KR20180008083A - An aromatic paper and manufacturing method thereof - Google Patents

Abstract

The present invention relates to an aromatic paper which can increase a period of scent while maintaining a constant scent, and a manufacturing method thereof. The method comprises the steps of: preparing paper; spraying on the paper; drying the sprayed paper; and sealing the dried paper.

Description

≪ Desc / Clms Page number 1 > AN AROMATIC PAPER AND MANUFACTURING METHOD THEREOF &

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a paper fragrance and a method for producing the same, and more particularly, to a paper fragrance capable of maintaining a certain fragrance while controlling the odor intensity of the paper fragrance and having a message inserted therein.

Generally, the fragrance is used for the indoor environment to be cleaned by eliminating the odor from the room or the indoor of the vehicle.

Recently, a variety of fragrances have been developed, and the aroma therapy, that is, the absorption of vegetable oil extracted from flowers, stems, leaves, roots and fruits of various plants into the body through the nose and skin to prevent and cure various diseases, skin beauty, And the development of psychotherapeutic natural therapies.

Korean Patent Publication No. 10-0894291 discloses a paper directioner Tek provided as a sheet having a uniform thickness and a method for producing the same. The paper directioner Tek has two sheets of paper, a nonwoven fabric to which a perfume is added, .

However, the paper directional material Te provided as a sheet having such a uniform thickness has a disadvantage that the room temperature of the vehicle is increased, or when the direct sunlight is exposed, the aromatic life cycle is shortened and the life cycle of the fragrance is shortened. A problem may arise which may cause discomfort due to incense.

Disclosure of Invention Technical Problem [8] Accordingly, the present invention has been made in view of the above problems, and an object of the present invention is to provide a paper fragrance and a method for producing the fragrance.

In order to solve the above problems, the present invention provides a method of manufacturing a semiconductor device, comprising: (a) preparing a tributary; (b) spraying on said feed stream; (c) drying the tributary; and (d) sealing the tributary.

In addition, the method further includes printing a message on the front or rear surface of the tributary after the step (c), wherein in the step (b), the spray is applied by adding .

Also, it is possible to provide the paper fragrance produced by the method for producing paper fragrance.

In order to solve the above-described problems, the present invention provides a method for producing a ferrite material, comprising the steps of: (a) preparing and pulverizing a raw material; (b) at least one natural selected from the above-mentioned pulverized raw materials, non-sintered binders and pine, elderberry, oak, yam, rosemary, wormwood, herb, gumone root, geranium, cinnamon, acacia, dandelion, 10 to 80 parts by weight of a plant extract and 10 to 80 parts by weight of a vegetable oil are mixed and aged for 5 to 15 days to prepare a mixture; (c) completely removing water from the mixture to form a powder, mixing the mixture with a polymer compound, and microencapsulating the mixture; (d) mixing the microcapsules with a urethane binder, a resin binder or polyethyl acrylate at a weight ratio of 1: 1 to 1: 3, and spraying the mixture onto paper by spraying; (e) removing water from the paper through a pressing process, and then drying the paper at room temperature; (f) immersing the dried paper in the coating material for 6 to 48 hours, and (g) secondary drying the immersed paper at room temperature, wherein the non-fired binder has a durability Wherein 20 to 30 parts by weight of clay, 10 to 20 parts by weight of clay herb and 10 to 20 parts by weight of herbal herb are mixed, based on 100 parts by weight of the herb fermentation product, 5 to 10 parts by weight of phenol, 5 to 10 parts by weight of rosin, and 1 to 5 parts by weight of a natural latex extract.

The preparation of the raw material in the step (a) may include adding 5 to 10% (w / v) of a herb as an organic directional powder to 10 liters of distilled water; Sterilizing the resultant mixture of the distilled water and the hub at 80 to 90 degrees for 10 to 60 minutes; Cooling the sterilized product at 10 to 20 degrees; Inoculating the cooled product with 0.1% to 0.5% (w / v) of a useful microorganism monarch (EFFECTIVE MICROORGANISMS); Fermenting the inoculated product at a temperature of 20 to 40 degrees C for 24 to 48 hours, a stirring speed of 600 to 900 rpm and an air flow rate of 0.2 to 0.5 vvm; Centrifuging the fermented fermentation broth at 5,000 to 10,000 rpm for 60 to 120 minutes; Separating the supernatant located on the upper part of the centrifuged fermentation broth and compressing the supernatant liquid; Lyophilizing the filtered filtrate by filtration; Obtaining a powder of the lyophilized herb fermentation product, and mixing the ceramic material.

The ceramic material may include at least one of feldspar porphyry, zeolite, kaolite, diatomaceous earth, benzonite, and talc, which are porous ceramics.

In addition, the beneficial microorganism monarch is selected from the group consisting of Lactobacillus delbrueckii, Lactobacillus casei, Lactobacillus bulgaricus, Lactobacillus plantarum, Lactobacillus lambosus, rhamnosus, and Micrococcus.

In addition, the method of manufacturing a paper fragrance may include the steps of: (c) forming microcapsules having a micro-particle size of several micrometers to several hundreds of micrometers in diameter so that the effect of the microcapsules is enhanced; .

In addition, the method of producing a paper fragrance may further include: after the step (g), printing a message on the front and back sides of the paper; Attaching a silicone seal in a strip shape on the front and back surfaces of the paper, and attaching a plurality of transparent stickers to each of the divided ranges of the silicone seal.

Also, it is possible to provide the paper fragrance produced by the method for producing paper fragrance.

The paper fragrance according to the embodiment of the present invention and its manufacturing method have an effect of increasing the fragrance period while maintaining a constant fragrance.

BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a flowchart sequentially illustrating a method of manufacturing a paper fragrance according to a first embodiment of the present invention; FIG.
FIG. 2 is a perspective view showing a paper fragrance manufactured by the manufacturing method shown in FIG. 1; FIG.
FIG. 3 is a flowchart sequentially showing a method of manufacturing a paper fragrance according to a second embodiment of the present invention; FIG.
4 is a perspective view showing the paper fragrance manufactured by the manufacturing method shown in FIG.

Hereinafter, the description of the present invention with reference to the drawings is not limited to a specific embodiment, and various transformations can be applied and various embodiments can be made. It is to be understood that the following description covers all changes, equivalents, and alternatives falling within the spirit and scope of the present invention.

In the following description, the terms first, second, and the like are used to describe various components and are not limited to their own meaning, and are used only for the purpose of distinguishing one component from another component.

Like reference numerals used throughout the specification denote like elements.

As used herein, the singular forms "a", "an" and "the" include plural referents unless the context clearly dictates otherwise. It is also to be understood that the terms " comprising, "" comprising, "or" having ", and the like are intended to designate the presence of stated features, integers, And should not be construed to preclude the presence or addition of one or more other features, integers, steps, operations, elements, components, or combinations thereof.

Hereinafter, embodiments of the present invention will be described in detail with reference to the accompanying drawings.

FIG. 1 is a flowchart sequentially illustrating a method of manufacturing a paper fragrance according to a first embodiment of the present invention, and FIG. 2 is a perspective view illustrating a paper fragrance manufactured by the manufacturing method shown in FIG.

Referring to FIGS. 1 and 2, a method of manufacturing a paper fragrance includes preparing a tributary stream S1, spraying the tributary stream S2, drying the tributary stream S3, and printing a message on the front or rear of the tributary (S4) and sealing the tributary (S5).

Step S1 of preparing the tributary can prepare a paper or pulp paper having a predetermined size.

Step S2 of spraying the tributary may spray herb oil or aroma oil to the tributary 2 in a spraying manner.

Step (S3) of drying the tributary stream can dry the tributary (2) at a normal temperature of 10 to 15 degrees.

Printing a message on the front or back side of the tributary (S4) may print the message (3) on the front or back side of the tributary (2).

Sealing the tributary (S5) may be accomplished by inserting a tributary into the coated paper (4) and sealing.

FIG. 3 is a flowchart sequentially illustrating a method for manufacturing a paper fragrance according to a second embodiment of the present invention, and FIG. 4 is a perspective view illustrating a paper fragrance manufactured by the manufacturing method shown in FIG.

Referring to FIGS. 3 and 4, a method for producing a paper fragrance includes preparing a raw material (S10), preparing a mixture (S20), microencapsulating the mixture (S30), injecting microcapsules onto paper (S40) of drying the paper, a step (S50) of drying the paper (S50), a step (S60) of immersing the dried paper, a step (S70) of drying the immersed paper (S70) (S80), attaching a silicone seal in a strip shape on the front and back surfaces of the paper (S90), and attaching a plurality of transparent stickers (S100) for each divided range of the silicone seal.

Step S10 of preparing the raw material is a step of adding 5% to 10% (w / v) of a herb as an organic directional powder to 10 liters (L) of distilled water (S110) (S 120), cooling the sterilized product at 10 to 20 ° C (S130), adding 0.1% to 0.5% (w / w) of the useful microorganism to the cooled product (S 120) v) (step S140), fermenting the inoculated product at a temperature of 20 to 40 degrees C for 24 to 48 hours, a stirring speed of 600 to 900 rpm and an aeration amount of 0.2 to 0.5 vvm (S150) Centrifuging the fermented broth at 5,000 to 10,000 rpm for 60 to 120 minutes (S160), separating the supernatant from the centrifuged fermentation broth, compressing the supernatant (S170), filtering the filtered filtrate (S180), obtaining a powder of the lyophilized herb fermentation product (S190) and mixing the ceramic material (S200).

The herb fermentation can be carried out in a stirred bioreactor (50 L scale).

Herbs are plants that smell. The hub can be used as is or dried.

The herb may include at least one of moon, anise, laurel, oregano, tarragon, basil, sage, thyme, mint, chervil, coriander, rosemary, hyssop, barley, lavish, safflower and lemon balm.

A step (S110) of adding 5% to 10% (w / v) of a hub as an organic directional powder to 10 liters of distilled water may add a hub as an organic directional powder to 10 liters (L) of distilled water.

If the amount of the herb is less than 5% (w / v), the antioxidant effect may be insignificant. In addition, when the addition amount of the hub is more than 10% (w / v), compatibility with the ceramic material may be poor. Therefore, the addition amount of the herb is preferably 5 to 10% (w / v).

The step of sterilizing the resultant mixture of the distilled water and the herb at 80 to 90 degrees for 10 to 60 minutes (S120) can heat the resultant obtained by mixing the distilled water and the herb with the temperature of 80 degrees for about 30 minutes to eliminate the virus.

In this case, Ultra High Temperature Sterilization (UHT) can be performed at 90 degrees for 5 seconds to 10 seconds.

The step of cooling the sterilized product at 10 to 20 degrees (S130) may cool the resultant of the mixture of the sterilized distilled water and the herb at a temperature of 15 degrees.

In this case, it may be cooled for 6 to 12 hours. The reason for cooling is to inoculate a useful microorganism monarch.

Inoculating 0.1-0.5% (w / v) EFFECTIVE MICROORGANISMS into the cooled product (S140) can be used to inoculate 0.5% of the beneficial microorganism monarch (EFFECTIVE MICROORGANISMS) on the cooled product.

