CN106188976A - The charcoal of a kind of active adsorption formaldehyde and purification air moulds anion sheet material and preparation method - Google Patents
The charcoal of a kind of active adsorption formaldehyde and purification air moulds anion sheet material and preparation method Download PDFInfo
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- CN106188976A CN106188976A CN201610699876.9A CN201610699876A CN106188976A CN 106188976 A CN106188976 A CN 106188976A CN 201610699876 A CN201610699876 A CN 201610699876A CN 106188976 A CN106188976 A CN 106188976A
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- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/001—Combinations of extrusion moulding with other shaping operations
- B29C48/0022—Combinations of extrusion moulding with other shaping operations combined with cutting
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
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- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
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- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
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- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92514—Pressure
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92895—Barrel or housing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
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- B29C2948/92904—Die; Nozzle zone
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- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
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- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/10—Homopolymers or copolymers of propene
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- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
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- C08J2497/00—Characterised by the use of lignin-containing materials
- C08J2497/02—Lignocellulosic material, e.g. wood, straw or bagasse
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Abstract
The invention discloses a kind of can active adsorption formaldehyde and purify the charcoal of air and mould anion sheet material and preparation technology thereof, the composition and ratio of its raw material is as follows: resin 5% 50%；Powdered carbon 5% 50%；Vermiculite power 5% 20%；Calcium carbonate 5% 15%；Plant fiber 5% 10%；Germanite powder 1% 5%；Tourmaline powder 0.5% 2%；ACR 0.5% 2%；PE wax 0.2% 2%；Foaming control agent 1% 5%；Complex stabilizer 1% 3%；Nano titanium oxide 1% 3%；Stearic acid 0.1% 2%；CPE 1% one 3%；Foaming agent 0.1% 1%.
Description
Technical field
The present invention relates to sheet material manufacturing technology field, being specifically related to one can be as decorative panels such as furniture-plates, wallboard, floors
Material uses, and the charcoal of energy active adsorption formaldehyde and purifying air moulds anion healthy sheet material and preparation technology thereof.
Background technology
Along with forest reserves limit is cut down the appearance of policy, wood-based plate, solid wood composite board by fast development and China of real estate
Solid wood board is replaced to be widely used in the field such as Furniture manufacture, indoor decorating after facing etc. various dalles.People
Make and form through high temperature compacting after plate, solid wood composite board are mainly mixed by a certain percentage by forest products residue and adhesive, can be a large amount of
Discharge strong (VOCS) volatile Organic substance abnormal smells from the patient, be the main next of the harmful substance pollutions such as formaldehyde, benzene, dimethylbenzene
Source, formaldehyde to the harm of human body in addition to causing zest chronic disease, moreover it is possible to react generation with the ionic chloride in air
Carcinogen--dichlormetbylether, causes the most renovated house can not live for a long time.
In order to solve human residential environment, several years ago, furnishing fields is wideling popularize the Wood plastic boards of " to mould Dai Mu ", wood
Moulding sheet material is exactly to add in resin that wood powder is hot-forming substitutes artificial composite board.Wood plastic boards is lightweight with it, intensity
High, easy to process, the advantages such as content of formaldehyde is low, it is widely used in household, office, building trade.Although Wood plastic boards formaldehyde
Content is low, but it can not absorb the noxious pollutants such as formaldehyde, toluene, dimethylbenzene, still cannot solve indoor environmental pollution to people
The infringement that body health is brought, becomes second polluter, causes secondary pollution.In order to enable the harmful substances such as formaldehyde adsorption, closely
Nian Lai, occurs in that the most again some what is called can purify the goods of air quality, such as number of patent application CN200510049608.4,
A kind of bamboo charcoal powder and the bamboo charcoal sheet material of adhesive mixing hydraulic press compacting；Such as number of patent application
CN200420054011.X adds bamboo charcoal particle in the interlayer of common sheet material and makes bamboo charcoal floor；Such as number of patent application
CN201510358009.4, adds Lauxite adhesive, through the composite material for decoration of hot pressing synthesis in carbon dust, zeolite powder.
Although above goods can formaldehyde adsorption to a certain extent, but by its characteristic, shape, composition of raw materials and production technology process
On restriction, properties of product are poor, hardness is low, nail-holding ability is inadequate, it is impossible to reach the serviceability of the dalle such as furniture, building.
