KR20120137058A - Airfreshener composition - Google Patents

Abstract

PURPOSE: An aroma composition is provided to facilitate handling and installation thereof and to be conveniently used regardless of a place. CONSTITUTION: An aroma composition comprises 0.01-10 wt% of polymer, 0.1-15 wt% of surfactant, 0.3-10 wt% of solubilizing agent, 3-25 wt% of evaporation promoter, and 3-25 wt% of perfume. The polymer is selected from a group consisting of acryl, amide, vinyl alcohol polymer, and the copolymer thereof. The surfactant is selected from a group consisting of sodium fatty acid, monoalkyl sulphate, alkyl poly oxyethylene sulphate, alkyl benzene sulfate, monoalkyl trimethyl ammonium salt, dialkyl dimethyl ammonium salt, and the mixture thereof.

Description

Air freshener composition

The present invention relates to a fragrance composition for a sheet-type fragrance and a sheet-type fragrance comprising the same.

In general, fragrances used for the purpose of attenuating or eliminating odors or odors are commonly used in general households, and the amount of their use is gradually increasing, and their types are also diversified such as liquids, gels, membranes, and electric types. It is a trend. Recently, with the improvement of living standards, the concept of air purification is changing, and various functional products such as fragrance diet products with aromatherapy effect and aromatherapy effect are being developed. And a fragrance for the purpose of improving the atmosphere with deodorization.

The fragrance is mainly developed liquid products or gel-type products, but these are disadvantages that are limited to the installation space and method due to the container of the product itself containing the fragrance. In particular, in the case of liquid type, there is a disadvantage in that the contents may spill or leak in case of falling as well as in the case of falling, and in the case of the gel type, there are many residues of volatilized residue after volatilization with the limitation of installation space. In order to fix it, there are disadvantages such as being able to leave a scratch on the space by the tape used on the bottom. In addition, the fragrances generally used are contained in a heavy container such as hard plastic or glass, which is inconvenient to handle, and in particular, there is a risk of being injured in case of damage to the container, which is difficult to handle.

To solve these shortcomings, non-woven type air fresheners have been developed and are commercially available.In the case of non-woven type, oil components such as incense are used.In order to keep the fragrance slowly volatilizing for a certain period of time, various mixed contents should be used. The less dry and moist state when used in the hand or cloth or other objects can be rather disadvantageous to increase the discomfort. In addition, some commercially available non-woven fabrics are manufactured by processing at high temperature and curing at room temperature.If they are incompletely dried during curing, they remain sticky and smeared even after being left for a long time. However, there is a problem that there is no softness and stiffness in the nonwoven fabric and the powdery powder falls on clothes or hands when dried.

As such, the fragrance may vary depending on the formulation and purpose of the fragrance composition. However, the fragrance may be limited due to problems such as leakage, spillage, limitation of installation space, inconvenience in use, and tendency to reject by hand foreign substances. It is expressed.

Accordingly, the problem to be solved by the present inventors is not spilling, leakage, and space constraints, and as a sheet-type fragrance that is easy to handle and store, it is also free from smearing, and has excellent phase stability, volatilization, and deodorizing and deodorizing effects. The drying time is short, the disadvantages and limitations of the sheet-type perfume is complemented and the main effect is to provide an improved perfume composition for sheet-type perfume and a sheet-type perfume applied to the perfume composition.

In order to solve the above problems, in the present invention, in the perfume composition for a sheet-type perfume, 0.01 to 10 parts by weight of polymer, 0.1 to 15 parts by weight of surfactant, emulsifying agent 0.3 in 100 parts by weight of the total composition. To provide a fragrance composition and a method for producing the same, including 10 to 10 parts by weight, 3 to 25 parts by weight of solubilization-volatile promoter, and 3 to 25 parts by weight of perfume.

More preferably, in the present invention, in the perfume composition for a sheet-type perfume, 1 to 5 parts by weight of the polymer, 1 to 10 parts by weight of the surfactant, and an emulsifying and solubilizing agent 3 To provide a fragrance composition and a method for producing the same, including 8 to 8 parts by weight, 3 to 7 parts by weight of solubilization-volatile accelerator, and 3 to 10 parts by weight of perfume.

