KR20150033596A - 접착제용 점착제로서 사용될 수 있고 탄소 원자 1 내지 20개의 알킬 (메트)아크릴레이트를 기제로 하는 유화 중합에 의해 생성될 수 있는 수성 중합체 분산액 - Google Patents
접착제용 점착제로서 사용될 수 있고 탄소 원자 1 내지 20개의 알킬 (메트)아크릴레이트를 기제로 하는 유화 중합에 의해 생성될 수 있는 수성 중합체 분산액 Download PDFInfo
- Publication number
- KR20150033596A KR20150033596A KR1020147024736A KR20147024736A KR20150033596A KR 20150033596 A KR20150033596 A KR 20150033596A KR 1020147024736 A KR1020147024736 A KR 1020147024736A KR 20147024736 A KR20147024736 A KR 20147024736A KR 20150033596 A KR20150033596 A KR 20150033596A
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- KR
- South Korea
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- weight
- adhesive
- polymer
- monomers
- acid
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- 229910000831 Steel Inorganic materials 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
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- IBVAQQYNSHJXBV-UHFFFAOYSA-N adipic acid dihydrazide Chemical compound NNC(=O)CCCCC(=O)NN IBVAQQYNSHJXBV-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 125000004103 aminoalkyl group Chemical group 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 238000013103 analytical ultracentrifugation Methods 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
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- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
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- 238000006243 chemical reaction Methods 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
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- 230000006866 deterioration Effects 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- LTYMSROWYAPPGB-UHFFFAOYSA-N diphenyl sulfide Chemical compound C=1C=CC=CC=1SC1=CC=CC=C1 LTYMSROWYAPPGB-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000007046 ethoxylation reaction Methods 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethyl mercaptane Natural products CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000009408 flooring Methods 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
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- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
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- PJUIMOJAAPLTRJ-UHFFFAOYSA-N monothioglycerol Chemical compound OCC(O)CS PJUIMOJAAPLTRJ-UHFFFAOYSA-N 0.000 description 1
- 150000002826 nitrites Chemical class 0.000 description 1
- 229920000847 nonoxynol Polymers 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
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- 238000011056 performance test Methods 0.000 description 1
- FHHJDRFHHWUPDG-UHFFFAOYSA-N peroxysulfuric acid Chemical compound OOS(O)(=O)=O FHHJDRFHHWUPDG-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
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- 239000004014 plasticizer Substances 0.000 description 1
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- 229920006122 polyamide resin Polymers 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000011496 polyurethane foam Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
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- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
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- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 230000001012 protector Effects 0.000 description 1
- KOUKXHPPRFNWPP-UHFFFAOYSA-N pyrazine-2,5-dicarboxylic acid;hydrate Chemical compound O.OC(=O)C1=CN=C(C(O)=O)C=N1 KOUKXHPPRFNWPP-UHFFFAOYSA-N 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
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- 239000011734 sodium Substances 0.000 description 1
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- WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 description 1
- 229910000342 sodium bisulfate Inorganic materials 0.000 description 1
