KR20130011739A - The interlayer inserting mothod for enhancing the bonding power at that time of combining al alloy with fe - Google Patents

The interlayer inserting mothod for enhancing the bonding power at that time of combining al alloy with fe Download PDF

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KR20130011739A
KR20130011739A KR1020110073107A KR20110073107A KR20130011739A KR 20130011739 A KR20130011739 A KR 20130011739A KR 1020110073107 A KR1020110073107 A KR 1020110073107A KR 20110073107 A KR20110073107 A KR 20110073107A KR 20130011739 A KR20130011739 A KR 20130011739A
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cast iron
aluminum alloy
mold
aluminum
bonding
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KR1020110073107A
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Korean (ko)
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KR101256126B1 (en
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김동규
손광석
한광식
강용주
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동아대학교 산학협력단
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K20/00—Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating
    • B23K20/16—Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating with interposition of special material to facilitate connection of the parts, e.g. material for absorbing or producing gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D19/00—Casting in, on, or around objects which form part of the product
    • B22D19/16—Casting in, on, or around objects which form part of the product for making compound objects cast of two or more different metals, e.g. for making rolls for rolling mills
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K20/00—Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating
    • B23K20/22—Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating taking account of the properties of the materials to be welded
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K20/00—Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating
    • B23K20/26—Auxiliary equipment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K2103/00—Materials to be soldered, welded or cut
    • B23K2103/18—Dissimilar materials
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/50—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for welded joints

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Pressure Welding/Diffusion-Bonding (AREA)

Abstract

PURPOSE: An interlayer inserting method is provided to generate an aluminum alloy-cast iron reaction layer which has a weaker brittleness than aluminum alloy-cast iron reaction layer and to easily control the thickness of the reaction layer. CONSTITUTION: An interlayer inserting method comprises: a step of polishing the exterior of cast iron(S100); a step of immersing the polished cast iron into a pure aluminum melt solution which is melted at 720-850 °C(S200); a step of inserting the immersed cast iron into a preheated mold(S300); a step of injecting aluminum alloy which is melted at 720-850 °C into the mold(S400); and a step of heat-treating the mold in a heat-treatment furnace for 1-2 hours and cools the same(S500). [Reference numerals] (AA) Start; (BB) End; (S100) Polishing the exterior of cast iron; (S200) Immersing the polished cast iron into a pure aluminum melt solution; (S300) Inserting the immersed cast iron in a preheated mold; (S400) Injecting molten aluminum alloy into the mold in which the cast iron is inserted; (S500) Heat-treating the mold, in which the aluminum alloy is injected, in a heat-treatment furnace and cooling

Description

알루미늄 합금과 주철소재의 이종접합 시 접합력 향상을 위한 중간층 삽입방법{The interlayer inserting mothod for enhancing the bonding power at that time of combining Al alloy with Fe}The interlayer inserting mothod for enhancing the bonding power at that time of combining Al alloy with Fe}

본 발명은 알루미늄 합금과 주철소재의 이종접합 시 접합력 향상을 위한 중간층 삽입방법에 관한 것으로서, 더욱 상세하게는 알루미늄 합금과 주철을 고온에서 용융접합 시 주철 계면에 형성되는 산화막으로 인하여 접합성이 감소하는 것을 방지하기 위하여 주철을 용융된 순수 알루미늄에 침지하여 알루미늄-철 반응층을 먼저 생성하고, 알루미늄 합금 용융액을 금형에 주입함으로써 접합력을 향상시킬 수 있는 알루미늄 합금과 주철소재의 이종접합 시 접합력 향상을 위한 중간층 삽입방법에 관한 것이다.
The present invention relates to a method for inserting an intermediate layer for improving the bonding strength during heterojunction between an aluminum alloy and a cast iron material, and more particularly, to reduce the bonding property due to an oxide film formed at the cast iron interface when the aluminum alloy and cast iron are melt-bonded at high temperature. In order to prevent this, the cast iron is immersed in the molten pure aluminum to produce an aluminum-iron reaction layer first, and the intermediate layer for improving the bonding strength in the heterojunction of the aluminum alloy and the cast iron material, which can improve the bonding strength by injecting the aluminum alloy melt into the mold. It relates to the insertion method.

