KR20180093850A - Solar cell panel - Google Patents

Abstract

The present invention provides a photovoltaic cell panel capable of increasing efficiency and output. According to an embodiment of the present invention, the photovoltaic cell panel comprises: a double-sided light receiving photovoltaic cell; a front surface unit positioned on a front surface of the double-sided light receiving photovoltaic cell; and a back surface unit positioned on a back surface of the doubled-sided light receiving photovoltaic cell. The back surface unit has UV transmittance.

Description

Solar Cell Panel {SOLAR CELL PANEL}

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a solar cell panel, and more particularly, to a solar cell panel including a double-side light-receiving solar cell.

With the recent depletion of existing energy sources such as oil and coal, interest in alternative energy to replace them is increasing. Among them, solar cells are attracting attention as a next-generation battery that converts solar energy into electric energy.

Since the solar cell must be exposed to the external environment for a long time, it is manufactured in a panel form by a packaging process for protecting the solar cell. Since the solar cell panel manufactured in this way must be developed in various environments, it must have high long-term reliability so that it can be generated for a long time in various environments.

In order to prevent problems such as deterioration due to ultraviolet rays, the solar panel may include an ultraviolet screening agent on the rear surface of the solar panel or a rear surface portion of the solar panel may be formed of a material having little optical transparency to reflect or block the light. It was common. When a solar cell having a double-side light receiving structure in which light is received on both sides of the solar cell panel is applied, it is difficult to utilize light or ultraviolet rays incident on the backside for photoelectric conversion, thereby limiting the efficiency or output of the solar cell panel .

The present invention provides a solar cell panel capable of improving efficiency and power.

A solar cell panel according to an embodiment of the present invention includes a double-side light-receiving solar cell; A front part positioned on a front surface of the double-sided light receiving type solar cell; And a rear portion positioned on a rear surface of the double-sided light receiving type solar cell, wherein the rear portion has ultraviolet transmittance.

In this embodiment, when a solar cell having a double-side light receiving structure is used because the rear portion has ultraviolet ray transmittance, ultraviolet rays incident on the rear surface can be used for photoelectric conversion. Thereby, the rear portion does not contain the ultraviolet screening agent. Instead, at least one of the plurality of layers constituting the back surface may include a UV stabilizer to minimize or prevent problems caused by ultraviolet light.

1 is an exploded perspective view schematically illustrating a solar cell panel according to an embodiment of the present invention.
2 is a sectional view cut along the line II-II in Fig.
3 is a cross-sectional view illustrating a solar cell according to an embodiment of the present invention.
4 is a front plan view of the solar cell shown in FIG.
FIG. 5 is a graph showing the relative value of intensity with respect to the solar spectrum according to the wavelength of light. FIG.
6 is a graph showing the quantum efficiency of a solar cell according to the wavelength of light.
7 is a partial enlarged view of a part of a solar cell panel according to another embodiment of the present invention.
8 is a partial enlarged view of a part of a solar cell panel according to another embodiment of the present invention.
9 is a partial enlarged view of a part of a solar cell panel according to another embodiment of the present invention.
10 is a partial enlarged view of a part of a solar cell panel according to another embodiment of the present invention.
Fig. 11 is a graph showing the results of measurement of the transmittance of the back surface according to Example 1 and Comparative Example 1. Fig.

Hereinafter, embodiments of the present invention will be described in detail with reference to the accompanying drawings. However, it is needless to say that the present invention is not limited to these embodiments and can be modified into various forms.

In the drawings, the same reference numerals are used for the same or similar parts throughout the specification. In the drawings, the thickness, the width, and the like are enlarged or reduced in order to make the description more clear, and the thickness, width, etc. of the present invention are not limited to those shown in the drawings.

Wherever certain parts of the specification are referred to as "comprising ", the description does not exclude other parts and may include other parts, unless specifically stated otherwise. Also, when a portion of a layer, film, region, plate, or the like is referred to as being "on" another portion, it also includes the case where another portion is located in the middle as well as the other portion. When a portion of a layer, film, region, plate, or the like is referred to as being "directly on" another portion, it means that no other portion is located in the middle.

Hereinafter, a solar cell panel according to an embodiment of the present invention will be described in detail with reference to the accompanying drawings.

FIG. 1 is an exploded perspective view schematically showing a solar cell panel according to an embodiment of the present invention, and FIG. 2 is a sectional view cut along a line II-II in FIG.

1 and 2, the solar cell panel 100 according to the present embodiment includes a solar cell 150 having a bi-facial structure, Includes a front portion FP and a rear portion RP located on the rear surface of the solar cell 150, and the rear portion RP has ultraviolet transmittance. And the front part (FP) can also have ultraviolet transmittance. The front part FP may include a front member 110 positioned on the front surface of the solar cell 150 and a first sealing member 131 disposed between the solar cell 150 and the front member 110 have. The rear portion RP may include a rear member 200 positioned on the rear surface of the solar cell 150 and a second sealing member 132 positioned between the solar cell 150 and the rear surface member 200 . This will be explained in more detail.

First, the solar cell 150 may include a photoelectric conversion unit that converts the solar cell into electric energy, and an electrode that is electrically connected to the photoelectric conversion unit and collects and transfers a current. In this embodiment, a photoelectric conversion portion including a semiconductor substrate (for example, a silicon wafer) and a conductive type region can be applied as an example. At this time, the solar cell 150 may have a double-sided light receiving type structure in which light can be received on both sides of the semiconductor substrate. An example of the solar cell 150 having such a double-side light-receiving structure will be described in detail with reference to FIGS. 3 and 4. Next, the solar cell panel 100 will be described in detail with reference to FIG. 1 and FIG.

FIG. 3 is a cross-sectional view illustrating a solar cell 150 according to an embodiment of the present invention, and FIG. 4 is a front plan view of the solar cell 150 shown in FIG.

In this embodiment, the solar cell 150 includes a semiconductor substrate 152 including a base region 10, conductive regions 20 and 30 formed on the semiconductor substrate 152 or on the semiconductor substrate 152, And electrodes 42 and 44 connected to the conductive regions 20 and 30, respectively. The conductive regions 20 and 30 may include a first conductive type region 20 and a second conductive type region 30 having different conductivity types and the electrodes 42 and 44 may include a first conductive type Type region 20 and a second electrode 44 connected to the second conductivity type region 30. The first electrode 42 and the second electrode 44 may be connected to each other. This will be explained in more detail.

The semiconductor substrate 152 may include a base region 10 having a first or second conductivity type including a first or second conductivity type dopant at a relatively low doping concentration. In one example, the base region 10 may have a second conductivity type. The base region 10 may be comprised of a single crystalline semiconductor (e.g., a single single crystal or polycrystalline semiconductor, such as single crystal or polycrystalline silicon, particularly monocrystalline silicon) comprising a first or second conductivity type dopant. The solar cell 150 based on the base region 10 or the semiconductor substrate 152 having a high degree of crystallinity and having few defects is excellent in electrical characteristics.

