KR20140144630A - Bubbles with elastic adhesive of the composition - Google Patents

Bubbles with elastic adhesive of the composition Download PDF

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KR20140144630A
KR20140144630A KR1020130066844A KR20130066844A KR20140144630A KR 20140144630 A KR20140144630 A KR 20140144630A KR 1020130066844 A KR1020130066844 A KR 1020130066844A KR 20130066844 A KR20130066844 A KR 20130066844A KR 20140144630 A KR20140144630 A KR 20140144630A
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composition
weight
present
mineral
elasticity
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KR101597192B1 (en
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박세경
이기영
정종하
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엔에프에스(주)
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J1/00Adhesives based on inorganic constituents
    • C09J1/02Adhesives based on inorganic constituents containing water-soluble alkali silicates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • C08K7/04Fibres or whiskers inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • C08K7/04Fibres or whiskers inorganic
    • C08K7/14Glass
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02Homopolymers or copolymers of hydrocarbons
    • C08L25/04Homopolymers or copolymers of styrene
    • C08L25/06Polystyrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04Homopolymers or copolymers of esters
    • C08L33/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/062Copolymers with monomers not covered by C08L33/06
    • C08L33/066Copolymers with monomers not covered by C08L33/06 containing -OH groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04Homopolymers or copolymers of esters
    • C08L33/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10Homopolymers or copolymers of methacrylic acid esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00Compositions of natural rubber
    • C08L7/02Latex
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J9/00Adhesives characterised by their physical nature or the effects produced, e.g. glue sticks

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The present invention relates to a bubble adhesive composition having elasticity characterized by mixing 50 wt% of sodium silicate, 8 wt% of fiber glass, 7 wt% of perlite, 5 wt% of mineral fibers, 5 wt% of cellulose fibers, 2 wt% of foaming agents (surfactants), 3 wt% of bentonite, 3 wt% of titanium oxide (TiO_2), 4 wt% of iron oxide (Fe_2O_3) and 11 wt% of acryl emulsion of solid states and 2 wt% of foamed styrofoam. The bubble adhesive composition is able to stably maintain the functions of finishing materials by preventing the deformation of the finishing materials even when being exposed to external impact or the crack of a wall by giving elasticity to the finishing materials at room temperature by adding acryl emulsion including acrylic resin with a glass transition temperature (Tg) of 20-30°C to a composition of a mineral bubble adhesive.

Description

탄성을 갖는 기포 접착제의 조성물{Bubbles with elastic adhesive of the composition}BACKGROUND OF THE INVENTION 1. Field of the Invention [0001] The present invention relates to a bubble-

본 발명은 탄성을 갖는 기포 접착제의 조성물에 관한 것으로, 더욱 상세하게는 미네랄 기포 접착제의 조성물에 유리전이온도(Tg)가 20 내지 30℃인 아크릴계 수지를 포함하는 아크릴 에멀전을 더 첨가하여 상온에서 마감재에 탄성을 부여함으로, 외부의 충격이나 벽면의 크랙에 노출되더라도 마감재의 변형을 방지하여 안정적으로 마감재의 기능을 유지할 수 있도록 유도하는 탄성을 갖는 기포 접착제의 조성물에 관한 것이다.More specifically, the present invention relates to a composition of a foamed adhesive having elasticity, and more particularly, to a composition of a mineral foam adhesive which further comprises an acrylic emulsion containing an acrylic resin having a glass transition temperature (Tg) of 20 to 30 DEG C, The present invention relates to a composition of a foam adhesive having elasticity which induces elasticity of a finish material to prevent the deformation of the finish material and maintain the function of the finish material stably even when exposed to an external impact or a crack on a wall surface.

일반적으로 건물 내 천장면에 기존의 통상으로 사용하는 단열 마감재는 규산소다(sodium silicate)에 폐지를 분쇄한 분말(cellulose fiber)를 혼합하여 조성하고, 그 조성물을 스프레이(spray) 분무칠 하여 경화시키는 방법으로 마감재를 간편히 형성하였다.Generally, a conventional thermal insulation finishing material used in conventional ceilings in a building is prepared by mixing sodium silicate with pulverized cellulose fiber and spraying the composition to cure The finish material was easily formed.

