KR100913191B1 - Grain shell treating method and a pillow thereby - Google Patents

Abstract

A method for processing grain shell and a pillow using the same are provided, which enables preservation and use of the grain shell for a long time without putrefaction. A method for processing a grain shell comprises: a process of preparing water-tourmaline mixture; a process of mixing a material having either Ce^3+ or Ce^4+; a process of mixing water-tourmaline and titanium dioxide to produce a third mixture; a process of mixing starch and grain shell; a process of mixing 5-9 weight part, 100 weight part of talc, and 28.6-42.9 weight part of water; a process of stirring or dispersing 56-64 weight part of talc mixture to coat; and a process of drying the grain shell.

Description

Grain shell treating method and a pillow using the same

The present invention relates to a processing method of grain husks and a pillow using the same, which can be used as a material for household goods such as pillows, cushions, cushions, mats by processing grain husks, for example, buckwheat husks.

Among the grain husks, it is widely known that buckwheat husks are good for health.

At present, the contents covering the pillow are mostly acrylic cotton and buckwheat skin. Acrylic cotton, however, does not absorb sweat from the head during bedtime and smells bad for long-term use, and general buckwheat husks can decay and cause secondary pollution due to poor breathability in the pillow. It is undesirably decaying inside and bacteria grow.

Accordingly, researches to replace the contents for pillows are being actively conducted. For example, ocher balls, sponges with wet coating of ocher, etc., and the ocher balls are heavy in weight and have no soft touch, and wet sponges with ocher are not breathable and sweat absorbent, and thus are applied to the contents of the pillow. Not suitable for

In particular, recently, pillow products for improving health and a good sleep are being developed and marketed, but a small number of products which are artificially anion and far-infrared radiation are known to generate cations and ozone. Excessive cations and ozone are not suitable for household goods because they cause mucosal coagulation, lung cells and respiratory disorders, and they show satisfactory performance in recent environmentally friendly, bio, deodorizing and antibacterial properties. Therefore, there is an urgent need for the contents of the pillow for a comfortable sleep.

The present invention is to solve the above-mentioned problems, the grain shell, for example, tourmaline (Toumaline), a silicate ore that emits anions in various compositions to prevent the buckwheat shells from spoiling, titanium dioxide with sterilizing function (Nano-Tion), a mixed powder obtained by mixing a talc having a high content of SiO 2 with far-infrared radiation at a constant rate, is applied with a natural starch resin and sprayed onto a wet buckwheat hull, which is applied with a natural mineral that does not rot. The present invention provides a method for processing grain husks.

The main constitution of the present invention comprises: (1) a water-tormarin mixture preparation step of mixing 100 parts by weight of tourmaline mineral with 44.4-51.9 parts by weight of water; (2) Titanium dioxide and rare earth element Ce To mix a substance containing a state of Ce ³⁺ or Ce ⁴⁺ (e.g. CeCl ₄ , CeCl ₃ , Ce ₂ (SO ₄ ) ₃ , Ce (CO ₃ ) ₂ , CeO ₂ , Ce ₂ O _3, etc.) Titanium dioxide mixture production process; (3) a tertiary mixture preparation step of mixing the water-wetting tourmaline mixture with the titanium dioxide mixture described above; (4) a grain husk mixing step of mixing starch and grain husk; (5) a talc mixture preparation step of mixing 5-9 parts by weight of the tertiary mixture, 100 parts by weight of talc, and 28.6-42.9 parts by weight of water; (6) a step of coating by spraying or stirring 56-64 parts by weight of the talc mixture mixed in (5) with respect to 100 parts by weight of the wet grain husk mixed in (4); (7) characterized in that it comprises a step of drying the grain husk coated in a drying apparatus, wherein the water used in the water-tormarin mixture preparation process is alkaline water of pH 8-9 Titanium and rare earth elements Ce Rare earth minerals of substances containing states such as Ce ³⁺ or Ce ⁴⁺ (e.g. CeCl ₄ , CeCl ₃ , Ce ₂ (SO ₄ ) ₃ , Ce (CO ₃ ) ₂ , CeO ₂ , Ce ₂ O _3, etc.) The mixing ratio is characterized in that 50:50 by weight ratio, in the tertiary mixture manufacturing process of mixing the water-tormarin mixture and the titanium dioxide mixture, the water-tormarin mixture and titanium dioxide mixture is a weight ratio It characterized in that the 50:50, in the grain shell mixing process of mixing the starch and grain husk, the starch and grain husk mixing is characterized in that the weight ratio of 50:50, the starch and grain husk At the time of mixing the grain husk mixing step, after the mixing, characterized in that it further comprises a aging step 10-20 hours, mixing the above-mentioned tertiary mixture 5-9 parts by weight, talc 100 parts by weight, water 28.6-42.9 parts by weight The water used in the talc mixture preparation process is characterized in that the pH 7 or more And characterized in that the pillow is prepared by putting the grain husk prepared in claim 1 into the pillow