An anti-reflection structure capable of minimizing reflection can be formed on the front and rear surfaces of the semiconductor substrate 152. For example, a texturing structure having a concavo-convex shape in the form of a pyramid or the like may be provided as an antireflection structure. The texturing structure formed in the semiconductor substrate 152 may have a certain shape (e.g., a pyramid shape) having an outer surface formed along a specific crystal plane (e.g., (111) plane) of the semiconductor. If the surface roughness of the semiconductor substrate 152 is increased due to such texturing, the reflectance of the light incident on the semiconductor substrate 152 may be reduced to minimize the loss of light. However, the present invention is not limited thereto, and a texturing structure may be formed on only one side of the semiconductor substrate 152, or a texturing structure may not be formed on the front and back sides of the semiconductor substrate 152.

A first conductive type region 20 having a first conductive type may be formed on one side (for example, a front side) of the semiconductor substrate 152. A second conductivity type region 30 having a second conductivity type may be formed on the rear surface of the semiconductor substrate 152. The first and second conductivity type regions 20 and 30 may have a different conductivity type from the base region 10 or may have a doping concentration higher than that of the base region 10, .

In this embodiment, the first and second conductivity type regions 20 and 30 may be configured as a doped region constituting a part of the semiconductor substrate 152. The first conductive type region 20 may be composed of a crystalline semiconductor (e.g., a single crystal or polycrystalline semiconductor, for example, single crystal or polycrystalline silicon, particularly monocrystalline silicon) including a first conductive type dopant. And the second conductivity type region 30 may be composed of a crystalline semiconductor (e.g., a single crystal or a polycrystalline semiconductor, for example, a single crystal or a polycrystalline silicon, particularly, a single crystal silicon) including a second conductive type dopant. As described above, when the first and second conductivity type regions 20 and 30 constitute a part of the semiconductor substrate 152, the junction characteristics with the base region 10 can be improved.

At this time, in the drawing, the first conductive type region 20 is formed as a whole and has a homogeneous structure having a uniform doping concentration, and the second conductive type region 30 has a uniform structure. Thus, the area of the first and second conductivity type regions 20 and 30 can be sufficiently secured, and the first and second conductivity type regions 20 and 30 can be formed by a simple process. However, the present invention is not limited thereto. Thus, the first conductive type region 20 can be a uniform structure or a selective structure, and the second conductive type region 30 can have a uniform structure, an optional structure, or a local structure have. The selective structure has a high doping concentration, a large junction depth, and a low resistance in a portion adjacent to the first or second electrode 42 or 44 in the first or second conductivity type region 20 or 30, Doping concentration, small junction depth, and high resistance. In the selective structure, the contact resistance with the first or second electrode 42, 44 can be reduced, and the recombination characteristic can be improved. In the local structure, the second conductive type region 30 is formed locally at a portion adjacent to the second electrode 44. [ In the local structure, the short-circuit current (Jsc) and the open-circuit voltage can be improved by minimizing the area of the second conductivity type region 30 to reduce recombination. Various other structures can be applied.

Alternatively, at least one of the first and second conductivity type regions 20 and 30 may be formed separately from the semiconductor substrate 152 above the semiconductor substrate 152. In this case, a semiconductor layer (for example, an amorphous semiconductor layer, an amorphous semiconductor layer, or the like) having a crystal structure different from that of the semiconductor substrate 152 is formed so that the first or second conductivity type regions 20 and 30 can be easily formed on the semiconductor substrate 152, A microcrystalline semiconductor layer, or a polycrystalline semiconductor layer, for example, an amorphous silicon layer, a microcrystalline silicon layer, or a polycrystalline silicon layer). At this time, a separate layer (a tunneling layer, a passivation layer, etc.) may be formed between the first and second conductive regions 20 and 30 and the semiconductor substrate 152.

One of the first and second conductivity type regions 20 and 30 having a conductivity type different from that of the base region 10 constitutes at least a part of the emitter region. The emitter region forms a pn junction with the base region 10 to produce a carrier by photoelectric conversion. The other of the first and second conductivity type regions 20 and 30 having the same conductivity type as the base region 10 constitutes at least a part of a surface field region. The electric field region forms an electric field that prevents carriers from being lost by recombination on the surface of the semiconductor substrate 152. [ For example, in this embodiment, the base region 10 has a second conductivity type, the first conductivity type region 20 constitutes an emitter region, and the second conductivity type region 30 constitutes a rear electric field region can do. However, the present invention is not limited thereto.

In the present embodiment, various materials which can represent n-type or p-type can be used as the first or second conductivity type dopant. As the p-type dopant, a group III element such as boron (B), aluminum (Al), gallium (Ga), or indium (In) can be used. In the case of the n-type, Group 5 elements such as phosphorus (P), arsenic (As), bismuth (Bi) and antimony (Sb) can be used. For example, the p-type dopant may be boron (B) and the n-type dopant may be phosphorus (P).

For example, in this embodiment, the base region 10 and the second conductivity type region 30 may have an n-type and the first conductivity type region 20 may have a p-type. Then, the base region 10 and the first conductive type region 20 form a pn junction. When the pn junction is irradiated with light, electrons generated by the photoelectric effect move toward the rear surface of the semiconductor substrate 152, are collected by the second electrode 44, and the holes move toward the front surface of the semiconductor substrate 152, 1 electrode 42. In this case, Thereby, electric energy is generated. Then, holes having a slower moving speed than electrons may move to the front surface of the semiconductor substrate 152, thereby improving the efficiency. However, the present invention is not limited thereto, and it is also possible that the base region 10 and the second conductivity type region 30 have a p-type and the first conductivity type region 20 has an n-type.

The first passivation film 22 and / or the second passivation film 22 are formed on at least the front surface of the semiconductor substrate 152 (more precisely, on the first conductive type region 20 formed on the front surface of the semiconductor substrate 152) Barrier film 24 may be located. And a second passivation film 32 as a second insulating film may be located at least on the rear surface of the semiconductor substrate 152 (more precisely on the second conductive type region 30 formed on the rear surface of the semiconductor substrate 152) have. The first passivation film 22 and the second passivation film 32 may be formed in contact with the semiconductor substrate 152 and / or the antireflection film 24 may be formed in contact with the first passivation film 22 . Then, the structure can be simplified. However, the present invention is not limited thereto.

The first passivation film 22 and the antireflection film 24 may be formed entirely on the front surface of the semiconductor substrate 152 substantially except for the first opening 102. [ The second passivation film 32 may be formed entirely on the rear surface of the semiconductor substrate 152 except for the second opening 104.