알루미늄, 알루미늄 합금 등의 알루미늄계 재료는 경량이고 내식성이 우수한 것을 활용하여 여러 분야에서 사용되고 있으며, 강도가 요구되는 용도에서는 후육화(厚肉化)에 의해 요구강도를 만족시키고 있다. 그러나, 이러한 후육화는 알루미늄 재료의 장점인 경량성을 손상시키지 않는 컴팩트한 설계에 대응하는 구조부재로서 적당하지 않은 문제점이 있었다.Aluminum-based materials such as aluminum and aluminum alloys are used in various fields by utilizing light weight and excellent corrosion resistance, and in applications requiring strength, they satisfy the required strength by thickening. However, such thickening has been problematic in that it is not suitable as a structural member corresponding to a compact design that does not impair the lightness, which is an advantage of aluminum materials.

기계강도가 양호한 철계 재료를 알루미늄계 재료와 접합할 수 있는 경우, 알루미늄계 재료는 후육화하지 않아도 필요강도가 얻을 수 있으며, 이를 위해 알루미늄 재료와 철계 재료와의 접합에 볼트 너트, 리벳, 끼워맞춤 등의 기계적 결합법이 채용되어 왔다. 그러나, 이러한 기계적 결합법에서는 우수한 이음이 얻어지기 어렵고, 생산성도 낮은 문제점이 있었다. When iron-based materials having good mechanical strength can be joined with aluminum-based materials, the aluminum-based materials can be obtained without the need for thickening. For this purpose, bolt nuts, rivets, and fittings are used to join aluminum and iron-based materials. Mechanical coupling methods, such as these, have been adopted. However, such a mechanical coupling method is difficult to obtain excellent joints, there is a problem in low productivity.

알루미늄계 재료와 철계 재료 간에 용융접합이 가능하게 되면, 기계적 결합법에 비해 생산성이 매우 높고, 양호한 특성을 갖을 수 있다. When the melt bonding between the aluminum-based material and the iron-based material is possible, the productivity is very high compared to the mechanical bonding method, and may have good characteristics.

종래, 알루미늄계 재료와 철계 재료(이종금속 재료) 간의 접합 방법에 관한 많은 연구가 이루어져 왔다. In the past, many studies have been made on a joining method between an aluminum-based material and an iron-based material (dissimilar metal material).

그 일례로서, 알루미늄 합금과 주철소재의 이종접합 시 주철소재의 재료를 접합하고자 하는 알루미늄 합금과 동일한 알루미늄 합금 용융액에 침지한 후 알루미늄 합금을 주입하는 기술이 제시된 바 있다. 도 1은 이러한 종래기술에 따른 알루미늄 합금((a)Al-7%Si, (b)Al-12%Si, (c)Al-17%Si)과 주철소재의 이종접합 방법에 의해서 생성된 접합물의 접합상태를 나타낸 도면이다. 도 1에 도시된 바와 같이, 이러한 기술의 경우 접합하고자 하는 알루미늄 합금(200)의 조성에 따라 취성(Brittle) 금속간 화합물인 알루미늄 합금-주철 중간층(110)이 형성되는 정도가 상이하였으며, 균일한 접합성을 갖는 접합물의 생산이 용이하지 않아 신뢰할 만한 접합물을 얻기가 어려운 문제점이 있었다.As an example, a technique of injecting an aluminum alloy after immersing the material of the cast iron material in the same aluminum alloy melt as the aluminum alloy to be joined during heterojunction between the aluminum alloy and the cast iron material has been proposed. 1 is a joint produced by the heterojunction method of the aluminum alloy ((a) Al-7% Si, (b) Al-12% Si, (c) Al-17% Si) and the cast iron material according to the prior art It is a figure which shows the bonding state of water. As shown in FIG. 1, according to the composition of the aluminum alloy 200 to be joined, the degree of formation of the aluminum alloy-cast iron intermediate layer 110, which is a brittle intermetallic compound, was different and uniform. There is a problem that it is difficult to obtain a reliable joint because the production of the joint having the bonding is not easy.

