KR20190007694A - A liquid aromatic agent composition having long term distribution characteristics and liquid aromatic agent kit including the same - Google Patents

Abstract

Disclosed is a liquid air freshener composition having even, long-lasting diffusibility and improved in cost efficiency and user convenience by having a composition which ensures long-lasting fragrance and is refillable. Also, disclosed is a liquid air freshener kit containing the same. The liquid air freshener composition comprises: 10-40 wt% of silicon oil; 10-40 wt% of hydrocarbon oil; 10-40 wt% of a solvent for activating volatilization; and 10-35 wt% of perfume.

Description

TECHNICAL FIELD The present invention relates to a liquid aromatic agent composition having uniform divergence characteristics over a long period of time and a liquid aromatic agent kit containing the same,

The present invention relates to a liquid perfume composition, and more particularly, to a liquid perfume composition which not only has excellent fragrance persistence but also has a composition that conforms to refill conditions, thereby improving economic efficiency and user convenience, To a liquid perfume composition and a liquid perfume kit comprising the same.

As the economy develops and the standard of living improves, the desire for well-being or healing also increases, leading to not only bad odors such as toilets, but also in a variety of spaces such as offices, homes, Fragrance use is increasing. As an example, since the influence of the smell of building materials that have not been noticed so far on health has become a social issue and the term 'sick house syndrome' has become accustomed to it, consumers' interest in health and desire for a comfortable living environment are more common than ever High. Particularly, in addition to the relaxation of stress and tension that is unavoidable in modern life, aromatherapy for improving concentration is attracting attention, and the development of fragrance materials and fragrance manufacturing techniques with various effects is continuously being carried out. Accordingly, in order to improve the quality of life, there is an increasing demand for products such as a fragrance or a diffuser which diffuses good fragrance in the room.

Perfume is a product that volatilizes fragrance for a certain period of time with a certain strength. Since most fragrance materials easily volatilize, there is a disadvantage that it is difficult to maintain the fragrance for a long time in a normal environment. Accordingly, the issue in the field of perfume technology is to keep the fragrance of a certain intensity long lasting with the aesthetic improvement of the perfume appearance, and various techniques for this have been developed.

Examples of the type of the fragrance include a liquid fragrance in which the fragrance is diluted with alcohol or other solvent, a gel fragrance in which the fragrance is dispersed in the gellant, a silica gel, a porous polymer, a porous ceramic, a felt and wood, Aerosols which are dispersed and injected into a can container together with a gas, and fragrance capsules in which fragrance is encapsulated with a polymer substance.

Korean Patent Publication No. 10-2007-0072706

As mentioned above, in the modern society, various kinds of fragrances are used in order to create a more pleasant environment. However, there are many indications that products having disadvantages in each fragrance have to be developed considering the convenience of the user. Particularly, in the case of a liquid aromatic agent based on ethanol, there is an advantage that it is easy to manufacture, but the container must be securely fixed, the initial strength of the fragrance is excessively strong, and the fragrance intensity is weakened at a rapid rate have. In addition, water-soluble gel fragrances using polysaccharide components such as carrageenan and gelatin have a property that the fragrance as an active ingredient is an oil that does not dissolve in water, 10% by weight, and the amount of volatilization at the beginning and end of use is not constant but rapidly decreases. In addition, the gel air freshener is not good in appearance due to a large amount of residue of volatilization, and refill is not possible, which is a disadvantage of purchasing the finished product every time. Therefore, efforts have been made to solve such problems in the related art.

Accordingly, an object of the present invention is to provide a liquid-phase aromatic composition having long-term uniform dispersion characteristics, which not only has a long-lasting fragrance strength but also has a composition corresponding to refill conditions, And to provide a liquid perfume kit comprising the same.

In order to achieve the above object, the present invention provides a silicone oil composition comprising 10 to 40% by weight of a silicone oil; 10 to 40% by weight of a hydrocarbon oil; 10 to 40% by weight of a solvent for promoting the volatilization; And 10 to 35% by weight of a perfume composition.

The present invention also relates to a liquid perfume composition; And 10 to 40% by weight of a hydrocarbon oil, 10 to 40% by weight of a solvent for promoting a volatilization, and 10 to 40% by weight of a solvent for accelerating the oxidation of the liquid. And 35% by weight of a perfume.