The first passivation film 22 or the second passivation film 32 is formed in contact with the semiconductor substrate 152 to passivate defects present in the front surface or bulk of the semiconductor substrate 152. Accordingly, it is possible to increase the open-circuit voltage of the solar cell 150 by removing recombination sites of the minority carriers. The antireflection film 24 reduces the reflectance of light incident on the front surface of the semiconductor substrate 152, thereby increasing the amount of light reaching the pn junction. Accordingly, the short circuit current Isc of the solar cell 150 can be increased.

The first passivation film 22, the antireflection film 24, and the second passivation film 32 may be formed of various materials. In one example, the first passivation film 22, the anti-reflection film 24 or the passivation film 32 is a silicon nitride film, a silicon nitride film containing hydrogen, silicon oxide, silicon nitride oxide, aluminum oxide film, a silicon carbide film, MgF _2, ZnS , TiO _2, and CeO ₂ , or a multi-layer structure in which two or more films are combined.

For example, in the present embodiment, the first passivation film 22 and / or the antireflection film 24 and the second passivation film 32 may not have a dopant or the like so as to have excellent insulating properties, passivation properties, and the like . However, the present invention is not limited thereto.

The first electrode 42 is formed by filling at least a portion of the first opening 102 and is electrically connected to the first conductive region 20 2 opening portion 104 and is electrically connected to (e.g., formed in contact with) the second conductive type region 30. [0050] The first and second electrodes 42 and 44 are made of various conductive materials (for example, metal) and may have various shapes.

Referring to FIG. 4, the first electrode 42 may include a plurality of finger electrodes 42a spaced apart from each other with a predetermined pitch. Although the finger electrodes 42a are parallel to each other and parallel to the edge of the semiconductor substrate 152, the present invention is not limited thereto. The first electrode 42 may include a bus bar electrode 42b formed in a direction crossing (for example, orthogonal to) the finger electrodes 42a and connecting the finger electrodes 42a. Only one bus bar electrode 42b may be provided or a plurality of bus bar electrodes 42b may be provided with a larger pitch than the pitch of the finger electrodes 42a as shown in FIG. At this time, the width of the bus bar electrode 42b may be larger than the width of the finger electrode 42a, but the present invention is not limited thereto. Therefore, the width of the bus bar electrode 42b may be equal to or smaller than the width of the finger electrode 42a.

The finger electrode 42a and the bus bar electrode 42b of the first electrode 42 may both be formed through the first passivation film 22 and the antireflection film 24 which are the first insulating film . That is, the first opening 102 may be formed corresponding to both the finger electrode 42a and the bus bar electrode 42b of the first electrode 42. [ However, the present invention is not limited thereto. As another example, the finger electrode 42a of the first electrode 42 may be formed through the first insulating film, and the bus bar electrode 42b may be formed on the first insulating film. In this case, the first opening 102 is formed in a shape corresponding to the finger electrode 42a, and may not be formed in a portion where only the bus bar electrode 42b is located.

The second electrode 44 may include a finger electrode and a bus bar electrode corresponding to the finger electrode 42a and the bus bar electrode 42b of the first electrode 42, respectively. The finger electrode 42a and the bus bar electrode 42b of the first electrode 42 may be directly applied to the finger electrode and the bus bar electrode of the second electrode 44. [ At this time, the content of the first passivation film 22 and the antireflection film 24 which are the first insulating film in the first electrode 42 is transferred from the second electrode 44 to the second passivation film 34 which is the second insulating film Can be applied. The width and pitch of the finger electrode 42a and the bus bar electrode 42b of the first electrode 42 may be the same as the width and pitch of the finger electrode and the bus bar electrode of the second electrode 44, .

However, the present invention is not limited thereto, and the first electrode 42 and the second electrode 44 may have different planar shapes, and various other modifications are possible.

As described above, in this embodiment, the first and second electrodes 42 and 44 of the solar cell 150 have a certain pattern, so that the solar cell 150 can be incident on the front and rear surfaces of the semiconductor substrate 152 It has a double-sided light-receiving structure. Accordingly, the amount of light used in the solar cell 150 can be increased to contribute to the efficiency improvement of the solar cell 150.

In the above description, an example of the solar cell 150 has been described with reference to Figs. 3 and 4. Fig. However, the present invention is not limited thereto, and the structure, mode, etc. of the solar cell 150 may be variously modified. For example, the solar cell 150 may be a photoelectric conversion unit having various structures such as using a compound semiconductor or using a dye sensitized material.

Referring again to FIGS. 1 and 2, a plurality of solar cells 150 are provided in this embodiment, and a plurality of solar cells 150 are electrically connected in series, parallel, or series-parallel by an interconnector 142 . Various shapes and shapes for connecting the solar cell 150 such as a ribbon and a wire can be applied to the inductor connector 142. The present invention is not limited to the number of the interconnectors 142 used in each solar cell 150, Do not.

3 and 4) formed on the front surface of the solar cell 150 and a second electrode (not shown in FIG. 3 and FIG. 4, hereinafter the same) formed on the rear surface of another adjacent solar cell 150. Specifically, Electrodes (44 in Fig. 3 and Fig. 4, the same applies hereinafter) can be connected by a tabbing process. In the tableting process, the interconnector 142 may be attached to the electrodes 42 and 44 of the solar cell 150 using a solder material.

Alternatively, a conductive film (not shown) may be attached between the solar cell 150 and the interconnector 142, and then the plurality of solar cells 150 may be connected in series or in parallel by thermocompression bonding. The conductive film (not shown) may be formed by dispersing electrically conductive particles formed of gold, silver, nickel, copper or the like having excellent conductivity in a film formed of an epoxy resin, an acrylic resin, a polyimide resin, a polycarbonate resin or the like. When the conductive film is compressed while being heated, the conductive particles are exposed to the outside of the film, and the solar cell 150 and the interconnector 142 can be electrically connected by the exposed conductive particles. When a plurality of solar cells 150 are modularized by the conductive film (not shown), the process temperature can be lowered, and warpage of the solar cell 150 can be prevented.

The bus ribbon 145 alternately connects both ends of the interconnect 142 of one row of solar cells 150 (i.e., solar cell strings) connected by the interconnect 142. The bus ribbons 145 may be arranged in the direction intersecting the ends of the solar cells 150 forming one row. The bus ribbon 145 may be connected to a junction box (not shown) that collects electricity generated by the solar cell 150 and prevents electricity from flowing backward.

However, the present invention is not limited thereto, and the connection structure between the solar cells 150, the connection structure between the solar cell 150 and the outside may be variously modified. Also, it is possible that the solar cell panel 100 is composed of one solar cell 150 without a plurality of solar cells 150.

The front substrate 110 is positioned on the first sealing material 131 to constitute the front surface of the solar cell panel 100 as another part of the front surface FP and the rear substrate 120 is disposed on the second sealing material 132 And constitutes the rear surface of the solar cell 150 as another part of the rear surface RP. At this time, in the present embodiment, the rear portion RP of the solar cell panel 100 has ultraviolet transmittance and ultraviolet rays are transmitted. In addition, the front panel FP of the solar panel 100 has UV transmittance, so that ultraviolet rays can be transmitted.

