KR100861085B1 - Coating material possible to emit negative ion and its manufacturing method - Google Patents

Abstract

A coating material capable of emitting anions is provided to emit anions and far infrared rays, to control humidity control ability, and to perform deodorant and antimicrobial actions. A method for preparing a coating material capable of emitting anions includes the steps of: (i) mixing 100 parts by weight of a tourmaline mineral having an ionic catalyst function when a hydroxyl group acts, with 44.4-51.9 parts by weight of an alkaline water to prepare a wet tourmaline; (ii) mixing titanium dioxide with a rare earth mineral of Ce^(3+) or Ce^(4+) to prepare a titanium dioxide mixture; and (iii) mixing the wet tourmaline of the step (i) with the titanium dioxide mixture of the step (ii).

Description

Anion-releasing coating agent and its manufacturing method {coating material possible to emit negative ion and its manufacturing method}

The present invention relates to a coating that releases anions and a method for producing the same.

In particular, among the products that anion and far-infrared radiation artificially for the purpose of health promotion, a small number of products are known to generate cations and ozone. Excessive cations and ozone are not suitable for household goods because they cause mucosal coagulation, lung cells and respiratory disorders, and they show satisfactory performance in recent environmentally friendly, bio, deodorizing and antibacterial properties. I can't

In addition, most of the products that generate negative ions can only emit negative ions, and furthermore, artificially generated electrical products have drawbacks that inevitably involve electrical energy consumption.

On the other hand, there is a building finish using tourmaline that releases anions, but this finish has the disadvantage of preventing the natural release of anions by preventing hydroxylation by depositing an inorganic adhesive that can not control moisture on the surface

In addition, the applied tourmaline-containing products used in daily household products are mixed with a high molecular material such as silicone to prevent the natural release of the anion and only negative ion radiation has the disadvantage of lowering the intrinsic efficacy of the tourmaline.

The present invention is to solve the above-mentioned conventional problems, rare earth of the anion-releasing silicate ore (Toumaline), photon catalyst and titanium dioxide (Nano-Tion) having a sterilizing function, Ce ³⁺ or Ce ⁴⁺ By mixing minerals in a certain ratio, we developed a coating agent that synergistically improves the release ability of anions, etc., which is beneficial to human body.

The main constitution of the method for producing an anion release coating agent of the present invention comprises the steps of: (1) preparing a wet tourmaline by mixing 100 parts by weight of tourmaline mineral having an ion catalytic function and 44.4-51.9 parts by weight of alkaline water when a hydroxyl group is acted on; (2) Titanium dioxide mixture production process of mixing titanium dioxide and rare earth minerals of Ce ³⁺ or Ce ⁴⁺ ; And (3) mixing the wet tourmaline of step (1) and the titanium dioxide mixture of step (2), wherein the alkaline water is at a pH of 8-10. The rare earth mineral of titanium and Ce ³⁺ or Ce ⁴⁺ is characterized in that the mixing ratio is 50:50 by weight, and in the process of mixing the wet tormarin and the titanium dioxide mixture, the wet tormarin and titanium dioxide mixture Silver by weight ratio of 50:50, the anionic release coating agent of the present invention, 100 parts by weight of tourmaline, 35-60 parts by weight of water, 65-85 parts by weight of titanium dioxide, rare earth of Ce ³⁺ or Ce ⁴⁺ It is characterized in that it comprises 65-85 parts by weight of minerals, the water is characterized in that the alkaline water of pH 8-10

The coating agent according to the present invention can perform anion release and radiation, far-infrared radiation, humidity control ability and deodorizing action of the coating agent itself, antibacterial action.

It also deodorizes volatile organic compounds in indoor air, such as formaldehyde odors and odors, to purify and clean surrounding air.

Commonly used grain husks, for example, general buckwheat husk is not breathable because it is difficult to long-term storage due to the development of bacteria, mold, secondary, but the coating is applied to the grain husk in accordance with the present invention, the film quality is formed It is not breathable and does not rot for long-term storage and use. In the buckwheat shell, etc. treated with the coating agent according to the present invention, microparasites such as mites, moths, head lice do not live, and prevent mold from occurring in general grain shells.

