테르 ITY사는 비연속으로 짧은 길이의 패턴의 형태를 띄고 있으며, 도 3에 도시된 바와 같이 폴리에스테르 부분연신사 또는 폴리에스테르 스핀드로오사 중 어느 하나(2)와 폴리에스테르 미연신사(1)가 혼재되지 않도록 배열됨에 따라 편성후 염색에 의해 연신(배향도)차에 의한 염색성 차를 활용하여 선형(Streaky) 패턴의 멜란지효과를 얻을 수 있도록 한 것이다.The polyester ITY yarn used in the present invention has the form of a pattern having a short length non-continuously, and as shown in FIG. 3, either the polyester partial stretch yarn or the polyester spin draw yarn (2) and the polyester are not opened. As the
본 발명에서 상기 ITY사의 교락수는 8~10개/m인 것이 선형(Streaky) 멜란지 효과를 최적으로 발현할 수 있고 멜란지 형태의 쏠림 현상 및 재현성 문제를 해결할 수 있어 바람직하다. In the present invention, it is preferable that the number of intersections of the ITY yarns is 8 to 10 / m, as it can optimally express a linear melange effect and solve a problem of melange-type tilting and reproducibility.
본 발명에서 환편공정은 상기 폴리에스테르 ITY사와 스판덱스모노필라멘트를 공급하여 루프장 140~145㎜, 환편속도 18~20rpm의 조건으로 싱글환편기로 싱글플레인조직으로 환편하게 된다.In the present invention, the circular knitting process is performed by supplying the polyester ITY company and spandex monofilament, and circular knitting into a single plane structure with a single circular knitting machine under conditions of a loop length of 140 to 145 mm and a circular knitting speed of 18 to 20 rpm.
루프장은 편물 제품 형성의 주요 요소로써 동일 조건하에서 루프장이 길수록 원단 밀도가 적어지며 루즈(loose)해지고 단위면적당 중량이 낮아지며 원단폭은 넓어진다. 반대로 루프장이 짧을수록 밀도가 많아지며 원단은 타이트(tight)해지고 단위면적당 중량이 높아지며 원단폭이 좁아진다. 따라서 본 발명에서는 선형멜란지 발현이 우수하고 신축성이 우수한 제품성 확보를 위해서는 루프장 140~145㎜가 되도록 하여 원단의 조직과 원사 Denier에 적정한 루프장을 선정하도록 하였다.The roof length is a major factor in the formation of knitted products. Under the same conditions, the longer the loop length, the less the fabric density, the looser, the lower the weight per unit area, and the wider the fabric width. Conversely, the shorter the loop length, the greater the density, the tighter the fabric, the higher the weight per unit area, and the narrower the fabric width. Therefore, in the present invention, in order to secure a product having excellent linear melange expression and excellent elasticity, a loop length of 140 to 145 mm was set to select an appropriate loop length for the fabric texture and yarn denier.
루프장 140㎜미만에서는 함께 사용되는 스판사의 절사 및 ITY사의 일부 절사로 단사 편직으로 인한 실 빠짐 등의 불량이 발생할 우려가 있었으며, 루프장 145㎜초과시에는 선형멜란지의 발현이 어려운 문제점이 있었다.When the roof length was less than 140 mm, there was a concern that defects such as thread breakage due to knitting of single yarn due to the cutting of the span yarn used together with the partial cutting of the ITY yarn, and there was a problem that the expression of linear melange was difficult when the loop length exceeded 145 mm.
본 발명의 편물의 안정적인 생산성 확보를 위해서는 최종 편물의 take-up 장력 균형 및 효율적인 편성 속도(rpm)등이 선정되어야 하는데, 편성속도는 18~20 rpm을 유지하여 환편하였으며, 최종 Take-up 장력은 원사의 섬도특성을 고려하여 18~22% 사이로 설정한다. In order to secure a stable productivity of the knitted fabric of the present invention, the take-up tension balance of the final knitted fabric and an efficient knitting speed (rpm), etc. should be selected, and the knitting speed was rounded by maintaining 18-20 rpm, and the final take-up tension is Set between 18 and 22% considering the fineness of the yarn.