The liquid fragrance composition and the liquid fragrance kit containing the fragrance composition of the present invention having long-term uniform dispersion characteristics according to the present invention not only have excellent fragrance persistence ability but also have a composition that conforms to refill conditions, thereby improving the economy and user convenience .

FIG. 1 is a graph showing the percent volatilization of a liquid perfume composition according to the number of days elapsed in one embodiment of the present invention and a comparative example.

Hereinafter, the present invention will be described in detail.

The liquid fragrance composition according to the present invention has 10 to 40% by weight of silicone oil, 10 to 40% by weight of hydrocarbon oil, 10 to 40% by weight of a solvent for promoting the volatilization and 10 to 35% In order to complement and improve the disadvantages of the conventional liquid perfume composition, it has been made to have a certain volatilization power by mixing two kinds of oil components having different properties.

The silicone oil is used for improving the degree of uniform (uniform) dissipation of the liquid aromatic agent and is preferably at least one selected from the group consisting of n-siloxane, polydimethylsiloxane (PDMS) and cyclosiloxane But are not limited thereto. Examples of the normal siloxane include disiloxane and trisiloxane, and examples of the polydimethylsiloxane include decamethyltetrasiloxane, dodecamethylpentasiloxane, and dimethicone ). Examples of the cyclosiloxane include dimethylcyclosiloxane, cyclopentasiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, and decamethylcyclohexasiloxane. Examples of the cyclosiloxane include dimethylcyclosiloxane, cyclopentasiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane and decamethylcyclohexasiloxane. And it is preferable to use at least one of the above dimethylcyclosiloxane, cyclopentasiloxane and decamethylcyclopentasiloxane as a silicone oil.

The content of the silicone oil is 10 to 40% by weight, preferably 20 to 30% by weight based on the whole liquid aromatic composition. When the content of the silicone oil is less than 10% by weight but exceeds 40% by weight, the fragrance may become weaker as the volatilization rate slows down. That is, in other words, it is difficult to constantly and continuously disperse the fragrance, so that it may be difficult to exert its function as a fragrance.

Next, the above-mentioned hydrocarbon oil is also used for improving the degree of volatilization of the liquid aromatic agent, and an (aliphatic) hydrocarbon-based oil containing carbon and hydrogen atoms may be used. The hydrocarbon oil is a branched (or branched) alkane, ester or mixture thereof having 8 to 16 carbon atoms, preferably 10 to 12 carbon atoms. Examples of the alkane include isodecane, iso (Isoparaffin) selected from the group consisting of dodecane and isohexadecane. Examples of esters include isooctyl acetate, isohexyl acetate and isodecyl acetate. acetate, and the like. Preferably, the hydrocarbon oil contains at least one alkane compound, and isododecane is more preferably used.

The content of the hydrocarbon oil is 10 to 40% by weight, preferably 20 to 30% by weight based on the total liquid aromatic composition. When the content of the hydrocarbon oil is less than 10% by weight, the volatilization rate may be slowed and the fragrance may be weakened. When the content of the hydrocarbon oil is more than 40% by weight, the volatilization rate may be excessively high.

Subsequently, the above-mentioned solvent for promoting volatilization has a great influence on solubilization, promotion of volatilization, stability of the formulation, etc., and examples thereof include alcoholic solvents such as glycol and diol, but the present invention is not limited thereto. Specific examples of the solvent for promoting the volatilization include alcohols such as ethanol, propylene glycol, dipropylene glycol, ethylene glycol, butylene glycol, dipropylene glycol methyl ether, diethylene glycol ethyl ether, dipropylene glycol methyl ether acetate, dipropylene glycol butyl ether , 1,2-hexanediol, propanediol, methylpropanediol, and methoxymethylbutanol, and it is preferable to use the above-mentioned dipropylene glycol methyl ether.

The content of the solvent for promoting the vaporization is 10 to 40% by weight, preferably 20 to 30% by weight based on the total liquid aromatic composition. When the content of the solvent for promoting the vaporization is less than 10% by weight, the phase stability and the rate of vaporization may decrease. When the content exceeds 40% by weight, the phase stability is increased. However, And it may be difficult to emit a continuous flavor.

Finally, the fragrance can be used without any limitation as long as it has a fragrance, and it can be roughly divided into animal fragrance, vegetable oil and aromatic compound. It is suitably selected in consideration of the use of the fragrance composition, You can choose to cook.