이러한 연구에서는 취성 금속간 화합물의 생성을 억제하기 위해 알루미늄계 재료와 철계 재료가 용융 및 혼합되는 것을 최대한 방지하며, 접합부에 취성 금속간 화합물이 생성되어도 접합물의 기계적 성능을 훼손하지 않도록 제어하는 것이 중요하게 되는데 종래 연구된 접합 방법들로는 범용성이 불량하거나 공정상의 복잡함으로 인해 품질의 안정성이 확보할 수 없고, 접합에 소요되는 비용이 증가하여 실용성이 결여되는 문제점이 여전히 해소되지 못했다.
In these studies, it is important to prevent the melting and mixing of aluminum-based materials and iron-based materials as much as possible to suppress the formation of brittle intermetallic compounds, and to control the formation of brittle intermetallic compounds at the joints so as not to compromise the mechanical performance of the joints. In the conventionally studied joining methods, the stability of the quality cannot be secured due to poor versatility or complexity of the process, and the cost of joining increases, and the problem of lack of practicality is still not solved.

상기와 같은 종래 기술의 문제점을 해결하기 위하여 안출된 본 발명은 알루미늄 합금과 주철의 용융 접합에서 알루미늄 합금-주철 반응층에 비해 상대적으로 취성이 약한 알루미늄-주철 반응층을 생성하게 하고, 이러한 반응층의 두께제어를 용이하게 하기 위한 목적이 있다.The present invention devised to solve the problems of the prior art as described above allows to produce an aluminum-cast iron reaction layer having a relatively weak brittleness compared to the aluminum alloy-cast iron reaction layer in the fusion bonding of aluminum alloy and cast iron, such a reaction layer The purpose is to facilitate the thickness control.

또한, 저융점 금속인 알루미늄 합금의 경우 용융상태로 유지되는 시간이 매우 짧은데 이를 순수 알루미늄 용융액에 침지함으로써 반응시간을 확보하기 위한 다른 목적이 있다.In addition, the aluminum alloy, which is a low melting point metal, has a very short time to be kept in a molten state, and has another purpose for securing a reaction time by immersing it in a pure aluminum melt.

또한, 이러한 반응층의 두께제어 및 반응시간 확보로 인해 접합력을 향상된 견고한 접합물을 제공함으로써 그 활용도를 넓히기 위한 또 다른 목적이 있다.
In addition, there is another object to broaden the utilization by providing a solid bond with improved bonding strength due to the control of the thickness of the reaction layer and securing the reaction time.

본 발명의 상기 목적은 알루미늄 합금과 주철의 용융 접합방법에 있어서, 상기 주철의 외면을 연마하는 제1단계, 연마된 주철을 720 내지 850℃에서 용융된 순수 알루미늄 용융액에 침지하는 제2단계, 침지된 주철을 예열된 금형에 삽입하는 제3단계, 상기 주철이 삽입된 금형에 720 내지 850℃에서 용융된 상기 알루미늄 합금을 주입하는 제4단계 및 상기 알루미늄 합금이 주입된 금형을 예열된 열처리로에서 1 내지 2시간 열처리하고, 이를 냉각하는 제5단계를 포함하는 알루미늄 합금과 주철소재의 이종접합 시 접합력 향상을 위한 중간층 삽입방법에 의해 달성된다.The object of the present invention is a melt bonding method of an aluminum alloy and cast iron, the first step of polishing the outer surface of the cast iron, the second step of immersing the polished cast iron in the molten pure aluminum melt at 720 to 850 ℃, immersion Inserting the cast iron into a preheated mold, a fourth step of injecting the molten aluminum alloy at 720 to 850 ° C. into the mold into which the cast iron is inserted, and a mold into which the aluminum alloy is injected is preheated. Heat treatment for 1 to 2 hours, and is achieved by the interlayer insertion method for improving the bonding strength during heterojunction of the aluminum alloy and cast iron material comprising a fifth step of cooling it.