Useful microorganism monarchs include Lactobacillus delbrueckii, Lactobacillus casei, Lactobacillus bulgaricus, Lactobacillus plantarum, Lactobacillus rhamnosus and Lactobacillus spp. Micrococcus, < / RTI > and the like.

For reference, the useful microorganism group is collected by collecting about 80 useful microorganisms such as yeast, lactic acid bacteria, mycelia, photosynthetic bacteria and actinomycetes. Useful microorganisms are good microorganisms such as yeast or lactic acid bacteria. Useful microorganisms can inhibit the growth of harmful microorganisms, or can help the growth of plants.

EM (Effective Micro-organisms) is an abbreviation of useful microorganism group. It is a combination of several microorganisms beneficial to humans among many microorganisms in nature. EM is a useful microorganism produced by cultivating 80 kinds of microorganisms beneficial to humans and the environment and excellent in antioxidant power, regenerative power and purification power. EM has excellent purification ability.

If the useful microorganism is less than 0.1%, it may be difficult to produce a herb fermentation product.

In addition, when the useful microbial population is more than 0.5%, miscibility with other materials and additives used to produce the fragrance may be deteriorated.

Therefore, the beneficial microorganism is preferably 0.1 to 0.5%.

The inoculated product is fermented for 24 to 48 hours at a temperature of 20 to 40 ° C, a stirring speed of 600 to 900 rpm and an aeration amount of 0.2 to 0.5 vvm (S150), and the resultant microorganism monogast and the inoculated product are incubated for 36 hours , The fermentation can be carried out at a temperature of 25 DEG C at a stirring speed of 750 rpm and aeration amount of 0.25 vvm.

Here, vvm, which is the unit of airflow, means volume of air added to liquid volume per minute.

Centrifuging the fermented fermentation broth at 5,000 to 10,000 rpm for 60 to 120 minutes (S160) can ferment fermented fermentation broth for 36 hours at 8,000 rpm for 90 minutes.

The step of separating the supernatant located on the upper part of the centrifuged fermentation broth and filtering the supernatant by filtration (S170) can separate the supernatant and the supernatant by centrifuging the fermentation broth.

Further, in the step of filtering and filtering the supernatant (S170), the supernatant located in the upper part of the centrifuged fermentation broth can be separated and the supernatant of the centrifuged fermentation broth can be squeezed and filtered.

The supernatant can be filtered (filter press, pressure of 2.0 kg / cm 2 or less, filter cloth 500 × 500 × 25 mm).

Accordingly, the supernatant can be obtained as a filtrate through filtration.

For reference, the lower solution may be a fermentation broth in which sediment is located at the bottom after centrifugation.

In the step of lyophilization (S180) of the filtered filtrate under pressure filtration, the filtered filtrate may be freeze-dried.

The filtrate can be lyophilized at -60 to -5 ° C during lyophilization. The freezing time can be from 24 hours to 48 hours.

By freeze-drying, the filtrate can be rapidly cooled to -40 ° C or below to maintain it in a solid state, while making it into a high vacuum state and removing moisture contained in the filtrate. Accordingly, there is an effect that the filtrate due to moisture can be prevented from being corrupted and contaminated.

In addition, the lyophilized filtrate can be pulverized by a pulverizer so as to have a powder shape having uniform properties.

For reference, when the filtrate is lyophilized, its shape changes to solid. The filtrate which has been converted into a solid in this manner can be used in the form of a powder.

The step (S190) of obtaining the powder of the lyophilized herb fermentation product can obtain the lyophilized powder of the herb fermentation product.

When the filtrate has completed lyophilization, the particles can be formed into small powders.

Thus, it is possible to obtain a fermented product in the form of a powder having a uniform property.

The step of mixing the ceramic material (S200) may mix the powder of the fermented herb with the ceramic material.

The ceramic material may include at least one of feldspar porphyry, zeolite, kaolite, diatomaceous earth, benzonite, and talc, which are porous ceramics. The porous ceramic material may be a mesoporous material having a pore diameter of 10 to 100 mu m.

When the diameter of the ceramic is less than 10 mu m, there is a possibility that the aromatic component may not be smudged. When the diameter of the ceramics is more than 100 mu m, the specific surface area in contact with air is increased, so that the life of the interior finishing material can be shortened.

Feldspar porphyry is divided into granitic rocks and chemical granites. Granite rocks are divided into granitic rocks, biotite granite, biotite granite, and translucent granite.

Feldspar porphyry is semi-plagioclase, which is composed mainly of feldspar and is composed of microcrystalline stone mixed with biotite and biotite. In this way, it is hard to distinguish whether or not the anticline is a quartzite or feldspar, so it is called feldspar porphyry.

The characteristics expected when applying feldspar porphyry to paper fragrances are as follows.

Excellent removal of harmful substances and decomposition of heavy metals. It is composed of 30,000 ~ 150,000 multi-layer porous per 1 cm3. It has a large specific surface area and is excellent in adsorption, decomposition, cement toxic neutralization, antimicrobial, insecticide and deodorization functions such as pollutants and heavy metals and recently it is used for removing dioxin.

Zeolite (ZEOLITE) is also called zeolite (zeolite). There are many kinds of zeolite, but there are common features such as high water content, crystal properties, and acidity. The hardness of the zeolite is not more than 6, and the specific gravity is about 2.2.

Zeolites are generally colorless transparent or white translucent. The zeolite was named after it boiled and bloomed when it was heated in the hull.

The zeolite can be adsorbed by other zeolites, because the zeolite is loosely bound to each atom in a crystal structure, and the water filling the space is released as a high heat, the skeleton remains. It is used as an adsorbent by taking advantage of the properties of zeolite and is used as a molecular sieve (molecular sieve) for separating fine particles of different sizes.

