KR20120039077A - Eco-friendly yellow soil brick stone and manufacturing method the same - Google Patents
Eco-friendly yellow soil brick stone and manufacturing method the same Download PDFInfo
- Publication number
- KR20120039077A KR20120039077A KR1020100083388A KR20100083388A KR20120039077A KR 20120039077 A KR20120039077 A KR 20120039077A KR 1020100083388 A KR1020100083388 A KR 1020100083388A KR 20100083388 A KR20100083388 A KR 20100083388A KR 20120039077 A KR20120039077 A KR 20120039077A
- Authority
- KR
- South Korea
- Prior art keywords
- weight
- parts
- ocher
- eco
- brick
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
- C04B14/10—Clay
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/26—Carbonates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B16/00—Use of organic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of organic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B16/04—Macromolecular compounds
- C04B16/06—Macromolecular compounds fibrous
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/24—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
- C04B28/26—Silicates of the alkali metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B1/00—Producing shaped prefabricated articles from the material
- B28B1/26—Producing shaped prefabricated articles from the material by slip-casting, i.e. by casting a suspension or dispersion of the material in a liquid-absorbent or porous mould, the liquid being allowed to soak into or pass through the walls of the mould; Moulds therefor ; specially for manufacturing articles starting from a ceramic slip; Moulds therefor
- B28B1/265—Producing shaped prefabricated articles from the material by slip-casting, i.e. by casting a suspension or dispersion of the material in a liquid-absorbent or porous mould, the liquid being allowed to soak into or pass through the walls of the mould; Moulds therefor ; specially for manufacturing articles starting from a ceramic slip; Moulds therefor pressure being applied on the slip in the filled mould or on the moulded article in the mould, e.g. pneumatically, by compressing slip in a closed mould
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Civil Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
Description
본 발명은 친환경 황토벽돌 및 이의 제조방법에 관한 것으로, 보다 상세하게는 황토를 주성분으로 메타규산소다, 탄산칼륨, 구연산칼륨 및 붕사를 혼합하여 원적외선 및 음이온을 방출함으로써 인체 건강에 이롭고 환경 친화적인 건축용 자재로서 활용이 가능한 친환경 황토벽돌 및 이의 제조방법에 관한 것이다.The present invention relates to an eco-friendly ocher brick and a method for manufacturing the same. More specifically, it is beneficial to human health and environment-friendly construction by releasing far infrared rays and anions by mixing sodium silicate, potassium carbonate, potassium citrate, and borax with the main component of ocher. It relates to an eco-friendly ocher brick and a method of manufacturing the same that can be used as a material.
예로부터 우리 조상들은 황토를 이용하여 건축용 자재를 만들어 이용하였으며, 주로 벽과 벽돌에 많이 사용되어 왔다. 또한, 황토는 토기를 구워내는 원료로 사용되기도 하여 우리 생활의 일부를 차지하면서 자연 친화적 매개체 역할을 하여왔다. Since ancient times, our ancestors have made and used building materials using loess, and have been used for walls and bricks. In addition, ocher has been used as a raw material for burning earthenware, and has been a natural vehicle as a part of our lives.
현대에 들어 건축 분야는 편리성, 경제성 및 내구성 등의 이점으로 시멘트 및 각종 화학제품을 이용하게 되었고, 이들은 각종 환경공해를 유발하고 있다. 특히, 상기 시멘트 및 건축 자재용 화학제품은 포르말린 등의 유해 독성가스가 많이 발생하여 새집증후군으로 아토피성 피부염, 알러지 비염 등의 각종 질환을 야기하는 등의 인체에 유해한 문제점이 있다. In modern times, the construction field has been using cement and various chemical products due to convenience, economy and durability, which causes various environmental pollution. In particular, the cement and building material chemicals are harmful to the human body, such as causing a variety of diseases, such as atopic dermatitis, allergic rhinitis as a sick house syndrome due to the generation of harmful toxic gases such as formalin.
또한, 상기 시멘트를 재료로 한 벽돌은 고열로 제조하는 과정에서 대기 및 폐자재를 유발하는 환경 오염 문제가 있다. In addition, the cement-based brick has a problem of environmental pollution causing air and waste materials in the process of manufacturing at high heat.