바람직하게는, 상기 알루미늄 합금은 알루미늄에 실리콘이 7, 12 또는 17중량% 중 어느 하나로 함유된 알루미늄-실리콘 합금인 것을 특징으로 한다.Preferably, the aluminum alloy is an aluminum-silicon alloy containing silicon in any one of 7, 12 or 17% by weight of aluminum.

또한 바람직하게는, 상기 제2단계에서 상기 침지는 2 내지 7분간 이루어지는 것을 특징으로 한다.Also preferably, in the second step, the immersion is performed for 2 to 7 minutes.

또한 바람직하게는, 상기 제3단계에서 상기 금형은 350 내지 450℃로 예열된 것을 특징으로 한다.Also preferably, in the third step, the mold may be preheated to 350 to 450 ° C.

또한 바람직하게는, 상기 제5단계에서 상기 열처리로는 410 내지 470℃로 예열된 것을 특징으로 한다.
Also preferably, in the fifth step, the heat treatment furnace is preheated to 410 to 470 ° C.

상기와 같은 종래 기술의 문제점을 해결하기 위하여 안출된 본 발명은 알루미늄 합금과 주철의 용융 접합에서 알루미늄 합금-주철 반응층에 비해 상대적으로 취성이 약한 알루미늄-주철 반응층을 생성하게 하고, 이러한 반응층의 두께제어를 용이하게 할 수 있는 효과가 있다.The present invention devised to solve the problems of the prior art as described above allows to produce an aluminum-cast iron reaction layer having a relatively weak brittleness compared to the aluminum alloy-cast iron reaction layer in the fusion bonding of aluminum alloy and cast iron, such a reaction layer There is an effect that can facilitate the thickness control of.

또한, 저융점 금속인 알루미늄 합금의 경우 용융상태로 유지되는 시간이 매우 짧은데 이를 순수 알루미늄 용융액에 침지함으로써 반응시간을 확보할 수 있는 다른 효과가 있다.In addition, the aluminum alloy, which is a low melting point metal, has a very short time to be maintained in a molten state, and there is another effect of securing a reaction time by immersing it in a pure aluminum melt.

또한, 이러한 반응층의 두께제어 및 반응시간 확보로 인해 접합력을 향상된 견고한 접합물을 제공함으로써 그 활용도를 넓힐 수 있는 또 다른 효과가 있다.
In addition, the thickness control of the reaction layer and securing the reaction time has another effect of broadening its utilization by providing a solid bond with improved bonding strength.

도 1은 종래기술에 따른 알루미늄 합금((a)Al-7%Si, (b)Al-12%Si, (c)Al-17%Si)과 주철소재의 이종접합 방법에 의해서 생성된 접합물의 접합상태를 나타낸 도면,
도 2는 본 발명에 따른 알루미늄 합금과 주철소재의 이종접합 시 접합력 향상을 위한 중간층 삽입방법을 나타낸 흐름도,
도 3은 본 발명에 따른 알루미늄 합금((a)Al-7%Si, (b)Al-12%Si, (c)Al-17%Si)과 주철소재의 이종접합 방법에 의해서 생성된 접합물의 접합상태를 나타낸 도면,
도 4는 종래기술과 본 발명에 따라 생성된 접합물의 접합력을 비교한 도면이다.1 is a joint produced by the heterojunction method of the aluminum alloy ((a) Al-7% Si, (b) Al-12% Si, (c) Al-17% Si) and the cast iron material according to the prior art Drawing showing the connection state,
Figure 2 is a flow chart showing an intermediate layer insertion method for improving the bonding strength when heterojunction of aluminum alloy and cast iron material according to the present invention,
Figure 3 is a joint produced by the heterojunction method of the aluminum alloy ((a) Al-7% Si, (b) Al-12% Si, (c) Al-17% Si) and the cast iron material according to the present invention Drawing showing the connection state,
Figure 4 is a view comparing the bonding force of the joint produced according to the prior art and the present invention.