Examples of the animal spices include musk, civet, ambergris, and castor.

Examples of the vegetable oils include citrus paradisi, Citrus aurantium, Melaeuca viridiflora, Lavandula angustifolia, Citrus limonum, Cymbopogon citratus, Rose Rosa damascena, R. centifolia, R. gallica), Rosemarinus officinalis, Aniba rosaeodora, Origanum majorana, Citrus reticulata, Melissa officinalis, Commiphora myrrha, Basil (Ocimum basilicum), Citrus bergamia, Veriveria zizanoides, Piper nigrum, Cupressus sempervirens, Santalum album, Metha spicata, Cinnamomum zeylanicum, Cedrus atlantica, Cymbopogon nardus, Achilleamilleflium, Citrus sinensis, Eucalyptus globulus, Canaga odorata, Jasminum grandiflorum, Pelargonium graveo, Lens, Juniperus communis, Zingiber officinale, Chamaemelum nobile, Matricaria recutita, Coriandrum sativum, Salvia sclarea, Eugenia caryophyllus, Thymus vulgaris, Melaleuca alternifolia, Pinus sylvestris, Pogostemon cablin, Cymbopogon martinii, Foeniculum vulgare, Mentha piperita, Hyssopus officinalis, Lilium (Citrus aurantifolia), Tilia europaea, Mytus communis, Viola odorata, Lippia citriodra, Betula alleghaniensis (yellow), B.pendula (silver), B.lenta cherry, bay (Laurus nobilis), vetiver (Andropogon muricatus), benzoin (Styrax benzoin; Elettaria cardamomum, Anthemis nobilis, Melaleuca leucadendron, Cinnamomun camphora, Citrus reticulata, Citrus vulgaris, Thuja occidentalis L., And Boswelliacarteri (frankincense).

Examples of the aromatic compounds include but are not limited to butylidene phthalide, phenethyl alcohol, phenethyl acetate, cis-hexen-1-ol, anethole benzyl alcohol, benzyl formate, isobornyl acetate, camphene, cis-citral, citronella, citronellol, benzoic acid, citronellol acetate, citronellyl acetate, cymene, decanal, dihydro linalool, dihydro myrcenol, dimethyl phenyl carbinol ( dimethyl phenyl carbinol, eucalyptol, geranial, geraniol, geranyl acetate, geranyl nitril, cis-3-hexenyl acetate, Hydroxy citronellal, d-limonene, linalool ( linalool), linalool oxide, linalyl acetate, linalyl propionate, methyl anthranilate,? -methyl ionone, methylnonyl acetaldehyde, methylphenylcar Vinyl acetate, laevo-mentyl acetate, menthone, iso-mentone, myrcene, myrcenyl acetate, myrcenol, nerol, neryl acetate, Nonyl acetate, phenylethyl alcohol,? -Pinene,? -Pinene,? -Terpinen,? -Terpineol,? -Terpineol, terpinylacetate butylcyclohexyl acetate, amyl cinnamic aldehyde, iso-amyl salicylate, caryophyllene, cedrene, and the like. , Cinnamic alcohol, coumarins, dimethyl Benzyl carvinyl acetate, ethyl vanillin, eugenol, iso-eugenol, fluoroacetate, heliotropin, 3-cis-hexenyl salicylate, Butyl-alpha-methylhydrocinnamate aldehyde,? -Methylionone, nerolidol, patchouly alcohol,? -Butyrolactone, Benzylphenol, benzyl salicylate, benzyl salicylate, benzyl salicylate, benzyl salicylate, benzyl salicylate, benzyl salicylate, benzyl salicylate, benzyl salicylate, , 3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethyl-cyclopenta-delta-2-benzopyran, hexyl cinnamic aldehyde, 4- (4- Methyl-4-methylpentyl) -3-cyclohexene-10-carboxyaldehyde, methyl cedriron, methyl dihydrozazomonate thymidine, ihydro jasmonate, methyl-β-naphthyl ketone, musk indanone, musk ketone, musk tibetene and phenyl ethyl phenylacetate.

The content of the perfume is 10 to 35% by weight, preferably 15 to 30% by weight, based on the whole liquid aromatic composition. When the content of the solvent for promoting the vaporization is less than 10% by weight, the odor is weak. When the content is more than 35% by weight, the phase stability is low and the fragrance is strong.