하지만, 종래의 마감재 조성물을 스프레이(spray) 분무칠 할 때 조성물의 중량으로 인하여 천장면에 고정되지 경화되지 못하고 마감재가 바닥으로 떨어지거나, 그 중량으로 인하여 마감재가 벽면을 타고 흘러내려 많은 비용적 손실이 발생하였다.However, when the conventional finishing composition is sprayed, due to the weight of the composition, the finishing material is not cured or hardened due to the weight of the composition, and the finishing material falls down to the floor, or the finishing material flows down the wall due to the weight, Lt; / RTI >

상기와 같은 문제점을 해결하기 위해, 본 출원인은 "미네랄 기포 접착제의 조성물(특허등록번호:제10-0712645호)"를 개발 제안하여, 가벼운 무게로 인해 흘러내리지 않고 간편히 접착 경화되어 시공이 편리할 뿐만 아니라, 불연, 단열, 광촉매기능을 제공하였다.In order to solve the above problems, the present applicant has proposed "a composition of a mineral foam adhesive (Patent Registration No.: No. 10-0712645)" to propose a simple and easy-to- In addition, it provided fire retardant, thermal insulation, and photocatalytic functions.

하지만, 본 출원인 개발한 "미네랄 기포 접착제의 조성물"은 마감재로 사용되어 경화되고 나면, 그 경화된 마감재가 높은 경도로 딱딱하게 경화되므로 외부의 충격이나 벽면에 크랙이 발생하면 마감재에 크랙이 쉽게 발생하여 마감재로서의 기능을 상실하는 문제점이 있었다.However, the "composition of mineral bubble adhesive" developed by the present applicant is used as a finishing material and hardened, the hardened finishing material is hardened with a high hardness, so that when the external impact or cracks occur on the wall, cracks easily occur in the finishing material So that the function as a finishing material is lost.

대한민국 특허등록번호:제10-0712645호(미네랄 기포 접착제의 조성물)Korean Patent Registration No: 10-0712645 (Composition of Mineral Bubble Adhesive)

본 발명은 상기한 바와 같은 제반 문제점을 해결하기 위하여 제안된 것으로, 그 목적은 미네랄 기포 접착제의 조성물에 유리전이온도(Tg)가 20 내지 30℃인 아크릴계 수지를 포함하는 아크릴 에멀전을 더 첨가하여 상온에서 마감재에 탄성을 부여함으로, 외부의 충격이나 벽면의 크랙에 노출되더라도 마감재의 변형을 방지하여 안정적으로 마감재의 기능을 유지할 수 있도록 유도하는 탄성을 갖는 기포 접착제의 조성물을 제공함에 있다.Disclosure of the Invention The present invention has been proposed in order to solve all of the above problems, and it is an object of the present invention to provide an acrylic emulsion containing an acrylic resin having a glass transition temperature (Tg) The present invention also provides a composition for a foam adhesive having elasticity that induces elasticity to a finish material to prevent the deformation of the finish material and maintain the function of the finish material stably even when exposed to an external impact or a crack on a wall surface.

상기와 같은 목적을 달성하기 위한 본 발명에 따른 탄성을 갖는 기포 접착제의 조성물은 규산소다(sodium silicate) 50중량%, 유리섬유(fiber glass) 8중량%, 펄라이트(perlite) 7중량%, 미네랄 화이버(mineral fiber) 5중량%, 분쇄한 폐지(cellulose fiber) 5중량%, 기포제(계면활성제) 2중량%, 벤토나이트(bentonite) 3중량%, 이산화티타늄(TIO2) 3중량%, 산화철(Fe2O3) 4중량% 및 고형분의 아크릴 에멀전 11중량%, 발포된 스티로폼 2중량%를 교반하여 혼합한 것을 특징으로 한다.In order to attain the above object, the present invention provides an elastic foam adhesive composition comprising 50% by weight of sodium silicate, 8% by weight of fiber glass, 7% by weight of perlite, (mineral fiber) 5%, pulverized abolished by weight (cellulose fiber) 5% by weight, foaming agent (surface active agent) 2% by weight of bentonite (bentonite), 3% by weight, titanium dioxide (TIO 2) 3% by weight of iron oxide (Fe 2 O 3 ) and 11% by weight of an acrylic emulsion having a solid content and 2% by weight of foamed styrofoam were mixed with stirring.