본 명세서 및 청구범위에 사용된 용어나 단어는 통상적이거나 사전적인 의미로 한정해서 해석되어서는 아니되며, 발명자는 그 자신의 발명을 가장 최선의 방법으로 설명하기 위해 용어의 개념을 적절하게 정의할 수 있다는 원칙에 입각하여 본 발명의 기술적 사상에 부합하는 의미와 개념으로 해석되어야만 한다.The terms and words used in the present specification and claims should not be construed as limited to ordinary or dictionary terms and the inventor may appropriately define the concept of the term in order to best describe its invention It should be construed as meaning and concept consistent with the technical idea of the present invention.

따라서, 본 명세서에 기재된 실시예와 도면에 도시된 구성은 본 발명의 가장 바람직한 일 실시예에 불과할 뿐이고 본 발명의 기술적 사상을 모두 대변하는 것은 아니므로, 본 출원시점에 있어서 이들을 대체할 수 있는 다양한 균등물과 변형예들이 있을 수 있음을 이해하여야 한다.Therefore, the embodiments described in this specification and the configurations shown in the drawings are merely the most preferred embodiments of the present invention and do not represent all the technical ideas of the present invention. Therefore, It is to be understood that equivalents and modifications are possible.

이하 첨부된 본 발명의 바람직한 실시예를 상세히 설명한다.Hereinafter, preferred embodiments of the present invention will be described in detail.

도 2는 본 발명에 따른 알루미늄 합금과 주철소재의 이종접합 시 접합력 향상을 위한 중간층 삽입방법을 나타낸 흐름도이다. 도 2에 도시된 바와 같이, 본 발명은 주철(100)의 외면을 연마하는 단계(S100)에 의해 개시된다. 대기 중에 노출된 주철(100)은 그 표면에 산화막 또는 다양한 이물질이 존재하게 되며, 열간침지를 실시하기 전 경면연마를 실시함으로써 이를 모두 제거해야 표면을 균일하게 코팅할 수 있게 된다.Figure 2 is a flow chart showing an intermediate layer insertion method for improving the bonding strength when heterojunction of aluminum alloy and cast iron material according to the present invention. As shown in Figure 2, the present invention is initiated by the step (S100) of polishing the outer surface of the cast iron (100). The cast iron 100 exposed to the atmosphere has an oxide film or various foreign substances on the surface thereof, and the surface is uniformly coated by removing all of them by performing mirror polishing before performing the hot immersion.

연마된 주철(100)은 720 내지 850℃에서 용융된 순수 알루미늄 용융액에 침지(S200)를 실시한다. 열간침지 또는 이종금속을 용융접합함에 있어 온도와 공정시간은 지대한 영향을 미치는데 이 둘은 서로 상관관계가 있으므로 적절하게 제어하는 것이 매우 중요하다. Polished cast iron 100 is immersed (S200) in the pure aluminum molten liquid melted at 720 to 850 ℃. In hot immersion or melt-bonding dissimilar metals, temperature and process time have a profound effect. Both of these are correlated, so proper control is very important.

더욱 상세하게, 공정시간은 온도가 높을수록 감소하게 되는데 공정시간을 단축하기 위해 용융온도를 높이게 되면 용탕 내에 가스 취입량이 증가함에 따라 접합물이 응고된 후 미세기공의 형성으로 기계적 성질이 감소하게 된다. 반면, 용융온도가 낮을 경우에는 침지를 실시한 주철(100)을 금형에 삽입한 후 알루미늄 합금(200) 용융액을 주입하는 사이, 주철(100) 표면에 형성된 알루미늄 코팅층이 응고하여 접합성을 저해하게 된다.More specifically, the process time decreases as the temperature increases, but when the melting temperature is increased to shorten the process time, the mechanical properties decrease due to the formation of micropores after the joint solidifies as the gas blowing amount in the melt increases. . On the other hand, when the melting temperature is low, the aluminum coating layer formed on the surface of the cast iron 100 solidifies while inserting the cast iron 100 having been immersed into the mold and then injecting the aluminum alloy 200 melt, thereby inhibiting the bonding property.