The zeolite makes a three-dimensional skeletal structure, but it has pores and contains water molecules and exchangeable cations.

Here, the water molecules are easily removed by heating at a relatively low temperature, but the skeleton of the structure is not changed, so that water vapor is absorbed in the air to fill the water. Such water is called zeolitic water.

The chemical composition can be expressed as [Wy (Si, Al) (O ₂ xnH ₂ O)]. W is mainly Na and Ca, and K, Mg, Ba, and Li are also included.

The application of zeolites in the industrial sector is entirely based on the unique application and mineralogical properties of these minerals.

The application mineralogical properties of zeolite are cation exchange properties, adsorption and molecular sieve properties, catalytic properties and dehydration and reabsorption properties.

The zeolite can be natural zeolite. Zeolite is one of crystalline aluminosilicates. Zeolite refers to a group of white or colorless hydrated aluminum silicate minerals whose main constituent metals are sodium, calcium and potassium and have feldspar-like components. Zeolites have fine pores, molecular sieve action and cation exchange capacity. Zeolites can be used as ion exchangers, adsorbents and catalysts. Zeolites have the ability to remove harmful substances such as heavy metals and dioxins. Zeolites can reduce the action of nitrosamines. The zeolite has an excellent effect of preventing the fragrance from being oxidized.

Kaolite belongs to a 1: 1 structure minerals in which silicate and aluminum plates share oxygen atoms. Kaolite is a substance with a high water absorption rate.

Kaolinite is a group of elevated minerals and has the formula [Al ₂ Si ₂ O ₅ (OH) ₄ ]. Kaolite is a hexahedral plate formed by combining a tetrahedral plate of silicic acid and an aluminum octahedron plate in a 1: 1 ratio. The electric charge of kaolite is the marginal charge mainly formed by breaking the edge surface, and it is charged either negatively or positively depending on the pH of the solution. The isoelectric point of kaolinite is between pH 6 and 7.

Kaolite is a kind of clay and is a monoclinic mineral. The density of kaolite is 2.609, and crystals are usually exposed as a form of absorbing dye.

The chemical composition of kaolite is pyrophosphate in Al ₂ Si ₂ O ₅ (OH) ₄ . The touch of kaolite is slippery, and it becomes materials such as ceramics and clay that are resistant to high temperature. The more these components are, the more suitable for ceramics to withstand high temperatures. Because kaolite is highly absorbent, it has a sticking property and has a characteristic odor.

Diatomite is a collection of sediments made of hard shells called diatoms. Diatomaceous earth accounts for about 90% of the chemical composition of the earth's typical chemical composition, silicic acid.

Diatomaceous earth is mixed with the complex structure of diatomaceous shells and other sediments, and is composed of very low densities and has characteristics of adsorption, transportation, filtration and polishing.

Diatomaceous earth is determined by the type of diatomaceous cells, developmental state, preservation state, impurity content, chemical composition and stability.

Diatomaceous earth is classified according to its physical and chemical uses on the product. Diatomaceous earth is made of innumerable porosity, and each particle is very irregularly shaped, forming a filter cake with 80 ~ 95% porosity and forming many capillary tubules due to unique diatomite particles.

Diatomite can also be used as a filter.

The use of diatomaceous fossils as filter media is commonly referred to as diatomite filtration. This diatomaceous earth is laminated and coated on the surface of a porous support or a filtration cartridge to a thickness of about 2 to 5 mm. This filter medium is a method in which water is pressurized and passed through a pressure vessel or is sucked through a vacuum.

Also, diatomaceous earth can be used as an abrasive.

Diatomaceous earth is a precision cutting abrasive that can be used on all metals and can be polished without causing metal scratches. It is also used for vehicle polish, tile cleaning and toothpaste.

Diatomaceous earth can also be used as an absorbent.

Diatomaceous earth, like zeolite, has internal voids that can absorb 2-3 times more liquid than its own weight. Diatomaceous earth is basically absorbent, which solidifies a liquid, and can prevent the leakage of absorbed material. This feature allows nitroglycerin to be absorbed in diatomite so that it can be stored and transported even more reliably. In the field of agrochemicals, when agrochemicals are manufactured, they can also be used to uniformly separate the agrochemical raw materials into diatomaceous earths in powder form.

Diatomite can also be used as a refractory.

Diatomite has low thermal conductivity. Also, diatomite has a characteristic of being resistant to thermal shock because it does not shrink easily even if it is fired at a high temperature. This feature is used as a very hard refractory. Diatomaceous earth refractory bricks have excellent insulation and soundproofing effect and can withstand up to about 1000 ℃.

 Also, diatomaceous earth can be used as a farm material.

The diatomaceous earth has a pH of about 3.0 to 5.0, and is used as a pH regulator in the myrtle soil in Korea. In addition, diatomaceous earth is excellent in insecticidal effect, and when well dried diatomaceous earth is sprayed on the grain reservoir, it can stick to the outer surface of the insect pest when it inflows, and can absorb and remove moisture of the insect pest.

Diatomaceous earth can also be used as an additive.

Diatomaceous earth has very low density, high water absorption and chemical stability, and can be used as an additive in various places. Diatomaceous earth is mainly used as an additive in the paint, plastic and polyethylene industries. Also, diatomaceous earth is used for the purpose of suppressing gloss, and the microstructure of diatomaceous earth can help adhesion.

Diatomaceous earth is a sedimentary rock in which diatomaceous earth, a kind of phytoplankton, is deposited in the sea or lake and fossilized only in the silicic acid part. Diatomite can purify indoor air. Diatomite has excellent ability to adsorb and decompose harmful substances.