편성후 염색시에는 통상의 염색방법으로 행할 수 있으나, 특히 2-tone을 발현시에는 분산염료로 염색하고, Multi-tone을 발현시에는 산성욕에서의 분산염료와 양이온염료로 일욕염색하여 멜란지 효과의 발현을 극대화할 수 있다.When dyed after knitting, it can be carried out by a conventional dyeing method.However, when expressing 2-tone, it is dyed with a disperse dye, and when expressing multi-tone, it is dyed with a disperse dye and a cationic dye in an acidic bath for a melange effect. Can maximize the expression of
그러므로 본 발명에 의하면, 편직물의 경우에는 루프의 형성에 의해 선형멜란지 무늬를 형성하기가 어려웠던 종래기술에서 탈피하고, 기존의 캐치온염색사(CDP)를 활용한 공정보다 상대적으로 가격경쟁력이 있는 레귤러 폴리에스테르사인 POY와 SDY 또는 HOY의 연신(배향도)차에 의한 염색성 차를 활용하여 선형멜란지효과를 편직물에도 발현할 수 있었다.Therefore, according to the present invention, in the case of knitted fabrics, the regular poly having a relatively competitive price competitiveness than the process using the conventional catch-on-dyeing yarn (CDP), which is difficult to form in the prior art, in which it was difficult to form a linear melange pattern by the formation of a loop. The linear melange effect could also be expressed in knitted fabrics by utilizing the dyeability difference due to the difference in stretching (orientation) between the esters POY and SDY or HOY.
도 1은 본 발명의 환편물인 실시예 1의 표면사진이며,
도 2는 본 발명의 환편물의 원사중 하나인 ITY사의 표면사진이며,
도 3은 본 발명의 환편물의 원사중 하나인 ITY사의 단면개략도이며,
도 4는 비교예 1의 환편물의 표면사진이다.1 is a surface photograph of Example 1, which is a circular knitted fabric of the present invention,
2 is a photograph of the surface of ITY yarn, one of the yarns of the circular knitted fabric of the present invention,
3 is a schematic cross-sectional view of ITY yarn, one of the yarns of the circular knitted fabric of the present invention,
4 is a photograph of the surface of the circular knitted fabric of Comparative Example 1.
다음의 실시예에서는 본 발명의 레귤러 폴리에스터사를 사용한 선형멜란지 무늬발현 환편물의 제조방법의 비한정적인 예시를 하고 있다.In the following examples, non-limiting examples of a method for manufacturing a linear melange pattern expressing circular knit fabric using the regular polyester yarn of the present invention are given.
[실시예 1][Example 1]
폴리에스테르 스핀드로오사(SDY (50d/36fila))와 폴리에스테르 미연신사(85d/72fila)를 공급하여 공기압 0.1kgf로 인터레이스한 후 권취한 폴리에스테르 ITY사(135d/108fila)와 스판덱스모노필라멘트(20d)를 공급하여 루프장 145㎜, 환편속도 20rpm의 조건으로 36인치/28게이지(니들 3168本)의 싱글환편기(금용(한국))로 싱글플레인조직으로 중량 215g/sqm으로 환편하고 편직성 및 멜란지 효과를 확인하기 위해 1yd씩 컷팅하여 분산염료를 염료농도 1% o.w.f, 액비 1:50, 온도 130 ℃, 40min, pH 4~4.5로 현장에서 염색하여 본 발명의 환편물을 제조하였다.Polyester spin dross yarn (SDY (50d / 36fila)) and polyester unstretched yarn (85d / 72fila) were supplied and interlaced with air pressure of 0.1kgf, and then wound up, followed by winding with polyester ITY yarn (135d / 108fila) and spandex monofilament (20d) ) To provide a single circular knitting machine (Geumyong (Korea)) of 36 inches / 28 gauges (needle 3168 本) under the condition of a loop length of 145 mm and a circular knitting speed of 20 rpm, circular knitting at a weight of 215 g / sqm with a single plane structure, knitting and melange In order to confirm the effect, each yd was cut, and the disperse dye was dyed in the field with a dye concentration of 1% owf, a liquid ratio of 1:50, a temperature of 130 ° C, 40min, and pH of 4 to 4.5 to prepare a circular knitted fabric of the present invention.