반면, 황토는 인체 건강에 유익한 원적외선이 방출되고, 주거 공간 내에 각종 제품에서 발생하는 휘발성 유기화학물질을 제거하는 효과가 특출하여 쾌적한 주거생활공간을 위한 재료로 관심이 커지고 있다. On the other hand, ocher is released as far infrared rays beneficial to human health, and the effect of removing volatile organic chemicals generated from various products in the residential space is exceptional, and as a material for a comfortable living space is increasing.
그러나 황토를 상업적으로 대량생산하여 건축용 자재로 사용하기에 적합한 기술의 개발이 미비하여 용도가 제한적이며, 종래 황토가 갖고 있는 원적외선 방출, 탈취 및 혈액순환을 좋게 해주는 것 이상의 기능을 부여하기에 한계가 있는 문제점이 있다.However, due to the inadequate development of technology suitable for building materials by commercially mass-producing ocher, its use is limited, and there is a limit to imparting functions beyond the improvement of far-infrared emission, deodorization, and blood circulation of conventional ocher. There is a problem.
본 발명은 상기 종래 기술의 문제점을 해결하기 위한 것으로서 건축 산업 전반에 사용되고 있는 자재들의 환경 공해 및 인체에 해로운 물질로부터 보호할 수 있으며, 인체 건강에 유익한 친환경 황토벽돌 및 이의 제조방법을 제공하는 데 그 목적이 있다.The present invention is to solve the problems of the prior art and can protect from environmental pollution and materials harmful to the human body of materials used throughout the building industry, and to provide an eco-friendly ocher brick and a method of manufacturing the same that is beneficial to human health There is a purpose.
본 발명은 황토 100중량부에 대하여, 메타규산소다 40~60중량부, 탄산칼륨 45~70중량부, 구연산칼륨 1~4중량부, 붕사 1~3중량부 및 물 100~1000중량부를 포함하는 친환경 황토벽돌을 제공한다.The present invention contains 40 to 60 parts by weight of sodium metasilicate, 45 to 70 parts by weight of potassium carbonate, 1 to 4 parts by weight of potassium citrate, 1 to 3 parts by weight of borax and 100 to 1000 parts by weight of water. Provide eco-friendly ocher bricks.
또한, 본 발명은 불순물을 걸러낸 생황토를 분쇄하여 입도를 조절하는 황토 선별 단계; 황토 100중량부에 대하여, 메타규산소다 40~60중량부, 탄산칼륨 45~70중량부, 구연산칼륨 1~4중량부, 붕사 1~3중량부 및 물 100~1000중량부를 교반기에 넣고 교반 혼련하는 혼련 단계; 혼련된 혼합물을 금형 내에 충진하여 1~20㎏/㎠의 압력으로 성형하는 가압성형 단계; 및 성형된 벽돌을 상온 또는 50~600℃에서 수분을 제거하는 건조 단계; 를 포함하는 친환경 황토벽돌의 제조방법을 제공한다.In addition, the present invention is the ocher screening step of adjusting the particle size by grinding the raw ocher filter out the impurities; 40 to 60 parts by weight of sodium metasilicate, 45 to 70 parts by weight of potassium carbonate, 1 to 4 parts by weight of potassium citrate, 1 to 3 parts by weight of borax and 100 to 1000 parts by weight of water are added to a stirrer and stirred and kneaded. Kneading step; A press molding step of filling the kneaded mixture into a mold and molding at a pressure of 1 to 20 kg / cm 2; And drying step of removing the moisture at room temperature or 50 ~ 600 ℃ the molded brick; It provides a manufacturing method of eco-friendly ocher brick comprising a.
이하 본 발명을 상세히 설명하기로 한다.Hereinafter, the present invention will be described in detail.
본 발명에 따른 친환경 황토벽돌은 황토 100중량부에 대하여, 메타규산소다 40~60중량부, 탄산칼륨 45~70중량부, 구연산칼륨 1~4중량부, 붕사 1~3중량부 및 물 100~1000중량부를 포함한다. Eco-friendly ocher brick according to the present invention is based on 100 parts by weight of ocher, 40 to 60 parts by weight of sodium metasilicate, 45 to 70 parts by weight of potassium carbonate, 1 to 4 parts by weight of potassium citrate, 1 to 3 parts by weight of borax and 100 to water Contains 1000 parts by weight.