For this reason, diatomaceous earth is a phytoplankton fossil containing about 5,000 pores of activated carbon (charcoal). The diatomaceous earth is referred to as a super porous body because the fine pore-filtered particles are filtered. The micro pores of diatomite can sustain humidity. In addition, diatomaceous earth has a property of removing odor and odor. Further, the diatomite has a large surface area and a small density, is excellent in thermal insulation, and has fire resistance.

Benzonite can detoxify harmful factors such as viruses and fungi.

Talc is a rock-like material composed mainly of magnesium. Talc can be used as a filler, gamma-dye and the like.

Further, montmorillonite, coles, sericite, and calcium bentonite can be further added.

The step S20 of producing the mixture comprises one or more selected from the group consisting of pulverized raw materials, non-sintered binders and pine trees, timber, juniper, yam, rosemary, wormwood, herb, gumoncho, geranium, cinnamon, acacia, dandelion, Or 10 to 80 parts by weight of two or more kinds of natural plant extracts and 10 to 80 parts by weight of vegetable oil may be mixed and then aged for 5 to 15 days to prepare a mixture.

The non-fired binder may be blended with 50 to 60 parts by weight of loess, 20 to 30 parts by weight of clay and 10 to 20 parts by weight of herbal herb to improve the durability of the paper fragrance.

Yellow loam is a harmless natural component binder. Loess is a material composed of iron (Fe), magnesium (Mg), sodium (Na), potassium (K2O), mina (Al2O3), calcium (CaCO3), silica (SiO2) Yellow loess is a yellow mineral composed of 0.05 to 0.01 mm silt particles and emits a large amount of far infrared rays. Hwangto has beneficial effects on human body such as blood circulation and promotion of metabolism, and can neutralize cement toxicity and the like.

The blending amount of the loess is preferably 50 to 60 parts by weight. When the loess is less than 50 parts by weight, the function of the binder may not be exhibited properly. In addition, when the loess exceeds 60 parts by weight, compatibility with other additives may be poor.

Clay means clay or kaolin for white porcelain. White clay becomes white when baked at high temperature. White clay is warm. Therefore, clay can increase the odor of the fragrance.

The blending amount of clay is preferably 20 to 30 parts by weight. If the clay is less than 20 parts by weight, the odor may be insignificant. In addition, when the clay is more than 30 parts by weight, compatibility with other additives may be poor.

Oriental herbs have good ingredients in the human body. Therefore, when herbal medicine is used as a binder of a fragrance, good components in the human body can be formed.

Herbal medicine can be mixed with any one of Chinese herb seeds, corn syrup, gugija, mulberry, sasae, yuan guanxi, plantain, dermis,

The blending amount of herbal medicine is preferably 10 to 20 parts by weight. If the herbal herb is less than 10 parts by weight, the herbal herb's potency may not be exerted properly. In addition, when the herbal medicine is more than 20 parts by weight, compatibility with other additives may be decreased.

In step S20 of preparing the mixture, a liquid component is extracted from a natural plant, and the extracted liquid component is evaporated to a degree of 80% or more by using a centrifuge or a distiller, : 1 to 1: 3, followed by aging for 5 to 15 days to form an oil.

For example, 10 to 80 parts by weight of an extract of a natural plant and 10 to 80 parts by weight of a vegetable oil are mixed and then aged for 5 to 15 days to form a mixture.

Here, in the case of extracting a liquid-phase extract component, in the case of a plant having a lot of moisture such as mugwort, it is extracted into a liquid form using a green juice, and in case of a dried plant such as a pine tree or a juniper, And boiled at about 100 캜 for 3 hours to 4 hours to extract the liquid phase.

At this time, the natural plant may be used alone, or a mixture of two or more components may be applied depending on the function.

The step of microencapsulating the mixture (S30) comprises completely removing the water again by mixing and aging the antibacterial, fragrance and insect repellent material in the form of oil, using a distiller or the like, and removing the moisture-removed antibacterial, Can be mixed.

That is, the moisture of the mixture is completely removed to form a powder, which is mixed with a polymer compound and microencapsulated.

Herein, the microencapsulation method of enclosing the inside of the antibacterial, fragrance and pest control material with the external polymer material is not particularly limited and may be adopted as long as it is a method commonly known in the art.

The step of microencapsulating the mixture (S30) can be carried out in the form of microparticles having a microcapsule diameter of several micrometers to several hundreds of micrometers in size so that the effect of the microcapsules is enhanced in direction . The step of microencapsulating the mixture (S30) may have a microcapsule diameter of 5 to 500 mu m.

As a material of the polymer compound, synthetic polymers such as water-soluble proteins such as gelatin and casein, carbohydrates such as cellulose, and copolymers of vinyl compound and phthalic anhydride can be used.

In step S40 of spraying the microcapsules onto paper, the microcapsules, the urethane binder, the resin binder or the polyethyl acrylate binder may be diluted in a ratio of 1: 1 to 1: 3, and then sprayed onto the paper.

The primary drying step (S50) of the paper may be performed at a temperature of 15 to 30 DEG C for 12 to 24 hours after removing moisture through a pressing process.

The step of dipping the dried paper (S60) can immerse the dried paper in the coating material for 6 to 48 hours.

The coating material can impart the function of the water repellency, fire resistance, flame retardancy and anti-corrosiveness of the fragrance. Further, the coating material may be a natural material.

5 to 10 parts by weight of natural extracted polyphenol, 5 to 10 parts by weight of pine rosin and 1 to 5 parts by weight of natural latex extract may be mixed with the coating material.