The present inventors have prepared a fragrance composition having a composition and content that complements and improves the disadvantages of the fragrance composition for sheet-type fragrances, and exhibits excellent phase stability, dryness, volatilization, and deodorization and deodorization.

Phase stability is evaluated as an important factor with regard to storage and ease of use of the fragrance composition. In addition, the sheet-type fragrance should be soft and not sticky and sticky when used in a dried state. The dry feeling has a great influence on the quality of the product and the customer's product satisfaction. Include the rate of drying, burying and sticking on drying, and softness after drying. In addition, volatilization and deodorization and deodorizing power is one of the important evaluation factors in the fragrance composition, and fragrance and deodorization and deodorizing power include strength and persistence as evaluation elements.

Polymers usable in the present invention include, but are not limited to, at least one selected from the group consisting of acrylics, amides, vinyl alcohol polymers, and copolymers thereof, such as acrylate copolymers, acrylates / C10. -30 alkyl acrylate crosspolymer, sodium polyacrylate, hydroxyethyl acrylate / sodium acryloyldimethyl taurate copolymer, ammonium acryloyl dimethyl taurate / vinylpyrrolidone copolymer, polyacrylamide / C13-14 Isoparaffin / laures-7 and the like can be used. More preferably for the purposes of the present invention, it is an acrylate copolymer. In the perfume composition according to the present invention, the content of the polymer is preferably 0.01 to 10 parts by weight of 100 parts by weight of the total perfume composition. If it is less than 0.01 part by weight, the stability and drying feeling is poor and volatilization is too fast, so the fragrance is strong, and it is difficult to volatilize a constant and continuous smell. Difficult to exercise

Surfactants usable in the present invention include, but are not limited to, at least one selected from sodium fatty acid, monoalkyl sulfate, alkylpolyoxyethylene sulfate, alkylbenzenesulfonate, monoalkyltrimethylammonium salt, or dialkyldimethylammonium salt. May be included and more preferably for the purposes of the present invention, alkylpolyoxyethylene sulfate. In the perfume composition according to the present invention, the content of the surfactant is preferably 0.1 to 15 parts by weight, more preferably 0.1 to 12 parts by weight, most preferably 0.15 to 12 parts by weight of 100 parts by weight of the total perfume composition. . If it is less than 0.1 part by weight, the stability of the phase is particularly weak, and it is difficult to volatilize a constant and persistent odor. If it is more than 15 parts by weight, the dryness is low and the volatilization is slow.

Emulsifying and solubilizing agents usable in the present invention include, but are not limited to, for example, sorbitan sesquioleate, glyceryl monostearate, polyoxyethylene sorbitan tristearate, polyoxyethylene sorbitan trioleate, polyoxyethylene glycol At least one or more selected from monostearate, polysorbate, polyoxyethylene monostearate, or polyoxyethylene hydrogenated castor oil may be included, and more preferably PEG-30 hydrogen may be used for the purposes of the present invention. Tide caster oil. In the fragrance composition according to the present invention, the content of the emulsifier-solubilizer is preferably 0.3 to 10 parts by weight, more preferably 0.3 to 8 parts by weight of 100 parts by weight of the total fragrance composition. If it is less than 0.3 part by weight, the phase stability is particularly weak, and if it is more than 10 parts by weight, the phase stability and dryness are particularly poor. Also preferably, the emulsifying and solubilizing agent usable in the present invention is not limited thereto, but a substance having a hydrophilic lipophilic balance (HLB) value of about 1 to about 20 may be used alone or in combination, and preferably an HLB value of 3 to about Materials of about 17 may be used alone or in combination, more preferably may have an HLB value of about 5 to 17.

Solubilization and volatilization accelerators have a great effect on the stability of the formulation as well as solubilization and volatilization promotion. The solvent used as the solubilization-volatile promoter for use in the present invention is not limited thereto, and may include, for example, at least one selected from ethanol, propylene glycol, dipropylene glycol, ethylene glycol, butylene glycol, and the like. More preferably for the purpose, ethanol. In the fragrance composition according to the present invention, the content of the solubilization-volatile promoter is preferably 3 to 25 parts by weight, more preferably 3 to 20 parts by weight of 100 parts by weight of the total perfume composition. Less than 3 parts by weight of the phase stability and dry feeling is particularly weak, slow volatilization, more than 25 parts by weight is particularly low phase stability, constant and persistent flavor volatilization is difficult.

