KR20140000504A - Eye make-up composition of oil-dispersion type or water-in-oil type - Google Patents

Abstract

The present invention relates to an oil-dispersion type or water-in-oil type eye make-up composition and, more specifically, to an oil-dispersion type or water-in-oil type eye make-up composition with enhanced oil resistance, water resistance, rub resistance, and make-up effects which includes a high melting point ester based wax, a glycerin fatty acid ester based oil dispersant, and a silicon based polymer / hydriding cyclopentadiene resin film former. Such eye make-up composition has excellent oil resistance, water resistance, rub resistance, and make-up effects and can be used as a material for a mascara or a liquid eyeliner.

Description

[0001] The present invention relates to an eye make-up composition of an oil-dispersible type or a water-in-oil type,

Disclosed herein is an oil-based, water-in-oil type eye makeup composition. The oil-based oil-in-water type eye makeup composition comprises oil-soluble, water-resistant, abrasion- To an oil-in-water or oil-dispersed eye makeup composition excellent in cosmetic effect.

In general, eye makeup products include mascara, eyeliner, eye shadow, and eye pencil. Among these, mascara and eye liner are representative. The mascara is used to curl the eyelashes and give a volume feeling to make the eyelashes lengthen and enrich the eyes. The eyeliner is used to give a facial expression to the eyes. The eyeliner expresses the outline of the eyes to make the eyes more clearly, It is used to emphasize more effectively. Especially, oriental women with relatively low eyelashes and small eyes compared to western women have a desire to express more clearly and clearly by making mascara or eyeliner makeup.

Mascara, etc. In the 70s and 80s, the focus was mainly on safety. In the 1990s, however, focusing on eyebrows and curling effects, In addition to these features, development focus has been focused on improving the affinity and adhesion of eyebrows with vegetable materials. In addition, products that make the film formed on the eyelashes blend in contact with water such as sweat and water are being developed continuously by blending polymers having excellent affinity with eyelashes.

Mascara and the like can be classified according to their formulations and functions, and can be broadly divided into an oil-in-water type, an oil-in-water type, a water-in-oil type, an oil-dispersion type, and a water-in-oil type. The oil-in-water type is a formulation mainly composed of solid oil, semi-solid oil, liquid oil, emulsifier, and water, and is liable to be erased in moisture, perspiration, etc., The contents of the make-up composition are spread, and as the time passes, the periphery of the eyes becomes dirty. In order to compensate for this, the water-in-oil film type developed in the present invention includes a water-soluble polymer or a polymer emulsion as a film-forming agent in an oil-in-water type. However, this formulation can not obtain sufficient continuity when a polymer substance is exposed to moisture for a long period of time. On the other hand, the water-in-oil or oil-dispersion type is composed of a solid oil fraction, a semi-solid oil fraction, a liquid oil fraction, and a volatile hydrocarbon-based oil, which is excellent in water resistance but has poor oil resistance and abrasion resistance. In addition, hydrocarbons / silicone oils (isododecane, cyclomethicone, etc.) used as oil or water dispersion types of trauma are slower in drying speed than water-in-oil and water-in-oil type trauma so that the mascara's eyelash curling and volume effect There is a drawback that it is lowered.

Therefore, in order to impart sustainability to the eye makeup product, a water-in-oil type formulation having excellent water resistance is selected, and in order to improve the oil resistance, the frictional resistance and the cosmetic effect, an appropriate amount of the oily polymer and resin is generally used. Oily polymers and resins are often used in mascara because of their ability to increase the sustainability to water with increasing content, but they have a disadvantage in that they are less persistent to sebum.

In recent years, silicon-based polymers and rosin-based resins are often mixed to compensate for the persistence of oil-based sebum and friction. However, rosin resins have high trait and color instability, low compatibility with oil type volatile hydrocarbon oils, and have been reported to cause eye allergy.

Accordingly, the inventors of the present invention have been studying an oil-dispersed or water-in-oil type eye makeup composition having improved oil resistance, frictional resistance and cosmetic effect, and have found that a high melting point ester wax, a glycerin fatty acid ester type oil dispersant and a silicone polymer / hydrogenated polycyclopentadiene resin film The present inventors have accomplished the present invention by confirming that the composition containing the lubricant exhibits excellent oil resistance, frictional resistance, curling and volume effect.

An object of the present invention is to provide an oil-dispersed or water-in-oil type eye makeup composition excellent in water resistance, oil resistance, frictional resistance and cosmetic effect.