한편, 침지시간이 짧을 경우에는 주철(100)이 반응온도까지 승온된 후 순수 알루미늄 원자와 반응하기 위한 시간이 충분하지 않음으로써 균일한 중간층이 형성되기 어려우며, 침지시간이 길 경우에는 알루미늄-주철 중간층(120)의 두께가 매우 두꺼워짐에 따라 접합력이 감소하게 되고, 알루미늄-주철 중간층(120) 형성에 의하여 주철(100)이 침식됨으로써 주철(100) 자체의 손실량이 증가하는 등의 문제점이 야기된다. On the other hand, when the immersion time is short, since the cast iron 100 is raised to the reaction temperature, the time for reacting with pure aluminum atoms is not sufficient, so that a uniform intermediate layer is difficult to form, and when the immersion time is long, the aluminum-cast iron intermediate layer As the thickness of the 120 is very thick, the bonding force decreases, and the cast iron 100 is eroded by the aluminum-cast iron intermediate layer 120, thereby causing a problem such as an increase in the loss of the cast iron 100 itself. .

이에 따라, 본 발명에서는 온도를 720 내지 850℃로, 시간을 2 내지 7분간으로 한정하는 것이 바람직하다.Accordingly, in the present invention, it is preferable to limit the temperature to 720 to 850 ° C and the time to 2 to 7 minutes.

침지된 주철(100)은 용탕에서 꺼내어져 예열된 금형에 삽입되게 된다(S300). The immersed cast iron 100 is taken out of the molten metal and inserted into the preheated mold (S300).

이때, 금형을 예열하는 것은 침지된 주철(100) 표면에 형성되어 있는 코팅층이 급속하게 응고하는 것을 억제하기 위함이며, 예열온도는 350 내지 450℃인 것이 바람직하다.At this time, the preheating of the mold is for suppressing rapid solidification of the coating layer formed on the immersed cast iron 100 surface, the preheating temperature is preferably 350 to 450 ℃.

주철(100)이 금형에 삽입되면, 720 내지 850℃에서 용융된 알루미늄 합금(200)을 주철(100)이 삽입된 금형에 주입하고(S400), 정압(압력)을 가하여 주철(100)과의 접합물을 생성하게 된다.When the cast iron 100 is inserted into the mold, the aluminum alloy 200 melted at 720 to 850 ° C. is injected into the mold into which the cast iron 100 is inserted (S400), and a positive pressure (pressure) is applied to the cast iron 100. Will create a joint.

이때, 열간침지 시 주철(100) 표면에 형성된 순수 알루미늄의 코팅층이 제거되고 알루미늄-주철 중간층(120)과 용융된 알루미늄 합금(200)이 직접적으로 맞닿아 두 소재의 접합이 이루어지게 되는 것이다.At this time, during hot immersion, the coating layer of pure aluminum formed on the surface of the cast iron 100 is removed, and the aluminum-cast iron intermediate layer 120 and the molten aluminum alloy 200 directly contact each other to thereby bond the two materials.

여기에서, 용융된 알루미늄 합금(200)의 온도가 너무 낮으면 주입이 용이하지 않아 정형주조에 적합하지 않기 때문에 열간침지한 주철(100) 표면에 형성된 코팅층을 효과적으로 제거하기 위하여 720 내지 850℃로 유지되는 것이 바람직하다.In this case, when the temperature of the molten aluminum alloy 200 is too low, it is not easy to inject and is not suitable for orthopedic casting, so it is maintained at 720 to 850 ° C. to effectively remove the coating layer formed on the surface of the hot immersion cast iron 100. It is desirable to be.

알루미늄 합금(200)이 금형에 주입되면, 예열된 열처리로에서 1 내지 2시간 열처리를 수행하며, 이를 냉각시키게 된다(S500). 이러한 공정은 접합물의 응고 시 발생하는 수축응력의 완화를 위함이며, 열처리로는 410 내지 470℃로 예열된 것이 바람직하다. When the aluminum alloy 200 is injected into the mold, the heat treatment is performed in a preheated heat treatment furnace for 1 to 2 hours, and cooled (S500). This process is to alleviate the shrinkage stress generated during solidification of the joint, the heat treatment is preferably preheated to 410 ~ 470 ℃.