The fragrances usable in the present invention can be used without limitation as long as they have flavor characteristics, for example, animal flavors include musk, civet, ambergris and castor, and vegetable oils include grapefruit. Fruit (Citrus paradisi), Neroli (Citrus aurantium), Nyauli (Melaeuca viridiflora), Lavender (Lavandula angustifolia), Lemon (Citrus limonum), Lemongrass (Cymbopogon citratus), Rose (Rosa damascena, R. centifolia, R. gallica ), Rosemary (Rosemarinus officinalis), Rosewood (Aniba rosaeodora), Marjoram (Origanum majorana), Mandarin (Citrus reticulata), Melissa officinalis, Myrrh (Commiphora myrrha), Basil (Ocimum basilicum), Bergamot (Citrus) , Viveiver (Veriveria zizanoides), Blackper (Piper nigrum), Cypress (Cupressus sempervirens), Sandalwood (Santalum album), Sthamint (Metha spicata), Cinnamomum zeylanicum, Cedarwood (Cedru s atlantica, Cymbopogon nardus, Achillea milleflium, Orange suite (Citrus sinensis), Eucalyptus (Eucalyptus globulus), Canaga odorata, Jasmine (Jasminum grandiflorum), Geranium (Pensargonium) Juniper berry (Juniperus communis), Ginger (Zingiber officinale), Chamomile Roman (Chamaemelum nobile), Chamomile Germanic (Matricaria recutita), Coriandrum sativum, Salvia sclarea, Clovebird (Eugenia caryophyllus) vulgaris, tea tree (Melaleuca alternifolia), pine (Pinus sylvestris), patchouli (Pogostemon cablin), palmarosa (Cymbopogon martinii), paneniculum vulgare, peppermint (Mentha piperita), hysso (hyssopus officinalis) aurantifolia, Tilia europaea, Mytus communis, Violet (Viola odorata), Verbena (Lippia citriodra), Birch (Betula alleghaniensis (yellow), B. pendula (silver), B. lenta (cherry) ), Bay (Laurus nobilis), Anverogon muricatus, benzoin (Styrax benzoin), cardamom (Elettaria cardamomum), chamomile (Anthemis nobilis), Melaleuca leucadendron, Campo (Cinnamomun camphora), Tangerine (Citrus reticulata) Gren (Citrus vulgaris), Thuja occidentalis L. and Franklinsense (Boswelliacarteri) may be included, and as an aromatic compound butylidene phthalide, phenethyl alcohol, pen Phenethyl acetate, cis-hexon-1-ol, anethol, benzaldehyde, benzyl acetate, benzyl alcohol, benzyl formate, iso-bornyl acetate, camphene Cis-citral, citronella, citronellol, citronellol, citronellyl acetate, ρ-cymene, decanal, dihydro linal Dihydrolinalool, dihydromyrcenol, Dimethyl phenyl carbinol, uraliptol, geranial, geraniol, geranyl acetate, geranyl nitril, cis-3-hexenyl acetate, Hydroxycitronellal, d-limonene, linalool, linalool oxide, linalyl oxide, linalyl acetate, linalyl propionate, methyl anthranilate , α-methyl ionone, methyl nonyl acetaldehyde, methyl phenylcarvinyl acetate, raebo-mentyl acetate, menthone, iso-mentone, mycene, myrsenyl acetate acetate, myrcenol, nerol, neryl acetate, nonyl acetate, phenylethyl alcohol, α-pinene, β-pinene, γ-terpinen , α-terpineol, β-terpineol, terpineyl acetate (terpinyl acetate), ρ-tert-butyl cyclohexyl acetate, amyl cinnamic aldehyde, iso-amyl salicylate, β-caryophyllene, cedrene , Cinnamic alcohol, coumarins, dimethyl benzyl carvinyl acetate, ethyl vanillin, eugenol, iso-eugenol, fluoroacetate ), Heliotropin, 3-cis-hexenyl salicylate, hexyl salicylate, ρ-tert-butyl-alpha-methyl hydrocinnamic acid aldehyde, δ-methyl ion Paddy, nerolidol, patcholic alcohol, phenyl hexanol, β-selinene, trichloromethyl phenyl carvinyl acetate, triethyl citrate, vanillin, veratraldehyde, benzophenone (benzophenon), benzyl sally , 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethyl-cyclopenta-δ-2-benzopyran, hexyl cinnamic aldehyde, 4- ( 4-hydroxy-4-methyl pentyl) -3-cyclohexene-10-carboxyaldehyde, methyl cedrylone, methyl dihydro jasmonate, methyl-β-naphthyl ketone, musk indanone, Musk ketones, or musk tibetene, and phenylethyl phenyl acetate and the like. Appropriate ingredients may be selected in consideration of the use of the fragrance composition, the application location, or the taste of the user, and the basic content known in the art of the selected ingredients may be set. However, depending on the content of the fragrance in the fragrance composition may affect the phase stability, dryness, volatilization, deodorization and deodorization, the fragrance is preferably included in 3 to 25 parts by weight of 100 parts by weight of the total fragrance composition. . When the content is less than 3 parts by weight, the fragrance, deodorization and deodorizing power stability and dryness are particularly weak, and when the content is more than 25 parts by weight, the phase stability is particularly low and the smell is strong.

