KR20170063156A - Circuit protection device and mobile electronic device with the same - Google Patents
Circuit protection device and mobile electronic device with the same Download PDFInfo
- Publication number
- KR20170063156A KR20170063156A KR1020150169200A KR20150169200A KR20170063156A KR 20170063156 A KR20170063156 A KR 20170063156A KR 1020150169200 A KR1020150169200 A KR 1020150169200A KR 20150169200 A KR20150169200 A KR 20150169200A KR 20170063156 A KR20170063156 A KR 20170063156A
- Authority
- KR
- South Korea
- Prior art keywords
- electrode
- electric shock
- shock protection
- capacitor
- internal
- Prior art date
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Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01C—RESISTORS
- H01C7/00—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material
- H01C7/10—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material voltage responsive, i.e. varistors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G4/00—Fixed capacitors; Processes of their manufacture
- H01G4/40—Structural combinations of fixed capacitors with other electric elements, the structure mainly consisting of a capacitor, e.g. RC combinations
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K9/00—Screening of apparatus or components against electric or magnetic fields
- H05K9/0007—Casings
- H05K9/0009—Casings with provisions to reduce EMI leakage through the joining parts
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K9/00—Screening of apparatus or components against electric or magnetic fields
- H05K9/0067—Devices for protecting against damage from electrostatic discharge
Landscapes
- Engineering & Computer Science (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Manufacturing & Machinery (AREA)
- Thermistors And Varistors (AREA)
Abstract
An electric shock protection device and a portable electronic device having the same are provided. The present invention relates to an electric shock protection element disposed between a body contactable conductor of an electronic device and a built-in circuit portion, comprising: a first body; a plurality of first internal electrodes arranged in a line in the first body; An electric shock protection unit including a second internal electrode spaced apart from the other electrodes; An outer electrode formed on an outer surface of the first element to be electrically connected to the first inner electrode and the second inner electrode; And a glass coating layer formed on the outer surface of the body including at least an area where the outer electrode and the outer surface of the body contact each other. According to this, it is possible to protect the user from the leakage current by the power source, protect the internal circuit from external static electricity, significantly improve the mechanical strength of the device, and maintain the initial design property even if the device is electrochemically post-treated .
Description
The present invention relates to an electric shock protection device and a portable electronic device having the same.
Recently, the adoption of a metal-made housing has been increasing in order to improve aesthetics and robustness of portable electronic devices.
However, since the metal housing is excellent in electrical conductivity due to the nature of the material, an electrical path can be formed between the housing and the built-in circuit depending on the particular device or part. Particularly, since the metal housing and the circuit part form a loop, when a static electricity having a high voltage instantaneously flows through a conductor such as a metal housing having a large exposed surface area, the circuit part such as an IC can be damaged, Measures are required.
On the other hand, such a portable electronic device typically uses a charger to charge the battery. Such a charger rectifies an external AC power source to a DC power source and then through a transformer to a low DC power source suitable for a portable electronic device. Here, in order to enhance the electrical insulation of the transformer, a Y-CAP composed of a capacitor is provided at both ends of the transformer.
However, when the Y-CAP does not have the normal characteristics, such as a non-genuine charger, the DC power may not be sufficiently blocked by the Y-CAP, and furthermore, a leakage current may be generated by the AC power. As shown in FIG.
Such a leakage current can be transmitted to a conductor that can be contacted with a human body as in an external case of a portable electronic device. As a result, the user can give an unpleasant feeling of crushing and, in severe cases, You can wear it.
Therefore, a portable electronic device such as a cellular phone employing a metal case is required to protect the user from such a leakage current.
On the other hand, since the device being studied for this purpose must be mounted on a printed circuit board through a conventional reflow soldering method or the like, an electrode (external electrode) is provided on the outer surface of the device so as to be electrically connected to the circuit board , The external electrode is easily peeled due to low adhesive strength due to compatibility with the outer surface of the device.
In order to improve the wettability during reflow soldering, plating of the outer electrode surface with nickel, lead, tin or the like is required, but the plating solution for this purpose can penetrate into the inside of the device, There is a problem that the function of a device designed to cut off the leakage current or protect the circuit from static electricity may be remarkably deteriorated.
Accordingly, there is a demand for a method for maintaining the inherent physical properties even when the device is subjected to a post-treatment process such as a plating solution, in addition to the protection from static electricity and the interruption of leakage current, and the mechanical strength of the device is remarkably improved.
SUMMARY OF THE INVENTION The present invention has been made in view of the above-described circumstances, and it is an object of the present invention to provide a method of protecting an internal circuit and / or a user from a leakage current caused by static electricity or an external power source, remarkably improving the mechanical strength of the device, An object of the present invention is to provide an electric shock protection device and a portable electronic device having the same.
An object of the present invention is to provide an electric shock protection device which is disposed between a body contactable conductor of an electronic device and a built-in circuit portion, comprising: a first body; a plurality of first internal electrodes arranged in a line in the first body; An electric shock protection unit including a plurality of first internal electrodes and a second internal electrode spaced apart from the first internal electrodes; An outer electrode formed on an outer surface of the first element to be electrically connected to the first inner electrode and the second inner electrode; And a glass coating layer formed on the outer surface of the body including at least an area where the outer electrode and the outer surface of the body contact each other.
In addition, it is possible to pass the static electricity without causing insulation breakdown when the static electricity flows from the conductor, and to prevent leakage current of the external power source flowing from the ground of the circuit part.
Vbr > Vin where Vbr is the breakdown voltage of the electric shock protection element, and Vin is the rated voltage of the external power supply of the electronic device.