본 발명에서 사용하는 메타규산소다(Sodium meta silicate;Na2SiO3)는 알칼리 빌더로서 경도(硬度, 알카리성)과 pH를 높여서 요구되는 탄산칼슘의 사용량을 충분히 용해될 수 있도록 하고, 알칼리 조건을 유지하여 세정력을 강화하고 지방을 중화시켜 무취 상태로 유지하며, 계면활성력을 촉진하여 미생물의 침투력과 살균 효과를 상승시켜 주는 역할을 한다. 이때, 본 발명의 조성물에서 황토 100 중량부 기준으로 메타규산소다를 40 중량부 미만을 사용하면 상기 역할의 효과가 저감되고, 60 중량부를 초과하면 인체나 동물의 피부나 점막 또는 눈 등에 자극을 줄 수 있기 때문에, 상술한 범위 내에서 사용하는 것이 바람직하다.Sodium meta silicate (Na 2 SiO 3 ) used in the present invention is an alkali builder to increase the hardness (alkalineity) and pH, so that the required amount of calcium carbonate can be sufficiently dissolved, maintaining the alkaline conditions It enhances cleansing power, neutralizes fat, keeps it odorless, and promotes surface active power to increase microbial penetration and sterilization effect. At this time, the use of less than 40 parts by weight of sodium metasilicate based on 100 parts by weight of ocher in the composition of the present invention, the effect of the role is reduced, if more than 60 parts by weight give irritation to the skin or mucous membranes or eyes of the human body or animal Since it can be used, it is preferable to use within the range mentioned above.
본 발명에서 사용하는 탄산칼륨(Potassium carbonate;K2CO3)는 백색분말 형태의 알칼리 소독제로서, 악취를 발생하거나 질병을 전염하는 바이러스나 세균 등을 소독하여 제거하는 역할을 하며, 황토 100 중량부 기준으로 45 중량부 미만을 사용하면 상술한 소독 효과가 저감되고 70 중량부를 초과하면 인체나 동물의 피부나 점막 또는 눈 등에 자극을 줄 수 있기 때문에, 상술한 범위 내에서 사용하는 것이 바람직하다.Potassium carbonate (K 2 CO 3 ) used in the present invention is an alkali disinfectant in the form of a white powder, and serves to disinfect and remove viruses or bacteria that cause odors or transmit diseases, and 100 parts by weight of ocher. If less than 45 parts by weight is used as a reference, the above-described disinfection effect is reduced, and if it is more than 70 parts by weight, it may cause irritation to the skin, mucous membranes or eyes of a human body or an animal, and therefore it is preferable to use within the above-mentioned range.
본 발명에서 사용하는 구연산칼륨(Potassium citrate; C6H5K3O7)은 탄산칼륨과 함께 칼륨이 이온화되면서 경도를 높이고, 자체의 살균 작용으로 소독 효과를 보다 상승시키며, 건축 기재가 부식되는 것을 방지하고, 탄산칼륨과 메타규산소다의 사용으로 인하여 지나치게 조성물이 알카리화되는 것을 억제해 주는 pH 조절제의 역할을 한다. 이때, 본 발명의 조성물에서 황토 100 중량부 기준으로 구연산칼륨을 1 중량부 미만으로 사용하면 상술한 효과가 미미하고, 4 중량부를 초과하여 사용하면 초과 사용량에 비하여 효과가 미미하고 오히려 충분히 용해되지 않아 침전되어 조성물이 탁하게 되는 문제점이 발생할 수 있기 때문에, 상술한 범위 내에서 사용하는 것이 바람직하다.Potassium citrate (C 6 H 5 K 3 O 7 ) used in the present invention increases the hardness as potassium is ionized together with potassium carbonate, and further increases the disinfection effect by its sterilization action, the building substrate is corroded And the use of potassium carbonate and sodium metasilicate to act as a pH adjuster to prevent excessive alkalinization of the composition. At this time, when the potassium citrate is used in an amount of less than 1 part by weight based on 100 parts by weight of ocher in the composition of the present invention, the above-mentioned effect is insignificant, and when used in excess of 4 parts by weight, the effect is insignificant compared to the amount of excess used and is not sufficiently dissolved. The problem of precipitation and turbidity of the composition may occur, so it is preferable to use it within the above-mentioned range.
