KR20200008136A - 중간 다공성 fau 제올라이트, 이의 생산 및 이들의 중유를 업그레이드하는 용도 - Google Patents
중간 다공성 fau 제올라이트, 이의 생산 및 이들의 중유를 업그레이드하는 용도 Download PDFInfo
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- KR20200008136A KR20200008136A KR1020197036518A KR20197036518A KR20200008136A KR 20200008136 A KR20200008136 A KR 20200008136A KR 1020197036518 A KR1020197036518 A KR 1020197036518A KR 20197036518 A KR20197036518 A KR 20197036518A KR 20200008136 A KR20200008136 A KR 20200008136A
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- South Korea
- Prior art keywords
- catalyst
- zeolite
- stream
- zeolitic material
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 239000010457 zeolite Substances 0.000 title claims abstract description 170
- 239000000295 fuel oil Substances 0.000 title description 43
- 238000004519 manufacturing process Methods 0.000 title description 8
- 239000003054 catalyst Substances 0.000 claims abstract description 205
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 126
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 114
- 239000000463 material Substances 0.000 claims abstract description 83
- 238000000034 method Methods 0.000 claims abstract description 70
- LXPCOISGJFXEJE-UHFFFAOYSA-N oxifentorex Chemical compound C=1C=CC=CC=1C[N+](C)([O-])C(C)CC1=CC=CC=C1 LXPCOISGJFXEJE-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910052751 metal Inorganic materials 0.000 claims description 50
- 239000002184 metal Substances 0.000 claims description 50
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 41
- 239000011148 porous material Substances 0.000 claims description 39
- 239000000203 mixture Substances 0.000 claims description 26
- 229910052759 nickel Inorganic materials 0.000 claims description 22
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 20
- 229910052750 molybdenum Inorganic materials 0.000 claims description 20
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 16
- 239000011734 sodium Substances 0.000 claims description 16
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims description 15
- 239000007864 aqueous solution Substances 0.000 claims description 15
- 229910044991 metal oxide Inorganic materials 0.000 claims description 13
- 150000004706 metal oxides Chemical class 0.000 claims description 13
- 238000010438 heat treatment Methods 0.000 claims description 11
- 238000005342 ion exchange Methods 0.000 claims description 11
- 229910052708 sodium Inorganic materials 0.000 claims description 10
- 229910052721 tungsten Inorganic materials 0.000 claims description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 8
- 229960000800 cetrimonium bromide Drugs 0.000 claims description 8
- 239000000377 silicon dioxide Substances 0.000 claims description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 7
- 239000004094 surface-active agent Substances 0.000 claims description 5
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 3
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- 238000006243 chemical reaction Methods 0.000 description 104
- 238000004517 catalytic hydrocracking Methods 0.000 description 46
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 45
- 230000008569 process Effects 0.000 description 42
- 239000000543 intermediate Substances 0.000 description 40
- 230000007704 transition Effects 0.000 description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 29
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 23
- 238000000926 separation method Methods 0.000 description 23
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 18
- 125000003118 aryl group Chemical group 0.000 description 17
- 229910052739 hydrogen Inorganic materials 0.000 description 17
- 239000001257 hydrogen Substances 0.000 description 17
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
- 238000006555 catalytic reaction Methods 0.000 description 15
- 239000000047 product Substances 0.000 description 14
- 230000009467 reduction Effects 0.000 description 14
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- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 13
- 150000001875 compounds Chemical class 0.000 description 13
- 150000004763 sulfides Chemical class 0.000 description 13
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 12
- 238000005336 cracking Methods 0.000 description 12
- 239000007789 gas Substances 0.000 description 12
- 238000005470 impregnation Methods 0.000 description 12
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- 150000002739 metals Chemical class 0.000 description 12