On the other hand, the above-described liquid fragrance composition may contain at least one component (additive) added to a conventional liquid fragrance such as an antioxidant, a dye, an ultraviolet absorber and an antiseptic.

On the other hand, the present invention can provide a liquid fragrance kit comprising the liquid fragrance composition described above (having long-term uniform diffusion characteristics). The liquid perfume kit comprises the above-described liquid perfume composition; And a container for containing the liquid perfume composition, and may further comprise a housing for containing the container therein, if necessary.

The container is not limited in its shape, structure and material as long as it can dissipate the fragrance of the liquid fragrance composition and prevent the deterioration of the composition. However, the fragrance can be diffused and the liquid fragrance composition leaves the container It is preferable that fine pores are formed on one surface or a plurality of surfaces of the container, or a cover for opening and closing is attached. In addition, the matters relating to the composition are applied mutatis mutandis to those described in the liquid aromatic composition.

As described above, the liquid fragrance composition and the liquid fragrance kit containing the fragrance composition of the present invention having long-term uniform dispersion characteristics according to the present invention are not only excellent in fragrance persistence, but also have a composition conforming to refill conditions, The convenience can be improved.

It will be apparent to those skilled in the art that various modifications and variations can be made in the present invention without departing from the spirit or scope of the invention as set forth in the appended claims. Such changes and modifications are intended to be within the scope of the appended claims.

[Examples 1 to 6] Preparation of liquid aromatic composition

(DC-244, manufactured by Dow Corning) or cyclopentasiloxane (DC-245, Dow Corning), a hydrocarbon oil such as isododecane (Creasil ID CG, manufactured by CIT ), Dipropylene glycol methyl ether (DPM, Dow Chemical), which is a solvent for promoting vaporization, and a combination fragrance (HP-60427, Hanvit flavoring) as a fragrance.

[Comparative Examples 1 to 16] Preparation of liquid aromatic composition

(Comparative Examples 2, 4 and 5 to 11) were excluded based on the composition of the following Table 1, or the contents of the components were excluded from the present invention (Comparative Examples 1 and 3), a liquid aromatic composition was prepared by the same methods and the same methods as in Examples 1 to 6 above.

[Comparative Examples 17 and 18] Preparation of liquid aromatic composition

According to the composition of Table 2 below, Comparative Example 17 produced a liquid fragrance composition in a conventional ethanol type, and Comparative Example 18 produced a liquid fragrance composition in a conventional aqueous type (containing purified water).

Silicone oil
(DC-244) Silicone oil
(DC-245) Hydrocarbon oil
(Creasil ID CG) Accelerated solvent
(DPM) Spices
(HP-60427) Example 1 20 20 40 20 Example 2 30 30 20 20 Example 3 35 35 10 20 Example 4 20 20 40 20 Example 5 30 30 20 20 Example 6 35 35 10 20 Comparative Example 1 10 10 60 20 Comparative Example 2 40 40 20 Comparative Example 3 10 10 60 20 Comparative Example 4 40 40 20 Comparative Example 5 70 10 20 Comparative Example 6 60 20 20 Comparative Example 7 40 40 20 Comparative Example 8 20 60 20 Comparative Example 9 70 10 20 Comparative Example 10 60 20 20 Comparative Example 11 40 40 20 Comparative Example 12 20 60 20 Comparative Example 13 70 10 20 Comparative Example 14 60 20 20 Comparative Example 15 40 40 20 Comparative Example 16 20 60 20

Comparative Example 17 Comparative Example 18 Ethanol 50 33 3-MMB 15 10 DPM 10 5 Combination fragrance 25 15 Purified water - 25 LA-7 - 12

* 3-MMB: 3-methoxymethylbutanol (Kuraray), combination fragrance: HP-60427 (fragrance for Hanbit), LA-7: laureth-

[Examples 1 to 6, Comparative Examples 1 to 18] Phase stability evaluation

The liquid fragrant compositions prepared in Examples 1 to 6 and Comparative Examples 1 to 18 were stored (or left to stand) at room temperature (25 ° C), high temperature (45 ° C) and low temperature (- 5 ° C) And the results are shown in Table 3 below. In Table 3, the better the phase stability, the higher the score. The ⊚ indicates excellent stability (4.5 points or more), the ◯ indicates superior phase stability (3.5-4.4), the Δ indicates (2.5 to 2.9 points), and the X mark means that the phase stability is poor (2.4 points or less), respectively. On the other hand, the explanation of the result of the phase stability evaluation will be explained together with the results of the volatility evaluation which will be described later.