At present, in order to be able to improve IAQ (indoor air quality), furnishing fields is wideling popularize " anion " product again.Anion quilt
Being described as " vitamin in air ", the physical and mental health of anion fine-purification indoor contaminated gas, beneficially human body, it passes through people
Nervous system and blood circulation by the telangiectasis of human body, blood circulation promoting can be played and promote the work of regenerative cell's tissue
With, the organism physiology activity on people produces impact.Human body every day it is generally required to suck a large amount of anion, due to urban construction, people
Mouth is concentrated, and natural conditions are unbalance, and negative ion concentration declines, especially indoor sealing, and air-conditioning is universal to be more negatively affected, anion
Only about 50/cm3, make us hypopnea, sultry headache, even result in the generation of the not clear respiratory disorders such as tracheitis.Though
Anion air conditioning and generator have listed, but cost is high, and power is low, consume electric energy.In order to provide the mankind one more healthy
Living environment, occur in that so-called anion goods on the market.Such as patent application CN201410317722.X, with Vermiculitum, glue
The glutinous each raw material of agent is mixed into slurry coating, spreads upon on automotive trim panel, obtains automotive trim panel capable of releasing negative ion.
And for example application number CN201310401006.5, is mixed by agitator with raw materials such as Vermiculitum, cement, paper pulp, zeolite, calcium silicates,
Dry by cylinder pressure method type again and make sheet material.And for example application number CN20151103167.0, with Adlerika, flyash, solely
Occupy the raw materials such as stone, zeolite, wood flour to be mixed by agitator, make sheet material through rolling out method or laminating.These goods are in certain journey
A small amount of anion can be discharged on degree, be also due to by the limit on its characteristic, shape, composition of raw materials and production technology process
System, properties of product are poor, hardness is low, nail-holding ability is inadequate, it is impossible to reach the serviceability of the dalle such as furniture, building, it is impossible to true
Just solving human habitat quality.In the market can the healthy element of releasing beneficial, active adsorption and automatic degradation of formaldehyde
Deng harmful substance, and the real environment-friendly sheet of air quality can be purified also in blank.
Summary of the invention
The present invention proposes in view of the above problems, it is an object of the invention to provide a kind of charcoal and moulds anion sheet material, and it is special
Levy and be, by weight, containing resin 5%-50%, powdered carbon 5%-50%, vermiculite power 5%-20%；Calcium carbonate 5%-15%；
Plant fiber 5%-10%；Germanite powder 1%-5%.
Charcoal of the present invention moulds anion sheet material, wherein, it is also possible to containing selected from tourmaline powder, ACR, PE wax, foaming
The processing aid that in regulator, complex stabilizer, nano titanium oxide, stearic acid, CPE 2%, foaming agent, any one is above.
Charcoal of the present invention moulds anion sheet material, and wherein, described resin is olefin(e) compound and derivant thereof.
Charcoal of the present invention moulds anion sheet material, and wherein, described olefin(e) compound and derivant thereof are preferably selected from polychlorostyrene
In ethylene, polyethylene, polypropylene more than any one.
Charcoal of the present invention moulds anion sheet material, and wherein, described Plant fiber is fine selected from the shell being 20 mesh～300 mesh
In dimension powder, bamboo fibre powder, wood fiber powder more than any one.
Charcoal of the present invention moulds anion sheet material, and wherein, described powdered carbon is 60 mesh～300 mesh fired by shell
Fruit shell carbon, bamboo charcoal, in Linesless charcoal more than any one.
Charcoal of the present invention moulds anion sheet material, and wherein, described vermiculite power is 20 mesh～600 mesh of high temperature puffing
Vermiculite power.
Charcoal of the present invention moulds anion sheet material, and wherein, described calcium carbonate is the lightweight carbonic acid of 600 mesh～1000 mesh
Calcium.
The present invention also provides for a kind of charcoal and moulds anion preparation of plates method, and this comprises the following steps:
The first step: the raw materials such as resin, powdered carbon, vermiculite power, germanite powder, calcium carbonate microparticle and processing aid are entered according to proportioning
Row filter, get the raw materials ready；
Second step: Plant fiber's powder is carried out maturation process；
3rd step: raw material good for proportioning is sequentially added mixture in high-speed mixer uniform；
4th step: the raw material mixed is put into low-temperature mixed machine cooling and stirring；
5th step: the raw material that the 4th step is handled well is delivered to double screw extruder, through molding die extrusion；
6th step: plasticizing extrusion stock is through stock mould hardening by cooling molding；
7th step: keep flat 24 hours after sheet forming traction being cut to cutting machine by standard plate with traction machine.
Charcoal of the present invention moulds anion preparation of plates method, the mixed at high speed process of described 3rd step, is by former
Material sequentially adds high-speed mixer be compounded from major ingredient, adjuvant to processing aid, and compounding temperature controls according to adjuvant difference
Between 105 DEG C～120 DEG C, form dry blend.