Here, having ultraviolet transmittance means that the transmittance of the rear portion (RP) or the front portion (FP) is 20% or more with respect to light having a wavelength of 300 nm to 400 nm. Here, the transmittance for light having a wavelength of 300 nm to 400 nm may be based on the lowest transmittance among all the transmittances for a wavelength of 300 nm to 400 nm. (For example, 20% to 100%) of light having a wavelength of 300 to 400 nm corresponding to ultraviolet rays is involved in photoelectric conversion of the solar cell 150 to improve the efficiency and output of the solar cell 100 It is based on this. As an example, the transmittance of the back surface portion (RP) or the front surface portion (FP) may be 20% to 80% for light having a wavelength of 300 nm to 400 nm.

When the rear portion RP has UV transmittance, the light incident on the rear surface of the solar cell 100 to which the solar cell 150 having the both-side light-receiving structure is applied, as in the present embodiment, The photoelectric conversion can be further performed. Referring to FIG. 5 showing the relative intensity of the intensity of sunlight according to the wavelength of light, light having a wavelength of 300 nm to 400 nm has an area over a certain level in the total solar spectrum area of the total solar spectrum Able to know. Referring to FIG. 6 showing the quantum efficiency of the solar cell according to the wavelength of light, it can be seen that the photovoltaic conversion of the solar cell can also be caused by the light having the wavelength of 300 to 400 nm. The efficiency and the output of the solar cell panel 100 can be improved by further using ultraviolet rays that occupy a certain level or more in the solar spectrum among the light incident on the rear surface of the solar cell panel 100. [ In addition, the front portion (FP) has ultraviolet transmittance and ultraviolet rays incident on the front surface can be used together to maximize photoelectric conversion.

In the present embodiment, since the rear portion RP has ultraviolet transmittance, the second seal member 132 and the rear member 200 may have ultraviolet transmittance. This will be explained in more detail.

In the present embodiment, the back member 200 may be made of a resin sheet. Thus, the thickness and weight of the solar cell panel 100 can be minimized. At this time, the rear member 200 may be transparent. For example, the backing member 200 may have a light transmittance of 80% or more (for example, 80% to 100%) with respect to light in the visible light region. For example, the backing member 200 does not include a separate pigment and can be transparent. The ultraviolet ray transmittance of the rear member 200 can be further improved

Here, the backing member 200 may include an ultraviolet stabilizer (UVS) and may not include a sunscreen agent. According to this, the rear member 200 does not include an ultraviolet ray blocking agent and can transmit ultraviolet rays, but can prevent problems such as deterioration that may occur due to transmission of ultraviolet rays including ultraviolet ray stabilizer (UVS).

The rear member 200 according to the present embodiment includes a first resin layer 221 located on the second sealing material 132 and a second resin layer 221 located on the first resin layer 221, And a second resin layer 222 disposed on the base member 210. The second resin layer 222 may be formed on the base member 210, A first adhesive layer 231 for bonding the first resin layer 221 to the base member 210 and a second adhesive layer 232 for bonding the base member 210 and the second resin layer 222 can do. However, depending on the materials and / or characteristics of the first resin layer 221 and the base member 210, the second resin layer 222 may or may not be included. The first resin layer 221 and the first and second resin layers 221 and 222 may be formed of an adhesive material in at least one of the base member 210, the first resin layer 221 and the second resin layer 222, 2 resin layers 221 and 222 may be coated. In this case, the first and / or second adhesive layers 231 and 232 may not be provided.

First, the base member 210, the first resin layer 221 and the second resin layer 222, and the first adhesive layer 231 and the second adhesive layer 232 are described in detail. Then, a UV stabilizer (UVS) The ultraviolet screening agent will be described in detail.

The first resin layer 221 positioned (for example, in contact with) the second sealing material 132 is a layer for adhesion with the second sealing material 132. The bonding strength with the second sealing member 132 is higher than that of the base member 210 and / or the second resin layer 222 (particularly, the base member 210). In consideration of this, the first resin layer 221 may include a fluoro polymer or a polyolefin-based material as a base material. As used herein, the term " base material " means a material containing the most weight percentages in each layer. The fluorine-based polymer will be described in detail later in the second resin layer 222. The first resin layer 221 can use the same fluorine-based material as the second resin layer 222 to improve the durability and reliability of the rear member 200. Alternatively, the first resin layer 221 may include a polyolefin-based material to reduce the material cost of the rear member 200. Examples of the polyolefin-based material that can be contained in the first resin layer 221 include ethylene-vinyl acetate (EVA), polyethylene (PE), and polypropylene (PP).

The base member 210 positioned (e.g., in contact with) the first resin layer 221 can serve as a base member for supporting the first resin layer 221 and / or the second resin layer 222 have. And the base member 210 may have an excellent insulating property to improve the insulating property of the rear member 200. For this purpose, the base member 210 has better insulating properties than the first resin layer 221 and / or the second resin layer 222 and can have a high mechanical strength. For example, the base member 210 may comprise a resin, and may include, for example, polyamide or polyester as a base material. The polyester is excellent in protecting the solar cell 150 because of its excellent mechanical properties, thermal characteristics, electrical characteristics, formability, chemical resistance and the like.

For example, the polyester may be a conventional polyester or an aqueous polyester. In general, when the polyester is used for a long period of time, mechanical properties may be deteriorated due to hydrolysis. In view of this, I can use an aqueous polyester. The aqueous polyester can be prepared by adding various materials (for example, phosphates of alkali metals or alkaline earth metals, inorganic ginseng salts, or the like, or suitable oligomers) to the polyester to reduce hydrolysis. Or by controlling the molecular weight of the polyester, or the like. In this case, the molecular weight of the aqueous polyester can be approximately 8,000 to 10,000. Various films, sheets and the like known as a general polyester (having a molecular weight of about 6,000 to 8,000) or a base member 210 containing an aqueous polyester can be used.

At this time, the polyester may include polyethylene terephthalate (PET). Polyethylene terephthalate is a saturated polyester resin obtained by a condensation reaction of terephthalic acid and ethylene glycol, and is excellent in heat resistance, weather resistance, insulation, and mechanical strength. In particular, the molding shrinkage rate is as small as about 0.1% to 0.6%, and it is possible to prevent the rear member 200 from being deformed by heat.

As the base member 210, there can be used a sheet-like (or film-like) sheet made of the above-mentioned resin by various methods. However, the present invention is not limited thereto, and the base member 210 may be manufactured by various methods.

The second resin layer 222 positioned (e.g., in contact with) the base member 210 is a layer constituting the outer surface of the solar cell panel 100 and has excellent environmental resistance (i.e., stability against heat and moisture, Durability) can be constructed. That is, the heat and moisture stability of the second resin layer 222 and the durability against ultraviolet rays can be controlled by the heat of the first resin layer 221 and / or the base member 210 (particularly, the base member 210) And the durability against ultraviolet rays may be higher.

