CN1690130A - Process for producing nano-modified health-care bamboo charcoal - Google Patents

Process for producing nano-modified health-care bamboo charcoal Download PDF

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Publication number
CN1690130A
CN1690130A CN 200410037685 CN200410037685A CN1690130A CN 1690130 A CN1690130 A CN 1690130A CN 200410037685 CN200410037685 CN 200410037685 CN 200410037685 A CN200410037685 A CN 200410037685A CN 1690130 A CN1690130 A CN 1690130A
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China
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bamboo charcoal
nano titanium
nano
titanium oxide
care
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CN 200410037685
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Chinese (zh)
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周娟
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Individual
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Individual
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Priority to CN 200410037685 priority Critical patent/CN1690130A/en
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  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

A nano modified healthy bamboo charcoal, which taking powdery bamboo charcoal of 20-400 order as main material, produced with slight nano titania and nano titania antibacterial agent. Because of porous structure and high adsorbability of bamboo charcoal, in addition to disassembling adsorbed toxic and harmful substance to carbon dioxide and water that is nontoxic and harmfulless, which is bactericide and disinfection, so the invention can clean effectively indoor air, diminish effluvium, nullifying the harm to people, which is useful in indoor mattress, velvet toy, insole and in-car cushion and backing mattress.

Description

A kind of production method of nano modification health-care bamboo charcoal
Technical field
The present invention relates to life health care articles for use technical field, particularly a kind of production method of nano modification health-care bamboo charcoal.
Background technology
Along with the Chinese society constant development of economy, the improving constantly of people's living standard, people's mode of life is also in continuous variation, and people have also had higher requirement to dress, home decoration, more beautiful, the fashion of clothes, home decoration is more luxurious.But along with the continuous development of science and technology, the various pollutions that people face increase the weight of thereupon.Clothes for example, effects such as wrinkle resistant, shrinkproof, fire-retardant can be played in order to make garment material by manufacturing enterprise, or, perhaps, in the course of processing, often add dyeing auxiliary and the resin finishing agent that contains formaldehyde in a large number in order to improve feel in order to keep stamp, painted weather resistance.In the room, furniture that some are used with artificial timber board system and the lumber core that when finishing, uses, they all contain a certain amount of formaldehyde.In the new car of buying, also exist benzene class harmful chemical.As everyone knows, formaldehyde is a kind of deleterious chemical substance, when the textiles that contains the formaldehyde that exceeds standard is made clothes and is through on one's body, and the people is in the artificial timber board Hepplewhite for a long time and use lumber core to carry out in the environment of interior decoration, because free formaldehyde can discharge gradually, after human body skin contacts, can suppress sweat gland secretion, cause xerosis cutis, crowfoot cracks, cause allergic symptoms such as skin erythema, papule, itch, also can cause respiratory inflammation simultaneously, even bring out cancer.It is a lot of to be used for indoor de-odorised product at present, and method is varied, and special-purpose distinguish the flavor of bacterial remover, deodorant to taste device, the disinfecting deodorising device etc. of going are arranged.Its method has the sorbing material of employing de-odorised, utilizes the ozone de-odorised, useful filter element filtering de-odorised, also useful chemical substance de-odorised.Adopt the sorbing material de-odorised, because the saturated shortcoming of ubiquity absorption, the time is long slightly, and effect just obviously reduces.Adopt the electrical installation de-odorised, except the needs power supply used inconvenience, prevailing price was not low, is difficult to generally adopt.At present few for preventing that fabric from causing the way of polluting, normally buy back novel clothes after, use earlier the salt water rinse, by salt sterilization, sterilization, friperie is carried out fully cool the solarization or rinsing, do not have more ways in addition.
Summary of the invention
The object of the present invention is to provide a kind of antibiotic, sterilizing function is remarkable, can eliminate the infringement of chemical substance to human body, cost is low, use range is the production method of nano modification health-care bamboo charcoal widely.
