KR20180090945A - Ball type deodorization and Air freshener used diatomite - Google Patents

Ball type deodorization and Air freshener used diatomite Download PDF

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Publication number
KR20180090945A
KR20180090945A KR1020170015873A KR20170015873A KR20180090945A KR 20180090945 A KR20180090945 A KR 20180090945A KR 1020170015873 A KR1020170015873 A KR 1020170015873A KR 20170015873 A KR20170015873 A KR 20170015873A KR 20180090945 A KR20180090945 A KR 20180090945A
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present
diatomite
diatomaceous earth
deodorant
ball type
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KR1020170015873A
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Korean (ko)
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김경태
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김경태
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/01Deodorant compositions
    • A61L9/014Deodorant compositions containing sorbent material, e.g. activated carbon
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2209/00Aspects relating to disinfection, sterilisation or deodorisation of air
    • A61L2209/20Method-related aspects
    • A61L2209/22Treatment by sorption, e.g. absorption, adsorption, chemisorption, scrubbing, wet cleaning

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  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Epidemiology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

The present invention is a deodorant containing diatomite as a main component. More specifically, the present invention relates to a molded article for indoor deodorization, having excellent functions as an eco-friendly material which has a cured structure without chemical adhesives used therein. The present invention further relates to a deodorant using the same. The diatomite-based deodorizable molded article provided in the present invention is composed of 60% of diatomite, 10% of gypsum powder, 15% of white cement, 10% of general flour paste, and 5% of a powdered resin.

Description

규조토를 이용한 볼타입 탈취 및 방향제{Ball type deodorization and Air freshener used diatomite}[0001] The present invention relates to a ball type deodorization and air freshener used diatomite,

본 발명은 규조토를 주성분으로 하는 볼 타입 탈취제로서 화학 접착제를 사용하지 않는 경화 구조로 이루어지는 친환경 소재로 기능이 우수하여 실내 탈취 개선에 기여하는 성형물과 이를 이용한 탈취제에 관한 것이다.The present invention relates to a ball-type deodorant comprising diatomaceous earth as a main component and an eco-friendly material having a cured structure that does not use a chemical adhesive.

최근 실내 탈취제에 대한 관심이 많이 대두되고, 법령의 제·개정 등으로 거주 공간의 실내 환경 향상이 이루어지고 있다. 하지만 아직도 화학제품을 주재료로 만들어진 탈취제가 만연하게 사용되어지고 있다. 휘발성 유기 화합물을 방출하는 접착제의 사용이 많고 불연 성능이 떨어지는 문제점이 있다. 더불어 밀폐된 실내 구조 속에서 화학제품에 노출되어 생활하는 경우가 많아 건강상 문제 및 환경오염까지 이어지고 있다. 이로서 쾌적한 생활환경이 유지되는 못하는 경우가 많다. In recent years, there has been much interest in indoor deodorant, and improvement of the indoor environment of the living space has been made by revising and revising laws and regulations. However, deodorants, which are made of chemical-based materials, are still being used extensively. There is a problem that the use of an adhesive releasing a volatile organic compound is large and the flame retardant performance is poor. In addition, since it is often exposed to chemical products in a closed indoor structure, health problems and environmental pollution are continuing. There are many cases where a pleasant living environment can not be maintained.

그리고 이러한 사회적 관심에 부응하여 천연 탈취제 제조를 목적으로 본 발명품을 개발하였다. In response to this social interest, the present invention was developed for the purpose of producing natural deodorant.

본 발명은 상기한 종래의 기술을 해결하고자 다공성의 규조토를 주재료로 사용하고, 결합재로서 화학 접착제를 사용하지 않고 성형물 가공 시 밀가루 풀을 이용하여 접착제로 사용하여 성형물을 결합하였다. 친환경의 결합재를 주요 경화구조로 하면서 친환경 소재로 조성되어 탈취, 조습기능을 가지게 됨으로서 실내 환경 개선에 기여하는 규조토 탈취제 성형물을 제공하는 것이다.In order to solve the above conventional art, porous diatomaceous earth is used as a main material, and a molding material is bonded using a flour paste as an adhesive without using a chemical adhesive as a binder. The present invention provides a molded article of a diatomaceous earth deodorant contributing to the improvement of the indoor environment by having an eco-friendly binding material as a main curing structure and being formed of an eco-friendly material and having a deodorizing and humidity control function.

상기의 목적을 달성하기 위한 본 발명의 기술적 방법은 규조토 60%, 석고가루 10%, 백시멘트 15%, 일반 밀가루 풀 10%, 분말수지 5%로 이루어지는 것을 특징으로 하는 탈취제이다.In order to achieve the above object, the technical method of the present invention is a deodorant comprising 60% of diatomaceous earth, 10% of gypsum powder, 15% of white cement, 10% of general flour paste, and 5% of powdered resin.