본 발명에서 사용하는 붕사(Borex;Na2B4O7)는 살균 및 방부의 역할을 하여, 유기성 폐기물을 분해하는 미생물을 소독하거나 유기성 폐기물를 방부하여 부패되지 않게 하여 악취를 억제하고 지방과 유분을 유화하여 지방의 산화로 인한 악취를 방지하는 역할을 하는데, 본 발명의 조성물에서는 황토 100 중량부 기준으로 1 중량부 미만을 사용하면 상술한 효과를 달성할 수 없고, 3 중량부를 초과하여 사용하면 충분히 용해되지 않고 침전되어 조성물이 탁해질 수 있기 때문에, 상술한 범위 내에서 사용하는 것이 바람직하다.Borax (Borex; Na 2 B 4 O 7 ) used in the present invention acts as a sterilization and antiseptic, so as to disinfect microorganisms that decompose organic waste or to prevent organic waste to decay to suppress odors and to reduce fat and oil By emulsifying to prevent odor due to oxidation of fat, in the composition of the present invention using less than 1 part by weight based on 100 parts by weight of ocher can not achieve the above-mentioned effect, if used in excess of 3 parts by weight It is preferable to use within the above-mentioned range because it may precipitate without dissolving and turbidity of the composition.
이와 같이, 본 발명에서 사용되는 조성물은 칼륨염을 위주로 사용하여 구성 성분 간에 서로 반응이 잘 되도록 유도하고, 이로써 황토벽돌로 성형할 때, 원적외선 및 음이온이 방출이 원활할 수 있도록 하여 인체에 유익할 수 있는 친환경 건축자재용으로 사용할 수 있도록 한다. As described above, the composition used in the present invention is mainly used in the potassium salt to induce a good reaction between the constituents, and thus when molded into ocher brick, far infrared rays and anions can be released to facilitate the human body It can be used for eco-friendly building materials.
또한, 본 발명의 친환경 황토벽돌은 질산은(Silver nitrate ; AgNO3)과 염화금(Gold chloride ; AuCl)을 추가로 포함할 수 있다. 상기 질산은 및 염화금은 성분 자체가 물에서 이온화되어 은과 금을 석출하고, 이들은 살균 효과와 악취를 분해하는 기능을 가지고 있어 종래 건축자재들을 대체함에 있어 인체에 보다 유익할 수 있는 기능성을 부여할 수 있다. 상기 질산은 및 염화금은 병용하여 사용하는 것이 더욱 바람직하다. 이때, 질산은 및 염화금, 각각 황토 100중량부에 대하여 0.03~0.04 중량부를 사용하는 것이 바람직하다. 상기 함량의 범위가 0.03 중량부 미만이면 기대하는 효과를 볼 수 없고, 0.04 중량부 초과이면 효과가 미미하다. In addition, the eco-friendly ocher brick of the present invention may further include silver nitrate (AgNO 3 ) and gold chloride (AuCl). The silver nitrate and silver chloride components themselves are ionized in water to precipitate silver and gold, and they have a bactericidal effect and a function of decomposing odors, thereby imparting more functional benefits to the human body in replacing conventional building materials. have. It is more preferable to use the said silver nitrate and gold chloride together. In this case, it is preferable to use 0.03 to 0.04 parts by weight of silver nitrate and gold chloride, respectively, based on 100 parts by weight of ocher. If the range of the content is less than 0.03 parts by weight, the expected effect is not seen, if the amount is more than 0.04 parts by weight, the effect is insignificant.
또한, 본 발명은 황토 100중량부에 대하여 수지코팅제 1~20중량부를 더 포함하는 것을 특징으로 한다. 상기 수지코팅제는 가공성을 향상시키기 위한 것으로, 상기 범위를 벗어나면, 성형 가공성을 수월하게 하는 효과를 보기 어렵고, 크랙이 생기거나 물에 의해 분해될 수 있다. 이때 사용되는 수지코팅제는 멜라민계 수지, 우레아계 수지, 페놀계 수지 또는 에폭시계 수지 중에서 선택된 어느 하나의 수지를 사용한 것을 특징으로 한다.
In addition, the present invention is characterized in that it further comprises 1 to 20 parts by weight of the resin coating agent with respect to 100 parts by weight of ocher. The resin coating agent is to improve the processability, if outside the above range, it is difficult to see the effect of facilitating molding processability, cracks may be generated or may be decomposed by water. The resin coating agent used at this time is characterized by using any one resin selected from melamine resin, urea resin, phenol resin or epoxy resin.