In addition, the rated voltage may be a national standard rated voltage.
The plurality of electrodes may be arranged in a line in the second internal electrode.
Each of the second internal electrodes may be disposed so as to overlap at least part of the first internal electrode.
In addition, each of the second internal electrodes may be disposed so as not to overlap with the first internal electrode.
The distance L between any two first internal electrodes disposed adjacent to and closest to the second internal electrodes among the plurality of first internal electrodes may be a distance between the first internal electrodes and the second internal electrodes, May be larger than the sum of the shortest distances (d1, d2).
The first elementary body may be formed of a plurality of sheet layers, at least a part of the sheet layer may be formed of a first varistor composition, and the remaining sheet layer may be formed of a second varistor composition different from the first varistor composition .
The thicknesses of the first internal electrode and the second internal electrode may independently be 2 to 10 탆.
Further, the glass coating layer may be formed on the outer surface of the body. The glass coating layer may be formed of a material selected from the group consisting of aluminum, silicon, germanium, indium, tin, lead, phosphorus, boron, gallium, lithium, sodium, potassium, rubidium, cesium, beryllium, magnesium, calcium, strontium, barium, neodymium, praseodymium, And may include at least one element selected from cerium, titanium, zirconium, tantalum, zinc, tungsten, vanadium, chromium, manganese, iron, cobalt, nickel, copper and molybdenum. In addition, the average thickness of the glass coating layer may be A to B m.
In order to allow a communication signal flowing from the conductor to pass therethrough, a second elementary body disposed at one side of the first elementary body of the electric shock protection element and at least a part of the electrode are provided inside the second elementary element, And a capacitor portion including a capacitor electrode electrically connected to the electrode. At this time, Vcp > Vbr, where Vcp is the dielectric breakdown voltage of the capacitor portion.
Also, the capacitor unit may be electrically connected in parallel with the electric shock protection unit.
In addition, the second element may include a dielectric.
The breakdown voltage Vbr of the electric shock protection element may be the sum of the unit breakdown voltages formed between the first and second inner electrodes adjacent to each other.
According to another aspect of the present invention, there is provided an electric shock protection element disposed between a body contactable conductor of an electronic device and a built-in circuit, comprising: a first body; a plurality of first internal electrodes arranged in a line in the first body; An electric shock protection unit including a first internal electrode and a second internal electrode spaced apart from the first internal electrode; And a capacitor electrode provided in the second elementary body so that at least a part of the surfaces of the second elementary body and the electrode disposed on one side of the first elementary body of the electric shock protection element for allowing the communication signal flowing from the conductor to pass therethrough, A capacitor portion; An external electrode formed on an outer surface of the first and second main bodies so as to be electrically connected to the first internal electrode, the second internal electrode, and the capacitor electrode; And a glass coating layer formed on the outer surface of the body including the outer surface of the body including the first body and the second body and the region in contact with the outer electrode.
On the other hand, the present invention provides a human body contactable conductor; Circuitry; And an electric shock protection element disposed between the conductor and the circuit portion, wherein the electric shock protection element includes a first elementary body, a plurality of first inner electrodes disposed in a line in the first elementary body, An electric shock protection unit including a second internal electrode spaced apart from an electrode and another column; An outer electrode formed on an outer surface of the first element to be electrically connected to the first inner electrode and the second inner electrode; And a glass coating layer formed on the outer surface of the body including at least an area where the outer electrode and the outer surface of the body contact each other.
In addition, the conductor may include at least one of an antenna, a metal case, and conductive ornaments for communication between the electronic device and an external device.
In addition, the metal case may be provided to partially surround or entirely surround the side of the housing of the electronic device.
In addition, the metal case may be provided to surround the camera, which is exposed to the outside on the front surface or the rear surface of the housing of the electronic device.
The present invention also relates to a human body contactable conductor; Circuitry; And an electric shock protection element disposed between the conductor and the circuit portion, wherein the electric shock protection element includes a first elementary body, a plurality of first inner electrodes disposed in a line in the first elementary body, An electric shock protection unit including a second internal electrode spaced apart from an electrode and another column; And a capacitor electrode provided in the second elementary body so that at least a part of the surfaces of the second elementary body and the electrode disposed on one side of the first elementary body of the electric shock protection element for allowing the communication signal flowing from the conductor to pass therethrough, A capacitor portion; An external electrode formed on an outer surface of the first and second main bodies so as to be electrically connected to the first internal electrode, the second internal electrode, and the capacitor electrode; And a glass coating layer formed on the outer surface of the body including the outer surface of the body including the first body and the second body and the region where the outer electrode abuts the body, and a portable electronic device having an electric shock protection function.
The present invention also provides a method of manufacturing a semiconductor device, comprising the steps of: (1) sintering a multilayer body including a plurality of first internal electrodes arranged in a line spaced apart and a second internal electrode spaced apart from the other first internal electrodes; ; (2) forming a glass coating layer on the outer surface of the first elementary body including at least the first outer surface of the first elementary body in a region corresponding to the inner electrode of the first elementary body; And (3) forming an external electrode to be electrically connected to the internal electrode.
(A) a first laminate including a plurality of first inner electrodes spaced in a line and a second inner electrode spaced apart from the other first inner electrodes; Forming a first body and a second body by sintering a second layered body disposed on one side of the first layered body including capacitor electrodes provided so as to overlap each other; (B) an outer surface of a first elementary body including at least an outer surface of a first elementary body of a region corresponding to an inner electrode of the first elementary body and a second elementary body outer surface corresponding to a capacitor electrode of the second elementary body, Forming a glass coating layer on the substrate; And (C) forming an external electrode to be electrically connected to the internal electrode and the capacitor electrode.