In consideration of this, the second resin layer 222 may include a fluorine-based polymer, a polyester (e.g., polyethylene terephthalate), or a polyolefin-based material as a base material. In particular, the second resin layer 222 may be formed of a fluorine resin such as polyvinyl fluoride (PVF), polyvinylidene fluoride (PVDF), ethylene tetrafluoroethylene (ETFE) It can be included as resin. The fluorine-based resin is excellent in weather resistance, chemical resistance and the like since it does not have a bond that may cause hydrolysis. Particularly, polyvinylidene fluoride is a polymer having a structure of (CH ₂ CF ₂ ) n and has a double fluorine molecular structure, and thus has excellent mechanical properties, weather resistance, chemical resistance and ultraviolet ray resistance. Alternatively, the second resin layer 222 may include a polyamide-based material as a base material. Various other base materials may be used for the second resin layer 222, and the present invention is not limited thereto.

The first and second resin layers 221 and 222 and the base member 210 may be transparent. For example, the first and second resin layers 221 and 222 and the base member 210 may each have a light transmittance of 80% or more (for example, 80% to 100%) with respect to light in the visible light region . For example, the first and second resin layers 221 and 222 and the base member 210 do not include separate pigments and may be transparent. The UV transmittance of the first and second resin layers 221 and 222 and the base member 210 can be further improved. The first and second resin layers 221 and 222 may be formed on the base member 210 by coating or lamination.

The first resin layer 221 and the second resin layer 222 may be made of the same material or different materials. At this time, the materials of the first resin layer 221 and the second resin layer 222 may be selected according to desired characteristics. For example, the first resin layer 221 may include a polyolefin-based material having a relatively low cost, and the second resin layer 222 may include a fluoropolymer having excellent environmental resistance.

For example, the first resin layer 221 may have a thickness of 5 to 250 mu m. If the thickness of the first resin layer 221 is less than 5 μm, the adhesion between the first resin layer 221 and the second sealing material 132 may not be excellent. If the thickness of the first resin layer 221 exceeds 250 μm The material cost may increase and the thickness of the solar cell panel 100 may increase. And the thickness of the base member 210 may be 30 to 400 mu m. If the thickness of the base member 210 is less than 30 탆, it may be difficult to have sufficient insulating properties, moisture barrier properties and mechanical strength. If the thickness of the base member 210 exceeds 400 袖 m, handling is inconvenient, material cost increases, and the thickness of the solar cell panel 100 may become thick. And the thickness of the second resin layer 222 may be 0 to 60 탆. Since the material of the second resin layer 222 is expensive due to the use of a material having excellent ultraviolet durability, the second resin layer 222 can be formed to have a thickness of 60 μm or less, thereby reducing the cost. Since the second resin layer 222 is not essential, it may not include the second resin layer 222, which will be described later in detail.

Alternatively, the thickness of the base member 210 may be greater than the thickness of the first resin layer 221 and the second resin layer 222, respectively. The thickness of the second resin layer 222 may be equal to or less than the thickness of the first resin layer 221. This is because the second resin layer 222 having high durability by ultraviolet rays has a relatively thick material so that the base member 210 has a sufficient thickness to support the rear member 200, To reduce material costs. However, the present invention is not limited thereto, and the thicknesses of the base member 210, the first resin layer 221, and the second resin layer 222 may be variously modified.

The first adhesive layer 231 and the second adhesive layer 232 which are located between the first resin layer 221 and the base member 210 or between the base member 210 and the second resin layer 222 and adhere them are bonded The material may be included as a base material. For example, as an adhesive material, polyurethane-based or acrylic-based adhesive materials having excellent adhesive properties and low material cost can be used. However, the present invention is not limited thereto and various adhesive materials can be used.

The thickness of the first and / or second adhesive layers 231 and 232 may be smaller than the base member 210 serving as the base member and the thickness of the first resin layer 221 and / or the second resin layer 222 ( (Particularly, the first resin layer 221). This is because the first or second adhesive layer 231 or 232 has only a thickness enough to have adhesive properties. In one example, the thickness of the first and / or second adhesive layers 231 and 232 may be between 3 um and 30 um. If the thickness of the first and / or second adhesive layers 231 and 232 is less than 3 μm, the adhesive properties of the first and / or second adhesive layers 231 and 232 may be deteriorated. If the thickness of the first and / or second adhesive layers 231 and 232 exceeds 30 mu m, the thickness of the backing member 200 may become thick and the material cost may increase. However, the present invention is not limited thereto and various modifications are possible.

However, as described above, since the base member 210, the first and second resin layers 221 and 222 may have various thicknesses, the present invention is not limited thereto. The thickness of the first and / or second adhesive layers 231 and 232 may be equal to or greater than the thickness of the base member 210, the first and second resin layers 221 and 222, and so on. In one example, the backing member 200, which is made of a resin sheet, may have a thickness of 35 to 1000um (for example, 100um to 1000um).

In the present embodiment, at least one of the plurality of layers constituting the rear member 200 includes a UV stabilizer (UVS), and all the layers constituting the rear member 200 may not include a UV blocking agent. That is, at least one of the base member 210, the first resin layer 221, the second resin layer 222, the first adhesive layer 231, and the second adhesive layer 232 includes a UV stabilizer (UVS) The base resin 210, the first resin layer 221, the second resin layer 222, the first adhesive layer 231 and the second adhesive layer 232 constituting the rear member 200 do not contain a sunscreen agent .

For example, UV stabilizers (UVS) may include hindered amine materials. The hindered amine-based material can quickly stabilize the radicals generated by the ultraviolet irradiation, and can effectively prevent problems such as changes in properties and deterioration of the rear member 200 due to ultraviolet rays.

UV stabilizers (UVS) include bis (2,2,6,6-tetramethyl-4-piperidyl) sebacate, bis- (N-octyloxytetramethyl) piperidinyl sebacate, bis (1,2,2,6,6-pentamethyl-4-piperidyl) sebacate (N-octyloxytetramethyl) piperidinyl sebacate bis (1,2,2,6,6-pentamethyl-4-piperidyl) sebacate, methyl-1,2,2,6,6-pentamethyl-4-piperidyl sebacate , 6,6-pentamethyl-4-piperidyl sebacate), and the like. However, the present invention is not limited thereto, and ultraviolet stabilizer (UVS) composed of various materials can be used.

At this time, when the total amount of the layer containing the ultraviolet stabilizer (UVS) is 100 parts by weight, ultraviolet stabilizer (UVS) may be included in an amount of 0.2 to 5 parts by weight. That is, for example, when the ultraviolet stabilizer (UVS) is included in the first adhesive layer 231, ultraviolet stabilizer (UVS) may be included in an amount of 0.2 to 5 parts by weight based on 100 parts by weight of the entire first adhesive layer 231. This can be uniformly dispersed in a layer containing UV stabilizer (UVS) and is limited to the content for realizing the effect of ultraviolet stabilizer (UVS), but the present invention is not limited thereto.