The fragrance composition according to the present invention is 0.01 to 10 parts by weight of the polymer, 0.1 to 15 parts by weight of surfactant, 0.3 to 10 parts by weight of emulsifying and solubilizing agent, 3 to 25 parts by weight of solubilizing agent and volatilizing agent in 100 parts by weight of the whole fragrance composition, And in addition to the 3 to 25 parts by weight of fragrance, the residual amount of water may be included.

To the fragrance composition according to the present invention, components other than polymers, surfactants, emulsifiers, solubilizers, solubilizers, volatilization accelerators, and fragrances may be added that can exhibit various functions within the scope of not impairing the object of the present invention. A material that can function as a fragrance can be used without limitation, including a substance which is not particularly limited and includes a substance known as a conventional fragrance component, without a problem in the stability of the formulation. For example, antiseptics, stabilizers, pigments, antibacterial agents, deodorants and deodorants or fungicides may be included. More preferably for the purpose of the present invention, mugwort extract and green tea extract may be further added.

The fragrance composition according to the present invention may be prepared by various methods known in the art, and may be prepared, for example, by adding a polymer, a surfactant, an emulsifying / solubilizing agent to a solubilizing agent and a volatilizing agent, and stirring at room temperature or high temperature.

The fragrance composition according to the present invention is intended to be applied to a sheet-type fragrance, the sheet type may be, for example, a nonwoven fabric type, a film type, or a film and a nonwoven laminate type, and preferably a nonwoven fabric type.

The nonwoven fabric may be formed by the mutual bonding of the polymer fibers, the polymer fibers are not limited thereto, the fineness of the polymer fibers is preferably 1 to 10 denier (denier), more preferably may be 3 to 7 denier. have. In addition, in consideration of the ease of web forming processing, the nonwoven fabric may be prepared by, for example, polypropylene, polyethylene terephthalate, polyethylene, nylon, rayon, pulp or acrylic, or a mixture thereof. , Polyethylene terephthalate, and polyethylene are preferred. In addition, the nonwoven fabric may be prepared by thermal bonding, air through, spun bonding or melt-blown methods.

The basis weight of the sheet is determined in consideration of the location of use, the content of the fragrance composition, the absorbency of the sheet, and the like. The basis weight of the sheet is not particularly limited, but is preferably 10 g / m ² to 100 g / m ² , and more preferably 35 g / m ² to 75 g / m ² . If the basis weight is less than 10g / m ² with respect to the basis weight of the sheet, the loading of the required active ingredients is too small, there may be a problem, and if the basis weight is 100g / m ² or more, the weight of the sheet itself is too heavy have.

In another aspect, the present invention provides a sheet-type fragrance to which the fragrance composition according to the present invention is applied.