Example
One Example
2 Example
3 Example
4 Example
5 Example
6 Comparative Example
One Comparative Example
2 Room temperature ◎ ◎ ◎ ◎ ◎ ◎ ◎ △ High temperature ◎ ◎ ◎ ◎ ◎ ◎ ◎ △ Low temperature ◎ ◎ ◎ ◎ ◎ ◎ ◎ □ Comparative Example
3 Comparative Example
4 Comparative Example
5 Comparative Example
6 Comparative Example
7 Comparative Example
8 Comparative Example
9 Comparative Example
10 Room temperature ◎ △ △ ○ ◎ ◎ △ ○ High temperature ◎ △ ○ ◎ ◎ ◎ ○ ◎ Low temperature ◎ □ X △ ◎ ◎ X ◎ Comparative Example
11 Comparative Example
12 Comparative Example
13 Comparative Example
14 Comparative Example
15 Comparative Example
16 Comparative Example
17 Comparative Example
18 Room temperature ○ ◎ △ ○ ◎ ◎ ◎ ◎ High temperature ◎ ◎ ○ ◎ ◎ ◎ ◎ ◎ Low temperature △ ◎ X △ ◎ ◎ ○ ○

[Examples 1 to 6, Comparative Examples 1 to 18] Evaluation of volatility

Four fiber reed sticks (thickness: 4 mm, length: 19 cm) were placed in the indoor environment with a low air flow at 26 ° C to prepare the liquid perfume composition prepared in Examples 1 to 6 and Comparative Examples 1 to 18 And the weight loss was measured at the same time every day for up to 4 weeks to evaluate the volatilization power of each liquid fragrance composition. The results are shown in Tables 4 to 6 below. In this case, the degree of volatilization was evaluated by converting the weight of the remaining fragrant composition into% in terms of the weight of the initial fragrance composition of 30 g as 100%, and as it converged to zero at 30 days, .

Example
One Example
2 Example
3 Example
4 Example
5 Example
6 Comparative Example
One Comparative Example
2 0 days 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 2 days 87.4 88.8 88.6 85.8 85.4 87.2 88.7 87.5 4 days 75.7 80.7 81.8 75.5 74.6 79.4 82.8 80.2 6 days 69.8 74.7 72.8 68.8 68.1 71.9 72.8 72.1 8 days 61.5 64.1 64.5 60.4 60.2 64.4 65.2 65.5 10 days 53.3 55.9 57.6 52.7 53.4 55.2 57.2 58.6 12th 48.8 48.9 50.4 45.6 46.8 48.1 51.8 51.4 14 days 42.6 42.1 44.1 38.9 39.2 42.4 45.6 43.1 16th 37.1 35.4 36.4 31.4 32.5 35.9 39.1 36.9 18th 31.8 29.7 30.2 27.4 27.9 29.2 34.4 30.4 20 days 26.3 22.8 23.6 20.8 21.2 23.2 28.5 24.1 22nd 20.9 16.5 17.2 13.4 14.4 16.8 21.1 17.4 24th 15.1 10.7 11.7 7.5 8.5 10.9 14.6 11.5 26th 8.6 6.3 6.8 3.9 4.2 6.8 8.8 6.9 28th 5.1 4.0 4.1 1.6 2.1 3.7 6.1 2.8 30 days 1.8 1.2 1.4 0.0 0.0 0.9 2.8 0.8

Comparative Example
3 Comparative Example
4 Comparative Example
5 Comparative Example
6 Comparative Example
7 Comparative Example
8 Comparative Example
9 Comparative Example
10 0 days 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 2 days 90.2 88.6 90.4 90.6 91.5 90.7 91.4 91.5 4 days 83.4 81.8 83.1 82.7 85.2 83.8 86.1 85.9 6 days 74.9 72.8 78.0 78.2 76.0 75.9 78.5 77.6 8 days 70.1 64.5 68.9 68.7 71.7 70.8 70.9 70.7 10 days 66.5 57.6 61.0 61.2 66.8 66.2 62.0 63.5 12th 60.4 50.4 53.7 53.8 61.5 60.7 55.7 58.9 14 days 54.3 44.1 47.5 46.8 55.6 54.6 48.5 52.4 16th 48.1 36.4 42.1 42.7 48.7 48.4 42.1 48.2 18th 39.5 30.2 38.8 39.1 40.6 39.7 37.8 40.5 20 days 34.4 23.6 33.5 34.5 35.3 34.4 32.5 34.9 22nd 25.7 17.2 29.5 29.8 26.8 25.7 27.5 28.2 24th 19.1 11.7 22.7 23.2 20.1 19.1 22.7 21.3 26th 13.2 5.8 17.8 18.1 14.2 13.7 17.8 13.8 28th 6.0 2.1 13.1 13.5 8.8 8.4 12.1 8.8 30 days 3.5 0.5 10.6 9.7 4.2 5.7 6.9 5.2