또한, 상기 아크릴 에멀전은 유리전이온도(Tg)가 20 내지 30℃인 아크릴계 수지가 포함되는 것을 특징으로 한다.The acrylic emulsion includes an acrylic resin having a glass transition temperature (Tg) of 20 to 30 ° C.

또한, 상기 아크릴계 수지로는 n-BuMA(n-Butyl Metha Acrylate)와, 2-HPMA(2-Hydroxy Propyl Metha Acrylate) 중에서 선택되는 1종 또는 2종을 혼합하여 사용하는 것을 특징으로 한다.The acrylic resin may be a mixture of one or two selected from n-BuMA (n-Butyl Methacrylate) and 2-HPMA (2-Hydroxy Propyl Methacrylate).

또한, 상기 아크릴 에멀전을 대신하여 천연고무인 라텍스(latex)가 사용되는 것을 특징으로 한다.In addition, latex, which is a natural rubber, is used in place of the acrylic emulsion.

이상에서와 같이 본 발명에 따른 탄성을 갖는 기포 접착제의 조성물에 의하면, 미네랄 기포 접착제의 조성물에 유리전이온도(Tg)가 20 내지 30℃인 아크릴계 수지를 포함하는 아크릴 에멀전을 더 첨가하여 상온에서 마감재에 탄성을 부여함으로, 외부의 충격이나 벽면의 크랙에 노출되더라도 마감재의 변형을 방지하여 안정적으로 마감재의 기능을 유지할 수 있도록 유도하는 효과가 있다.As described above, according to the composition of the elastic foam adhesive of the present invention, an acrylic emulsion containing an acrylic resin having a glass transition temperature (Tg) of 20 to 30 ° C is further added to the composition of the mineral foam adhesive, So that it is possible to prevent the deformation of the finish material and to stably maintain the function of the finish material even if it is exposed to an external impact or a crack on the wall surface.

본 발명의 바람직한 실시예에 따른 탄성을 갖는 기포 접착제의 조성물를 첨부된 도면에 의거하여 상세히 설명한다. 본 발명의 요지를 불필요하게 흐릴 수 있다고 판단되는 공지 기능 및 구성에 대한 상세한 기술은 생략한다.The composition of a bubble adhesive having elasticity according to a preferred embodiment of the present invention will be described in detail with reference to the accompanying drawings. Detailed descriptions of well-known functions and constructions that may be unnecessarily obscured by the gist of the present invention will be omitted.

본 발명의 실시예에 따른 탄성을 갖는 기포 접착제의 조성물은 규산소다(sodium silicate) 50중량%, 유리섬유(fiber glass) 8중량%, 펄라이트(perlite) 7중량%, 미네랄 화이버(mineral fiber) 5중량%, 분쇄한 폐지(cellulose fiber) 5중량%, 기포제(계면활성제) 2중량%, 벤토나이트(bentonite) 3중량%, 이산화티타늄(TIO2) 3중량%, 산화철(Fe2O3) 4중량% 및 고형분의 아크릴 에멀전 11중량%, 발포된 스티로폼 2중량%를 충분히 교반 혼합하여 조성한다.The composition of the elastic foam adhesive according to the embodiment of the present invention is composed of 50% by weight of sodium silicate, 8% by weight of fiber glass, 7% by weight of perlite, 5% by weight of mineral fiber 5 5 wt% of pulverized cellulose fiber, 2 wt% of foaming agent (surfactant), 3 wt% of bentonite, 3 wt% of titanium dioxide (TIO 2 ), 4 wt% of iron oxide (Fe 2 O 3 ) %, An acrylic emulsion having a solid content of 11% by weight, and a foamed styrofoam of 2% by weight.