In order to solve the above problems, there is provided an eye makeup composition comprising, as an active ingredient, 5 to 20 wt% of high melting point ester wax, 0.5 to 10 wt% of an emulsifier and 5 to 50 wt% of a film- .

The eye makeup composition of the present invention is preferably an oil-dispersible or water-in-oil type.

The eye makeup composition according to an embodiment of the present invention is superior in oil resistance and abrasion resistance to a conventional composition prepared by mixing with an oil-based film forming agent, a silicone polymer alone, or a rosin-based resin. Respectively.

The high melting point ester wax is used for imparting curling and volume effect to the eyelashes, and preferably contains 5 to 20 wt% of the total composition, and has a melting point of 70 to 90 캜.

When the content of the high-melting point ester wax is less than 5 wt% based on the total weight of the composition, the curling effect is lowered. When the content is more than 20 wt%, the formulation stability is deteriorated.

Conventionally, low-melting wax having a melting point lower than 70 캜 such as vegetable natural wax or synthetic hydrocarbon wax has been mainly used according to the purpose, but it has a disadvantage in that the oil resistance is poor and under-eye bleeding is caused.

The high melting point ester wax is preferably at least one selected from the group consisting of carnauba wax, rice bran wax, and candelilla wax, but is not limited thereto.

The emulsifier is added to improve the formulation stability of the eye makeup composition, and preferably contains 0.5 to 10 wt% of the total composition, preferably a glycerin fatty acid ester.

The glycerin fatty acid ester system is preferably, but not limited to, polyethylene glycol-N glyceryl stearate or glyceryl isostearate.

The film forming agent is preferably a silicone-based polymer and a hydrogenated polycyclopentadiene resin in order to impart oil resistance, frictional resistance and cosmetic effect of the composition, and is preferably 5 to 50 wt%, more preferably 7 to 20 wt% % < / RTI > by weight of the composition. If the content of the film-forming agent is less than 7 wt%, the film-forming effect is insignificant and does not contribute to the improvement of sustainability. If the content of the film-forming agent is more than 50 wt%, the film-forming agent is poor in spreadability and stickiness and stiffness in the eyelashes after drying .

The silicone-based polymer is preferably, but not limited to, trimethylsiloxysilicate, polypropylsilsesquioxane, or a complex thereof.

The eye makeup composition may be formulated into a conventional eye makeup formulation. Preferably, it may be formulated into mascara or eyeliner, but is not limited thereto.

According to one embodiment of the present invention, the eye makeup composition of the present invention is excellent in oil resistance, water resistance, frictional resistance, and cosmetic effect, and has a merit that a beautifully shaped eyelash can be realized while minimizing under-eye bleeding caused by tears or sebum.

INDUSTRIAL APPLICABILITY The present invention is an oil-dispersible or water-in-oil type eye makeup composition, and has excellent water resistance, oil resistance, abrasion resistance and cosmetic effect.

Hereinafter, the present invention will be described in more detail with reference to Examples. However, the following examples are only for illustrating the present invention and the scope of the present invention is not limited by these examples.

Example  1 to 2: Production of mascara composition

Mascara compositions were prepared according to the compositions of Table 1 below. Components 1 to 16 were mixed with stirring while being heated to 90 DEG C, and then Components 17 and 18 were injected into the mixture of Components 1 to 16 and dispersed by stirring. After cooling to 25 캜, the mixture was filled in a mascara container.

ingredient Example 1 (wt%) Example 2 (wt%) 1. Isododecane Balance Balance 2. Trimethylsiloxylicillate / polypropyl silsesquioxane 13 8 3. Hydrogenated polycyclopentadiene 0 5 4. Pentaerythritol hydronezide rosinate 0 0 5. Beads wax 5 5 6. Carnauba Wax 10 10 7. Paraffin wax 4 4 8. Rice bran wax 4 4 9. Polyethylene wax One One 10. VP / Eicosene polymer 4 4 11. Polyethylene glycol-30 glyceryl stearate 2 2 12. Glyceryl isostearate 0.5 0.5 13. Propylene carbonate 3 3 14. Ethylene diamine / stearyl dimer dilinoleate copolymer 2 2 15. Distearatium hectorite 5 5 16. Phenoxyethanol 0.1 0.1 17. Iron oxide / triethoxycaprylylsilane 6 6 18. Silica 0.5 One