The ultraviolet screening agent may be composed of various materials capable of blocking ultraviolet rays. For example, the backing member 200 according to the present embodiment (more specifically, all layers constituting the backing member 200) may not include a sunblocking agent composed of a benzophenone based material or a benzotriazole based material .

In this embodiment, at least one of the first adhesive layer 231 and the second adhesive layer 232 may include a UV stabilizer (UVS). That is, the base member 210, the first and second resin layers 221 and 222 do not include the adhesive material and the ultraviolet stabilizer (UVS), and the first and second adhesive layers 231 and 232 are made of the adhesive material and the ultraviolet ray Stabilizers (UVS). Thus, the properties of the first and second resin layers 221 and 222 can be prevented from deteriorating. For example, if the ultraviolet stabilizer (UVS) is included in the first resin layer 221 adjacent to the sealing material 130, the adhesion of the UVS to the second sealing material 132 may be deteriorated, Can be degraded. Since the second resin layer 222 located on the outer side is made of a material having excellent ultraviolet durability, it is not necessary to separately include a UV stabilizer (UVS).

The first and second adhesive layers 231 and 232 can be made in a state of adhesive mixture and applied on the base member 210 by a simple process of adding UV stabilizers (UVS) (UVS) may be included in the UV stabilizer. Further, the ultraviolet light stabilizer (UVS) is uniformly distributed on the first and second adhesive layers 231 and 232 formed to have a small thickness, thereby effectively preventing the problem caused by ultraviolet rays.

On the other hand, since the base member 210, the first and second resin layers 221 and 222 are supplied in the form of a film or a sheet, it is difficult to change the composition, so that the process may become complicated if they include a UV stabilizer (UVS).

Here, in this embodiment, the first adhesive layer 231 and the second adhesive layer 232 have the same composition and can have the same characteristics. Then, the first adhesive layer 231 and the second adhesive layer 232 may be formed using a mixture of the same adhesive material and a UV stabilizer (UVS), thereby simplifying the process and reducing the material cost. The same equipment, process conditions, and the like can be used by making the thicknesses of the first adhesive layer 231 and the second adhesive layer 232 substantially the same (for example, within a thickness difference of 10%). Then, the process can be simplified and the material cost can be further reduced. However, the present invention is not limited to this, and the composition and characteristics of the first adhesive layer 231 and the second adhesive layer 232 can be made different from each other.

In addition, in this embodiment, both the first and second adhesive layers 231 and 232 include an adhesive material and a UV stabilizer (UVS) to minimize the problem caused by ultraviolet rays. However, the present invention is not limited thereto, and UVS may be included in at least one of the first and second adhesive layers 231 and 232. For example, the first adhesive layer 231 may include an adhesive material and a UV stabilizer (UVS), and the second adhesive layer 232 may include an adhesive material but not a UV stabilizer (UVS). As another example, the second adhesive layer 232 may include an adhesive material and a UV stabilizer (UVS), and the first adhesive layer 231 may include an adhesive material but not an ultraviolet stabilizer (UVS). Thus, it is possible to prevent the layers located on the inner side of the second adhesive layer 232 from being deteriorated by ultraviolet rays from the rear member 200.

The first and / or second adhesive layers 231 and 232 described above may be manufactured by various methods and used in the manufacture of the backsheet 200 by various methods. For example, in order to form the first and / or second adhesive layers 231 and 232, an adhesive mixture may be prepared by mixing an adhesive material, a UV stabilizer (UVS), and other additives. Various methods known as mixing methods can be used.

The adhesive mixture thus prepared is coated on one side of the base member 210 to form a first adhesive layer 231 and laminated with heat and pressure in a state in which the first resin layer 221 in the form of a film or sheet is placed thereon The base member 210 and the first resin layer 221 are adhered to each other by the first adhesive layer 231. For example, when the printing method is used, the first adhesive layer 231 can be uniformly applied on one side of the base member 210, and the adhesive property can be further improved. Can be improved.

The adhesive mixture thus prepared is applied to the other surface of the base member 210 to form a second adhesive layer 232. The second resin layer 222 in the form of a film or sheet is placed on the second adhesive layer 232, The base member 210 and the second resin layer 222 are adhered to each other by the second adhesive layer 232. For example, if the printing method is used, the second adhesive layer 232 can be evenly applied on the other surface of the base member 210, Can be improved.

The first resin layer 221, the first adhesive layer 231, the base member 210, the second adhesive layer 232, and the second resin layer 222 are bonded to and joined to each other, 200). At this time, the first resin layer 221, the first adhesive layer 231, the base member 210, the second adhesive layer 232, and the second resin layer 222 are contacted with each other to form the structure of the rear sheet 200 Can be simplified. However, the present invention is not limited thereto, and various modifications are possible, for example, a separate layer is disposed between the two layers.

The first resin layer 221 is bonded to the base member 210 using the first adhesive layer 231 and then the second resin layer 222 is bonded to the base member 210 using the second adhesive layer 232. [ 220). However, the present invention is not limited to this order. The first resin layer 221 is bonded to the base member 220 using the first adhesive layer 231 after the second resin layer 222 is bonded to the base member 210 using the second adhesive layer 232. [ Or the like.

The first adhesive layer 231 is used to bond the first resin layer 221 to one surface of the base member 210 and the second adhesive layer 232 to the other surface of the base member 210 The step of adhering the second resin layer 222 can be performed separately to improve the adhesive properties of the first and second resin layers 221 and 222. [ However, the present invention is not limited to this, and the first and second adhesive layers 231 and 232 may be formed on both sides of the base member 210, and then the first and second resin layers 221 and 222 may be positioned, They may be adhered at once by applying pressure. Then, the manufacturing process of the back sheet 200 can be simplified. Various other variations are possible.

In this embodiment, the second sealing material 132 constituting another part of the rear portion RP may also have an ultraviolet permeability. The second sealant 132 may not include an ultraviolet screening agent and may include a UV stabilizer (UVS). However, the present invention is not limited thereto. When the ultraviolet light stabilizer (UVS) is contained in the rear member 200 and the problem caused by ultraviolet rays can be prevented, the second sealing member 132 does not include a UV stabilizer .

The second sealant 132 prevents moisture and oxygen from entering and chemically binds each element of the solar cell panel 100. The second sealant 132 may include an insulating material having translucency and adhesion as a base material, and may further include a UV stabilizer (UVS). For example, the second sealing material 132 may include an ethylene vinyl acetate resin (EVA), a polyvinyl butyral, a silicon resin, an ester resin, an olefin resin, a polyethylene resin, an ionomer, can do. As the ultraviolet stabilizer, the description of the ultraviolet stabilizer described in the back member 200 may be applied as it is.