Polyphenols are antioxidants that convert active oxygen (harmful oxygen) in the body into harmless substances. Polyphenols have the ability to protect DNA from damage by exposure to reactive oxygen species. The polyphenol can be a natural polyphenol that does not contain a chemical.

The blending amount of the naturally extracted polyphenol is preferably 5 to 10 parts by weight. If the amount of the polyphenol is less than 5 parts by weight, the effect of the polyphenol may not be exhibited properly. When the polyphenol content is more than 10 parts by weight, compatibility with other additives may be deteriorated.

The rosin is a colorless transparent liquid that is secreted when the pine tree is damaged. Songjin has the property of not dissolving in water. Songjin is used as a waterproofing agent.

The blending amount of the rosin is preferably 5 to 10 parts by weight. If the amount of the rosin is less than 5 parts by weight, the waterproof property may not be exhibited properly. Further, when the amount of the rosin is more than 10 parts by weight, compatibility with other additives may be deteriorated.

Natural latex means rubber having 85% or more natural rubber. The remaining 15% of the natural latex can be foamed. Natural latex is excellent in water resistance.

The blending amount of the natural latex extract is preferably 1 to 5 parts by weight. When the amount of the natural latex extract is less than 1 part by weight, the waterproof property may not be exhibited properly. In addition, when the amount of the natural latex extract is more than 5 parts by weight, miscibility with other additives may be deteriorated.

Further, when a coating material prepared by mixing 5 to 10 parts by weight of natural extracted polyphenol, 5 to 10 parts by weight of rosin and 1 to 5 parts by weight of natural latex extract is used as a coating solution, it can be melted at a Tg or more of each material.

The step of secondary drying the immersed paper (S70) may dry the immersed paper at 15 ° C to 30 ° C for 12 to 24 hours.

The step S80 of printing a message on the front and back sides of the paper is performed by printing the message 50 on the front and back sides of the paper 20 or by printing the message 50 on the front side and the rear side of the paper 20, . The printing step S80 of printing a message on the front and back sides of the paper may use a printing paint or a luminous paint on the yarn so that the message 50 can enhance the cyanicity while emitting light even in a dark place or at night.

The step S90 of attaching the silicone seal in a strip shape on the front and back surfaces of the paper is performed by attaching the silicone seal 30 to the front and rear surfaces of the paper 20, It is possible to prevent the oil from falling off from the surface of the paper sheet 20 when the oil is bared.

The step of attaching a plurality of transparent stickers (S100) to each of the divided ranges of the silicone seals can attach a plurality of transparent stickers (40) to each of the divided ranges of the silicone seals (30) attached to the surface of the paper .

Accordingly, when the paper fragrance 10 has a certain period of time or does not have a fragrance in the divided range, the paper fragrance 10 has an effect of maintaining a constant fragrance while peeling off the transparent stickers 40 in the other divided areas.

Hereinafter, the paper perfume of the present invention and its production method will be described in more detail with reference to examples. The analysis results of the paper fragrances and the comparative examples used in the examples are shown in the table.

It is to be understood, however, that these examples are provided so that the scope of the present invention is not limited thereto.

For comparison, paper fragrances (Example 1), paper fragrances without microcapsules (Example 2) and comparative examples (paper fragrances not coated with coating materials) were compared.

[Example 1] A paper fragrance according to an embodiment of the present invention

10% (w / v) of a herb as an organic directional powder was added to 10 liters of distilled water (L), and the resultant mixture of distilled water and herb was sterilized at 90 degrees for 60 minutes. The sterilized resultant was cooled at 20 degrees, The resulting product was inoculated with 0.5% (w / v) of EFFECTIVE MICROORGANISMS and the inoculated product was fermented for 48 hours at a temperature of 40 ° C, a stirring speed of 900 rpm and aeration amount of 0.5 vvm, Centrifuged at 10,000 rpm for 120 minutes, the supernatant located at the upper part of the centrifuged fermentation broth was separated, the supernatant was filtered, the freeze-dried filtered filtrate was lyophilized, and the ceramic material 20 The raw material is pulverized and the pulverized raw material, the non-sintered binder and the pine wood, the white wood, the juniper, the yam, the rosemary, the wormwood, the herb, the gumoncho, the geranium, the cinnamon, the acacia, the dandelion, Lily , 80 parts by weight of a natural plant extract selected from the group consisting of vegetable oil and vegetable oil, and 80 parts by weight of vegetable oil were mixed and aged for 15 days to prepare a mixture. The water of the mixture was completely removed to form a powder, The microcapsules were mixed with a urethane binder or a resin binder or polyethylacrylate in a weight ratio of 1: 3, sprayed onto paper by a spraying method, the paper was subjected to a pressing process to remove water, And the dried paper is immersed in the coating material for 48 hours and the dipped paper is secondarily dried at room temperature and the non-fired binder is added to the loess 60, based on 100 parts by weight of the herb fermentation, 30 parts by weight of clay and 20 parts by weight of herbal herb were mixed, and the coating material was mixed with the herb fermentation product 100 Amount of a mixture of polyphenols, 10 parts by weight of rosin, 10 parts by weight and 5 parts by weight of natural latex extract the reference section were prepared paper perfume.