Charcoal of the present invention moulds anion preparation of plates method, and described 4th step is by high temperature feedstock good for mixture
Put into and low-temperature mixed machine carries out cooling and stirring, make temperature be reduced to about 45 DEG C.
Charcoal of the present invention moulds anion preparation of plates method, and the extruder barrel temperature of described 5th step arranges 130
DEG C～190 DEG C, die extrusion temperature controls at 120 DEG C～190 DEG C, and extrusion pressure is saved in more than 17MPa.
Charcoal of the present invention moulds anion preparation of plates method, described 6th step stock mould hardening by cooling forming temperature
Control at 16 DEG C～32 DEG C.
Charcoal of the present invention moulds anion preparation of plates method, after traction cut plate cutting a size of 1220mm ×
The standard plate of 2440mm, it is also possible to make wallboard that length-width ratio is 200mm-6000mm × 100mm-600mm and length-width ratio is
Other variously-shaped dalles such as the floor of 300mm-2000mm mm × 100mm-300mm, wherein thickness as required may be used
Control between 3.5mm-50mm.
The present invention is in addition to having the function of general decor sheet material, and self is without noxious pollutants such as formaldehyde, benzene, ammonia, and energy
Active adsorption and automatic degradation of formaldehyde, benzene, dimethylbenzene, ammonia, phenol and the harmful substance such as sulfide, nitride, within 24 hours, formaldehyde is clean
Rate reaches 52.9%, and purifying formaldehyde effect persistency is 46.5%.Meanwhile, also can lasting a large amount of anion releasings, every cube li
Rice anion burst size reaches more than 2000, really plays body natural curability, improves body constitution, prevents aging, prevention
Cancer, adjusts the health cares such as neural.And can saw, can dig, can follow closely, shore hardness reaches 59HD, is 2 times of general timber.
Nail-holding ability reaches 1199N, is 3 times of general timber.Bending strength reaches 21MPa, and Deflection Modulus of Elasticity reaches 1976MPa.Remote high
Use standard in current Furniture panel.It will replace density board, woodwork plate, plywood, thick china, finger-jointed plate the most on the market
Etc. with serious pollution composite decorative board, and the most popular Wood plastic boards.Charcoal is moulded anion sheet material and is solved from basic
Dalle in the market of having determined absorb water in moist and many water environments after making moist easily rot, the problem such as dilatancy, solve
Determine the problems such as traditional bamboo and wood products cannot apply in particular circumstances.Charcoal moulds anion sheet material health environment-friendly, the house of finishing
Can directly move in, thoroughly improve household working environment, build without the nontoxic space of aldehyde.It is to manufacture the product such as furniture, floor from now on
Main material, house ornamentation, handle official business, the aspect such as building will be used widely, build without aldehyde space for the mankind, thoroughly solve people
Class health problem.Being suitable for the state basic policy of China's sustainable development, promote the well-being of mankind society, and market prospect is had an optimistic view of.
Detailed description of the invention
The concrete processing technique of the present invention is described in further detail by combined process flow process:
The charcoal that the invention discloses a kind of energy active adsorption formaldehyde and purification air mould anion sheet material, the composition of its raw material
Proportioning is as follows: resin 5%-50%；Powdered carbon 5%-50%；Vermiculite power 5%-15%；Calcium carbonate 5%-15%；Plant fiber 5%-
10%；Germanite powder 1%-5%；Tourmaline powder 0.5%-2%；ACR 0.5%-2%；PE wax 0.2%-2%；Foaming control agent
1%-5%；Complex stabilizer 1%-3%；Nano titanium dioxide 1%-3%；Stearic acid 0.1%-2%；CPE 1%-3%；
Foaming agent 0.1%-1%.
The charcoal that the invention also discloses a kind of energy active adsorption formaldehyde and purification air mould anion preparation of plates technique,
Comprise the steps:
The first step: the raw materials such as resin, powdered carbon, vermiculite power, germanite powder, calcium carbonate microparticle and processing aid are entered according to proportioning
Row filter, get the raw materials ready；Second step: Plant fiber's powder is carried out maturation process；3rd step: raw material good for proportioning is sequentially added height
In speed mixer, mixture is uniform；4th step: the raw material mixed is put into low-temperature mixed machine cooling and stirring；5th step: by the 4th
The raw material that step is handled well delivers to double screw extruder, through molding die extrusion；6th step: plasticizing extrusion stock cools down through stock mould
Hardened forming；7th step: keep flat 24 hours after sheet forming traction being cut to cutting machine by standard plate with traction machine.