Commonly used grain husks, for example, buckwheat husks are not breathable, so if they rot, they are difficult to be stored for a long time due to the development of bacteria and mold, which makes it difficult to use them for a long time in a pillow. The spray coating of natural mineral powder on the grain shell, for example, when used in a pillow, does not form a film on the surface of the natural mineral attached to the surface of the grain shell.

Grain husks treated according to the invention are human and environmentally friendly

In other words, tonerline, silicate ore that emits negative ions, titanium dioxide (Nano-Tion) with sterilizing function, and talc, which has far-infrared radiation-induced Sio2 content, are mixed in a certain ratio among natural ore components coated with powder. It is able to release anion smoothly, and can act as far-infrared radiation, deodorizing and antibacterial.

In addition, buckwheat husks coated with natural mineral powders prevent microscopic parasites such as mites, moths and head lice, and prevent mold from general grain husks.

It also deodorizes the smells of formaldehyde and odors in the indoor air, so when used as a pillow, for example, it clears the air around the pillow.

In addition, for example, the general buckwheat husk is weak and the cortex itself is not restoring force and durability when subjected to the compressive force, but the present invention is a natural starch resin immersed in the hull cortex, so that the film is molded and resistant to the compressive force, natural starch resin Since the natural ore composition powder is sprayed before drying, the cortex becomes an organic coating, so durability is strongly formed.

According to the present invention, by using the grain husks such as buckwheat, which has been disposed of by conventional storage and use, there is an effect of reducing acrylic cotton production raw materials by replacing acrylic cotton used as a material of various household goods.

Hereinafter, the present invention will be described in detail with reference to specific examples.

(1) Preparation of Primary Water-Tormarin Mixture

First, based on 100 parts by weight of tourmaline mineral, 44.4-51.9 parts by weight of water, preferably 48.1 parts by weight is mixed. For water, use alkaline water of pH 8-10. Thus, the reaction of the hydroxyl ion makes the primary ion catalyst reaction bond.

As is already known, the chemical composition of toumaline, an anion-releasing silicate ore, is a complex borosilicate of aluminum, such as iron, magnesium, alkali metals and the like. It is usually hexagonal or nine-angled, sometimes triangular, and sometimes different in crystalline form. They also have flat rhombohedrons, needles, and hairs, and sometimes form granules or blocks. The cleavage is not clear, and the monocytes are not flat or shell-shaped. Hardness 7.0-7.5 and specific gravity 2.98-3.20. Glass gloss or resin gloss. Electricity is generated by friction, and this name is given because both ends are charged positively and negatively when heated.

Known main effects of tourmaline, known as a spontaneous electrode with ion catalytic function and a permanent electrode, are known to release anions naturally.

-Water quality improvement

Weak alkaline (optimum PH7.4), subdividing clusters of water (molecular population),

Contains minerals, bactericidal effect, deodorant effect, removes chlorine odor

-Health Improvement

Negative ions are good for skin with excellent metabolism, cell function, immune function activation, blood purification, autonomic nerve stabilization, penetration, wetting and moisturizing effect.

-Environmental improvement

Significantly reduced foreign matters and odors in drains, water is good for cleaning, reducing detergent usage, removing pet odors and promoting plant growth

-Effect in life

When you put tourmarin in your bathtub or washbasin, you'll feel warm even at low temperatures. Appetite increased. My shoulders have softened Atopy improved. Athlete's foot was cured. The skin is smooth. The smell is gone. I have asthma. The bathtub does not get dirty. The smell of the drain is gone.

-In the drink

Tea and coffee taste better. The smell of the mouth is gone. Appetite increased. Constipation is gone. Chlorine odor has been removed.

-Smelly places

The smell of the refrigerator is removed. The smell of the bed disappears. The smell of cigarettes and mold disappears.

-Used for cleaning

Even with less detergent, the washing effect is the same. Mold did not fall well fell off. The contact lens and glasses were cleaned well.

-For use in aquariums or ponds

Goldfish and tropical fish do not get dirty. The unpleasant smell went away. Used for any fish (fresh water, saltwater) Pond odors disappeared and the water became clear.

