KR20060070499A - Compositions of Functional Adhesives and Methods for Making the Same - Google Patents

Compositions of Functional Adhesives and Methods for Making the Same Download PDF

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Publication number
KR20060070499A
KR20060070499A KR1020060042334A KR20060042334A KR20060070499A KR 20060070499 A KR20060070499 A KR 20060070499A KR 1020060042334 A KR1020060042334 A KR 1020060042334A KR 20060042334 A KR20060042334 A KR 20060042334A KR 20060070499 A KR20060070499 A KR 20060070499A
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weight
water
silicate
soluble
composition
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KR1020060042334A
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Korean (ko)
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전창호
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전창호
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
    • C08L1/08—Cellulose derivatives
    • C08L1/10—Esters of organic acids, i.e. acylates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J1/00—Adhesives based on inorganic constituents
    • C09J1/02—Adhesives based on inorganic constituents containing water-soluble alkali silicates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/04—Non-macromolecular additives inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J9/00—Adhesives characterised by their physical nature or the effects produced, e.g. glue sticks

Abstract

본 발명은 기능성 접착제의 조성물 및 그의 제조방법으로서, 주거생활 실내의 벽지, 바닥제등 각종의 유기용제를 사용한 화학접착제로 인한 인체의 피부질환, 두통, 호흡기장애등의 문제점을 근본적으로 해결코자 환경친화적이고, 인체친화적인 수용성 에너지 절감, 전자파 및 수맥파 자폐 기능성 접착제의 조성물 및 그의 제조방법에 목적이 있다.The present invention is a composition of a functional adhesive and a method for manufacturing the same, which is environmentally friendly to fundamentally solve problems such as skin diseases, headaches, respiratory disorders of the human body caused by chemical adhesives using various organic solvents such as wallpaper, flooring, etc. It is aimed at the composition of the human-friendly water-soluble energy saving, electromagnetic and water-wave autism functional adhesives and a method of manufacturing the same.

이의 조성물로서, 교반기에서 계속적인 교반중에 고형분 40％농도의 점액질 액상의 1. 규산소다(sodium silicate(고형분 40％농도의 점액질)): 40중량％, 2. 규산칼리 : 19중량％, 3. 수용성 아크릴 에멀젼(acryl emulsion): 5중량, 4. 수용성 폴리우레탄(polyurethane emulsion) : 5중량％, 5. 카르복시 메틸 셀룰로오즈(carboxymethyl cellulose): 2중량％, 6. 비이온계면활성제 : 1중량％, 7. 벤토나이트(bentonite) : 10중량％, 8. 황토(또는 제올라이트, 규조토): 5중량％, 9. 석고분말: 5중량％, 10. 활성탄(carbon black): 1중량％, 11. 실리카분말(silicate powder): 5중량％, 12. 콜로이달 은(colloidal silver): 1중량％를 교반기에서 혼합하여 조성한 열에너지 축열기능, 전자파 차폐기능, 수맥파 차폐기능의 특징이 있는 기능성 접착제의 조성물 및 그의 제조방법.As a composition thereof, during continuous stirring in a stirrer, 1.40% by weight of solid silicate (sodium silicate): 40% by weight, 2. silicate: 19% by weight, 3. Water-soluble acrylic emulsion: 5% by weight, 4. water-soluble polyurethane emulsion: 5% by weight, 5. carboxymethyl cellulose: 2% by weight, 6. nonionic surfactant: 1% by weight, 7. bentonite: 10% by weight, 8. loess (or zeolite, diatomaceous earth): 5% by weight, 9. gypsum powder: 5% by weight, 10. activated carbon (carbon black): 1% by weight, 11. silica powder (silicate powder): 5% by weight, 12. colloidal silver (colloidal silver): a composition of a functional adhesive characterized by heat energy storage function, electromagnetic wave shielding function, water-wave shielding function formed by mixing 1% by weight in a stirrer and preparation thereof Way.