The resin of the described first step is Corvic (pvc), it is also possible to be polyvinyl resin (PE), acrylic resin
(PP)；Powdered carbon is 60 mesh～the fruit shell carbon of 300 mesh fired by shell, it is also possible to the same bamboo charcoal of mesh number, Linesless charcoal etc. are planted
Thing powdered carbon；Vermiculite power is the Vermiculitum powder forming 20 mesh～600 mesh through 600 DEG C～900 DEG C of high temperature puffings；Tourmaline particles is
100 mesh～800 mesh；Calcium carbonate is 600 mesh～the precipitated calcium carbonate of 1000 mesh.
The shell fiber dust that Plant fiber's powder is 20 mesh～300 mesh of described second step, it is also possible to be same mesh number
Bamboo fibre powder, wood fiber powder；
The mixed at high speed process of described 3rd step, is sequentially to add the most mixed by raw material from major ingredient, adjuvant to processing aid
Conjunction machine is compounded, and compounding temperature controls between 105 DEG C～120 DEG C according to adjuvant difference, forms dry blend；
Described 4th step is to put into the high temperature feedstock that mixture is good to carry out cooling and stirring in low-temperature mixed machine, makes temperature reduce
To about 45 DEG C；
The extruder barrel temperature of described 5th step arranges 130 DEG C～190 DEG C, and die extrusion temperature controls at 120 DEG C～190
DEG C, extrusion pressure is saved in more than 17MPa；
Described 6th step stock mould hardening by cooling forming temperature controls at 16 DEG C～32 DEG C.
The standard plate of plate cutting a size of 1220mm × 2440mm is cut, it is also possible to make after described 7th step traction
Length-width ratio is the wallboard of 200mm-6000mm × 100mm-600mm and length-width ratio is 300mm-2000mm mm × 100mm-300mm
Other variously-shaped dalles such as floor, wherein thickness can be controlled between 3.5mm-50mm as required.
The charcoal of a kind of energy active adsorption formaldehyde and purification air mould anion preparation of plates technique, comprises the steps:
The first step: carry out screening according to proportioning by the raw materials such as resin, powdered carbon, vermiculite power, germanite powder, calcium carbonate microparticle and processing aid,
Get the raw materials ready；Second step: Plant fiber's powder is carried out maturation process；3rd step: raw material good for proportioning is sequentially added mixed at high speed
In machine, mixture is uniform；4th step: the raw material mixed is put into low-temperature mixed machine cooling and stirring；5th step: the 4th step is processed
Good raw material delivers to double screw extruder, through molding die extrusion；6th step: plasticizing extrusion stock becomes through stock mould hardening by cooling
Type；7th step: keep flat 24 hours after sheet forming traction being cut to cutting machine by standard plate with traction machine.
The present invention utilizes the advantages such as powdered carbon hexagonal molecular structure, fine and closely woven porous, characterization of adsorption, efficiently solve formaldehyde, benzene,
The absorption problem of the noxious pollutants such as ammonia, amine such as toluene, dimethylbenzene, ethylo benzene, chlorobenzene；Utilize the unique structural property of Vermiculitum,
Adsorptivity and ion-exchange capacity combine pyroelectricity and the piezoelectricity of tourmaline, and efficiently solving current dalle cannot hold
Discharge a large amount of negative oxygen ion problems, neutralization decomposing formaldehyde for a long time and fall to PM2.5 in air, activating human body cells, adjust body
Liquid and nervous system, activate the effects such as relevant physiological activity, strengthening respiratory system and removing free radical slow down aging.Utilize without aldehyde
Resin efficiently solves the problem that other binding agent formaldehyde pollutions are serious, makes product be really achieved without aldehyde effect；Utilize calcium zinc multiple
Close stabilizer and improve the problem that mixed with resin dispersion is uneven, it is provided that the condition of dustless production；Add inside and outside lubricant agent, reduce
Processing rubs, improves processing characteristics, and then improve the surface property of sheet material；Add chliorinated polyvinyl chloride CPE and plant is fine
Dimension, is effectively increased the elasticity of sheet material, toughness and low temperature properties.Add Nano titanium dioxide powder, efficiently solve powdered carbon and inhaling
The problem cannot automatically degraded after receiving formaldehyde, it is to avoid secondary pollution.Utilize the special characteristics such as 32 current potentials of germanite atom, adjust people
Body abnormal current potential function, captures the electronics of cancerous cell, plays the change of suppression disease, increases the purposes of product, improves product
Class, comprehensive decontamination air, become the Green environmental-protection building material that can breathe.