An electric shock protection device and a portable electronic device having the same according to an embodiment of the present invention include an electric shock protection device for connecting a conductor and a circuit portion in a portable electronic device in which a conductor such as a metal case is exposed to the outside, It protects the user and internal circuits from leakage current and static electricity and realizes high capacitance, minimizing the attenuation of the communication signal and delivering it.
1 is a perspective view of an electric shock protection device according to an embodiment of the present invention. FIG. 1B is an exploded perspective view of an electric shock protection unit included in an electric shock protection device, and FIG. 1C is a longitudinal sectional view of FIG. 1A,
2 is a longitudinal sectional view of an electric shock protection device according to an embodiment of the present invention,
FIG. 3 is a view showing an electric shock protection unit included in an embodiment of the present invention. FIG. 3 (a) is an exploded perspective view of the electric shock protection unit, FIG. 3
FIG. 4 is a perspective view of an electric shock protection unit included in an embodiment of the present invention, FIG. 4A is an exploded perspective view of the electric shock protection unit, FIG. 4B is a longitudinal sectional view of FIG.
FIG. 5 is a longitudinal sectional view of an electric shock protection unit included in an embodiment of the present invention, FIGS. 5A and 5B are diagrams illustrating various positional relationships of internal electrodes included in the electric shock protection unit,
FIG. 6 is a perspective view of an electric shock protection device according to an embodiment of the present invention. FIG. 6B is an exploded perspective view of the electric shock protection device included in the electric shock protection device. 6C is a longitudinal sectional view of FIG. 6A,
7A and 7B are views showing various arrangements of the electric shock protection unit and the capacitor unit in the electric shock protection device according to the embodiment of the present invention,
8A to 8E are views showing various forms of a capacitor portion made of dissimilar materials in an electric shock protection device according to an embodiment of the present invention,
FIGS. 9A to 9E are conceptual diagrams showing an application example of an electric shock protection device according to an embodiment of the present invention,
10A to 10C are schematic equivalent circuit diagrams for explaining operation of (a) leakage current, (b) static electricity (ESD), and (c) communication signal of the electric shock protection device according to the embodiment of the present invention,
11A and 11B show simulation results of the pass frequency band according to the capacitance,
Figs. 12A and 12B are SEM photographs of the surface of a sintered body, Fig. 12A is a photograph of a surface of a sintered body having no glass coating layer formed thereon, and Fig. 12B is a photograph of a sintered body surface after a glass coating layer is formed.
Hereinafter, exemplary embodiments of the present invention will be described in detail with reference to the accompanying drawings, which will be readily apparent to those skilled in the art to which the present invention pertains. The present invention may be embodied in many different forms and is not limited to the embodiments described herein. In order to clearly illustrate the present invention, parts not related to the description are omitted, and the same reference numerals are assigned to the same or similar components throughout the specification.
1A to 1C, an electric
The electric
Vbr> Vin where Vbr is the sum of the breakdown voltages formed between the nearest first
At this time, the
The first
When the electric shock protection housing according to an embodiment of the present invention is not further provided with a
The internal electrodes included in the
The
The breakdown voltage Vbr of the electric
The first
At this time, the first internal electrode or the second internal electrode does not leak static electricity or leakage current to adjacent external electrodes (not shown) of the
For example, a distance L between any two first
The distance between the second
More specifically, the first
At this time, the first
In addition, the second
Here, the first
When the plurality of sheets are stacked, the electric
In another example, the electric shock protection unit 210 'may be laminated so that the first
The
The outer electrode may further include a plating layer (not shown) on the surface of the electrode to further improve ease of soldering and electrical connection when the device is mounted on a circuit board by flow soldering or the like. The plating layer may be formed using a conventional plating method, and may include at least one of metals such as nickel, tin, copper, and tin-lead alloys. At this time, when two or more kinds of metals are included, two or more kinds may be included in one layer in the form of a mixture or an alloy, or a plating layer may be formed of a plurality of layers and each layer may be formed of one kind of metal . The thickness of the plating layer may be 0.1 to 5 탆, but is not limited thereto.
On the other hand, a
The
If the thickness is less than 0.5 탆, the
As described above, the electric shock protection housing according to an embodiment of the present invention includes (1) a plurality of first internal electrodes spaced in a line and a second internal electrode spaced apart from the first internal electrodes Sintering the laminate to produce a first body; (2) forming a glass coating layer on the outer surface of the first elementary body including at least the first outer surface of the first elementary body in a region corresponding to the inner electrode of the first elementary body; And (3) forming an external electrode to be electrically connected to the internal electrode.
First, in step (1), a first
The varistor sheet layers 111 and 112 can be manufactured by press molding the varistor sheet forming composition into a sheet form. The composition for forming a varistor sheet may include a varistor forming component, and may further include a binder, a curing agent, a solvent, and the like. The varistor forming component may include at least one of a semiconductive material, a Pr-based material, and a Bi-based material including at least one of ZnO, SrTiO 3 , BaTiO 3 , and SiC. The average particle diameter of the varistor forming component powder may be 0.1 to 5 占 퐉, for example, 0.1 to 1 占 퐉. If the average particle diameter of the powder is less than 0.1 占 퐉, there may be a problem of greatly increasing the manufacturing cost. If the average particle diameter exceeds 1 占 퐉, if two or more kinds of varistor forming components are mixed for controlling the sintering temperature, The sintered body may not be uniformly mixed and there may be a problem that the first sintered body does not have a proper volume shrinkage ratio after sintering.