Since the fragrance composition according to the present invention has excellent phase stability, dryness, volatilization, and deodorization and deodorizing power, the sheet-type fragrance to which the fragrance composition is applied is easy to store, install, and use, and is free from hand stains. In addition, since the fragrance composition can be uniformly distributed on the sheet in a predetermined constant mixing amount and density, the sheet-type fragrance to which the fragrance composition is applied can be divided into suitable sizes according to the use place and method, and the area used can be easily controlled. There is an advantage to this. Therefore, it is economical and convenient because it can give a directional effect by cutting to a size suitable for narrow and narrow areas that were difficult to install in the past.

Usually, the total amount of the perfume composition is determined in consideration of the effective amount of the perfume composition required for the sheet-type perfume and the absorbency of the sheet. Although not limited thereto, the perfume composition according to the present invention is preferably applied in an amount of 100 to 500 parts by weight based on 100 parts by weight of the entire sheet. If it is less than 100 parts by weight, there is a problem that an excessively large amount of sheets must be used to express the required performance. If the amount is more than 500 parts by weight, the weight of the sheet tends to be too heavy.

A method for producing a sheet-type perfume using the perfume composition according to the present invention is known in the art, for example, a method of dipping and impregnating the sheet in a preparation solution containing the perfume composition, spray coating method, inkjet coating method, gravure Coating or roll coating can be used.

In the detailed description of the present invention described above with reference to a preferred embodiment of the present invention, those skilled in the art and those skilled in the art, those skilled in the art, the present invention described in the claims It will be understood that various modifications and changes can be made in the present invention without departing from the spirit and scope of the invention. Therefore, the technical scope of the present invention should not be limited to the contents described in the detailed description of the specification, but should be defined by the claims.

As described above, the fragrance composition of the present invention and the sheet-type fragrance to which the fragrance composition is applied are easy to install and handle due to the softness of the product itself and the ease of shape change, and its small volume and light weight, and it does not get on the hands when used. It can be easily used in any place without a sense of rejection, there is an advantage that it is easy to process. In particular, the fragrance composition of the composition and content according to the present invention can maximize the odor, deodorization and air purification effect through the volatilization of excellent fragrance components.

Hereinafter, preferred embodiments and experimental examples are provided to facilitate understanding of the present invention. However, the following Examples and Experimental Examples are only for illustrating the present invention, the present invention is not limited to the following Examples and Experimental Examples.

[Example]

Example 1 Preparation of Perfume Composition and Nonwoven Type Perfume Impregnated with It

As described in Table 1 and Table 2 below, the A-H components were mixed to prepare a perfume composition. Then, it was applied to a nonwoven fabric, supported, and then cut to prepare a nonwoven fabric-type perfume.

However, in showing the components of the compositions of the following Comparative Examples and Examples in the present invention,

     A: water

     B: acrylate copolymer

     C: alkyl polyoxyethylene sulfate

     D: Spices

     E: PEG-30 hydrogenated castor oil

     F: Ethanol

     G: mugwort extract

     H: Green Tea Extract

It is prescribed by.

division A B C D E F G H Example 1 to100 0.01 0.1 3.0 0.3 3.0 0.2 0.3 Example 2 to100 0.1 10.0 3.0 0.3 3.0 0.2 0.3 Example 3 to100 1.0 3.0 10.0 10.0 3.0 0.2 0.3 Example 4 to100 3.0 5.0 25.0 6.0 3.0 0.2 0.3 Example 5 to100 5.0 1.0 20.0 4.0 3.0 0.2 0.3 Example 6 to100 10.0 15.0 5.0 2.0 3.0 0.2 0.3 Example 7 to100 10.0 1.0 3.0 0.3 3.0 0.2 0.3 Example 8 to100 5.0 15.0 5.0 1.5 7.0 0.2 0.3 Example 9 to100 3.0 5.0 10.0 3.5 25.0 0.2 0.3 Example 10 to100 1.0 10.0 20.0 6.0 20.0 0.2 0.3 Example 11 to100 0.1 3.0 25.0 10.0 10.0 0.2 0.3 Example 12 to100 3.0 2.0 3.0 0.3 3.0 0.2 0.3 Example 13 to100 1.0 5.0 20.0 6.0 15.0 0.2 0.3 Example 14 to100 3.0 3.0 10.0 5.0 10.0 0.2 0.3 Example 15 to100 5.0 1.0 25.0 8.0 10.0 0.2 0.3 Example 16 to100 10.0 1.0 3.0 4.0 25.0 0.2 0.3