The present invention is in addition to having the function of general decor sheet material, and self is without noxious pollutants such as formaldehyde, benzene, ammonia, and energy
Active adsorption and automatic degradation of formaldehyde, benzene, dimethylbenzene, ammonia, phenol and the harmful substance such as sulfide, nitride, within 24 hours, formaldehyde is clean
Rate reaches 52.9%, and purifying formaldehyde effect persistency is 46.5%.Meanwhile, also can lasting a large amount of anion releasings, every cube li
Rice anion burst size reaches more than 2000, really plays body natural curability, improves body constitution, prevents aging, prevention
Cancer, adjusts the health cares such as neural.And can saw, can dig, can follow closely, shore hardness reaches 59HD, is 2 times of general timber.
Nail-holding ability reaches 1199N, is 3 times of general timber.Bending strength reaches 21MPa, and Deflection Modulus of Elasticity reaches 1976MPa.Remote high
Use standard in current Furniture panel.It will replace density board, woodwork plate, plywood, thick china, finger-jointed plate the most on the market
Etc. with serious pollution composite decorative board, and the most popular Wood plastic boards.Charcoal is moulded anion sheet material and is solved from basic
Dalle in the market of having determined absorb water in moist and many water environments after making moist easily rot, the problem such as dilatancy, solve
Determine the problems such as traditional bamboo and wood products cannot apply in particular circumstances.Charcoal moulds anion sheet material health environment-friendly, the house of finishing
Can directly move in, thoroughly improve household working environment, build without the nontoxic space of aldehyde.It is to manufacture the product such as furniture, floor from now on
Main material, house ornamentation, handle official business, the aspect such as building will be used widely, build without aldehyde space for the mankind, thoroughly solve people
Class health problem.Being suitable for the state basic policy of China's sustainable development, promote the well-being of mankind society.
Embodiment 1
Weigh resin 40%, powdered carbon 20%, vermiculite power 12%, calcium carbonate 8%, bamboo fibre 7%, germanite powder 2.5%, electrically
Stone powder 1.1%, ACR 0.7%, PE wax 0.3%, foaming control agent 3%, complex stabilizer 2%, Nano titanium dioxide 1%,
Stearic acid 0.2%, CPE 2%, foaming agent 0.2% are got the raw materials ready；
Bamboo fibre powder is carried out maturation process (actual conditions, such as temperature？Time？)；By raw material good for proportioning sequentially
After mixture is uniform in high-speed mixer at adding 105 DEG C～120 DEG C, puts into the low-temperature mixed machine cooling and stirring of 45 DEG C, will stir
The raw material mixed delivers to 130 DEG C～190 DEG C of double screw extruders, through 120 DEG C～190 DEG C, more than 17MPa molding die extrusion,
By plasticizing extrusion stock after 16 DEG C～32 DEG C of stock mould hardening by cooling molding, use traction machine by sheet forming traction to cutting
Machine keeps flat 24 hours after cutting by standard plate.
The sheet material obtained according to embodiment 1, within 24 hours, purifying formaldehyde rate reaches 52.9%, and purifying formaldehyde effect persistency is
46.5%.Meanwhile, also can lasting a large amount of anion releasings, every cubic centimetre of anion burst size reaches more than 2000, Er Qieke
Sawing, can dig, can follow closely, shore hardness reaches 59HD, is 2 times of general timber.Nail-holding ability reaches 1199N, bending strength reaches
21MPa, Deflection Modulus of Elasticity reach 1976MPa.
Embodiment 2
Weigh resin 35%, powdered carbon 20%, vermiculite power 15%, calcium carbonate 10%, the wood fiber 6.5%, germanite powder 2.5%,
Tourmaline powder 1%, ACR 0.8%, PE wax 0.4%, foaming control agent 2.7%, complex stabilizer 2.2%, nanoscale titanium dioxide
Titanium 1.3%, stearic acid 0.3%, CPE 2%, foaming agent 0.3% are got the raw materials ready；
Wood fiber powder is carried out maturation process (actual conditions, such as temperature？Time？)；By raw material good for proportioning sequentially
After mixture is uniform in high-speed mixer at adding 105 DEG C～120 DEG C, puts into the low-temperature mixed machine cooling and stirring of 45 DEG C, will stir
The raw material mixed delivers to 130 DEG C～190 DEG C of double screw extruders, through 120 DEG C～190 DEG C, more than 17MPa molding die extrusion,
By plasticizing extrusion stock after 16 DEG C～32 DEG C of stock mould hardening by cooling molding, use traction machine by sheet forming traction to cutting
Machine keeps flat 24 hours after cutting by standard plate.
The sheet material obtained according to embodiment 2, within 24 hours, purifying formaldehyde rate reaches 52.9%, and purifying formaldehyde effect persistency is
46.5%.Meanwhile, also can lasting a large amount of anion releasings, every cubic centimetre of anion burst size reaches more than 2000, Er Qieke
Sawing, can dig, can follow closely, shore hardness reaches 59HD, is 2 times of general timber.Nail-holding ability reaches 1199N, bending strength reaches
21MPa, Deflection Modulus of Elasticity reach 1976MPa.