-Used for flowerbed vases

Flowers last long Water does not rot The growth of plants is fast. The color of the flower is vivid. Pests disappear. Vegetables grow very well. Rice, vegetables and fruits taste good

(2) secondary rare earth mineral mixtures

And titanium dioxide and rare earth elements, Ce Substances containing such a state of Ce ³⁺ or Ce ⁴⁺ (e.g. CeCl ₄ , CeCl ₃ , Ce ₂ (SO ₄ ) ₃ , Ce (CO ₃ ) ₂ , CeO ₂ , Ce ₂ O _3, etc.) Prepare a mineral powder mixture mixed at about 50:50 The mixing ratio may be added or subtracted to around 10-20% Titanium dioxide has a photocatalytic function and a sterilization function

(3) a tertiary mixture of a water-tourmaline mixture and the mineral mixture of (2)

The tourmaline containing water prepared in the primary ion catalytic reaction bond and the mineral powder mixture of (2) are mixed at a weight ratio of about 50:50. This mixing ratio can also be added or subtracted around 10-20%.

(4) quaternary mixtures of starch and cereal (eg buckwheat) husks

And prepare fiber starch resin

"Fiber starch resin" is a resin in which starch extracted from potatoes, sweet potatoes, and the like, and aliphatic polyester which is harmless to humans to eat. This starch resin is an environmentally friendly resin that contains no harmful gases even after it is burned. This eco-friendly natural starch resin is produced by a manufacturing company in Korea, for example, S & B Environment Co., Ltd.

The starch resin and the buckwheat husk are mixed at a weight ratio of about 50:50.

The mixing ratio may be reduced by 10-20%. The mixing ratio may be further added or subtracted, and may be in a state of sufficient humidity to have adhesion to the buckwheat husk. The above resins are not necessarily starch resins, and any other resin may be used if the resin is harmless to the human body. Buckwheat husks are not limited to this and other similar grain husks may be used.

The buckwheat husks with the starch absorbed are subjected to a aging process to further improve the adhesion of the starch, that is, to absorb sufficient starch. It takes about 10-20 hours to mature. In this way, the starch resin, which serves as an adhesive to the buckwheat shell, is applied evenly and has sufficient aging time, and the coating may be well performed in a subsequent process.

(5) Preparation of the fifth talc mixture

5-9 parts by weight of the tertiary mixture, which is the water-tormarin mixture of (3) and the mineral mixture of (2), preferably 7 parts by weight, 100 parts by weight of talc, 28.6-42.9 parts by weight of water, preferably 35.7 parts by weight do

Talc is prepared in powder form with high SiO ₂ content emitting far infrared rays.

Talc is a colorless to gray powder that is widely used in rubber, medicine, fire protection materials, plating, insecticides, flame retardants, fillers, etc. and has a molecular formula of Mg 3 H 2 (SiO 3) 4. Talc is hydrophobic to water and has a strong affinity for organics, so it has strong adhesion (adhesiveness) and excellent water resistance when added to resins, rubbers, etc. Instead of talc, other materials with high SiO ₂ content may be used.

It is preferable that water uses pH 7 or more. The reason is because of the ion reaction effect as described above. Another reason for the alkaline aqueous solution to enter is to prevent the deterioration or mixing of other materials when mixing with other materials. If the water content is above the above range, the adhesive strength is lowered, and if it is less than this, the fluidity is poor, which is not preferable.

(6) 5th mixture coating process of buckwheat husk

With respect to 100 parts by weight of the strong and wet buckwheat husk prepared in the fourth mixing aging step, 56-64 parts by weight, preferably 50 parts by weight of the above-mentioned fifth talc mixture is sprayed or stirred. The talc mixture is sufficiently coated on the buckwheat husk prepared in the fourth mixing ripening step, so that the buckwheat husk is coated.

If the input ratio of the talc mixture is more than the above range, there is a problem that the talc mixture is not attached, if it is less than that, the entire coating is not complete.

Then, the buckwheat husks coated with the mineral mixture powder are sufficiently dried in a predetermined drying apparatus.

Look at the various experimental data on the buckwheat husk coated according to the present invention

In the buckwheat husk shell according to the present invention, the anion emission was measured by the KICM-FIR-1042 test method.

Table 1 Anion Release Test Report

Test Items Test result Test Methods Anion (ION / cc)  Normal buckwheat husk 75 KICM-FIR-1042 (Korea Institute of Construction Materials)  Buckwheat peel of the present invention 2412

As shown in the test report, the anion release was excellent in the buckwheat husk according to the present invention.

In the natural mineral talc is mainly composed of Al and Si, the results of the measurement of the far infrared radiation effect is shown in Table 2.