[Example 2] A paper fragrance to which a microcapsule was not added according to an example of the present invention

10% (w / v) of a herb as an organic directional powder was added to 10 liters of distilled water (L), and the resultant mixture of distilled water and herb was sterilized at 90 degrees for 60 minutes. The sterilized resultant was cooled at 20 degrees, The resulting product was inoculated with 0.5% (w / v) of EFFECTIVE MICROORGANISMS and the inoculated product was fermented for 48 hours at a temperature of 40 ° C, a stirring speed of 900 rpm and aeration amount of 0.5 vvm, Centrifuged at 10,000 rpm for 120 minutes, the supernatant located at the upper part of the centrifuged fermentation broth was separated, the supernatant was filtered, the freeze-dried filtered filtrate was lyophilized, and the ceramic material 20 A raw material is pulverized, and the pulverized raw material is mixed with a urethane binder, a resin binder or polyethylacrylate at a weight ratio of 1: 3, and then the mixture is sprayed on paper , The paper is firstly dried at room temperature after removing moisture through a press process, the dried paper is immersed in the coating material for 48 hours, the paper after the immersion is secondarily dried at room temperature, and the non- To enhance the durability, 60 parts by weight of loess, 30 parts by weight of clay and 20 parts by weight of herbal herb were mixed based on 100 parts by weight of the herb fermentation product. The coating material contained 10 parts by weight of polyphenol, And 5 parts by weight of the natural latex extract were mixed to prepare paper fragrances.

[Comparative Example 1]

10% (w / v) of a herb as an organic directional powder was added to 10 liters of distilled water (L), and the resultant mixture of distilled water and herb was sterilized at 90 degrees for 60 minutes. The sterilized resultant was cooled at 20 degrees, The resulting product was inoculated with 0.5% (w / v) of EFFECTIVE MICROORGANISMS and the inoculated product was fermented for 48 hours at a temperature of 40 ° C, a stirring speed of 900 rpm and aeration amount of 0.5 vvm, Centrifuged at 10,000 rpm for 120 minutes, the supernatant located at the upper part of the centrifuged fermentation broth was separated, the supernatant was filtered, the freeze-dried filtered filtrate was lyophilized, and the ceramic material 20 The raw material is pulverized and the pulverized raw material, the non-sintered binder and the pine wood, the white wood, the juniper, the yam, the rosemary, the wormwood, the herb, the gumoncho, the geranium, the cinnamon, the acacia, the dandelion, Lily , 80 parts by weight of a natural plant extract selected from the group consisting of vegetable oil and vegetable oil, and 80 parts by weight of vegetable oil were mixed and aged for 15 days to prepare a mixture. The water of the mixture was completely removed to form a powder, The microcapsules were mixed with a urethane binder, a resin binder or polyethyl acrylate at a weight ratio of 1: 3, sprayed onto paper by a spraying method, the paper was subjected to a pressing process to remove moisture, A perfume was prepared.

For reference, this Comparative Example 1 is a product in which the coating material is not coated.

≪ Test example of paper fragrance >

The deodorization rates of ammonia, formaldehyde, toluene, methylmercaptan, trimethylamine and hydrogen sulfide of the paper fragrance prepared in Example 2 were measured and the results are shown in Tables 1 to 6.

For reference, Tables 1 to 6 show the deodorization rates of ammonia, formaldehyde, toluene, methylmercaptan, trimethylamine and hydrogen sulfide of paper fragrances as a result of measuring the residual gas concentration based on KS I 2218: 2009.

 Ammonia deodorization test of paper fragrance Test Items Elapsed time (minutes) Blank concentration
(μmol / mol) Sample concentration
(μmol / mol) Deodorization rate (%) Ammonia [NH ₃ ] deodorization test 0 50 50 0.0 30 49 24 51.0% 60 49 20 59.1% 90 49 16 67.3% 120 48 15 68.7%

Formaldehyde deodorization test of paper fragrance Test Items Elapsed time (minutes) Blank concentration
(μmol / mol) Sample concentration
(μmol / mol) Deodorization rate (%) Formaldehyde [HCHO] deodorization test 0 50 50 0.0 30 49 26 46.9% 60 49 23 53.0% 90 49 17 65.3% 120 48 16 66.6%

Toluene deodorization test of paper fragrance Test Items Elapsed time (minutes) Blank concentration
(μmol / mol) Sample concentration
(μmol / mol) Deodorization rate (%) toluene
[C ₆ H ₅ CH ₃ ] deodorization test 0 50 50 0.0 30 49 40 18.3% 60 49 34 30.6% 90 49 27 44.8% 120 48 22 54.1%

Deodorization test of methylmercaptan of paper fragrance Test Items Elapsed time (minutes) Blank concentration
(μmol / mol) Sample concentration
(μmol / mol) Deodorization rate (%) Methylmercaptan [CH ₃ SH] deodorization test 0 50 50 0.0 30 49 38 22.4% 60 49 33 32.7% 90 49 31 36.7% 120 48 25 47.9%

Deodorization test of paper perfume with threylmethylamine Test Items Elapsed time (minutes) Blank concentration
(μmol / mol) Sample concentration
(μmol / mol) Deodorization rate (%) Deodorization test of tritylmethylamine [(CH ₃ ) ₃ N] 0 50 50 0.0 30 49 28 42.8% 60 49 25 48.9% 90 49 24 51.0% 120 48 20 58.3%

Hydrogen sulfide deodorization test of paper fragrance Test Items Elapsed time (minutes) Blank concentration
(μmol / mol) Sample concentration
(μmol / mol) Deodorization rate (%) Hydrogen sulfide
[H ₂ S]
Deodorization test 0 50 50 0.0 30 49 31 36.7% 60 49 27 44.8% 90 49 23 53.0% 120 48 21 56.2%

As shown in Tables 1 to 6, the deodorization rates of paper fragrances according to the examples of the present invention were 18.3% to 68.7% in all items of the deodorization test for ammonia, formaldehyde, toluene, methylmercaptan, trimethylamine and hydrogen sulfide, And it was confirmed that the deodorizing effect was very good.

