KR20150021558A - C5-c12 탄화수소 혼합물로부터 btx를 생산하는 방법 - Google Patents

C5-c12 탄화수소 혼합물로부터 btx를 생산하는 방법 Download PDF

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Publication number
KR20150021558A
KR20150021558A KR1020157000058A KR20157000058A KR20150021558A KR 20150021558 A KR20150021558 A KR 20150021558A KR 1020157000058 A KR1020157000058 A KR 1020157000058A KR 20157000058 A KR20157000058 A KR 20157000058A KR 20150021558 A KR20150021558 A KR 20150021558A
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hydrocracking
catalyst
btx
product stream
hydrocarbons
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Korean (ko)
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앤드류 마크 워드
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사우디 베이식 인더스트리즈 코포레이션
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    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/64Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
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    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C4/00Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
    • C07C4/02Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by cracking a single hydrocarbon or a mixture of individually defined hydrocarbons or a normally gaseous hydrocarbon fraction
    • C07C4/06Catalytic processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04Alumina
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    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08Silica
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    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12Silica and alumina
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
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    • B01J23/42Platinum
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    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/44Noble metals
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    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/615100-500 m2/g
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    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63Pore volume
    • B01J35/6350.5-1.0 ml/g
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    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64Pore diameter
    • B01J35/643Pore diameter less than 2 nm
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    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64Pore diameter
    • B01J35/6472-50 nm
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C4/00Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
    • C07C4/08Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule
    • C07C4/12Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule from hydrocarbons containing a six-membered aromatic ring, e.g. propyltoluene to vinyltoluene
    • C07C4/14Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule from hydrocarbons containing a six-membered aromatic ring, e.g. propyltoluene to vinyltoluene splitting taking place at an aromatic-aliphatic bond
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    • C10G45/00Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/62Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing platinum group metals or compounds thereof
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    • C10G45/00Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/68Aromatisation of hydrocarbon oil fractions
    • C10G45/70Aromatisation of hydrocarbon oil fractions with catalysts containing platinum group metals or compounds thereof
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    • C10G47/00Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
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    • C10G47/00Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
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    • C10G47/00Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
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    • C10G65/00Treatment of hydrocarbon oils by two or more hydrotreatment processes only
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    • CCHEMISTRY; METALLURGY
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    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C07C2529/42Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing iron group metals, noble metals or copper
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    • C10G2400/00Products obtained by processes covered by groups C10G9/00 - C10G69/14
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  • Chemical & Material Sciences (AREA)
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  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
  • Nanotechnology (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1020157000058A 2012-06-05 2013-06-04 C5-c12 탄화수소 혼합물로부터 btx를 생산하는 방법 Withdrawn KR20150021558A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12004292 2012-06-05
EP12004292.4 2012-06-05
PCT/EP2013/061425 WO2013182534A1 (en) 2012-06-05 2013-06-04 Process for producing btx from a c5-c12 hydrocarbon mixture

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KR20150021558A true KR20150021558A (ko) 2015-03-02

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KR1020157000058A Withdrawn KR20150021558A (ko) 2012-06-05 2013-06-04 C5-c12 탄화수소 혼합물로부터 btx를 생산하는 방법

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US (1) US9926240B2 (enExample)
EP (1) EP2855636B1 (enExample)
JP (1) JP2015523345A (enExample)
KR (1) KR20150021558A (enExample)
CN (1) CN104395436B (enExample)
EA (1) EA028843B1 (enExample)
SG (1) SG11201407321SA (enExample)
WO (1) WO2013182534A1 (enExample)

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EP3110915B1 (en) * 2014-02-25 2018-11-14 Saudi Basic Industries Corporation Process for producing btx from a c5-c12 hydrocarbon mixture
CN109593558B (zh) * 2014-02-25 2021-04-09 沙特基础工业公司 使用热解由混合烃源生产btx的方法
US10358612B2 (en) 2014-02-25 2019-07-23 Saudi Basic Industries Corporation Process for producing BTX from a mixed hydrocarbon source using catalytic cracking
JP6415586B2 (ja) * 2014-02-25 2018-10-31 サウジ ベーシック インダストリーズ コーポレイションSaudi Basic Industries Corporaiton 炭化水素をオレフィンに変換する方法
CN106062148B (zh) * 2014-02-25 2019-01-15 沙特基础工业公司 用于将烃转化成烯烃的方法
KR102375386B1 (ko) * 2014-02-25 2022-03-17 사우디 베이식 인더스트리즈 코포레이션 코킹을 이용하여 혼합 탄화수소 급원으로부터 btx를 생산하는 방법
WO2015128018A1 (en) * 2014-02-25 2015-09-03 Saudi Basic Industries Corporation Process and installation for the conversion of crude oil to petrochemicals having an improved ethylene and btx yield
KR20170018426A (ko) * 2014-06-13 2017-02-17 사빅 글로벌 테크놀러지스 비.브이. C5-c12 탄화수소 혼합물로부터 벤젠을 생산하는 방법
EP3154687B1 (en) * 2014-06-13 2020-05-20 SABIC Global Technologies B.V. Process for producing benzene from a c5-c12 hydrocarbon mixture
EP3157891A1 (en) * 2014-06-17 2017-04-26 SABIC Global Technologies B.V. Process for producing benzene and lpg2
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WO2016005297A1 (en) * 2014-07-08 2016-01-14 Sabic Global Technologies B.V. Process for producing btx and lpg
RU2017132467A (ru) 2015-02-19 2019-03-19 Сабик Глобал Текнолоджиз Б.В. Системы и способы, связанные с производством полиэтилена
CA2982885C (en) * 2015-04-27 2023-05-02 Shell Internationale Research Maatschappij B.V. Conversion of biomass or residual waste material to biofuels
CN107835847B (zh) * 2015-05-06 2020-08-18 沙特基础工业全球技术有限公司 用于生产btx的方法
US10941348B2 (en) 2015-05-15 2021-03-09 Sabic Global Technologies B.V. Systems and methods related to syngas to olefin process
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