division A B C D E F G H Comparative Example 1 to100 0.009 0.1 3.0 0.3 3.0 0.2 0.3 Comparative Example 2 to100 10.5 0.1 10.0 3.0 3.0 0.2 0.3 Comparative Example 3 to100 10.0 0.09 3.0 0.3 3.0 0.2 0.3 Comparative Example 4 to100 5.0 16.0 5.0 1.5 7.0 0.2 0.3 Comparative Example 5 to100 1.0 10.0 2.0 0.3 3.0 0.2 0.3 Comparative Example 6 to100 3.0 5.0 30.0 8.0 3.0 0.2 0.3 Comparative Example 7 to100 0.1 10.0 3.0 0.2 3.0 0.2 0.3 Comparative Example 8 to100 10.0 15.0 5.0 11.0 3.0 0.2 0.3 Comparative Example 9 to100 0.1 10.0 3.0 0.3 2.0 0.2 0.3 Comparative Example 10 to100 10.0 1.0 3.0 4.0 30.0 0.2 0.3

[ Experimental Example ]

According to the above examples and comparative examples Efficacy effect was evaluated as follows about the prepared fragrance composition and the nonwoven type fragrance to which it was applied. The results are shown in Tables 4 and 5 below. From the following results, it was found that more detailed metering and manufacturing steps are required for the production of the perfume composition of the present invention. More specific efficacy evaluation results are as follows.

Experimental Example 1 Phase Stability Evaluation

The phase stability evaluation was evaluated by observing the state of the phase after storage of the fragrance composition at room temperature (25 ° C), high temperature (45 ° C), and low temperature (-3 ° C) for 30 days. The higher the stability, the higher the score.

As a result, especially low phase stability was shown when it contained 0.09 weight part of surfactants, 30 weight part of fragrances, 0.2 weight part of emulsifiers and solubilizers, 2.0 weight part or 30 weight parts of solubilization and volatilization accelerators.

From the above results, it can be seen that the emulsifying and solubilizing agent has a great influence on the stability of the phase despite a slight difference in amount.

Experimental Example 2. Evaluation of Dryness

In the evaluation of dryness, the nonwoven fabric type air freshener to which the air freshener composition was applied was stored in a constant temperature and humidity chamber at 25 ° C. and a humidity of 40 to 45%, and after a predetermined time, the dry state of the sheet was confirmed. After dividing each evaluation group, the sense of dryness was evaluated by sensory touch by hand, and the evaluation criteria and evaluation results which quantified the degree are shown in Table 4 and Table 5. The better the feeling of drying, the higher the score.

In the nonwoven type air freshener, the dryness of the nonwoven fabric has a great influence on the product quality and the customer's product satisfaction. The nonwoven fabric-type fragrance, which is a characteristic of this product, is characterized in that it does not adhere to the hand when used as a fragrance in a dried state.

As a result of the evaluation of dryness, especially when it was 10.5 weight part of polymers, 16 weight part of surfactants, or 11 weight part of emulsifying and solubilizing agents, the low dry feeling was shown. Within the range of 0.01 to 10 parts by weight of the polymer, 0.1 to 15 parts by weight of the surfactant, and 3 to 25 parts by weight of the solubilizing and volatilizing agent, the more the content of the polymer or the surfactant and the less the solubilizing and the volatilizing agent is, The time became short and showed a good dry feeling. However, it is evaluated that the drying time is not infinitely long because the content of the polymer or the surfactant is decreased and the content of the solubilizer and the volatilization accelerator is increased.