Referring to Tables 1 to 6, paper air freshener according to an embodiment of the present invention has excellent deodorizing property in deodorizing indoor pollutants.

The present invention can release the fragrance of the hub and the like while removing the odor fundamentally.

The paper air freshener according to the embodiment of the present invention can increase the time of smell, and the smell can be constantly and continuously smelled.

The present invention also has the advantage of being semi-permanently reusable with oil spray.

In addition, the present invention can solve the chemical side effects of conventional fragrances.

The paper air freshener according to an embodiment of the present invention has a function of dehumidifying an inorganic material other than a directional function and removing a harmful substance by establishing a ceramic material and a binding binder utilizing application and mineralogical characteristics.

In addition, the blending amount of the paper fragrance according to the embodiment of the present invention was selected in consideration of the pseudo ratio considering the strength, durability and moldability.

The paper air freshener according to the embodiment of the present invention is an interior finishing material that emits far-infrared rays and negative ions, and can absorb and clean harmful substances such as formaldehyde, antifungal and carbon dioxide in a room or an automobile interior, .

Further, the paper fragrance according to the embodiment of the present invention is excellent in moisture absorption, moisture absorption and sucking performance.

Further, the paper air freshener according to the embodiment of the present invention can improve indoor air quality and is excellent in deodorizing action.

Further, by using the paper perfume according to the embodiment of the present invention, a message can be delivered and the advertisement effect is excellent.

While the present invention has been described in connection with what is presently considered to be practical exemplary embodiments, it is to be understood that the invention is not limited to the disclosed embodiments, but, on the contrary, It will be clear to the person.

1: Paper air freshener
2: Tributary
3: Messages
4: Coated paper
10: Paper fragrances
20: Paper
30: Silicone seal
40: transparent sticker
50: Message

Claims (10)

(a) preparing a tributary;
(b) spraying on said feed stream;
(c) drying said feed stream and
(d) sealing said tributary. The method according to claim 1,
After the step (c)
Further comprising the step of printing a message on the front or back side of said tributary,
In the step (b)
Wherein the spray is applied with a hub oil or aroma oil. A paper fragrance produced by the method of any one of claims 1 or 2. (a) preparing and pulverizing a raw material;
(b) one or more natural materials selected from the above-mentioned pulverized raw materials, non-sintered binders and pine wood, timber, kale, yam, rosemary, wormwood, herb, gumoncho, geranium, cinnamon, acacia, dandelion, rose and lily 10 to 80 parts by weight of a plant extract and 10 to 80 parts by weight of a vegetable oil are mixed and aged for 5 to 15 days to prepare a mixture;
(c) completely removing water from the mixture to form a powder, mixing the mixture with a polymer compound, and microencapsulating the mixture;
(d) mixing the microcapsules with a urethane binder, a resin binder or polyethyl acrylate at a weight ratio of 1: 1 to 1: 3, and spraying the mixture onto paper by spraying;
(e) removing water from the paper through a pressing process, and then drying the paper at room temperature;
(f) immersing the dried paper in the coating material for 6 to 48 hours and
(g) secondarily drying the dipped paper at room temperature,
The non-fired binder is prepared by mixing 50 to 60 parts by weight of loess, 20 to 30 parts by weight of clay and 10 to 20 parts by weight of herbal herb based on 100 parts by weight of the fermented product of the herb to improve the durability of the paper fragrance,
Wherein the coating material comprises 5 to 10 parts by weight of polyphenol, 5 to 10 parts by weight of rosin and 1 to 5 parts by weight of a natural latex extract based on 100 parts by weight of the fermented herb. 5. The method of claim 4,
The raw material preparation in the step (a)
Adding 5 to 10% (w / v) of a herb as an organic directional powder to 10 liters (L) of distilled water;
Sterilizing the resultant mixture of the distilled water and the hub at 80 to 90 degrees for 10 to 60 minutes;
Cooling the sterilized product at 10 to 20 degrees;
Inoculating the cooled product with 0.1% to 0.5% (w / v) of a useful microorganism monarch (EFFECTIVE MICROORGANISMS);
Fermenting the inoculated product at a temperature of 20 to 40 degrees C for 24 to 48 hours, a stirring speed of 600 to 900 rpm and an air flow rate of 0.2 to 0.5 vvm;
Centrifuging the fermented fermentation broth at 5,000 to 10,000 rpm for 60 to 120 minutes;
Separating the supernatant located on the upper part of the centrifuged fermentation broth and compressing the supernatant liquid;
Lyophilizing the filtered filtrate by filtration;
Obtaining a powder of the lyophilized herb fermentation product and
And mixing the ceramic material. 6. The method of claim 5,
The ceramic material may be,
A method of producing a paper fragrance comprising at least one of porous ceramic feldspar porphyry, zeolite, kaolite, diatomaceous earth, benzonite, and talc. 6. The method of claim 5,
The useful microorganism monarch is selected from the group consisting of Lactobacillus delbrueckii, Lactobacillus casei, Lactobacillus bulgaricus, Lactobacillus plantarum, Lactobacillus rhamnosus, And Micrococcus. ≪ Desc / Clms Page number 24 > 5. The method of claim 4,
Wherein the microcapsules are produced in the form of ultrafine particles having a microscopic size of several micrometers to several hundreds of micrometers in diameter so that the effect of the microcapsules in the direction increases in the step (c) ≪ / RTI > 5. The method of claim 4,
After the step (g)
Printing a message on the front and back sides of the paper;
Attaching a silicone seal on the front and back surfaces of the paper in a strip shape, and
And attaching a plurality of transparent stickers to each of the confined ranges of the silicone seal. A paper fragrance produced by the method of any one of claims 4 to 9.

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