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- 229910052717 sulfur Inorganic materials 0.000 description 12
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- 238000012546 transfer Methods 0.000 description 10
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- 150000002430 hydrocarbons Chemical group 0.000 description 9
- 150000002500 ions Chemical group 0.000 description 9
- 239000003921 oil Substances 0.000 description 9
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 8
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- 239000002585 base Substances 0.000 description 8
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- 239000012685 metal catalyst precursor Substances 0.000 description 8
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- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 6
- 230000004048 modification Effects 0.000 description 6
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- 239000002253 acid Substances 0.000 description 5
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- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 4
- -1 Ethylene, propylene, butene Chemical class 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 4
- 238000002441 X-ray diffraction Methods 0.000 description 4
- 150000001336 alkenes Chemical class 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 229910017052 cobalt Inorganic materials 0.000 description 4
- 239000010941 cobalt Substances 0.000 description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 4
- 239000003085 diluting agent Substances 0.000 description 4
- 239000002019 doping agent Substances 0.000 description 4
- 229910052976 metal sulfide Inorganic materials 0.000 description 4
- 229910052698 phosphorus Inorganic materials 0.000 description 4
- 239000011574 phosphorus Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 229910052796 boron Inorganic materials 0.000 description 3
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 238000004939 coking Methods 0.000 description 3
- 239000003502 gasoline Substances 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- 150000002605 large molecules Chemical class 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229920002521 macromolecule Polymers 0.000 description 3
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- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 3
- 239000010937 tungsten Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 150000001491 aromatic compounds Chemical class 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 238000012512 characterization method Methods 0.000 description 2
- 239000000571 coke Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 238000010908 decantation Methods 0.000 description 2
- 238000006477 desulfuration reaction Methods 0.000 description 2
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- 238000004821 distillation Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
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- 238000004231 fluid catalytic cracking Methods 0.000 description 2
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 2
- 125000005842 heteroatom Chemical group 0.000 description 2
- 125000000623 heterocyclic group Chemical group 0.000 description 2
- 238000005984 hydrogenation reaction Methods 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 239000004570 mortar (masonry) Substances 0.000 description 2
- 229910000480 nickel oxide Inorganic materials 0.000 description 2
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
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- 150000004032 porphyrins Chemical class 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 2
- 229910001948 sodium oxide Inorganic materials 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
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- 230000000153 supplemental effect Effects 0.000 description 2
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 2
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- 238000006276 transfer reaction Methods 0.000 description 2
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- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 229910017318 Mo—Ni Inorganic materials 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