도 3은 본 발명에 따른 알루미늄 합금((a)Al-7%Si, (b)Al-12%Si, (c)Al-17%Si)과 주철소재의 이종접합 방법에 의해서 생성된 접합물의 접합상태를 나타낸 도면이다. 도 3에 도시된 바와 같이, 각각의 알루미늄 합금(200)((a)Al-7%Si, (b)Al-12%Si, (c)Al-17%Si)과 주철(100) 접합물의 중간층은 실리콘이 동일한 중량% 함유된 도 1의 것과 비교하여 그 범위가 넓고, 균일하게 형성된다. 이러한 것은 초음파탐상법(Ultrasonic Test, UT)으로 접합면을 측정한 결과, 종래기술은 약 90~95%, 본 발명은 98%이상을 나타낸 것으로 증명된다.Figure 3 is a joint produced by the heterojunction method of the aluminum alloy ((a) Al-7% Si, (b) Al-12% Si, (c) Al-17% Si) and the cast iron material according to the present invention It is a figure which shows the bonding state. As shown in FIG. 3, each aluminum alloy 200 ((a) Al-7% Si, (b) Al-12% Si, (c) Al-17% Si) and the cast iron 100 joint The intermediate layer has a wider range and is formed uniformly compared to that of Fig. 1 containing the same weight percent of silicon. This is the result of measuring the bonding surface by the Ultrasonic Test (Ultrasonic Test, UT), it is proved that the conventional technology is about 90-95%, the present invention is 98% or more.

특히, 실리콘이 17중량% 함유된 알루미늄 합금(200)과 주철(100) 접합물(c)의 중간층은 동일한 공정을 수행한 다른 실리콘 조성의 것((a), (b))과 비교할 때 비교적 안정적인 분포를 보인다. In particular, the intermediate layer of the aluminum alloy 200 and the cast iron 100 joint (c) containing 17% by weight of silicon is relatively compared with those of other silicon compositions ((a), (b)) which have performed the same process. Stable distribution

따라서, 본 발명에 따라 알루미늄 합금(200)과 주철(100)로 이루어진 접합물을 형성하고자 할 때, 알루미늄 합금(200)은 실리콘이 17중량% 함유된 것으로 구성되는 것이 바람직하다.Therefore, when the aluminum alloy 200 and the cast iron 100 is to be formed in accordance with the present invention, it is preferable that the aluminum alloy 200 is composed of 17 wt% silicon.

도 4는 종래기술과 본 발명에 따라 생성된 접합물의 접합력을 비교한 도면이다. 이는 실리콘이 동일한 중량% 함유된 알루미늄 합금(200)과 주철(100)을 각각 종래기술과 본 발명의 공정으로 접합하여 접합력을 측정한 것이며, Chalmers Test에 의해 수행되었다. 도 4에 도시된 바와 같이, 종래기술에 의한 것은 6~10MPa, 본 발명은 8~19MPa인 것으로 측정되었으며, 본 발명의 공정에 의한 것에서 접합력이 크게 향상되었다.Figure 4 is a view comparing the bonding force of the joint produced according to the prior art and the present invention. This was measured by bonding the aluminum alloy 200 and the cast iron 100 containing the same weight percent silicon by the prior art and the process of the present invention, respectively, and was performed by the Chalmers Test. As shown in Figure 4, the conventional technology was measured to be 6 ~ 10MPa, the present invention is 8 ~ 19MPa, the bonding force is greatly improved by the process of the present invention.

본 발명은 이상에서 살펴본 바와 같이 바람직한 실시예를 들어 도시하고 설명하였으나, 상기한 실시예에 한정되지 아니하며 본 발명의 정신을 벗어나지 않는 범위 내에서 당해 발명이 속하는 기술분야에서 통상의 지식을 가진 자에 의해 다양한 변경과 수정이 가능할 것이다.
While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it is clearly understood that the same is by way of illustration and example only and is not to be taken by way of limitation, Various changes and modifications will be possible.