여기서, 상기 규산소다는 무기질 난연제로 본 발명의 탄성을 갖는 기포 접착제의 조성물에서는 접착제의 용도로 사용되며, 상기 유리섬유 및 미네랄 화이버는 경량으로 점성과 가교의 역할로 사용되어 본 발명의 탄성을 갖는 기포 접착제의 조성물이 마감재로 사용되면 마감재의 견고한 접착 구조를 유도하며, 상기 퍼라이트 및 벤토나이트는 완제품의 단열 및 흡음 기능을 향상시키는 용도로 사용되며, 상기 이산화티타늄은 유해물질을 산화 분해하여 환경정화(환경오염을 제거하고 항균, 탈취하는 등의 효과)하는 광촉매 기능을 기대할 수 있다.Said silicate is an inorganic flame retardant and is used as an adhesive in a composition of a foam adhesive having elasticity of the present invention. The glass fiber and the mineral fiber are used in light weight as a function of viscosity and crosslinking, When the composition of the foam adhesive is used as a finish material, it induces a firm bonding structure of the finish material. The perlite and bentonite are used for improving the heat insulation and sound absorption function of the finished product. The titanium dioxide oxidizes and decomposes harmful substances It is possible to expect a photocatalytic function of removing environmental pollution and effecting antibacterial and deodorization).

한편, 상기 스티로폼은 본 발명의 탄성을 갖는 기포 접착제의 조성물이 사용되는 마감재가 우수한 방음 및 단열의 기능을 갖도록 유도하되, 상기 스티로폼은 원료인 폴리스티렌(PS)에 발포제와 함께 난연제(F,Cl,Br)가 함유되어 있는 폴리스티렌(EPS) 원료를 발포하여 난연성이 부여된 스티로폼을 사용하여 제품의 불연성능을 유지함은 물론이다.In the meantime, the styrofoam is used to induce the finishing material in which the composition of the elastic bubble adhesive of the present invention has excellent soundproofing and heat insulating function, and the styrofoam is added to the raw material polystyrene (PS) together with the blowing agent (F, Cl, It is of course also possible to maintain the fire-retardant performance of the product by using foamed styrofoam by foaming a raw material of polystyrene (EPS) containing Br.

한편, 상기 아크릴 에멀전은 본 발명의 탄성을 갖는 기포 접착제의 조성물이 사용되는 마감재가 탄성을 가지도록, 유리전이온도(Tg)가 20 내지 30℃인 아크릴계 수지를 포함하여 제작함이 바람직하다.In the meantime, the acrylic emulsion is preferably made of an acrylic resin having a glass transition temperature (Tg) of 20 to 30 ° C so that the finish material used in the composition of the elastic bubble adhesive of the present invention has elasticity.

따라서, 본 발명에 따른 탄성을 갖는 기포 접착제의 조성물이 사용되는 마감재는 상온에서 탄성을 확보함으로, 외부의 충격이나 벽면의 크랙에 노출되더라도 마감재의 변형을 방지하여 안정적으로 마감재의 기능을 유지할 수 있도록 유도하는 장점을 기대할 수 있다.Therefore, the finishing material using the composition of the elastic bubble adhesive according to the present invention secures elasticity at room temperature, so that even if it is exposed to external impact or cracks on the wall, the finishing material is prevented from being deformed and the function of the finishing material can be stably maintained The advantage of inducing can be expected.

이때, 상온에서 마감재가 탄성을 확보할 수 있도록 상기 아크릴계 수지로는 20℃의 유리전이온도(Tg)를 갖는 n-BuMA(n-Butyl Metha Acrylate), 26℃의 유리전이온도(Tg)를 갖는 2-HPMA(2-Hydroxy Propyl Metha Acrylate) 중에서 선택되는 1종 또는 2종을 혼합하여 사용함이 바람직하다.In order to ensure the elasticity of the finishing material at room temperature, the acrylic resin has n-BuMA (n-Butyl Methacrylate) having a glass transition temperature (Tg) of 20 ° C and a glass transition temperature 2-hydroxypropyl methaacrylate (2-HPMA), or a combination of two or more thereof.