Accordingly, the varistor forming component may be pulverized through mechanical milling or the like so as to have an aimed average particle size before mixing with the binder, and then dried. The drying process may be performed at a temperature of 50 to 200 for 30 minutes to 10 hours, but is not limited thereto. After the drying process, the final dielectric powder can be prepared by further pulverizing to have the desired average particle size.
The binder can be used without limitation in the case of a binder used for producing a known green sheet, and as a non-limiting example thereof, a polyvinyl butyral resin, a polyvinylacetate resin, and a polyacrylic resin And the like. The binder may be mixed in an amount of 1 to 30 parts by weight based on the total weight of the varistor forming component and the binder. If the binder is contained in an amount of less than 1 part by weight, the binder strength of the varistor-forming component is lowered, and the mechanical strength of the body may be considerably lowered even after sintering. In addition, if the binder is contained in an amount exceeding 30 parts by weight, the air permeability of the sheet itself after being manufactured into a sheet form is not good, and an internal air trap may occur when a thick film staking method is applied. And the adhesion may be increased even with a small amount of moisture, and workability may be deteriorated, and volume shrinkage during drying of the sheet is remarkable, and there is a possibility that the sheet bends or the quality of the surface is deteriorated.
Further, the solvent may be water, a known organic solvent, and may vary depending on the specific kind of the binder selected, so that the present invention is not particularly limited thereto.
The above-described varistor sheet-forming composition can be molded into a single sheet layer, for example, by press molding. The press molding may be performed using a general press molding method used in the art. For example, the granules are put into a molding mold having a diameter of 7.0 to 10.0 mm, and then a pressure of 800 to 1,200 kg / A press molded product to be produced can be produced. Thereafter, the first
The varistor sheet layers 111 and 112 formed on one surface of the
Etching the outer surface of the first body by the step 1-2) of the first body produced through steps 1-1) described above.
The etching is performed by protruding the
The etching can be carried out through conventional dry etching or wet etching, for example, through a hydrochloric acid solution when wet etching is performed. The hydrochloric acid solution may be used at a concentration of 1 to 50 vol%, and the concentration may be changed according to the size and composition of the first body to be etched. Also, the etching time can be performed for 1 minute to 24 hours, and the etching time can be changed depending on the size of the body and the concentration of the etching solution used. Meanwhile, the step 1-2) should be performed at an appropriate level, and the degree of surface corrosion of the first element is too high when the first element is etched and the glass coating layer is not formed properly in step 2) The glass coating layer is unstable, and the coating blur increases, and / or the electrical characteristics of the electric shock protection device, for example, the insulation resistance IR can be reduced. If the etching is performed in a small amount, the electrical contactability between the
After the step 1-2), the washing process can be further performed, thereby preventing the over-drying. The washing process may be carried out through a conventional method using water or a conventional organic solvent or solution used in a washing process, so that the present invention is not particularly limited thereto.
Meanwhile, between the steps 1-1) and 1-2), it is possible to further polish the edges of the first
The polishing may be performed by a known method, and may be performed using an abrasive or a grinding stone. Depending on the surface area of the first body, the number of revolutions for polishing, the amount of distilled water supplied, and the like may be changed.
Meanwhile, a heat treatment process may be further performed before the polishing process to volatilize the binder and the solvent that may be present in the first body. If the binder or the solvent remains in the first elementary body, there is a problem that the defective rate due to the sticking phenomenon between the first elementary body and the inner wall or the first elementary body due to frictional force generated during the polishing process may increase. The heat treatment may be performed at a temperature of 500 to 800 ° C for 1 minute to 24 hours, but may be changed depending on the type of the varistor forming component, the solvent, and the organic solvent of the first body.
Next, in step (2), a step of forming a glass coating layer on the outer surface of the first elementary body including at least the first outer surface of the first elementary body in a region corresponding to the inner electrode of the first elementary body may be performed, 2-1) treating a glass coating layer forming composition on an outer surface of a first body; And 2-2) drying the glass coating layer forming composition; 2-3) ball milling the surface of the dried glass coating layer-forming composition; And 2-4) firing the glass coating layer-forming composition.
First, in step 2-1), the glass coating layer may be formed by treating a part or all of the outer surface of the first body with a glass coating layer forming composition, wherein the glass coating layer forming composition includes a glass component, a binder component, and a solvent can do. Wherein the glass component is selected from the group consisting of aluminum, silicon, germanium, indium, tin, lead, phosphorous, boron, gallium, lithium, sodium, potassium, rubidium, cesium, beryllium, magnesium, calcium, strontium, barium, neodymium, praseodymium, erbium, Titanium, zirconium, tantalum, zinc, tungsten, vanadium, chromium, manganese, iron, cobalt, nickel, copper and molybdenum. The glass component may preferably comprise silicon, zinc, manganese, magnesium, potassium, calcium and boron. The content of each of the elements is 10 to 35% by weight of silicon, 5 to 15% by weight of manganese, 0.5 to 5% by weight of magnesium, 2 to 10% by weight of potassium, 3 to 10% by weight of calcium, 2 to 10% %, Zinc 5-15% by weight, but it is not limited thereto, and it is possible to reduce the content of some components and increase the content of the other components, or to add other kinds of components not described . The glass component may be included in the composition as a granule, and the average particle diameter of the glass component may be 0.1 to 10 탆, but is not limited thereto. In addition, it is more preferable to use the glass component having a uniform particle size distribution, whereby the thickness of the glass coating layer can be made uniform, and the formed coating layer can be more stably bonded to the outer surface of the body.