Embodiment 3
Weigh resin 40%, powdered carbon 15%, vermiculite power 20%, calcium carbonate 8%, coir 5%, germanite powder 2%, electricity
Gas stone powder 1.5%, ACR 0.9%, PE wax 0.4%, foaming control agent 3%, complex stabilizer 1.5%, Nano titanium dioxide
0.5%, stearic acid 0.4%, CPE 1.5%, foaming agent 0.3% are got the raw materials ready；
Wood fiber powder is carried out maturation process (actual conditions, such as temperature？Time？)；By raw material good for proportioning sequentially
After mixture is uniform in high-speed mixer at adding 105 DEG C～120 DEG C, puts into the low-temperature mixed machine cooling and stirring of 45 DEG C, will stir
The raw material mixed delivers to 130 DEG C～190 DEG C of double screw extruders, through 120 DEG C～190 DEG C, more than 17MPa molding die extrusion,
By plasticizing extrusion stock after 16 DEG C～32 DEG C of stock mould hardening by cooling molding, use traction machine by sheet forming traction to cutting
Machine keeps flat 24 hours after cutting by standard plate.
The sheet material obtained according to embodiment 3, within 24 hours, purifying formaldehyde rate reaches 52.9%, and purifying formaldehyde effect persistency is
46.5%.Meanwhile, also can lasting a large amount of anion releasings, every cubic centimetre of anion burst size reaches more than 2000, Er Qieke
Sawing, can dig, can follow closely, shore hardness reaches 59HD, is 2 times of general timber.Nail-holding ability reaches 1199N, bending strength reaches
21MPa, Deflection Modulus of Elasticity reach 1976MPa.
The invention has the beneficial effects as follows: utilize the advantages such as powdered carbon hexagonal molecular structure, fine and closely woven porous, characterization of adsorption, effectively
Solve the absorption problem of the noxious pollutants such as ammonia, amine such as formaldehyde, benzene,toluene,xylene, ethylo benzene, chlorobenzene；Utilize Vermiculitum only
Special structural property, adsorptivity and ion-exchange capacity combines pyroelectricity and the piezoelectricity of tourmaline, efficiently solves at present
Dalle cannot persistently discharge a large amount of negative oxygen ion problem, neutralization decomposing formaldehyde and fall to PM2.5 in air, activates people
Somatic cell, adjusts body fluid and nervous system, activates relevant physiological activity, strengthening respiratory system and removing free radical slow down aging etc.
Effect.Utilize and efficiently solve, without urea formaldehyde, the problem that other binding agent formaldehyde pollutions are serious, make product be really achieved and imitate without aldehyde
Really；Calcium-zinc composite stabilizing agent is utilized to improve the problem that mixed with resin dispersion is uneven, it is provided that the condition of dustless production；In adding
External lubricant, reduces in processing and rubs, improve processing characteristics, and then improve the surface property of sheet material；Add chlorinated polyvinyl chloride second
Alkene CPE and Plant fiber, be effectively increased the elasticity of sheet material, toughness and low temperature properties.Add Nano titanium dioxide powder, efficient solution
The problem that powdered carbon of having determined cannot be degraded after absorbing formaldehyde automatically, it is to avoid secondary pollution.Utilize the spies such as 32 current potentials of germanite atom
Different characteristic, adjusts human body abnormal current potential function, captures the electronics of cancerous cell, plays the change of suppression disease, increases product
Purposes, improves the class of product, comprehensive decontamination air, becomes the Green environmental-protection building material that can breathe.
The present invention is in addition to having the function of general decor sheet material, and self is without noxious pollutants such as formaldehyde, benzene, ammonia, and energy
Active adsorption and automatic degradation of formaldehyde, benzene, dimethylbenzene, ammonia, phenol and the harmful substance such as sulfide, nitride, within 24 hours, formaldehyde is clean
Rate reaches 52.9%, and purifying formaldehyde effect persistency is 46.5%.Meanwhile, also can lasting a large amount of anion releasings, every cube li
Rice anion burst size reaches more than 2000, really plays body natural curability, improves body constitution, prevents aging, prevention
Cancer, adjusts the health cares such as neural.And can saw, can dig, can follow closely, shore hardness reaches 59HD, is 2 times of general timber.