Example  3 to 4: Production of mascara composition

Mascara compositions were prepared according to the compositions of Table 2 below. Components 1 to 16 were mixed with stirring while being heated to 90 DEG C, and then Components 17 and 18 were injected into the mixture of Components 1 to 16 and dispersed by stirring. Component 19 heated to 70 占 폚 was then injected and emulsified and then cooled to 25 占 폚 and filled in a mascara container.

ingredient Example 3 (wt%) Example 4 (wt%) 1. Isododecane Balance Balance 2. Trimethylsiloxylicillate / polypropyl silsesquioxane 8 8 3. Hydrogenated polycyclopentadiene 5 5 4. Pentaerythritol hydronezide rosinate 0 0 5. Beads wax 3 5 6. Carnauba Wax One 10 7. Paraffin wax 6 4 8. Rice bran wax One 4 9. Polyethylene wax One One 10. VP / Eicosene polymer 4 4 11. Polyethylene glycol-30 glyceryl stearate 2 2 12. Glyceryl isostearate 0.5 0.5 13. Propylene carbonate 3 One 14. Ethylene diamine / stearyl dimer dilinoleate copolymer 2 2 15. Distearatium hectorite 5 3 16. Phenoxyethanol 0.1 0.1 17. Iron oxide / triethoxycaprylylsilane 6 6 18. Silica 0.5 0.5 19. Purified water 7 4

Comparative Example  1 to 2: Production of mascara composition

Mascara compositions were prepared according to the compositions in Table 3 below. Components 1 to 16 were mixed with stirring while being heated to 90 DEG C, and then Components 17 and 18 were injected into the mixture of Components 1 to 16 and dispersed by stirring. After cooling to 25 캜, the mixture was filled in a mascara container.

ingredient Comparative Example 1 (wt%) Comparative Example 2 (wt%) 1. Isododecane Balance Balance 2. Trimethylsiloxylicillate / polypropyl silsesquioxane 13 8 3. Hydrogenated polycyclopentadiene 0 5 4. Pentaerythritol hydronezide rosinate 0 0 5. Beads wax 3 5 6. Carnauba Wax One 10 7. Paraffin wax 6 4 8. Rice bran wax One 4 9. Polyethylene wax One One 10. VP / Eicosene polymer 4 4 11. Polyethylene glycol-30 glyceryl stearate 2 0 12. Glyceryl isostearate 0.5 0 13. Propylene carbonate 5 3 14. Ethylene diamine / stearyl dimer dilinoleate copolymer 2 2 15. Distearatium hectorite 8 8 16. Phenoxyethanol 0.1 0.1 17. Iron oxide / triethoxycaprylylsilane 6 6 18. Silica 0 One

Comparative Example  3 to 4: Production of mascara composition

Mascara compositions were prepared according to the compositions in Table 4 below. Components 1 to 16 were mixed with stirring while being heated to 90 DEG C, and then Components 17 and 18 were injected into the mixture of Components 1 to 16 and dispersed by stirring. Component 19 heated to 70 占 폚 was then injected and emulsified and then cooled to 25 占 폚 and filled in a mascara container.

ingredient Comparative Example 3 (wt%) Comparative Example 4 (wt%) 1. Isododecane Balance Balance 2. Trimethylsiloxylicillate / polypropyl silsesquioxane 8 13 3. Hydrogenated polycyclopentadiene 0 0 4. Pentaerythritol hydronezide rosinate 5 0 5. Beads wax 5 3 6. Carnauba Wax 10 One 7. Paraffin wax 4 One 8. Rice bran wax 4 One 9. Polyethylene wax One One 10. VP / Eicosene polymer 4 4 11. Polyethylene glycol-30 glyceryl stearate 2 0 12. Glyceryl isostearate 0.5 0 13. Propylene carbonate One 3 14. Ethylene diamine / stearyl dimer dilinoleate copolymer 2 2 15. Distearatium hectorite 3 8 16. Phenoxyethanol 0.1 0.1 17. Iron oxide / triethoxycaprylylsilane 6 6 18. Silica 0.5 0.5 19. Purified water 4 7

Experimental Example  One: Feeling  Test

The mascara produced in the above Examples and Comparative Examples was subjected to quality evaluation by 20 women aged 25 to 35 years. The comparison items were as follows: 1. The average score was calculated by giving 0 ~ 5 points to each item after the review. The data were repeated five times in order to ensure the accuracy of the data. The results are shown in Table 5 below.