The glass coating layer forming composition may be prepared by dipping the
Next, the drying step of the composition for forming a glass coating layer can be performed in step 2-2), and the formation of the glass coating layer can be facilitated through the drying step. The drying process may be performed at 60 to 200 ° C for 10 minutes to 2 hours, but is not limited thereto.
Next, the step of ball milling the surface of the dried glass coating layer-forming composition may be carried out in the step 2-3), thereby preventing the glass component from being clumped in the dried glass coating layer- The uniformity of the coating layer can be improved. The ball milling can be performed by a conventional method. At this time, the ball to be used may be a ball of a common material such as a ceramic material such as zirconium, and the particle diameter of the ball to be used may also be changed according to the purpose, so that the present invention is not particularly limited thereto.
Next, the step of baking the glass coating layer-forming composition may be performed in steps 2-4. The glass component can be melted on the surface of the first elementary body through the firing to form a glass coating layer through crystal growth of the elementary body surface. Specifically, it may be fired at 600 to 1000 ° C for about 10 minutes to about 2 hours in an atmospheric atmosphere or a nitrogen atmosphere. However, the firing temperature may be changed depending on the kind of the used glass component. Specifically, FIG. 12A shows the surface of the first elementary body before the formation of the glass coating layer. As shown in FIG. 12B, it can be seen that as the glass coating layer is formed, the outer appearance of the elementary body surface becomes uniform and the separation of the powder forming the elementary body can be prevented .
Next, in step (3), an external electrode is formed to be electrically connected to the internal electrode.
The
The conductive component may include at least one selected from the group consisting of Ag, Au, Cu, Ni, Pd, and Pt. The conductive component may be included in the composition as a granule, wherein the average particle size of the conductive component may be 0.1 to 10 탆.
The glass component may be selected from the group consisting of aluminum, silicon, germanium, indium, tin, lead, phosphorus, boron, gallium, lithium, sodium, potassium, rubidium, cesium, beryllium, magnesium, calcium, strontium, barium, neodymium, praseodymium, erbium, And may contain at least one element selected from among cerium, titanium, zirconium, tantalum, zinc, tungsten, vanadium, chromium, manganese, iron, cobalt, nickel, copper and molybdenum, Or zinc, silicon, boron and aluminum. At this time, the content of each element may be 5 to 20 wt% in the external electrode forming composition based on the oxide.
The glass component may be included in the composition as a granular material. In this case, the glass component may have an average particle diameter of 0.1 to 10 mu m, thereby improving the dispersibility. Through this, the adhesion of the glass component Can be improved.
The external electrode forming composition may further include a solvent and a binder component in addition to the conductive component and the glass component.
The binder component may be used without limitation in the case of conventional binders used for producing external electrodes, and as a non-limiting example, polyvinylbutyral resin, polyvinylacetate resin, ethyl cellulose , Nitrocellulose, polyacrylic resin, and the like.
In addition, the above-mentioned solvent can be used without limitation in the case of ordinary water or organic solvent which does not affect the above-mentioned conductive component and glass component to be used, and which does not cause problems in dissolving additives such as a binder component and other dispersant. As a non-limiting example, butoxyethoxy ethyl acetate), ethylene glycol, diethylene glycol, triethylene glycol, ethylene glycol monobutyl ether, propylene glycol monoethyl ether propylene glycol monomethyl ether, diethylene glycol methyl ether, glycerol, diethylene glycol ethyl ether acetate, terpineol, menthol, ), Diethylene glycol methyl ethyl ether (MEDG), and butyl diglycol (BDG), which may be used alone or in combination.
At this time, the external electrode forming composition may contain 5 to 20 parts by weight of a glass component, 1 to 10 parts by weight of a binder component and 5 to 20 parts by weight of a solvent, based on 100 parts by weight of the conductive component. If the glass component is contained in an amount of less than 5 parts by weight based on the conductive component, the adhesion strength between the desired external electrode and the body may not be exhibited. If the glass component exceeds 20 parts by weight based on the conductive component, / When the external electrode is contacted, the glass component dissolves and acts as an obstacle on the contact surface, so there may be a problem of contact failure.
The viscosity of the external electrode forming composition may be 10 to 60 Kcps as measured on Brookfield HBDV-1 SC4-14, 10 RPM. If the viscosity range is unsatisfactory, it may not be easy to form the external electrode with the desired thickness, and the dispersibility of each component in the composition is weak, so that the mechanical strength of the manufactured external electrode, There is a problem.
The external electrode forming composition described above can be applied to the outer surface of the body by a conventional method. As a non-limiting example of the coating method, a blade coating, a flow coating, a casting, A method of transfer, a method of brushing, dipping or spraying may be used. The applied external electrode forming composition can be sintered at 600 to 1000 ° C for about 10 minutes to about 2 hours in an atmospheric or nitrogen atmosphere and then dried at 60 to 200 ° C for 10 minutes to 2 hours before the sintering process have.
Meanwhile, as shown in FIG. 6, the electric shock protection device according to an embodiment of the present invention includes
Vcp > Vbr where Vbr is the breakdown voltage of the electric shock protection element, and Vcp is the breakdown voltage of the capacitor portion.
The
3B, the
The dielectric constant of the second
The second
The
A plurality of
If the distance between the capacitor electrodes is less than 15 mu m, it is difficult to ensure a sufficient capacitance for passing the communication signal of the wireless communication band without attenuation. If the distance exceeds 100 mu m, the distance between the capacitor electrodes is limited, Since the number of stacked sheet layers including the electrode is limited, it is difficult to realize a high capacity capacitor.