Experimental Example 3. Evaluation of Volatility

Volatile force evaluation, one of the most important evaluation factors in fragrances, was conducted. The volatilization power was evaluated by measuring the weight before drying (weight immediately after the manufacture) while storing the nonwoven fabric-type air freshener prepared in Example 1 in a constant temperature and humidity chamber having a temperature of 25 ° C. and a humidity of 40 to 45%. (Weight immediately after drying) was measured, and the volatilization sustainability was evaluated together with the volatilization power after drying. The evaluation of volatilization was carried out by leaving the dried nonwoven fabric-type fragrance in a room-type space with a constant temperature (1m width and 1m length) capable of constant temperature and humidity with a temperature of 25 ° C and a humidity of 40 to 45%. After taking the odor, the volatility of the odor was evaluated by sensory and the degree was quantified, and the scales and the evaluation results are shown in Tables 4 and 5. The higher the volatility, the higher the score.

The evaluation result showed particularly low volatilization in the case of 0.009 parts by weight of polymer, 0.09 parts by weight of surfactant, 2 parts by weight of fragrance, 0.2 parts by weight of emulsifying / solubilizing agent, 2 parts by weight of solubilizing agent or volatilization accelerator, or 30 parts by weight. In the case of volatilization, the inventors have many differences depending on the content of polymer, surfactant, and solubilizing and volatilizing agent, and the polymer can form a mutual network structure to suppress the volatilization of fragrance, and the surfactant can The volatilization can be suppressed, so that when the content of the polymer and the surfactant is less than 0.01 part by weight and 0.1 part by weight, respectively, or when the content of the solubilizing and volatilizing accelerator (e.g., alcohol) capable of spontaneous volatilization is greater than 25 parts by weight, It has been found that it is difficult to volatilize a constant and persistent fragrance due to the rapid volatilization of scent and strong odor. In addition, when the content of the polymer and the surfactant exceeds 10 parts by weight or 15 parts by weight, respectively, or when the content of the solubilizing and volatilizing agent is less than 3 parts by weight, the volatilization is slowed and the fragrance is weakened, thereby exhibiting the function and efficacy as a fragrance. It was analyzed as difficult to do. In addition, the degree of emulsification and solubilization according to the content of the emulsifying and solubilizing agent can also affect the volatilization a lot. Therefore, it can be seen that the solubilization, volatilization accelerator, and emulsification and solubilizer together with the polymer and the surfactant can exhibit excellent functions and efficacy as a fragrance when composed in a range of contents.

Experimental Example 4. Evaluation of deodorizing and deodorizing power

In order to evaluate the deodorizing and deodorizing effect, the dried nonwoven fabric type air freshener is left in a room-type space of a constant scale (1m in width and 1m in length) capable of constant temperature and humidity with a temperature of 25 ° C. and a humidity of 40 to 45%, and then a odor is generated. After evaluating the deodorant and deodorant effect by organizing a professional evaluation team composed of 35 general members and smelling it, the degree was quantified. The higher the deodorizing and deodorizing power, the higher the score.

As a result, when the content of the fragrance is 2 parts by weight, it showed a particularly low deodorizing and deodorizing effect. Deodorizing and deodorizing effect was insignificant when the content of the fragrance was less than 3 parts by weight, and the deodorizing and deodorizing effect was excellent when the content of the fragrance was more than 25 parts by weight, but rather, a strong smell was expressed.

Experimental Example 5. Overall Satisfaction Evaluation

35 professional evaluation teams were asked to evaluate the overall satisfaction, and the scales and the evaluation results are shown in Tables 4 and 5. From the above evaluation results, the satisfaction with the fragrance composition and the fragrance of Examples 1-16 was very high.

Therefore, when viewed through the above-described contents and the following table, the perfume composition of the present invention is excellent in the stability of the phase, and when applied to a nonwoven fabric has excellent drying feeling, such as no stain on the hand with a quick drying time, excellent fragrance and volatilization force In addition to having a deodorizing and deodorizing effect also appeared to be excellent, the overall satisfaction was also very good. In addition, as can be seen from the results of the present invention, if the excellent volatility is evaluated as excellent deodorizing and deodorizing effect was found that there is a high connection between the volatility and deodorizing and deodorizing effect.