- 229940079827 sodium hydrogen sulfite Drugs 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
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- 239000000057 synthetic resin Substances 0.000 description 1
- 238000010345 tape casting Methods 0.000 description 1
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- 235000007586 terpenes Nutrition 0.000 description 1
- WMXCDAVJEZZYLT-UHFFFAOYSA-N tert-butylthiol Chemical compound CC(C)(C)S WMXCDAVJEZZYLT-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 150000003566 thiocarboxylic acids Chemical class 0.000 description 1
- YODZTKMDCQEPHD-UHFFFAOYSA-N thiodiglycol Chemical compound OCCSCCO YODZTKMDCQEPHD-UHFFFAOYSA-N 0.000 description 1
- 229950006389 thiodiglycol Drugs 0.000 description 1
- NJRXVEJTAYWCQJ-UHFFFAOYSA-N thiomalic acid Chemical compound OC(=O)CC(S)C(O)=O NJRXVEJTAYWCQJ-UHFFFAOYSA-N 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- ZTWTYVWXUKTLCP-UHFFFAOYSA-N vinylphosphonic acid Chemical class OP(O)(=O)C=C ZTWTYVWXUKTLCP-UHFFFAOYSA-N 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- DGVVWUTYPXICAM-UHFFFAOYSA-N β‐Mercaptoethanol Chemical compound OCCS DGVVWUTYPXICAM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/10—Homopolymers or copolymers of methacrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/38—Pressure-sensitive adhesives [PSA]
- C09J7/381—Pressure-sensitive adhesives [PSA] based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C09J7/385—Acrylic polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
- C09J2203/334—Applications of adhesives in processes or use of adhesives in the form of films or foils as a label
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesive Tapes (AREA)
- Graft Or Block Polymers (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP12153979.5 | 2012-02-06 | ||
| EP12153979 | 2012-02-06 | ||
| PCT/EP2013/051188 WO2013117428A1 (de) | 2012-02-06 | 2013-01-23 | Als tackifier für klebstoffe anwendbare wässrige polymerdispersion, herstellbar durch emulsionspolymerisation auf basis von c1- bis c20 alkyl(meth)acrylaten |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20150033596A true KR20150033596A (ko) | 2015-04-01 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020147024736A Ceased KR20150033596A (ko) | 2012-02-06 | 2013-01-23 | 접착제용 점착제로서 사용될 수 있고 탄소 원자 1 내지 20개의 알킬 (메트)아크릴레이트를 기제로 하는 유화 중합에 의해 생성될 수 있는 수성 중합체 분산액 |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP2812407B1 (enExample) |
| JP (1) | JP6133331B2 (enExample) |
| KR (1) | KR20150033596A (enExample) |
| CN (1) | CN104093807B (enExample) |
| BR (1) | BR112014018254B1 (enExample) |
| ES (1) | ES2755050T3 (enExample) |
| WO (1) | WO2013117428A1 (enExample) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018117694A1 (ko) * | 2016-12-21 | 2018-06-28 | 주식회사 엘지화학 | 키스택이 우수한 점착제 조성물 |
| KR20210031320A (ko) * | 2019-09-11 | 2021-03-19 | 주식회사 엘지화학 | 아크릴 계 에멀젼 점착제 조성물 |
| WO2021246640A1 (ko) * | 2020-06-03 | 2021-12-09 | 주식회사 엘지화학 | 수성 점착제 조성물, 이의 제조 방법, 및 이를 사용하여 제조된 점착 부재 |
| KR20210150278A (ko) * | 2020-06-03 | 2021-12-10 | 주식회사 엘지화학 | 수성 점착제 조성물, 이의 제조 방법, 및 이를 사용하여 제조된 점착 부재 |
| US11359118B2 (en) | 2016-12-21 | 2022-06-14 | Lg Chem, Ltd. | Adhesive composition having excellent kisstack |
| US11870077B2 (en) | 2018-11-20 | 2024-01-09 | Lg Chem, Ltd. | Binder composition for secondary battery electrode and electrode mixture |
| WO2024128580A1 (ko) * | 2022-12-16 | 2024-06-20 | 코오롱인더스트리 주식회사 | 점접착 부여 수지 및 이의 제조 방법 |
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| CN113529207B (zh) | 2015-07-14 | 2024-04-12 | 巴斯夫欧洲公司 | 基于涂覆芯材料的纤丝 |
| WO2018141399A1 (en) * | 2017-02-03 | 2018-08-09 | Synthomer Usa Llc | Pressure sensitive adhesive compositions and methods for preparing same |
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| CN120769894A (zh) | 2023-02-27 | 2025-10-10 | 巴斯夫欧洲公司 | 包含可紫外线交联的聚(甲基)丙烯酸酯和可辐射固化的可自由基聚合的化合物的可紫外线固化的无溶剂热熔粘合剂 |