For example, when the second sealing material 132 is 100 parts by weight, the ultraviolet stabilizer (UVS) may be included in an amount of 0.2 to 5 parts by weight. This is because the ultraviolet light stabilizer (UVS) can be uniformly dispersed in the second sealant 132 and the ultraviolet light stabilizer (UVS) effect is achieved. However, the present invention is not limited thereto.

 The second sealant 132 may be transparent. For example, the second sealant 132 may have a light transmittance of 80% or more (for example, 80% to 100%) with respect to light in the visible light region. For example, the second sealant 132 may be transparent because it does not include a separate pigment. As a result, ultraviolet transmittance of the second sealant 132 can be further improved.

In this embodiment, the front portion FP may also have ultraviolet transmittance. That is, the transmittance of the front part FP to light having a wavelength of 300 nm to 400 nm may be 20% or more. To this end, the front member 110 and the first sealing member 131 constituting the front portion FP may have ultraviolet transmittance.

The front member 110 and the first sealing member 131 may be transparent. For example, the front member 110 and the first sealing member 131 may have a light transmittance of 80% or more (for example, 80% to 100%) with respect to light in the visible light region. For example, the front member 110 and the first sealing member 131 may be transparent because they do not include separate pigments. As a result, ultraviolet light transmittance of the front panel FP can be further improved.

In one example, the front member 110 may comprise a glass substrate. Then, the front member 110 can have ultraviolet light transmittance due to high transparency or transparency of the glass substrate. If the front member 110 is formed of a glass substrate, the solar cell 150 can be protected with high safety due to its excellent translucency, durability, and insulation characteristics. By using the front member 110 made of a glass substrate and the rear member 200 made of a resin sheet, the thickness and weight can be reduced while improving the durability.

As the first sealing material 131, the base material described in the second sealing material 132 can be used as it is, and a detailed description thereof will be omitted. The first sealant 131 may contain an ultraviolet stabilizer (UVS) like the second sealant 132 and may not include a sunscreen agent. Thus, problems caused by ultraviolet rays can be minimized. For example, the first sealant 131 and the second sealant 132 may be made of the same material. However, the present invention is not limited thereto, and the first sealing material 131 may not include a UV stabilizer (UVS), or the first sealing material 131 may be composed of a material different from the second sealing material 132.

The solar cell panel 100 according to the present embodiment is formed by integrating the rear member 200, the second sealing member 132, the solar cell 150, the first sealing member 131, and the front member 110 by a lamination process or the like Can be formed.

In the present embodiment, when the solar cell 150 having a double-side light receiving structure is used because the rear portion FP has UV transmittance, ultraviolet rays incident on the rear surface can be used for photoelectric conversion. As a result, the rear portion FP does not contain an ultraviolet screening agent. Instead, at least one of the plurality of layers constituting the rear portion FP may include a UV stabilizer (UVS) to minimize or prevent problems caused by ultraviolet light.

In the above-described embodiments, UV stabilizers (UVS) are included in the second sealant 132 and the first and second adhesive layers 231 and 232 among the various layers of the rear member 200. However, the present invention is not limited thereto and various modifications are possible. Hereinafter, a solar cell panel according to another embodiment of the present invention will be described in detail with reference to FIGS. 7 to 10. FIG. Only a portion corresponding to the enlargement circle in Fig. 2 is shown in Figs. 7 to 10 for the sake of simplicity and clear illustration. Hereinafter, the same or similar portions as those of the above-described embodiments may be applied to the above description, and thus detailed description will be omitted and only different portions will be described in detail. It is also within the scope of the present invention to combine the above-described embodiments or variations thereof with the following embodiments or modifications thereof.

7 is a partial enlarged view of a part of a solar cell panel according to another embodiment of the present invention.

Referring to FIG. 7, in this embodiment, the base member 210 and the first and second resin layers 221 and 222 each include a UV stabilizer (UVS). A layer having a relatively thick thickness may contain a UV stabilizer (UVS) so as to contain a sufficient amount of UV stabilizer (UVS) to minimize the problem of ultraviolet transmission. As a variant, it is also possible in this case not to include the first and second adhesive layers 231 and 232. Alternatively, as another variant, at least one of the first and second adhesive layers 231 and 232 may further comprise a UV stabilizer (UVS).

8 is a partial enlarged view of a part of a solar cell panel according to another embodiment of the present invention.

8, in this embodiment, the base member 210 and the first resin layer 221 each include a UV stabilizer (UVS) and the second resin layer 222 is omitted, The outer surface of the member 200 or the solar cell panel 100 may be formed. Since the base member 210 and the first resin layer 221 have superior ultraviolet durability, the second resin layer 222 for improving ultraviolet durability can be omitted, thereby simplifying the structure and reducing the material cost. As a variant, it is also possible in this case not to include the first adhesive layer 231. Alternatively, the first adhesive layer 231 may further include a UV stabilizer (UVS).

9 is a partial enlarged view of a part of a solar cell panel according to another embodiment of the present invention.

9, in this embodiment, the base member 210, the first adhesive layer 231, and the first resin layer 221 each include a UV stabilizer (UVS).

In this way, at least one of the plurality of layers constituting the rear member 200 may include UV stabilizers (UVS). That is, the present invention is not limited to which layer of the plurality of layers constituting the backing member 200 contains UV stabilizer (UVS). (UVS) are contained in the plurality of layers constituting the backing member 200, the different layers may contain the same ultraviolet stabilizer (UVS) and may contain different ultraviolet stabilizers have.

10 is a partial enlarged view of a part of a solar cell panel according to another embodiment of the present invention.

Referring to FIG. 10, in the present embodiment, the rear member 200 may be composed of a glass substrate (for example, a single glass substrate). When the rear member 200 includes a glass substrate, the rear member 200 may have ultraviolet light transmittance due to the high translucency or transparency of the glass substrate. If the rear member 200 is formed of a glass substrate, the solar cell 150 can be protected with high safety due to its excellent translucency, durability and insulation characteristics. At this time, it is preferable that the second sealing material 132 does not contain a UV stabilizer so as to prevent a problem caused by ultraviolet rays.

Hereinafter, the present invention will be described in more detail with reference to experimental examples of the present invention. The examples of the present invention are for illustrating the present invention, but the present invention is not limited thereto.

Example 1

The solar cell panel was manufactured by integrating the rear member, the second sealing member, the double-sided light receiving solar cell, the first sealing member, and the front member by a lamination process. At this time, the first and second sealing materials used were ethylene vinyl acetate as a base material, and 1 part by weight of bis (2,2,6,6-tetramethyl-4-piperidyl) sebacate (bis , 6-tetramethyl-4-piperidyl) sebacate). The backing member is made of a base material made of polyethylene terephthalate as a base material, and 1 part by weight of bis (2,2,6,6-tetramethyl-4-piperidyl) sebacate a first resin layer made of polyamide as a base material and a fluorine-based polymer as a base material are formed by using first and second adhesive layers containing bis (2,2,6,6-tetramethyl-4-piperidyl) sebacate as ultraviolet stabilizers. And a second resin layer made of a base material. At this time, the backing member does not include a separate pigment.