규산소다(sodium silicate). 규산칼리(potassium silicate). 수용성 아크릴 에멀젼(acryl emulsion). 수용성 폴리우레탄 에멀젼(polyurethane emulsion). 카르 복시 메틸 셀루로오즈(carboxymethyl cellulous). 비이온계면활성제. 벤토나이트(bentonite). 황토. 석고분말. 활성탄(carbon black). 실리카분말(silicate powder). 콜로이달 은(colloidal silver). Sodium silicate. Potassium silicate. Water soluble acrylic emulsion. Water soluble polyurethane emulsion. Carboxymethyl cellulous. Nonionic surfactants. Bentonite. ocher. Gypsum powder. Activated carbon. Silica powder. Colloidal silver.

Description

기능성 접착제의 조성물 및 그의 제조방법{omitted}Composition of the functional adhesive and a method for producing the same

본 발명은 기능성 접착제의 조성물 및 그의 제조방법으로서, 주거생활 실내의 벽지, 바닥제등 각종의 휘발성 유기용제를 사용한 화학접착제로 인한 새집 증후군으로 화재시 유독가스의 발생, 인체의 피부질환, 두통, 호흡기장애등의 문제점을 근본적으로 해결한 비 휘발성, 난연, 수용성 접착제로서 무기질 접착제인 규산소다(sodium silicate), 규산칼리(potassium silicate), 축열기능의 황토, 수축작용의 안정제로 벤토나이트(bentonite), 축열 및 전자파 차페기능의 활성탄(carbon black), 콜로이달 은(colloidal silver)등을 사용하여 조성된 인체친화적인 기능성 접착제의 조성물 및 그의 제조방법.The present invention relates to a composition of a functional adhesive and a method of manufacturing the same, which is caused by a new house syndrome caused by a chemical adhesive using various volatile organic solvents such as wallpaper and flooring in a living room, generation of toxic gases in case of fire, skin diseases of the human body, headache, respiratory tract. Non-volatile, flame-retardant and water-soluble adhesives that fundamentally solve the problems of disability such as inorganic silicate (sodium silicate), silicate (potassium silicate), thermal storage loess, bentonite, heat storage and A composition of a human-friendly functional adhesive using carbon black, colloidal silver, etc., having an electromagnetic shielding function, and a method of manufacturing the same.

본 발명은 상기와 같은 종래의 문제점을 해결하기 위해 안출한 것으로서, 종래의 접착제는 유기용제를 사용하여 포르마린으로 축합하여 만든 멜라민, 요소 수지 접착제, 또는 유기용제를 사용한 우레탄, 아크릴 수지 등은 휘발성 냄새가 강하고, 화재시에 유독가스의 발생의 문제점을 해결하기 위하여 수용성 접착제를 만들고자 하는 것으로서, 무기질으로서 접착제 기능이 있는 규산소다(sodium silicate), 규산칼리(potassium silicate)수용성 액상의 단점인 으름이 빠르고, 경화가 늦어 접착제의 표면에 피막이 발생하는 문제점을 벤토나이트(bentonite), 증점제인 카르복시 메틸 셀루로오즈(caboxymethyl cellulose)를 첨가, 접착표면의 계면력을 높이는 , 혼화성이 우수한 비이온 계면활성제를 1％ 첨가하고, 항균기능 및 전자파 차폐기능, 열 보존이 우수한 황토, 활성탄(carbon black) 콜로이달 은(colloidal silver)를 첨가하고 경화 강도를 높이고자 실리카분말(silicate powder)를 첨가하여 조성한 것에 그 기술적 차이가 있는 기능성 접착제의 조성물 및 그의 제조방법.The present invention has been made to solve the above conventional problems, the conventional adhesive is melamine, urea resin adhesive, or a urethane, acrylic resin using the organic solvent condensed with formarin using an organic solvent has a volatile odor In order to solve the problem of the generation of toxic gas at the time of fire, it is to make water-soluble adhesive, which is a disadvantage of sodium silicate and potassium silicate water-soluble liquid, which has an adhesive function as a mineral. In addition, bentonite and carboxymethyl cellulose, a thickening agent, are added to the surface of the adhesive due to the slow curing. %, Ocher, activated carbon (antimicrobial function, electromagnetic shielding function, heat storage) carbon black) A composition of a functional adhesive having a technical difference in that it is formed by adding colloidal silver and adding a silica powder to increase curing strength, and a method of manufacturing the same.

본 발명의 조성물을 상세히 설명하면 다음과 같다.The composition of the present invention will be described in detail as follows.