Table 2 Far-infrared emission test report

Test Items Test result Test Methods Far infrared ray emission amount (40 ℃) Emissivity (5 ~ 20㎛) 0.913  KICM-FIR -1005 (Korea Institute of Construction Materials) Radiant energy (w / ㎡) 3.68 ㅧ 100

As shown in the test report, it emits radiation in the far-infrared wavelength, which is widely known to be beneficial to the human body.

Titanium dioxide (Nano-Tion), which has a deodorizing function, has strong oxidation and reducing power, and is excellent for deodorizing formaldehyde (HCHO) sulfur dioxide, nitrogen oxide, and various odors which are not good for the human body. Table 4 below is a deodorization test report

[Table 4] Deodorization test report (using HCHO)

 Test Items Deodorization test Elapsed time Empty concentration (ppm) Sample concentration (ppm) Deodorization rate (%)   Test result 0 81 81 0 30 78 34 56.4 60 75 30 60.0 90 72 27 62.5 120 70 25 64.3 Test Methods KICM-FIR-1085 (Korea Building Materials Testing Institute)

Titanium dioxide with bactericidal function (Nano-Tion) was measured by KICM-FIR-1002 to have a corresponding antibacterial function against other strains such as Staphylococcus aureus, Pseudomonas aeruginosa. (See Table 5 below)

[Table 5] Antimicrobial Test Report
Test Items Test result Test Methods Initial concentration (CFU / 40p) Concentration after 24 hours (CFU / 40p) Bacterial Reduction Rate (%) Antibacterial test by E. coli Normal buckwheat husk 422 2882 KICM-FIR-1002 (Korea Institute of Construction Materials) Invented Buckwheat Peel 422 3 99.3

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The buckwheat husk, which has undergone the above-described treatment, can be used as a core material such as a pillow, a cushion, a cushion, a mat, and the like.

The buckwheat husks described above are merely exemplary and may also use the husks of other grains and other crops beneficial to the human body, and these should also be included in the technical scope of the present invention.

Claims (8)

(1) a water-tourmarin mixture preparation step of mixing 100 parts by weight of tourmaline mineral with 44.4-51.9 parts by weight of water; (2) Titanium dioxide and rare earth element Ce Mix materials containing CeCl ₄ , CeCl ₃ , Ce ₂ (SO) ₄ , Ce (CO ₃ ) ₂ , CeO ₂ and Ce ₂ O ₃ selected from the group consisting of Ce ³⁺ or Ce ⁴⁺ Titanium dioxide mixture production process; (3) a tertiary mixture preparation step of mixing the water-tormarin mixture and the titanium dioxide mixture described above; (4) a grain husk mixing step of mixing starch and grain husk; (5) a talc mixture preparation step of mixing 5-9 parts by weight of the tertiary mixture, 100 parts by weight of talc, and 28.6-42.9 parts by weight of water; (6) a step of coating by spraying or stirring 56-64 parts by weight of the talc mixture mixed in (5) with respect to 100 parts by weight of the wet grain husk mixed in (4); (7) a grain husk processing method comprising the step of drying the coated grain husk in a drying apparatus; The method of claim 1, The water used in the water-tormarin mixture preparation step is a processing method of grain husk, characterized in that the alkaline water of pH 8-9 The method of claim 1, Titanium dioxide and the rare earth element Ce Mix materials containing CeCl ₄ , CeCl ₃ , Ce ₂ (SO) ₄ , Ce (CO ₃ ) ₂ , CeO ₂ and Ce ₂ O ₃ selected from the group consisting of Ce ³⁺ or Ce ⁴⁺ The ratio is 50:50 by weight ratio, The grain husk processing method. The method of claim 1, In the tertiary mixture preparation step of mixing the water-tormarin mixture and the titanium dioxide mixture, the water-tormarin mixture and the titanium dioxide mixture are 50:50 in weight ratio. The method of claim 1, In the grain husk mixing step of mixing the starch and grain husk, the processing method of grain husk, characterized in that the mixing of starch and grain husk is 50:50 in weight ratio The method of claim 1, At the time of the grain husk mixing step of mixing the starch and grain husk, after the mixing, the processing method of grain husk, characterized in that it further comprises a aging process for 10-20 hours The method of claim 1, 5-9 parts by weight of the tertiary mixture, 100 parts by weight of talc, water 28.6-42.9 parts by weight of water used in the talc mixture preparation step of mixing process characterized in that the pH of 7 or more processing method A pillow prepared by putting a grain husk prepared by any one of claims 1 to 7 into a pillow.