본 발명은 친환경 황토벽돌 제조방법에 있어서,The present invention in the eco-friendly ocher brick manufacturing method,
불순물을 걸러낸 생황토를 분쇄하여 입도를 조절하는 황토 선별 단계;Ocher sorting step of controlling the particle size by grinding the raw ocher filtered out impurities;
황토 100중량부에 대하여, 메타규산소다 40~60중량부, 탄산칼륨 45~70중량부, 구연산칼륨 1~4중량부, 붕사 1~3중량부 및 물 100~1000중량부를 교반기에 넣고 교반 혼련하는 혼련 단계;40 to 60 parts by weight of sodium metasilicate, 45 to 70 parts by weight of potassium carbonate, 1 to 4 parts by weight of potassium citrate, 1 to 3 parts by weight of borax and 100 to 1000 parts by weight of water are added to a stirrer and stirred and kneaded. Kneading step;
혼련된 혼합물을 금형 내에 충진하여 1~20㎏/㎠의 압력으로 성형하는 가압성형 단계;A press molding step of filling the kneaded mixture into a mold and molding at a pressure of 1 to 20 kg / cm 2;
성형된 벽돌을 상온 또는 50~600℃에서 수분을 제거하는 건조 단계;Drying step of removing the moisture in the molded brick at room temperature or 50 ~ 600 ℃;
를 포함하는 것을 특징으로 하는 친환경 황토벽돌 제조방법을 제공한다.It provides an environmentally friendly ocher brick manufacturing method comprising a.
상기 친환경 황토벽돌 제조방법은 공정을 단순화하였기 때문에 제조비용의 절감을 가져올 수 있는 이점이 있다.The eco-friendly ocher brick manufacturing method has an advantage of reducing the manufacturing cost because the process is simplified.
상기 친환경 황토벽돌 제조방법에 의하여 제조된 황토벽돌은 다양한 분야에서 건축자재 등으로 이용되어 원적외선과 음이온이 다량 방출되는 황토의 이점과 함께 인체에 유해할 수 있는 오염물질로부터 건강한 환경을 지켜낼 수 있는 친환경 공간을 제공할 수 있게 된다.The ocher brick manufactured by the eco-friendly ocher brick manufacturing method can be used as a building material in various fields to protect a healthy environment from pollutants that may be harmful to the human body with the advantage of ocher that far infrared rays and negative ions are released. It will be able to provide an eco-friendly space.
이상에서 설명한 바와 같이, 본 발명에 따른 친환경 벽돌은 건축 산업 현장의 다양한 분야에서 사용되는 건축 자재로 사용됨에 있어서, 원적외선과 음이온이 다량 방출될 뿐만 아니라, 인체에 안정하고 무해하여 주거환경을 보다 쾌적하고 건강하게 유지할 수 있으며, 악취 제거 및 소독 효과를 나타낼 수 있다. 또한, 본 발명의 친환경 황토 벽돌의 제조방법은 공정이 간단하여 대량생산이 가능하고, 제조 비용을 절감할 수 있는 이점이 있다.As described above, the eco-friendly brick according to the present invention is used as a building material used in various fields of the construction industry site, not only emits a large amount of far infrared rays and anions, but also is stable and harmless to the human body to make the living environment more comfortable. It can keep healthy and healthy, and it can remove odor and disinfect. In addition, the manufacturing method of eco-friendly ocher brick of the present invention has the advantage that the process is simple, mass production is possible, and the manufacturing cost can be reduced.
이하, 본 발명을 실시예에 의해 상세히 설명한다.Hereinafter, the present invention will be described in detail by way of examples.
단, 하기 실시예는 본 발명을 예시하는 것일 뿐, 본 발명의 내용이 하기 실시예에 의해 한정되는 것은 아니다.
However, the following examples are merely to illustrate the invention, but the content of the present invention is not limited by the following examples.
[실시예 1]Example 1
불순물을 제거한 생황토를 분쇄기를 이용하여 ?~?의 입도를 갖도록 조절한 순수한 황토 100kg을 준비하였다. 상기 황토와 90℃ 이상으로 가열한 물 100ℓ에 메타규산소다(Na2SiO3) 45kg을 투입하여 균일하게 용해하고, 상기 용액에 탄산칼륨(K2CO3) 50kg을 투입하고 용해한 다음, 구연산칼륨(C6H5K3O7) 2kg을 투입하여 다시 균일하게 용해하고, 붕사(Na2B4O7) 1.33kg를 투입하여 교반기에 넣고 교반 혼련함으로써 완전히 용해시킨 후, 이를 100×25×20㎜의 규격의 금형에 충진하여 1~20㎏/㎠의 압력으로 성형하고, 상온에서 건조하여 친환경 황토 벽돌을 제조할 수 있었다.
