KR20160006775A - Co₂ 포함 폼 및 관련 방법 - Google Patents
Co₂ 포함 폼 및 관련 방법 Download PDFInfo
- Publication number
- KR20160006775A KR20160006775A KR1020157035128A KR20157035128A KR20160006775A KR 20160006775 A KR20160006775 A KR 20160006775A KR 1020157035128 A KR1020157035128 A KR 1020157035128A KR 20157035128 A KR20157035128 A KR 20157035128A KR 20160006775 A KR20160006775 A KR 20160006775A
- Authority
- KR
- South Korea
- Prior art keywords
- certain embodiments
- polyol
- composition
- apc
- foam
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
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- 239000006260 foam Substances 0.000 title claims abstract description 82
- 238000000034 method Methods 0.000 title claims abstract description 58
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- 239000011496 polyurethane foam Substances 0.000 claims abstract description 27
- 238000002156 mixing Methods 0.000 claims abstract description 9
- 150000003077 polyols Chemical class 0.000 claims description 306
- 229920005862 polyol Polymers 0.000 claims description 254
- 239000005056 polyisocyanate Substances 0.000 claims description 112
- 229920001228 polyisocyanate Polymers 0.000 claims description 112
- 125000001931 aliphatic group Chemical group 0.000 claims description 102
- 150000002118 epoxides Chemical class 0.000 claims description 36
- 239000004417 polycarbonate Substances 0.000 claims description 31
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- 125000000623 heterocyclic group Chemical group 0.000 claims description 21
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- 238000007334 copolymerization reaction Methods 0.000 claims description 17
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 claims description 13
- 238000004519 manufacturing process Methods 0.000 claims description 12
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- 238000010438 heat treatment Methods 0.000 claims description 4
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- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 104
- -1 monosubstituted oxirane, disubstituted oxirane, Chemical class 0.000 description 70
- 125000003118 aryl group Chemical group 0.000 description 61
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 41
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- 239000004721 Polyphenylene oxide Substances 0.000 description 34
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- 239000003054 catalyst Substances 0.000 description 25
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- 125000000217 alkyl group Chemical group 0.000 description 19
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 19
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- 125000001424 substituent group Chemical group 0.000 description 19
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 18
- 150000002009 diols Chemical class 0.000 description 18
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 18
- 229910052717 sulfur Inorganic materials 0.000 description 18
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- 239000004814 polyurethane Substances 0.000 description 17
- YXRKNIZYMIXSAD-UHFFFAOYSA-N 1,6-diisocyanatohexane Chemical compound O=C=NCCCCCCN=C=O.O=C=NCCCCCCN=C=O.O=C=NCCCCCCN=C=O YXRKNIZYMIXSAD-UHFFFAOYSA-N 0.000 description 16
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 16
- 150000005846 sugar alcohols Polymers 0.000 description 16
- 229920001897 terpolymer Polymers 0.000 description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 15
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 15
- 150000001261 hydroxy acids Chemical class 0.000 description 14
- 239000001569 carbon dioxide Substances 0.000 description 13
- 229910002092 carbon dioxide Inorganic materials 0.000 description 13
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 13
- 150000001412 amines Chemical class 0.000 description 12
- 239000012986 chain transfer agent Substances 0.000 description 12
- 125000000524 functional group Chemical group 0.000 description 12
- 239000000178 monomer Substances 0.000 description 12
- 239000007787 solid Substances 0.000 description 12
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 11
- 239000000654 additive Substances 0.000 description 11
- 239000003153 chemical reaction reagent Substances 0.000 description 11
- PSGAAPLEWMOORI-PEINSRQWSA-N medroxyprogesterone acetate Chemical compound C([C@@]12C)CC(=O)C=C1[C@@H](C)C[C@@H]1[C@@H]2CC[C@]2(C)[C@@](OC(C)=O)(C(C)=O)CC[C@H]21 PSGAAPLEWMOORI-PEINSRQWSA-N 0.000 description 11
- 239000000047 product Substances 0.000 description 11
- 125000003342 alkenyl group Chemical group 0.000 description 10
- 125000002947 alkylene group Chemical group 0.000 description 10
- 125000000304 alkynyl group Chemical group 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 10