본 발명의 의해 제조된 성형물은 규조토를 주재료로 하고 탈취에 기여하며 모든 첨가제가 친환경 자제이므로 인체에 무해, 환경오염에 저해되는 요소가 없다.The molded product produced by the present invention is mainly made of diatomaceous earth and contributes to deodorization. Since all the additives are eco-friendly, there is no harmful substance to the human body and no obstacle to environmental pollution.

본 발명의 주성분인 규조토는 이미 널리 알려져 있고 산업적으로 유용하게 사용되어져 오고 있다. 이러한 규조토는 식물성 플랑크톤인 규조류의 단세포 생물이 퇴적하여 암석화한 것으로 SiO2가 80% 이상이며, 미세 기공으로 이루어진 경량의 천연 광물이다. 이러한 규조토의 특성으로 산업적으로 여과조제, 단열재, 흡수제로 이용되고 건축용으로는 유해 가스의 흡착·분해 및 탈취 성능을 이용하거나 불연이나 경량 및 친환경의 건축 소재의 재료 등으로 활용되고 있다. Diatomaceous earth, which is a main component of the present invention, has been widely known and has been industrially useful. These diatomaceous earths are lightweight natural minerals composed of micropores with more than 80% of SiO 2 , which is formed by the deposition of monocellular organisms of phytoplankton, monosized organisms. This diatomaceous earth is used industrially as a filter aid, insulation, and absorbent, and it is used for building use of absorption, decomposition and deodorization of noxious gas, and as a material of fireproof, lightweight and eco-friendly building material.

일반적으로 규조토는 채광을 하여 선별, 분쇄를 한 뒤 소성 과정을 거치면서 수분, 불순물을 재거하고 시용에 적합한 입도로 가공하는 과정으로 제조된다. 이렇게 가공된 규조토 분말은 산지나 용도에 따라 물리적 성능이 달라지는데 본 발명에 적합한 규조토는 최적의 성능을 발현하기 위해 흡수율이 180 ~ 250이고 평균입경이 50 ~ 80㎛인 규조토를 사용하는 것이 적합하다. 흡수율이 적을 경우는 규조토의 기본 특성인 공극이 적어서 그 활성도가 떨어지게 된다. 마찬가지로 입도가 너무 작아도 기공이 분쇄로 인해 사라지게 되어 본 발명에 적합한 성능을 충분히 나타내기 어렵게 된다. 규조토의 평균입경이 10 내지 100㎛인 것이 이용될 수 있는데 더욱 바람직하게는 50 ~ 80㎛인 것이 비표면적, 흡수율이 높아 유해 가스의 흡착·분해, 탈취 및 조습 기능이 뛰어나다.Generally, diatomaceous earth is produced by mining, screening and grinding, followed by sintering process to remove water and impurities, and processing to a suitable particle size for application. The diatomite powder thus processed has different physical properties depending on the place of production or use. In order to exhibit optimal performance, the diatomaceous earth suitable for the present invention is preferably a diatomaceous earth having an absorption rate of 180 to 250 and an average particle size of 50 to 80 탆. When the water absorption rate is low, the basic property of the diatomaceous earth is small and the activity thereof is lowered. Similarly, even if the particle size is too small, the pores disappear due to the pulverization, making it difficult to sufficiently exhibit the performance suitable for the present invention. The diatomaceous earth having an average particle diameter of 10 to 100 mu m can be used, more preferably 50 to 80 mu m, because it has a high specific surface area and a high water absorption rate, and is excellent in adsorption / decomposition, deodorization and humidity control of noxious gas.

상기 규조토의 조성은 50 ~ 65중량%가 바람직하다. 규조토의 사용량이 적으면 적을수록 본 발명에서 요구하는 성능이 떨어짐은 자명한 사실이다. 한편 65중량% 이상의 조성이 되면 피착재와의 접착력, 강도, 시공성이 나빠져 실내 탈취제로서의 내구성을 지속적으로 유지하기 어렵게 된다. The composition of the diatomite is preferably 50 to 65% by weight. It is obvious that the smaller the amount of diatomaceous earth used, the lower the performance required in the present invention. On the other hand, when the composition is at least 65% by weight, adhesion with the adherend, strength, and workability are deteriorated, making it difficult to continuously maintain durability as a room deodorant.

본 발명에 있어서 경화구조를 형성하는 조성물로서 규조토 60%, 석고가루 10%, 백시멘트 15%, 일반 밀가루 풀 10%, 분말수지 5%을 사용하는 것이 바람직하다.In the present invention, it is preferable to use 60% of diatomaceous earth, 10% of gypsum powder, 15% of white cement, 10% of general flour paste and 5% of powdered resin as a composition for forming a cured structure.