여기서, 상기 아크릴 에멀전을 대신하여 우수한 탄성을 갖는 천연고무인 라텍스(latex)가 사용될 수 있음은 물론이다.It is needless to say that latex which is natural rubber having excellent elasticity can be used instead of the acrylic emulsion.

상기와 같은 구성을 가진 본 발명의 실시예에 따른 탄성을 갖는 기포 접착제의 조성물은 다음과 같이 조성하여 사용한다.The composition of the elastic bubble adhesive according to the embodiment of the present invention having the above-described composition is used as follows.

먼저, 규산소다(sodium silicate) 500g, 유리섬유(fiber glass) 80g, 펄라이트(perlite) 70g, 미네랄 화이버(mineral fiber) 50g, 분쇄한 폐지(cellulose fiber) 50g, 기포제(계면활성제) 20g, 벤토나이트(bentonite) 30g, 이산화티타늄(TIO2) 30g, 산화철(Fe2O3) 40g 및 고형분의 아크릴 에멀전 130g을 충분히 교반하여 본 발명의 탄성을 갖는 기포 접착제의 조성물로 제작한다.First, 500 g of sodium silicate, 80 g of fiber glass, 70 g of perlite, 50 g of mineral fiber, 50 g of pulverized cellulose fiber, 20 g of foaming agent (surfactant) 30 g of bentonite, 30 g of titanium dioxide (TIO 2 ), 40 g of iron oxide (Fe 2 O 3 ) and 130 g of solid acrylic emulsion are thoroughly agitated to prepare a composition of the elastic foam adhesive of the present invention.

이때, 상기 아크릴 에멀전으로 n-BuMA(n-Butyl Metha Acrylate)를 사용하여 본 발명의 탄성을 갖는 기포 접착제의 조성물로 형성되는 마감재가 상온에서 충분한 탄성이 확보되도록 유도한다.At this time, n-BuMA (n-Butyl Methacrylate) as the acrylic emulsion is used to induce the finish material formed from the composition of the elastic foam adhesive of the present invention to secure sufficient elasticity at room temperature.

상기와 같이 조성된 본 발명의 탄성을 갖는 기포 접착제의 조성물(1000g)에 물을 5000g을 첨가 교반하여 희석시킨 후, 건물의 벽면이나 천장에 스프레이 분무칠 하여 일정시간 자연 경화시켜 단열, 불연, 광촉매기능 뿐만 아니라, 상온에서 우수한 탄성을 확보하여 외부의 충격이나 벽면의 크랙에 노출되더라도 효과적으로 변형 및 크랙을 방지할 수 있는 마감재를 간편히 형성할 수 있다.5000 g of water was added to 1000 g of the elastic foam adhesive composition of the present invention, which was diluted with stirring, sprayed on the wall or ceiling of the building, spontaneously cured for a predetermined period of time, It is possible to easily form a finishing material capable of effectively preventing deformation and cracking even when exposed to an external impact or a crack on a wall surface.

본 발명은 첨부된 도면에 도시된 실시예를 참고로 설명되었으나 이는 예시적인 것으로 상술한 실시예에 한정되지 않으며, 당해 분야에서 통상의 지식을 가진 자라면 이로부터 다양한 변형 및 균등한 실시예가 가능하다는 점을 이해할 수 있을 것이다. 또한, 본 발명의 사상을 해치지 않는 범위 내에서 당업자에 의한 변형이 가능함은 물론이다. 따라서, 본 발명에서 권리를 청구하는 범위는 상세한 설명의 범위 내로 정해지는 것이 아니라 후술되는 청구범위와 이의 기술적 사상에 의해 한정될 것이다.
While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it is clearly understood that the same is by way of illustration and example only and is not to be construed as limiting the scope of the invention as defined by the appended claims. You will understand the point. It goes without saying that variations can be made by those skilled in the art without departing from the spirit of the present invention. Accordingly, the scope of claim of the present invention is not limited within the scope of the detailed description, but will be defined by the following claims and technical ideas thereof.