Comparative Example 1

A solar cell panel was manufactured in the same manner as in Example 1, except that the first and second sealing members and the rear member did not contain a UV stabilizer, and the rear member used was a UV blocking agent and a white pigment.

The transmittance of the back surface according to Example 1 and Comparative Example 1 was measured and the results are shown in Fig. Rear power, rear power and total power generation according to Example 1 and Comparative Example 1 were measured, and the value of Comparative Example 1 was set as 100% in Table 1, and the relative value was described as the value of Example 1. At this time, a plurality of solar cell panels according to Example 1 were manufactured and measured, and a plurality of solar cell panels according to Comparative Example 1 were manufactured and measured. In Comparative Example 1, average values of a plurality of solar cell panels were described. In Example 1, values of a plurality of solar cells are described as ranges. Here, the rear output and the rear power generation amount are measured in a state in which light is not incident on the front portion but only light is incident on the rear portion, and the total power generation amount is measured in a state where light is incident on both the front portion and the rear portion.

Example 1 Comparative Example 1 Rear Output [%] 101 ~ 103 100 Rear power generation [%] 101 ~ 103 100 Total power generation [%] 100.5 to 102 100

Referring to FIG. 11, it can be seen that the transmittance of the rear portion of the first embodiment is as high as 80% or more, whereas the transmittance of the rear portion of Comparative Example 1 is as low as about 0%.

Referring to Table 1, it can be seen that Example 1 has higher rear power, rear power generation and total power generation than Comparative Example 1. According to this, it can be seen that the output and efficiency of the solar cell panel can be improved by using the rear portion which can transmit ultraviolet rays to the solar cell panel to which the solar cell of the double-side light receiving structure is applied.

Features, structures, effects and the like according to the above-described embodiments are included in at least one embodiment of the present invention, and the present invention is not limited to only one embodiment. Further, the features, structures, effects, and the like illustrated in the embodiments may be combined or modified in other embodiments by those skilled in the art to which the embodiments belong. Therefore, it should be understood that the present invention is not limited to these combinations and modifications.

100: Solar panel
110: front member
131: first sealing material
132: second sealing material
200: rear member
210: Base member
221: first resin layer
222: second resin layer
231: first adhesive layer
232: second adhesive layer
UVS: UV stabilizer

Claims (18)

Double-sided light-receiving solar cells;
A front member positioned on a front surface of the double-sided light receiving type solar cell; And
The back surface member positioned on the rear surface of the double-
Lt; / RTI >
Wherein the rear member comprises a base member, a first resin layer located on one side of the base member, a second resin layer located on the other side of the base member, and a second resin layer located on the other side of the base member, A first adhesive layer for bonding the first resin layer and a second adhesive layer for bonding the base member and the second resin layer between the base member and the second resin layer,
Wherein at least one of the first adhesive layer and the second adhesive layer comprises an ultraviolet stabilizer. The method according to claim 1,
Wherein the rear member does not include an ultraviolet screening agent and has ultraviolet transmittance. 3. The method of claim 2,
And a transmittance of the rear member to light having a wavelength of 300 nm to 400 nm is 20% or more. 3. The method of claim 2,
Wherein the base member, the first resin layer, the second resin layer, the first adhesive layer, and the second adhesive layer each do not include an ultraviolet screening agent. The method according to claim 1,
Wherein at least one of the first adhesive layer and the second adhesive layer including the ultraviolet stabilizer comprises a hindered amine material as an ultraviolet stabilizer and a benzophenone based material or a benzotriazole based material as an ultraviolet shielding agent Does not have solar panels. 6. The method of claim 5,
Wherein at least one of the first adhesive layer and the second adhesive layer including the ultraviolet stabilizer is bis (2,2,6,6-tetramethyl-4-piperidyl) sebacate as an ultraviolet stabilizer, 6,6-tetramethyl-4-piperidyl sebacate, bis- (N-octyloxytetramethyl) piperidinyl sebacate, bis (1,2,2,6) , 6-pentamethyl-4-piperidyl sebacate, bis (1,2,2,6,6-pentamethyl-4-piperidyl) sebacate, Methyl-4-piperidyl sebacate (methyl 1,2-diol sebacate). The method according to claim 1,
Wherein the base member, the first resin layer, and the second resin layer do not contain a UV stabilizer. The method according to claim 1,
Wherein at least one of the first adhesive layer including the ultraviolet stabilizer and the second adhesive layer includes 100 parts by weight of the ultraviolet light stabilizer, wherein the ultraviolet light stabilizer is contained in an amount of 0.2 to 5 parts by weight, panel. The method according to claim 1,
Wherein the base member comprises a polyamide or polyester as a base material,
The first resin layer may include a fluoro polymer or a polyolefin based material as a base material,
Wherein the second resin layer comprises a fluorine-based polymer, a polyester or a polyolefin-based material as a base material. 10. The method of claim 9,
Wherein the first resin layer comprises at least one of ethylene vinyl acetate (EVA), polyethylene (PE), and polypropylene (PP)
Wherein the second resin layer comprises one of polyvinyl fluoride (PVF), polyvinylidene fluoride (PVDF), and ethylene tetrafluoroethylene (ETFE). The method according to claim 1,
The second resin layer is located on the outer surface of the base member, the first resin layer is located on the inner surface of the base member,
The thickness of the base member is larger than the thickness of the first resin layer and the second resin layer,
Wherein the thickness of the second resin layer is equal to or less than the thickness of the first resin layer. The method according to claim 1,
Wherein the first adhesive layer or the second adhesive layer comprises a polyurethane-based or acrylic-based adhesive material as a base material. The method according to claim 1,
Wherein the thickness of the first and second adhesive layers is smaller than that of each of the base member, the first resin layer, and the second resin layer. The method according to claim 1,
Wherein the first adhesive layer and the second adhesive layer each comprise an ultraviolet stabilizer. The method according to claim 1,
A first sealing material disposed between the double-side light-receiving solar cell and the front surface member; And
And a second sealing material disposed between the double-side light-receiving solar cell and the rear surface member
Further comprising:
Wherein the front member, the first sealing member, and the second sealing member each have ultraviolet transmittance. 16. The method of claim 15,
Wherein at least one of the first sealing material and the second sealing material includes an ultraviolet stabilizer and does not include a sunscreen agent. 16. The method of claim 15,
Wherein the front substrate is a glass substrate. 16. The method of claim 15,
Wherein the second sealing material comprises ethylene vinyl acetate as a base material.

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