When coating the grains using the coating agent according to the present invention, by utilizing the shells of buckwheat, such as buckwheat was discarded by conventional storage and use to replace the acrylic cotton used as a material of various household goods to reduce acrylic cotton production raw materials There is effect

In addition, it can be used as a coating material for interior materials, finishing materials in the construction field, or coating materials for finishing materials.

The present invention will be further described below.

First, the reaction scheme of generating anion in the coating agent of the present invention will be described in detail.

When silicate ore tourmaline (Toumaline) and alkaline aqueous solution are mixed with an ion catalyst function and having a permanent electrode (per-manent element) as a spontaneous electrode, dissociation phenomenon occurs in the first step by the aqueous solution.

The formula of silicate ore toumaline is XY ₃ Z ₆ [Si ₆ O ₁₈ ] [BO ₃ ] ₃ (O, OH, F) _{4 in the} double: X = Ca, K, Na: Y = Fe ²⁺ , Mg ²⁺ , Al, Li, Fe ³⁺ , Mn ²⁺ : Z = Al, Cr ³ , Fe ³⁺ . The surface hydroxylated by the reaction of Na +, Mg ²⁺ , Fe ²⁺ , Fe ³⁺ , B ³⁺ with water on a large amount of mineral destruction surface of finely ground Toumaline has an anion. By attracting cations in the surrounding water or air, the anion concentration becomes high. H ₂ O comes out of negative ions and hydrogen by tourmaline metal ion and permanent electrode.

The scheme is 2H ₂ O + e → H ₃ O _2- + ½H ₂ . Thus, tourmaline is called an ion catalyst. Alkaline water (Alkali Water): H ₂ O the H ⁺ and OH ^- are dissociated into H ⁺ is when the H ₂ receives the most ^e-OH-portion of which is combined with cations in the water and the other is OH ^- are left in.

Reaction of O ₂

O ₂ + e → O ₂ ......................................... ...(One)

O ₂ + 3e + 3H ⁺ → OH + H ₂ O ... (2)

O ₂ ⁺ 4e + 3H + → and _{^{OH - + H 2 O .......................... (}} 3)

O ₂ + 4e + 4H ⁺ → 2H ₂ O ... (4)

Reaction of H ₂ O

H ₂ O + e → and H + OH ^- ..................................... (5 )

H ₂ O + e → and ^{OH + H + 2e → OH -} + H + + e ........... (6)

Or H ⁺ + e → H 2 · H → H ₂ ↑ ..... (7)

ㆍ H + .OH → O + H ₂ O ....................... (8)

O + ・ OH → H + O ₂ ↑ .................. (9)

Ion-Up Catalyst Reaction of O ₂ , H ₂ O

In formula (2) + (6) * 3, 6 electrons

2H ₂ O + O ₂ + 6e → 4OH + 6e ......... (10)

In formula (3) + (6) * 3, 7 electrons

_{2H 2 O + O 2 + 7e} → 4OH - + 3e ...................... (11)

As shown in Eqs. (10) and (11), two strong H ₂ O, one O _2, and six electrons result in four strong free radicals and seven electrons give four anions. Ion-Up Catalytic Reaction of Titanium Dioxide (Nano-TiO ₂ ), Ce ³⁺ and Ce ⁴⁺ with Photocatalytic Function

2TiO ₂ + hυ → 2TiO ₂ + O ₂ ........................................ (12)

^{_{O 2 + e - → O 2}} - ......................................... (13)

2H ₂ O + hυ → O ₂ + 4H + 4e ....................... (14)

Ce ⁴⁺ + O2 → Ce ³⁺ + O ₂ ............. (15)

And Ce ³⁺ + ^{OH → Ce 4+ + OH - .............................} (16)

Equation (13), (14), (15), (16) gives the following equation.