100 kg of pure ocher was prepared by adjusting the raw ocher from which impurities were removed to have a particle size of? ~ ?. 45 kg of sodium metasilicate (Na 2 SiO 3 ) was added and dissolved uniformly in 100 l of water heated to 90 ° C. or higher, and dissolved in 50 kg of potassium carbonate (K 2 CO 3 ). 2 kg of (C 6 H 5 K 3 O 7 ) was added to dissolve uniformly again, and 1.33 kg of borax (Na 2 B 4 O 7 ) was added to the stirrer to completely dissolve by stirring and kneading, and then 100 × 25 × Filled in a 20 mm mold and molded at a pressure of 1 ~ 20 kg / ㎠, dried at room temperature it could be produced eco-friendly ocher bricks.
[실시예 2][Example 2]
상기 실시예 1과 동일한 방법으로 순수한 황토 100kg과 90℃ 이상으로 가열한 물 100ℓ에 메타규산소다) 45 kg, 탄산칼륨 50 kg, 구연산칼륨 2 kg, 붕사 1.33 kg을 교반기에 넣고, 추가로 염화금(AuCl) 0.033g을 투입하여 교반 혼련함으로써 완전히 용해시킨 후, 이를 100×25×20㎜의 규격의 금형에 충진하여 1~20㎏/㎠의 압력으로 성형하고, 상온에서 건조하여 친환경 황토 벽돌을 제조할 수 있었다.
45 kg of sodium metasilicate), 50 kg of potassium carbonate, 2 kg of potassium citrate, and 1.33 kg of borax were put into a stirrer in 100 kg of pure ocher and 100 l of water heated to 90 ° C. or more in the same manner as in Example 1, and further, gold chloride ( AuCl) 0.033g was added to dissolve completely by stirring and kneading, and then it was filled into a mold of 100 × 25 × 20 mm and molded at a pressure of 1-20 kg / cm 2, and dried at room temperature to produce eco-friendly ocher bricks. Could.
[실시예 3]Example 3
상기 실시예 1과 동일한 방법으로 순수한 황토 100kg과 90℃ 이상으로 가열한 물 100ℓ에 메타규산소다) 45 kg, 탄산칼륨 50 kg, 구연산칼륨 2 kg, 붕사 1.33 kg을 교반기에 넣고, 추가로 염화금(AuCl) 0.033g 및 질산은(AuCl) 0.033g을 투입하여 교반 혼련함으로써 완전히 용해시킨 후, 이를 100×25×20㎜의 규격의 금형에 충진하여 1~20㎏/㎠의 압력으로 성형하고, 상온에서 건조하여 친환경 황토 벽돌을 제조할 수 있었다.
45 kg of sodium metasilicate), 50 kg of potassium carbonate, 2 kg of potassium citrate, and 1.33 kg of borax were put into a stirrer in 100 kg of pure ocher and 100 l of water heated to 90 ° C. or more in the same manner as in Example 1, and further, gold chloride ( AuCl) 0.033g and silver nitrate (AuCl) 0.033g were completely dissolved by stirring and kneading, and then filled into a mold having a size of 100 × 25 × 20 mm, and molded at a pressure of 1-20 kg / cm 2 and at room temperature. By drying it was possible to produce eco-friendly ocher bricks.
이상과 같이 본 발명의 실시예는 본 발명의 보다 전반적인 이해를 돕기 위한 것으로, 본 발명이 상기 실시예에 한정되는 것이 아니며, 본 발명이 속하는 분야에서 통상의 지식을 가진 자라면 이러한 기재로부터 다양한 수정 및 변형이 가능하다. 따라서, 본 발명의 사상은 설명된 실시예에 국한되어 정해져서는 아니되며, 후술하는 특허청구범위뿐 아니라 이 특허청구범위와 균등하거나 등가적 변형이 있는 모든 것들은 본 발명 사상의 범주에 속한다고 할 것이다.As described above, the embodiments of the present invention are intended to help a more general understanding of the present invention, and the present invention is not limited to the above embodiments, and those skilled in the art to which the present invention pertains various modifications from these descriptions. And variations are possible. Therefore, the spirit of the present invention should not be limited to the described embodiments, and all of the equivalents or equivalents of the claims as well as the claims to be described later will belong to the scope of the present invention. .