In particular, the results of the analysis of the examples and comparative examples, despite the difference between the same component and the trace amount, there is a significant difference in the effect according to the difference in the content of each component, the critical significance of the numerical range of the content of the perfume composition according to the present invention It was found out.

Evaluation criteria for each efficacy effect
Evaluation standard Very good Great usually Inadequate Bad 4.5 or more 3.5 to 4.4 3.0 ~ 3.4 2.5 ~ 2.9 2.4 or less ◎ ○ △ ▽ ×

Evaluation result by efficacy effect of Example division Stability
Evaluation results Dryness
Evaluation results Volatility
Evaluation results Deodorization / Deodorization
Evaluation results Overall
satisfaction Example 1 △ △ △ △ △ Example 2 ○ ○ ○ ○ ○ Example 3 ◎ ◎ ◎ ◎ ◎ Example 4 ◎ ◎ ◎ ◎ ◎ Example 5 ◎ ◎ ◎ ◎ ◎ Example 6 ◎ ◎ ◎ ◎ ◎ Example 7 ◎ ◎ ○ ○ ○ Example 8 ◎ ◎ ◎ ◎ ◎ Example 9 ◎ ◎ ◎ ◎ ◎ Example 10 ◎ ◎ ◎ ◎ ◎ Example 11 ○ ○ ◎ ◎ ◎ Example 12 ◎ ◎ ○ ○ ○ Example 13 ○ ◎ ◎ ◎ ◎ Example 14 ◎ ◎ ◎ ◎ ◎ Example 15 ◎ ○ ◎ ◎ ◎ Example 16 ○ ◎ ○ ○ ○

Evaluation result by efficacy effect of comparative example division Stability
Evaluation results Dryness
Evaluation results Volatility
Evaluation results Deodorization / Deodorization Evaluation Results Overall
satisfaction Comparative Example 1 ▽ ▽ △ △ × Comparative Example 2 △ × ○ ○ △ Comparative Example 3 × △ △ ○ × Comparative Example 4 △ × ○ ○ × Comparative Example 5 △ △ △ × × Comparative Example 6 × ▽ ○ ○ × Comparative Example 7 × △ △ △ × Comparative Example 8 ▽ × ○ ○ △ Comparative Example 9 × ▽ △ △ × Comparative Example 10 × △ △ △ ×

Claims (8)

In the fragrance composition for sheet-type fragrance, 0.01 to 10 parts by weight of polymer, 0.1 to 15 parts by weight of surfactant, emulsifying and solubilizing agent 0.3 in 100 parts by weight of the total composition. A fragrance composition comprising 10 to 10 parts by weight, 3 to 25 parts by weight of solubilization-volatile accelerator, and 3 to 25 parts by weight of perfume. The perfume composition of claim 1, wherein the polymer comprises at least one selected from the group consisting of acryl, amide, vinyl alcohol polymer, and copolymers thereof. The method of claim 1, wherein the surfactant comprises at least one selected from the group consisting of sodium fatty acid, monoalkyl sulfate, alkyl polyoxyethylene sulfate, alkylbenzene sulfonate, monoalkyltrimethylammonium salt, dialkyldimethylammonium salt, and mixtures thereof. Perfume composition, characterized in that. The method of claim 1, wherein the emulsifying and solubilizing agent is sorbitan sesquioleate, glyceryl monostearate, polyoxyethylene sorbitan tristearate, polyoxyethylene sorbitan trioleate, polyoxyethylene glycol monostearate, Perfume composition, characterized in that it comprises at least one selected from the group consisting of polysorbate, polyoxyethylene monostearate, polyoxyethylene hydrogenated castor oil, and mixtures thereof. The fragrance composition of claim 1, wherein the solubilization-volatile promoter comprises at least one selected from the group consisting of ethanol, propylene glycol, dipropylene glycol, ethylene glycol, butylene glycol, and mixtures thereof. The fragrance composition of claim 1, wherein the fragrance composition further comprises one or more adjuvants selected from the group consisting of preservatives, stabilizers, colorants, antimicrobials, deodorants and deodorants and fungicides. The fragrance composition according to claim 1, wherein the sheet-type fragrance is a nonwoven type fragrance. The sheet type perfume applied to the perfume composition of any one of Claims 1-7.