^{_{H 2 O → OH - + H}} + ......................................... (17)

2H ⁺ + 2e → H ₂ ......................... ( 18)

Part is OH ^- is also ⁺ H + → H ₂ O.

As shown in the above scheme, the composition of rare earth minerals such as toumaline, titanium dioxide (Nano-TiO ₂ ), Ce ³⁺ and Ce ⁴⁺ is reacted with water, air, and ascending dissociation to a minimum mass. It releases the maximum amount of negative ions continuously.

Furthermore, environmental sciences contain trace amounts of metal ions and rare earth ions in water, air, and the earth, and these are found to be helpful for air purification.The reaction of photons → electrons → excited molecules → anions is a reaction between metal ions and rare earths. As the ions act as a catalyst, the reaction circulates permanently and releases anions and acts as a photon catalyst. Also, the ion catalyst composition composed of natural minerals has a high permeability and high energy, and disperses the anions to a distant place.

As shown in Table 1 below, the ion catalyst composition (Toumaline + Moisture + Rare Earth Minerals of Nano-TiO ₂ + Ce ³⁺ and Ce ⁴⁺ ) is cross-catalyzed to produce higher yields than those produced by natural minerals. Is measured.

       Material name   Ion production ion / cm 3 Nano-Tio ₂      150      Toumaline      550 Rare Earth Minerals of Ce ³⁺ and Ce ⁴⁺     4700    Ion Catalyst Composition     9960

By using the composition prepared in the present invention in a minimal amount of building finishing materials or daily necessities, the negative ions are released semi-permanently to have the following effects.

(1) Change the air by increasing the negative ions.

_{2H 2 O + O 2 + 4e} → 4OH -

(2) Since the negative ions in the indoor space are always full, this purifies the air.

NOX + SO ₂ + NH ₃ + hv → (NH ₄ ) SO ₄ 2NH ₄ NO ₃

(3) This promotes the growth of photosynthetic plants.

2H ₂ O + hv → O ₂ + 4H ⁺ + 4e

CO ₂ + O ₂ + 4H ⁺ + 4e → C (H ₂ O) ₂ + O ₂

(4) It has the effect of making the environment beneficial to human body, antibacterial function and volatile organic compounds (VOC) in the indoor space by photon catalyst and deodorizing.

Hereinafter, the present invention will be described in detail with reference to specific examples.

(1) 1st wet tourmaline preparation

First, based on 100 parts by weight of tourmaline mineral, 44.4-51.9 parts by weight of water, preferably 48.1 parts by weight is mixed. For water, use alkaline water of pH 8-10. As a result, the hydroxylation action leads to the reaction of the primary ion catalyst. The amount and pH of alkaline water (water) can be adjusted appropriately depending on the water content of tourmaline itself.

The tourmaline used in the present invention has an ion catalytic function among various minerals emitting anions, and has a permanent nationwide as a spontaneous electrode. The chemical component is a complex borosilicate of aluminum, iron, magnesium, alkali metal and the like. Electricity is generated by friction, and this name is given because both ends are charged positively and negatively when heated.

Known major effects of tourmaline, known to naturally release anions with ion catalysis, are:

-Water quality improvement

Weak alkaline (optimum PH7.4), subdividing clusters of water (molecular population),

Contains minerals, bactericidal effect, deodorant effect, removes chlorine odor

-Health Improvement

Negative ions are good for skin with excellent metabolism, cell function, immune function activation, blood purification, autonomic nerve stabilization, penetration, wetting and moisturizing effect.

-Environmental improvement

Significantly reduced foreign matters and odors in drains, water is good for cleaning, reducing detergent usage, removing pet odors and promoting plant growth

-Effect in life

When you put tourmarin in your bathtub or washbasin, you'll feel warm even at low temperatures. Appetite increased. My shoulders have softened Atopy improved. Athlete's foot was cured. The skin is smooth. The smell is gone. I have asthma. The bathtub does not get dirty. The smell of the drain is gone.

-In the drink

Tea and coffee taste better. The smell of the mouth is gone. Appetite increased. Constipation is gone. Chlorine odor has been removed.