중량％로 1. 규산소다(sodium silicate(고형분 40％농도의 점액질)): 40중량％, 2. 규산칼리(potassium silicate(고형분 40％농도의 점액질)): 19중량％, 3. 수용성 아크릴 에멀젼(acryl emulsion): 5중량％, 4. 수용성 폴리우레탄 에멀젼(polyurethane emulsion): 5중량％, 5. 카르복시 메틸 셀루로오즈(carboxymethyl cellulose): 2중량％, 6. 비이온계면활성제: 1중량％, 7. 벤토나이트(bentonite): 10중량％, 8. 황토(또는 제올라이트, 규조토): 5중량％, 9. 석고분말: 5중량％, 10. 활성탄(carbon black): 1중량％, 11. 실리카분말(silicate powder): 5중량％, 12. 입도가 0.3-1.3nm, 은이온(Ag+)농도가 16ppm인 콜로이달 은(colloidal silver): 1중량％를 교반중에 첨가하여 수용성 점액질의 기능성 접착제를 완성 하였다.By weight% 1. Sodium silicate (Sodium silicate (Solid 40% solids)): 40% by weight, 2. Silicate (potassium silicate (Solid 40% Solids)): 19% by weight, 3. Water-soluble acrylic emulsion (acryl emulsion): 5% by weight, 4. Water-soluble polyurethane emulsion: 5% by weight, 5. Carboxymethyl cellulose: 2% by weight, 6. Nonionic surfactant: 1% by weight , 7. bentonite: 10% by weight, 8. loess (or zeolite, diatomaceous earth): 5% by weight, 9. gypsum powder: 5% by weight, 10. carbon black: 1% by weight, 11. silica Silicate powder: 5% by weight, 12. Colloidal silver with particle size 0.3-1.3nm, silver ion (Ag + ) concentration: 16ppm: 1% by weight of water-soluble mucolytic adhesive Completed.

상술한 바와 같이 본 발명에 의하여 만들어진 수용성 접착제는 난연, 불휘발성, 축열 효과에 의한 에너지절감, 전자파차폐, 나노입자의 콜로이달 은(colloidal silver)에 의하여 수맥파, 전자파를 방전시키고, 박테리아, 바이러스균에 대한 99.9％의 항균력이 확인 되었다.As described above, the water-soluble adhesive produced by the present invention is flame retardant, nonvolatile, energy saving due to the heat storage effect, electromagnetic shielding, discharge of the water wave, electromagnetic waves by the colloidal silver of the nanoparticles, bacteria, virus bacteria An antimicrobial activity of 99.9% against was confirmed.

Claims (1)

본 발명은 중량％로, 1. 규산소다(sodium silicate(고형분 40％농도의 점액질)): 40중량％, 2. 규산칼리(potassium silicate(고형분 40％농도의 점액질)): 19중량％, 3. 수용성 아크릴 에멀젼(acryl emulsion): 5중량％, 4. 수용성 폴리우레탄 에멀젼(polyurethane emulsion): 5중량％, 5. 카르복시 메틸 셀루로오즈(carboxymethyl cellulose): 2중량％, 6. 비이온계면활성제: 1중량％, 7. 벤토나이트(bentonite): 10중량％, 8. 황토(또는 제올라이트, 규조토): 5중량％, 9. 석고분말: 5중량％, 10. 활성탄(carbon black): 1중량％, 11. 실리카분말(silicate powder): 5중량％, 12. 입도가 0.3-1.3nm, 은이온(Ag+)농도가 16ppm인 콜로이달 은(colloidal silver)용액: 1중량％를 교반중에 혼합하여 점액질의 수용성 접착제의 그 특징이 있는 기능성 접착제의 조성물 및 그의 제조방법.The present invention is in weight percent, 1. Sodium silicate (sodium silicate (slime content of 40% solids)): 40% by weight, 2. Potassium silicate (potassium silicate (slime content 40% solids)): 19% by weight, 3 Water-soluble acrylic emulsion: 5% by weight, 4. water-soluble polyurethane emulsion: 5% by weight, 5. carboxymethyl cellulose: 2% by weight, 6. nonionic surfactant : 1% by weight, 7. Bentonite: 10% by weight, 8. Ocher (or zeolite, diatomaceous earth): 5% by weight, 9. Gypsum powder: 5% by weight, 10. Activated carbon (carbon black): 1% by weight , 11. Silicate powder: 5% by weight, 12. Colloidal silver solution with particle size 0.3-1.3nm, silver ion (Ag + ) concentration: 16ppm: 1% by weight while mixing A composition of the functional adhesive characterized by the mucus-soluble water-soluble adhesive, and a method for producing the same.
KR1020060042334A 2006-05-04 2006-05-04 Compositions of Functional Adhesives and Methods for Making the Same KR20060070499A (en)