| WO2026073795A1 (en) | 2024-10-01 | 2026-04-09 | Basf Se | Mixtures of additives for the stabilization of adhesives, sealants and elastomers |
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| JPH07107150B2 (ja) * | 1987-03-27 | 1995-11-15 | 日本合成ゴム株式会社 | エマルジヨン型感圧接着剤 |
| US5196504A (en) * | 1991-10-15 | 1993-03-23 | Avery Dennison Corporation | Repulpable pressure-sensitive adhesive compositions |
| JPH06145262A (ja) * | 1992-09-03 | 1994-05-24 | Rohm & Haas Co | 多段階ポリマーを含有する耐水性組成物 |
| US5461103A (en) * | 1993-05-11 | 1995-10-24 | Air Products And Chemicals, Inc. | Process for producing a stable aqueous pressure sensitive adhesive polymer emulsion |
| US5800873A (en) * | 1994-10-03 | 1998-09-01 | Basf Lacke+Farben Ag | Process for the production of sealed packaging containers and the use of a sealing coating for coating plastics films |
| US6124417A (en) * | 1995-08-25 | 2000-09-26 | Avery Dennison Corporation | Water-activatable polymers for ink-jet imprintable constructions |
| DE19632203A1 (de) * | 1996-08-09 | 1998-02-12 | Basf Ag | Haftklebstoffe mit geringen Mengen Styrol |
| DE19709723A1 (de) * | 1997-03-10 | 1998-09-17 | Basf Ag | Verfahren zur Herstellung von Abdichtungen und Beschichtungen sowie zum Verkleben von Fliesen oder Fussbodenbelägen |
| JP2004509213A (ja) * | 2000-09-14 | 2004-03-25 | ローム アンド ハース カンパニー | 低分子量高分子添加剤を含有する接着剤組成物 |
| KR20050106419A (ko) * | 2003-02-07 | 2005-11-09 | 설패이스 스페셜티즈, 에스.에이. | 수성 중합체 분산액 및 방법 |
| JP4250757B2 (ja) * | 2003-02-28 | 2009-04-08 | 綜研化学株式会社 | エマルジョン型粘着剤の製造方法 |
| DE10353201A1 (de) | 2003-11-13 | 2005-06-16 | Basf Ag | Polymerdispersionen, enthaltend Sulfobernsteinsäureester |
| JP5403865B2 (ja) * | 2006-03-01 | 2014-01-29 | 日東電工株式会社 | 粘着シート類 |
| EP1923405A1 (de) * | 2006-11-17 | 2008-05-21 | Elotex AG | Verfahren zur Herstellung von Dispersionen und deren Verwendung |
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2013
- 2013-01-23 CN CN201380008307.XA patent/CN104093807B/zh active Active
- 2013-01-23 JP JP2014555991A patent/JP6133331B2/ja not_active Expired - Fee Related
- 2013-01-23 BR BR112014018254-0A patent/BR112014018254B1/pt active IP Right Grant
- 2013-01-23 WO PCT/EP2013/051188 patent/WO2013117428A1/de not_active Ceased
- 2013-01-23 KR KR1020147024736A patent/KR20150033596A/ko not_active Ceased
- 2013-01-23 ES ES13701075T patent/ES2755050T3/es active Active
- 2013-01-23 EP EP13701075.7A patent/EP2812407B1/de active Active
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018117694A1 (ko) * | 2016-12-21 | 2018-06-28 | 주식회사 엘지화학 | 키스택이 우수한 점착제 조성물 |
| US11359118B2 (en) | 2016-12-21 | 2022-06-14 | Lg Chem, Ltd. | Adhesive composition having excellent kisstack |
| US11870077B2 (en) | 2018-11-20 | 2024-01-09 | Lg Chem, Ltd. | Binder composition for secondary battery electrode and electrode mixture |
| KR20210031320A (ko) * | 2019-09-11 | 2021-03-19 | 주식회사 엘지화학 | 아크릴 계 에멀젼 점착제 조성물 |
| WO2021246640A1 (ko) * | 2020-06-03 | 2021-12-09 | 주식회사 엘지화학 | 수성 점착제 조성물, 이의 제조 방법, 및 이를 사용하여 제조된 점착 부재 |
| KR20210150278A (ko) * | 2020-06-03 | 2021-12-10 | 주식회사 엘지화학 | 수성 점착제 조성물, 이의 제조 방법, 및 이를 사용하여 제조된 점착 부재 |
| US12584048B2 (en) | 2020-06-03 | 2026-03-24 | Lg Chem, Ltd. | Aqueous adhesive composition, manufacturing method of the same, adhesive member manufactured using the same |
| WO2024128580A1 (ko) * | 2022-12-16 | 2024-06-20 | 코오롱인더스트리 주식회사 | 점접착 부여 수지 및 이의 제조 방법 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104093807B (zh) | 2017-09-12 |
| JP2015511976A (ja) | 2015-04-23 |
| CN104093807A (zh) | 2014-10-08 |
| BR112014018254B1 (pt) | 2021-08-24 |
| ES2755050T3 (es) | 2020-04-21 |
| EP2812407A1 (de) | 2014-12-17 |
| EP2812407B1 (de) | 2019-08-21 |
| WO2013117428A1 (de) | 2013-08-15 |
| BR112014018254A8 (pt) | 2017-07-11 |
| JP6133331B2 (ja) | 2017-05-24 |
| BR112014018254A2 (pt) | 2017-06-20 |
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