KR20150007657A

KR20150007657A - The deodorant process of manufacture and deodorant

Info

Publication number: KR20150007657A
Application number: KR20130081929A
Authority: KR
Inventors: 고주현
Original assignee: 고주현
Priority date: 2013-07-12
Filing date: 2013-07-12
Publication date: 2015-01-21

Abstract

The present invention relates to a deodorant manufacturing method capable of easily and cheaply manufacturing a high-efficiency deodorizing agent which rapidly removes various kinds of odors due to a complex pathway with various causative substances without generating secondary pollutants and continues the deodorizing effect for a long time And a deodorant.
The general deodorization method shows the local effect only on the odor generated due to the complex action of various living environment and the very large number of causative substances, and the comprehensive measures to cope with the odor are difficult in heavy equipment investment and maintenance, This will increase the production of pollutants, which will deteriorate the living environment of the residence, as well as the deterioration of the natural environment.
Accordingly, the present invention relates to a method for producing a high-efficiency deodorant, comprising the steps of: preparing an active ingredient extract blend composition of a plant obtained by extracting an effective ingredient of a plant containing antibacterial, deodorant, , A step of preparing a complex by adding a water-soluble sulfur and a basic agent, an acidic agent and a peroxidic agent, and a method of adding a mixed composition liquid of an extract of an effective ingredient of a plant to chelate and combine the characteristics of other materials with chelating agents It can be used very usefully for the sources of bad odors in various routes because it quickly removes various odors generated in the industrial field and exhibits sterilizing power against various bacteria such as decomposing bacteria and persimmon bacteria for a long period of time

Description

TECHNICAL FIELD The present invention relates to a deodorant and a deodorant,

The present invention can easily remove various types of odors generated in various living environments, and can prevent the generation of secondary pollutants in the deodorized material and prevent the formation of secondary pollutants in sulfur compounds, nitrogen compounds, aldehydes, hydrocarbons, The present invention relates to a method for manufacturing a deodorant and a deodorant capable of easily and cheaply manufacturing a high efficiency deodorizing agent which keeps the deodorizing effect by killing the destructive bacteria by exerting a powerful sterilizing effect.

To this end, the present invention relates to a method for producing a water-soluble sulfur, comprising the steps of: preparing an active ingredient of a plant containing antibacterial, deodorant and aromatic substances and preparing an extract mixture composition obtained by mixing with an alcohol; The method comprising the steps of: preparing a composite by adding a surfactant, an acidic agent, and an oxidizing agent, and adding an extract mixture composition after the step.

General methods for removing odors include, but are not limited to, collection and filtration deodorization, catalytic oxidation, physical methods using adhesive and adsorbing compounds, and chemical reactions such as oxidation, reduction and neutralization of components of odorous substances Chemical methods, biological methods using microorganisms, methods of constructing a deodorizing system using these various methods in combination, methods of utilizing effective ingredients extracted from plants, and methods of using ozone are used for removing odors.

The deodorization method using the conventional methods alone or in combination can not cope with all the components of the odorous substance having a wide variety of properties and physicochemical properties, and thus the deodorizing effect portion is weak and rather the second environmental pollution source is produced It is reality that is doing

Although various methods of deodorization using facilities are locally effective, they have heavy equipment investment and maintenance difficulties. Therefore, the deterioration of the environment of the residential life as well as the deterioration of the natural environment are serious,

Accordingly, it is an object of the present invention to provide a deodorizing agent which can sterilize a spoilage organism and has a long-lasting deodorizing effect, The purpose of this study is to improve the living conditions of the farmers and improve the living environment

In order to achieve the object of the present invention, it is composed of water-soluble sulfur which chelates, fuses and stabilizes complexes and complexes of deodorant, sterilization, active ingredient extracts of plants containing aromatic components, base agents, acid agents and peroxide oxidants

1, Preparation of Extract Mixture Composition

1-1, Araneum: Rosaceae is a small tall tree belonging to the genus Rosaceae. Its bark is grayish brown and its leaves are odd-numbered leaf-like sawtooth. Leaves include flavono, astragalin, hiperoside, And egg yolk contains flavonoid glycosides such as 6-7% of tannins, hyperin, rutin and quercetin, and essential oils such as K, Na, Ca, and Mg salts.

1-2, early Fincus: The scientific name is Zanthoxylum piperitum APDC, which grows up to 2m in height and has a spindle in the node. There is a directional oil gland on the leaves, sanshool Ⅰ, sanshule Ⅱ, , And essential oils such as citrone, phellandrene, dipentene and geraniol, and tannin, hyperperin, and xanthoxylin

1-3, active ingredient extract composition of plant: The leaves and branches of the plant are collected and pulverized, purified water is extracted, and the active ingredient is extracted from a hot water extractor, filtered and concentrated or hydrated to obtain an extract solution Obtained by mixing the active ingredient extract obtained by sterilization with ozone and the alcohol (selected in ethanol or methanol) at an arbitrary ratio exhibits a very excellent deodorizing, sterilizing and antibacterial effect.