The objective of the invention is to be achieved through the following technical solutions: a kind of nano modification health-care bamboo charcoal, it is a main raw material with 20-400 order particle-like bamboo charcoal, is equipped with a small amount of nano titanium oxide and nano titanium dioxide anti-bacterial agent and makes.Add and at first count size man-hour according to the bamboo charcoal order, take out nano titanium oxide in proportion, put into and become 8-9 boiling water doubly with nano titanium oxide weight, after stirring is dissolved, add nano titanium dioxide anti-bacterial agent more in proportion, stirring makes the nano titanium oxide mixed emulsion, to become with bamboo charcoal powder weight then to stir in the 1-1.5 boiling water adding bamboo charcoal powder doubly and make bamboo charcoal suspension, again bamboo charcoal suspension is injected 100 ℃ nano titanium oxide mixed emulsion, stirring makes nano modification health-care bamboo charcoal emulsion, evaporate through routine at last, after the drying, just obtain the nano modification health-care bamboo charcoal.The content of each composition (weight) per-cent is in the health-care bamboo charcoal: nano titanium oxide 1-4%, nano titanium dioxide anti-bacterial agent 0.8-3%, bamboo charcoal powder 93-98.2%.The bamboo charcoal order is counted size and is decided according to product requirement.Bamboo charcoal order number is big more, and nano titanium oxide and nano titanium dioxide anti-bacterial agent proportion are big more.
Because bamboo charcoal itself has vesicular structure and stronger characterization of adsorption, be processed into the powder shape after, specific surface area increases suddenly, thereby characterization of adsorption strengthens suddenly, deodorizing, dehumidifying, fungi-proofing effect enlarge markedly.And the nano titanium oxide in the health-care bamboo charcoal can produce similar photosynthetic light-catalyzed reaction under the effect of light, produces extremely strong free radical and the active oxygen of oxidation capacity.These products can resolve into carbonic acid gas and water to organic pollutant (as formaldehyde, ammonia, benzene), have antibacterial, germicidal action simultaneously.Nano titanium dioxide anti-bacterial agent is on the basis of nanometer titanic oxide material, and by the metal ion antibacterial agents such as year silver that absorption or ion-exchange method are produced, it is antibacterial, sterilizing ability is more obvious.
The health-care bamboo charcoal that utilizes the present invention to produce can purify air in the room effectively, remove stench, and have dehumidifying, mildew-resistant, antibiotic, a germ-resistant function, can the formaldehyde, ammonia, phenmethyl etc. of absorption are poisonous, objectionable impurities is decomposed into nontoxic, harmless carbonic acid gas and water, can be widely used in indoor mattress, cloth type toy, shoe-pad and the indoor cushion of car, back pad, eliminate the infringement hidden danger of chemical substance, for people bring health for human body.Because this health-care bamboo charcoal possesses capacity of decomposition, do not need the cool flushing of shining simultaneously, only need the clean surface packing, get final product life-time service, keep original performance.This invention cost is low in addition, is easily accepted by consumers in general.
Embodiment
A kind of nano modification health-care bamboo charcoal, it is a main raw material with 20-400 order particle-like bamboo charcoal, is equipped with a small amount of nano titanium oxide and nano titanium dioxide anti-bacterial agent and makes.Adding man-hour, at first the bamboo section of being cut into is put into stove at secluding air or feed under the condition of little air and heat, is that 600-800 ℃ conventional pyrolytic process is made bamboo charcoal with final carbonization temperature, is ground into 20-400 purpose particle-like bamboo charcoal then.Count size according to the bamboo charcoal order again, take out nano titanium oxide in proportion, put in the boiling water of 8-9 times of nano titanium oxide weight, make its off-bottom after stirring 20-30min, and then add nano titanium dioxide anti-bacterial agent in proportion, behind the restir 10-30min, make the nano titanium oxide mixed emulsion.Used bamboo charcoal order number is big more, and nano titanium oxide and nano titanium dioxide anti-bacterial agent consumption are big more.The bamboo charcoal powder of again order of relevant nanometer amount of titanium being counted scope adds to stir in the boiling water that becomes 1-1.5 times with bamboo charcoal powder weight and makes bamboo charcoal suspension.At last bamboo charcoal suspension is injected 100 ℃ nano titanium oxide mixed emulsion, stir 30min, just make nano modification health-care bamboo charcoal emulsion.After taking-up nano modification health-care bamboo charcoal emulsion is carried out routine evaporation, drying, promptly obtain the black nano health-care bamboo charcoal.
Embodiment 1 (when bamboo charcoal order number is the 60-80 order)
Taking-up 15 gram nano titanium oxides are put into 130 gram boiling water and are stirred, make its off-bottom, add 10 gram nano titanium dioxide anti-bacterial agent restir then, make the nano titanium oxide mixed emulsion, take out 975 gram 60-80 order bamboo charcoal powders at last, join to stir in the boiling water of 1300 grams and make bamboo charcoal suspension.After again the nano titanium oxide mixed emulsion being heated to 100 ℃, bamboo charcoal suspension is injected nano titanium oxide mixing supernatant liquid, behind the stirring 30min, obtain nano modification health-care bamboo charcoal emulsion.After evaporation, drying, just obtain 1000 gram black nano modification health-care bamboo charcoals.
Embodiment 2 (when bamboo charcoal order number is the 250-300 order)
Taking-up 35 gram nano titanium oxides are put into 300 gram boiling water and are stirred, make its off-bottom, add 25 gram nano titanium dioxide anti-bacterial agent restir then, make the nano titanium oxide mixed emulsion, take out 945 gram 250-300 order bamboo charcoal powders at last, join to stir in the boiling water of 1200 grams and make bamboo charcoal suspension.After again the nano titanium oxide mixed emulsion being heated to 100 ℃, bamboo charcoal suspension is injected nano titanium oxide mixing supernatant liquid, behind the stirring 30min, obtain nano modification health-care bamboo charcoal emulsion.After evaporation, drying, just obtain 1000 gram black nano modification health-care bamboo charcoals.