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- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- VXAUWWUXCIMFIM-UHFFFAOYSA-M aluminum;oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Al+3] VXAUWWUXCIMFIM-UHFFFAOYSA-M 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- DIYFBCCLCOWCMH-UHFFFAOYSA-N azane;heptane Chemical compound N.CCCCCCC DIYFBCCLCOWCMH-UHFFFAOYSA-N 0.000 description 1
- 239000003637 basic solution Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 229910001423 beryllium ion Inorganic materials 0.000 description 1
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- 239000013626 chemical specie Substances 0.000 description 1
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- QGUAJWGNOXCYJF-UHFFFAOYSA-N cobalt dinitrate hexahydrate Chemical compound O.O.O.O.O.O.[Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O QGUAJWGNOXCYJF-UHFFFAOYSA-N 0.000 description 1
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- 230000007246 mechanism Effects 0.000 description 1
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- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 description 1
- 229910000476 molybdenum oxide Inorganic materials 0.000 description 1
- AOPCKOPZYFFEDA-UHFFFAOYSA-N nickel(2+);dinitrate;hexahydrate Chemical compound O.O.O.O.O.O.[Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O AOPCKOPZYFFEDA-UHFFFAOYSA-N 0.000 description 1
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
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- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 150000002897 organic nitrogen compounds Chemical class 0.000 description 1
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 description 1
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- ITRNXVSDJBHYNJ-UHFFFAOYSA-N tungsten disulfide Chemical compound S=[W]=S ITRNXVSDJBHYNJ-UHFFFAOYSA-N 0.000 description 1
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Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/026—After-treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/28—Molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/30—Tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/75—Cobalt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/755—Nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/041—Mesoporous materials having base exchange properties, e.g. Si/Al-MCM-41
-
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- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/20—Sulfiding
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- Chemical & Material Sciences (AREA)
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- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
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- General Chemical & Material Sciences (AREA)
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Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201762507520P | 2017-05-17 | 2017-05-17 | |
| US62/507,520 | 2017-05-17 | ||
| US15/821,001 | 2017-11-22 | ||
| US15/821,001 US10407311B2 (en) | 2017-05-17 | 2017-11-22 | Zeolites, the production thereof, and their uses for upgrading heavy oils |
| PCT/US2018/030435 WO2018212986A1 (en) | 2017-05-17 | 2018-05-01 | Mesoporous fau zeolites, the production thereof, and their use for upgrading heavy oils |
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| KR20200008136A true KR20200008136A (ko) | 2020-01-23 |
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| US (1) | US10407311B2 (enExample) |
| EP (1) | EP3625172A1 (enExample) |
| JP (1) | JP2020520335A (enExample) |
| KR (1) | KR20200008136A (enExample) |
| CN (1) | CN110603226A (enExample) |
| SA (1) | SA519410571B1 (enExample) |
| WO (1) | WO2018212986A1 (enExample) |
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| JP2020527638A (ja) * | 2017-07-17 | 2020-09-10 | サウジ アラビアン オイル カンパニーSaudi Arabian Oil Company | 油アップグレードに続く蒸気分解により重質油を処理するためのシステムおよび方法 |
| US11066606B2 (en) | 2019-11-12 | 2021-07-20 | Saudi Arabian Oil Company | Systems and methods for catalytic upgrading of vacuum residue to distillate fractions and olefins with steam |
| US11066605B2 (en) * | 2019-11-12 | 2021-07-20 | Saudi Arabian Oil Company | Systems and methods for catalytic upgrading of vacuum residue to distillate fractions and olefins |
| US12378130B2 (en) * | 2022-01-06 | 2025-08-05 | Saudi Arabian Oil Company | Methods of synthesis of mesoporous nano-sized zeolite beta by hydrothermal treatment and uses thereof |
| US12304824B2 (en) | 2022-01-06 | 2025-05-20 | Saudi Arabian Oil Company | Methods of synthesis of mesoporous nano-sized beta zeolites by desilication and uses thereof |