2, Water soluble sulfur production

2-1, Sulfur: Sulfur has been known since prehistoric times and is a non-metal frequently used for disinfection, medicines, fumigation, and bleaching of cloth. Many sulfur compounds are useful for many purposes in modern industries. Biomolecules also contain sulfur as a constituent I have. Sulfur atoms make a wide variety of molecular forms by SS-chaining, and since there are many possible forms of crystals formed by accumulation of these molecules, sulfur has the largest number of allotopes among all elements and SS bonds are easily broken and a few inactive elements , Iridium, tellurium, nitrogen), and so on.

2-2, since sulfur is very reactive, it reacts with chlorine (Cl ₂ ) to produce sulfur chloride (S ₂ Cl ₂ ), which acts as an excellent solvent for the organic compound. RSH The compounds are called mercaptans which hold thiol mercury. The thiol compounds are easily oxidized to form compounds with disulfide bonds (-SS-). The oxidizing agents, chlorite and hydrogen peroxide (H ₂ O ₂ ) (RSO ₃ H), it can exhibit excellent deodorizing and sterilizing effect in this reaction process.

2-3, water-soluble sulfur: Sulfur powder, salt, caustic soda and water are mixed at an arbitrary ratio and stirred to mix the fresh water with the molten sulfur and caustic soda mixed with organic acid (acetic acid, formic acid, anhydrous acetic acid) To produce a water-soluble sulfur having a sulfur content of 22% in which the caustic soda is properly neutralized.

3, the organic acid added to the water-soluble sulfur is consumed in the caustic soda titration contained in the manufacturing process of the water-soluble sulfur, and the remaining organic acid after neutralization of caustic soda is chelating agent for the base material, acidic agent, And functions to stabilize the other substances by fusing them, so that the deodorization effect is maximized.

4, Addition of other deodorant substances

The cause of odor is generated through complex and diverse routes such as sulfur compounds, nitrogen compounds, aldehydes, hydrocarbons, fatty acids, etc. In addition, when unpleasant smell due to propagation of spoilage bacteria and various mesophilic bacteria is added, Since it is very complicated, it is necessary to maximize the deodorizing effect by fusing and stabilizing various deodorant substances having different functional groups in order to completely remove the odor. In addition, the deodorizing effect is suppressed It must be sustainable. Therefore, the present invention is capable of exhibiting a complex high-efficiency deodorizing effect as well as a sterilizing power by adding sodium chlorite, ammonium persulfate, phosphorus pentoxide, cobalt chloride hexahydrate (carboxymethyl chloride), which are strong oxidizing agents.

5, in order to help understand the complex use of deodorant substances having different functional groups used in the deodorizer of the present invention, deodorant materials suitable for deodorization of the causative substances are listed in Table 1 below.

The deodorant of the present invention rapidly removes various odors generated by the substances causing the odor of various pathways and sustains the deodorizing effect for a long time by exerting a sterilizing power against various bacteria such as spore bacterium. have

Figure 1 Deodorant manufacturing process diagram

The present invention relates to a method of manufacturing a deodorant for achieving the object of the present invention by helping to understand the complex use of deodorant materials having different functional groups used in the deodorizer of the present invention, The details will be described with reference to the drawings as follows

1, Manufacture of mixed composition liquid of extract of plant active ingredient containing deodorant, sterilization and direction component

1-1, the leaves and branches of R. japonica and P. japonicus are collected and mixed at the same or an arbitrary ratio by weight of each plant species, and are pulverized and immersed in an integer of 500 times the weight of the plant pulverized material to prepare a plant pulverizing composition

1-2, and 1-1, the active ingredient is extracted from a plant extractor, filtered, concentrated or admixed with water to obtain an extract of the active ingredient 300 parts by weight relative to the weight of the plant material

The active ingredient extract obtained in steps 1-3 and 1-2 is sterilized by ozone

1-4, "30 to 50% by weight of the extract of the active ingredient sterilized by ozone in step 1 to 3, and 10 to 20% by weight of alcohol (selected in ethanol and methanol)

The "mixed composition liquid of extract of active ingredient of plant" prepared by steps 1-5 and 1-4 shows excellent deodorization, sterilization and antibacterial effect.

2, Water soluble sulfur production

2-1, 25 to 40 parts by weight of sulfur powder, 0.1 to 0.2 parts by weight of salt, and 10 to 30 parts by weight of caustic soda are added to a stirrer

2-2 and 25-70 parts by weight of water are slowly mixed and stirred and low-speed stirring (rpm 15-25) is carried out to obtain molten sulfur + caustic soda melt by reaction of caustic soda with reaction heat and acid and alkali

2-3, and 20-250 parts by weight of water are added to the melt of step 2-2 to make 100 parts by weight of sulfur + caustic soda melt

10 to 30 parts by weight of organic acid (selected from glacial acetic acid, formic acid and anhydrous acetic acid) is added to 100 parts by weight of sulfur + caustic soda melt obtained in steps 2-4 and 2-3 to titrate the caustic soda