Claims (4)

1. the production method of a nano modification health-care bamboo charcoal, it is characterized in that: it is a main raw material with 20-400 order particle-like bamboo charcoal, the nano titanium oxide and the nano titanium dioxide anti-bacterial agent that are equipped with suitable proportion are made, add and in proportion nano titanium oxide is put into boiling water earlier man-hour, after stirring is dissolved, add nano titanium dioxide anti-bacterial agent again, restir makes the nano titanium oxide mixed emulsion, in proportion the bamboo charcoal powder is poured into then to stir in the boiling water and made bamboo charcoal suspension, again bamboo charcoal suspension is injected 100 ℃ nano titanium oxide mixed emulsion, stirring makes nano modification health-care bamboo charcoal emulsion, evaporate through routine at last, after the drying, promptly obtain the nano modification health-care bamboo charcoal.
2. the production method of a kind of nano modification health-care bamboo charcoal according to claim 1 is characterized in that: the content of each composition (weight) per-cent is in the health-care bamboo charcoal: nano titanium oxide 1-4%, nano titanium dioxide anti-bacterial agent 0.8-3%, bamboo charcoal powder 93-98.2%.
3. the production method of a kind of nano modification health-care bamboo charcoal according to claim 1 is characterized in that: the weight ratio of nano titanium oxide and boiling water is 1: 8-9; The weight ratio of bamboo charcoal powder and boiling water is 1: 1-1.5.
4. the production method of a kind of nano modification health-care bamboo charcoal according to claim 2, it is characterized in that: nano titanium oxide is relevant with used bamboo charcoal order number with the nano titanium dioxide anti-bacterial agent proportion, bamboo charcoal order number is big more, and nano titanium oxide and nano titanium dioxide anti-bacterial agent proportion are big more.
CN 200410037685 2004-04-29 2004-04-29 Process for producing nano-modified health-care bamboo charcoal Pending CN1690130A (en)

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CN 200410037685 CN1690130A (en) 2004-04-29 2004-04-29 Process for producing nano-modified health-care bamboo charcoal

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Application Number Priority Date Filing Date Title
CN 200410037685 CN1690130A (en) 2004-04-29 2004-04-29 Process for producing nano-modified health-care bamboo charcoal

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CN1690130A true CN1690130A (en) 2005-11-02

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101173116B (en) * 2006-10-30 2011-06-22 华楙生化科技股份有限公司 Multifunctional composite powder body structure of bamboo charcoal and application in fibre production thereof
CN104448954A (en) * 2013-09-25 2015-03-25 华楙生技股份有限公司 Multifunctional porous composite powder
CN105034134A (en) * 2015-07-29 2015-11-11 安徽鑫润新型材料有限公司 Waterproof, corrosion-resistant and health-care fiber composite board and manufacturing method thereof
CN105034135A (en) * 2015-07-29 2015-11-11 安徽鑫润新型材料有限公司 Flame-retardant and health-care fiber composite board and manufacturing method thereof
CN105058545A (en) * 2015-07-29 2015-11-18 安徽鑫润新型材料有限公司 Oil-proof antifouling health-care fiber composite board and manufacturing method thereof
CN105108875A (en) * 2015-07-29 2015-12-02 安徽鑫润新型材料有限公司 Mildewproof dampproof health-care fiber composite board and preparation method thereof
CN105286200A (en) * 2015-08-17 2016-02-03 张伟鑫 Deodorization insole and preparation method thereof
CN109157055A (en) * 2018-09-20 2019-01-08 浙江万昌家具股份有限公司 The production technology of bamboo charcoal nano sping mattress

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101173116B (en) * 2006-10-30 2011-06-22 华楙生化科技股份有限公司 Multifunctional composite powder body structure of bamboo charcoal and application in fibre production thereof
CN104448954A (en) * 2013-09-25 2015-03-25 华楙生技股份有限公司 Multifunctional porous composite powder
CN104448954B (en) * 2013-09-25 2016-09-28 华楙生技股份有限公司 Multifunctional porous matter composite granule
CN105034134A (en) * 2015-07-29 2015-11-11 安徽鑫润新型材料有限公司 Waterproof, corrosion-resistant and health-care fiber composite board and manufacturing method thereof
CN105034135A (en) * 2015-07-29 2015-11-11 安徽鑫润新型材料有限公司 Flame-retardant and health-care fiber composite board and manufacturing method thereof
CN105058545A (en) * 2015-07-29 2015-11-18 安徽鑫润新型材料有限公司 Oil-proof antifouling health-care fiber composite board and manufacturing method thereof
CN105108875A (en) * 2015-07-29 2015-12-02 安徽鑫润新型材料有限公司 Mildewproof dampproof health-care fiber composite board and preparation method thereof
CN105286200A (en) * 2015-08-17 2016-02-03 张伟鑫 Deodorization insole and preparation method thereof
CN109157055A (en) * 2018-09-20 2019-01-08 浙江万昌家具股份有限公司 The production technology of bamboo charcoal nano sping mattress

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