At this time, the thickness of each of the capacitor electrodes constituting the
For example, when the interval between the pair of capacitor electrodes facing each other is 20 μm, the thickness of the capacitor electrode may be set to be in the range of 2 to 10 μm. If the thickness of the capacitor electrode is 2 mu m or less, the capacitor electrode can not function as an electrode. If the thickness of the capacitor electrode is more than 10 mu m, the thickness of the capacitor electrode becomes thick, and the distance between the capacitor electrode for forming the capacitor portion is limited. Since the number of stacked sheet layers including the electrode is limited, it is difficult to realize a high capacity capacitor.
The shortest distance d2 between the free ends of the capacitor electrodes that are not connected to the external electrodes and the
6, one
As described above, the electric
Meanwhile, the above-described electric
Meanwhile, the electrodes included in the electric
The distance between the
Meanwhile, the electric
6B, the
6 includes (A) a first laminated body including a plurality of first internal electrodes arranged in a line and a second internal electrode spaced apart from the first internal electrodes by a distance from the first internal electrodes, and The method comprising the steps of: preparing a first and a second body by sintering a second layered body disposed on one side of the first layered body including capacitor electrodes provided so that at least a part of the electrodes overlap each other; (B) an outer surface of a first elementary body including at least an outer surface of a first elementary body of a region corresponding to an inner electrode of the first elementary body and a second elementary body outer surface corresponding to a capacitor electrode of the second elementary body, Forming a glass coating layer on the substrate; And (C) forming an external electrode to be electrically connected to the internal electrode and the capacitor electrode.
First, the method of manufacturing the first laminate in the step (A) is the same as the one described in the step (1) of the example of manufacturing the electric shock protection device described above, and a detailed description thereof will be omitted. Also, in the second laminate, a plurality of sheets are formed through the composition for forming a capacitor sheet as in the above-described step (1), and capacitor electrodes are formed on one surface of the sheet so as to have a desired width and thickness And then laminating them. At this time, the capacitor sheet forming composition may include a dielectric component instead of the varistor forming component of the varistor sheet layer forming composition, and the dielectric component includes low temperature sintered ceramics (LTCC) and high temperature sintered ceramics A ceramic material and a magnetic material. In this case, the ceramic material may be an oxide-based ceramic compound or a non-oxide-based ceramic compound, wherein the oxide-based ceramic compound is BeO, MgO, LaCrO 3, PbTiO 3, (Ba, Pb)
Meanwhile, the outer surfaces of the first and second sintered bodies sintered through step A-1 may be subjected to an etching process (step A-2). In addition, the first and second main bodies having the outer surface etched may further include an edge and a triple point to further polish the outer surface, and the specific method is the same as the description of the step (1).
Thereafter, a glass coating layer may be formed on the outer surfaces of the first and second polished bodies (step B). 3, the
After the formation of the
7 to 8, various embodiments of the electric shock protection device according to the embodiment of the present invention will be described in more detail. As shown in FIG. 7A, the electric shock protection device 100 ' A plurality of electric
In addition, the number of the
In another embodiment, as shown in Figs. 8A to 8E, the plurality of sheet layers constituting the
More specifically, at least one of the plurality of sheet layers constituting the
At this time, the first ceramic material and the second ceramic material may be heterogeneous ceramic materials. Here, the meaning of 'heterogeneous' means that the physical properties are mutually consulted even if the chemical formulas are different from each other or the chemical formulas are the same.
That is, the first ceramic material and the second ceramic material include at least one selected from Er 2 O 3 , Dy 2 O 3 , Ho 2 O 3 , V 2 O 5 , CoO, MoO 3 , SnO 2 and BaTiO 3 Metal oxide compound, ferrite, low temperature co-fired ceramic (LTCC), high temperature co-fired ceramic (HTCC), or the like.
In addition, the first ceramic material is Er 2 O 3, Dy 2 O 3, Ho 2
Further, the first ceramic material and the second ceramic material include at least one selected from Er 2 O 3 , Dy 2 O 3 , Ho 2 O 3 , V 2 O 5 , CoO, MoO 3 , SnO 2 and BaTiO 3 Metal-based oxide compounds, and may be made of one selected from ferrite.
That is, the first ceramic material and the second ceramic material may be formed in various forms of metal oxide compound, ferrite, low temperature co-fired ceramic (LTCC), and high temperature co-fired ceramic (HTCC) Or cured.
Meanwhile, in the
As shown in FIG. 8A, the
Hereinafter, for convenience of description, it is assumed that the second ceramic material is a heterogeneous material.
8A to 8D show various arrangement relationships of the first ceramic material and the second ceramic material. The non-hatched portion (A) means that the sheet is made of the first ceramic material, and the hatched portion (B) in the figure means that the sheet is made of the second ceramic material. That is, in FIGS. 8A to 8D, the reference numerals A and B refer to the material of the sheet.