The molten liquid in which the caustic soda in steps 2-5 and 2-4 is properly neutralized is filtered to obtain a sulfur melt

2-6, and 2-5 steps to produce a water-soluble sulfur having a sulfur content of 22% of 100 parts by weight

3, deodorant preparation (see Fig. 1)

"A Type " super strong and highly efficient deodorant (color: reddish brown, pH: 12.93, Example" A "

3-1, 10 to 40% by weight of water and 5 to 20% by weight of sodium chlorite are added to a stirrer to prepare a mixture

3-2 and 3-1, low-speed stirring (rpm 15-25) was carried out, and 5-20 wt% of the water-soluble sulfur prepared by the method of the above 2 was added, followed by stirring for 5 to 40 minutes to effect the reaction

After the reaction in steps 3-3 and 3-2, 2 to 10% by weight of ammonium persulfate is added and dissolved while being stirred at a low speed

3-4, Slowly and quantitatively adding an aqueous solution of phosphorus pentoxide inducing a vigorous reaction by adding the same ratio of 2 to 10% by weight of phosphorus pentoxide while stirring at a low speed, if the appropriate reaction is maintained, the 3-3 step non- The ammonium persulfate floats and the dissolution is promoted to secure the transparency of the mixed solution

3-5, 2 to 10% by weight of cobalt chloride hexahydrate ("cobalt dichromate" "application of Clause 4-2") is added at low speed stirring, and the mixture is stirred for 5 to 30 minutes

3-6, and after 3-5 steps, the stirring is stopped for 1 to 5 hours to stabilize the complex oxide

After the completion of steps 3-7 and 3-6, 30-50% by weight of the "mixed composition liquid of the extract of the active ingredient extracts" prepared by the above-mentioned method 1 was added while low-speed stirring (rpm 15-25) Stir

3-8, stirring is stopped, and after stabilization for 1 to 5 hours, it is packed

3-9 The deodorant prepared by the above-described method has difficulty in securing transparency due to the use of cobalt chloride hexahydrate, which is limited in its use but exhibits an ultra-strong, high-efficiency deodorizing effect

3-10, the collection point of odor-generating substances, and the disposal site of the odor source are very high and the value of the use is very high for the large-scale disposal site of the large-scale source requiring rapid treatment

4, securing transparency of deodorant

4-1, 3-9, and the method of manufacturing which can secure the transparency of the deodorant is as follows

4-2, "B" Type high-efficiency deodorant (color: yellow transparent, pH: 12.1, example "B")

1) In step 3-5 above, cobalt chloride hexahydrate is used instead of cobalt dichromate

2) Deodorant has yellow color and transparency can be secured

3) The deodorizing power of the deodorant of the above 2 is reduced to about 5 ~ 10% of the deodorant "A Type" manufactured by the "A" method

4) It shows excellent deodorizing effect on bad odor sources where odor sources such as interior of house, slaughter house, etc. are relatively less corrupt

4-3, "C" Type High efficiency deodorant (color: yellow transparent, pH: 10.75, example "C")

1) Excluding the above steps 3-5

2) Deodorant is colorless and transparent to ensure transparency

3) The deodorizing power of the deodorant of the above 2 is reduced to 10-15% of the deodorant produced by the "B Type" method

4) Excellent deodorizing effect on bad odor sources such as food factory, industrial use, etc.

5, a deodorant prepared by the method according to the third embodiment of the deodorant manufacturing method described above was replaced with the deodorant prepared by the method according to the method of Example 4-2 of Example "A" The deodorant prepared in accordance with the production method according to item 3 was designated as "C" in the example, and the deodorant test results are shown in Table 2

5-1, deodorization test condition

1) Measuring instrument: MultiRAE IR (RAE System CO; LTD USA)

2) Room temperature: 20 ℃ + - 2 ℃

3) Relative humidity: 60%

4) Injection amount of gas: 100ppm each injection amount of gas

5) Deodorant injection amount: 5ml

6) Specification of test vessel: 250 x 250 x 300 (mm)

5-2, deodorization test method

1) Four kinds of gases are injected in the same amount

2) Spray 5ml of deodorant

3) Measure the gas concentration in the container every 5 minutes

Unsigned

Claims

A method for producing a deodorant comprising the steps of preparing a mixture of 10 to 40% by weight of water and 5 to 20% by weight of sodium chlorite, adding 5 to 20% by weight of water soluble sulfur, 2 to 10% by weight of ammonium persulfate, 2 to 10% 2 to 10% by weight of cobalt 6 or cobalt dichromate, 30 to 50% by weight of a mixed composition of an extract of an effective ingredient extract of plants, and stirring and mixing

Wherein the aqueous solution comprises 10 to 40% by weight of water, 5 to 20% by weight of sodium chlorate, 5 to 20% by weight of water-soluble sulfur, 2 to 10% by weight of ammonium persulfate, 2 to 10% 2 to 10% by weight of cobalt or bichromate, 30 to 50% by weight of a mixed composition of an extract of an effective ingredient of a plant,