Claims (4)

미네랄 기포 접착제의 조성물에 있어서,
규산소다(sodium silicate) 50중량%, 유리섬유(fiber glass) 8중량%, 펄라이트(perlite) 7중량%, 미네랄 화이버(mineral fiber) 5중량%, 분쇄한 폐지(cellulose fiber) 5중량%, 기포제(계면활성제) 2중량%, 벤토나이트(bentonite) 3중량%, 이산화티타늄(TIO2) 3중량%, 산화철(Fe2O3) 4중량% 및 고형분의 아크릴 에멀전 11중량%, 발포된 스티로폼 2중량%를 교반하여 혼합한 것을 특징으로 하는 탄성을 갖는 기포 접착제의 조성물.
In the composition of the mineral foam adhesive,
50% by weight of sodium silicate, 8% by weight of fiber glass, 7% by weight of perlite, 5% by weight of mineral fiber, 5% by weight of pulverized cellulose fiber, 2 wt% of a surfactant, 3 wt% of bentonite, 3 wt% of titanium dioxide (TIO 2 ), 4 wt% of iron oxide (Fe 2 O 3 ), 11 wt% of an acrylic emulsion of solid content, % Of the total weight of the composition is mixed with stirring.
제 1 항에 있어서,
상기 아크릴 에멀전은 유리전이온도(Tg)가 20 내지 30℃인 아크릴계 수지가 포함되는 것을 특징으로 하는 탄성을 갖는 기포 접착제의 조성물.
The method according to claim 1,
Wherein the acrylic emulsion contains an acrylic resin having a glass transition temperature (Tg) of 20 to 30 占 폚.
제 2 항에 있어서,
상기 아크릴계 수지로는,
n-BuMA(n-Butyl Metha Acrylate)와, 2-HPMA(2-Hydroxy Propyl Metha Acrylate) 중에서 선택되는 1종 또는 2종을 혼합하여 사용하는 것을 특징으로 하는 탄성을 갖는 기포 접착제의 조성물.
3. The method of claim 2,
As the acrylic resin,
The composition of claim 1, wherein one or two selected from n-BuMA (n-Butyl Metha Acrylate) and 2-HPMA (2-Hydroxy Propyl Metha Acrylate) are mixed.
제 1 항에 있어서,
상기 아크릴 에멀전을 대신하여 천연고무인 라텍스(latex)가 사용되는 것을 특징으로 하는 탄성을 갖는 기포 접착제의 조성물.
The method according to claim 1,
Wherein a latex, which is a natural rubber, is used in place of the acrylic emulsion.
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20060070499A (en) * 2006-05-04 2006-06-23 전창호 Compositions of Functional Adhesives and Methods for Making the Same
KR100712645B1 (en) 2005-11-30 2007-05-02 전창호 Composition of mineral bubble adhesive
KR20090016809A (en) * 2007-08-13 2009-02-18 (주)새론화인켐 Process for preparing flame retardant one component inorganic adhesive and one component inorganic adhesive prepared thereby
KR101142392B1 (en) * 2010-08-26 2012-05-07 양필성 Liquefied adhesion enhancer for improving adhesive property between wall and wallpaper

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100712645B1 (en) 2005-11-30 2007-05-02 전창호 Composition of mineral bubble adhesive
KR20060070499A (en) * 2006-05-04 2006-06-23 전창호 Compositions of Functional Adhesives and Methods for Making the Same
KR20090016809A (en) * 2007-08-13 2009-02-18 (주)새론화인켐 Process for preparing flame retardant one component inorganic adhesive and one component inorganic adhesive prepared thereby
KR101142392B1 (en) * 2010-08-26 2012-05-07 양필성 Liquefied adhesion enhancer for improving adhesive property between wall and wallpaper

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