Specifically, as shown in FIG. 8B, the entire plurality of sheet layers constituting the
8C and 8D, a portion of the plurality of sheets constituting the
As described above, in the electric shock protection device 100 '' according to the embodiment of the present invention, the first ceramic material A and the second ceramic material B are selected and the first ceramic material A, which is a different kind of ceramic material, By arranging the
For example, as shown in FIGS. 8A to 8D, when a second ceramic material, which is a different kind of ceramic material, is disposed in the
8E, at least one
With this configuration, the electric
The above-described
Here, the portable
Such a portable
At this time, the housing of the portable
In particular, the metal case may be provided to partially surround or entirely surround the side of the housing of the portable
As such, the electric
Such an
That is, when the
When the plurality of
For example, when the camera of the portable
In addition, when the
Meanwhile, as shown in FIG. 9B, the electric
9C, the electric
As shown in FIG. 9D, the electric
9E, the electric
10A to 10C, the electric
10A, when the leakage current of the external power source flows into the
At this time, the
As a result, the electric
Further, as shown in FIG. 10B, when static electricity flows from the outside through the
Since the dielectric breakdown voltage Vcp of the
Here, the
Further, as shown in Fig. 10C, when a communication signal is input through the
Here, the capacitances of the
However, as shown in FIG. 11B, it can be seen that the capacitance of the capacitor portion is not influenced by the reception sensitivity during communication at a capacitance of about 20 pF or more, preferably 30 pF or more. In the wireless communication frequency band, it is preferable to use a capacitor including a body having a dielectric constant of 20 F / m or more so that it is easier to realize a high capacitance of 20 F or more. As a result, the electric
While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it is to be understood that the invention is not limited to the disclosed exemplary embodiments, It will be understood by those skilled in the art that various changes in form and details may be made therein without departing from the spirit and scope of the invention as defined by the appended claims.
10: portable
14:
110, 210: an electric shock protection part 120: a capacitor part
111, 112: varistor sheet layer
111a, 111b, 112a: internal electrodes
Claims (44)
An electric shock protection unit comprising a first element, a plurality of first internal electrodes arranged in a line within the first element, and a second internal electrode spaced apart from the first internal electrode by a distance from the first internal electrode;
An outer electrode formed on an outer surface of the first element to be electrically connected to the first inner electrode and the second inner electrode; And
And a glass coating layer formed on the outer surface of the body including at least an area where the outer electrode and the outer surface of the body containing the first body are in contact with each other.
An electric shock protection element satisfying the following expression: < EMI ID = 1.0 > wherein the electric current passing through the electric conductor is passed through the electric conductor,
Vbr> Vin
Here, Vbr is the breakdown voltage of the electric shock protection element, and Vin is the rated voltage of the external power supply of the electronic device.
Wherein the rated voltage is a national standard rated voltage.
Wherein the second internal electrode has a plurality of electrodes spaced apart in a line.
Wherein each of the second internal electrodes is disposed to overlap at least a part of the first internal electrode.
And each of the second internal electrodes is disposed so as not to overlap with the first internal electrode.
A distance L between any two first inner electrodes disposed adjacent to and closest to the second inner electrode among the plurality of first inner electrodes is a distance between the two first inner electrodes and the second inner electrode, (d1, d2).
Wherein at least a part of the sheet layer is formed of a first varistor composition and the remaining sheet layer is formed of a second varistor composition different from the first varistor composition.
Wherein the first prism body comprises at least one of a semiconductive material, a Pr-based material, and a Bi-based material including at least one of ZnO, SrTiO 3 , BaTiO 3, and SiC.
Wherein the thicknesses of the first internal electrode and the second internal electrode are independently 2 to 10 mu m.
Wherein the first internal electrode and the second internal electrode each independently comprise any one or more of Ag, Au, Pt, Pd, Ni and Cu.
Wherein the glass coating layer is formed on the outer surface of the elementary body.
Wherein the glass coating layer comprises at least one selected from the group consisting of aluminum, silicon, germanium, indium, tin, lead, phosphorus, boron, gallium, lithium, sodium, potassium, rubidium, cesium, beryllium, magnesium, calcium, strontium, barium, neodymium, praseodymium, erbium, And a glass component containing at least one element selected from titanium, zirconium, tantalum, zinc, tungsten, vanadium, chromium, manganese, iron, cobalt, nickel, copper and molybdenum.
Wherein the glass coating layer has an average thickness of 0.5 to 10 占 퐉.
A second elementary body disposed on one side of the first elementary body of the electric shock protection element and a second elementary body disposed on the second elementary element so as to overlap at least a part of the surfaces of the second elementary element and the electrode, And a capacitor portion including a capacitor electrode electrically connected to the capacitor portion.
Vcp > Vbr, wherein Vcp is an insulation breakdown voltage of the capacitor section.
Wherein the capacitor unit is electrically connected in parallel with the electric shock protection unit.
And said second elementary body comprises a dielectric.
Wherein the breakdown voltage (Vbr) of the electric shock protection element is a sum of unit breakdown voltages respectively formed between the first adjacent first internal electrode and the second internal electrode.
An electric shock protection unit comprising a first element, a plurality of first internal electrodes arranged in a line within the first element, and a second internal electrode spaced apart from the first internal electrode by a distance from the first internal electrode;
And a capacitor electrode provided in the second elementary body so that at least a part of the surfaces of the second elementary body and the electrode disposed on one side of the first elementary body of the electric shock protection element for allowing the communication signal flowing from the conductor to pass therethrough, A capacitor portion;
An external electrode formed on an outer surface of the first and second main bodies so as to be electrically connected to the first internal electrode, the second internal electrode, and the capacitor electrode; And
And a glass coating layer formed on the outer surface of the body including the outer surface of the element body including the first elementary body and the second elementary body and the region where the outer electrode is in contact with the outer surface.
An electric shock protection element satisfying the following expression: < EMI ID = 1.0 > wherein: the electric current is passed through the conductor without passing through the dielectric breakdown, and the leakage current of the external power source,
Vbr> Vin
Here, Vbr is the breakdown voltage of the electric shock protection element, and Vin is the rated voltage of the external power supply of the electronic device.
Vcp > Vbr, wherein Vcp is an insulation breakdown voltage of the capacitor section.
Wherein the capacitor unit is electrically connected in parallel with the electric shock protection unit.
Wherein the communication signal has a wireless communication frequency band.