Claims (6)
메타규산소다 40~60중량부, 탄산칼륨 45~70중량부, 구연산칼륨 1~4중량부, 붕사 1~3중량부 및 물 100~1000중량부를 포함하는 친환경 황토벽돌.Per 100 parts by weight of ocher,
Eco-friendly ocher brick comprising 40 to 60 parts by weight of sodium metasilicate, 45 to 70 parts by weight of potassium carbonate, 1 to 4 parts by weight of potassium citrate, 1 to 3 parts by weight of borax and 100 to 1000 parts by weight of water.
황토 100중량부에 대하여 질산은(Siver nitrate) 0.03~0.04 중량부를 더 포함하는 것을 특징으로 하는 친환경 황토벽돌.The method of claim 1,
Eco-friendly ocher brick, characterized in that it further comprises 0.03 ~ 0.04 parts by weight of silver nitrate (Siver nitrate) with respect to 100 parts by weight of ocher.
황토 100중량부에 대하여 염화금(Gold chloride) 0.03~0.04 중량부를 더 포함하는 것을 특징으로 하는 친환경 황토벽돌.The method of claim 1,
Eco-friendly ocher brick, characterized in that it further comprises 0.03 ~ 0.04 parts by weight of gold chloride (Gold chloride) based on 100 parts by weight of ocher.
황토 100중량부에 대하여 수지코팅제 1~20중량부를 더 포함하는 것을 특징으로 하는 친환경 황토벽돌.The method of claim 1,
Eco-friendly ocher brick, characterized in that it further comprises 1 to 20 parts by weight of the resin coating agent with respect to 100 parts by weight of ocher.
상기 수지코팅제는 멜라민계 수지, 우레아계 수지, 페놀계 수지 또는 에폭시계 수지 중에서 선택된 어느 하나인 것을 특징으로 친환경 황토벽돌.The method of claim 4, wherein
The resin coating agent is an environmentally friendly ocher brick, characterized in that any one selected from melamine resin, urea resin, phenol resin or epoxy resin.
황토 100중량부에 대하여, 메타규산소다 40~60중량부, 탄산칼륨 45~70중량부, 구연산칼륨 1~4중량부, 붕사 1~3중량부 및 물 100~1000중량부를 교반기에 넣고 교반 혼련하는 혼련 단계;
혼련된 혼합물을 금형 내에 충진하여 1~20㎏/㎠의 압력으로 성형하는 가압성형 단계;
성형된 벽돌을 상온 또는 50~600℃에서 수분을 제거하는 건조 단계;
를 포함하는 것을 특징으로 하는 친환경 황토벽돌 제조방법.Ocher sorting step of controlling the particle size by grinding the raw ocher filtered out impurities;
40 to 60 parts by weight of sodium metasilicate, 45 to 70 parts by weight of potassium carbonate, 1 to 4 parts by weight of potassium citrate, 1 to 3 parts by weight of borax and 100 to 1000 parts by weight of water are added to a stirrer and stirred and kneaded. Kneading step;
A press molding step of filling the kneaded mixture into a mold and molding at a pressure of 1 to 20 kg / cm 2;
Drying step of removing the moisture in the molded brick at room temperature or 50 ~ 600 ℃;
Eco-friendly ocher brick manufacturing method comprising a.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020100083388A KR101138285B1 (en) | 2010-08-27 | 2010-08-27 | eco-friendly yellow soil brick stone and manufacturing method the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020100083388A KR101138285B1 (en) | 2010-08-27 | 2010-08-27 | eco-friendly yellow soil brick stone and manufacturing method the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20120039077A true KR20120039077A (en) | 2012-04-25 |
| KR101138285B1 KR101138285B1 (en) | 2012-07-11 |
Family
ID=46139506
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020100083388A KR101138285B1 (en) | 2010-08-27 | 2010-08-27 | eco-friendly yellow soil brick stone and manufacturing method the same |
Country Status (1)
| Country | Link |
|---|---|
| KR (1) | KR101138285B1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101401445B1 (en) * | 2013-01-23 | 2014-05-30 | 주식회사 에이유 | Composition for reducing volatile organic compounds and preparation method thereof |
| CN109251003A (en) * | 2018-11-23 | 2019-01-22 | 黄河勘测规划设计有限公司 | Non-burning brick method is prepared using shale Extra-fine sand |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20220158420A (en) | 2021-05-24 | 2022-12-01 | 윤영서 | An Energy Bar Marine Ecosystem |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100420400B1 (en) | 2001-04-30 | 2004-03-04 | (주)이인 | Multi-functional material emitting far-infrared ray in aqueous phase and the use thereof |