- 239000000126 substance Substances 0.000 description 10
- 235000013877 carbamide Nutrition 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 9
- 239000003086 colorant Substances 0.000 description 9
- 229920001577 copolymer Polymers 0.000 description 9
- 150000002334 glycols Chemical class 0.000 description 9
- 229930195733 hydrocarbon Natural products 0.000 description 9
- 239000001257 hydrogen Substances 0.000 description 9
- 229910052739 hydrogen Inorganic materials 0.000 description 9
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 8
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 8
- 150000001298 alcohols Chemical class 0.000 description 8
- 229910052736 halogen Inorganic materials 0.000 description 8
- 150000002367 halogens Chemical class 0.000 description 8
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 8
- 229920000728 polyester Polymers 0.000 description 8
- 239000005058 Isophorone diisocyanate Substances 0.000 description 7
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 7
- 125000004429 atom Chemical group 0.000 description 7
- 125000005442 diisocyanate group Chemical group 0.000 description 7
- 239000003063 flame retardant Substances 0.000 description 7
- 235000011187 glycerol Nutrition 0.000 description 7
- 150000002430 hydrocarbons Chemical class 0.000 description 7
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 7
- 150000003254 radicals Chemical class 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- LVGUZGTVOIAKKC-UHFFFAOYSA-N 1,1,1,2-tetrafluoroethane Chemical compound FCC(F)(F)F LVGUZGTVOIAKKC-UHFFFAOYSA-N 0.000 description 6
- HBAQYPYDRFILMT-UHFFFAOYSA-N 8-[3-(1-cyclopropylpyrazol-4-yl)-1H-pyrazolo[4,3-d]pyrimidin-5-yl]-3-methyl-3,8-diazabicyclo[3.2.1]octan-2-one Chemical class C1(CC1)N1N=CC(=C1)C1=NNC2=C1N=C(N=C2)N1C2C(N(CC1CC2)C)=O HBAQYPYDRFILMT-UHFFFAOYSA-N 0.000 description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 6
- SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 230000000996 additive effect Effects 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 229920005906 polyester polyol Polymers 0.000 description 6
- 235000013772 propylene glycol Nutrition 0.000 description 6
- 229940113165 trimethylolpropane Drugs 0.000 description 6
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 5
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 5
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 description 5
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 5
- 229920000538 Poly[(phenyl isocyanate)-co-formaldehyde] Polymers 0.000 description 5
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- 239000000853 adhesive Substances 0.000 description 5
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- 125000003277 amino group Chemical group 0.000 description 5
- 239000000460 chlorine Substances 0.000 description 5
- YMWUJEATGCHHMB-UHFFFAOYSA-N dichloromethane Natural products ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
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- 125000005843 halogen group Chemical group 0.000 description 5
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- 150000002431 hydrogen Chemical group 0.000 description 5
- 238000010348 incorporation Methods 0.000 description 5
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- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 5
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 5
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/44—Polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/703—Isocyanates or isothiocyanates transformed in a latent form by physical means
- C08G18/705—Dispersions of isocyanates or isothiocyanates in a liquid medium
- C08G18/706—Dispersions of isocyanates or isothiocyanates in a liquid medium the liquid medium being water
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7614—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
- C08G18/7621—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring being toluene diisocyanate including isomer mixtures
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
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| US61/822,692 | 2013-05-13 | ||
| PCT/US2014/037903 WO2014186397A1 (en) | 2013-05-13 | 2014-05-13 | Co2 containing foams and related methods |
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| KR20160006775A true KR20160006775A (ko) | 2016-01-19 |
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Cited By (1)
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| KR20230013746A (ko) | 2021-07-20 | 2023-01-27 | 현대자동차주식회사 | 폴리올 조성물, 이를 이용하여 폴리우레탄 폼을 제조하는 방법 및 이 방법을 통해 제조된 폴리우레탄 폼 |
Families Citing this family (11)
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| CN103333330A (zh) | 2008-09-08 | 2013-10-02 | 诺沃梅尔公司 | 聚碳酸酯多元醇组合物和方法 |