100 : 주철
110 : 알루미늄 합금-주철 중간층
120 : 알루미늄-주철 중간층
200 : 알루미늄 합금100: cast iron
110: aluminum alloy-cast iron intermediate layer
120: aluminum-cast iron intermediate layer
200: aluminum alloy

Claims (5)

알루미늄 합금과 주철의 용융 접합방법에 있어서,
상기 주철의 외면을 연마하는 제1단계;
연마된 주철을 720 내지 850℃에서 용융된 순수 알루미늄 용융액에 침지하는 제2단계;
침지된 주철을 예열된 금형에 삽입하는 제3단계;
상기 주철이 삽입된 금형에 720 내지 850℃에서 용융된 상기 알루미늄 합금을 주입하는 제4단계; 및
상기 알루미늄 합금이 주입된 금형을 예열된 열처리로에서 1 내지 2시간 열처리하고, 이를 냉각하는 제5단계
를 포함하는 알루미늄 합금과 주철소재의 이종접합 시 접합력 향상을 위한 중간층 삽입방법.
In the melt bonding method of aluminum alloy and cast iron,
A first step of polishing the outer surface of the cast iron;
A second step of immersing the polished cast iron in a pure aluminum melt melted at 720 to 850 ° C .;
Inserting the immersed cast iron into the preheated mold;
Injecting the molten aluminum alloy at 720 to 850 ° C. into the mold into which the cast iron is inserted; And
A fifth step of heat-treating the mold in which the aluminum alloy is injected in a preheated heat treatment furnace for 1 to 2 hours, cooling it
Interlayer insertion method for improving the bonding strength during heterojunction of aluminum alloy and cast iron material comprising a.
제 1 항에 있어서,
상기 알루미늄 합금은 알루미늄에 실리콘이 7, 12 또는 17중량% 중 어느 하나로 함유된 알루미늄-실리콘 합금인 것을 특징으로 하는 알루미늄 합금과 주철소재의 이종접합 시 접합력 향상을 위한 중간층 삽입방법.
The method of claim 1,
Wherein the aluminum alloy is an aluminum-silicon alloy containing silicon in any one of 7, 12 or 17% by weight of aluminum, the intermediate layer insertion method for improving the bonding strength in the heterojunction of the aluminum alloy and cast iron material.
제 1 항에 있어서,
상기 제2단계에서
상기 침지는 2 내지 7분간 이루어지는 것을 특징으로 하는 알루미늄 합금과 주철소재의 이종접합 시 접합력 향상을 위한 중간층 삽입방법.
The method of claim 1,
In the second step
Wherein the immersion is an intermediate layer insertion method for improving the bonding strength during heterojunction of aluminum alloy and cast iron material, characterized in that for 2 to 7 minutes.
제 1 항에 있어서,
상기 제3단계에서
상기 금형은 350 내지 450℃로 예열된 것을 특징으로 하는 알루미늄 합금과 주철소재의 이종접합 시 접합력 향상을 위한 중간층 삽입방법.
The method of claim 1,
In the third step
Wherein the mold is preheated to 350 to 450 ℃ the intermediate layer insertion method for improving the bonding strength during heterojunction of the aluminum alloy and cast iron material.
제 1 항에 있어서,
상기 제5단계에서
상기 열처리로는 410 내지 470℃로 예열된 것을 특징으로 하는 알루미늄 합금과 주철소재의 이종접합 시 접합력 향상을 위한 중간층 삽입방법.

The method of claim 1,
In the fifth step
The heat treatment furnace is an intermediate layer insertion method for improving the bonding strength when the heterogeneous bonding of aluminum alloy and cast iron material, characterized in that preheated to 410 ~ 470 ℃.

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CN107723650A (en) * 2017-10-25 2018-02-23 安徽恒利增材制造科技有限公司 A kind of bimetallic casting method of engine cylinder-body ferro-aluminum
KR20210028867A (en) * 2019-09-05 2021-03-15 주식회사 히즈시스템 Method for manufacturing mold using 3d printer
WO2022124644A1 (en) * 2020-12-11 2022-06-16 한국생산기술연구원 Cast iron-aluminum binding material having good interfacial bonding strength and heat transfer characteristic and method for manufacturing same

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