Comparative Example
11 Comparative Example
12 Comparative Example
13 Comparative Example
14 Comparative Example
15 Comparative Example
16 Comparative Example
17 Comparative Example
18 0 days 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 2 days 91.3 91.3 91.1 89.9 90.4 91.8 88.3 90.2 4 days 84.0 84.1 87.0 84.0 84.7 84.6 75.6 83.4 6 days 73.2 78.6 77.0 74.6 75.7 78.1 58.3 75.8 8 days 67.3 67.9 72.5 68.5 70.5 67.3 46.8 68.2 10 days 59.2 59.6 68.5 58.9 67.5 60.6 32.2 60.8 12th 52.7 53.2 62.4 53.8 61.4 53.6 20.8 53.4 14 days 48.2 48.7 56.8 49.2 55.9 48.1 12.9 47.3 16th 41.7 42.1 49.7 42.6 49.1 42.6 6.7 42.5 18th 34.6 35.4 41.3 35.1 40.5 36.4 3.2 38.6 20 days 28.3 29.1 36.4 29.3 34.9 29.6 1.2 34.9 22nd 22.7 23.2 27.5 23.7 26.7 23.4 0.0 31.5 24th 17.3 17.7 20.7 17.9 19.8 17.5 - 28.9 26th 9.0 9.4 14.8 10.4 13.1 9.7 - 25.2 28th 6.2 6.7 7.6 7.2 6.4 6.2 - 22.7 30 days 3.3 3.9 4.6 4.0 3.5 3.7 - 19.5

As shown in Tables 4 to 6, Examples 4 and 5 in which silicon oil, hydrocarbon oil, and a solvent for promoting the volatilization were mixed in addition to the perfume showed the most constant volatility. Also, in Examples 1 to 3 and 6, in which silicon oil, hydrocarbon oil, and a solvent for promoting the volatilization were mixed in addition to the fragrance, a certain volatilization force was also exhibited. In addition, in Examples 1 to 6, excellent phase stability was also shown, as shown in Table 3 above.

However, in the case of Comparative Examples 1 and 3 in which the constituents were the same as those in Examples 1 to 6, the phase stability was excellent, but the volatilization values at the passage of 30 days were 2.8 and 2.1, which were lower than those of Examples 1 to 6 , Indicating that the content of the solvent for promoting the vaporization is deviated from the present invention (i.e., more than 40% by weight). In addition, in Comparative Examples 2 and 4, although it was confirmed that the volatilization power was excellent even though the solvent for promoting the volatilization was not used, as shown in Table 3, since the phase stability was lowered, In addition, it can be seen that it also affects phase stability.

On the other hand, even a part of Comparative Examples 5 to 16 exhibited relatively good phase stability, but showed very poor results in the volatility evaluation. Therefore, it can be confirmed through the comparison between Examples 1 to 6 and Comparative Examples 5 to 16 that the silicon oil and the hydrocarbon oil have a synergistic effect that the volatilization power is promoted when the mixture is used, rather than alone.

FIG. 1 is a graph showing the percent volatilization of a liquid perfume composition according to the number of days elapsed in one embodiment of the present invention and a comparative example. As shown in Tables 4 and 6 and in FIG. 1, in the case of Comparative Examples 17 and 18 based on a conventional liquid aromatic composition, it was found that after 100 days of volatilization in 22 days or 30 days The residual amount of the composition was excessively large, resulting in a failure to exhibit a constant and continuous smell, and the results were in contrast to those of Examples 4 and 5 in which the remaining amount of the composition converged to zero at 30 days.