본 발명은 저탄소, 친환경 소재로서 본 발명에 적용된다. 또한 초기 경화를 확보하고 균열 방지를 위해 일체형 제환시스템 및 자동제환기로 성형한다The present invention is applied to the present invention as a low carbon, eco-friendly material. In addition, to ensure initial hardening and to prevent cracking, it is molded into an integral system and an automatic ventilation system

<< 실시예Example >>

실시예Example 1 One

규조토 60%, 석고가루 10%, 백시멘트 15%, 일반 밀가루 풀 10%, 분말수지 5%을 사용하는 것이 바람직하다. 통상에 혼합 믹싱기로 교반한다.It is preferable to use 60% of diatomaceous earth, 10% of gypsum powder, 15% of white cement, 10% of general flour paste, and 5% of powdered resin. Usually, the mixture is stirred with a mixing mixer.

미립제분 -> 혼합믹싱 -> 다량면장환 -> 다량환제환 -> 표면코팅화 -> 건조과정 -> 다양포장 을거쳐 제품을양산한다Granulated milling -> Mixing Mixing -> Large Quantity Cotton -> Large Quantity Circulation -> Surface Coating -> Drying Process -> Mass production of products through various packaging

실시예Example 2 2

규조토 60%, 석고가루 10%, 백시멘트 15%, 일반 밀가루 풀 10%, 분말수지 5%을 사용하는 것이 바람직하다.It is preferable to use 60% of diatomaceous earth, 10% of gypsum powder, 15% of white cement, 10% of general flour paste, and 5% of powdered resin.

제품설비로는 혼합믹싱기,장환기,제환기,컨베어밸트,건조기로 볼의 크기는 5~6미리 시편을 제작하여 그 결과를 이래에 표에 나타내었다 .The product equipments are mixed mixer, ventilator, ventilator, conveyor belt and drier. The size of the balls is 5 ~ 6mm and the results are shown in the table.

구 분division 실시예 1Example 1 실시예 2Example 2 비 고Remarks 초기 건조에 따른 내잔갈림성Haze after initial drying 이상없음clear 이상없음clear KS F 4715:2007KS F 4715: 2007 접착강도Adhesive strength N/㎟N / mm &lt; 2 & 0.60.6 0.50.5 항곰팡이 시험Antifungal test 00 00 ASTM G21:2013
혼합균주 5종, 4주 배양
ASTM G21: 2013
5 kinds of mixed strains, 4 weeks culture
폼알데하이드 탈취율Formaldehyde Deodorization Rate 30분30 minutes 85%85% 89%89% 조달청 MAS 등록 시험방법 조건
시험가스의 초기 농도,
폼알데하이드 : 20μmol/mol
암모니아 : 50μmol/mol
PPS MAS registration test method condition
The initial concentration of test gas,
Formaldehyde: 20 μmol / mol
Ammonia: 50 mu mol / mol
60분60 minutes 95%95% 99%99% 암모니아 탈취율Ammonia deodorization rate 30분30 minutes 88%88% 90%90% 60분60 minutes 96%96% 99%99% 총휘발성 유기화합물(TVOC)Total volatile organic compounds (TVOC) mg/㎡·hmg / m 2 · h 0.0140.014 0.0120.012 실내공기질 공정시험 기준
(환경부 고시 제2010-24호)
Indoor air quality process test standard
(Ministry of Environment Notice No. 2010-24)
톨루엔(Toluene)Toluene mg/㎡·hmg / m 2 · h 불검출Non-detection 불검출Non-detection 폼알데하이드(Formaldehyde)Formaldehyde mg/㎡·hmg / m 2 · h 0.0010.001 0.0010.001 열방출시험(총열방출량)Heat Release Test (Total Heat Emission) MJ/㎡MJ / ㎡ 2.22.2 1.91.9 KS F ISO 5660-1:2008KS F ISO 5660-1: 2008 열방출율이 연속으로 200KW/㎡를 초과하는 시간When the heat release rate exceeds 200 KW / m &lt; 2 &gt; continuously secsec 00 00

Claims (2)

규조토 60%, 석고가루 10%, 백시멘트 15%, 일반 밀가루 풀 10%, 분말수지 5%로 이루어지는 것을 특징으로 하는 탈취제이다.60% diatomaceous earth, 10% gypsum powder, 15% white cement, 10% general flour paste, and 5% powdered resin. 제 1항에 있어서 소성 규조토 1종 또는 2종 이상의 조합으로 이루어지는 것을 함유하는 탈취제이다.The deodorant according to claim 1, which is a deodorant containing one or two or more kinds of fired diatomite.
KR1020170015873A 2017-02-04 2017-02-04 Ball type deodorization and Air freshener used diatomite KR20180090945A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2806798A1 (en) * 2019-08-14 2021-02-18 Gonzalez Araceli Escribano Product with diatomaceous earth to absorb sweat (Machine-translation by Google Translate, not legally binding)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2806798A1 (en) * 2019-08-14 2021-02-18 Gonzalez Araceli Escribano Product with diatomaceous earth to absorb sweat (Machine-translation by Google Translate, not legally binding)

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