-Smelly places

The smell of the refrigerator is removed. The smell of the bed disappears. The smell of cigarettes and mold disappears.

-Used for cleaning

Even with less detergent, the washing effect is the same. Mold did not fall well fell off. The contact lens and glasses were cleaned well.

-For use in aquariums or ponds

Goldfish and tropical fish do not get dirty. The unpleasant smell went away. Used for any fish (fresh water, saltwater) Pond odors disappeared and the water became clear.

-Used for flowerbed vases

Flowers last long Water does not rot The growth of plants is fast. The color of the flower is vivid. Pests disappear. Vegetables grow very well. Rice, vegetables and fruits taste good

(2) secondary rare earth mineral mixtures

And a mineral powder mixture prepared by mixing rare earth minerals of titanium dioxide, Ce ³⁺ and Ce ⁴⁺ in a weight ratio of about 50:50. The mixing ratio may be added or subtracted by 10-20%. Titanium dioxide has photocatalytic function and sterilization function

(3) tertiary mixtures of wettormarin and the mineral mixture of (2)

The tourmaline containing water prepared in the primary ion catalytic reaction bond and the mineral powder mixture of (2) are mixed at a weight ratio of about 50:50. This mixing ratio can also be added or subtracted around 10-20%.

The coating agent according to the invention, 100 parts by weight of tourmaline, 35-60 parts by weight of alkali water of pH 8-10, preferably 47.9 parts by weight, 65-85 parts by weight of titanium dioxide, preferably 74 parts by weight, Ce ³⁺ or Ce ⁴⁺ 65-85 parts by weight preferably 74 parts by weight

Water can be adjusted according to the water content of tourmaline itself. If the amount of water in the range of about the reaction can be made to the active catalytic reaction of the primary tourmaline by the hydroxyl group action. If the content of water is too small, the ion catalytic reaction is not smooth, which is not preferable.

The materials used in the coatings described above preferably use powders as much as possible, but may be larger particulates rather than necessarily powders.

Titanium dioxide with deodorizing function (Nano-TiO ₂ ) has strong oxidation and reducing power, and is excellent for deodorizing formaldehyde (HCHO) sulfur dioxide, nitrogen oxide, and various odors which are bad for the human body. The bactericidal titanium dioxide (Nano-Tion) has a corresponding antibacterial function against other strains such as Staphylococcus aureus and Pseudomonas aeruginosa.

Titanium dioxide and Ce ³⁺ or Ce ⁴⁺ may be added or subtracted in the range of about 10-20% by weight for half and half of mixing, respectively. Although it is irrelevant even if it exceeds the said range, when one component is excessively large in terms of the overall effect, since the function of another component falls, it is not preferable.

Claims (6)

(1) preparing a wet tourmaline by mixing 100 parts by weight of tourmaline mineral having an ion catalytic function and 44.4-51.9 parts by weight of alkaline water when the hydroxyl group acts; (2) Titanium dioxide mixture production process of mixing titanium dioxide and rare earth minerals of Ce ³⁺ or Ce ⁴⁺ ; And (3) A method for producing an anion release coating agent comprising the step of mixing the wet tourmaline of step (1) and the titanium dioxide mixture of step (2). The method of claim 1, The alkali water is an anion release coating method characterized in that the pH 8-10. The method of claim 1, Mixing ratio of the rare earth minerals of the titanium dioxide and Ce ³⁺ or Ce ⁴⁺ is 50:50 by weight ratio. The method of claim 1, In the process of mixing the wet tourmaline and the titanium dioxide mixture, the wet tourmaline and titanium dioxide mixture is 50:50 by weight ratio manufacturing method Tourmaline 100 parts by weight, 35-60 parts by weight of water, 65-85 parts by weight of titanium dioxide, Anionic release coating agent comprising 65 to 85 parts by weight of rare earth minerals of Ce ³⁺ or Ce ⁴⁺ The method of claim 5, wherein The water is an anionic release coating agent, characterized in that the alkaline water of pH 8-10