[비교예 1] [Comparative Example 1]
상기 실시예 1에서 폴리에스테르 ITY사를 제조할 때 공기압을 1.0kgf로 인터레이스하는 것을 제외하고는 실시예 1과 동일하게 환편물을 제조하였다.When preparing the polyester ITY in Example 1, except for interlacing the air pressure to 1.0kgf, circular knit fabrics were prepared in the same manner as in Example 1.
도 1에 나타난 바와 같이 편물의 표면에 선형멜란지 효과가 선명하게 나타남을 확인할 수 있었으나, 비교예 1의 편물사진인 도 4에서는 선형패턴이 아닌 촘촘한 형태의 멜란지 패턴이 나타나 표면 도트멜란지 효과가 나타나며 Tone이 몰려 위단이 발생되는 것을 확인할 수 있었다.As shown in FIG. 1, it was confirmed that the linear melange effect was clearly visible on the surface of the knitted fabric, but in FIG. 4, which is a knitted photograph of Comparative Example 1, a dense melange pattern was formed rather than a linear pattern, and the surface dot melange effect appeared and Tone It was confirmed that the rush was generated.
1 : 폴리에스테르 미연신사
2 : 폴리에스테르 부분연신사 또는 폴리에스테르 스핀드로오사 중 어느 하나 1: Polyester unstretched yarn
2: Either a polyester partial stretch yarn or a polyester spin draw yarn
Claims (3)
상기 폴리에스테르 ITY사는 폴리에스테르 부분연신사 또는 폴리에스테르 스핀드로오사 중 어느 하나와 폴리에스테르 미연신사를 공급하여 공기압 0.1~0.5kgf로 인터레이스한 후 권취한 폴리에스테르 ITY사인 것을 특징으로 하는 레귤러 폴리에스터사를 사용한 선형멜란지 무늬발현 환편물의 제조방법.According to claim 1,
The polyester ITY yarn is a regular polyester yarn characterized in that it is a polyester ITY yarn wound after being interlaced with air pressure of 0.1 to 0.5 kgf by supplying either a polyester partial stretch yarn or a polyester spin draw yarn and a polyester unstretched yarn. Method of manufacturing a linear melange pattern expressing circular knitted fabric using a.
상기 폴리에스테르 ITY사의 교락수는 8~10개/m인 것을 특징으로 하는 레귤러 폴리에스터사를 사용한 선형멜란지 무늬발현 환편물의 제조방법.According to claim 2,
The method of manufacturing a linear melange pattern expressing circular knit fabric using a regular polyester yarn, characterized in that the number of intersections of the polyester ITY is 8 to 10 / m.
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CN113564790A (en) * | 2021-07-21 | 2021-10-29 | 孙新玲 | Single-layer fabric and sports wear |
CN113668170A (en) * | 2021-08-18 | 2021-11-19 | 辽宁国科科技有限公司 | Pollution interception for dyeing and finishing fabric |
KR20240088056A (en) | 2022-12-13 | 2024-06-20 | 주식회사 여주티앤씨 | Process Of Producing Triacetate Like Polyester Knits |
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KR20010029390A (en) | 1999-09-30 | 2001-04-06 | 조민호 | Manufacturing of silk like polyester fabric having melange effect. |
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KR20010029390A (en) | 1999-09-30 | 2001-04-06 | 조민호 | Manufacturing of silk like polyester fabric having melange effect. |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN113564790A (en) * | 2021-07-21 | 2021-10-29 | 孙新玲 | Single-layer fabric and sports wear |
CN113668170A (en) * | 2021-08-18 | 2021-11-19 | 辽宁国科科技有限公司 | Pollution interception for dyeing and finishing fabric |
KR20240088056A (en) | 2022-12-13 | 2024-06-20 | 주식회사 여주티앤씨 | Process Of Producing Triacetate Like Polyester Knits |
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