The distance between the capacitor portion and the electric shock protection portion may be a distance between the first inner electrode and the second inner electrode disposed nearest to the second inner electrode of the plurality of first inner electrodes, d2) greater than the sum.
Wherein a distance between the capacitor portion and the electric shock protection portion is 15 to 100 mu m.
Wherein the thickness of the capacitor electrode is 2 to 10 mu m.
Wherein an interval between the capacitor electrodes is 15 to 100 mu m.
Circuitry; And
And an electric shock protection element disposed between the conductor and the circuit portion,
An electric shock protection unit comprising a first element, a plurality of first internal electrodes arranged in a line within the first element, and a second internal electrode spaced apart from the first internal electrode by a distance from the first internal electrode;
An outer electrode formed on an outer surface of the first element to be electrically connected to the first inner electrode and the second inner electrode; And
And a glass coating layer formed on the outer surface of the body including at least an area where the outer electrode and the outer surface of the body contact each other.
Wherein the electric shock protection device is a portable electronic device having an electric shock protection function satisfying the following expression in order to cut off the leakage current of the external power source flowing from the ground of the circuit part after allowing the static electricity to pass therethrough, :
Vbr> Vin
Here, Vbr is the breakdown voltage of the electric shock protection element, and Vin is the rated voltage of the external power supply of the electronic device.
Wherein the conductor has at least one of an antenna, a metal case, and a conductive ornamental for communication between the electronic device and an external device.
Wherein the metal case has an electric shock protection function that partially surrounds or entirely surrounds the side of the housing of the electronic device.
Wherein the metal case is provided so as to surround a camera provided to be exposed to the outside on a front surface or a rear surface of the housing of the electronic device.
Circuitry; And
And an electric shock protection element disposed between the conductor and the circuit portion,
An electric shock protection unit comprising a first element, a plurality of first internal electrodes arranged in a line within the first element, and a second internal electrode spaced apart from the first internal electrode by a distance from the first internal electrode;
And a capacitor electrode provided in the second elementary body so that at least a part of the surfaces of the second elementary body and the electrode disposed on one side of the first elementary body of the electric shock protection element for allowing the communication signal flowing from the conductor to pass therethrough, A capacitor portion;
An external electrode formed on an outer surface of the first and second main bodies so as to be electrically connected to the first internal electrode, the second internal electrode, and the capacitor electrode; And
And a glass coating layer formed on the outer surface of the body including the outer surface of the body including the first body and the second body and the region where the outer electrode abuts.
Wherein the static electricity is passed through the conductor without passing through the dielectric breakdown and the leakage current of the external power source flowing from the ground of the circuit part is cut off and the communication signal is passed through without passing through the dielectric breakdown from the static electricity A portable electronic device having an electric shock protection function:
Vbr> Vin, Vcp> Vbr
Here, Vbr is the breakdown voltage of the electric shock protection device, Vin is the rated voltage of the external power supply of the electronic device, and Vcp is the breakdown voltage of the capacitor.
Wherein the capacitor portion is provided on at least one of the upper and lower portions of the electric shock protection portion or at least one of both the upper and lower portions of the electric shock protection portion at regular intervals.
(2) forming a glass coating layer on the outer surface of the first elementary body including at least the first outer surface of the first elementary body in a region corresponding to the inner electrode of the first elementary body; And
(3) forming an outer electrode to be electrically connected to the inner electrode.
1-1) sintering a multilayer body including a plurality of first internal electrodes arranged in a line and spaced apart from other ones of the plurality of first internal electrodes to manufacture a first body; And
1-2) etching the outer surface of the first elementary body;
Further comprising the step of polishing the edge of the first body between steps 1-1) and 1-2).
2-1) treating the outer surface of the first body with a composition for forming a glass coating layer; And
2-2) drying the glass coating layer forming composition;
2-3) ball milling the surface of the dried glass coating layer-forming composition; And
2-4) firing the composition for forming a glass coating layer.
(B) an outer surface of a first elementary body including at least an outer surface of a first elementary body of a region corresponding to an inner electrode of the first elementary body and a second elementary body outer surface corresponding to a capacitor electrode of the second elementary body, Forming a glass coating layer on the substrate; And
(C) forming an external electrode to be electrically connected to the internal electrode and the capacitor electrode.
A-1) a first laminate including a plurality of first inner electrodes spaced in a line and a second inner electrode spaced apart from the other first inner electrodes, and at least some of the electrodes overlapping each other Sintering a second stacked body disposed on one side of the first stacked body including the capacitor electrode so as to manufacture the first and second sintered bodies; And
A-2) etching the outer surfaces of the first and second bodies.
Further comprising the step of polishing an edge of the first body between the step A-1) and the step A-2).
B-1) treating a glass coating layer-forming composition on an outer surface of a first body; And
B-2) drying the glass coating layer-forming composition;
B-3) ball milling the surface of the dried glass coating layer-forming composition; And
B-4) firing the composition for forming a glass coating layer.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20190008147A (en) * | 2017-07-14 | 2019-01-23 | 주식회사 아모텍 | Hybrid electric device and electronic device with the same |
WO2020055139A1 (en) * | 2018-09-14 | 2020-03-19 | 주식회사 아모텍 | Method for producing composite device and composite device realized thereby |
-
2015
- 2015-11-30 KR KR1020150169200A patent/KR20170063156A/en unknown
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20190008147A (en) * | 2017-07-14 | 2019-01-23 | 주식회사 아모텍 | Hybrid electric device and electronic device with the same |
WO2020055139A1 (en) * | 2018-09-14 | 2020-03-19 | 주식회사 아모텍 | Method for producing composite device and composite device realized thereby |
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