[Example 5, Comparative Examples 19 and 20] Horsetail satisfaction evaluation

(5% by weight in Comparative Example 19 and 40% by weight in Comparative Example 20) after setting the content of the perfume to be deviated from the present invention (10 to 35% by weight) according to the composition shown in Table 7 below. The perfume satisfaction of the perfume was evaluated in comparison with each other, and the results are shown in Table 8 below. In the following Table 8, the ⊚ mark indicates that the satisfaction of the flavor is very high (not less than 4.5 points), the mark □ indicates that the satisfaction of the flavor is low (2.5 to 2.9 points), X The sign indicates that satisfaction with the fragrance is very low (2.4 points or less), which is calculated from the average value of the score.

Silicone oil
(DC-245) Hydrocarbon oil
(Creasil ID CG) Accelerated solvent
(DPM) Spices
(HP-60427) Example 5 30 30 20 20 Comparative Example 19 30 30 35 5 Comparative Example 20 30 30 - 40

division Example 5 Comparative Example 19 Comparative Example 20 Satisfaction Satisfaction ◎ □ X

As shown in Table 8, the fragrance of the fragrance of Example 5 was very high, the fragrance of Comparative Example 19 had a weak fragrance strength and the degree of satisfaction was low, and the fragrance of Comparative Example 20 had a fragrance strength of And the degree of satisfaction was very low.

Based on the above results, the silicone oil, the hydrocarbon oil, and the solvent for promoting the volatilization must be used together, and even if they are used together, they are required to be blended to a certain extent to exhibit a uniform volatilization force as a liquid aromatic agent, .

Claims (13)

10 to 40% by weight of silicone oil;
10 to 40% by weight of a hydrocarbon oil;
10 to 40% by weight of a solvent for promoting the volatilization; And
10 to 35% by weight of a perfume. The liquid fragrance composition according to claim 1, wherein the silicone oil is at least one selected from the group consisting of normal siloxane, polydimethylsiloxane, and cyclosiloxane. 3. The liquid fragrance composition according to claim 2, wherein the normal siloxane is a disiloxane or trisiloxane and the polydimethylsiloxane is selected from the group consisting of decamethyltetrasiloxane, dodecamethylpentasiloxane and dimethicone. The liquid fragrance composition according to claim 2, wherein the cyclosiloxane is selected from the group consisting of dimethylcyclosiloxane, cyclopentasiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane and decamethylcyclohexasiloxane. The liquid fragrance composition according to claim 1, wherein the hydrocarbon oil is selected from alkanes, esters and mixtures thereof in branched form having from 8 to 16 carbon atoms. [6] The method of claim 5, wherein the alkane is at least one isoalkane selected from the group consisting of isodecane, isododecane and isohexadecane, and the ester is selected from the group consisting of isooctyl acetate, isohexyl acetate and isodecyl acetate ≪ / RTI > The liquid aromatic agent composition according to claim 1, wherein the solvent for promoting the volatilization is at least one alcohol-based solvent selected from glycol and diol. [3] The method of claim 1, wherein the solvent for promoting the volatilization is selected from the group consisting of ethanol, propylene glycol, dipropylene glycol, ethylene glycol, butylene glycol, dipropylene glycol methyl ether, diethylene glycol ethyl ether, dipropylene glycol methyl ether acetate, Is at least one member selected from the group consisting of ether, 1,2-hexanediol, propanediol, methylpropanediol and methoxymethylbutanol. The liquid fragrance composition according to claim 1, wherein the fragrance is selected from the group consisting of animal flavors, vegetable oils and aromatic compounds. The liquid perfume composition according to claim 1, wherein the liquid fragrance composition further comprises at least one selected from the group consisting of antioxidants, pigments, ultraviolet absorbers, and preservatives. Liquid fragrance composition; And
A container for receiving said liquid fragrance composition,
Characterized in that the liquid perfume composition comprises 10 to 40% by weight of silicone oil, 10 to 40% by weight of hydrocarbon oil, 10 to 40% by weight of a solvent for accelerating the oxidation and 10 to 35% Perfume kit. The container according to claim 11, characterized in that the container is provided with fine pores on one surface or a plurality of surfaces thereof or attached with an opening-and-closing lid so as to be able to diverge the fragrance and prevent the liquid- , A liquid perfume kit. 12. The liquid perfume kit of claim 11, wherein the liquid perfume kit further comprises a housing for receiving the container therein.

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