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100780555B1 (en) * 2006-04-22 2007-11-30 양필성 Constructing method of panel material sticking on surface of concrete wall of construction
KR100855165B1 (en) * 2006-10-18 2008-08-29 주식회사 칠만공사 A process which make a waterproof stuff of loess
EP2142598A1 (en) * 2007-04-26 2010-01-13 Encepkorea CO., LTD. Fire retardancy and shape retention reinforced polyester
CN102863907A (en) * 2012-10-17 2013-01-09 中南林业科技大学 Flexible water-resistant silicate wood adhesive and preparation method thereof
KR101225534B1 (en) * 2010-11-10 2013-01-25 박은수 Preparation of nano porous polymeric electro conductive nano composite filler and inorganic waterproof silicate water-born coating agent with electro-magnetic Silicate shielding properties there in and a manufacturing method
KR101461073B1 (en) * 2014-03-13 2014-11-13 고병권 Functional adhesive composition and method of manufacturing the same
KR20140144630A (en) * 2013-06-11 2014-12-19 엔에프에스(주) Bubbles with elastic adhesive of the composition
WO2015016802A1 (en) * 2013-07-29 2015-02-05 Tac Boya Sanayi Ve Ticaret Ltd. Sti̇. Electromagnetic radiation shielding paint
CN109266266A (en) * 2018-08-30 2019-01-25 浙江理工大学 A kind of water polyacrylic acid/polyurethane/SiO2The preparation method of nano combined binder

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100780555B1 (en) * 2006-04-22 2007-11-30 양필성 Constructing method of panel material sticking on surface of concrete wall of construction
KR100855165B1 (en) * 2006-10-18 2008-08-29 주식회사 칠만공사 A process which make a waterproof stuff of loess
EP2142598A1 (en) * 2007-04-26 2010-01-13 Encepkorea CO., LTD. Fire retardancy and shape retention reinforced polyester
US20100152335A1 (en) * 2007-04-26 2010-06-17 Yong Jong Lee Fire retardancy and shape retention reinforced polyester
US8142689B2 (en) * 2007-04-26 2012-03-27 Encepkorea Co., Ltd. Fire retardancy and shape retention reinforced polyester
EP2142598A4 (en) * 2007-04-26 2012-11-28 Encepkorea Co Ltd Fire retardancy and shape retention reinforced polyester
KR101225534B1 (en) * 2010-11-10 2013-01-25 박은수 Preparation of nano porous polymeric electro conductive nano composite filler and inorganic waterproof silicate water-born coating agent with electro-magnetic Silicate shielding properties there in and a manufacturing method
CN102863907A (en) * 2012-10-17 2013-01-09 中南林业科技大学 Flexible water-resistant silicate wood adhesive and preparation method thereof
KR20140144630A (en) * 2013-06-11 2014-12-19 엔에프에스(주) Bubbles with elastic adhesive of the composition
WO2015016802A1 (en) * 2013-07-29 2015-02-05 Tac Boya Sanayi Ve Ticaret Ltd. Sti̇. Electromagnetic radiation shielding paint
KR101461073B1 (en) * 2014-03-13 2014-11-13 고병권 Functional adhesive composition and method of manufacturing the same
CN109266266A (en) * 2018-08-30 2019-01-25 浙江理工大学 A kind of water polyacrylic acid/polyurethane/SiO2The preparation method of nano combined binder
CN109266266B (en) * 2018-08-30 2020-06-19 浙江理工大学 Water-based polyacrylate/polyurethane/SiO2Preparation method of nano composite adhesive

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