Nail-holding ability reaches 1199N, is 3 times of general timber.Bending strength reaches 21MPa, and Deflection Modulus of Elasticity reaches 1976MPa.Remote high
Use standard in current Furniture panel.It will replace density board, woodwork plate, plywood, thick china, finger-jointed plate the most on the market
Etc. with serious pollution composite decorative board, and the most popular Wood plastic boards.Charcoal is moulded anion sheet material and is solved from basic
Dalle in the market of having determined absorb water in moist and many water environments after making moist easily rot, the problem such as dilatancy, solve
Determine the problems such as traditional bamboo and wood products cannot apply in particular circumstances.Charcoal moulds anion sheet material health environment-friendly, the house of finishing
Can directly move in, thoroughly improve household working environment, build without the nontoxic space of aldehyde.It is to manufacture the product such as furniture, floor from now on
Main material, house ornamentation, handle official business, the aspect such as building will be used widely, build without aldehyde space for the mankind, thoroughly solve people
Class health problem.Being suitable for the state basic policy of China's sustainable development, promote the well-being of mankind society.
It should be noted that the present invention is not limited to the details of one exemplary embodiment described in description, this specification is simply
Being been described by according to exemplary embodiment, the most each embodiment only comprises an independent technical scheme, this specification
This narrating mode be only easy to everybody and understand the present invention.Those skilled in the art should be using patent specification as one
Individual entirety, the technical scheme in each one exemplary embodiment simply carries out appropriately combined according to anion healthy plate characteristic, respectively implements
Technical scheme described in example still can be revised, and wherein portion of techniques feature is carried out equivalent.Every in skill of the present invention
In art parameter area, without departing substantially from spirit, basic feature and the technical parameter of the present invention, any amendment made, equivalent are replaced
Change, improvement etc., within the scope of the technical scheme of the protection that should be included in the present invention.
Claims (14)
1. a charcoal moulds anion sheet material, it is characterised in that by weight, containing resin 5%-50%, powdered carbon 5%-50%, trematodiasis
Stone powder 5%-20%；Calcium carbonate 5%-15%；Plant fiber 5%-10%；Germanite powder 1%-5%.
Charcoal the most according to claim 1 moulds anion sheet material, wherein, it is also possible to containing selected from tourmaline powder, ACR, PE wax,
In foaming control agent, complex stabilizer, nano titanium oxide, stearic acid, CPE2%, foaming agent, any one above processing helps
Agent.
Charcoal the most according to claim 1 moulds anion sheet material, and wherein, described resin is olefin(e) compound and derivant thereof.
Charcoal the most according to claim 3 moulds anion sheet material, and wherein, described olefin(e) compound and derivant thereof are preferably selected from
In polrvinyl chloride, polyethylene, polypropylene more than any one.
Charcoal the most according to any one of claim 1 to 4 moulds anion sheet material, and wherein, it is 20 that described Plant fiber is selected from
In the shell fiber dust of mesh～300 mesh, bamboo fibre powder, wood fiber powder more than any one.
Charcoal the most according to any one of claim 1 to 4 moulds anion sheet material, and wherein, described powdered carbon is to be fired by shell
60 mesh～the fruit shell carbon of 300 mesh, bamboo charcoal, Linesless charcoal in more than any one.
Charcoal the most according to any one of claim 1 to 4 moulds anion sheet material, and wherein, described vermiculite power is high temperature puffing
20 mesh～the vermiculite power of 600 mesh.
Charcoal the most according to any one of claim 1 to 4 moulds anion sheet material, wherein, described calcium carbonate be 600 mesh～
The precipitated calcium carbonate of 1000 mesh.
9. charcoal moulds an anion preparation of plates method, and this comprises the following steps:
The first step: the raw materials such as resin, powdered carbon, vermiculite power, germanite powder, calcium carbonate microparticle and processing aid are sieved according to proportioning
Select, get the raw materials ready；
Second step: Plant fiber's powder is carried out maturation process；
3rd step: raw material good for proportioning is sequentially added mixture in high-speed mixer uniform；
4th step: the raw material mixed is put into low-temperature mixed machine cooling and stirring；
5th step: the raw material that the 4th step is handled well is delivered to double screw extruder, through molding die extrusion；
6th step: plasticizing extrusion stock is through stock mould hardening by cooling molding；
7th step: keep flat 24 hours after sheet forming traction being cut to cutting machine by standard plate with traction machine.
Charcoal the most according to claim 9 moulds anion preparation of plates method, the mixed at high speed process of described 3rd step,
Being that raw material is sequentially added high-speed mixer be compounded from major ingredient, adjuvant to processing aid, compounding temperature is different according to adjuvant
Control between 105 DEG C～120 DEG C, form dry blend.
11. charcoals according to claim 9 mould anion preparation of plates method, and described 4th step is by height good for mixture
Temperature raw material is put into and is carried out cooling and stirring in low-temperature mixed machine, makes temperature be reduced to about 45 DEG C.