| US12138622B2 (en) | 2022-10-21 | 2024-11-12 | Saudi Arabian Oil Company | Methods of producing catalysts comprising one or more oxides of nickel and one or more oxides of silver |
| CN115957828A (zh) * | 2022-12-14 | 2023-04-14 | 中国石油大学(北京) | 一种废塑料催化裂解用催化剂及其制备方法 |
| US12479736B2 (en) * | 2023-02-14 | 2025-11-25 | Saudi Arabian Oil Company | Mesoporous zeolites and methods of making the same |
| DK182117B1 (en) * | 2024-04-24 | 2025-08-22 | Topsoe As | Hydrodeoxygenation catalyst loading system |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US4503023A (en) * | 1979-08-14 | 1985-03-05 | Union Carbide Corporation | Silicon substituted zeolite compositions and process for preparing same |
| FR2698862B1 (fr) * | 1992-12-08 | 1995-01-13 | Elf Aquitaine | Procédé de synthèse d'un aluminosilicate cristallin enrichi en silice, ayant la structure de la mazzite, l'aluminosilicate obtenu et son utilisation comme catalyseur de transformation des hydrocarbures. |
| US7589041B2 (en) * | 2004-04-23 | 2009-09-15 | Massachusetts Institute Of Technology | Mesostructured zeolitic materials, and methods of making and using the same |
| CA2625544A1 (en) | 2005-10-12 | 2007-04-19 | Valorbec Societe En Commandite, Represented By Gestion Valeo S.E.C. | Silica nanoboxes, method of making and use thereof |
| CN101343068B (zh) * | 2007-07-09 | 2010-08-18 | 中国石油化工股份有限公司 | 一种y型分子筛及其制备方法 |
| US8183734B2 (en) * | 2008-07-28 | 2012-05-22 | Direct Drive Systems, Inc. | Hybrid winding configuration of an electric machine |
| US8524625B2 (en) * | 2009-01-19 | 2013-09-03 | Rive Technology, Inc. | Compositions and methods for improving the hydrothermal stability of mesostructured zeolites by rare earth ion exchange |
| ES2875884T3 (es) * | 2009-01-19 | 2021-11-11 | Grace W R & Co | Introducción de mesoporosidad en zeolitas con bajo contenido en Si/A1 |
| US8685875B2 (en) * | 2009-10-20 | 2014-04-01 | Rive Technology, Inc. | Methods for enhancing the mesoporosity of zeolite-containing materials |
| CN102049308B (zh) * | 2009-10-27 | 2013-04-10 | 中国石油化工股份有限公司 | 加氢裂化催化剂载体及其制备方法 |
| FR2952379B1 (fr) * | 2009-11-10 | 2012-05-11 | Inst Francais Du Petrole | Procede d'hydrocraquage mettant en oeuvre une zeolithe modifiee par un traitement basique |
| US20110171121A1 (en) * | 2010-01-08 | 2011-07-14 | Rive Technology, Inc. | Compositions and methods for making stabilized mesoporous materials |
| FR2970259B1 (fr) * | 2011-01-07 | 2014-07-18 | IFP Energies Nouvelles | Procede d'hydrocraquage utilisant un catalyseur zeolithique contenant deux fonctions hydrogenantes distinctes. |
| WO2012138910A2 (en) * | 2011-04-08 | 2012-10-11 | Rive Technology, Inc. | Mesoporous framework-modified zeolites |
| US9376324B2 (en) * | 2012-01-13 | 2016-06-28 | Rive Technology, Inc. | Introduction of mesoporosity into zeolite materials with sequential acid, surfactant, and base treatment |
| CA2850979A1 (en) * | 2012-01-13 | 2013-07-18 | Rive Technology, Inc. | Introduction of mesoporosity into low silica zeolites |
| WO2013123299A1 (en) * | 2012-02-17 | 2013-08-22 | Kior, Inc. | Mesoporous zeolite-containing catalysts for the thermoconversion of biomass and for upgrading bio-oils |
| US9573121B2 (en) * | 2012-11-08 | 2017-02-21 | Rive Technology, Inc. | Mesoporous zeolite catalyst supports |
| CN103394368B (zh) * | 2013-07-22 | 2015-06-17 | 中国海洋石油总公司 | 一种含复合分子筛的轻油型加氢裂化催化剂及其制备方法和应用 |
| US10626019B2 (en) * | 2014-12-30 | 2020-04-21 | W. R. Grace & Co.-Conn. | Methods for preparing zeolites with surfactant-templated mesoporosity and tunable aluminum content |
-
2017
- 2017-11-22 US US15/821,001 patent/US10407311B2/en active Active
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2018
- 2018-05-01 JP JP2019561231A patent/JP2020520335A/ja active Pending
- 2018-05-01 KR KR1020197036518A patent/KR20200008136A/ko not_active Withdrawn
- 2018-05-01 EP EP18730153.6A patent/EP3625172A1/en not_active Withdrawn
- 2018-05-01 WO PCT/US2018/030435 patent/WO2018212986A1/en not_active Ceased
- 2018-05-01 CN CN201880030375.9A patent/CN110603226A/zh active Pending
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2019
- 2019-11-17 SA SA519410571A patent/SA519410571B1/ar unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP3625172A1 (en) | 2020-03-25 |
| WO2018212986A1 (en) | 2018-11-22 |
| JP2020520335A (ja) | 2020-07-09 |
| CN110603226A (zh) | 2019-12-20 |
| SA519410571B1 (ar) | 2022-12-13 |
| US20180334390A1 (en) | 2018-11-22 |
| US10407311B2 (en) | 2019-09-10 |
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