| KR100804731B1 (en) | 2006-11-21 | 2008-02-19 | 김명자 | The production method of building materials and vessels using environment-friendly yellow earth |
| KR100943096B1 (en) | 2009-07-09 | 2010-02-18 | 장현진 | Multifunctional binder composition using paper ash |
-
2010
- 2010-08-27 KR KR1020100083388A patent/KR101138285B1/en not_active IP Right Cessation
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101401445B1 (en) * | 2013-01-23 | 2014-05-30 | 주식회사 에이유 | Composition for reducing volatile organic compounds and preparation method thereof |
| CN109251003A (en) * | 2018-11-23 | 2019-01-22 | 黄河勘测规划设计有限公司 | Non-burning brick method is prepared using shale Extra-fine sand |
| CN109251003B (en) * | 2018-11-23 | 2021-06-29 | 黄河勘测规划设计研究院有限公司 | Method for preparing baking-free brick by using argillaceous powder fine sand |
Also Published As
| Publication number | Publication date |
|---|---|
| KR101138285B1 (en) | 2012-07-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR101508438B1 (en) | a environment-friendly Functional wallpaper adhesive composite and manufacturing method | |
| KR101138285B1 (en) | eco-friendly yellow soil brick stone and manufacturing method the same | |
| KR100643509B1 (en) | Natural chlorinated composition using natural mineral and plant material | |
| KR101997101B1 (en) | Yellow soil brick composition and the saidmanufacturing process | |
| CN106927740A (en) | A kind of nano-far-infrared diatom ooze feature wall wall material | |
| KR101246849B1 (en) | Minerals aqueous solution and its manufacturing method | |
| CN106268295A (en) | A kind of automotive trim environmental pollution scavenger | |
| KR20080004938A (en) | Method of producing functional cement mortar and the functional cement mortar produced by the method | |
| JP5940047B2 (en) | Waste water purification material | |
| KR100939069B1 (en) | Artificial stone composition and method of making thesame | |
| KR100861085B1 (en) | Coating material possible to emit negative ion and its manufacturing method | |
| KR20160125316A (en) | Silica as a main component Sanitary manufacturing method using the antibacterial composition of matter and their composite material | |
| KR20120006668A (en) | Manufacturing method of a paint comprising natural mineral | |
| KR20230099308A (en) | manufacturing method of composition for deodorization using mineral | |
| WO2017203299A1 (en) | Self-sanitising compositions and method for the production thereof | |
| CN102992435A (en) | Organic-inorganic composite adsorptive rural well water disinfecting ceramic chip | |
| KR101872347B1 (en) | Pellet composition for eco-friendly green tide and red tide removal and method for producing the same | |
| KR100879178B1 (en) | Deodorizer and method for production thereof | |
| KR101069808B1 (en) | Loess brick | |
| KR20220032955A (en) | Method for preparing composition for antibacterial deodorization and neutralizing harmful substances to human body | |
| CN1903736A (en) | Compounding method of composite water quality purifier having disinfectant, deodour, water purifying three in one action for aquaculture | |
| KR100808127B1 (en) | Firing object activating body and plant | |
| KR20190131298A (en) | A Composition of Building Materials Containing Diatomite and illite | |
| KR101274581B1 (en) | Method for manufacturing a liquid deodorant containing sericite ingredient, and a liquid deodorant produced thereby | |
| CN103503878A (en) | Production method for smog bane |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A201 | Request for examination | ||
| E701 | Decision to grant or registration of patent right | ||
| GRNT | Written decision to grant | ||
| FPAY | Annual fee payment |
Payment date: 20180111 Year of fee payment: 6 |
|
| R401 | Registration of restoration | ||
| LAPS | Lapse due to unpaid annual fee |