| KR102055540B1 (ko) | 2011-05-09 | 2019-12-13 | 사우디 아람코 테크놀로지스 컴퍼니 | 고분자 조성물 및 방법 |
| JP2014524965A (ja) | 2011-07-25 | 2014-09-25 | ノボマー, インコーポレイテッド | ポリウレタンに使用するための脂肪族ポリカーボネート |
| ES2752043T3 (es) | 2012-11-07 | 2020-04-02 | Saudi Aramco Tech Co | Composiciones de espuma de poliuretano de gran resistencia y métodos |
| US10308759B2 (en) | 2014-04-03 | 2019-06-04 | Saudi Aramco Technologies Company | Aliphatic polycarbonate polyol compositions |
| CN106700030B (zh) * | 2016-12-30 | 2021-06-08 | 浙江华峰新材料有限公司 | 慢回弹海绵用聚氨酯树脂及制备方法和应用 |
| PL3728367T3 (pl) * | 2017-12-21 | 2025-10-20 | Econic Technologies Limited | Sztywne pianki |
| WO2019204553A1 (en) | 2018-04-18 | 2019-10-24 | Saudi Aramco Technologies Company | End-group isomerization of poly(alkylene carbonate) polymers |
| US11180609B2 (en) | 2018-08-02 | 2021-11-23 | Saudi Aramco Technologies Company | Sustainable polymer compositions and methods |
| MA53727A (fr) | 2018-09-24 | 2021-12-29 | Saudi Aramco Tech Co | Copolymères séquencés de polycarbonate et procédés associés |
| JP2024525422A (ja) | 2021-06-23 | 2024-07-12 | サウジ アラムコ テクノロジーズ カンパニー | ポリオール組成物及び方法 |
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| US1922459A (en) | 1933-08-15 | Their production | ||
| US2846408A (en) | 1954-01-19 | 1958-08-05 | Bayer Ag | Cellular polyurethane plastics of improved pore structure and process for preparing same |
| US3887505A (en) * | 1973-12-03 | 1975-06-03 | Basf Wyandotte Corp | Preparation of low density flexible urethane foams with enhanced load-bearing properties |
| US4005035A (en) * | 1974-12-24 | 1977-01-25 | Tecnik International Corporation | Composition for reinforced and filled high density rigid polyurethane foam products and method of making same |
| GB8528071D0 (en) * | 1985-11-14 | 1985-12-18 | Shell Int Research | Polycarbonates |
| US4939182A (en) | 1988-07-27 | 1990-07-03 | The Dow Chemical Company | Melamine-alkanolamine condensates and polyurethanes prepared therefrom |
| US4883826A (en) | 1988-07-27 | 1989-11-28 | The Dow Chemical Company | Tertiary amine-containing polyols prepared in a mannich condensation reaction using a mixture of alkanolamines |
| US5120815A (en) | 1989-06-29 | 1992-06-09 | The Dow Chemical Company | Tertiary amine-containing polyols prepared in a mannich condensation reaction using a mixture of alkanolamines |
| US5801210A (en) * | 1997-10-29 | 1998-09-01 | Bayer Corporation | Method and apparatus for the production of essentially void free foams |
| IT1319643B1 (it) * | 2000-11-09 | 2003-10-23 | Enichem Spa | Procedimento per la produzione di schiume poliuretaniche rigide edarticoli finiti da esse ottenuti. |
| JP2003082050A (ja) * | 2001-09-11 | 2003-03-19 | Achilles Corp | 液状二酸化炭素の定量供給装置およびこれを用いたポリウレタンフォームの発泡装置 |
| JP3909598B2 (ja) * | 2001-12-21 | 2007-04-25 | 旭硝子株式会社 | 低反発軟質ポリウレタンフォームの製造方法 |
| JP4694191B2 (ja) * | 2004-12-17 | 2011-06-08 | 住化バイエルウレタン株式会社 | ポリウレタンフォーム成形品の製造法 |
| US7670501B2 (en) * | 2005-05-27 | 2010-03-02 | Bayer Materialscience Llc | Carbon dioxide blown low density, flexible microcellular polyurethane elastomers |
| TW200804151A (en) * | 2006-07-07 | 2008-01-16 | Yao-Sin Liao | Air sealing body |
| US20080058468A1 (en) * | 2006-08-31 | 2008-03-06 | Bayer Materialscience Llc | Low density rigid reinforced polyurethanes and a process for their production |
| EP2126239A4 (en) * | 2007-01-30 | 2011-03-02 | Firestone Building Products Llc | BUILDING PLATES AND COMPOSITE PLATES OF POLYURETHANE AND POLYISOCYANURATE HIGH DENSITY |
| CN103333330A (zh) * | 2008-09-08 | 2013-10-02 | 诺沃梅尔公司 | 聚碳酸酯多元醇组合物和方法 |
| CN101857670B (zh) * | 2009-04-10 | 2013-04-03 | 拜耳材料科技(中国)有限公司 | 聚氨酯微孔弹性体及其制备方法和应用 |
| US20120183694A1 (en) * | 2011-01-18 | 2012-07-19 | Owens Corning Intellectual Capital, Llc | Hybrid polyurethane spray foams made with urethane prepolymers and rheology modifiers |
| KR102055540B1 (ko) * | 2011-05-09 | 2019-12-13 | 사우디 아람코 테크놀로지스 컴퍼니 | 고분자 조성물 및 방법 |
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| CN114774053A (zh) | 2012-04-16 | 2022-07-22 | 沙特阿美技术公司 | 粘合剂组合物和方法 |
| ES2752043T3 (es) * | 2012-11-07 | 2020-04-02 | Saudi Aramco Tech Co | Composiciones de espuma de poliuretano de gran resistencia y métodos |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20230013746A (ko) | 2021-07-20 | 2023-01-27 | 현대자동차주식회사 | 폴리올 조성물, 이를 이용하여 폴리우레탄 폼을 제조하는 방법 및 이 방법을 통해 제조된 폴리우레탄 폼 |
| US12312453B2 (en) | 2021-07-20 | 2025-05-27 | Hyundai Motor Company | Polyol composition, method for preparing polyurethane foam using the same, and polyurethane foam prepared by the method |
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| HK1223388A1 (zh) | 2017-07-28 |
| US20200325296A1 (en) | 2020-10-15 |
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