Test Items Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Example 1 Example 2 Example 3 Example 4 Volume sense ◎ ○ ○ ○ ○ ◎ ◎ ◎ Curling feeling ○ ◎ ◎ ○ ◎ ◎ ○ ◎ Brittle × × △ × ○ ○ △ ○ No blurring × ○ ○ × × ○ ○ ○ No powder left △ ◎ ◎ △ △ ◎ ◎ ◎ Curing continuity △ ◎ △ △ △ ◎ ◎ ◎ Product evaluation score: × = 1 or less, △ = 1 to 2.5, ○ = 2.5 to 4, ◎ = 4 or more

As shown in Table 2, it was confirmed that Examples 2 and 4 according to the present invention are significantly superior to the mascara compositions of the Comparative Examples in volume, curling feel, spreadability, no bleeding, no flaking, and curing continuity.

Experimental Example  2: Water resistance, oil resistance and My Friction  evaluation

1) Water resistance

In order to compare the water resistance of the compositions of the above Examples and Comparative Examples, the following test methods were used and the results are shown in Table 6. A 200 ml beaker was filled with 100 ml of purified water, and an appropriate amount of the composition of the above Example or Comparative Example was applied to the artificial eyelashes uniformly, followed by thoroughly dried, shaken for 30 minutes, and then observed.

Test Items Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Example 1 Example 2 Example 3 Example 4 Water resistance ○ ○ ○ ○ ○ ○ ○ ○ * ○: More than two-thirds of the sample film attached to the eyelashes remains
* △: Sample film attached to eyelashes remains 1/3 to 2/3
* X: Less than 1/3 sample film attached to eyelashes

2) Oil resistance

The results are shown in Table 7 below. The results are shown in Table 7 below. [Table 7] < tb > < tb > < TABLE >

Test Items Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Example 1 Example 2 Example 3 Example 4 Oil resistance △ ○ ○ △ △ ○ ○ ○ * ○: More than two-thirds of the sample film attached to the eyelashes remains
* △: Sample film attached to eyelashes remains 1/3 to 2/3
* X: Less than 1/3 sample film attached to eyelashes

3) My Friction

The artificial lashes were uniformly coated with an appropriate amount of the composition of the present invention or the comparative example, and then dried thoroughly with a strong force of 100 times or more. Observation results are shown in Table 8 below.

Test Items Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Example 1 Example 2 Example 3 Example 4 My Friction △ ○ ○ △ △ ○ ○ ○ * ○: More than two-thirds of the sample film attached to the eyelashes remains
* △: Sample film attached to eyelashes remains 1/3 to 2/3
* X: Less than 1/3 sample film attached to eyelashes

As shown in Tables 7 and 8, the compositions of Examples 2 to 4 according to the present invention exhibited similar water resistance as compared with the compositions of the Comparative Examples, and excellent oil resistance and frictional resistance, respectively.

As shown in Tables 1 to 8, the present inventors have conducted experiments in which all of the film forming agents composed of the high melting point ester wax of 5 wt% or more according to the present invention, the glycerin fatty acid ester emulsifier, the silicone polymer and the hydrogenated polycyclopentadiene resin Examples 2 and 4 show excellent water resistance, oil resistance and frictional resistance as compared with the compositions of the other examples and comparative examples, and it can be confirmed that the overall usability is excellent.

Claims (8)

An eye makeup composition containing 5 to 20 wt% of a high melting point ester wax, 0.5 to 10 wt% of an emulsifier, and 5 to 50 wt% of a film former as an active ingredient, based on the total composition weight.
The eye makeup composition of claim 1, wherein the eye makeup composition is an oil-dispersible or oil-in-water type.
The eye makeup composition of claim 1, wherein the high melting point ester wax has a melting point in the range of 70 ° C to 90 ° C.
The eye makeup composition of claim 1, wherein the high melting point ester wax is at least one selected from the group consisting of carnauba wax, rice bran wax, and candelilla wax.
The eye makeup composition of claim 1, wherein the emulsifier is a glycerin fatty acid ester.
6. The eye makeup composition according to claim 5, wherein the glycerin fatty acid ester is polyethylene glycol-Nglyceryl stearate or glyceryl isostearate.
The eye makeup composition of claim 1, wherein the film former is a silicone-based polymer and a hydrogenated polycyclopentadiene resin.
The eye makeup composition of claim 7, wherein the silicone polymer is trimethylsiloxysilicate, polypropylsilsesquioxan or a mixture thereof.