12. charcoals according to claim 9 mould anion preparation of plates method, and the extruder barrel temperature of described 5th step sets
Putting 130 DEG C～190 DEG C, die extrusion temperature controls at 120 DEG C～190 DEG C, and extrusion pressure is saved in more than 17MPa.
13. charcoals according to claim 9 mould anion preparation of plates method, and described 6th step stock mould hardening by cooling becomes
Type temperature controls at 16 DEG C～32 DEG C.
14. charcoals according to claim 9 mould anion preparation of plates method, cut plate cutting a size of after traction
The standard plate of 1220mm × 2440mm, it is also possible to make wallboard that length-width ratio is 200mm-6000mm × 100mm-600mm and
Length-width ratio is other variously-shaped dalles such as the floor of 300mm-2000mm mm × 100mm-300mm, wherein thickness root
It can be controlled between 3.5mm-50mm according to needs.
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| CN201610699876.9A CN106188976A (en) | 2016-08-23 | 2016-08-23 | The charcoal of a kind of active adsorption formaldehyde and purification air moulds anion sheet material and preparation method |
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| CN106836731A (en) * | 2016-12-30 | 2017-06-13 | 无锡市中富塑胶有限公司 | A kind of Environmental-protection bamboo carbon slab and preparation method thereof |
| CN107082940A (en) * | 2017-06-20 | 2017-08-22 | 合肥尚涵装饰工程有限公司 | A kind of fire resisting Wood plastic composite capable of purifying air and preparation method thereof |
| CN107698899A (en) * | 2017-11-06 | 2018-02-16 | 河源市耐宝新型建材有限公司 | A kind of carbonaceous material and its preparation method and application |
| CN107740549A (en) * | 2017-08-23 | 2018-02-27 | 广州市五羊艺冠声学材料有限公司 | Without aldehyde ecology abatvoix and preparation method thereof |
| CN108003495A (en) * | 2017-11-24 | 2018-05-08 | 湖北名望世家装饰材料股份有限公司 | A kind of wood moulding Carbon fibe plate and preparation method thereof |
| CN108410078A (en) * | 2017-11-16 | 2018-08-17 | 辽宁新世界科技股份有限公司 | A kind of environmental protection wood moulding integrated wall plate and preparation method thereof |
| CN109233141A (en) * | 2018-07-20 | 2019-01-18 | 浙江农林大学 | A kind of manufacturing process of high shielding charcoal mould plate |
| CN109593378A (en) * | 2018-12-13 | 2019-04-09 | 湖南竹海炭生源生物科技有限公司 | A kind of environmental bamboo charcoal plate and preparation method thereof |
| WO2019090463A1 (en) * | 2017-11-07 | 2019-05-16 | 河源市耐宝新型建材有限公司 | Carbon-containing material, preparation method therefor and use thereof |
| CN109796676A (en) * | 2019-01-21 | 2019-05-24 | 浙江省林业科学研究院 | A kind of low VOC bamboo fibre interior trim profile and preparation method thereof |
| CN111019272A (en) * | 2019-12-30 | 2020-04-17 | 唐山市唯森新材料有限公司 | Negative ion decorative material, preparation method thereof, decorative plate and application thereof |
| CN111040334A (en) * | 2019-12-05 | 2020-04-21 | 福建工程学院 | Environment-friendly PVC (polyvinyl chloride) foamed sheet added with activated bamboo charcoal and manufacturing method thereof |
| CN111592773A (en) * | 2020-06-18 | 2020-08-28 | 杨明杰 | Nanometer tourmaline negative ion skirting line and production process thereof |
| CN112209665A (en) * | 2020-10-16 | 2021-01-12 | 深圳市绿意雅科技有限公司 | Pouring material for ceiling board and production process thereof |
| CN113024888A (en) * | 2021-03-16 | 2021-06-25 | 福建六正新材料科技有限公司 | Anion plate additive and application thereof, polyvinyl chloride anion plate and preparation method and application thereof |
| CN113831665A (en) * | 2021-10-14 | 2021-12-24 | 安徽炭元高新科技集团有限公司 | Multifunctional negative ion carbon composite board and manufacturing process thereof |
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| CN109233141A (en) * | 2018-07-20 | 2019-01-18 | 浙江农林大学 | A kind of manufacturing process of high shielding charcoal mould plate |
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| CN111040334A (en) * | 2019-12-05 | 2020-04-21 | 福建工程学院 | Environment-friendly PVC (polyvinyl chloride) foamed sheet added with activated bamboo charcoal and manufacturing method thereof |
| CN111019272A (en) * | 2019-12-30 | 2020-04-17 | 唐山市唯森新材料有限公司 | Negative ion decorative material, preparation method thereof, decorative plate and application thereof |
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